JPH0284588A - Stone wash-toned silk knitted fabric - Google Patents
Stone wash-toned silk knitted fabricInfo
- Publication number
- JPH0284588A JPH0284588A JP21428088A JP21428088A JPH0284588A JP H0284588 A JPH0284588 A JP H0284588A JP 21428088 A JP21428088 A JP 21428088A JP 21428088 A JP21428088 A JP 21428088A JP H0284588 A JPH0284588 A JP H0284588A
- Authority
- JP
- Japan
- Prior art keywords
- silk
- knitted fabric
- fabric
- amino
- modified silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 60
- 239000004575 stone Substances 0.000 title description 5
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000002752 cationic softener Substances 0.000 claims description 16
- 238000005096 rolling process Methods 0.000 claims description 13
- 230000037303 wrinkles Effects 0.000 abstract description 13
- 238000011282 treatment Methods 0.000 abstract description 11
- 206010061592 cardiac fibrillation Diseases 0.000 abstract description 8
- 230000002600 fibrillogenic effect Effects 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 abstract description 4
- 238000004043 dyeing Methods 0.000 abstract description 3
- 239000004902 Softening Agent Substances 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 13
- 238000012545 processing Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000007787 solid Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002216 antistatic agent Substances 0.000 description 5
- 210000001215 vagina Anatomy 0.000 description 5
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 206010016256 fatigue Diseases 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003608 nonionic fabric softener Substances 0.000 description 1
- 239000004669 nonionic softener Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009732 tufting Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ストーンウオツシェ調Ｍ４織編物に係り、更
に詳しくは、予めＮ３５１ｍ物にカチオン系柔軟剤とア
ミノ変性シリコンを付着せしめて揉み加工し、新規な外
観及び風合を付与したストーンウォッシュ調絹Ｑ編物に
関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a stonewashed M4 woven or knitted fabric, and more specifically, a cationic softener and amino-modified silicone are attached to N351m fabric in advance and then rubbed. This invention relates to a stonewashed silk Q knitted fabric that has been processed to give it a new appearance and texture.
（従来技術とその問題点）
従来、天然木綿の洗いざらし感と着古し！！１覚をもつ
ストーンウォッシュＵＲＮ品は、石、棒等で布帛を叩く
事により行われてきた。この方法により得られる製品は
皺がなく、非常にナチュラルな風合であるが、この方法
では工業的に大量生産出来ないという問題があった。(Conventional technology and its problems) Conventionally, natural cotton has a washed-out feel and wears out! ! Stone-washed URN items with 1 sense have been made by hitting the fabric with stones, sticks, etc. The product obtained by this method has no wrinkles and has a very natural texture, but there is a problem that this method cannot be industrially mass-produced.
そこで、上記の問題点を解決するために、工業的には液
流染色機、ウィンス、ロータリーワッシャー等で布帛を
揉む事でストーンウォッシュ品！！！品が作られてきた
。上記機台の中では特にロータリーワッシャーが無張力
状態で揉み効果が作用することにより、ナチュラルな感
じの製品が得られる為、一般的に採用されてきた。しか
し、ロータリーワッシャーを用いると熱水の町布する衝
撃力が大きく、素材、組織によってはローブ状の皺、擦
れ形状の斑等が目立つ問題があった。Therefore, in order to solve the above problems, industrially, stonewashed products are created by rolling the fabric with a jet dyer, wince, rotary washer, etc. ! ! products have been made. Among the above-mentioned machines, the rotary washer in particular has been commonly used because it produces a natural-looking product by exerting a kneading effect in a tension-free state. However, when a rotary washer is used, there is a problem in that the impact force generated by hot water is large, and depending on the material and structure, lobe-like wrinkles, scratch-shaped spots, etc. are noticeable.
これを解決するものとして、特開昭５６−７９７６１号
公報にはロータリーワッシャーの熱媒体として熱水のか
わり１ζ水蒸気を用いる方法が、また特開昭５８−１６
９５８４号公報には織物をアンドン巻きにしてその両耳
部の数ケ所を糸綴じし、アンドン巻きの内側に弾力性を
有する緩衝体を位置せしめた状態でロータリーワッシャ
ー加工をする方法が提案されている。To solve this problem, Japanese Patent Application Laid-Open No. 56-79761 discloses a method of using 1ζ steam instead of hot water as a heat medium for a rotary washer.
Publication No. 9584 proposes a method in which a fabric is wrapped in a back-and-over winding, stitched at several places on both edges, and then processed with a rotary washer while an elastic buffer is placed inside the back-and-over winding. There is.
