JPH03130463A - Method for scouring textile product - Google Patents
Method for scouring textile productInfo
- Publication number
- JPH03130463A JPH03130463A JP1265851A JP26585189A JPH03130463A JP H03130463 A JPH03130463 A JP H03130463A JP 1265851 A JP1265851 A JP 1265851A JP 26585189 A JP26585189 A JP 26585189A JP H03130463 A JPH03130463 A JP H03130463A
- Authority
- JP
- Japan
- Prior art keywords
- textile product
- treatment
- scouring
- ozone
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004753 textile Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 14
- 238000009991 scouring Methods 0.000 title claims description 15
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 abstract description 12
- 239000000126 substance Substances 0.000 abstract description 9
- 229920002994 synthetic fiber Polymers 0.000 abstract description 3
- 239000012209 synthetic fiber Substances 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- NAFOIZPSUNESOU-UHFFFAOYSA-N [B].[I] Chemical compound [B].[I] NAFOIZPSUNESOU-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、繊維製品、糸条、糸、布帛、二次製品等の繊
維製品に対する新規な精練方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a novel scouring method for textile products such as textile products, threads, threads, fabrics, and secondary products.
（従来の技術）
従来、繊維製品は、天然繊維の場合は繊維自体が夾雑物
を不純物として保有しており、さらには紡績、織成、編
成において、油剤、糊剤等が付着含浸される。合成繊維
においても、紡糸油剤、その後の工程での油剤、糊剤が
付与される。(Prior Art) Conventionally, when textile products are natural fibers, the fibers themselves contain impurities and are further impregnated with oils, glues, etc. during spinning, weaving, and knitting. Synthetic fibers are also given spinning oils, oils and sizing agents in subsequent steps.
これらの、繊維以外の付与されたもの、または夾雑物は
、精練により除去し、後の工程の、漂白、染色、仕上げ
に対して、支障のないようにしている。These added substances other than fibers or impurities are removed by scouring so that they do not interfere with the subsequent steps of bleaching, dyeing, and finishing.
従来、これらの精練には、アルカリ物質、界面活性剤、
洗剤等の利用により実施されている。Traditionally, these scouring methods include alkaline substances, surfactants,
This is done by using detergents, etc.
また近年においては、低温プラズマ処理も提案されてい
る。（例えば、特開昭５８−６００６０号公報、特開昭
５８−８７３８３号公報）（発明が解決しようとする課
題）
従来の精練方法において、アルカリ物質、界面活性剤、
洗剤の組み合わせによる精練においては、薬剤を多量に
使用する費用もさることながら、これら薬剤の後処理（
無公害化）に多大のコストが必要となる。さらに低温プ
ラズマにおいては、初期の装置コストが高いこと、さら
に減圧下における処理のため、繊維製品を減圧下におく
装置が必要である。また減圧下による処理のため、その
減圧条件のコントロール等工程が繁雑となり易い。In recent years, low-temperature plasma treatment has also been proposed. (For example, JP-A-58-60060, JP-A-58-87383) (Problems to be Solved by the Invention) In conventional scouring methods, alkaline substances, surfactants,
In scouring using a combination of detergents, in addition to the cost of using large amounts of chemicals, the post-treatment of these chemicals (
(Pollution-free) will require a large amount of cost. Furthermore, in the case of low-temperature plasma, the initial cost of equipment is high, and furthermore, since the process is carried out under reduced pressure, an apparatus for placing the textile product under reduced pressure is required. In addition, since the treatment is performed under reduced pressure, the process such as controlling the reduced pressure conditions tends to be complicated.
（課題を解決するための手段）
本発明はかかる従来の課題を考慮して、種々の課題を解
決する新規なる精練方法を提供するものである。(Means for Solving the Problems) The present invention takes these conventional problems into consideration and provides a novel scouring method that solves various problems.
すなわち本発明は、繊維製品の精練において、繊維製品
に対して、オゾン処理およびＵＶ光照射処理を併用する
ことを特徴とする精練方法である。That is, the present invention is a scouring method characterized by using ozone treatment and UV light irradiation treatment on the textile product in combination.
すなわち本発明は、精練すべき繊維製品を、オゾンによ
って処理することと、ＵＶ光にさらして処理することを
併用して処理することにより、薬剤の使用なく、かつ大
がかりな減圧装置が不要の精練が可能となる方法である
。In other words, the present invention enables scouring without the use of chemicals and without the need for a large-scale decompression device by treating the textile products to be scoured using a combination of ozone treatment and exposure to UV light. This is a method that makes it possible.
