JPH026697A - Adhesive sheet - Google Patents
Adhesive sheetInfo
- Publication number
- JPH026697A JPH026697A JP14412188A JP14412188A JPH026697A JP H026697 A JPH026697 A JP H026697A JP 14412188 A JP14412188 A JP 14412188A JP 14412188 A JP14412188 A JP 14412188A JP H026697 A JPH026697 A JP H026697A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- sheet
- layer
- sensitive adhesive
- pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 73
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 73
- 239000010410 layer Substances 0.000 claims abstract description 32
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 20
- 239000012790 adhesive layer Substances 0.000 claims abstract description 17
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 4
- 239000000057 synthetic resin Substances 0.000 claims abstract description 4
- 239000002904 solvent Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000006082 mold release agent Substances 0.000 claims description 2
- 230000002538 fungal effect Effects 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 34
- -1 dimethylsiloxane Chemical class 0.000 description 15
- 229920002050 silicone resin Polymers 0.000 description 12
- 238000012856 packing Methods 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 239000003522 acrylic cement Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000012943 hotmelt Substances 0.000 description 5
- 239000002390 adhesive tape Substances 0.000 description 4
- 239000011111 cardboard Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 239000002519 antifouling agent Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011120 plywood Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 229920006264 polyurethane film Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920004449 Halon® Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- PQPVPZTVJLXQAS-UHFFFAOYSA-N hydroxy-methyl-phenylsilicon Chemical class C[Si](O)C1=CC=CC=C1 PQPVPZTVJLXQAS-UHFFFAOYSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000005001 laminate film Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003097 polyterpenes Chemical class 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesive Tapes (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明はシート、テープ等の裏面にライナー層を有し、
これに粘着剤を塗布した粘着シート、特に壁紙、ラベル
、荷造りテープ等に有用な粘着シートに関する。[Detailed description of the invention] Industrial application field The present invention has a liner layer on the back side of a sheet, tape, etc.
This invention relates to an adhesive sheet coated with an adhesive, particularly an adhesive sheet useful for wallpaper, labels, packing tapes, etc.
従来技術
従来、壁紙、ラベル、荷造テープ等には基材シート裏面
に粘着剤を塗布した粘着テープが頻々用いられている。BACKGROUND OF THE INVENTION Conventionally, adhesive tapes in which an adhesive is applied to the back surface of a base sheet have been frequently used for wallpaper, labels, packing tapes, and the like.
従来の粘着シートは、基材シートに直接粘着剤が塗布さ
れているため、経時的に基材シート中に粘着剤が浸透し
、粘着性が低下し、あるいは、基材シート表面にしみを
生ずる場合があった。In conventional adhesive sheets, the adhesive is applied directly to the base sheet, so the adhesive penetrates into the base sheet over time, reducing the adhesiveness or causing stains on the surface of the base sheet. There was a case.
発明が解決しようとする課題
本発明は作業性がよく高い粘着力を有し、貼付後経時的
な汚れ、染み、浮き、粘着性の低下がない粘着シートを
提供することを目的とする。Problems to be Solved by the Invention The object of the present invention is to provide a pressure-sensitive adhesive sheet that has good workability and high adhesive strength, and does not become stained, stained, floated, or deteriorate in adhesive strength over time after application.
課題を解決するための手段
本考案は第１図に示すごとく基材シート（１）、基材シ
ート（１）の裏面に接着されたライナー層（７）および
ライナー層（７）に油性粘着剤層（８）が設けられた粘
着シートに関する。Means for Solving the Problems As shown in Figure 1, the present invention includes a base sheet (1), a liner layer (7) adhered to the back surface of the base sheet (1), and an oil-based adhesive on the liner layer (7). The present invention relates to an adhesive sheet provided with a layer (8).
基材シート（１）は−層構成であっても多層構成であっ
てもよい。−層構成の例は第２図に示すごとく壁紙、粘
着テープ、ラベル等の表面を形成する表面シート（３）
のみからなるものであり、多層構成の例は第３図に示す
ごとく表面シート（３）の裏面に裏打接着剤の層（４）
を設けて、裏打紙（５）を接着させた三層構成のもの、
あるいは第１図に示すごとく、第３図の態様の粘着シー
トの表面シ裏打接着剤（４）は従来から壁紙に使用され
ている裏打接着剤を使用すればよい。その様な接着剤と
しては、澱粉糊、ＰＶＡ、酢ビ系接着剤、ポリアクリル
系接着剤等がある。表面シート（３）がビニナ・
ルクロス等のときは、裏打接着剤を用いることなく、ホ
ットメルト法により裏打紙を表面シート（３）に接着し
てもよい。そのときはホットメルト層が裏打接着剤層（
４）である。The base sheet (1) may have a -layer structure or a multilayer structure. - An example of the layer structure is the top sheet (3) that forms the surface of wallpaper, adhesive tape, labels, etc. as shown in Figure 2.
