JPH0267202A - Mothproofing molded product - Google Patents
Mothproofing molded productInfo
- Publication number
- JPH0267202A JPH0267202A JP21917988A JP21917988A JPH0267202A JP H0267202 A JPH0267202 A JP H0267202A JP 21917988 A JP21917988 A JP 21917988A JP 21917988 A JP21917988 A JP 21917988A JP H0267202 A JPH0267202 A JP H0267202A
- Authority
- JP
- Japan
- Prior art keywords
- repellent
- mothproofing
- resin
- molded product
- cockroaches
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000000562 conjugate Substances 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000010406 interfacial reaction Methods 0.000 description 1
- 229930002839 ionone Natural products 0.000 description 1
- 150000002499 ionone derivatives Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- SDTZLYYMKYPKGF-UMKPCWOVSA-N lintenone Chemical compound C([C@@H]1[C@H]2C(=O)CC([C@@]3(C)CC[C@]1(C)[C@@]23C)C)C\C(C)=C\CCC1=CC(=O)OC1 SDTZLYYMKYPKGF-UMKPCWOVSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- FBMAHDGTCDISLJ-UHFFFAOYSA-N neoavarol Natural products CC1CCC(C(CCC2)=C)(C)C2C1(C)CC1=CC(O)=CC=C1O FBMAHDGTCDISLJ-UHFFFAOYSA-N 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 230000000422 nocturnal effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000003016 pheromone Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- TZDMGBLPGZXHJI-UHFFFAOYSA-N pinocarvone Chemical compound C1C2C(C)(C)C1CC(=O)C2=C TZDMGBLPGZXHJI-UHFFFAOYSA-N 0.000 description 1
- 229930007051 pinocarvone Natural products 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 235000017509 safranal Nutrition 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
［利用分野］
本発明はゴキブリ、蟻、ナメクジなどの衛生害虫及びコ
クヌストモドキ、ノシメ」クガ、アズキゾウムシなどの
穀物声虫などに顕著な忌避効果を示す成型物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Application] The present invention relates to a molded article that exhibits a remarkable repellent effect on sanitary pests such as cockroaches, ants, and slugs, and on grain voiceworms such as the stag beetle, the snail weevil, and the adzuki bean weevil.
更に詳しくは、忌避剤を芯物質どして内包する無ｉ質多
孔性マイクＵカプセルを含有してなる成型物に関する。More specifically, the present invention relates to a molded product containing an iridium-free porous microphone U capsule containing a repellent as a core material.
［従来技術１
ゴキブリ類は現在、熱帯地方を中心に世界に約４千種は
ど分布で、その大部分は野外に棲息しているものである
。それらの中で、わが国の家作性のゴキブリにはチャバ
ネゴキブリ、クロゴギブリ、ヤマトゴギブリ、ワモンゴ
キブリ等の数秒が知られている。これらのゴキブリは食
品害虫としてばかりではなく、病害の伝播者としてイエ
バエと並んで衛生上駆除すべき害虫である。集合フェロ
モン等により、群居する性質を持つこれらのゴギブリは
、水分、食物の摂取に好都合な場所の間隙に集合し、隠
れ、夜間台所の食物の残りとか、厨芥に徘徊する雑食性
の昆虫である。[Prior Art 1] Currently, there are approximately 4,000 species of cockroaches distributed throughout the world, mainly in tropical regions, and most of them live outdoors. Among them, domestic cockroaches in Japan include German cockroaches, Japanese cockroaches, Japanese cockroaches, American cockroaches, and several other cockroaches. These cockroaches are not only food pests, but also pests that spread diseases and should be exterminated for sanitary reasons, along with house flies. These cockroaches, which have the tendency to live in groups due to their aggregation pheromones, are omnivorous insects that gather and hide in crevices where they can obtain water and food, and wander around in food scraps in the kitchen or kitchen garbage at night. .
近年、ゴキブリ類の分布地域および棲息数が著しく増加
する傾向にある。これらの現象は家庭およびビルの暖房
設備の普及と豊富な食物等により冬期の生棲活動、増殖
活動を助長させた為に生じたものである。In recent years, the distribution area and number of cockroaches have been increasing significantly. These phenomena have occurred because the spread of heating equipment in homes and buildings and the abundance of food have encouraged winter living and breeding activities.
