JPH03138359A - Thin film forming device - Google Patents

Thin film forming device

Info

Publication number
JPH03138359A
JPH03138359A JP27556789A JP27556789A JPH03138359A JP H03138359 A JPH03138359 A JP H03138359A JP 27556789 A JP27556789 A JP 27556789A JP 27556789 A JP27556789 A JP 27556789A JP H03138359 A JPH03138359 A JP H03138359A
Authority
JP
Japan
Prior art keywords
thin film
grids
substrate
counter electrode
evaporation source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP27556789A
Other languages
Japanese (ja)
Other versions
JP2905512B2 (en
Inventor
Wasaburo Ota
太田 和三郎
Mikio Kinoshita
幹夫 木下
Tatsuya Sato
達哉 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Priority to JP27556789A priority Critical patent/JP2905512B2/en
Publication of JPH03138359A publication Critical patent/JPH03138359A/en
Application granted granted Critical
Publication of JP2905512B2 publication Critical patent/JP2905512B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Physical Vapour Deposition (AREA)
  • Physical Deposition Of Substances That Are Components Of Semiconductor Devices (AREA)
  • Surface Treatment Of Optical Elements (AREA)

Abstract

PURPOSE:To form a high quality thin film on a substrate kept at a low temp. by generating a glow discharge via a leak voltage transformer of a driving frequency which is not a high frequency between grids disposed above and below and thereby ionizing gases and material to be evaporated. CONSTITUTION:The material is evaporated in an evaporating source 9 in a vacuum chamber consisting of a base plate 1 and a bell-jar 2 and the thin film of the above-mentioned material is formed on a substrate 15 which is positioned to face this material and is held on a counter electrode 5 kept at the same potential or negative potential. The grids 6, 8 which allow the passage of the evaporated material are disposed between the evaporating source 9 and counter electrode 5 of the above-mentioned thin film forming device. The stable glow discharge is generated between the grids 6 and 8 by the leak voltage transformer 18 of the driving frequency which is not the high frequency. The above-mentioned material to be evaporated is ionized and accelerated in this way and is thereby brought into collision against the substrate 15, by which the dense and homogeneous thin film having the good adhesive property is efficiently formed.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は薄膜形成装置に関する。この発明はプラスチッ
クレンズやLSIの製造に利用できる。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a thin film forming apparatus. This invention can be used to manufacture plastic lenses and LSIs.

[従来の技術] 蒸発させた材料物質をイオン化して腹膜を行うようにす
ると、材料物質がイオンという帯電状態にあるので基板
に向かって加速し易く、このため緻密で強い膜を形成で
きる。また材料物質がイオン化しているため反応が容易
に行われるから、反応性や結晶化を必要とする製膜を熱
エネルギーを与えることなく実現でき、従って低温での
製膜が可能であり、プラスチック基板のような耐熱性の
ない基板にも・緻密・均質で密着性のよい薄膜を形成で
きる。
[Prior Art] When the vaporized material is ionized to form a peritoneal membrane, the material is in a charged state of ions, so it is easily accelerated toward the substrate, and therefore a dense and strong film can be formed. In addition, since the material is ionized, reactions can easily take place, making it possible to form films that require reactivity or crystallization without applying thermal energy. It is possible to form dense, homogeneous, and highly adhesive thin films even on substrates that do not have heat resistance, such as substrates.

このように「材料物質を蒸発させた後、イオン化して製
膜を行う」ようにした薄膜形成装置としては、蒸発した
材料物質のイオン化をフィラメントにより発生させた熱
電子により行うようにしたものが知られている。
As a thin film forming apparatus that ``forms a film by ionizing the material after evaporating it,'' there is one that uses thermoelectrons generated by a filament to ionize the evaporated material. Are known.

[発明が解決しようとする課題] 本発明の目的は「材料物質を蒸発させた後、イオン化し
て製膜を行う」方式の、新規な薄膜形成装置を提供する
ことにある。
[Problems to be Solved by the Invention] An object of the present invention is to provide a novel thin film forming apparatus that uses a method of "forming a film by ionizing the material after evaporating it."