An example of a multilayer structure is as shown in Figure 3, where a backing adhesive layer (4) is placed on the back side of a top sheet (3).
A three-layer structure with a backing paper (5) glued to it,
Alternatively, as shown in FIG. 1, the surface lining adhesive (4) of the pressure-sensitive adhesive sheet in the embodiment shown in FIG. 3 may be a lining adhesive conventionally used for wallpaper. Such adhesives include starch glue, PVA, vinyl acetate adhesive, polyacrylic adhesive, and the like. When the topsheet (3) is made of Vinina Lucros, etc., the backing paper may be adhered to the topsheet (3) by a hot melt method without using a backing adhesive. In that case, the hot melt layer is the backing adhesive layer (
4).
化粧層（２）は、表面シート（３）の汚れを防ぐために
用いる。化粧層（２）は、適当な防汚剤、例えばパラフ
ィン類、剥離用ポリマー、シリコーン樹脂、フッ素系防
汚剤、帯電防止剤等を所望により適当な樹脂系被膜形成
剤と共に溶剤に希釈して塗布、印刷、スプレー等により
表面シート表面を処理することにより得られる。化粧層
（２）は一般の壁紙等にも設けであるが、本発明では単
に、防汚のみの目的でなく、壁紙等を巻いて保存すると
き、剥離紙を用いなくとも、基材シート（１）と粘着剤
（８）が接着しないようにするために有用な場合がある
。基材シート表面と粘着剤（８）が粘着しな一ト（３）
の表面にさらに化粧層（２）を設けたもの等がある。The decorative layer (2) is used to prevent the top sheet (3) from becoming dirty. The decorative layer (2) is prepared by diluting a suitable antifouling agent, such as paraffins, a release polymer, a silicone resin, a fluorine antifouling agent, an antistatic agent, etc., in a solvent together with an appropriate resin film forming agent if desired. It can be obtained by treating the surface of the topsheet by coating, printing, spraying, etc. The decorative layer (2) is also provided on general wallpaper, etc., but in the present invention, it is not only for the purpose of antifouling, but also when the wallpaper, etc. is rolled up and stored, it can be used as a base sheet (2) without using release paper. It may be useful to prevent 1) from adhering to the adhesive (8). The surface of the base sheet and the adhesive (8) are not sticky (3)
There are also those that further provide a decorative layer (2) on the surface.
表面シート（３）は粘着シート、即ち壁紙、ラベル、荷
造テープ等の本体をなすものであって、その表面に適当
な模様が印刷されたものであってよい。材質は壁紙、ラ
ベル、荷造用テープ等に一般に用いられている紙、不織
布、布、ビニルクロス等ものでよい。The top sheet (3) is an adhesive sheet, which forms the main body of wallpaper, labels, packing tape, etc., and may have a suitable pattern printed on its surface. The material may be paper, nonwoven fabric, cloth, vinyl cloth, etc., which are commonly used for wallpaper, labels, packing tapes, etc.
裏打紙（５）は、壁紙等、将来貼り替えを要するとき表
面シート（３）とライナー（７）との剥離を容易にし、
下地を傷めず表面シート（３）のみが剥離されるように
設けるものである。この裏打紙（５）は、貼り替えを意
図して作られた従来の壁紙には必須のものであったが、
本発明では、同じ貼り替えを目的とするものであっても
粘着剤自体に工夫をすることにより、ライナー自体を壁
紙から剥がすことが可能となるので必ずしも必要でない
。裏打紙（５）はそれ自体薄く剥げる必要があるので紙
を用いるのが好ましい。The backing paper (5) makes it easy to peel off the top sheet (3) and liner (7) when wallpaper or the like needs to be replaced in the future.
It is provided so that only the top sheet (3) can be peeled off without damaging the base. This backing paper (5) was essential for conventional wallpaper that was made with the intention of being reapplied.
In the present invention, even if the purpose is to reapply the liner, it is not necessary because the liner itself can be peeled off from the wallpaper by devising the adhesive itself. It is preferable to use paper as the backing paper (5) because it needs to peel off thinly.
