JPH0284595A - Mark material having insecticide emitting function - Google Patents
Mark material having insecticide emitting functionInfo
- Publication number
- JPH0284595A JPH0284595A JP23709288A JP23709288A JPH0284595A JP H0284595 A JPH0284595 A JP H0284595A JP 23709288 A JP23709288 A JP 23709288A JP 23709288 A JP23709288 A JP 23709288A JP H0284595 A JPH0284595 A JP H0284595A
- Authority
- JP
- Japan
- Prior art keywords
- microcapsules
- mark
- cloth
- insect repellent
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 54
- 239000002917 insecticide Substances 0.000 title abstract description 5
- 239000003094 microcapsule Substances 0.000 claims abstract description 35
- 239000004744 fabric Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011148 porous material Substances 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000000853 adhesive Substances 0.000 claims abstract description 4
- 230000001070 adhesive effect Effects 0.000 claims abstract description 4
- 239000000077 insect repellent Substances 0.000 claims description 38
- 150000004703 alkoxides Chemical class 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 abstract description 29
- 239000011230 binding agent Substances 0.000 abstract description 14
- 238000000034 method Methods 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000006068 polycondensation reaction Methods 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 239000012790 adhesive layer Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000012943 hotmelt Substances 0.000 description 8
- 229920003002 synthetic resin Polymers 0.000 description 7
- 239000000057 synthetic resin Substances 0.000 description 7
- 241000255925 Diptera Species 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- ONBQEOIKXPHGMB-VBSBHUPXSA-N 1-[2-[(2s,3r,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy-4,6-dihydroxyphenyl]-3-(4-hydroxyphenyl)propan-1-one Chemical compound O[C@@H]1[C@H](O)[C@@H](CO)O[C@H]1OC1=CC(O)=CC(O)=C1C(=O)CCC1=CC=C(O)C=C1 ONBQEOIKXPHGMB-VBSBHUPXSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 229940126142 compound 16 Drugs 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- JAXFJECJQZDFJS-XHEPKHHKSA-N gtpl8555 Chemical compound OC(=O)C[C@H](N)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](C(C)C)C(=O)N1CCC[C@@H]1C(=O)N[C@H](B1O[C@@]2(C)[C@H]3C[C@H](C3(C)C)C[C@H]2O1)CCC1=CC=C(F)C=C1 JAXFJECJQZDFJS-XHEPKHHKSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明はマイクロカプセルに防虫剤を封入し、これを布
地あるいは接着剤に含ませて上着、下着、靴下、帽子の
如き衣類等に装着し、長期間にわたって当該防虫剤の発
散効果を得て蚊、蝿等から回避することを可能とした防
虫剤発散機能を有するマーク材に関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention involves encapsulating an insect repellent in microcapsules, impregnating it with fabric or adhesive, and attaching it to clothing such as jackets, underwear, socks, and hats. The present invention also relates to a mark material having an insect repellent dispersion function that allows the insect repellent to be dispersed over a long period of time and to avoid mosquitoes, flies, etc.
［発明の背景］
蚊、蝿等が身辺にまとわりつくことは余り快適なことで
はない。従って、従来から蚊取線香、殺虫剤、蝿取紙等
によってこれらを回避し、または駆除するに至っている
。[Background of the Invention] Having mosquitoes, flies, etc. all around you is not very comfortable. Therefore, mosquito coils, insecticides, fly paper, etc. have been used to avoid or exterminate these insects.
然しなから、例えば、屋外でスポーツを行おうとする時
、この種の薬剤等が有効でないことは言うまでもない。However, it goes without saying that this type of drug is not effective when, for example, one tries to play sports outdoors.
従って、従来から、スプレー式防虫剤を皮膚に噴霧し、
あるいは、液状の防虫剤を塗布するという方法が採用さ
れている。Therefore, conventionally, spray-type insect repellents are sprayed on the skin,
Alternatively, a method of applying liquid insect repellent has been adopted.