[課題を解決するための手段] 以下、本発明を説明する。[Means to solve the problem] The present invention will be explained below.

本発明の薄膜形成装置は「真空槽と、蒸発源と、対電極
と、第1および第2のグリッドと、漏洩変圧器と」を有
する。
The thin film forming apparatus of the present invention includes "a vacuum chamber, an evaporation source, a counter electrode, first and second grids, and a leakage transformer."

「真空槽」は、薄膜形成を行うための空間を形成するが
、この真空槽には[活性ガスあるいは不活性ガスまたは
これら両者の混合ガス」を導入ガスとして導入すること
ができる。
A "vacuum chamber" forms a space for forming a thin film, and an "active gas, an inert gas, or a mixture of the two gases" can be introduced into this vacuum chamber as an introduction gas.

「蒸発源」は、真空槽内に於いて薄膜の材料物質を蒸発
させる。
The "evaporation source" evaporates the thin film material in a vacuum chamber.

「対電極」は、真空槽内に於いて[薄膜を形成されるべ
き基板」を蒸発源と対向させて保持するが、蒸発源と同
電位もしくは蒸発源に対して負電位にされる。
The "counter electrode" holds the "substrate on which a thin film is to be formed" facing the evaporation source in the vacuum chamber, and is set at the same potential as the evaporation source or at a negative potential with respect to the evaporation source.

「第1のグリッド」は、材料物質を通過させ得るように
形成され、蒸発源と対電極との間に配備される。
The "first grid" is formed to allow the material to pass therethrough and is disposed between the evaporation source and the counter electrode.

「第2のグリッド」は、材料物質を通過させ得るように
形成され、第1のグリッドと蒸発源との間に配備される
The "second grid" is formed to allow the material to pass therethrough and is arranged between the first grid and the evaporation source.

「漏洩変圧器」は、第1および第2のグリッド間に高岡
j堤でない駆動周波数の交流電圧を印加して、これらグ
リッド間に安定したグロー放電を発生させる。
The "leakage transformer" applies an alternating current voltage with a drive frequency that is not equal to Takaoka's voltage between the first and second grids to generate a stable glow discharge between these grids.

第1および第2のグリッドの一方もしくは双方の構成母
材は、薄膜形成材料もしくはその一部で構成することが
できる。
The constituent base material of one or both of the first and second grids may be composed of a thin film forming material or a portion thereof.

[作  用] 真空槽内に導入された活性ガスもしくは不活性ガスある
いはこれらの混合ガス、蒸発源から蒸発した材料物質は
、第1および第2のグリッド間に於いてグリッド間の放
電によりイオン化される。
[Function] Active gas, inert gas, or a mixture thereof introduced into the vacuum chamber, and materials evaporated from the evaporation source are ionized by electric discharge between the grids between the first and second grids. Ru.

第1および第2のグリッド間への交流電圧印加は「漏洩
変圧器」により行われるため、過渡的なアーク放電が起
きず、安定したグロー放電が発生する。
Since the alternating current voltage is applied between the first and second grids using a "leakage transformer," transient arc discharge does not occur and stable glow discharge occurs.

第1、第2のグリッド間に形成される電界は、印加され
る電圧の変化に応じ向きが逆転する。この電界が第2の
グリッドから第1のグリッドに向くときは、両グリッド
間に発生した正イオンが基板側へ加速される。また上記
電界が第1のグリッドから第2のグリッドに向かうとき
は、負イオンが基板側へ加速される。
The direction of the electric field formed between the first and second grids is reversed in response to changes in the applied voltage. When this electric field is directed from the second grid to the first grid, positive ions generated between both grids are accelerated toward the substrate. Further, when the electric field is directed from the first grid to the second grid, negative ions are accelerated toward the substrate.

加速されたイオンは第1のグリッドを通過して基板へ向
かって飛行し、高速で基板に衝突する。
The accelerated ions fly toward the substrate through the first grid and collide with the substrate at high speed.

