JPH027286B2 - - Google Patents
Info
- Publication number
- JPH027286B2 JPH027286B2 JP56114630A JP11463081A JPH027286B2 JP H027286 B2 JPH027286 B2 JP H027286B2 JP 56114630 A JP56114630 A JP 56114630A JP 11463081 A JP11463081 A JP 11463081A JP H027286 B2 JPH027286 B2 JP H027286B2
- Authority
- JP
- Japan
- Prior art keywords
- polyethylene
- container
- oil
- liquid paraffin
- average molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 polyethylene Polymers 0.000 claims description 19
- 239000004698 Polyethylene Substances 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 17
- 239000002537 cosmetic Substances 0.000 claims description 8
- 229940057995 liquid paraffin Drugs 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 210000004709 eyebrow Anatomy 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
- 239000001593 sorbitan monooleate Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229940099259 vaseline Drugs 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 208000026438 poor feeding Diseases 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
本発明は、改良された油性化粧料、更に詳しく
は、アイブロウ、アイシヤドウ、アイライナー、
口紅等のスチツク状油性化粧料に関するもので、
容器に上記化粧料を直接流し込み充填し固定され
る際、容器との離型性にすぐれ、所謂“壁ハガレ
現象”にすぐれた効果を有する、仕上がり品の表
面状態が極めてきれいなスチツク状油性化粧料を
提供するものである。
従来の油性化粧料は、固化剤として動・植物ワ
ツクス、鉱物ワツクスを使用し製造しているが、
化粧容器に利用されている金属容器例えばアルマ
イト加工アルミ材、ステンレス容器、或いは、ポ
リエチレン、ポリプロピレン、アクリロニトリル
スチレン共重合物、アクリロニトリルブタジエ
ン、スチレン共重合物、ポリメチルメタアクリレ
ートポリ塩化ビニル、ポリカーボネート、ポリエ
チレンテレフタレート、ポリアセタール等の合成
樹脂容器に、流し込み充填固化させた中味は、容
器との濡れ、収縮率との関連から、固化後、容器
と一部密着し、消費者が、容器から繰出し使用す
る際ひどいものでは折損、繰出し不良、中味側面
の削除、表面光沢の低下等の問題が起り易く、製
造者の悩みの種となつている。これらを回避する
為、製造者は、容器よりやや細めの径に成型し容
器に装着するとか、製品により容器や種々の形状
をしたカプセル容器に直接充填し固化させる場合
は、予じめ容器内面に離型剤を塗布し対処してい
るのが実状である。本発明者らは、上記欠点を回
避する目的で鋭意研究の結果ポリエチレンの平均
分子量（MW）が約300〜約700、好ましくは500
〜700を、３〜95重量％、好ましくは３〜10重量
％配合することにより表面光沢にすぐれしかも容
器から成形後繰出す際、繰出し不良、折損、中味
側面の削除の全くないスチツク状油性化粧料を完
成した。ポリエチレンの平均分子量が700以上に
なると、溶解性が不良となり、ワツクスとして使
用できない。又、300以下では固化力も劣り、使
用が困難である。従つて、従来のワツクス類に比
較して固化力が大で、溶解性も良好なポリエチレ
ンの平均分子量は300〜700が極めて使用し易いこ
とである。次に、油性化粧料の組成分として配合
される同時に、前記欠点を解消する為に、ポリエ
チレンの重要な特性として、透明性が要求され
る。この透明性については、流動パラフイン、ス
クワラン等の非極性を使用した場合、従来の炭化
水素ワツクス、固型パラフイン、セレシン等で固
化力が小さいが、本発明のポリエチレン（平均分
子量300〜700）を使用すれば、少量で固化し、し
かも透明性も良好で、約15％まで透明性にすぐれ
る。又、その他の固化剤であるカルナバワツク
ス、キヤンデリワツクス等を使用しても透明性で
は、ポリエチレンより劣る。なお、ポリエチレン
の平均分子量300〜700の軟化点は85℃〜105℃で
ある。次に各実施例をあげて説明する。先ず、実
施例１と比較例をあげて説明する。
実施例 １
フアウンデイシヨン
ポリエチレンワツクス（Mw≒500） ６％
流動パラフイン 48
カオリン 20
酸化チタン（ルチル型） 20
酸化鉄 ５
ソルビタンモノオレート １
比較例
フアウンデイシヨン
流動パラフイン 48％
セシレン ３
固形パラフイン ２
カルナバワツクス １
カオリン 20
酸化チタン 20
酸化鉄 ５
ソルビタンモノオレート １
結果は次の通りである。
The present invention provides improved oil-based cosmetics, more specifically, eyebrows, eyeshadows, eyeliners,
Concerning stick-like oil-based cosmetics such as lipstick,
A stick-like oil-based cosmetic that has excellent releasability from the container and has an excellent effect on the so-called "wall peeling phenomenon" when the above-mentioned cosmetic is poured directly into a container and is filled and fixed, and the surface condition of the finished product is extremely clean. It provides: Conventional oil-based cosmetics are manufactured using animal/vegetable waxes and mineral waxes as solidifying agents.