そして、綿、ナイロン、ポリエステル、アセテート、レ
ーヨン等の素材では、通常又は上述した特殊な方法でロ
ータリーワッシャーによる揉み加工がなされ、ストーン
ウォッシュ調製品が開発され、市場には数多く出回って
いる。Materials such as cotton, nylon, polyester, acetate, and rayon are rubbed with a rotary washer using the normal or special method described above, and stonewashed products have been developed, and many of them are on the market.
しかし絹熾瑞物は、繊維束が細措度の礒維に分割（フィ
ブリル化）しやすく、上記液流染色機、ウィンス、ロー
タリーワッシャーで揉み加工を施すとローブ状の皺、擦
れ形状の斑等が目立ち、工業的方法ではストーンウォッ
シュ調製品は商品化出来なかった。However, the fiber bundles of fine silk tend to split into fine fibers (fibrillation), and when rubbed using the jet dyeing machine, wince, or rotary washer described above, lobe-like wrinkles and scratched spots appear. etc., and stonewash preparations could not be commercialized using industrial methods.
本発明者等は、上述のような実情に鑑み、ストーンウォ
ッシェ調絹織編物の工業的方法での商品化の検討を重ね
た結果、ロータリーワッシャー等で揉み加工する前に、
仕上剤としてカチオン系柔軟剤とアミノ変性シリコンを
付与するとフィブリル化の防止が可能で島るとの知見を
得た。In view of the above-mentioned circumstances, the inventors of the present invention have repeatedly considered the commercialization of stone-washed silk woven and knitted products using industrial methods.
We have found that fibrillation can be prevented by applying a cationic softener and amino-modified silicone as finishing agents.
本発明は、絹織縄物自体のソフトな肌ざわりを損なうこ
となく、皺が均一で、且つ擦れ形状の斑のない立毛状態
と反溌感とを有する、全く新規なストーンウォッシュ１
絹織編物の提供を目的とするものである。The present invention provides a completely new stone wash 1 that has uniform wrinkles and a raised state with no scratched spots and a resilient feeling without impairing the soft feel of the silk woven rope itself.
The purpose is to provide silk woven and knitted fabrics.
（問題点を解決するための手段）
すなわち本発明は、揉み加工前に仕上剤を付着せしめた
組織絹物であって、前記仕上剤がカチオン系柔軟剤とア
ミノ変性シリコンであり、カチオン系柔軟剤の付Ｓ量が
絹、織編物重量の０．２〜１．５％を占め且つアミノ変
性シリコンの付着量が絹織編物重量の０．１〜１．０％
を占めているストーンウォッシュ調絹織纒物である。(Means for Solving the Problems) That is, the present invention provides tissue silk to which a finishing agent is attached before rolling, the finishing agent being a cationic softener and an amino-modified silicone, and a cationic softener and an amino-modified silicone. The amount of S attached to the agent accounts for 0.2 to 1.5% of the weight of the silk, woven or knitted fabric, and the amount of attached amino-modified silicone is 0.1 to 1.0% of the weight of the silk or woven or knitted fabric.
It is a stone-washed silk woven fabric that occupies most of the area.
（作用）
本発明は、揉み加工前Ｉこ、絹に対する吸着性の高いカ
チオン系柔軟剤とアミノ変性シリコンとを適宜爪月穢閘
物に付着せしめているので、仕上剤が口維束の保護肩と
して働き、また熱水中でも仕上剤は脱落しないため、揉
み加工時の熱水の１維束に対する衝撃力を弱める事がで
きる。このため、絹ｍ絶のフィブリル化が防止され、結
果としてローブ皺や擦れ形状のない高品質な製品が得ら
れるのである。またアミノ変性シリコンの持つ作用によ
り、反溌惑に優れた風合になるので島る。(Function) In the present invention, a cationic softener with high adsorption to silk and an amino-modified silicone are properly attached to the filth before the rolling process, so that the finishing agent protects the oral fiber bundles. Since it acts as a shoulder and the finishing agent does not fall off even in hot water, it is possible to weaken the impact force on a single fiber of hot water during rolling. Therefore, fibrillation of the silk material is prevented, and as a result, a high-quality product without wrinkles or chafing can be obtained. In addition, the action of amino-modified silicone gives it a texture that is excellent in resisting distractions.
カチオン系柔軟剤の付着量は、通常組織絹物の０．２〜
１．６％、好ましくは０．５〜ａ、 ｅ％を占める。The amount of cationic softener deposited on tissue silk is usually 0.2~
It accounts for 1.6%, preferably 0.5-a, e%.
即ち付Ｍｊｌが前記０．２％よりも少ないものであれば
、繊維束を完全に保護できず、フィブリル化を防止する
には不充分であり、一方これが１．５％より多くなると
絹特有の風合が損われ、ぬめり感が多くなるのでいずれ
も不適である。In other words, if Mjl is less than the above 0.2%, the fiber bundle cannot be completely protected and it is insufficient to prevent fibrillation, whereas if it is more than 1.5%, silk Both are unsuitable because the texture is impaired and the feeling becomes slimy.