このようにして基板に緻密で密着性の良い薄膜が形成さ
れる。
In this way, a dense and highly adhesive thin film is formed on the substrate.

なお、第1および第2のグリッドに漏洩変圧器により印
加される交流電圧のJC流τスが高すぎると、電界の向
きの変化が速すぎてイオンが一方向に十分に加速されな
い、従って本発明では、イオンを基板側に十分に加速で
きるような「高周波でない駆動周波数」の漏洩変圧器を
用いる。駆動周波数は商用周波数程度で良い。
Note that if the JC current τ of the AC voltage applied to the first and second grids by the leaky transformer is too high, the direction of the electric field will change too quickly and the ions will not be sufficiently accelerated in one direction. The invention uses a leaky transformer with a "non-high drive frequency" that can sufficiently accelerate ions toward the substrate. The driving frequency may be around the commercial frequency.

第1および第2のグリッドには、薄膜形成の際に加速さ
れたイオンが衝突するので、グリッドの構成材料がスパ
ッタされ、スパッタされたグリッド材料は形成される薄
膜中に不純物として混入する。そこで第1および第2の
グリッドの少なくとも一方の母材を薄膜形成材料もしく
はその一部で構成すると、上記不純物の混入を有効に軽
減もしくは防止できる。
Accelerated ions collide with the first and second grids during thin film formation, so the constituent material of the grids is sputtered, and the sputtered grid material mixes into the formed thin film as impurities. Therefore, if the base material of at least one of the first and second grids is made of a thin film forming material or a part thereof, the above-mentioned contamination of impurities can be effectively reduced or prevented.

口実施例コ 以下、図面を参照しつつ具体的な実施例に即して説明す
る。
Embodiments Hereinafter, specific embodiments will be described with reference to the drawings.

実施例を示す図に於いて、ペルジャー2はバッキング4
を介してベースプレート1と一体化され真空槽を構成し
ている。
In the figure showing the embodiment, Pelger 2 is attached to backing 4.
It is integrated with the base plate 1 via a vacuum chamber.

ベースプレート1は、支持体を兼ねた電極10゜11、
13.14により貫通されているが、これら電極の貫通
部は勿論気密状態であり、またこれら電極とベースプレ
ート1との間は電気的に絶縁されている。ベースプレー
トlの中央部に穿設された孔1aは図示されない真空系
へ連結されている。
The base plate 1 includes electrodes 10 and 11 that also serve as supports;
13 and 14, the penetrating portions of these electrodes are of course airtight, and these electrodes and the base plate 1 are electrically insulated. A hole 1a bored in the center of the base plate 1 is connected to a vacuum system (not shown).

一対の電極14の間には、タングステンやモリブデン等
の金属をコイル状に形成した抵抗加熱式の蒸発源9が支
持されている。蒸発源としては他にビーム蒸発源等、従
来の真空蒸着方式で知られた種々の方式のものを適宜用
いることができる。
A resistance heating type evaporation source 9 made of metal such as tungsten or molybdenum and formed into a coil shape is supported between the pair of electrodes 14 . As the evaporation source, various types of conventional vacuum evaporation methods, such as a beam evaporation source, can be used as appropriate.

電極10には対電極5が支持され、対電極5の蒸発源9
に対向する側の面には、:a膜を形成されるべき基板1
5が適宜の方法で支持されている。
A counter electrode 5 is supported on the electrode 10, and an evaporation source 9 of the counter electrode 5 is supported on the electrode 10.
On the surface facing the substrate 1 on which the :a film is to be formed.
5 is supported in an appropriate manner.

電極11には第1のグリッド6が支持され、電極13に
は第2のグリッド8が支持されている。これら第1およ
び第2のグリッド6.8は蒸発した材料物質を通過させ
得るように形成されており、この例では網目状である。
A first grid 6 is supported on the electrode 11, and a second grid 8 is supported on the electrode 13. These first and second grids 6.8 are designed to allow the vaporized material to pass through them and are in the form of a mesh in this example.

