JPH03161428A - Cleansing cosmetic - Google Patents

Cleansing cosmetic

Info

Publication number
JPH03161428A
JPH03161428A JP29996289A JP29996289A JPH03161428A JP H03161428 A JPH03161428 A JP H03161428A JP 29996289 A JP29996289 A JP 29996289A JP 29996289 A JP29996289 A JP 29996289A JP H03161428 A JPH03161428 A JP H03161428A
Authority
JP
Japan
Prior art keywords
liquid
oil
cleansing cosmetic
polyoxyethylene
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP29996289A
Other languages
Japanese (ja)
Other versions
JP2977568B2 (en
Inventor
Tadashi Matsui
正 松井
Keizo Tezuka
手塚 敬三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanebo Ltd
Original Assignee
Kanebo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
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Application filed by Kanebo Ltd filed Critical Kanebo Ltd
Priority to JP1299962A priority Critical patent/JP2977568B2/en
Publication of JPH03161428A publication Critical patent/JPH03161428A/en
Application granted granted Critical
Publication of JP2977568B2 publication Critical patent/JP2977568B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Cosmetics (AREA)

Abstract

PURPOSE:To obtain a cleansing cosmetic, composed of a specific nonionic surfactant, water and an oil which is a liquid at ordinary temperature and excellent in preservation stability and various organoleptic characteristics. CONSTITUTION:A cleansing cosmetic composed of (A) 5.0-15.0wt.% nonionic surfactant, composed of one or two or more pasty nonionic surfactants which are liquid or pasty at ordinary temperature and having 7-14 HLB value, e.g. sorbitan monolaurate, glycerol monooleate, polyoxyethylene sorbitol tetraoleate (40 EO), (B) 0.1-2.0wt.% deionized purified water or purified water and (C) 80-95% oil which is a liquid at ordinary temperature, e.g. liquid paraffin, squalane, synthetic ester oil (e.g. isopropyl myristate) or a vegetable oil (e.g. olive oil). The respective raw materials can be homogeneously mixed and dissolved while, as necessary, heating the materials to afford a liquid transparent cleansing cosmetic.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、非イオン界面活性剤と水と油からなる、保存
安定性及び官能特性に優れたクレンジング化粧料に関す
る. 〔従来の技術および発明が解決しようとする課題〕 一a的に、液状の油をベースとしたクレンジングオイル
は油を含む汚れに対し相溶性に優れ、クレンジング効果
が高いが、反面界面活性剤を含有しない為に、水で洗い
流すことができないという欠点を有していることが知ら
れている。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a cleansing cosmetic composition comprising a nonionic surfactant, water and oil and having excellent storage stability and sensory properties. [Prior art and problems to be solved by the invention] First, cleansing oils based on liquid oil have excellent compatibility with oil-containing dirt and have a high cleansing effect, but on the other hand, they do not contain surfactants. It is known that it has the disadvantage that it cannot be washed away with water because it does not contain it.

又、特開昭62−108806号公報には特定の非イオ
ン界面活性剤と液体油とを必須成分として含有する非水
クレンジング料が開示され、水での洗い流しに関しては
改善されているものの、保存安定性については未だ不十
分である。
Furthermore, JP-A-62-108806 discloses a non-aqueous cleansing agent containing a specific non-ionic surfactant and liquid oil as essential ingredients, and although it is improved in terms of rinsing with water, it is difficult to store. Stability is still insufficient.

すなわち本発明客#増は、各種官能特性に優れている上
、保存安定性の高いクレンジング化粧料を提供すること
を目的としている。
That is, the objective of the present invention is to provide a cleansing cosmetic composition that is excellent in various sensory properties and has high storage stability.

〔課題を解決するための手段〕[Means to solve the problem]

本発明は、 (a)常温で液状ないしペースト状の非イオン界面活性
剤の1種又は2種以上から戒る、HLI直7〜14の非
イオン界面活性剤5.0〜1 5. 0重量%. (b)水0. 1〜2. 0重量%. (c)常温で液状の油5 からなることを特徴とするクレンジング化粧料である. 以下、本発明の構戊について詳説する.本発明に用いら
れる非イオン界面活性剤は、常温で液状ないしペースト
状で、その1種又は2種以上を組合せて用いられる。
The present invention provides: (a) One or more nonionic surfactants that are in liquid or paste form at room temperature, HLI direct 7 to 14 nonionic surfactants 5.0 to 1. 0% by weight. (b) Water 0. 1-2. 0% by weight. (c) A cleansing cosmetic comprising an oil that is liquid at room temperature. The structure of the present invention will be explained in detail below. The nonionic surfactants used in the present invention are liquid or paste at room temperature, and may be used alone or in combination of two or more.

