JPH0263A - Photomask cover - Google Patents
Photomask coverInfo
- Publication number
- JPH0263A JPH0263A JP1089136A JP8913689A JPH0263A JP H0263 A JPH0263 A JP H0263A JP 1089136 A JP1089136 A JP 1089136A JP 8913689 A JP8913689 A JP 8913689A JP H0263 A JPH0263 A JP H0263A
- Authority
- JP
- Japan
- Prior art keywords
- thin film
- photomask
- plasticizer
- thickness
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010409 thin film Substances 0.000 claims abstract description 25
- 229920002678 cellulose Polymers 0.000 claims abstract description 16
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 239000010408 film Substances 0.000 abstract description 17
- 239000011521 glass Substances 0.000 abstract description 15
- 238000005266 casting Methods 0.000 abstract description 9
- 239000002904 solvent Substances 0.000 abstract description 8
- 239000000020 Nitrocellulose Substances 0.000 abstract description 6
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 abstract description 6
- 229920001220 nitrocellulos Polymers 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000009835 boiling Methods 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract description 2
- 150000002576 ketones Chemical class 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 229920002301 cellulose acetate Polymers 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000009750 centrifugal casting Methods 0.000 description 3
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 3
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- -1 fatty acid esters Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
Landscapes
- Preparing Plates And Mask In Photomechanical Process (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はリソグラフィーにおけるフォトマスク保護用の
樹脂薄膜から成るフォトマスクカバーに関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a photomask cover made of a thin resin film for protecting a photomask in lithography.
集積回路の製造のためのリソグラフィーにおいて、光源
に紫外線を用いたフォトレジストは、高い解像力と高い
生産性が特徴であり、特に集積度の高いウェハ乃至チッ
プの製造に極めて有用である。In lithography for manufacturing integrated circuits, photoresists using ultraviolet rays as a light source are characterized by high resolution and high productivity, and are particularly useful for manufacturing highly integrated wafers or chips.
この方式は、解像力が高いだけにフォトマスクの画像面
上への小さなゴミの付着はエツチング画像の精度を低下
させ、不良品発生の原因になるほか、ゴミ除去の作業に
より、フォトマスク自体を傷めやすく、その寿命を低下
させる。Although this method has high resolution, small dust adhering to the image surface of the photomask reduces the accuracy of the etched image and causes defective products, and the process of removing dust can damage the photomask itself. easily, reducing its lifespan.
上記の対策として、フォトマスクの画像面側の光路中に
樹脂薄膜からなるフォトマスクカバーを挿入して、空気
中のゴミの付着からフォトマスク画像を保護する方法が
用いられている。As a countermeasure against the above problem, a method is used in which a photomask cover made of a thin resin film is inserted into the optical path on the image side of the photomask to protect the photomask image from adhesion of dust in the air.
この場合、ゴミはフォトマスクの画像面上に付着するか
わりに、樹脂薄膜の表面に付着することになる。この際
、薄膜自身の厚み及びフォトマスク画像と薄膜との距離
が全面にわたって一定であれば、薄膜上の異物、即ちゴ
ミの存在の影響をレジスト面においてアウトフォーカシ
ングさせることが可能であり、フォトマスク画像に忠実
なパターンを露光により得ることができる。In this case, the dust will adhere to the surface of the resin thin film instead of adhering to the image surface of the photomask. At this time, if the thickness of the thin film itself and the distance between the photomask image and the thin film are constant over the entire surface, it is possible to outfocus the effect of foreign matter, that is, dust, on the thin film on the resist surface, and the photomask A pattern faithful to the image can be obtained by exposure.
発明者等は、鋭意研究の結果、可塑剤が添加されていな
いセルロースエステル薄膜をフォトマスクカバーの薄膜
材料として使用することにより、フォトマスク保護用に
適したフォトマスフカバーが得られることを認め、本発
明に到達した。As a result of intensive research, the inventors have recognized that a photomask cover suitable for protecting a photomask can be obtained by using a cellulose ester thin film to which no plasticizer is added as the thin film material for the photomask cover. , arrived at the present invention.
本発明に使用する薄膜の材料に要求される物性は以下の
通りである。The physical properties required of the thin film material used in the present invention are as follows.
イ 露光に使用する光の特定領域、(特にこの場合UV
領域)で、できるだけ吸収が少ないこと。b. The specific area of light used for exposure (especially in this case UV
area), with as little absorption as possible.
口 薄い膜厚でも十分強度があり、支持枠で支持した後
、クリープや収縮のないこと。Even though the film is thin, it has sufficient strength and does not creep or shrink after being supported by a support frame.
ハ 結晶や配向により透過光に方向性を生じせしめない
こと。C. Directionality should not be caused in transmitted light due to crystals or orientation.