Metal containers used for cosmetic containers, such as anodized aluminum materials, stainless steel containers, or polyethylene, polypropylene, acrylonitrile styrene copolymer, acrylonitrile butadiene, styrene copolymer, polymethyl methacrylate polyvinyl chloride, polycarbonate, polyethylene terephthalate The contents poured into synthetic resin containers such as polyacetal and solidified will partially adhere to the container after solidification due to wetness with the container and shrinkage rate. These problems tend to occur, such as breakage, poor feeding, removal of the sides of the contents, and loss of surface gloss, which is a source of concern for manufacturers. In order to avoid these problems, manufacturers may mold the product into a slightly narrower diameter than the container and attach it to the container, or if the product is directly filled into containers or capsule containers of various shapes and solidified, the manufacturer may pre-fill the inner surface of the container. The actual situation is to apply a mold release agent to deal with the problem. In order to avoid the above drawbacks, the present inventors have conducted extensive research and found that the average molecular weight (MW) of polyethylene is about 300 to about 700, preferably 500.
By blending 3 to 95% by weight, preferably 3 to 10% by weight of ~700, a stick-like oil-based makeup with excellent surface gloss and no defects in feeding, breakage, or removal of the side of the contents when feeding out from the container after molding. Completed the fee. When the average molecular weight of polyethylene exceeds 700, its solubility becomes poor and it cannot be used as a wax. Moreover, if it is less than 300, the solidifying power is poor and it is difficult to use it. Therefore, it is extremely easy to use polyethylene having an average molecular weight of 300 to 700, as it has greater solidifying power and better solubility than conventional waxes. Next, transparency is required as an important property of polyethylene in order to eliminate the above-mentioned drawbacks when it is incorporated as a component of oil-based cosmetics. Regarding this transparency, when non-polar materials such as liquid paraffin and squalane are used, conventional hydrocarbon waxes, solid paraffin, ceresin, etc. have low solidifying power, but the polyethylene of the present invention (average molecular weight 300-700) When used, it solidifies in a small amount and has good transparency, with transparency up to about 15%. Further, even if other solidifying agents such as carnauba wax and Candeli wax are used, the transparency is inferior to that of polyethylene. Note that the softening point of polyethylene having an average molecular weight of 300 to 700 is 85°C to 105°C. Next, each example will be given and explained. First, Example 1 and a comparative example will be explained. Example 1 Foundation polyethylene wax (Mw≒500) 6% Liquid paraffin 48 Kaolin 20 Titanium oxide (rutile type) 20 Iron oxide 5 Sorbitan monooleate 1 Comparative example Foundation liquid paraffin 48% Secilene 3 Solid paraffin 2 Carnauba wax 1 Kaolin 20 Titanium oxide 20 Iron oxide 5 Sorbitan monooleate 1 The results are as follows.