これらのゴキブリの防除方法としては夜間活動性などの
性質を利用して残効性の高い殺虫剤をゴキブリの潜伏場
所や通路等に噴霧または塗布する方法、あるいはその集
合性を利用して粘着剤を塗布した特殊容器、更に誘引剤
を併用した特殊容器を用いて捕獲する方法、誘引剤と殺
虫剤とを同時に用いる方法等が研究され、実用化されて
いる。Methods for controlling these cockroaches include spraying or applying highly persistent insecticides to cockroaches' hiding places and passageways, taking advantage of their nocturnal activity, or using adhesives to take advantage of their aggregation properties. Methods of capturing insects using a special container coated with insecticide, a special container containing an attractant, and a method of using an attractant and an insecticide at the same time have been researched and put into practical use.
しかし、それらの方法によるゴキブリの防除効果は必ず
しも充分とは言えない。However, the effects of controlling cockroaches by these methods are not necessarily sufficient.
更にａ位に置換基を有しないアリル基を有する化合物お
よびアミノアルコールの一連化合物のゴキブリに対する
忌避１作用について報告されているが（特開昭５０−１
０５８２１号、同５０−５８２２７号公報）、チャバネ
ゴキブリ、クロゴキブリを防除するには、橘めて力価が
弱い。Furthermore, it has been reported that a series of compounds having an allyl group with no substituent at the a-position and amino alcohols have a repellent effect on cockroaches (Japanese Unexamined Patent Publication No. 50-1
No. 05821, No. 50-58227), German cockroaches, and black cockroaches have a weak potency.
更にリナロール、ゲラニオール、プレゴン、シトラール
、テルピネオール、カルボン、メントール、リナリルア
セテート、メントン、ピペリトン、シトロネラール、シ
ト０ネロール、ネロール、シネオールは顕著なゴキブリ
忌避活性作用を示１のに対し、類似の化合物であっても
シクロゲラニオール、サフラナール、カラン、ビナン、
サテン、カレン、ピネン、カンフエン、ボルネオールル
テノール、ペンベノール、ミルテナール、ピノカルボン
、リンテノン、カンファー、カロン、ヨノン等の化合物
には、活性が全くないか権めて弱いことが報告されてい
る（特公昭６１−１５０４１ ）。Furthermore, linalool, geraniol, pulegone, citral, terpineol, carvone, menthol, linalyl acetate, menthone, piperitone, citronellal, citronellol, nerol, and cineol exhibit remarkable cockroach repellent activity1, whereas similar compounds do not. Even cyclogeraniol, safranal, karan, binan,
It has been reported that compounds such as satin, carene, pinene, camphene, borneol rutenol, penbenol, myrtenal, pinocarvone, lintenone, camphor, chalon, and ionone have no or very weak activity (Special Publications No. 61 -15041).
［発明が解決しようとする問題点］
しかしながら、上記した顕著なゴキブリ忌避活性作用を
示１化合物から成る忌避剤を、たとえばゴキブリの楡息
場所、潜伏場所または通路などに直接、噴霧したり、撒
布したり、あるいは塗布したり、あるいは該忌避剤を含
有させた紙片、布片などを設置する等の方法によって、
ゴ４ブリをある一定地域外へ逃避させ、ゴキブリからの
被害を防除しようとする際、忌避活性作用を示す化合物
が揮散などにＪ、り失なわれるため残効性に問題があっ
た。[Problems to be Solved by the Invention] However, it is difficult to spray or scatter a repellent consisting of a single compound that exhibits the above-mentioned remarkable cockroach repellent activity, for example, directly onto cockroach stagnation sites, hiding places, or passageways. By methods such as applying the repellent, or placing pieces of paper or cloth containing the repellent,
When attempts are made to control the damage caused by cockroaches by causing cockroaches to escape from a certain area, there is a problem with residual effectiveness because the compound that exhibits repellent activity is lost due to volatilization.
これを解決する手段として、マイクロカプセル中に忌避
剤を内包させ適度な速度で忌避有効成分を外部に放出す
る技術、いわゆる制御放出技術がある。しかし、マイク
ロカプセルは微粉末状であるため飛散し易く、取扱い上
不便であり、又、飛散したマイクロカプセルの微粉末は
吸入されて人体に害を及ぼすなどの衛生上の問題もある
。更に、微粉末状のマイクロ、カプセルは撒布した個所
から飛散などにより失なわれ易くＪ忌避効果が十分に発
揮されるとは占いがたかった。As a means to solve this problem, there is a so-called controlled release technology, which involves encapsulating a repellent in microcapsules and releasing the repellent active ingredient to the outside at an appropriate rate. However, since microcapsules are in the form of fine powder, they are easily scattered and are inconvenient to handle, and there are also hygiene problems such as the fine powder of scattered microcapsules being inhaled and causing harm to the human body. Furthermore, fine powder micros and capsules are easily lost by scattering from the area where they are sprayed, making it difficult to predict that they will have a sufficient J repelling effect.