裏打紙（５）を表面シート（３）に接着するためのいよ
うにするために用いる離型用ポリマーとしては、重合性
エチレン結合を有するカルボン酸の長鎖アルキルエステ
ルと極性基、例えばアセチル基、カルボキシル基、ニト
リル基、アミド基、アミノ基等を含む七ツマー類の共重
合体、塩化ビニリデン共重合体等が例示される。また、
シリコーン樹脂類としてはフェニルメチルシロキサン、
ジメチルシロキサン等を含む樹脂類；フッ素系防汚剤と
しては長鎖フルオロアルキル基、テトラフルオロエチレ
ン、ヘキサフルオロエチレン等の重合鎖を有する界面活
性剤またはポリマー類が例示される。The release polymer used to bond the backing paper (5) to the top sheet (3) is a long-chain alkyl ester of carboxylic acid having a polymerizable ethylene bond and a polar group, such as an acetyl group. , a heptamer copolymer containing a carboxyl group, a nitrile group, an amide group, an amino group, etc., and a vinylidene chloride copolymer. Also,
Silicone resins include phenylmethylsiloxane,
Resins containing dimethylsiloxane and the like; examples of fluorine-based antifouling agents include surfactants or polymers having long-chain fluoroalkyl groups, polymer chains such as tetrafluoroethylene and hexafluoroethylene.
上記基材シートの裏面にはライナー（７）を接着させる
。ライナー（７）は種々のポリマーフィルム、例えば、
ポリ塩化ビニル、ポリ塩化ビニリデン、ポリスチレン、
ポリプロピレン、ポリエチレン、ポリエチレンラミネー
トセロファン、ポリエステルフィルム、ポリアミドフィ
ルム、ポリウレタンフィルムあるいはこれらの共重合フ
ィルム、混合フィルム、ラミネートフィルム等積々のも
のが例示される。A liner (7) is adhered to the back surface of the base sheet. The liner (7) can be made of various polymeric films, e.g.
polyvinyl chloride, polyvinylidene chloride, polystyrene,
Examples include polypropylene, polyethylene, polyethylene-laminated cellophane, polyester film, polyamide film, polyurethane film, and copolymer films, mixed films, and laminate films thereof.
好ましくは経済性の点でポリ塩化ビニルフィルム、ポリ
エチレンフィルム、ポリプロピレンフィルム、ポリスチ
レンフィルム等でアリ、特にフィルムと粘着剤との付着
性の点でポリ塩化ビニルフィルム、ポリスチレンフィル
ム等が好ましい。また溶剤型粘着剤に対する耐溶剤性の
点でポリエチレンまたはポリプロピレンフィルムまたは
シートを用いるのが好ましい。Preferred are polyvinyl chloride film, polyethylene film, polypropylene film, polystyrene film, etc. from the economic point of view, and particularly preferred are polyvinyl chloride film, polystyrene film, etc. from the viewpoint of adhesion between the film and the adhesive. Further, it is preferable to use polyethylene or polypropylene film or sheet from the viewpoint of solvent resistance against solvent-based adhesives.
ライナー（７）と基材シート（１）の接着はライナー用
ポリマーフィルムと基材シートとを接着剤または粘着剤
を介して接着してもよく、あるいは、基材シート上にフ
ィルム形成性ポリマーを塗布乾燥して、ライナー層を形
成してもよく、あるいはホットメルト法を用いて基材シ
ート上にポリマーフィルムまたはシートをホットメルト
によって形成してもよい。さらに、ポリウレタンフィル
ム等のごとく、基材シート上でウレタン反応を生じさせ
て（インサイチュ重合法）ライナー（７）を形成させて
もよい。The liner (7) and the base sheet (1) may be adhered to each other by bonding the liner polymer film and the base sheet with an adhesive or a pressure-sensitive adhesive, or by attaching a film-forming polymer onto the base sheet. A liner layer may be formed by coating and drying, or a hot melt method may be used to form a polymer film or sheet on a base sheet by hot melt. Furthermore, the liner (7) may be formed by causing a urethane reaction on a base sheet (in-situ polymerization method), such as a polyurethane film.
ライナー（７）の厚さは６−１５０μ＋＋＋、特に１２
に溶剤が浸透することがない。しかしながら、好ましく
はホットメルトによる接着か接着剤による接着である。The thickness of the liner (7) is 6-150μ+++, especially 12
Solvents do not penetrate. However, hot melt bonding or adhesive bonding is preferred.
粘着剤は表面シートが紙等の吸液性素材の場合には経時
的に粘着剤が表面シート側に移行して接着力が低下する
場合がある。When the topsheet is made of a liquid-absorbing material such as paper, the adhesive may migrate to the topsheet side over time and the adhesive force may decrease.
ライナー（７）の裏面には、油性粘着剤層（８）を設け
る。油性粘着剤層（８）は前述のライナー接着層（６）
で説明した粘着剤を用いてもよい。An oil-based adhesive layer (8) is provided on the back side of the liner (7). The oil-based adhesive layer (8) is the aforementioned liner adhesive layer (6).
The adhesive described above may also be used.