二 薄膜よりフォトマスクに悪影響を及ぼすような物質
がでないこと。2. There should be no substances that would adversely affect the photomask compared to the thin film.
本発明の可塑剤が添加されていないセルロースエステル
薄膜はこれらの条件を満足するものである。The cellulose ester thin film of the present invention to which no plasticizer is added satisfies these conditions.
即ち、本発明は可塑剤を添加していないセルロースエス
テルを有機溶剤に溶解し、平滑なガラス板上に流延した
薄膜を、水中で剥離し、湿潤状態で支持枠に支持させた
後乾燥させることにより得られたフォトマスクカバーで
ある。That is, in the present invention, cellulose ester without added plasticizer is dissolved in an organic solvent, and a thin film is cast on a smooth glass plate, peeled off in water, supported on a support frame in a wet state, and then dried. This is the photomask cover obtained by this method.
本発明に使用する膜材料としてはセルロースエステルが
適当であり、セルロースエステルとは、硝酸セルロース
、酢酸セルロース、プロピオン酸セルロース、酪酸酢酸
セルロースなどを指す。就中、硝酸セルロースは本発明
の目的に特に適当である。Cellulose ester is suitable as the membrane material used in the present invention, and cellulose ester refers to cellulose nitrate, cellulose acetate, cellulose propionate, cellulose acetate butyrate, and the like. Among these, cellulose nitrate is particularly suitable for the purposes of the present invention.
樹脂薄膜の製造には、所謂流延方式を用いることによっ
て、配向性のない膜を得る。セルロースエステルはケト
ン、低級脂肪酸エステルなどの比較的低沸点溶剤に容易
に溶解し、溶液濃度及び流延厚みを規定することにより
、所定の出来上がり厚みの薄膜を製造することができる
。In manufacturing the resin thin film, a so-called casting method is used to obtain a film without orientation. Cellulose esters are easily dissolved in relatively low boiling point solvents such as ketones and lower fatty acid esters, and by regulating the solution concentration and casting thickness, a thin film with a predetermined finished thickness can be produced.
フォトマスク保護用薄膜には、例えば2.8±0.3μ
mや4.5±0.3μmなどの一定の厚みのものが使用
される。For example, the thickness of the photomask protective thin film is 2.8±0.3μ.
A material having a certain thickness such as m or 4.5±0.3 μm is used.
流延時の流延基板を平滑なガラス板とし、溶媒除去後水
中に浸漬すると、薄膜はガラス板から自然に剥がれるの
で、容易に回収することができる。この薄膜をアルミニ
ウム支持枠に直接マウントし、生乾きの状態のとき、支
持枠と膜の接触部分に沿って、揮発性の溶剤を少量塗布
し乾燥させると、膜が支持枠に接着するとともに、ごく
僅かに膜が収縮しようとして、均一な緊張状態での支持
が得られる。When a smooth glass plate is used as the casting substrate during casting, and the thin film is immersed in water after removing the solvent, the thin film is naturally peeled off from the glass plate and can be easily recovered. This thin film is directly mounted on an aluminum support frame, and when it is partially dry, a small amount of volatile solvent is applied along the contact area between the support frame and the membrane and dried. The membrane attempts to contract slightly, providing support under uniform tension.
硝酸セルロースをはじめとするセルロースエステルは透
明度が高く、UV領域にも吸収が少なく、光学的に優れ
た材料である。また、本来結晶性が小さいのに分子構造
が剛直であるため、成形後のディメンショナルスタビリ
ティがある。Cellulose esters such as cellulose nitrate are highly transparent, have little absorption in the UV region, and are optically excellent materials. In addition, although the crystallinity is originally low, the molecular structure is rigid, so it has dimensional stability after molding.
適当な流延溶剤が利用でき、ガラス板への密着性に乏し
いため、力を加えずに薄膜だけを回収することができ、
薄膜は水によりごく僅か膨潤するなど種々の利点がある
が、本発明はこれらの利点をたくみに利用したものであ
る。Appropriate casting solvents can be used, and since it has poor adhesion to the glass plate, only a thin film can be collected without applying force.
Thin films have various advantages, such as being swollen very slightly by water, and the present invention takes advantage of these advantages.