個々の非イオン界面活性剤のH L B {iは、特に
制約されることはなく、非イオン界面活性剤全体として
7〜l4になる様に調整できるものであれば良い。
The H L B {i of each nonionic surfactant is not particularly limited, and may be one that can be adjusted to 7 to 14 for the nonionic surfactant as a whole.

具体的には例えば、ソルビタン脂肪酸エステルでは、ソ
ルビタンモノラウレート,ソルビタンモノオレエート.
ソルビタンセスキイソステアレート等,グリセリン脂肪
酸エステルでは、グリセリンモノオレエート.グリセリ
ンモノイソステアレート等,ポリグリセリン脂肪酸エス
テルでは、ジグリセリルモノオレエート.ヘキサグリセ
リルモノミリステート,デカグリセリルジイソステアレ
ート等,ボリオキシエチレンソルビタン脂肪酸エステル
では、ボリオキシエチレンソルビタンモノオレエート(
6E.O.) ,ボリオキシエチレンソルビタントリオ
レエート(20E.O.)等.ボリオキシエチレンソル
ビノト脂肪酸エステルでは、ボリオキシエチレンソルビ
ソトテトラオレエート(40E.O,) ,ポリオキシ
エチレンソルビットモノラウレート(6E.O.)等,
ボリオキンエチレングリセリン脂肪酸エステルでは、ボ
リオキシエチレングリセリルモノオレエート(5E.O
.) ,ボリオキシエチレングリセリルモノオレエート
(15E.o,)等.ポリエチレングリコール脂肪酸エ
ステルでは、ボリオキシエチレンモノラウレート(10
E.O.),ボリオキシエチレンモノオレエー1− (
6B.0.)等,ボリオキシエチレンアルキルエーテル
では、ポリオキシエチレンラウリルエーテル(2E.O
.) .ポリオキシェチレンオレイルエーテル(7E.
O.)等.ポリオキシエチレンポリオキシプロビレンア
ルキルエーテルでは、ポリオキシエチレン(1)ボリオ
キシプロピレン(4)セチルエーテル等.ポリオキシェ
チレンアルキルフエニルエーテルでは、ボリオキシェチ
レンノニルフエニルエーテル(5E.O,) ,ポリオ
キシェチレンノニルフエニルエーテル(10[!.0,
) 等,ポリオキシエチレンヒマシ油・硬化ヒマシ油で
は、ポリオキシエチレンヒマシ油(20[!.0.),
ポリオキシエチレン硬化ヒマシ油(40E.O,)等,
トリ (ポリオキシエチレンアルキルエーテル)リン酸
でハ、トリ(ボリオキシエチレン(4)ラウリルエーテ
ル)リン酸等が好ましいものとして挙げることができる
が、これらに限定されるものではない。
Specifically, for example, sorbitan fatty acid esters include sorbitan monolaurate, sorbitan monooleate.
Among glycerin fatty acid esters such as sorbitan sesquiisostearate, glycerin monooleate. Among polyglycerin fatty acid esters such as glycerin monoisostearate, diglyceryl monooleate. Among polyoxyethylene sorbitan fatty acid esters such as hexaglyceryl monomyristate and decaglyceryl diisostearate, polyoxyethylene sorbitan monooleate (
6E. O. ), polyoxyethylene sorbitan trioleate (20E.O.), etc. Polyoxyethylene sorbitate fatty acid esters include polyoxyethylene sorbitotetraoleate (40E.O.), polyoxyethylene sorbitol monolaurate (6E.O.), etc.
Borioquin ethylene glycerin fatty acid ester is polyoxyethylene glyceryl monooleate (5E.O
.. ), polyoxyethylene glyceryl monooleate (15E.o,), etc. Among polyethylene glycol fatty acid esters, polyoxyethylene monolaurate (10
E. O. ), polyoxyethylene monooleate 1- (
6B. 0. ), polyoxyethylene alkyl ether, polyoxyethylene lauryl ether (2E.O
.. ). Polyoxyethylene oleyl ether (7E.
O. )etc. Examples of polyoxyethylene polyoxypropylene alkyl ether include polyoxyethylene (1) polyoxypropylene (4) cetyl ether, etc. Polyoxyethylene alkyl phenyl ethers include boroxyethylene nonylphenyl ether (5E.O,), polyoxyethylene nonylphenyl ether (10[!.0,
), polyoxyethylene castor oil/hydrogenated castor oil, polyoxyethylene castor oil (20[!.0.), etc.
Polyoxyethylene hydrogenated castor oil (40E.O,) etc.
Preferable examples include tri(polyoxyethylene alkyl ether) phosphoric acid, tri(polyoxyethylene (4) lauryl ether) phosphoric acid, but the present invention is not limited thereto.