ライナー裏面の粘着剤層は、壁面等から来る水分やあく
による影響を避けるため油性の粘着剤層とする。この様
な油性粘着剤層を形成するに適した粘着剤は溶剤型であ
る。ライナーと壁面間での再剥離を目的とする場合に好
ましい粘着剤はシリコーン系剥離剤や発泡樹脂ビーズ等
を配合したアクリル系粘着剤である。特にシリコーン樹
脂を０゜１〜５重量％配合した溶剤型アクリル系粘着剤
である。The adhesive layer on the back side of the liner is an oil-based adhesive layer to avoid the effects of moisture and dirt coming from the wall surface, etc. A solvent-based adhesive is suitable for forming such an oil-based adhesive layer. When the purpose is to re-peel between the liner and the wall surface, a preferred adhesive is an acrylic adhesive containing a silicone release agent, foamed resin beads, or the like. In particular, it is a solvent-type acrylic adhesive containing 0.1 to 5% by weight of silicone resin.
溶剤型アクリル系粘着剤としては、例えばブタノール、
２−エチルヘキシルアルコール等の比較的炭素ｔの多い
アルコールでエステル化したアク〜２５μｍが好ましい
。Examples of solvent-based acrylic adhesives include butanol,
Preferably, the thickness is esterified with an alcohol having a relatively large number of carbon atoms such as 2-ethylhexyl alcohol and has a thickness of ~25 μm.
接着剤を用いるときは、使用するライナーの種類によっ
て異なるがポリ酢酸ビニル系接着剤、アクリル系接着剤
、ポリウレタン系接着剤、ポリブタジェン系接着剤、ポ
リ塩化ビニル系接着剤等の接着剤等が例示される。粘着
剤としては、アクリル系粘着剤、例えは（メタ）アクリ
ル酸低級アルキルエステルを主体としてこれに酢酸ヒニ
ル、スチレン、アクリロニトリル等と、官能基含有モノ
マ、例えは（メタ）アクリル酸、ヒドロキシエチル（メ
タ）アクリレート、アクリルアミド、グリシジル（メタ
）アクリレート、マレイン酸等を共重合したポリマー：
天然ゴム、イソプレンゴム、スチレンブタジェンゴム、
ブチルゴム等のエラストマーを主体とするもの；ロジン
、エステルカム、ポリテルペン類の粘着付与剤を配合し
たもの等が例示される。これらの接着剤や粘着剤は、ラ
イナーとの接着性をよくするため、溶剤型を用いるのが
好ましい。溶剤型粘着剤は予めライナー側に塗布乾燥し
、これに基材シートを粘着すれば基材シートリル酸を主
成分とし、これに（メタ）アクリル酸エステル、（メタ
）アクリル酸、無水マレイン酸、（メタ）アクリルアミ
ド、（メタ）アクリロニトリル、ヒドロキシエチル（メ
タ）アクリレート、グリシジルメタクリレート、ジメチ
ルアミノエチルメタクリレート等を共重合し、必要によ
り、アミン類、ポリアミン類等で部分的に中和したもの
等が例示される。When using an adhesive, examples include polyvinyl acetate adhesive, acrylic adhesive, polyurethane adhesive, polybutadiene adhesive, polyvinyl chloride adhesive, etc., depending on the type of liner used. be done. The adhesive is an acrylic adhesive, for example, a lower alkyl (meth)acrylic acid ester as a main ingredient, and a monomer containing a functional group, such as (meth)acrylic acid, hydroxyethyl ( Polymers copolymerized with meth)acrylate, acrylamide, glycidyl(meth)acrylate, maleic acid, etc.:
Natural rubber, isoprene rubber, styrene butadiene rubber,
Examples include those mainly composed of elastomers such as butyl rubber; those containing tackifiers such as rosin, estercam, and polyterpenes. These adhesives and pressure-sensitive adhesives are preferably solvent-based in order to improve adhesion to the liner. The solvent-based adhesive is applied to the liner side in advance and dried, and if a base sheet is attached to this, the base sheet contains lyric acid as the main component, (meth)acrylic ester, (meth)acrylic acid, maleic anhydride, Examples include copolymerization of (meth)acrylamide, (meth)acrylonitrile, hydroxyethyl (meth)acrylate, glycidyl methacrylate, dimethylaminoethyl methacrylate, etc. and, if necessary, partially neutralized with amines, polyamines, etc. be done.
上記のごとき溶剤型アクリル系粘着剤はこれをそのまま
基材シートに塗布すると浸透性が高いため、基材シート
表面にまで粘着剤が浸透する。従って、壁紙等を製造す
る上で支障がある。本発明では、基材シートと粘着剤間
に合成樹脂フィルムのライナー（７）が設けであるので
問題がない。The solvent-based acrylic pressure-sensitive adhesive described above has high permeability when directly applied to a base sheet, so that the pressure-sensitive adhesive penetrates into the surface of the base sheet. Therefore, there is a problem in manufacturing wallpaper and the like. In the present invention, there is no problem because a synthetic resin film liner (7) is provided between the base sheet and the adhesive.