ところが、この種の防虫剤は発散し易いために短期的効
果しか望むことが出来ず、しかも汗等によって容易に流
失してしまう。また、皮膚に直接塗布等を行うためにこ
れを嫌う人も多く且つ塗布乃至噴霧行為が煩雑であると
の指摘もなされている。However, since this type of insect repellent is easily dispersed, only short-term effects can be expected, and moreover, it is easily washed away by sweat or the like. Furthermore, it has been pointed out that many people dislike this method because it is applied directly to the skin, and that the act of applying or spraying is complicated.
［発明の目的コ
本発明は前記の不都合を克服するためになされたもので
あって、防虫剤からなる粒子を多孔質の超微粒子、例え
ば、水の分子よりも小さな粒子内に封入したマイクロカ
プセル化組成物をマーク材に含有させ、衣類等が製品と
して完成した後で所望の場所にこのマーク材の貼着等を
行って、長期間にわたり防虫効果を得ることを可能とす
る防虫剤発散機能を有するマーク材を提供することを目
的とする。[Object of the Invention] The present invention has been made to overcome the above-mentioned disadvantages, and provides microcapsules in which insect repellent particles are encapsulated within porous ultrafine particles, for example, particles smaller than water molecules. Insect repellent release function that makes it possible to obtain an insect repellent effect for a long period of time by incorporating a chemical composition into a mark material and attaching the mark material to a desired location after the garment, etc. is completed as a product. The purpose of the present invention is to provide a mark material having the following characteristics.
［目的を達成するた杓の手段］
前記の目的を達成するために、本発明は衣類等を構成す
る布地に対して配設されるマーク材において、前記マー
ク材はマーク材本体若しくはマーク材を布地に貼着する
接着剤に防虫剤を封じ込めた超微細孔の多孔質で且つ三
次元構造のマイクロカプセルを含ませるよう構成するこ
とを特徴とする。[Means for Achieving the Object] In order to achieve the above object, the present invention provides a marking material disposed on a fabric constituting clothing or the like, wherein the marking material is a marking material itself or a marking material. It is characterized in that the adhesive attached to the fabric contains microcapsules with three-dimensional structure and porous ultra-fine pores in which the insect repellent is encapsulated.
［実施態様］
次に、本発明に係る防虫剤発散機能を有するマーク材に
ついて好適な実施態様を挙げ、添付の図面を参照しなが
ら以下詳細に説明する。なお、ここで、衣類等とは、上
着、下着、靴下、帽子等の利用者がその身体に装着可能
な全ての製品を含むものとする。[Embodiments] Next, preferred embodiments of the marking material having an insect repellent dispersion function according to the present invention will be described in detail with reference to the accompanying drawings. Note that clothing, etc., as used herein, includes all products that can be worn on the user's body, such as jackets, underwear, socks, and hats.
先ず、マーク材に含有される防虫刺入のマイクロカプセ
ルについて説明する。第１図に示すように、マイクロカ
プセル１０は、実質的に、防虫剤からなる粒子を多孔質
、超微粒子内に封入したマイクロカプセル化組成物であ
る。この場合、マイクロカプセル１０の径は略１０〜１
００１００ｎ、０１μｍ乃至０．１μｍ）程度であって
、エチルシリケートあるいは金属アルコキシドからなる
シリカ材１２の粒子間若しくはその中央部に防虫剤から
なる粒子１４が存在している。シリカ材１２の粒子間隔
はオンゲス上ローム単位で示される超微細である。なお
、金属アルコキシドから合成される粒子径の値は反応系
の実験変数を変化させても前述の粒子径が殆ど変化して
いないことが判明している。First, the insect repellent microcapsules contained in the mark material will be explained. As shown in FIG. 1, the microcapsule 10 is essentially a microencapsulated composition in which particles of an insect repellent are encapsulated within porous, ultrafine particles. In this case, the diameter of the microcapsule 10 is approximately 10 to 1
00100n, 01 μm to 0.1 μm), and particles 14 made of insect repellent are present between or in the center of particles of silica material 12 made of ethyl silicate or metal alkoxide. The particle spacing of the silica material 12 is ultrafine, expressed in Onges loam units. It has been found that the particle size synthesized from the metal alkoxide does not change much even if the experimental variables of the reaction system are changed.