史に、忌避剤を内包するマイクロカプセルを樹脂に練り
込んで得られた、残効性及び忌避活性が損なわれること
なく、安全性を有する樹脂成型物は知られていなかった
。Historically, no resin molded product was known that was obtained by kneading microcapsules encapsulating a repellent into a resin and had a safe residual effect and repellent activity.
本発明者は、上記した問題点を解決すべく研究した結果
、上記の顕著なゴキブリ忌避活性作用を示す化合物から
成る忌避剤を内包せしめた無機質多孔質マイク０ｗ１）
プセルを賦形剤とともに打錠して得た成型物、又は、熱
可塑性樹脂、熱硬化性樹脂と混合し、得られた混合物を
成型して得られた樹脂成型物は、該化合物の忌避活性作
用を損うことなく、上記問題を解決することができるこ
と、更に、該化合物は、ゴキブリのみならず、蟻、ナメ
クジ、蚊などの衛生害虫及びコクヌストモドキ、ノシメ
コクガ、アズキゾウムシなどの穀物害虫などに対しても
顕著な忌避効果を示すことを見出し、この知見に拮き、
本発明をなすに至った。As a result of research to solve the above-mentioned problems, the present inventors have discovered an inorganic porous microphone 0w1) containing a repellent made of a compound that exhibits the above-mentioned remarkable cockroach-repelling activity.
A molded product obtained by compressing Pucelle into a tablet with an excipient, or a resin molded product obtained by mixing the mixture with a thermoplastic resin or thermosetting resin and molding the resulting mixture, has the repellent activity of the compound. The above-mentioned problem can be solved without impairing the effect, and furthermore, the compound is effective against not only cockroaches but also sanitary pests such as ants, slugs, and mosquitoes, and grain pests such as the black-and-white beetle, the white-spotted moth, and the bean weevil. We found that it also has a remarkable repellent effect on
The present invention has been accomplished.
［問題点を解決するための手段］
本発明において用いられる忌避有効成分は、リナロール
、ゲラニオール、ブレボン、シトラール、テルピネオー
ル、カルボン、メントール、リナリルアセテート、メン
トン、ピペリトン、シトロネラール、シトロネロール、
ネロール、シネオール及びα位に分岐をもつアルキルフ
ェノール類である。[Means for solving the problem] The repellent active ingredients used in the present invention include linalool, geraniol, brevon, citral, terpineol, carvone, menthol, linalyl acetate, menthone, piperitone, citronellal, citronellol,
These are nerol, cineole, and alkylphenols with a branch at the α-position.
前記α位に分岐をもつアルキル基の炭素数は３３−メチ
ル−６−ｔ−ブチルアニソール及び３．６−ジイツプロ
ピルフエノールなどが例示される。Examples of the carbon number of the alkyl group having a branch at the α-position include 33-methyl-6-t-butylanisole and 3,6-diitupropylphenol.
