JPH03136066A - Color developing toner composition - Google Patents
Color developing toner compositionInfo
- Publication number
- JPH03136066A JPH03136066A JP1275398A JP27539889A JPH03136066A JP H03136066 A JPH03136066 A JP H03136066A JP 1275398 A JP1275398 A JP 1275398A JP 27539889 A JP27539889 A JP 27539889A JP H03136066 A JPH03136066 A JP H03136066A
- Authority
- JP
- Japan
- Prior art keywords
- developer
- dye
- color
- color developing
- toner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 15
- 239000002243 precursor Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims description 9
- 239000011162 core material Substances 0.000 claims description 5
- 230000002776 aggregation Effects 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 2
- 238000005054 agglomeration Methods 0.000 abstract 2
- 239000000975 dye Substances 0.000 description 17
- -1 propyl gallic acid ester Chemical class 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- 239000003094 microcapsule Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 238000004220 aggregation Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- WCOXQTXVACYMLM-UHFFFAOYSA-N 2,3-bis(12-hydroxyoctadecanoyloxy)propyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC(O)CCCCCC)COC(=O)CCCCCCCCCCC(O)CCCCCC WCOXQTXVACYMLM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- MFGZXPGKKJMZIY-UHFFFAOYSA-N ethyl 5-amino-1-(4-sulfamoylphenyl)pyrazole-4-carboxylate Chemical compound NC1=C(C(=O)OCC)C=NN1C1=CC=C(S(N)(=O)=O)C=C1 MFGZXPGKKJMZIY-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 235000013872 montan acid ester Nutrition 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002545 silicone oil Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- SSWMLKYBHOTWFA-UHFFFAOYSA-J tris[(2-hydroxybenzoyl)oxy]stannyl 2-hydroxybenzoate Chemical compound [Sn+4].Oc1ccccc1C([O-])=O.Oc1ccccc1C([O-])=O.Oc1ccccc1C([O-])=O.Oc1ccccc1C([O-])=O SSWMLKYBHOTWFA-UHFFFAOYSA-J 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- JRBNKLYSGIHONX-UHFFFAOYSA-L zinc;1-carboxynaphthalen-2-olate Chemical compound [Zn+2].C1=CC=C2C(C(=O)O)=C([O-])C=CC2=C1.C1=CC=C2C(C(=O)O)=C([O-])C=CC2=C1 JRBNKLYSGIHONX-UHFFFAOYSA-L 0.000 description 1
- YWUGXWVYRWGTFR-UHFFFAOYSA-L zinc;2-butoxybenzoate Chemical compound [Zn+2].CCCCOC1=CC=CC=C1C([O-])=O.CCCCOC1=CC=CC=C1C([O-])=O YWUGXWVYRWGTFR-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Developing Agents For Electrophotography (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野１
本発明は、染料または染料前駆体との作用によって発色
する顕色剤をトナー化する時の組成物に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to a composition for forming a toner from a color developer that develops color through the action of a dye or a dye precursor.
［従来技術１
従来、顕色剤は水系溶媒中に超微粒子として分散されて
おり、バイングー、添加剤等の調整をした上で抄紙され
た紙に塗布し、顕色剤シートという特殊紙として存在し
ていた。この顕色剤シートによる画像形成技術は、特開
昭５８−８８７３９号公報、特開昭５９−３０５３７号
公報、特開昭５９−１３７９４４号公報等に記載されで
いる。[Prior art 1 Conventionally, color developer is dispersed as ultrafine particles in an aqueous solvent, and after adjusting the binder and additives, it is applied to the paper that is made to form a special paper called a color developer sheet. Was. This image forming technique using a color developer sheet is described in Japanese Patent Laid-Open Nos. 58-88739, 30537-1983, 137944-1980, and the like.