溶剤型アクリル系接着剤にシリコーン樹脂を少量配合す
ると下地との粘着性がコントロールできる。特に局部的
な粘着が抑制され、しかも全体としての粘着性は維持さ
れる。従って、剥離に際して下地を傷めることなく、円
滑な剥離か可能となる。その結果、これを荷造用粘着テ
ープ等に用いるとダンボール表面の紙が粘着テープ側に
付着したまま剥離されると言う従来の荷造テープにみら
れる欠点が解消される。従って一度使用したダンボール
を再使用できる。同様のことがラベルについても言える
。また一般家屋の内壁には通常貼り替え用の下紙が貼ら
れており、この上に壁紙が貼られているが、壁紙を剥が
すと従来の壁紙では下紙も一緒に破れてしまう。従って
貼り替え用の新しい壁紙は、直接壁素材に貼らなけれは
ならなくなる。壁素材、例えばアスベスト、コンクリー
ト、石膏等の素材に直接壁紙を貼りつけると、壁のアク
による染み、剥離、結露によるカビの発生等のため壁紙
が汚れ易い。下紙が破れなかったとしても、あるいは、
ベニヤ板等前記のごとき欠点のあまりない壁面に貼った
場合でも、従来の壁紙では裏打紙が局部的に壁面に残り
、それを剥ぎとるのが困難である。剥ぎ取らずに、その
上に壁紙を貼ると表面に凹凸を生し、美観を損なう。こ
の様な現象は、単に粘着剤の粘着力の強さに起因するの
ではなく、局部的に粘着力の強い部分と弱い部分Ｉ
的な粘着力の差を生じ易い。By adding a small amount of silicone resin to a solvent-based acrylic adhesive, the adhesion to the base can be controlled. In particular, local adhesion is suppressed, and the overall adhesion is maintained. Therefore, smooth peeling is possible without damaging the base during peeling. As a result, when this tape is used for packing adhesive tapes, etc., the drawback of conventional packing tapes, such as paper on the surface of the cardboard being peeled off while remaining attached to the adhesive tape side, is overcome. Therefore, once used cardboard can be reused. The same goes for labels. In addition, a replacement paper is usually pasted on the interior walls of ordinary houses, and wallpaper is pasted on top of this, but when the wallpaper is removed, with conventional wallpaper, the paper will tear along with it. Therefore, new wallpaper for replacement must be applied directly to the wall material. When wallpaper is attached directly to a wall material, such as asbestos, concrete, or plaster, the wallpaper tends to become dirty due to stains, peeling, and mold growth due to condensation. Even if the bottom paper is not torn, or
Even when pasted on a wall surface that does not have many of the above-mentioned defects, such as a plywood board, with conventional wallpaper, the backing paper remains locally on the wall surface and is difficult to remove. If you paste wallpaper on top of it without removing it, the surface will become uneven and the aesthetic appearance will be spoiled. Such a phenomenon is not simply caused by the strength of the adhesive force of the adhesive, but tends to cause a local difference in adhesive strength between areas with strong adhesive force and areas with weak adhesive force.
シリコーン樹脂を配合した粘着剤はこれを直接基材シー
トに塗布すると基材シートに浸透するが本発明ではライ
ナー層があるためその心配がない。If an adhesive containing a silicone resin is applied directly to a base sheet, it will penetrate into the base sheet, but in the present invention, there is no need to worry about this because there is a liner layer.
粘着剤層としてシリコーン樹脂を配合した粘着剤を用い
、基材シート表面に化粧層（２）を設けると、そのまま
巻き取って保管しても粘着層と基材シート表面が粘着す
ることがなく、剥離紙が不要となる。その結果、巻き取
りが容易となり、作業現場で剥離紙の仕末に困ることが
ない。更に、シリコーン樹脂を配合するとライナー層と
壁素材との剥離が下地を損傷することなしに行なえるた
め裏打紙は必ずしも必要でなくなる。If an adhesive containing silicone resin is used as the adhesive layer and a decorative layer (2) is provided on the surface of the base sheet, the adhesive layer and the surface of the base sheet will not stick together even if it is rolled up and stored as is. No release paper is required. As a result, it becomes easy to wind up, and there is no need to worry about how to finish the release paper at the work site. Furthermore, when a silicone resin is blended, the liner layer and wall material can be peeled off without damaging the underlying material, so a paper lining is not necessarily required.
以下、実施例をあげて本発明を説明する。The present invention will be explained below with reference to Examples.