1対の電極14は蒸発源9の加熱用電源17に接続され
、電極11.13は漏洩変圧器18の2次側の各出力端
子に接続されている。
The pair of electrodes 14 is connected to the heating power source 17 of the evaporation source 9, and the electrodes 11.13 are connected to each output terminal on the secondary side of the leakage transformer 18.

なお、この実施例のように電極10を介して対電極5を
漏洩変圧器18の2次側出力端子に図の如く接続し、対
電極5が第2のグリッド8と同電位になるようにすると
、第1のグリッド6を基板5の側に通過した正・負イオ
ンが、グリッド間の電界の向きが反転するときグリッド
6と対電極5の間に形成される電界により基板の側へ加
速される利点がある0図の接地は必ずしも必要ではない
As in this embodiment, the counter electrode 5 is connected to the secondary output terminal of the leaky transformer 18 via the electrode 10 as shown in the figure, so that the counter electrode 5 has the same potential as the second grid 8. Then, the positive and negative ions that have passed through the first grid 6 toward the substrate 5 are accelerated toward the substrate by the electric field formed between the grid 6 and the counter electrode 5 when the direction of the electric field between the grids is reversed. Grounding of Figure 0 is not always necessary, as it has the advantage of being

また、この実施例では蒸発源9と対電極5は同電位とさ
れる。
Further, in this embodiment, the evaporation source 9 and the counter electrode 5 are at the same potential.

実際には、各電極間の接続は種々のスイッチを含み、こ
れらスイッチの操作により薄膜形成のプロセスを実現す
るが、これらスイッチは図示を省略されている。
Actually, the connection between each electrode includes various switches, and the thin film forming process is realized by operating these switches, but these switches are omitted from illustration.

以下、この実施例装置による薄膜形成を説明する。Thin film formation using this embodiment apparatus will be described below.

蒸発源9に材料物質を保持させ、基板15を対電極5に
図の如く支持させたら、真空系により真空槽内を104
〜10− ’Torrの圧力に、減圧する。
After the material is held in the evaporation source 9 and the substrate 15 is supported on the counter electrode 5 as shown in the figure, the inside of the vacuum chamber is
Vacuum to a pressure of ~10-'Torr.

続いて必要に応じて、アルゴン等の不活性ガス、酸素・
水素や窒素等の活性ガス、あるいはこれら活性ガス・不
活性ガスの混合ガスを導入ガスとして10°〜10− 
’Torr程度の圧力に導入する。この導入ガスの導入
は図示されないバルブの調整により行われる。
Then, if necessary, inert gas such as argon, oxygen, etc.
10° to 10-
'Introduce the pressure to about Torr. This introduction of the introduced gas is performed by adjusting a valve (not shown).

この状態で蒸発源9により材料物質を蒸発させると、蒸
発した材料物質は広がりをもって基板15の側へ飛行す
る。
When the material is evaporated by the evaporation source 9 in this state, the evaporated material spreads and flies toward the substrate 15.

このとき、漏洩変圧器18により第1および第2のグリ
ッド6.8間に交流電圧を印加するとグリッド6.8間
に安定したグロー放電が生じ、グリッド間空間に存在す
る材料物質・導入ガスが正または負にイオン化される。
At this time, when an AC voltage is applied between the first and second grids 6.8 by the leakage transformer 18, a stable glow discharge occurs between the grids 6.8, and the material substance/introduced gas existing in the space between the grids is Can be positively or negatively ionized.

このイオン化の際、正にイオン化されるか負にイオン化
されるかはイオン化される物質の電子親和性により決定
される。
During this ionization, whether the substance is positively ionized or negatively ionized is determined by the electron affinity of the substance to be ionized.

グリッド6.8間にはグリッド間の電位差に応じて電界
が形成されるが、この電界の向きは、第1のグリッド6
から第2のグリッド8の側へ向かう向きと、その逆向き
とに交互に変化する。
An electric field is formed between the grids 6 and 8 depending on the potential difference between the grids, but the direction of this electric field is different from that of the first grid 6.
The direction alternately changes from the direction toward the second grid 8 side and the opposite direction.