ここで、画像形成技術とは、互いに隔離された二つまた
はそれ以上の成分が、圧力または温度変化などのような
物理的外力によって隔離を解除され、互いに反応する事
によって光学的な変化、光の吸収領域、あるいは吸収強
度の変化を起こし、外方に応じた記録がなされるような
すべての機能を指すものである０例えば、光の照射によ
り機械的破壊強度が変化するようなマイクロカプセルが
任意の媒体上に担持しである感光感圧記ｔｔ媒体と顕色
剤シーＦを重ね合わせ、圧力現像することにより機械的
破壊強度の異なったマイクロカプセルの選択的清快を起
こし、マイクロカプセルに含まれた無色または僅かに着
色した染料または、染料前駆体と反応して染料を発色せ
しめうる物質、すなわち、染料受容体である顕色剤と反
応して顕色剤シート上に顕像を形成するような画像形成
系である。Here, image forming technology refers to two or more components isolated from each other that are released from isolation by physical external forces such as pressure or temperature changes, and react with each other to produce optical changes and light. For example, a microcapsule whose mechanical breaking strength changes when irradiated with light refers to all functions that cause a change in the absorption area or absorption intensity and are recorded according to the external direction. By superimposing the photosensitive pressure recording TT medium supported on an arbitrary medium and the color developer Sea F, and developing under pressure, microcapsules with different mechanical breaking strengths are selectively cleared, and the microcapsules are separated into microcapsules. A colorless or slightly colored dye contained therein, or a substance that can cause the dye to develop color by reacting with the dye precursor, i.e., reacts with the developer, which is a dye receptor, to form a developed image on the developer sheet. It is an image forming system that
これら−船釣な画像形成系は、特殊紙と呼ばれる染料受
容体を塗布した顕色剤シート上にしか画像を形成するこ
とができなかった。These conventional image forming systems could only form images on a developer sheet coated with a dye receptor called special paper.
［発明が解決しようとする課題］
しかしながら、画像を形成しようとする対象は顕色剤シ
ートだけではなく様々な任意の媒体にある。従って、感
光感圧記録媒体に担持されたマイクロカプセルとの作用
によって発色する顕色剤を粉体化し、静電的に任意の媒
体上に塗布できるような顕色剤トナーが提案された。[Problems to be Solved by the Invention] However, the object on which images are to be formed is not only the developer sheet but also various arbitrary media. Therefore, a color developer toner has been proposed in which a color developer that develops color through interaction with microcapsules supported on a photosensitive and pressure sensitive recording medium is pulverized and can be applied electrostatically onto any medium.
しかし、製造が容易で加圧定着性能、流動性能が充分で
あり、繰り返し使用に対して現像性能、定着性能が安定
しでおり、トナー担持体、トナーケースへの癒着を起こ
さず、保存中に凝集、ケーキ化しない保存安定性の良好
である顕色剤トナーを得ることは難しかった。However, it is easy to manufacture, has sufficient pressure fixing performance and fluidity performance, and has stable development performance and fixing performance even after repeated use. It has been difficult to obtain a color developer toner that does not agglomerate or cake and has good storage stability.
顕色剤に軟質物質を含有した顕色剤トナーは、圧力定着
性は良好であるが、微粉砕してトナー化することが困難
であり、接触するトナー担持体、トナーケースへの癒着
を起こしたり保存中に顕色剤トナー同士が凝集、ケーキ
化するという開運があった。Developer toner containing a soft substance in the developer has good pressure fixability, but is difficult to pulverize into a toner and may cause adhesion to the toner carrier and toner case that it comes into contact with. As luck would have it, the developer toner would aggregate and form a cake during storage.
また、硬質の樹脂を顕色剤に混合すると、トナー化する
ことは容易であり、荷電性、保存性には優れているが圧
力定着性はきわめて良くない。すなわち、硬質樹脂は定
着される被記録媒体よりも硬いものが多く圧力を加えた
ときに、単に被記録媒体に押しつけられただけで、繊維
に絡まないためである。Further, when a hard resin is mixed with a color developer, it is easy to form a toner and has excellent chargeability and storage stability, but the pressure fixability is extremely poor. That is, the hard resin is harder than the recording medium to which it is fixed, so when pressure is applied, it is simply pressed against the recording medium and does not get tangled with the fibers.
本発明は、上述した問題点を解決するためになされたも
のであり、被記録媒体である普通紙に対して加圧による
定着性が良好であり、保存時に凝集、ケーキングの起こ
らない顕色剤トナーのｊＩｌｔ物を提供することにある
。The present invention has been made in order to solve the above-mentioned problems, and provides a color developer that has good fixability under pressure on plain paper, which is a recording medium, and that does not cause aggregation or caking during storage. Our objective is to provide toner products.
［ｉ！！題を解決するための手段１
この目的を達成するために本発明の顕色剤トナー組成物
は、染料または染料前駆体と反応しで発色させる染料前
駆体である顕色剤に離型性物質が含有されていることも
しくは、前記顕色剤を芯物質とする外殻に離型性物質を
含有していることからなる。[i! ! Means for Solving the Problem 1 In order to achieve this object, the developer toner composition of the present invention contains a release agent in the developer, which is a dye precursor that reacts with a dye or a dye precursor to develop a color. or a releasable substance is contained in an outer shell having the color developer as a core substance.