これらの１種又は２種以上をそのままゴキブリ、蟻、ナ
メクジなどの、衛生害虫及びコクヌストモドキ、ノシメ
コクガ、アズキゾウムシなどの穀物“８虫に対する忌避
剤として使用することもできるが、適当な液体担体く例
えば溶剤）に溶解または分散させ、あるいは、適当な固
体担体（例えば、希釈剤、増量剤）と混合するかまたは
これに吸着させ、所要の場合には、更に乳化剤、分散剤
、懸濁剤、展開剤、浸透剤、湿潤剤、安定剤などを添加
し、油剤、乳剤、水和剤、粉剤、錠剤、噴霧剤などの剤
型で使用することもできる。液体担体として例えば、水
、アル」−ル類（例えば、メチルアルコール、エチルア
ルコール、エチレングリコール）、ケトン類（例えば、
アレトン、メチル１デルケトン）、エーテル類（例えば
ジ第４サン、テトラヒドロフラン、メチルセルブ）脂肪
族炭化水系類（例えば、ガソリン、ケロセン、灯油）、
芳香族炭化水素類（例えば、ベンゼン、トルエン、キシ
レン、ソルベントナフサ）やその他有機塩基類（例えば
、ピリジン）、ハロゲン化炭化水素（例えば、クロロホ
ルム、四塩化炭素）ｌ！アミド類（例えば、ジメヂルボ
ルムアミド）、エステル類（例えば、酢酸エチル、酢酸
ブチル、脂肪酸のグリセリンエステル）、ニトリル類（
例えば、アセトニトリル）、硫黄化合物（例えば、ジメ
ヂルスルホキシド）などの溶媒が適当であり、これらの
一種または二種以上の混合物を使用する。One or more of these can be used as is as a repellent against sanitary pests such as cockroaches, ants, and slugs, as well as against grain insects such as the brown beetle, the corn weevil, and the azuki bean weevil. or mixed with or adsorbed onto a suitable solid carrier (e.g. diluent, filler) and, if necessary, emulsifiers, dispersants, suspending agents, etc. It can also be used in the form of oils, emulsions, wettable powders, powders, tablets, sprays, etc. by adding spreading agents, penetrating agents, wetting agents, stabilizers, etc.For example, water, alcohol, etc. can be used as liquid carriers. - alcohols (e.g. methyl alcohol, ethyl alcohol, ethylene glycol), ketones (e.g.
aletone, methyl 1-derketone), ethers (e.g. diquaternary, tetrahydrofuran, methyl selb), aliphatic hydrocarbons (e.g. gasoline, kerosene, kerosene),
Aromatic hydrocarbons (e.g. benzene, toluene, xylene, solvent naphtha), other organic bases (e.g. pyridine), halogenated hydrocarbons (e.g. chloroform, carbon tetrachloride) l! amides (e.g. dimethylborumamide), esters (e.g. ethyl acetate, butyl acetate, glycerin esters of fatty acids), nitriles (e.g.
For example, solvents such as acetonitrile) and sulfur compounds (for example, dimedyl sulfoxide) are suitable, and one or a mixture of two or more of these are used.
希釈、増量剤としては、植物性粉末（例えば、大豆粉、
タバコ粉、小麦粉、木粉など）、鉱物性粉末（例えば、
カオリン、ベントナイト、酸性白土などのクレー類、滑
石粉、ロウ石粉などのタルク類、珪藻土、雲母粉などの
シリカ類など）、さらにアルミナ、硫黄粉末、活性炭な
ども用いられ、これらの一種または二種以上の混合物を
使用する。As diluting and bulking agents, vegetable powders (e.g. soybean flour,
tobacco powder, wheat flour, wood flour, etc.), mineral powders (e.g.
Clays such as kaolin, bentonite, and acid clay; talcs such as talc powder and waxite powder; silicas such as diatomaceous earth and mica powder; and alumina, sulfur powder, and activated carbon are also used, and one or two of these are used. Use a mixture of the above.
また、乳化剤、展着剤、浸透剤としては、必用に応じて
石けん類、高級アルコールの硫酸エステル、アルキルス
ルホン酸塩、アルキルアリールスルホン酸塩、第４級ア
ンモニウム塩、オキシアルキルアミン脂肪酸エステル、
ポリアルギレンオキサイド系、アンヒトＯソルビトール
系などが広く使用し得る。In addition, as emulsifiers, spreaders, and penetrants, soaps, higher alcohol sulfuric esters, alkyl sulfonates, alkylaryl sulfonates, quaternary ammonium salts, oxyalkylamine fatty acid esters,
Polyargylene oxide type, anthro-O sorbitol type, etc. can be widely used.
また、必要に応じて、カゼイン、ゼラチン、でん粉、ア
ル１！ン酸、寒天、ＣＭＣ、ポリビニルアルコール、松
根油、糠油、ショ糖、グルコース、モラセス、アミノ酸
等を配合する事もできる。Also, if necessary, add casein, gelatin, starch, Al 1! It is also possible to blend phosphoric acid, agar, CMC, polyvinyl alcohol, pine oil, bran oil, sucrose, glucose, molasses, amino acids, etc.