ここで、このマイクロカプセル１０の製造法としては、
防虫剤からなる粒子１４をエチルシリケートや金属アル
コキシド溶液に分散させた後、ゾル−ゲル触媒を加え、
通常、数分乃至数１０分の範囲内でゾルーゲル法固有の
加水分解および重縮合反応を完了させて第１図および第
２図に示すマイクロカプセル１０を作成する。この場合
、マイクロカプセル１０は微小な粒子であるため、物理
的には破壊されず、また、触媒作用を介して当該マイク
ロカプセル１０を形成する外周の金属アルコキシドであ
るシリカ材１２によって超微細孔で且つ多孔質の壁が画
成されるため、封入された防虫剤からなる粒子１４がこ
のマイクロカプセル１０の超微細孔より徐々に揮発され
ることになる。また、このシリカ材１２によって画成さ
れる超微細孔は水分子より孔径が小さく、従って、長期
にわたって防虫性と耐洗濯性を有している。そして、こ
のマイクロカプセル１０が集合して第３図に示すような
三次元状の包接化合物１６を形成する。Here, the method for manufacturing this microcapsule 10 is as follows:
After dispersing particles 14 made of an insect repellent in an ethyl silicate or metal alkoxide solution, a sol-gel catalyst is added,
Usually, the hydrolysis and polycondensation reactions specific to the sol-gel method are completed within a few minutes to several tens of minutes to produce the microcapsules 10 shown in FIGS. 1 and 2. In this case, since the microcapsules 10 are minute particles, they are not physically destroyed, and the silica material 12, which is a metal alkoxide on the outer periphery, forms the microcapsules 10 through catalytic action. Moreover, since the porous wall is defined, the encapsulated insect repellent particles 14 are gradually volatilized from the ultrafine pores of the microcapsules 10. Further, the ultra-fine pores defined by this silica material 12 have a smaller pore diameter than water molecules, and therefore have long-term insect repellency and washing resistance. Then, the microcapsules 10 are aggregated to form a three-dimensional clathrate compound 16 as shown in FIG.
次に、このように構成される包接化合物１６をマーク材
に含有させる工程について説明する。Next, a process of incorporating the clathrate compound 16 configured as described above into the mark material will be explained.
先ず、衣類、例えば、Ｔシャツにマーク材を装着する場
合について例示する。その際、マーク材の基本構成物と
しては、好適には、短繊維植毛材が利用される。そこで
、短繊維植毛材をＴシャツに貼着するための糊剤、すな
わち、バインダー２０に防虫剤からなる粒子１４を含有
するマイクロカプセル１０を攪拌混在させる。適宜、こ
のバインダー２０に顔料を加えて色の調整を図ることも
可能である。First, a case where a mark material is attached to clothing, for example, a T-shirt will be illustrated. In this case, short fiber flocked material is preferably used as the basic constituent of the mark material. Therefore, microcapsules 10 containing particles 14 made of an insect repellent are stirred and mixed with a binder 20, which is a glue for attaching the short fiber flocking material to a T-shirt. It is also possible to adjust the color by adding a pigment to the binder 20 as appropriate.
次いで、これをシルクスクリーン２２によって印刷等の
手法によりＴシャツ等の布地面２４に所望の図柄状に印
刷する。この結果、図形化された短繊維移植接着層２６
が形成されることになる。Next, this is printed in a desired pattern on a cloth surface 24 of a T-shirt or the like using a method such as printing using a silk screen 22. As a result, the shaped short fiber grafted adhesive layer 26
will be formed.
さらに、前記接着層２６が乾燥しないうちに植毛台紙２
８に植設された短繊維群３０の先端部をこれに重ね合わ
せて加熱押圧する。この結果、前記短繊維移植接着層２
６は所定圧力下に強制乾燥され、Ｔシャツ等の布地面２
４に図柄状に印刷形成された短繊維移植接着層２６のみ
に植毛台紙２８に植設された短繊維群３０の先端部が貼
着される。Furthermore, before the adhesive layer 26 dries, the flocked mount 2
The tip of the short fiber group 30 planted in 8 is superimposed on this and heated and pressed. As a result, the short fiber grafted adhesive layer 2
6 is forcibly dried under a predetermined pressure, and the cloth surface 2 of a T-shirt, etc.