１作用１
上記の構成を有する本発明の顕色剤トナーは、染料受容
体である顕色ｎｔ分を少なくとも１種類含有し、これに
離型性物質を混合または、顕色剤成分を芯物質として離
型性物質で覆うことによって、その効果が現われる。1 Effect 1 The color developer toner of the present invention having the above configuration contains at least one type of color developer nt which is a dye receptor, and a releasing substance is mixed therein, or a color developer component is mixed with a core substance. This effect appears by covering it with a mold release material.
［実施例１ 以下、本発明の構成要素を説明する。[Example 1 Hereinafter, the constituent elements of the present invention will be explained.
画像形成系に用いられる染料及び染料前駆体としでは、
クリスタルバイオレットラクトン、ペンゾイルロイフメ
チレンプルー等が代表的であるがその他多くの種類が知
られており、実用化されている。染料受容体、いわゆる
顕色剤成分としては、酸性白土、ベントナイト、カオリ
ナイト、アタパルガイド等の天然粘度鉱物；タンニン酸
、没食子酸、プロピル没食べ子酸エステル等のような有
機酸及びそのエステル；７エ）−ル樹脂、マレイン酸Ｏ
（脂、フェノール−アセチレン樹脂、少なくとも１個の
ヒドロキシ基を有するカルボン酸とホルムアルデヒドと
の縮重合物のような酸性ポリマー；サリチル酸亜鉛、サ
リチル酸錫、２−ヒドロキシナフトエ酸亜鉛、３−５−
ノーし一ブチルサリチル酸亜鉛、３．５−（１−メチル
ベンジルサリチル酸亜鉛のような芳香族カルボン酸の４
を属塩；亜鉛、ニッケル等の多価金属で変性した金属塩
変性フェノール樹脂系化合物等及びこれらの混合物があ
げられる。As dyes and dye precursors used in image forming systems,
Representative examples include crystal violet lactone and penzoyl roif methylene blue, but many other types are known and have been put into practical use. Dye receivers, so-called color developer components, include natural clay minerals such as acid clay, bentonite, kaolinite, and attapulgite; organic acids and their esters such as tannic acid, gallic acid, propyl gallic acid ester, etc.; d)-el resin, maleic acid O
(acidic polymers such as fats, phenol-acetylene resins, condensates of formaldehyde and carboxylic acids having at least one hydroxyl group; zinc salicylate, tin salicylate, zinc 2-hydroxynaphthoate, 3-5-
4 of aromatic carboxylic acids such as zinc butylsalicylate, 3,5-(1-methylbenzylsalicylate)
metal salts modified with polyvalent metals such as zinc and nickel, and mixtures thereof.
これら顕色剤の混合物を粉体化して静電的に任意の媒体
に塗布しようとする場合、顕色剤の定着性、帯電性が影
響して＠用転写できないのを改善するために染料前駆体
である顕色剤の改質を行なうわけである。この時有用な
のが離型性物質を顕色剤に含有させることあるいは顕色
剤を、離型性物質を含有する外殻で覆うことでありその
離型性物質の例としては、ポリ弗化エチレン、弗素樹脂
、弗素化炭化水素、シリコンオイルなどがあげられまた
、任意の媒体への定着性、接着性がよくなり、顕色剤と
の接着性もよい物質としてワックス及び粘着剤のような
定着付与剤を混合する。例えば、粘着剤として知られて
いるエチレン−酢酸ビニル共重合体、ポリビニルエーテ
ル、塩化ビニル−酢酸ビニル共重合体、ポリ塩化ビニル
、ポリアクリル酸エステル、エチレンー二チルアクリレ
ート共重合体、ポリ酢酸ビニル、ポリビニルブチラール
、ポリ酢酸ビニル等があげられる。また、ワックスとし
ては、カルナバワックス、キャンデリラ７ノクス、ライ
スワックス、う７リンワツクス、ホホバワックス、ツヤ
パンワックス、蜜ろうワックス、パラフィンワックス、
マイクロクリスタリンワックス、モンタン酸エステルワ
ックス、ハロゲン化パラフィンワックス、カスターワッ
クス、ジュラ・ンクワンクス、サゾールワ・ンクス、ア
ミドワックス、オシケライトやポリエチレン、ポリプロ
ピレンのようなポリオレフィン類等があげられる。これ
らの成分を顕色剤の特質を失わないように単独あるいは
混合して用いるのがよい。When powdering a mixture of these color developers and electrostatically applying it to a desired medium, a dye precursor is used to improve the inability to transfer due to the fixing and charging properties of the color developer. This is done by modifying the color developer, which is the body of the color developer. What is useful at this time is to include a release material in the color developer or to cover the color developer with an outer shell containing a release material. Examples of release materials include polyfluoride. Examples include ethylene, fluororesin, fluorinated hydrocarbons, silicone oil, etc. Wax and adhesives are also used as substances that have good fixing and adhesion properties to arbitrary media and also have good adhesion to color developers. Mix the fixing agent. For example, ethylene-vinyl acetate copolymer, polyvinyl ether, vinyl chloride-vinyl acetate copolymer, polyvinyl chloride, polyacrylic acid ester, ethylene-dityl acrylate copolymer, polyvinyl acetate, which are known as adhesives. Examples include polyvinyl butyral and polyvinyl acetate. In addition, waxes include carnauba wax, candelilla 7 nox, rice wax, 7 lin wax, jojoba wax, glossy bread wax, beeswax wax, paraffin wax,
Examples include microcrystalline wax, montanic acid ester wax, halogenated paraffin wax, castor wax, Jura Nquanx, Sasolwa Nx, amide wax, osikelite, and polyolefins such as polyethylene and polypropylene. It is preferable to use these components alone or in combination so as not to lose the properties of the color developer.