非イオン界面活性剤全体としてのHLB値は7〜I4で
ある。
The HLB value of the nonionic surfactant as a whole is 7 to I4.

HLB値が7未満ではクレンジング化粧料を水で洗い流
しにくくなり、14を超えると液体油との相溶性が悪く
なり保存安定性も低下する.非イオン界面活性剤の含有
量は、クレンジング化粧料全体を100重量%として5
.0〜l5.0重量%である. 5.0重量%未満ではクレンジング化粧料を水で洗い流
しにくくなり、■5.0重量%を超えると保存安定性が
低下し易くなる. 本発明に用いられる水は、イオン交換樹脂で処理した脱
イオン精製水又は、蒸留水等の精製水が、一般に用いら
れる。
If the HLB value is less than 7, the cleansing cosmetic will be difficult to wash off with water, and if it exceeds 14, the compatibility with liquid oil will deteriorate and the storage stability will decrease. The content of nonionic surfactant is 5% by weight of the entire cleansing cosmetic.
.. 0 to 5.0% by weight. If it is less than 5.0% by weight, it becomes difficult to wash away the cleansing cosmetic with water, and if it exceeds 5.0% by weight, storage stability tends to decrease. The water used in the present invention is generally deionized purified water treated with an ion exchange resin or purified water such as distilled water.

また、水とともに、エタノールを適用することもできる
Moreover, ethanol can also be applied together with water.

本発明に用いられる常温で液状を呈する油は、例えば流
動バラフィン.スクワラン.液状の合戒エステル油(イ
ソブロピル1リステート,イソプロビルパルミテート,
トリ−2−エチルヘキサン酸グリセリン等).i状の植
物油(オリーブ油,サフラワー油等)等を挙げることが
できるが、これらに限定されるものではない。
The oil that is liquid at room temperature used in the present invention is, for example, liquid paraffin. Squalane. Liquid Hekai ester oil (isopropyl 1 lystate, isopropyl palmitate,
glycerin tri-2-ethylhexanoate, etc.). Examples include, but are not limited to, i-form vegetable oils (olive oil, safflower oil, etc.).

これらの液状の油は単独または2種以上を組合せて使用
することができる。
These liquid oils can be used alone or in combination of two or more.

その含有量は、およそ80〜95重景%であるが、これ
に限定されるものではない。
Its content is approximately 80-95%, but is not limited to this.

本発明のクレンジング化粧料には、上記成分のほかに、
多価アルコール.香料.色素,防腐剤,殺菌剤.#化防
止剤,紫外線吸収剤,パール剤,油性ゲル化剤.皮膚栄
養剤など、通常化粧料に用いらる原料を本発明の目的を
違或する範囲で適宜配合することができる. 〔実施例〕 以下、実施例にて本発明を説明する. 実施例に記載の%とは重量%を意味する。
In addition to the above ingredients, the cleansing cosmetic of the present invention includes:
Polyhydric alcohol. Fragrance. Pigments, preservatives, fungicides. Antioxidant, ultraviolet absorber, pearl agent, oil-based gelling agent. Raw materials commonly used in cosmetics, such as skin nutrients, may be appropriately incorporated within the scope of the purpose of the present invention. [Example] The present invention will be explained below with reference to Examples. % described in Examples means % by weight.

実施例に記載の保存安定性試験.官能特性試験は下記の
方法にて実施した。
Storage stability test described in Examples. The sensory characteristics test was conducted using the following method.

(1)  保存安定性試験 試料を5℃及び45℃の恒温槽に入れ、2週間後の状態
を観察した。
(1) Storage stability test Samples were placed in thermostats at 5°C and 45°C, and the condition was observed after 2 weeks.

(2)  官能特性試験 パネル20人によって官能特性試験を行ない、「汚れと
のなしみ易さ」,「水によるすすぎ易さ」,「洗い上り
」の各項目について「汚れとのなじみが良い」.「水に
よるすすぎが容易である」,「汚れを含んだ油が皮膚に
残らない」と答えた人数を示した. 実施例1〜3.比較例1〜3 (戒状透明クレンジング
化粧料). 第1表上段の組或の如く、液状透明クレンジング化粧料
を調製し、前記諸試験を実施した。その結果を第1表下
段に示した。
(2) Sensory properties test A sensory property test was conducted by a panel of 20 people, and the results were ``good compatibility with dirt'' for each of the following items: ``ease of staining'', ``ease of rinsing with water'', and ``washing up''. The number of people who answered that ``rinsing with water is easy'' and ``no oil containing dirt remains on the skin'' was shown. Examples 1-3. Comparative Examples 1 to 3 (Kaisho transparent cleansing cosmetics). A liquid transparent cleansing cosmetic composition was prepared as shown in the upper row of Table 1, and the various tests described above were conducted. The results are shown in the lower part of Table 1.