The tips of the short fiber groups 30 implanted on the flocking mount 28 are adhered only to the short fiber implant adhesive layer 26 printed in a pattern on 4.
次いで、布地面２４から植毛台紙２８を剥がし取れば、
前記植毛台紙２８に植設された短繊維群３０は比較的簡
単に剥離されて布地面２４に図柄状に移植され、この結
果、前記布地面２４に短繊維からなる植毛図柄が形成さ
れることになる。これがマーク材である。Next, if the flocked mount 28 is peeled off from the fabric surface 24,
The short fiber group 30 planted on the flocked mount 28 is relatively easily peeled off and transplanted to the fabric surface 24 in a pattern, and as a result, a flocked pattern made of short fibers is formed on the fabric surface 24. become. This is the mark material.
すなわち、布地面２４に合成樹脂を主成分とし且つ防虫
剤をマイクロカプセル化して内包するインク （バイン
ダー２０）を用いて図柄状の短繊維移植接着層２６を印
刷形成した後、これが乾燥しないうちに植毛台紙２８に
植設された短繊維群３０の先端部を重ね合わせてアイロ
ン等の加熱押圧器具３２で加熱押圧する。この結果、植
毛台紙２８に植設された短繊維群３０の先端部をＴシャ
ツ等の布地面２４に当接した状態で乾燥し、これによっ
て水分が蒸発し、布地面２４に図柄状に、印刷形成され
た短繊維移植接着層２６を構成する合成樹脂液が布地面
２４の繊維質に浸透する。従って、短繊維移植接着層２
６を形成する合成樹脂は互いに合成樹脂と合成樹脂の間
で、また、合成樹脂を付着した短繊維群３０の先端部お
よび合成樹脂を浸透した布地面２４を構成する繊維質相
互間で架橋反応が促進されることになる。この合成樹脂
による架橋反応の結果、布地面２４に植毛台紙２８の短
繊維群３０が植設されることになる。そして、その結着
が完了した時、布地面２４から植毛台紙２８を剥がし取
ると、植毛台紙２８から布地面２４に対して印刷形成さ
れた短繊維移植接着層２６通りの図柄状に短繊維群３０
が引き抜かれて移植が完了する。すなわち、布地面２４
には短繊維群３０による図柄が形成される。この時、防
虫剤発散性のマイクロカプセル１０がその微細な多孔質
部分から発散して防虫効果が得られる。That is, after printing the short fiber grafting adhesive layer 26 in the shape of a pattern on the fabric surface 24 using an ink (binder 20) that contains synthetic resin as a main component and microencapsulating an insect repellent, the short fiber grafting adhesive layer 26 is printed before it dries. The tips of the short fiber groups 30 planted on the flocking mount 28 are overlapped and heated and pressed using a heating pressing device 32 such as an iron. As a result, the tip of the short fiber group 30 planted on the flocking mount 28 dries while in contact with the cloth surface 24 of a T-shirt, etc., and as a result, the moisture evaporates and a pattern is formed on the cloth surface 24. The synthetic resin liquid constituting the printed short fiber graft adhesive layer 26 penetrates into the fibers of the fabric surface 24. Therefore, the short fiber graft adhesive layer 2
The synthetic resin forming 6 undergoes a crosslinking reaction between the synthetic resins and between the fibers constituting the tips of the short fiber group 30 to which the synthetic resin is attached and the fabric surface 24 impregnated with the synthetic resin. will be promoted. As a result of this crosslinking reaction by the synthetic resin, short fiber groups 30 of the flocked mount 28 are planted on the fabric surface 24. When the binding is completed, the flocked mount 28 is peeled off from the fabric surface 24, and the short fibers are grouped in the pattern of the short fiber graft adhesive layer 26 printed from the flocked mount 28 onto the fabric surface 24. 30
is pulled out and the transplant is completed. That is, the fabric surface 24
A pattern is formed by short fiber groups 30. At this time, the insect repellent-releasing microcapsules 10 are released from their fine porous portions, providing an insect repellent effect.