顕色剤にトナーとしての帯電性を付与する物質としては
、ニグロシン染料、合金属染料、４級アンモニウム塩な
どの荷電制御剤を混合して使うのが好ましい、また、顕
色剤トナー表面の流動性、滑性を保つために脂肪族炭化
水素、高級脂肪族系アルコールなどの外滑材を混合して
もよい。As a substance that imparts chargeability to the color developer as a toner, it is preferable to use a mixture of charge control agents such as nigrosine dye, metal alloy dye, and quaternary ammonium salt. An external lubricant such as an aliphatic hydrocarbon or a higher aliphatic alcohol may be mixed in order to maintain the properties and lubricity.
上記した構成の混合物を予備混合、混線を経て、粉砕機
により粉砕する。粉砕で得られた顕色剤トナーが、ｌｌ
ｌ７Ｉｌ凝集、粘着凝集を起こすようであれば、スプレ
ードライ法、懸濁重合法、乳化重合法などの方法によっ
て顕色剤トナー表面にコーティングを施すことも可能で
ある。できた顕色剤トナーは、静電方式現像装置のトナ
ーケースに充填され、顕色剤同士や現像担持体との接触
、摩擦により帯電し、現像担持体から、静電引力によっ
て任意の媒体上に転写され、画像記録媒体として有用と
なる。The mixture having the above-mentioned structure is premixed, mixed, and then pulverized by a pulverizer. The developer toner obtained by pulverization is
If 17Il aggregation or adhesive aggregation occurs, it is also possible to apply a coating to the developer toner surface by methods such as spray drying, suspension polymerization, and emulsion polymerization. The resulting developer toner is filled into a toner case of an electrostatic developing device, charged by contact and friction between the developer and the developer carrier, and then transferred from the developer carrier onto any medium by electrostatic attraction. The image is transferred to the image recording medium and becomes useful as an image recording medium.
［実験例］
ｐ−７ｚ−ニル７ｚ／−ル １００ｆｆｌ
ｓｐ ｔ ７’ ｆ ルア ｚ ／ −ル４０ ｎ
ポリエチレンワックス ２０部エチレン
−酢酸ビニル共重合体 １０部ポリテトラフルオ
ロエチレン ５部荷電制御剤
２ｇ上記混合物を１００℃で溶融混練し
、常温で冷却固化させる。塊状にできた樹脂混合物は、
粗粉砕機で粉砕され、気流式ジェットミルで微粉砕され
る。粉砕してできあがったものは、非常に綱かい数ミク
ロンのものから数百ミクロンのものまで含まれるために
これをカットするために気流分級機で分級して５〜２０
ミクロンの範囲の顕色剤トナーを得る。この顕色剤トナ
ーを使って、非磁性−成分現像系で現像を行うと、流動
性が良（、良好な静電転写が行われた。[Experiment example] p-7z-nyl 7z/-l 100ffl
sp t 7' f lua z / -ru 40 n
Polyethylene wax 20 parts Ethylene-vinyl acetate copolymer 10 parts Polytetrafluoroethylene 5 parts Charge control agent
2g of the above mixture was melt-kneaded at 100°C and solidified by cooling at room temperature. The resin mixture formed into lumps is
It is ground in a coarse grinder and then finely ground in an air jet mill. The pulverized product is very thin, ranging in size from a few microns to hundreds of microns, so in order to cut it, it is classified with an air classifier and divided into 5 to 20 microns.
A developer toner in the micron range is obtained. When this developer toner was used for development in a non-magnetic component development system, it had good fluidity (and good electrostatic transfer was performed).