(調製方法) 組戒中の各原料を必要に応して加温しながら均一に混合
溶解して、液状透明クレンジング化粧料を得た。
(Preparation method) Each raw material in the composition was uniformly mixed and dissolved while heating as necessary to obtain a liquid transparent cleansing cosmetic.

(特性) 第1表の如く、精製水を含有しない比較例1及び4.0
%配合の比較例2では保存安定性が悪く、二層に分離し
た。
(Characteristics) As shown in Table 1, Comparative Examples 1 and 4.0 that do not contain purified water
In Comparative Example 2, which had a composition of %, the storage stability was poor and it separated into two layers.

固体状のボリオキンエチレンモノステアレート(10E
.O,)を含有した比較例3では、保存安定性,官能特
性ともに悪かった。
Solid vorioquine ethylene monostearate (10E
.. In Comparative Example 3 containing O,), both storage stability and sensory characteristics were poor.

一方、実施例1〜3は保存安定性,官能特性と実施例4
〜7,比較例4〜7 (液状透明クレンジング化粧料) 第2表上段のU或にて、実施例1と同様にして液状透明
クレンジング化粧料を調製し、前記緒試HLB{直が4
.3であるソノレビタンモノオレエートを含有した比較
例4及び、界面活性剤の含有量が2.5%である比較例
5は、「水によるすすぎ易さ」 「洗い上り」が悪かっ
た. H L B {直が15のボリオキシエチレンソノレビ
クンモノオレエート(20E.O,)を含有している比
較例6.及び非イオン界面活性剤を20.0%含有して
いる比較例7では、保存安定性が悪く、二層に分れ7.
0.9.9.14.0.及び10.3である実施例4〜
7は、保存安定性.官能特性ともに優れていた。
On the other hand, Examples 1 to 3 show storage stability, sensory properties, and Example 4.
~7, Comparative Examples 4 to 7 (Liquid transparent cleansing cosmetics) Liquid transparent cleansing cosmetics were prepared in the same manner as in Example 1 at U in the upper row of Table 2, and
.. Comparative Example 4 containing sonolevitan monooleate (No. 3) and Comparative Example 5 containing 2.5% surfactant had poor ``ease of rinsing with water'' and ``washing off''. H L B {Comparative Example 6 containing polyoxyethylene sonolevicune monooleate (20E.O,) with a diameter of 15. Comparative Example 7 containing 20.0% of nonionic surfactant had poor storage stability and separated into two layers.
0.9.9.14.0. and Example 4~ which is 10.3
7 is storage stability. Both sensory properties were excellent.

〔発明の効果〕〔Effect of the invention〕

以上記載の如く、本発明は保存安定性及び官能特性に優
れた有用なるクレンジング化粧料を提供することは明ら
かである。
As described above, it is clear that the present invention provides a useful cleansing cosmetic composition with excellent storage stability and sensory properties.

Claims (1)

【特許請求の範囲】 (a)常温で液状ないしペースト状の非イオン界面活性
剤の1種又は2種以上から成る、 HLB値7〜14の非イオン界面活性剤5.0〜15.
0重量%、 (b)水0.1〜2.0重量%、 (c)常温で液状の油、 からなることを特徴とするクレンジング化粧料。
[Scope of Claims] (a) A nonionic surfactant having an HLB value of 7 to 14 and 5.0 to 15.
0% by weight, (b) 0.1 to 2.0% by weight of water, and (c) an oil that is liquid at room temperature.
JP1299962A 1989-11-17 1989-11-17 Cleansing cosmetics Expired - Fee Related JP2977568B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1299962A JP2977568B2 (en) 1989-11-17 1989-11-17 Cleansing cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1299962A JP2977568B2 (en) 1989-11-17 1989-11-17 Cleansing cosmetics

Publications (2)

Publication Number Publication Date
JPH03161428A true JPH03161428A (en) 1991-07-11
JP2977568B2 JP2977568B2 (en) 1999-11-15

Family

ID=17879073

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1299962A Expired - Fee Related JP2977568B2 (en) 1989-11-17 1989-11-17 Cleansing cosmetics

Country Status (1)