実施例１および比較例１および２
市販壁紙（塩化ビニルシートの裏面に裏打紙を接着した
無粘着剤シート）の裏面に溶剤型ポリアクリル酸エステ
ル系粘着剤（綜研化学株式会社製）を６０ｇ／ｒｎ２塗
布乾燥した。これにポリエチレンシート（厚さ１２μｍ
）をライナーとして貼りつけを生ずるためである。この
様な現象が溶剤型粘着剤にシリコーン樹脂を配合するこ
とにより、実質的な粘着力の低下をきたすことなく抑制
される。Example 1 and Comparative Examples 1 and 2 60 g of a solvent-based polyacrylic acid ester adhesive (manufactured by Soken Kagaku Co., Ltd.) was applied to the back side of commercially available wallpaper (adhesive-free sheet with backing paper adhered to the back side of a vinyl chloride sheet). rn2 was applied and dried. Add to this a polyethylene sheet (thickness 12 μm)
) is used as a liner to cause adhesion. Such a phenomenon can be suppressed by blending a silicone resin into a solvent-based adhesive without causing a substantial decrease in adhesive strength.
従来一般には、粘着剤は、その粘着性の向上を主たる目
的として改良が加えられてきており、それに剥離性に優
れたシリコーン樹脂を配合することは、粘着性を低下さ
せることとなるため、全く意図されていなかった。本発
明においても粘着剤樹脂固形分に対し、シリコーン樹脂
固形分換算で１０重量％より多く用いると粘着性か低下
する。In the past, adhesives have generally been improved with the main purpose of improving their tackiness, and adding silicone resin, which has excellent releasability, to them would reduce the tackiness, so it was completely unnecessary. It wasn't meant to be. Also in the present invention, if the silicone resin is used in an amount exceeding 10% by weight based on the solid content of the adhesive resin, the tackiness decreases.
また０、１重量％より少ないと上述のごとき効果は十分
に達成することができない。Further, if the content is less than 0.1% by weight, the above-mentioned effects cannot be sufficiently achieved.
シリコーン樹脂は油溶性のものを用いるのが好ましく、
例えばポリジメチルンロキサン、ジメチルシロキサン／
フェニルメチルシロキサン共重合体
等剥離剤として一般に用いられているものを用いればよ
い。It is preferable to use an oil-soluble silicone resin,
For example, polydimethylsiloxane, dimethylsiloxane/
A commonly used release agent such as phenylmethylsiloxane copolymer may be used.
粘着剤とシリコーン樹脂とは両者とも溶剤型であるのが
好ましい、エマルジョン型の場合は局部１ま
た。Both the adhesive and the silicone resin are preferably solvent-based, and in the case of an emulsion-type, they are used locally.
別に溶剤型ポリアクリル酸エステル系粘着剤（綜研化学
株式会社製）のみからなるライナー裏面用粘着剤（Ｉ）
およびその９重量部とジメチルポリシロキサンを主成分
とするシリコーン離型剤（信越化学工業株式会社製）１
重量部を均一に混合してライナー裏面用粘着剤（Ｉ［）
を調製した。Separately, an adhesive for the back side of the liner (I) consisting only of a solvent-based polyacrylic acid ester adhesive (manufactured by Soken Kagaku Co., Ltd.)
and 9 parts by weight of silicone mold release agent (manufactured by Shin-Etsu Chemical Co., Ltd.) containing dimethylpolysiloxane as the main components 1
Adhesive for the back side of liner (I [)]
was prepared.
市販壁紙に接着したポリエチレンシー１〜に上記ライナ
ー裏面用粘着剤（Ｉ）および（ＩＩ）をそれぞれ７５ｇ
／＋＋＋２の割合で塗布、乾燥して、粘着剤付壁紙（Ｉ
）および（ｎ）を得た。これを粘着および剥離試験に供
した。Add 75 g each of the above liner backside adhesives (I) and (II) to polyethylene sheet 1 adhered to commercially available wallpaper.
/+++2 coating, drying, adhesive wallpaper (I
) and (n) were obtained. This was subjected to adhesion and peeling tests.
別に比較のため、実施例１で用いた市販壁紙の裏面に直
接溶剤型ポリアクリル酸エステル系粘着剤を塗布した壁
紙（Ａ）、市販壁紙に実施例１で用いた市販壁紙の裏面
にポリビニルアルコール系接着剤を塗布した壁紙（Ｂ）
を調製しこれを粘着および剥離試験に供した。Separately, for comparison, wallpaper (A) in which a solvent-type polyacrylate adhesive was directly applied to the back of the commercially available wallpaper used in Example 1, and a commercially available wallpaper in which polyvinyl alcohol was applied to the back of the commercially available wallpaper used in Example 1. Wallpaper coated with adhesive (B)
was prepared and subjected to adhesion and peeling tests.