また、アミノ変性シリコンの付着量は通常絹織編物の０
，１〜１．０％、好ましくはＯ１２〜０．５％を占める
。即ち付着量が前記０．１％よりも少ないものであれば
、ａ維束を完全に保護できず、フィブリル化を防止する
には不充分であり、また良好な風合を与える反溌感を得
ることもできない。一方これが１．０％よりも多くなる
と絹特有の風合が損われ、ぬめり感が多（なるのでいず
れも不適である。In addition, the amount of amino-modified silicone deposited is usually 0 on silk woven or knitted fabrics.
, 1 to 1.0%, preferably O12 to 0.5%. In other words, if the amount of adhesion is less than the above 0.1%, it will not be possible to completely protect the a-fibers, it will be insufficient to prevent fibrillation, and it will not give a rebound feeling that gives a good texture. I can't even get it. On the other hand, if this amount exceeds 1.0%, the unique texture of silk will be impaired and the silk will become too slimy, so both are unsuitable.
（実施例） 次に実施例によって本発明を具体的に説明する。(Example) Next, the present invention will be specifically explained with reference to Examples.
第１表に示す様に、８種類の絹織物を常法に従って糊抜
、精練、染色、フィックス処理を行った。As shown in Table 1, eight types of silk fabrics were subjected to desizing, scouring, dyeing, and fixing treatments according to conventional methods.
（以下、、余白）
第１表の実施例に示すようＩζ本発明でいう絹織編物と
は、生糸または絹紡糸単独、またはそれ等と他の天然ｄ
維、合成機維の混紡あるいは交織による織物及び編物が
挙げられ、これらのａｍ構造物を構成する経糸、緯糸の
番手、密度はロータリワッシャー加工等で組織乱れの発
生しないものであれば特に限定されない。また絹織編物
における絹の構成比率は特に限定されないが、紹特有の
ソフトな肌ざわりを得る為には６０％以上の構成比率が
好ましい。そして、生糸を用いた絹織編物の場合は、揉
み加工時のフィブリル化が大きいため皺が発生しやすい
ので、カチオン系柔軟剤とアミノ変性シリコンに加えて
グリオキザール系樹脂を併用する事が好ましい、付着量
は通常Ｍａ編物の０．９〜Ｌ ０％を占めるのが好まし
い。(Hereinafter, blank space) As shown in the examples in Table 1, the silk woven and knitted fabric referred to in the present invention refers to raw silk or spun silk alone, or those and other natural d
Examples include woven and knitted fabrics made by blending or interweaving fibers and synthetic fibers, and the counts and densities of the warps and wefts that make up these am structures are not particularly limited as long as they do not cause tissue disturbance when processed with a rotary washer, etc. . The composition ratio of silk in silk woven and knitted fabrics is not particularly limited, but a composition ratio of 60% or more is preferable in order to obtain the characteristic soft touch. In the case of silk woven and knitted fabrics using raw silk, wrinkles are likely to occur due to large fibrillation during rolling, so it is preferable to use glyoxal resin in addition to cationic softeners and amino-modified silicones. The amount of adhesion is preferably 0.9 to 0% of the Ma knitted fabric.
上記絹織編物に付与するカチオン系柔軟剤の組成は特に
限定されないが、第３ｐＡアミン系、第４級アンモニウ
ム塩系、第４級ピリジニウム塩系が好ましい。また、ア
ミノ変性シリコンの組成は特に限定されないが、下記に
示す構造のものが好ましい。The composition of the cationic softener applied to the silk woven or knitted fabric is not particularly limited, but tertiary pA amine type, quaternary ammonium salt type, and quaternary pyridinium salt type are preferable. Further, the composition of the amino-modified silicon is not particularly limited, but those having the structure shown below are preferable.
そして、ストーンウォッシュカ、フ絹織−物の好ましい
加工方法としては、仕上剤を付与後、タフキングし、袋
詰めし、ロータリーワッシャーで揉み加工した後、タン
ブラ−乾燥機で乾燥する方法がある。A preferred method for processing stone-washed silk fabrics is to apply a finishing agent, tuff it, pack it into bags, rub it with a rotary washer, and then dry it with a tumble dryer.
上記の加工方法を簡単に説明する。The above processing method will be briefly explained.
上記前処理後の相識編物に仕上剤を付与するに際しては
、通常のパッド装置を用い、常法に従って乾燥し、樹脂
を併用した場合にはキユアリングを行う。When applying a finishing agent to the above-mentioned pre-treated knitted fabric, it is dried in accordance with a conventional method using a conventional pad device, and when a resin is used in combination, curing is performed.