前記の実施態様においては、シルクスクリーン印刷によ
って、バインダー２０とＴシャツ等の布地面２４に文字
状若しくは図柄状に印刷することにより、短繊維植毛材
を貼着する工程を介してマーク材と、このマーク材が貼
着される衣類等について説明したが、短繊維植毛材に対
して、直接、シルクスクリーン印刷によりバインダー２
０を印刷し、次いで、これをＴノヤツ等に転写して図柄
等からなるマーク材を得ることが可能なことは勿論であ
る。In the above-mentioned embodiment, the marking material is formed through the process of pasting short fiber flocking material by printing letters or designs on the binder 20 and the fabric surface 24 of a T-shirt or the like using silk screen printing. We have explained about the clothing etc. to which this mark material is attached, but the binder 2 is directly applied to the short fiber flocked material by silk screen printing.
It goes without saying that it is possible to print a 0 and then transfer it to a T-piece or the like to obtain a mark material consisting of a pattern or the like.
すなわち、バインダー２０に、先ず、所望の防虫剤から
なる粒子１４を含むマイクロカプセル１０を攪拌して混
在させる。次いで、短繊維植毛台紙の短繊維群３０上に
、シルクスクリーン２２を介してマイクロカプセル１０
を含むバインダー２０を印刷する。実質的に所望の図柄
がこのバインダー２０によって短繊維群３０上に描出さ
れる。その上にホットメルト樹脂層を塗布あるいは散布
する。次に、乾燥させてマーク材を得る。そして、購買
者がその図柄と香料とを基準として所望のマーク材を選
択する時、Ｔシャツ等の布地面２４にこの選ばれたマー
ク材を載置し、ホットプレスでバインダー２０を布地面
２４に対面させて加圧加熱する。そして、植毛台紙２８
を剥離すれば、前記選択された図形の、しかも防虫効果
を発揮する衣類等が得られることになる。That is, first, microcapsules 10 containing particles 14 made of a desired insect repellent are mixed into the binder 20 by stirring. Next, the microcapsules 10 are placed on the short fiber group 30 of the short fiber flocking board through the silk screen 22.
A binder 20 containing the following is printed. Substantially a desired pattern is drawn on the short fiber group 30 by the binder 20. A hot melt resin layer is applied or sprayed thereon. Next, it is dried to obtain a mark material. When the purchaser selects a desired mark material based on the design and fragrance, the selected mark material is placed on the fabric surface 24 of a T-shirt, etc., and the binder 20 is applied to the fabric surface 24 using a hot press. Heat under pressure by placing them facing each other. And flocking mount 28
By peeling it off, clothing or the like having the selected pattern and exhibiting an insect repellent effect can be obtained.
さらに、ホットメルト剤４２に防虫剤を含有するマイク
ロカプセル１０を混在させ、同様の効果を得ることも可
能である。すなわち、マーク地４０の一面に防虫剤を含
有するマイクロカプセル１０を混在させたホットメルト
剤４２を塗布する。Furthermore, it is also possible to obtain the same effect by mixing the microcapsules 10 containing an insect repellent in the hot melt agent 42. That is, a hot melt agent 42 mixed with microcapsules 10 containing an insect repellent is applied to one surface of the marking area 40.
次いで、ホットメルト剤４２側を、例えば、Ｔシャツ４
４の布地面２４に対面させる。そして、このマーク地４
０にアイロン等を押し当てて加圧加熱する。この結果、
ホットメルト剤４２は溶融してマーク地４０とＴシャツ
４４に含浸し、従って、ホットメルト剤４２に含まれる
マイクロカプセル１０も同様に各々の素材に浸透するに
至る。Next, the hot melt agent 42 side is placed on, for example, a T-shirt 4.
4 to face the cloth surface 24 of No. 4. And this mark place 4
Press and heat with an iron or the like. As a result,
The hot-melt agent 42 melts and impregnates the marking area 40 and the T-shirt 44, and accordingly, the microcapsules 10 contained in the hot-melt agent 42 also permeate each material.