また、本発明で使用する忌避剤に殺虫剤（１機塩素系殺
虫剤、有機リン系殺虫剤、カーバメイト系殺虫剤、入熱
系殺虫剤など）、共力剤、他種の忌避剤、香料、殺菌抗
カビ剤などを配合し、混合使用もできる。In addition, the repellents used in the present invention include insecticides (1-unit chlorine insecticides, organophosphorus insecticides, carbamate insecticides, heat input insecticides, etc.), synergists, other types of repellents, and fragrances. It can also be used in combination with sterilizing and anti-fungal agents.
本発明で使用されるマイクロカプセルは、無機物質を壁
材とする無機質多孔質マイクロカプセルである。この無
機質多孔質マイクロカプセルは、壁材として、炭酸カル
シウム、炭酸バリウム、炭酸マグネシウムなどのアルカ
リ土類金属炭酸塩、ケイ酸カルシウム、ケイ酸バリウム
、ケイ酸マグネシウムなどのアルカリ土類金属ケイ酸塩
、シリカ、酸化コバルト、酸化ニッケルなどの金に１Ｍ
化物、炭酸コバルト、炭酸ニッケル、塩基性炭酸銅など
の金属炭酸塩、及びコバルト、ニッケル、銅などの金属
を用い、特開昭５１−８６０７５、特開昭５３−！２２
５３０などに記載の、いわゆる、「界面反応法」により
製造されるものである。粒系が０，５〜１５０１ＪＩＲ
１比表面積が５０〜２０００Ｔｄ／ｇ、粒子表面の細孔
径が２〜ｅｏｒｖの無機質多孔質マイク【Ｉカプセルが
本発明において好ましく用いられる。なお、本発明の目
的のためには、中空カプセルであっても非中空カプセル
であってもよく、従ってカプセルの壁の厚みには特に制
限はない。このようなマイクロカプセルとしては、鈴木
油脂工業株式会社製のゴツトボール（商品名）などが例
示される。忌避剤のマイクロカプセル化は、液状の忌避
剤の場合には、溶液、懸濁液など液状の忌避剤を、好ま
しくは常温、常圧で、無機質多孔質マイクロカプセルに
含浸させることにより行なわれる。又、固体状の忌避剤
の場合には、該マイクロカプセルの製造時にマイクロカ
プセル化される。マイクロカプセル化される忌避剤の呈
は忌避剤に用いられる各成分の種類、使用場所、臭覚の
個人差などに依存するが、マイクロカプセル１００１１
部に対して、１０〜１００重量部、の範囲から選ばれる
。The microcapsules used in the present invention are inorganic porous microcapsules whose walls are made of an inorganic substance. These inorganic porous microcapsules have wall materials such as alkaline earth metal carbonates such as calcium carbonate, barium carbonate, and magnesium carbonate; alkaline earth metal silicates such as calcium silicate, barium silicate, and magnesium silicate; 1M in gold such as silica, cobalt oxide, nickel oxide, etc.
JP-A-51-86075, JP-A-Sho 53-! 22
It is produced by the so-called "interfacial reaction method" described in 530 and the like. Grain system is 0.5~1501JIR
An inorganic porous microphone [I capsule] having a specific surface area of 50 to 2000 Td/g and a pore diameter of 2 to eorv on the particle surface is preferably used in the present invention. Note that for the purpose of the present invention, the capsule may be a hollow capsule or a non-hollow capsule, and therefore there is no particular restriction on the thickness of the capsule wall. Examples of such microcapsules include Gottoball (trade name) manufactured by Suzuki Yushi Kogyo Co., Ltd. In the case of a liquid repellent, microencapsulation of the repellent is carried out by impregnating inorganic porous microcapsules with a liquid repellent such as a solution or suspension, preferably at room temperature and normal pressure. Furthermore, in the case of a solid repellent, it is microencapsulated during the production of the microcapsules. The appearance of the microcapsulated repellent depends on the type of each component used in the repellent, the place of use, individual differences in sense of smell, etc. Microcapsule 10011
10 to 100 parts by weight.
このようにして得られた忌避剤を内包する無機質多孔質
マイクロカプセルを混合すべき熱可塑性樹脂としては、
エチレン酢酸ビニル共用合体、ポリ塩化ビニル、ボリエ
ブレン、などが例示され、熱硬化性樹脂としては、尿素
樹脂、メラミン樹脂、フェノール樹脂、エポキシ樹脂な
どが例示されるが、これらに限定されるものではない。The thermoplastic resin to be mixed with the inorganic porous microcapsules containing the repellent thus obtained is as follows:
Examples include ethylene-vinyl acetate co-conjugate, polyvinyl chloride, polyethylene, etc., and examples of thermosetting resins include urea resin, melamine resin, phenol resin, epoxy resin, etc., but are not limited to these. .