クツキング方法は、絹織編物を縫目で分割し、幅方向を
軸に２枚に畳んだ後、耳部を糸で覆く畷じる方法でもよ
いし、吊線、吊染と同様に巻き吊り、耳部を糸で緩く綴
じる方法でもよい。袋詰めのための袋は、ポリエステル
、ナイロン、麻等の素材が使用出来るが、ｉ８ Ｄ、Ｐ
Ｉｒ物との擦れが少ないぼりエステルネットが好ましい
。ロータリーワッシャーの処理条件は、回転数２５〜４
５回転／分、浴比１；５０〜１ ：５ＯＯ１設定温度６
０〜１００℃でかつ設定時間６〜９０分の範囲が好まし
く、回転数３０〜４０回転／分、浴比１ ：１００〜１
： ２００．設定温度５０°〜６０℃ でかつ設定時間
ｓｏ−ｇｏ分の範囲が更に好ましい。上記の処理条件の
範囲外であると皺が斑になったり、ａ編物表面にピリン
グ等の欠点が発生する場合がある。The shoe-king method can be done by dividing the silk woven or knitted fabric at the seams, folding it into two sheets along the width direction, and then covering the edges with thread, or by wrapping and hanging them in the same way as hanging lines and hanging dyeing. Alternatively, the edges may be loosely bound with thread. Materials such as polyester, nylon, and hemp can be used for bags for packing, but i8 D, P
It is preferable to use a streamer ester net, which is less likely to rub against Ir materials. The processing conditions for the rotary washer are 25 to 4 rotations.
5 rotations/min, bath ratio 1:50~1:5OO1 set temperature 6
Preferably, the temperature is 0 to 100°C and the setting time is 6 to 90 minutes, the number of rotations is 30 to 40 revolutions/min, and the bath ratio is 1:100 to 1.
: 200. More preferably, the set temperature is 50° to 60° C. and the set time is in the range of so-go minutes. If the above treatment conditions are outside the range, wrinkles may become uneven and defects such as pilling may occur on the surface of the a-knitted fabric.
さらに、ストーンウ中ツシュ調を強調したい場合には、
ロータリーワッシャーの中に小石、軽石、パチンコ玉等
を入れる事が好ましい。Furthermore, if you want to emphasize the tone of the stone,
It is preferable to put pebbles, pumice stones, pachinko balls, etc. into the rotary washer.
次に第１表に示す絹織物を用いた具体的実施例によって
本発明を更に詳細に説明する。Next, the present invention will be explained in more detail with reference to specific examples using silk fabrics shown in Table 1.
実施例１
フィックス処理後の絹り物にパディング装置を用いて、
カチオン系柔軟剤（一方社油脂社製、ビクロン２９．固
型分２０％）５重量％、アミノ変性シリコン（大阪ケミ
カル社製、テキサシリコン、固型分１２％）δ重ｈ１％
、静電防止剤（第一工業！ｉｌｌ某社製、ニレノンＮｎ
２０ ） ２ ｆｆｌ ｉｔ％、残部を水で１００％
とした加工液を絹１哉物の目付の６０％付与して、赤外
線付乾燥機で１２０℃×４０秒間乾燥した。Example 1 Using a padding device on silk fabric after fixing,
Cationic softener (manufactured by Ipposha Yushi Co., Ltd., Viclon 29. Solid content 20%) 5% by weight, amino-modified silicone (manufactured by Osaka Chemical Co., Ltd., Texasilicon, solid content 12%) δ weight h 1%
, antistatic agent (Daiichi Kogyo!ill, manufactured by a certain company, Nirenone Nn
20) 2 ffl it%, balance 100% with water
The resulting processing liquid was applied to 60% of the fabric weight of silk and dried in an infrared dryer at 120° C. for 40 seconds.
次に仕上剤を付与した絹織物をＤ目を分割し、幅方向を
軸に２枚に畳み、耳部を１０ ｃｍ間隔で糸で緩く綴じ
た。その後、タッキングした絹織物をポリエステルネッ
トに入れ、ロータリーワッシャーに投入した。ロータリ
ーワッシャーの処理条件は５０回転／分、浴比１：１０
Ｇ、温度６０℃、時間５０分であり、その中で揉み加工
を行った。Next, the silk fabric to which the finishing agent had been applied was divided into D stitches, folded into two sheets with the width direction as an axis, and the edges were loosely bound with thread at 10 cm intervals. Thereafter, the tacked silk fabric was placed in a polyester net and placed in a rotary washer. Processing conditions for the rotary washer are 50 rotations/min, bath ratio 1:10
G, the temperature was 60° C. and the time was 50 minutes, and the rolling process was performed therein.