電界がグリッド8からグリッド6へ向かうときは正イオ
ンがグリッド6側へ加速されてグリッド6を通過する。
When the electric field moves from the grid 8 to the grid 6, positive ions are accelerated toward the grid 6 and pass through the grid 6.

また電界の向きが逆になれば負イオンがグリッド6側へ
加速されてグリッド6を通過する。換言すればグリッド
間の電界の向きの変化に応じて、正負のイオンが交互に
グリッド6を基板15側に通過する。
Furthermore, when the direction of the electric field is reversed, negative ions are accelerated toward the grid 6 and pass through the grid 6. In other words, positive and negative ions alternately pass through the grid 6 toward the substrate 15 side according to changes in the direction of the electric field between the grids.

グリッド6を通過したイオンは基板15に高速で衝突し
て薄膜を形成する。
The ions that have passed through the grid 6 collide with the substrate 15 at high speed to form a thin film.

この実施例に於いては、対電極5が第2のグリッド8と
同電位となっているので、グリッド6を通過した正(負
)イオンは、グリッド間の電界の向きが反転して負(正
)イオンがグリッド6側へ加速されるとき、グリッド6
と対電極5の間に形成される電界により基板15側へ加
速されるので薄膜の基板への密着性はより強くなる。
In this embodiment, since the counter electrode 5 is at the same potential as the second grid 8, the positive (negative) ions that have passed through the grid 6 reverse the direction of the electric field between the grids and become negative ( Positive) When ions are accelerated toward grid 6, grid 6
Since the thin film is accelerated toward the substrate 15 by the electric field formed between the electrode 5 and the counter electrode 5, the adhesion of the thin film to the substrate becomes stronger.

形成される薄膜の構造は、蒸発源に保持させる材料物質
と導入ガスとにより定まる。
The structure of the formed thin film is determined by the material held in the evaporation source and the introduced gas.

蒸発源に保持させる材料物質としてAIを用い、不活性
ガスとしてアルゴン、活性ガスとして酸素を混合した導
入ガスを10−’Torrの圧力に導入して成膜を行え
ば、基板上にAIJ3の薄膜を形成できる。またこの場
合、材料物質として上記AIに替えてSiもしくはSi
Oを選択すれば、 5iftの薄膜を成膜できるし、材
料物質としてInもしくはZnを選択すればIn、03
あるいはZnOの薄膜が得られる。
If a thin film of AIJ3 is formed on the substrate by using AI as the material to be held in the evaporation source and introducing a gas mixture of argon as the inert gas and oxygen as the active gas at a pressure of 10-'Torr, a thin film of AIJ3 will be formed on the substrate. can be formed. In this case, Si or Si is used instead of the above-mentioned AI as the material.
If O is selected, a 5ift thin film can be formed, and if In or Zn is selected as the material, In, 03
Alternatively, a thin film of ZnO can be obtained.

また、蒸発源にCdを保持させ、導入ガスとしてH2S
を用いればCdSの薄膜が得られる。
In addition, Cd is held in the evaporation source, and H2S is used as the introduced gas.
A thin film of CdS can be obtained by using .

さらに、不活性ガスアルゴンとともに活性ガスとしてア
ンモニアを導入し、蒸発源にTiもしくは’raを保持
させて成膜を行えばTiN、TaNの薄膜を得ることが
で きる。
Furthermore, a thin film of TiN or TaN can be obtained by introducing ammonia as an active gas together with the inert gas argon and forming a film while holding Ti or 'ra in the evaporation source.

また第1.第2のグリッドの少なくとも一方の構成母材
を薄膜の材料もしくはその一部とすることにより、グリ
ッド構成母材がスパッターにより薄膜へ不純物として混
入するのを有効に軽減もしくは防止でき、薄膜の純度・
組成制御性を高くすることができる。
Also number 1. By making at least one constituent base material of the second grid a thin film material or a part thereof, it is possible to effectively reduce or prevent the grid constituent base material from being mixed into the thin film as an impurity due to sputtering, and improve the purity of the thin film.
Composition controllability can be improved.