［発明の効果コ
以上のように、本発明によれば、防虫剤からなる粒子を
超微細孔の多孔質マイクロカプセル内に封入し、このマ
イクロカプセルを添加してマーク材を得ている。この結
果、次なる効果を奏する。[Effects of the Invention] As described above, according to the present invention, particles of an insect repellent are encapsulated in porous microcapsules with ultra-fine pores, and the marking material is obtained by adding the microcapsules. As a result, the following effects are achieved.
■ 防虫剤からなる粒子がこのマイクロカプセルの超微
細孔より徐々に揮発するためマーク材から長期にわたり
防虫効果を得ることが出来る。■ Particles made of insect repellent gradually evaporate through the ultra-fine pores of these microcapsules, making it possible to obtain insect repellent effects over a long period of time from the mark material.
この場合、前記超微細孔は水分子より小さいのでマイク
ロカプセル内に水分子が浸透し難く、従って、高い耐洗
濯性が得られる。In this case, since the ultra-fine pores are smaller than water molecules, it is difficult for water molecules to penetrate into the microcapsules, and therefore, high washing resistance can be obtained.
■ 衣類にこのマーク材を貼着した場合、このマーク材
本来の機能に加えて防虫機能が加わるので、商品価値が
高いものになる。■ When this marking material is attached to clothing, it has a high commercial value because it has an insect repellent function in addition to its original function.
■ また、本発明によれば、直接、防虫剤を皮膚等に塗
り、あるいは噴霧する必要がないために、当該塗布作業
等の繁雑さから開放され、また、発汗と共に塗布された
防虫剤が流出し、皮膚を伝わるという不快感もない。■ Furthermore, according to the present invention, there is no need to directly apply or spray the insect repellent to the skin, etc., which eliminates the complexity of the application process, and the applied insect repellent flows out with perspiration. Also, there is no discomfort caused by it being transmitted through the skin.
■ さらに、本発明では、マーク材に防虫剤を含むマイ
クロカプセルを含有させ、しかもマーク材は衣類として
の製品の最終段階で付されるものであるために、防虫剤
発散機能についていえば需要者が衣類を購買した段階で
初期状態にある。従って、防虫機能が損なわれることが
ない状態で需要者は所望の衣類を着用出来る。Furthermore, in the present invention, the mark material contains microcapsules containing an insect repellent, and since the mark material is added at the final stage of the product as clothing, the insect repellent release function is difficult for consumers to understand. is in its initial state when the clothing is purchased. Therefore, the consumer can wear desired clothing without compromising the insect repellent function.
以上、本発明について好適な実施態様を挙げて説明した
が、本発明はこの実施態様に限定されるものではなく、
マーク材に対する着色剤にこのマイクロカプセルを含ま
せるのみならず、ホットメルト剤と図柄構成物質との間
にバインダーを介装するものにあっては、このバインダ
ーにマイクロカプセルを混在させても同様の効果が得ら
れる等、本発明の要旨を逸脱しない範囲において種々の
変更が可能なことは勿論である。Although the present invention has been described above with reference to preferred embodiments, the present invention is not limited to these embodiments.
In addition to containing microcapsules in the coloring agent for the mark material, if a binder is interposed between the hot melt agent and the design constituent material, the same effect can be obtained even if the microcapsules are mixed in the binder. It goes without saying that various changes can be made without departing from the gist of the present invention, such as obtaining effects.