しかる後咳組織物をタンブラ−乾燥機で乾燥し、実施例
１の製品を得た。The post-cough tissue was dried in a tumble dryer to obtain the product of Example 1.
実施例！
フィックス処理後の絹織物にパディング装置を用いて、
グリオキザール系樹脂（住人化学社製、スミテックスレ
ジンＮ３−１１１．固型分４６％）５Ｍ量％、金属塩系
触媒（住人化学社製、スミテックスアクセレーターＸ−
８０）１．５重ｆｉ％、カチオン系柔軟剤（一方社油脂
社製、ビクロン２９゜固型分２０％）５Ｍ量％、アミノ
変性シリコン（大阪ケミカル社製、テキサシリコン、固
型分１２％）５重量％、静電防止剤（第一工業製薬社製
、ニレノンｍ２０）２ｉｉ％、残部を水で１００％とし
た加工液をＭｔａ物の日付の６０％付与して、赤外線付
乾燥機で１２０℃×４０秒間乾燥し、引続いて１８０℃
で３０秒間キユアリングした。Example! Using a padding device on the silk fabric after fix treatment,
Glyoxal resin (manufactured by Sumima Kagaku Co., Ltd., Sumitex Resin N3-111. Solid content 46%) 5M amount %, metal salt catalyst (manufactured by Sumiteku Kagaku Co., Ltd., Sumitex Accelerator X-
80) 1.5 weight fi%, cationic softener (manufactured by Ichisha Yushi Co., Ltd., Vicron 29° solid content 20%) 5M amount%, amino-modified silicone (manufactured by Osaka Chemical Co., Ltd., Texasilicon, solid content 12%) ) 5% by weight, 2ii% of antistatic agent (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd., Nilenone M20), and the balance of 100% water, was added to 60% of the date of the Mta material, and dried in an infrared dryer. Dry at 120°C for 40 seconds, then at 180°C
I cured it for 30 seconds.
次に仕上剤を付与した絹織物を縫目で分割し、実施例１
と同様のタッキングを施し、ポリエステルネットに入れ
、ロータリーワッシャーに投入した。ロータリーワッシ
ャーの処理条件は実施例１と同様であり、その中で揉み
加工を行い、しかる後膣絹織物をタンブラ−乾燥機で乾
燥し、実施例２の製品を得た。Next, the silk fabric to which the finishing agent was applied was divided at the seam, and Example 1
It was tacked in the same manner as above, placed in a polyester net, and placed in a rotary washer. The processing conditions in the rotary washer were the same as in Example 1, and the rolling process was carried out therein, after which the vagina silk fabric was dried in a tumble drier to obtain the product of Example 2.
比較例１
フィックス処理後の絹織物を０目で分割し、実施例１と
同様のタッキングを施し、ポリエステルネットに入れ、
ロータリーワッシャーに投入した。Comparative Example 1 The silk fabric after the fix treatment was divided at 0 stitches, tacked in the same manner as in Example 1, placed in a polyester net,
I put it in the rotary washer.
ロータリーワッシャーの処Ｊ■条件は実施例１と同様で
あり、その中で揉み加工を行い、しかる後膣絹織物をタ
ンブラ−乾燥機で乾燥し、比較例１の製品を得た。The conditions of the rotary washer were the same as in Example 1, and the rolling process was carried out therein, and the vagina silk fabric was then dried in a tumble drier to obtain the product of Comparative Example 1.
比較例２
フィックス処理後の絹織物にパディング装置を用いて、
カチオン系柔軟剤（一方社油脂社製、ビクロン２９、固
型分２０％）５重量％、静電防止剤（第一工業製薬社製
、エレメントｋＸ２０）２重量％、残部を水で１００％
とした加工液を絹織物の日付の６０％付与して、赤外線
付乾燥機で１２０℃×４０秒間乾燥した。Comparative Example 2 Using a padding device on silk fabric after fixing treatment,
5% by weight of cationic softener (manufactured by Ipposha Yushisha Co., Ltd., Vicron 29, solid content 20%), 2% by weight of antistatic agent (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., Element kX20), the balance is 100% with water.
A processing solution of 60% of the date was applied to the silk fabric, and the fabric was dried at 120° C. for 40 seconds using an infrared dryer.
次に仕上剤を付与したＭ ａ物を０目で分割し、実施例
１と同様のタフキングを施し、ポリエステルネットに入
れ、ロータリーワッシャーに投入した。ロータリーワッ
シャーの処理条件は実施例１と同様であり、その中で揉
み加工を行い、しかる後膣絹織物をタンブラ−乾燥機で
乾燥し、比較例２の製品を得た。Next, the Ma product to which the finishing agent had been applied was divided into 0-mesh pieces, subjected to tufting in the same manner as in Example 1, placed in a polyester net, and placed in a rotary washer. The processing conditions in the rotary washer were the same as in Example 1, and the rolling process was carried out therein, after which the vagina silk fabric was dried in a tumble drier to obtain the product of Comparative Example 2.