［実験例２］
ｐ−７二二ルフエノール １００部エチレン
−酢酸ビニル共重合体 ６０部マイクロクリスタ
リンワックス ３０部上記混合物を１００〜１２
０°Ｃで５分間溶融混練し、常温で冷却固化する。ｉ状
にできた混合物を粗砕機で０．５〜１１の粒子に粉砕し
、気流式ジェットミルで微粉砕する。こうして平均粒径
５〜１５μ蓮の粉砕品が得られるが、大きな粒子や細か
な粒子を混入しているためにこれを分級して５〜２０μ
ｍの範囲にはいる顕色剤トナーの芯物質を得る。[Experimental Example 2] p-7 dinylphenol 100 parts Ethylene-vinyl acetate copolymer 60 parts Microcrystalline wax 30 parts
Melt and knead at 0°C for 5 minutes, then cool and solidify at room temperature. The i-shaped mixture is pulverized into particles of 0.5 to 11 in size using a coarse pulverizer, and then finely pulverized using an air jet mill. In this way, a pulverized product with an average particle size of 5 to 15 μm is obtained, but since it contains large particles and fine particles, it is classified to 5 to 20 μm.
A developer toner core material is obtained which falls within the range of m.
ポリテトラプルオロエチレンの固形分濃度３０％二マル
ジ１ン３０部と荷電制御剤２部を水２００部の中にホモ
ジナイザーを用いて分散する。この分散溶液に前記顕色
剤トナーの芯物質となる顕色剤圧力定着成分６０部を分
散してスラリーとし、スプレードライヤーで噴霧乾燥す
る。噴霧乾燥条件は、出口温度７０℃、送液ｊｉ Ｉ
Ｓ ｇ／ ｗｉｎ、噴霧乾燥空気量０．５＋ａ″／輸で
行なった。この顕色剤トナーを使って非磁性−成分現像
系で現像を行なうと流動性が良く、良好な静電転写が行
なわれた６［発明の効果１
以上詳述したことから明らかなよろに、本発明によれば
、静電方式による飛用、転写を行なうことのできる顕色
削粉体を得ることができ、任意の媒体への定着性がよく
、融着、凝集がないために現像安定性が良くなり、帯電
性にも優れた顕色剤トナーを得ることができる。30 parts of polytetrafluoroethylene with a solid content of 30% and 2 parts of a charge control agent are dispersed in 200 parts of water using a homogenizer. In this dispersion solution, 60 parts of the developer pressure fixing component, which is the core material of the developer toner, is dispersed to form a slurry, and the slurry is spray-dried using a spray dryer. The spray drying conditions were: outlet temperature 70°C, liquid feeding ji I
Sg/win, spray drying air amount 0.5+a''/in. When this developer toner was used for development in a non-magnetic component development system, it had good fluidity and good electrostatic transfer. [Effects of the Invention 1] As is clear from the above detailed description, according to the present invention, it is possible to obtain a color-developing grinding powder that can carry out flying and transfer by an electrostatic method, and It is possible to obtain a color developer toner that has good fixability to the medium, has good development stability because there is no fusion or aggregation, and has excellent chargeability.
Claims (1)
容体である顕色剤を粉体化した乾式トナーの組成物にお
いて、 前記顕色剤に離型性物質が含有されていることを特徴と
する顕色剤トナー組成物。 ２、染料または染料前駆体と反応して発色させる染料受
容体である顕色剤を粉体化した乾式トナーの組成物にお
いて、前記顕色剤を芯物質とする外殻に離型性物質を含
有していることを特徴とする顕色剤トナー組成物。[Scope of Claims] 1. A dry toner composition in which a color developer, which is a dye receptor that reacts with a dye or a dye precursor to develop color, is powdered, wherein the color developer contains a releasing substance. A developer toner composition characterized in that: 2. In a dry toner composition in which a developer, which is a dye receptor that reacts with a dye or a dye precursor to develop color, is powdered, a release material is added to an outer shell containing the developer as a core material. A toner composition comprising a color developer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1275398A JPH03136066A (en) | 1989-10-23 | 1989-10-23 | Color developing toner composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1275398A JPH03136066A (en) | 1989-10-23 | 1989-10-23 | Color developing toner composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03136066A true JPH03136066A (en) | 1991-06-10 |
Family
ID=17554944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1275398A Pending JPH03136066A (en) | 1989-10-23 | 1989-10-23 | Color developing toner composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03136066A (en) |
-
1989
- 1989-10-23 JP JP1275398A patent/JPH03136066A/en active Pending
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