粘着および剥離試験
１０００ Ｘ ］ ＯＯＱ Ｘ Ｉ Ｏ（ｍｍ）の木質
合板の表面にハトロン紙を張った供試板表面上に上記壁
紙（Ｉ）、（Ａ）および（Ｂ）と貼りつけた。ハ１−ロ
ン紙はその側縁部を木質合板裏面で酢酸ビニル／アクリ
ル系接着剤を用いて接着し、表面は合板と接着していな
い。Adhesion and peeling test 1000×] OOQ The side edges of the Halon paper were adhered to the back side of the wood plywood using a vinyl acetate/acrylic adhesive, and the front side was not adhered to the plywood.
壁紙と貼りつけたパネルを温度３０°Ｃ５相対湿度９０
％に調節した室内に２ケ月保存し、その粘着性および剥
離性を判断した。The wallpaper and pasted panels were kept at a temperature of 30°C and a relative humidity of 90°C.
% in a room for 2 months, and its adhesiveness and peelability were evaluated.
壁紙（Ｉ）および（ｎ）は全く剥離は観察されなかった
。壁紙（ＩＴ）はライナー紙とハトロン紙を指で強制剥
離すると、強い粘着性を示すが、局部的な強固な接着は
なく円滑に剥離し供紙板上のハトロン紙は破れなかった
。また別紙（Ｉ）を剥離すると裏打紙とライナー間で剥
離し、剥離紙がライナー層上に均一に残存し、ハトロン
紙上にライナーが残った。No peeling was observed in wallpapers (I) and (n). When the liner paper and the Hatron paper were forcibly peeled off with fingers, the wallpaper (IT) exhibited strong adhesion, but there was no strong local adhesion and the wallpaper was peeled off smoothly, and the Hatron paper on the paper board was not torn. Further, when Separate Paper (I) was peeled off, the backing paper and the liner were peeled off, and the release paper remained uniformly on the liner layer, and the liner remained on the Hatron paper.
壁紙（Ａ）は剥離は観察されなかったが強制剥離に際し
、局部的に強い抵抗があり、供紙板上のハトロン紙を破
らずにあるいは裏打紙の局部的な破れなしに剥離するの
（キ困難であった。No peeling was observed for wallpaper (A), but there was strong local resistance when forcedly peeling it off, making it difficult to peel it off without tearing the Hatron paper on the paper board or without locally tearing the backing paper. Met.
紙により溶剤型粘着剤や壁面からの化学成分、あく等が
表面シート側に移行しないので表面の汚れやじみが防げ
るのみならず、粘着剤の表面シートへの移行にともなく
経時的な粘着性劣化が防げる。Paper prevents solvent-based adhesives and chemical components from the wall surface, dirt, etc. from transferring to the top sheet, which not only prevents surface stains and smudges, but also improves tackiness over time as the adhesive transfers to the top sheet. Prevents deterioration.
粘着剤として、溶剤型粘着剤とシリコーン離型剤とを併
用すると粘着強度を実質上低下させることなく、かつ粘
着性を均一にし、強制的な剥離に際しては剥離が円滑に
行なわれ、下地を傷めることがない。When a solvent-based adhesive and a silicone release agent are used in combination as an adhesive, the adhesive strength is not substantially reduced and the adhesiveness is made uniform, and when forced peeling is performed, the peeling is performed smoothly and the base material is not damaged. Never.
第１図から第３図は本発明粘着シートの模式的断面図で
ある。
（１）基材シート、 （２）化粧層、（３）表面シー
ト、 （４）裏打接着層、（５）裏打紙、
（６）接着層、（７）ライナー （８）粘着層。
特許出願人 山 本 森 之 資
化 理 人 弁理士 青 山 葆 はか１名壁紙（Ｂ）
は、壁紙の縁および隅に剥離かみられ、これを強制剥離
すると剥離紙か部分的に供紙パネル上に残存し、これを
とり除くのは困難であった。
実施例２
厚さ７５μｍ１幅５０ｍｍのクラフト紙製テープの裏面
に、実施例１と同様にして、ポリエチレンフィルムを粘
着し、その裏面にライナー用粘着剤（実施例１の粘着剤
（ｎ）と同じ。但しシリコーン剥離剤は１重量％使用）
を塗布乾燥し、さらに表面をパラフィン処理した。これ
を巻き取って荷造用テープを得た。これをダンボールに
貼りつけ、室内に１日保管後、強制剥離した。剥離に際
して、相当の粘着強度を示したが局部的な強い粘着はな
く円滑な剥離が行なわれダンボールの表面は傷まず、完
全に剥離することができた。
発明の効果
本発明粘着シート１オライナー層が設けであるため、溶
剤型粘着剤を用いても表面シートを傷めることかない。
溶剤型粘着剤の使用により、湿度による剥離や懲の発生
が抑えられる。またライナー第１図
第２図
第３図1 to 3 are schematic cross-sectional views of the pressure-sensitive adhesive sheet of the present invention. (1) base sheet, (2) decorative layer, (3) top sheet, (4) backing adhesive layer, (5) backing paper,
(6) adhesive layer, (7) liner (8) adhesive layer. Patent applicant: Moriyuki Yamamoto, patent attorney: Haka Aoyama Wallpaper (B)
Peeling was observed at the edges and corners of the wallpaper, and when it was forcibly removed, part of the release paper remained on the paper panel, making it difficult to remove. Example 2 A polyethylene film was adhered to the back side of a kraft paper tape having a thickness of 75 μm and a width of 50 mm in the same manner as in Example 1, and a liner adhesive (same as the adhesive (n) in Example 1) was applied to the back side of the craft paper tape. (However, silicone release agent is used at 1% by weight)