本発明でいう繊維とは、木綿、麻、絹、羊毛等の天然繊
維、ビスコースレーヨン、アセテート繊維、ベンベルブ
繊維、プロミ・ソクス繊維、ポリエステル繊維、ナイロ
ン繊維、ポリアクリル系繊維、ビニロン繊維等の半合成
、合成の繊維があり、単独の場合でも、混合使用のもの
でもよい。また本発明でいう繊維製品とは、上述の繊維
からなる製品のもので、具体的には、原綿、ト・ツブ、
トウ、紡績糸、フィラメント糸、加工糸、織物、編物、
不織布、さらに、くつ下、セーター等の二次製品も上げ
られる。The fibers used in the present invention include natural fibers such as cotton, hemp, silk, and wool, viscose rayon, acetate fiber, bembelub fiber, promi-sox fiber, polyester fiber, nylon fiber, polyacrylic fiber, vinylon fiber, etc. There are semi-synthetic and synthetic fibers, which can be used alone or in combination. In addition, the textile products referred to in the present invention refer to products made of the above-mentioned fibers, and specifically include raw cotton, tofu,
Tow, spun yarn, filament yarn, processed yarn, woven fabric, knitted fabric,
Non-woven fabrics and secondary products such as socks and sweaters are also included.
本発明におけるオゾン処理とは、精練すべき繊維製品を
、オゾンを含んだ雰囲気にさらしてとり去るべき、糊剤
等をオゾン処理することであり、このときの条件として
、オゾンの濃度は、１１０００ＰＰ〜５００００ＰＰＭ
、好ましくは１５００〜３００００ＰＰＭ、さらに好
ましくは２０００〜３００００ＰＰＭであり、あまり希
釈であるとより長時間処理する必要があり生産性にわい
て好ましくない。このときの温度は、特に限定されず１
０℃〜９０°Ｃの範囲で適宜選択すればよい。オゾン処
理の時間は、１０秒〜５分程度であり、処理される繊維
製品の必要精練度に応じて選定すればよい。Ozone treatment in the present invention refers to exposing the textile product to be refined to an ozone-containing atmosphere to ozone-treat the sizing agent and the like to be removed. ~50000PPM
, preferably from 1,500 to 30,000 PPM, more preferably from 2,000 to 30,000 PPM; too much dilution requires a longer treatment time, which is unfavorable in terms of productivity. The temperature at this time is not particularly limited and is 1
The temperature may be appropriately selected within the range of 0°C to 90°C. The ozone treatment time is approximately 10 seconds to 5 minutes, and may be selected depending on the required degree of scouring of the textile product to be treated.
本発明におけるＵＶ光照射処理とは、精練すべき繊維製
品を、一定光度のＵＶ光にさらすことであり、このとき
使用されるＵＶ光、波長２５４ｎｍを中心とする光線を
主体とするものであり、その光量としては、繊維製品面
に対して１０〜８０ｍＷ／ｃＪの範囲が好ましいが特に
限定されるものではない。温度は１０〜９０″０１時間
は、３０秒〜５分程度であり、適宜選択すればよい。The UV light irradiation treatment in the present invention refers to exposing the textile product to be refined to UV light of a certain intensity, and the UV light used at this time is mainly light with a wavelength of 254 nm. The amount of light is preferably in the range of 10 to 80 mW/cJ relative to the surface of the textile product, but is not particularly limited. The temperature is 10 to 90'' and the time is about 30 seconds to 5 minutes, and may be selected as appropriate.
これらのオゾン処理とＵＶ光照射処理は、別々に処理し
てもよく、同時処理をしてもよいが、好ましくは、同時
処理である。さらに前記処理は、繊維製品が、水分率で
５％以下、好ましくは３％以下のいわゆるドライ状態で
ある方が、効果的であり好ましい。These ozone treatment and UV light irradiation treatment may be performed separately or simultaneously, but preferably, they are performed simultaneously. Furthermore, the treatment is more effective and preferred when the textile product is in a so-called dry state with a moisture content of 5% or less, preferably 3% or less.
（実施例）
毛焼き後の乾燥生機（水分率２．０％、綿１００％の５
０番手のブロード）を、大気圧下でオゾン濃度１７０Ｑ
ＯＰＰＭ１２００ Ｗの低圧水銀ランプで４０ｍ Ｗ
／ ｃｉで、１分間処理し、その後９０℃×１５分間（
ダイサーフＬ Ｆ ２ｇ／ｌ ） ｉ’Ａ ’１５’ｃ
いした。（Ａ試料）
比較として、毛焼き後の乾燥生機（実施例と同一サンプ
ル）を、プラズマ処理Ｌ Ｃ２０ｇ／！ 、ノイゲンＨ
Ｌ Ｏ，Ｓｇ／ｌの精練浴で６０ ’ＣＸ ５時間処理
し、後実施例と同様に湯洗いした。（Ｂ試料）他の比較
例として毛焼き後の乾燥生機（実施例と同一サンプル）
を、酵素中、Ｏ，１Ｔｏｒｒ下で、３００Ｗのプラズマ
処理を１分間行ない、実施例と同様に、湯洗いした。（
Ｃ試料）
得られた各試料を乾燥し、ＪＩＳ−Ｌ−１０１８のバイ
レック法による吸水性とヨウ素ホウ素呈色反応を測定し
た。結果を表−１に示す。(Example) Gray dryer after burning (moisture content 2.0%, 100% cotton 5
0 broad) at an ozone concentration of 170Q under atmospheric pressure.