第１図は本発明に係るマーク材に含まれる超微細孔を有
する多孔質マイクロカプセルの拡大概略説明図、
第２図は本発明に係るマーク材に含まれる超微細孔の多
孔質マイクロカプセルの拡大断面図、第３図は第１図並
びに第２図に示すマイクロカプセルの集合体である三次
元構造の拡大概略説明図、
第４図乃至第８図はＴシャツにマーク材を形成するプロ
セスを示す説明図、
第９図はホットメルト剤に防虫剤含有マイクロカプセル
を浸透させた状態の本発明に係るマーク材の斜視図、
第１０図は本発明に係るマーク材をＴシャツに使用した
状態を示す全体図である。
１０・・・マイクロカプセル １２・・・シリカ材１４
・・・粒子 １６・・・包接化合物２０・
・・バインダー ２２・・・シルクスクリーン２
４・・・布地面 ２Ｇ・・・短繊維移植接着
層２８・・・植毛台紙 ３０・・・短、ＩａＰ
４群４０・・・マーク地４２・・・ホントメルト剤特許
出願人 株式会社 東 京 宝 来 社同 上 株式
会社 ワーク・ステーション−−−、、、ｊｎ−。FIG. 1 is an enlarged schematic explanatory diagram of porous microcapsules having ultrafine pores contained in the mark material according to the present invention, and FIG. An enlarged sectional view, FIG. 3 is an enlarged schematic explanatory view of a three-dimensional structure that is an aggregate of microcapsules shown in FIGS. 1 and 2, and FIGS. 4 to 8 are a process of forming a mark material on a T-shirt. FIG. 9 is a perspective view of the mark material according to the present invention in which a hot melt agent is impregnated with insect repellent-containing microcapsules, and FIG. 10 is a diagram showing the mark material according to the present invention used in a T-shirt. It is an overall diagram showing the state. 10...Microcapsule 12...Silica material 14
...Particle 16...Inclusion compound 20.
... Binder 22 ... Silkscreen 2
4...Fabric surface 2G...Short fiber graft adhesive layer 28...Flocked mount 30...Short, IaP
Group 4 40...Mark area 42...Hontomelt agent patent applicant Tokyo Horai Co., Ltd. Work Station Co., Ltd.---,,,jn-.
Claims (3)
材において、前記マーク材はマーク材本体若しくはマー
ク材を布地に貼着する接着剤に防虫剤を封じ込めた超微
細孔の多孔質で且つ三次元構造のマイクロカプセルを含
ませるよう構成することを特徴とする防虫剤発散機能を
有するマーク材。(1) In a marking material placed on fabric constituting clothing, etc., the marking material is a porous material with ultra-fine pores in which an insect repellent is encapsulated in the marking material body or the adhesive that adheres the marking material to the fabric. What is claimed is: 1. A mark material having an insect repellent dispersion function, characterized in that it is configured to include microcapsules having a three-dimensional structure.
ロカプセル化組成物は径が約１０〜１００ｎｍであるこ
とを特徴とする防虫剤発散機能を有するマーク材。(2) The marking material according to claim 1, wherein the porous microencapsulated composition has a diameter of approximately 10 to 100 nm.
ロカプセル化組成物はエチルシリケートあるいは金属ア
ルコキシドからなるシリカ材と、防虫剤の粒子とからな
ることを特徴とする防虫剤発散機能を有するマーク材。(3) The mark material according to claim 2, wherein the porous microencapsulated composition is a mark having an insect repellent release function, characterized in that the porous microencapsulated composition is composed of a silica material made of ethyl silicate or metal alkoxide, and particles of an insect repellent. Material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23709288A JPH0284595A (en) | 1988-09-20 | 1988-09-20 | Mark material having insecticide emitting function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23709288A JPH0284595A (en) | 1988-09-20 | 1988-09-20 | Mark material having insecticide emitting function |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0284595A true JPH0284595A (en) | 1990-03-26 |
Family
ID=17010291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23709288A Pending JPH0284595A (en) | 1988-09-20 | 1988-09-20 | Mark material having insecticide emitting function |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0284595A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2108735A1 (en) | 2008-04-11 | 2009-10-14 | Cognis IP Management GmbH | Loadable fibres and textile sheets |
| WO2010067902A1 (en) * | 2008-12-12 | 2010-06-17 | Sumitomo Chemical Company, Limited | Resin composition for filaments |
-
1988
- 1988-09-20 JP JP23709288A patent/JPH0284595A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2108735A1 (en) | 2008-04-11 | 2009-10-14 | Cognis IP Management GmbH | Loadable fibres and textile sheets |
| WO2009124686A1 (en) * | 2008-04-11 | 2009-10-15 | Cognis Ip Management Gmbh | Chargeable fibres and textile fabrics |
| WO2010067902A1 (en) * | 2008-12-12 | 2010-06-17 | Sumitomo Chemical Company, Limited | Resin composition for filaments |
| AP3393A (en) * | 2008-12-12 | 2015-08-31 | Sumitomo Chemical Co | Resin composition for filaments |
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