was applied and dried, and the surface was further treated with paraffin. This was rolled up to obtain a packing tape. This was pasted on a cardboard box, kept indoors for one day, and then forcibly peeled off. Upon peeling, it showed considerable adhesive strength, but there was no localized strong adhesion, and the peeling was smooth and the cardboard surface was not damaged and could be completely peeled off. Effects of the Invention Since the pressure-sensitive adhesive sheet 1 of the present invention is provided with an oliner layer, the top sheet will not be damaged even if a solvent-based pressure-sensitive adhesive is used. By using a solvent-based adhesive, peeling and cracking due to humidity can be suppressed. Also, the liner Figure 1 Figure 2 Figure 3
Claims (1)
された合成樹脂製ライナー層（７）およびライナー層（
７）に油性粘着剤層（８）が設けられた粘着シート。 ２、基材シート（１）が表面シート（３）および裏打紙
（５）からなり、裏打紙（５）が表面シートの裏面に裏
打接着剤層（４）により接着されている第１項記載の粘
着シート。３、基材シート（１）が化粧層（２）を有す
る表面シート（３）からなる第１項記載の粘着シート。 ４、基材シート（１）が化粧層（２）を有する表面シー
ト（３）および裏打紙（５）からなり、裏打紙（５）が
表面シート（３）に裏打接着剤層（４）により接着され
ている第１項記載の粘着シート。 ５、表面シート（３）が浸透性素材からなる第３項記載
の粘着シート。 ６、油性粘着剤層（８）が、シリコーン離型剤を溶剤型
粘着剤に配合した粘着剤を塗布乾燥することにより得ら
れるものである第１項記載の粘着シート。 ７、シリコーン離型剤が固形分換算で溶剤型粘着剤固形
分の０．１〜１０重量％配合されている第６項記載の粘
着シート。 ８、油性粘着剤層に剥離紙を貼付した第１項記載の粘着
シート。[Claims] 1. A base sheet (1), a synthetic resin liner layer (7) adhered to the back surface of the base sheet (1), and a liner layer (
7) A pressure-sensitive adhesive sheet provided with an oil-based pressure-sensitive adhesive layer (8). 2. Item 1, wherein the base sheet (1) is composed of a top sheet (3) and a backing paper (5), and the backing paper (5) is adhered to the back surface of the top sheet by a backing adhesive layer (4). adhesive sheet. 3. The pressure-sensitive adhesive sheet according to item 1, wherein the base sheet (1) comprises a top sheet (3) having a decorative layer (2). 4. The base sheet (1) consists of a top sheet (3) having a decorative layer (2) and a backing paper (5), and the backing paper (5) is attached to the top sheet (3) by a backing adhesive layer (4). The pressure-sensitive adhesive sheet according to item 1, which is bonded. 5. The adhesive sheet according to item 3, wherein the top sheet (3) is made of a permeable material. 6. The pressure-sensitive adhesive sheet according to item 1, wherein the oil-based pressure-sensitive adhesive layer (8) is obtained by applying and drying a pressure-sensitive adhesive prepared by blending a silicone release agent with a solvent-type pressure-sensitive adhesive. 7. The pressure-sensitive adhesive sheet according to item 6, wherein the silicone mold release agent is blended in an amount of 0.1 to 10% by weight of the solid content of the solvent-based pressure-sensitive adhesive in terms of solid content. 8. The adhesive sheet according to item 1, wherein a release paper is attached to the oil-based adhesive layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14412188A JPH026697A (en) | 1988-06-09 | 1988-06-09 | Adhesive sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14412188A JPH026697A (en) | 1988-06-09 | 1988-06-09 | Adhesive sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH026697A true JPH026697A (en) | 1990-01-10 |
Family
ID=15354682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14412188A Pending JPH026697A (en) | 1988-06-09 | 1988-06-09 | Adhesive sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH026697A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0734400A (en) * | 1993-07-22 | 1995-02-03 | Sankoo Kogyo Kk | Wallpaper with tacky agent |
-
1988
- 1988-06-09 JP JP14412188A patent/JPH026697A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0734400A (en) * | 1993-07-22 | 1995-02-03 | Sankoo Kogyo Kk | Wallpaper with tacky agent |
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