【表】【table】
【表】
実施例 ２
アイブロウ
ポリエチレン（軟化点85℃） 65％
ポリエチレン（軟化点102℃） 30
カーボンブラツク ５
香料 適量
ポリエチレン95％を加熱溶解し、カーボンブラ
ツク５％及び香料を撹拌混合したパイプに充填す
る。
実施例 ３
アイシヤドウ
ポリエチレン（Mw＝700） 10％
流動パラフイン 39
ワセリン ５
ソルビタンセスキオレート １
マイカ 33
群青 10
酸化鉄（赤） ２
香料 適量
ポリエチレン10％、流動パラフイン39％、ワセ
リン５％、活性剤１％を加熱溶解し、無機粉末45
％を加え撹拌混合する。脱気後容器に充填する。
実施例 ４
口紅
ポリエチレン（MW）＝700 ３
キヤンデリラワツクス １
グリセリンイソステアート 40
流動パラフイン 46
酸化チタン ４
酸化チタン−マイカ ３
有機粉末 ３
香料 適量
ポリエチレン３％、キヤンデリラワツクス１
％、エステル油40％、流動パラフイン46％を加熱
溶解し、無機粉末７％、有機粉末３％を加え撹拌
混合し、容器に充填する。[Table] Example 2 Eyebrow polyethylene (softening point: 85°C) 65% Polyethylene (softening point: 102°C) 30 Carbon black 5 Fragrance Appropriate amount 95% polyethylene was heated and melted, and 5% carbon black and fragrance were mixed by stirring and filled into a pipe. do. Example 3 Eye shadow polyethylene (Mw=700) 10% Liquid paraffin 39 Vaseline 5 Sorbitan sesquiolate 1 Mica 33 Ultramarine 10 Iron oxide (red) 2 Fragrance Appropriate amount Polyethylene 10%, Liquid paraffin 39%, Vaseline 5%, Activator Heat and melt 1%, inorganic powder 45
% and stir to mix. After degassing, fill the container. Example 4 Lipstick polyethylene (MW) = 700 3 Candelilla wax 1 Glycerin isostearate 40 Liquid paraffin 46 Titanium oxide 4 Titanium oxide-mica 3 Organic powder 3 Fragrance Appropriate amount Polyethylene 3%, Candelilla wax 1
%, ester oil 40%, and liquid paraffin 46% are heated and dissolved, 7% inorganic powder and 3% organic powder are added, stirred and mixed, and the mixture is filled into a container.
Claims (1)
することを特徴とするスチツク状油性化粧料。1. A stick-like oily cosmetic characterized by containing polyethylene (average molecular weight 300-700).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11463081A JPS5815904A (en) | 1981-07-22 | 1981-07-22 | Oil-based cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11463081A JPS5815904A (en) | 1981-07-22 | 1981-07-22 | Oil-based cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5815904A JPS5815904A (en) | 1983-01-29 |
| JPH027286B2 true JPH027286B2 (en) | 1990-02-16 |
Family
ID=14642643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11463081A Granted JPS5815904A (en) | 1981-07-22 | 1981-07-22 | Oil-based cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5815904A (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59148713A (en) * | 1983-02-10 | 1984-08-25 | Shiseido Co Ltd | Pencil-type cosmetic |
| JPS59212423A (en) * | 1983-05-18 | 1984-12-01 | Shiseido Co Ltd | Cosmetic pencil |
| JPS6192165U (en) * | 1984-11-20 | 1986-06-14 | ||
| US5200173A (en) * | 1989-08-30 | 1993-04-06 | Revlon Consumer Products Corporation | Molded cosmetic products containing uniform ultra glossy wet look surface finish |
| FR2715294B1 (en) | 1994-01-26 | 1996-03-22 | Oreal | Anhydrous cosmetic or dermatological composition containing the combination of a silicone oil and a wax of an ethylene homo- or copolymer. |
| JP4799012B2 (en) * | 2005-03-10 | 2011-10-19 | 株式会社 資生堂 | Oily solid cosmetics |
| JP4800115B2 (en) * | 2005-06-14 | 2011-10-26 | 株式会社 資生堂 | Anti-shine agent and cosmetics containing the same |
| US20070259012A1 (en) * | 2006-05-03 | 2007-11-08 | John Castro | Clear Cosmetic Compositions and Methods Of Use |
| JP2011098935A (en) | 2009-11-09 | 2011-05-19 | Shiseido Co Ltd | Stick-type cosmetic and method for producing the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5146588A (en) * | 1974-10-19 | 1976-04-21 | Shiseido Co Ltd | |
| JPS536436A (en) * | 1976-07-02 | 1978-01-20 | Oreal | New cosmetic composition for lipsticks and new compound for said composition and its production method |
-
1981
- 1981-07-22 JP JP11463081A patent/JPS5815904A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5146588A (en) * | 1974-10-19 | 1976-04-21 | Shiseido Co Ltd | |
| JPS536436A (en) * | 1976-07-02 | 1978-01-20 | Oreal | New cosmetic composition for lipsticks and new compound for said composition and its production method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5815904A (en) | 1983-01-29 |
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