混合割合は、樹脂１００重槽部に対して、１〜５０重昂
部である。The mixing ratio is 1 to 50 parts by weight per 100 parts by weight of the resin.
前記の忌避剤を内包する無ｖ！Ａ質多孔質マイクロカプ
セルと熱可塑性樹脂又は、熱硬化性樹脂を混合し、成型
物を得る方法としては、例えば、カレンダーロール法、
射出成型法、インフレーション法、押出成型法などの従
来樹脂成型物の製造に広く用いられている方法、及び条
件を用いることができる。成型物の形状としては、シー
ト、各種の立体成型物など任意の形態をとることができ
、又、シート等を更に加工して所定の形態とすることも
勿論可能である。No-v containing the above-mentioned repellent! Examples of the method of mixing A-type porous microcapsules with a thermoplastic resin or a thermosetting resin to obtain a molded product include a calendar roll method,
Methods and conditions widely used in the production of conventional resin molded products, such as injection molding, inflation, and extrusion, can be used. The shape of the molded product can be any arbitrary shape, such as a sheet or various three-dimensional molded products, and it is of course possible to further process the sheet or the like into a predetermined shape.
更に、忌避剤を内包する無機質多孔質マイクロカプセル
は、結晶性セルロースなどの賦形剤を加えて、公知の方
法に従って打錠とすることもできる。Furthermore, the inorganic porous microcapsules containing the repellent can be made into tablets by adding an excipient such as crystalline cellulose according to a known method.
上述のようにして得られる本発明の防虫用成型物（打錠
品）、防虫用樹脂成型物は、ゴキブリなどの衛生害虫又
は、アズキゾウムシなどの穀物害虫の棲息場所、通路、
潜伏場所などに設置、貼付するなどの方法により、衛生
害虫及び穀物害虫による被害を防除することができる。The insect repellent molded product (tablet product) and insect repellent resin molded product of the present invention obtained as described above can be used to prevent sanitary pests such as cockroaches or grain pests such as the bean weevil from living in, passages,
Damage caused by sanitary pests and crop pests can be controlled by installing or pasting them in hiding places.
以下実施例により具体的に説明する。This will be explained in detail below using examples.
実施例１〜７
忌避有効成分として、メントール、カルボン、無機質多
孔質マイクロカプセルとしてゴツトボール１６Ｃｋ （
鈴木油脂工業株式会社製、商品名）、及び下記衣１に示
した樹脂等を用いて各シート及び打錠量を得た。Examples 1 to 7 Menthol, carvone as repellent active ingredients, Gottoball 16Ck (as inorganic porous microcapsules)
Each sheet and the amount of tablets were obtained using Suzuki Yushi Kogyo Co., Ltd. (trade name) and the resin shown in Clothing 1 below.
次に、ブ曳７バネゴキブリの飼育箱の隅に上記のシー１
−及び打錠量を設置し、忌避効果を［ｆしたくゴヤブリ
類はその習性として飼育箱の隅に集まり易い）。すぐ方
向転換し全く隅に留まる事のないものを忌避効果がある
とし、またチャバネゴキブリに全く影響を示さないもの
を忌避効果がないと判断し、試験を行ったが、いずれも
顕著な忌避効果を示した。Next, place the above sheet 1 in the corner of the breeding box for the Buhiki 7 spring cockroaches.
- and the amount of tablets to be compressed to obtain a repellent effect (goya species tend to gather in the corners of breeding boxes as a habit). Tests were conducted on those that quickly changed direction and never stayed in a corner, and those that did not show any effect on German cockroaches as having no repellent effect. Indicated.