比較例３
フィックス処理後の褐１１物にパディング装置を用いて
、アミノ変性シリコン（大阪ケミカル社製、テキサシリ
コン、固型分１２％）３７Ｈ１％、静電防止剤（第一工
業製薬社製、ニレノンＮｎ２０ ’） ２１ｉ量％、残
部を水で１００％とした加工液を絹織物の目付の６０％
付与して、赤外線付乾燥機で１１Ｏ’ＣＸ４０秒間乾燥
した。Comparative Example 3 A padding device was used on the brown 11 material after the fix treatment, and amino-modified silicone (Texasilicon, manufactured by Osaka Chemical Co., Ltd., solid content 12%) 37H1%, antistatic agent (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd., Nilenone Nn20') 21i amount%, the balance was 100% with water, and the processing liquid was added to 60% of the basis weight of the silk fabric.
It was applied and dried in an infrared dryer at 110'CX for 40 seconds.
次に仕上剤を付与した絹織物を鳩目で分割し、実施例１
と同様のタッキングを施し、ポリエステルネットに入れ
、ロータリーワッシャーに投入した。ロータリーワッシ
ャーの処理条件は実施例１と同様であり、その中で揉み
加工を行い、しかる後膣ｗｉ織物をタンブラ−乾燥機で
乾燥し、比較例３の製品を得た。Next, the silk fabric to which the finishing agent was applied was divided by eyelets, and Example 1
It was tacked in the same manner as above, placed in a polyester net, and placed in a rotary washer. The processing conditions of the rotary washer were the same as in Example 1, and the rolling process was carried out therein, and then the vagina wi fabric was dried in a tumble drier to obtain a product of Comparative Example 3.
比較例４
フィックス処理後の絹織物にパディング装置を用いて、
非イオン系柔軟剤（花王アトラス社製、ソフテックスＮ
−４９１、固型分３０％）５式量％、ジメチルシリコン
（共栄社油脂社製、ライトシリコンＲ１６７、固型分１
６％）３重量％、静電防止剤（第一工業製薬社製、ニレ
ノンＮ１２０）２重ｆｆｉ％、残部を水で１００％とし
た加工液を絹織物の日付の６０％付与して、赤外綜付乾
燥機で１２０℃×４０秒間乾燥した。Comparative Example 4 Using a padding device on silk fabric after fixing treatment,
Non-ionic softener (manufactured by Kao Atlas Co., Ltd., Softex N
-491, solid content 30%) 5 formula weight%, dimethyl silicone (manufactured by Kyoeisha Yushi Co., Ltd., Light Silicone R167, solid content 1
6%) 3% by weight, an antistatic agent (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., Nyrenone N120) 2 times ffi%, and the balance 100% with water, was applied to 60% of the date of the silk fabric, and red It was dried at 120° C. for 40 seconds in a dryer with external heddles.
次に仕上剤を付与した絹織物を縫目で分割し、実施例１
と同様のタッキングを施し、ポリエステルネットに入れ
、ロータリーワッシャーに投入した。ロータリーワッシ
ャーの処理条件は実施例１と同様であり、その中で揉み
加工を行い、しかる後膣絹織物をタンブラ−乾燥機で乾
燥し比較例４の製品を得た。Next, the silk fabric to which the finishing agent was applied was divided at the seam, and Example 1
It was tacked in the same manner as above, placed in a polyester net, and placed in a rotary washer. The processing conditions in the rotary washer were the same as in Example 1, and the rolling process was carried out therein, and then the vagina silk fabric was dried in a tumble dryer to obtain a product of Comparative Example 4.
得られたストーンウォッシュ調製品については以下の評
価を行った。The obtained stonewash preparation was evaluated as follows.
外観は専門検査員１０名の肉眼鶴察により判断した。そ
の判断基準は次の通りである。The appearance was determined by visual inspection by 10 specialized inspectors. The criteria for this judgment are as follows.
Ｏ：皺の均一性に優れ、擦れ形状の斑がない。O: Excellent wrinkle uniformity and no scratch-shaped spots.
△：皺の均一性やや劣り、擦れ形状の斑が若干ある。Δ: The uniformity of wrinkles is slightly poor, and there are some scratch-shaped spots.
×：皺の均−性劣り擦れ形状の斑がある。×: The uniformity of wrinkles is poor, and there are scratch-shaped spots.
これらの評価の結果を第２表に示す。The results of these evaluations are shown in Table 2.