40m W with OPPM1200W low pressure mercury lamp
/ci for 1 minute, then at 90°C for 15 minutes (
Daisurf LF 2g/l) i'A '15'c
I wanted it. (Sample A) For comparison, a dried greige machine (same sample as in the example) after burning was plasma treated with LC20g/! , Neugen H
It was treated in a scouring bath of LO, Sg/l for 5 hours at 60'CX, and then washed with hot water in the same manner as in the example. (Sample B) Another comparative example is a drying machine after burning (same sample as the example)
was subjected to plasma treatment at 300 W for 1 minute in an enzyme atmosphere under O, 1 Torr, and washed with hot water in the same manner as in the example. (
Sample C) Each of the obtained samples was dried, and the water absorption and iodine-boron color reaction were measured by the Bayreck method of JIS-L-1018. The results are shown in Table-1.
表 −１ 稍同−の効果が得られることが判る。Table-1 It can be seen that a somewhat similar effect can be obtained.
（発明の効果）
本発明のオゾン処理とＵＶ光照射処理とを併用した、繊
維製品の精練法により、精練後の薬剤の回収や廃棄のた
めの処理が不要であり、また減圧装置等の特別な装置が
必要でない、簡素なる方法で、有効に精練しうることか
わかった。(Effects of the Invention) The scouring method for textile products that uses both ozone treatment and UV light irradiation treatment of the present invention eliminates the need for treatment for recovering and disposing of chemicals after scouring, and also requires special treatment such as a decompression device. It was found that scouring can be done effectively using a simple method that does not require any special equipment.
Claims (1)
ン処理とＵＶ光照射処理とを併用することを特徴とする
繊維製品の精練方法。(1) A method for scouring textile products, which comprises using ozone treatment and UV light irradiation treatment on the textile products in combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1265851A JPH03130463A (en) | 1989-10-12 | 1989-10-12 | Method for scouring textile product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1265851A JPH03130463A (en) | 1989-10-12 | 1989-10-12 | Method for scouring textile product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03130463A true JPH03130463A (en) | 1991-06-04 |
Family
ID=17422956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1265851A Pending JPH03130463A (en) | 1989-10-12 | 1989-10-12 | Method for scouring textile product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03130463A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1074800C (en) * | 1993-02-16 | 2001-11-14 | 联邦科学和工业研究组织 | Wool and wool-blend fabric treatment |
| JP2008240166A (en) * | 2007-03-26 | 2008-10-09 | National Institute Of Advanced Industrial & Technology | Method for photo-modifying natural fiber and apparatus therefor |
| JP2010535951A (en) * | 2007-08-10 | 2010-11-25 | ライプニッツ−インスティトゥート フュール プラズマフォルシュング ウント テヒノロギー エー．ファウ． | Textile cleaning and sterilization method using plasma, and plasma lock |
| CN101914847A (en) * | 2010-07-29 | 2010-12-15 | 湖北康源药业有限公司 | Medicinal lining cloth and processing method thereof |
| WO2014104695A1 (en) * | 2012-12-26 | 2014-07-03 | 주식회사 코아띠 | Smart pad |
| JP2020020082A (en) * | 2018-07-18 | 2020-02-06 | 地方独立行政法人神奈川県立産業技術総合研究所 | Fabric bleaching method and method for reducing color reversion of bleached fabric |
-
1989
- 1989-10-12 JP JP1265851A patent/JPH03130463A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1074800C (en) * | 1993-02-16 | 2001-11-14 | 联邦科学和工业研究组织 | Wool and wool-blend fabric treatment |
| JP2008240166A (en) * | 2007-03-26 | 2008-10-09 | National Institute Of Advanced Industrial & Technology | Method for photo-modifying natural fiber and apparatus therefor |
| JP2010535951A (en) * | 2007-08-10 | 2010-11-25 | ライプニッツ−インスティトゥート フュール プラズマフォルシュング ウント テヒノロギー エー．ファウ． | Textile cleaning and sterilization method using plasma, and plasma lock |
| CN101914847A (en) * | 2010-07-29 | 2010-12-15 | 湖北康源药业有限公司 | Medicinal lining cloth and processing method thereof |
| WO2014104695A1 (en) * | 2012-12-26 | 2014-07-03 | 주식회사 코아띠 | Smart pad |
| JP2020020082A (en) * | 2018-07-18 | 2020-02-06 | 地方独立行政法人神奈川県立産業技術総合研究所 | Fabric bleaching method and method for reducing color reversion of bleached fabric |
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