［発明の効果］
本発明の防虫用樹脂組成物及び防虫用打錠物は、含有さ
れる忌避有効成分の残効性を損なうことなく、ゴキブリ
、蟻、ナメクジ、蚊などの衛生害虫及びコクヌストモド
ギ、ノシメ７１クガ、アズキゾウムシなどの穀物害虫に
対して顕著な忌避効果を示し、又、忌避有効成分を内包
する無機質多孔質マイクロカプセルが飛散することがな
いので、安全性の点でも優れ、衛生害虫による被害を効
果的に防除することができる。[Effects of the Invention] The insect repellent resin composition and insect repellent tablets of the present invention are effective against sanitary pests such as cockroaches, ants, slugs, and mosquitoes, as well as sanitary insect pests such as cockroaches, ants, slugs, and mosquitoes, without impairing the residual effectiveness of the repellent active ingredients contained therein. It has a remarkable repellent effect on grain pests such as Noshime 71 kuga and adzuki beetle, and since the inorganic porous microcapsules that contain the repellent active ingredient do not scatter, it is also excellent in terms of safety and is highly effective against sanitary pests. It is possible to effectively prevent damage caused by
家敷蜜醪４絆に濠ｋ。Ieshiki Mitsumomi 4 bonds and moat k.
イー岨「人−伊１１ｊ１ 憶 くYi ``Human-Ita 11j1 memory Ku
Claims (4)
クロカプセルを含有してなる防虫用樹脂成型物。(1) An insect repellent resin molded product containing inorganic porous microcapsules containing a repellent as a core material.
ゴン、シトラール、テルピネオール、カルボン、メント
ール、リナリルアセテート、メントン、ピペリトン、シ
トロネラール、シトロネロール、ネロール、シネオール
、及びα位に分岐をもつアルキルフェノール類の１種又
は２種以上を忌避有効成分として含有することを特徴と
する請求項１の防虫用樹脂成型物。(2) The repellent is one of linalool, geraniol, pulegone, citral, terpineol, carvone, menthol, linalyl acetate, menthone, piperitone, citronellal, citronellol, nerol, cineol, and alkylphenols having a branch at the α-position, or The insect repellent resin molded article according to claim 1, characterized in that it contains two or more types as effective repellent ingredients.
クロカプセルを打錠してなる防虫用成型物。(3) An insect repellent molded product made by compressing inorganic porous microcapsules containing a repellent as a core material.
ゴン、シトラール、テルピネオール、カルボン、メント
ール、リナリルアセテート、メントン、ピペリトン、シ
トロネラール、シトロネロール、ネロール、シネオール
、及びα位に分岐をもつアルキルフェノール類の１種又
は２種以上を忌避有効成分として含有することを特徴と
する請求項３の防虫用成型物。(4) The repellent is one of linalool, geraniol, pulegone, citral, terpineol, carvone, menthol, linalyl acetate, menthone, piperitone, citronellal, citronellol, nerol, cineol, and alkylphenols having a branch at the α-position, or The insect repellent molded article according to claim 3, characterized in that it contains two or more kinds as effective repellent ingredients.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21917988A JPH0267202A (en) | 1988-09-01 | 1988-09-01 | Mothproofing molded product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21917988A JPH0267202A (en) | 1988-09-01 | 1988-09-01 | Mothproofing molded product |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0267202A true JPH0267202A (en) | 1990-03-07 |
Family
ID=16731437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21917988A Pending JPH0267202A (en) | 1988-09-01 | 1988-09-01 | Mothproofing molded product |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0267202A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991015118A1 (en) * | 1990-04-09 | 1991-10-17 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| JPH0420631A (en) * | 1990-05-15 | 1992-01-24 | Toyo Tire & Rubber Co Ltd | Moth-proof heat-insulating board and its manufacture |
| US5227406A (en) * | 1990-04-09 | 1993-07-13 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| JPH07112902A (en) * | 1993-10-15 | 1995-05-02 | Daiwa Kagaku Kogyo Kk | Cockroach repellent composition |
| US5621013A (en) * | 1992-06-24 | 1997-04-15 | Primavera Laboratories, Inc. | Insect replellent blends, lotions, and sprays |
| US5753686A (en) * | 1992-09-18 | 1998-05-19 | International Flavors & Fragrances Inc. | Method for repelling fire ants and horn flies and compositions for repelling fire ants and horn flies and acting as anti-feedants for fire ants and horn flies |
| KR19990054320A (en) * | 1997-12-26 | 1999-07-15 | 성재갑 | Composition for protecting human body from insects |
| US6255356B1 (en) * | 2000-03-30 | 2001-07-03 | International Flavors & Fragrances Inc. | Method for inhibiting from feeding, cockroaches |