第２表
第２表から明らかなように、カチオン系柔軟剤とアミノ
変性シリコンを併用した製品は、皺の均一性に例れ、擦
れ形状の斑のないものである。特に生糸を用いたＭ織物
（生地陽３）は、仕上剤に樹脂を併用した方が好ましい
結果をもたらすことを確認した。As is clear from Table 2, the products using a combination of a cationic softener and amino-modified silicone have uniform wrinkles and no unevenness in the form of rubbing. In particular, it was confirmed that for the M fabric (fabric positive 3) using raw silk, the use of a resin in combination with the finishing agent brought about preferable results.
また、非イオン系柔軟剤、ジメチルシリコン等の変性さ
れていないシリコンを使用した場合、絹に対する吸着性
が悪いため熱水中でかなり腓落し、熱水の町布する＠撃
力を弱める事ができなく、従って擦れ形状の斑がある製
品しか得られないことがわかる。In addition, when non-ionic fabric softeners or unmodified silicones such as dimethyl silicone are used, they tend to fall off considerably in hot water due to their poor adsorption to silk, weakening the impact force of hot water. It can be seen that this is not possible, and therefore only a product with scratch-shaped spots can be obtained.
また感触は専門検査員１０名の触感により判断した。そ
の判断基準は次の通りである。In addition, the feel was judged by the touch of 10 professional inspectors. The criteria for this judgment are as follows.
○：反０感優れる。○: Excellent anti-zero feeling.
△：反溌感やや劣る。△: Repulsion feeling is slightly inferior.
×：反溌感劣る。×: Poor reactivity.
これらの評価の結果を第３表に示す。The results of these evaluations are shown in Table 3.
（以下、余白）
第３表
第５表から明らかなように、樹脂を使わず、カチオン系
柔軟剤とア【ノシリコンを併用した製品は反溌感に優れ
るものである。反扮惑は樹脂を併用しない仕上剤の方が
得られるが、生糸を含む絹織物（生地Ｉ！Ｉりの場合第
２表との結果において樹脂を併用した方が良いことがわ
かる。また、ジメチルシリコン等の変性されていないシ
リコンを使用した場合は反溌感が得られないことがわか
る。(Hereinafter, blank space) As is clear from Table 3 and Table 5, products that do not use resin but use a cationic softener and an [anosilicon] have an excellent rebound feeling. Anti-distraction can be obtained with a finishing agent that does not use a resin in combination, but in the case of silk fabrics (fabric I!I) containing raw silk, the results in Table 2 show that it is better to use a resin in combination. It can be seen that when unmodified silicone such as dimethyl silicone is used, no repulsion feeling is obtained.
比較例５
フィックス処理後の絹織物に実施例１と同じ加工液を付
与し、同様１ζ乾燥し、比較例５の製品を得た。Comparative Example 5 The same processing liquid as in Example 1 was applied to the silk fabric after the fix treatment, and the same was dried in the same manner as in Example 1 to obtain a product of Comparative Example 5.
比較例６ 得た。Comparative example 6 Obtained.
次に実施例１．実施例２．比較例５．比較例６で得られ
た織物の風合をＫＥＳ（周端式布帛の風合測定規格）に
より測定した。これらの評価の結果（Ｉｉ！、緯方向の
平均）を第４表に示す。Next, Example 1. Example 2. Comparative example 5. The feel of the fabric obtained in Comparative Example 6 was measured by KES (handle measurement standard for edge-type fabrics). The results of these evaluations (Ii!, average in the latitudinal direction) are shown in Table 4.
（以下余白）
第４表から明らかなように、本発明実施例で得られた製
品は厚み差（５０ｆｆ／ｃｍｆ圧縮時の厚み−０，６９
ｆ／ｃｍ！圧縮時の厚み）かられかるように脹らみ感が
ある。また、平均マサツ係数かられかるように溺さがあ
り、従来の絹製品と異り全く新規な風合である。(Left below) As is clear from Table 4, the products obtained in the examples of the present invention have a thickness difference (thickness at 50ff/cmf compression -0.69
f/cm! There is a feeling of swelling as if from the thickness (thickness when compressed). In addition, it has a soft texture as seen from the average mass coefficient, and unlike conventional silk products, it has a completely new texture.
（発明の効果）
本発明は、以上に述べた構成により、次のような効果を
奏する。(Effects of the Invention) The present invention achieves the following effects with the configuration described above.
、ｍ ｎ ｉ物にカチオン系柔軟剤とアミノ変性シリコ
ンを付着せしめているため、その後の揉み加工において
フィブリル化がおこらず、その為得られる製品は絹織編
物自体のソフトな肌ざわりを損なうことなく、皺が均一
で擦れ形状の斑のない立毛状態と反挽感を有するもので
ある。その風合、外観は全く新規なものであり、洗いざ
らしのラフな魅力をもつものである。Because the cationic softener and amino-modified silicone are attached to the m n i material, fibrillation does not occur during the subsequent rolling process, and as a result, the resulting product loses the soft feel of the silk woven or knitted fabric itself. It has uniform wrinkles, no spots in the shape of rubbing, and has a pilsed state and a feeling of repulsion. Its texture and appearance are completely new, and it has a washed-out, rough appeal.