[発明の効果] 以上1本発明によれば新規な薄膜形成装置を提供できる
。この装置は上述の如き構成となっているため、ガラス
基板等の耐熱性ある基板への薄膜形成は言うまでもなく
、プラスチックのような耐熱性のない基板にも良好に薄
膜を形成できる。
[Effects of the Invention] According to the present invention, a novel thin film forming apparatus can be provided. Since this apparatus has the above-described configuration, it is possible to form thin films not only on heat-resistant substrates such as glass substrates, but also on non-heat-resistant substrates such as plastics.

また薄膜を構成する材料はイオンとして基板に向かって
加速され、十分に高いエネルギーをもって基板に衝突す
るので薄膜の密着性、稠密・均質性が良い。
Furthermore, the material constituting the thin film is accelerated toward the substrate as ions and collides with the substrate with sufficiently high energy, resulting in good adhesion, density, and homogeneity of the thin film.

【図面の簡単な説明】[Brief explanation of the drawing]

図は、本発明の1実施例を示す図である。 The figure shows one embodiment of the invention.

Claims (2)

【特許請求の範囲】[Claims] 1.真空槽と、 この真空槽内に於いて材料物質を蒸発させるための蒸発
源と、 上記真空槽内に於いて、薄膜を形成されるべき基板を上
記蒸発源と対向させて保持し、蒸発源と同電位もしくは
蒸発源に対して負電位にされる対電極と、 蒸発した材料物質を通過させ得るように形成され、上記
蒸発源と対電極との間に、対電極側から蒸発源側に向か
って第1、第2の順に配備される第1および第2のグリ
ッドと、 これら第1および第2のグリッド間に安定したグロー放
電を発生させる、高周波でない駆動周波数の漏洩変圧器
と、を有する薄膜形成装置。
1. a vacuum chamber; an evaporation source for evaporating a material in the vacuum chamber; a substrate on which a thin film is to be formed is held in the vacuum chamber facing the evaporation source; a counter electrode that is at the same potential as or a negative potential with respect to the evaporation source; and a counter electrode that is formed so as to allow the evaporated material to pass therethrough, and between the evaporation source and the counter electrode, from the counter electrode side to the evaporation source side. first and second grids arranged in the order of the first and second grids, and a leakage transformer with a drive frequency that is not a high frequency and generates a stable glow discharge between the first and second grids. A thin film forming apparatus with
2.請求項1に於いて、第1および第2のグリッドの一
方もしくは双方の構成母材を、薄膜形成材料もしくはそ
の一部で構成したことを特徴とする薄膜形成装置。
2. 2. The thin film forming apparatus according to claim 1, wherein the base material of one or both of the first and second grids is made of a thin film forming material or a part thereof.
JP27556789A 1989-10-23 1989-10-23 Thin film forming equipment Expired - Fee Related JP2905512B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27556789A JP2905512B2 (en) 1989-10-23 1989-10-23 Thin film forming equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27556789A JP2905512B2 (en) 1989-10-23 1989-10-23 Thin film forming equipment

Publications (2)

Publication Number Publication Date
JPH03138359A true JPH03138359A (en) 1991-06-12
JP2905512B2 JP2905512B2 (en) 1999-06-14

Family

ID=17557248

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27556789A Expired - Fee Related JP2905512B2 (en) 1989-10-23 1989-10-23 Thin film forming equipment

Country Status (1)

Country Link
JP (1) JP2905512B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100108917A (en) * 2009-03-31 2010-10-08 서울반도체 주식회사 Linear led module and led lighting apparatus comprising the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20100108917A (en) * 2009-03-31 2010-10-08 서울반도체 주식회사 Linear led module and led lighting apparatus comprising the same

Also Published As

Publication number Publication date
JP2905512B2 (en) 1999-06-14

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