| JP2002544142A (en) * | 1999-05-10 | 2002-12-24 | バイオセンソリー，インコーポレイテッド | Method, apparatus and composition for controlling the ability of a mosquito to track the smell of a mosquito in an environmentally limited three-dimensional space |
| JP2003026507A (en) * | 2001-07-16 | 2003-01-29 | Osaka Kasei Kk | Exterminator agent against harmful gastropods and method for exterminating the harmful gastropods |
| WO2003013243A1 (en) * | 2001-08-11 | 2003-02-20 | Quest International B.V. | Insect repellents |
| JP2004175745A (en) * | 2002-11-28 | 2004-06-24 | S T Chem Co Ltd | Insect-proofing agent for grain/dried food product and method for controlling insect pest for grain/dried food product |
| JP2006077055A (en) * | 2004-09-07 | 2006-03-23 | Achilles Corp | Termite-proofing polyurethane foam heat-insulating material |
| JP2014210788A (en) * | 2005-11-30 | 2014-11-13 | エーデン リサーチ ピーエルシー | Terpene-containing composition and method of making and using the same |
| JP2015500815A (en) * | 2011-12-06 | 2015-01-08 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Disinfectant composition |
-
1988
- 1988-09-01 JP JP21917988A patent/JPH0267202A/en active Pending
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991015118A1 (en) * | 1990-04-09 | 1991-10-17 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| EP0524972A1 (en) * | 1990-04-09 | 1993-02-03 | Primavera Lab Inc | Insect repellent lotions and sprays. |
| US5227406A (en) * | 1990-04-09 | 1993-07-13 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| US5346922A (en) * | 1990-04-09 | 1994-09-13 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| EP0524972B1 (en) * | 1990-04-09 | 1995-06-21 | PRIMAVERA LABORATORIES, Inc. | Insect repellent lotions and sprays |
| US5648398A (en) * | 1990-04-09 | 1997-07-15 | Primavera Laboratories, Inc. | Insect repellent lotions and sprays |
| JPH0420631A (en) * | 1990-05-15 | 1992-01-24 | Toyo Tire & Rubber Co Ltd | Moth-proof heat-insulating board and its manufacture |
| US5621013A (en) * | 1992-06-24 | 1997-04-15 | Primavera Laboratories, Inc. | Insect replellent blends, lotions, and sprays |
| US5753686A (en) * | 1992-09-18 | 1998-05-19 | International Flavors & Fragrances Inc. | Method for repelling fire ants and horn flies and compositions for repelling fire ants and horn flies and acting as anti-feedants for fire ants and horn flies |
| JPH07112902A (en) * | 1993-10-15 | 1995-05-02 | Daiwa Kagaku Kogyo Kk | Cockroach repellent composition |
| KR19990054320A (en) * | 1997-12-26 | 1999-07-15 | 성재갑 | Composition for protecting human body from insects |
| JP2002544142A (en) * | 1999-05-10 | 2002-12-24 | バイオセンソリー，インコーポレイテッド | Method, apparatus and composition for controlling the ability of a mosquito to track the smell of a mosquito in an environmentally limited three-dimensional space |
| JP4838426B2 (en) * | 1999-05-10 | 2011-12-14 | バイオセンソリー，インコーポレイテッド | Method, apparatus and composition for suppressing the ability of mosquitoes to follow odors in an environmentally limited three-dimensional space |
| US6255356B1 (en) * | 2000-03-30 | 2001-07-03 | International Flavors & Fragrances Inc. | Method for inhibiting from feeding, cockroaches |
| JP2003026507A (en) * | 2001-07-16 | 2003-01-29 | Osaka Kasei Kk | Exterminator agent against harmful gastropods and method for exterminating the harmful gastropods |
| WO2003013243A1 (en) * | 2001-08-11 | 2003-02-20 | Quest International B.V. | Insect repellents |
| US7455852B2 (en) | 2001-08-11 | 2008-11-25 | Quest International B.V. | Insect repellents |
| JP2004175745A (en) * | 2002-11-28 | 2004-06-24 | S T Chem Co Ltd | Insect-proofing agent for grain/dried food product and method for controlling insect pest for grain/dried food product |
| JP2006077055A (en) * | 2004-09-07 | 2006-03-23 | Achilles Corp | Termite-proofing polyurethane foam heat-insulating material |
| JP2014210788A (en) * | 2005-11-30 | 2014-11-13 | エーデン リサーチ ピーエルシー | Terpene-containing composition and method of making and using the same |
| JP2015500815A (en) * | 2011-12-06 | 2015-01-08 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Disinfectant composition |
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