Claims (1)
って、前記仕上剤がカチオン系柔軟剤とアミノ変性シリ
コンであり、カチオン系柔軟剤の付着量が絹織編物重量
の０．２〜１．５％を占め且つアミノ変性シリコンの付
着量が絹織編物重量の０．１〜１．０％を占めているス
トーンウォッシュ調絹織編物。(1) A silk woven or knitted fabric to which a finishing agent has been applied before rolling, wherein the finishing agent is a cationic softener and an amino-modified silicone, and the amount of the cationic softener attached is 0.0% of the weight of the silk woven or knitted fabric. A stone-washed silk woven or knitted fabric in which the amount of amino-modified silicone is 2 to 1.5% and the amount of amino-modified silicone attached is 0.1 to 1.0% of the weight of the silk woven or knitted fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63214280A JPH0730507B2 (en) | 1988-08-29 | 1988-08-29 | Stone-wash silk weaving |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63214280A JPH0730507B2 (en) | 1988-08-29 | 1988-08-29 | Stone-wash silk weaving |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0284588A true JPH0284588A (en) | 1990-03-26 |
| JPH0730507B2 JPH0730507B2 (en) | 1995-04-05 |
Family
ID=16653118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63214280A Expired - Lifetime JPH0730507B2 (en) | 1988-08-29 | 1988-08-29 | Stone-wash silk weaving |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0730507B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009097125A (en) * | 2007-10-18 | 2009-05-07 | Teijin Techno Products Ltd | Fiber structure having excellent cut resistance and method for producing the same |
| CN105040270A (en) * | 2015-08-19 | 2015-11-11 | 苏州奇妙蚕丝科技有限公司 | Method for processing pure silk through biotechnology process and product and application thereof |
| CN105780258A (en) * | 2016-04-26 | 2016-07-20 | 谱拉歌世服饰有限公司 | Thermal jacquard knitted fabric obtained through yarn blending of lightweight long-staple cotton and hollow specially-shaped polyester |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5277229A (en) * | 1975-12-19 | 1977-06-29 | Toray Ind Inc | Acrylic staple fiber having cashmere-like touch |
| JPS5418992A (en) * | 1977-07-13 | 1979-02-13 | Japan Exlan Co Ltd | Milling treatment of acrylic fiber article containing animal fiber |
| JPS5926945A (en) * | 1982-07-29 | 1984-02-13 | ピ−ピ−ジ−・インダストリ−ズ・インコ−ポレ−テツド | Aqueous sizing composition for chopped glass fiber |
| JPS61201080A (en) * | 1984-06-02 | 1986-09-05 | ダウ・コ−ニング・リミテツド | Composition and method for treating knitted fabric |
-
1988
- 1988-08-29 JP JP63214280A patent/JPH0730507B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5277229A (en) * | 1975-12-19 | 1977-06-29 | Toray Ind Inc | Acrylic staple fiber having cashmere-like touch |
| JPS5418992A (en) * | 1977-07-13 | 1979-02-13 | Japan Exlan Co Ltd | Milling treatment of acrylic fiber article containing animal fiber |
| JPS5926945A (en) * | 1982-07-29 | 1984-02-13 | ピ−ピ−ジ−・インダストリ−ズ・インコ−ポレ−テツド | Aqueous sizing composition for chopped glass fiber |
| JPS61201080A (en) * | 1984-06-02 | 1986-09-05 | ダウ・コ−ニング・リミテツド | Composition and method for treating knitted fabric |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009097125A (en) * | 2007-10-18 | 2009-05-07 | Teijin Techno Products Ltd | Fiber structure having excellent cut resistance and method for producing the same |
| CN105040270A (en) * | 2015-08-19 | 2015-11-11 | 苏州奇妙蚕丝科技有限公司 | Method for processing pure silk through biotechnology process and product and application thereof |
| CN105780258A (en) * | 2016-04-26 | 2016-07-20 | 谱拉歌世服饰有限公司 | Thermal jacquard knitted fabric obtained through yarn blending of lightweight long-staple cotton and hollow specially-shaped polyester |
| CN105780258B (en) * | 2016-04-26 | 2018-04-20 | 谱拉歌世服饰有限公司 | Light weight type long-staple cotton, hollow profiled dacron blended yarn jacquard weave thermal protection knitted fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0730507B2 (en) | 1995-04-05 |
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