Country Link
JP (1) JP2977568B2 (en)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05178734A (en) * 1991-12-27 1993-07-20 Kose Corp Solid-like water-in-oil type emulsified cosmetic
JPH07215840A (en) * 1994-01-31 1995-08-15 Shiseido Co Ltd Skin-cleansing agent
JPH09175936A (en) * 1995-12-28 1997-07-08 Kao Corp Cleansing composition
JPH1135421A (en) * 1997-07-17 1999-02-09 Shiseido Co Ltd Liquid oil-based skin detergent
JP2001270808A (en) * 2000-01-20 2001-10-02 Shiyuu Uemura Keshohin:Kk Self-emulsifying type oily cosmetic composition and method for improving storage stability of the self- emulsifying type oily cosmetic composition
JP2001342115A (en) * 2000-03-30 2001-12-11 Kose Corp Oil detergent
JP2002241224A (en) * 2001-02-15 2002-08-28 Shiseido Co Ltd Oil-like cleansing cosmetic
JP2003146867A (en) * 2001-11-09 2003-05-21 Internatl Toiretsu Lease Kk Cleansing hand cleaner and cleansing shampoo
WO2003080004A1 (en) * 2002-03-26 2003-10-02 Kao Corporation Cleansing preparation
JP2003286133A (en) * 2002-03-29 2003-10-07 Nof Corp Cleansing cosmetic
JP2004075554A (en) * 2002-08-12 2004-03-11 Kanebo Ltd Cleansing cosmetic
JP2004168715A (en) * 2002-11-20 2004-06-17 Pola Chem Ind Inc Foamed external preparation for skin
WO2008052956A1 (en) * 2006-11-04 2008-05-08 Unilever Plc Make-up remover cosmetic compositions
JP2008184415A (en) * 2007-01-29 2008-08-14 Kao Corp Cleansing composition
JP2010209033A (en) * 2009-03-12 2010-09-24 Lion Corp Skin cleansing agent composition
JP4610115B2 (en) * 2001-03-28 2011-01-12 株式会社コーセー Cleansing cosmetics
US8298557B2 (en) 2008-06-19 2012-10-30 Shiseido Company, Ltd. Cleansing cosmetic composition
JP2018027907A (en) * 2016-08-17 2018-02-22 日進化学株式会社 Oil foam aerosol composition

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05178734A (en) * 1991-12-27 1993-07-20 Kose Corp Solid-like water-in-oil type emulsified cosmetic
JPH07215840A (en) * 1994-01-31 1995-08-15 Shiseido Co Ltd Skin-cleansing agent
JPH09175936A (en) * 1995-12-28 1997-07-08 Kao Corp Cleansing composition
JPH1135421A (en) * 1997-07-17 1999-02-09 Shiseido Co Ltd Liquid oil-based skin detergent
JP2001270808A (en) * 2000-01-20 2001-10-02 Shiyuu Uemura Keshohin:Kk Self-emulsifying type oily cosmetic composition and method for improving storage stability of the self- emulsifying type oily cosmetic composition
JP2001342115A (en) * 2000-03-30 2001-12-11 Kose Corp Oil detergent
JP4638018B2 (en) * 2000-03-30 2011-02-23 株式会社コーセー Oily cleaning agent
JP2002241224A (en) * 2001-02-15 2002-08-28 Shiseido Co Ltd Oil-like cleansing cosmetic
JP4610115B2 (en) * 2001-03-28 2011-01-12 株式会社コーセー Cleansing cosmetics
JP2003146867A (en) * 2001-11-09 2003-05-21 Internatl Toiretsu Lease Kk Cleansing hand cleaner and cleansing shampoo
WO2003080004A1 (en) * 2002-03-26 2003-10-02 Kao Corporation Cleansing preparation
JP2003286133A (en) * 2002-03-29 2003-10-07 Nof Corp Cleansing cosmetic
JP2004075554A (en) * 2002-08-12 2004-03-11 Kanebo Ltd Cleansing cosmetic
JP2004168715A (en) * 2002-11-20 2004-06-17 Pola Chem Ind Inc Foamed external preparation for skin
WO2008052956A1 (en) * 2006-11-04 2008-05-08 Unilever Plc Make-up remover cosmetic compositions
JP2008184415A (en) * 2007-01-29 2008-08-14 Kao Corp Cleansing composition
JP4602999B2 (en) * 2007-01-29 2010-12-22 花王株式会社 Cleansing composition
US8298557B2 (en) 2008-06-19 2012-10-30 Shiseido Company, Ltd. Cleansing cosmetic composition
JP2010209033A (en) * 2009-03-12 2010-09-24 Lion Corp Skin cleansing agent composition
JP2018027907A (en) * 2016-08-17 2018-02-22 日進化学株式会社 Oil foam aerosol composition

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Publication number Publication date
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