−mにセルロースエステルの加工性は、可塑剤を使用す
ることにより向上するが、可塑剤の使用はUV領域の吸
収、ガラス面への接着性、クリープ性、可塑剤の揮発に
よるフォトマスクへの汚染など、本発明の目的には好ま
しくない効果が出る。本発明によれば、可塑剤が添加さ
れていないセルロースエステル薄膜を使用することによ
り、上記のセルロースエステル本来の性能を利用して、
本発明の目的を達成し得る。-m The processability of cellulose ester can be improved by using a plasticizer, but the use of a plasticizer can cause problems such as absorption in the UV region, adhesion to glass surfaces, creep property, and photomask formation due to volatilization of the plasticizer. Effects that are undesirable for the purposes of the present invention, such as contamination, occur. According to the present invention, by using a cellulose ester thin film to which no plasticizer is added, the above-mentioned inherent performance of cellulose ester is utilized.
The object of the present invention can be achieved.
以下の実施例によりさらに本発明を説明する。The following examples further illustrate the invention.
実施例1
硝化綿R3−5(ダイセル化学工業製、イソプロパツー
ル混綿、固型分70%)64g、メチルエチルケトン1
46 g 、酢酸ブチル120g及びトルエン120g
からなる硝化綿ドープを、クリアランス50μmのパー
コーターを用いて、平滑なガラス板上に塗布し、24時
間室温(20℃)に放置乾燥し、さらに60℃で1時間
乾燥した。乾燥フィルム化した硝化綿をガラス板ごと静
かに清浄な水中に浸漬した。暫時放置すると、硝化綿フ
ィルムはガラス板から自然に剥離したので、−旦直径約
150mmの円形アルミフレームを用いて形を崩さない
ようすくい上げ、該フレーム内の部分を内径100mm
、外径110mm、厚みlQmmのアルミニウム支持枠
の上面にマウントした。次いで、フィルムの支持枠との
接触界面に沿って、少量のメチルエチルケトンを塗布し
、風乾することによって、フィルムを支持枠に接着させ
た。支持枠の外側にはみ出している部分のフィルムを切
り除き、60℃で3時間乾燥させると、均一な緊張度で
支持された厚さ3μm(比重1.6)の硝酸セルロース
フィルムから成るフォトマスクカバーを得た。Example 1 Nitrified cotton R3-5 (manufactured by Daicel Chemical Industries, isopropanol blended cotton, solid content 70%) 64 g, 1 methyl ethyl ketone
46 g, butyl acetate 120 g and toluene 120 g
A nitrified cotton dope consisting of the following was applied onto a smooth glass plate using a percoater with a clearance of 50 μm, left to dry at room temperature (20° C.) for 24 hours, and further dried at 60° C. for 1 hour. The dried film-formed nitrified cotton was gently immersed together with the glass plate in clean water. After being left for a while, the nitrified cotton film naturally peeled off from the glass plate, so I scooped it up using a circular aluminum frame with a diameter of about 150 mm without losing its shape, and cut the part inside the frame into an inner diameter of 100 mm.
, was mounted on the upper surface of an aluminum support frame having an outer diameter of 110 mm and a thickness of 1Q mm. The film was then adhered to the support frame by applying a small amount of methyl ethyl ketone along the contact interface of the film with the support frame and air drying. After cutting off the part of the film protruding outside the support frame and drying it at 60°C for 3 hours, a photomask cover made of cellulose nitrate film with a thickness of 3 μm (specific gravity 1.6) supported with uniform tension was created. I got it.
実施例2
実施例1の硝化綿ドープに代えて、酢酸綿LT105(
ダイセル化学工業製)60g、塩化メチレン846g及
びメタノール94gからなる酢酸綿を用いて、実施例1
に準じて酢酸セルロースフィルムを作製した。但し流延
厚みは50μm、支持枠とフィルムとの接着に用いた溶
剤は塩化メチレン/メタノール=9/1の混合溶剤であ
った。Example 2 Instead of the nitrified cotton dope of Example 1, acetic acid cotton LT105 (
Example 1 Using acetic acid cotton consisting of 60 g (manufactured by Daicel Chemical Industries), 846 g of methylene chloride, and 94 g of methanol,
A cellulose acetate film was prepared according to . However, the casting thickness was 50 μm, and the solvent used for bonding the support frame and the film was a mixed solvent of methylene chloride/methanol=9/1.
同様にして均一な緊張度で支持された厚さ3μm(比重
1.3)のフィルムから成るフォトマスクカバーを得た
。Similarly, a photomask cover made of a film with a thickness of 3 μm (specific gravity 1.3) supported with uniform tension was obtained.
実施例3
硝化綿R5−7(ダイセル化学工業製、イソプロパツー
ル混綿、固型分70%>20g、酢酸ブチル50g1酢
酸イソブチル50g及びシクロへキサノン90gからな
る硝化綿ドープを作製した。Example 3 Nitrified cotton R5-7 (manufactured by Daicel Chemical Industries, Ltd., isopropanol blended cotton, solid content 70% > 20 g, nitrified cotton dope consisting of 50 g of butyl acetate, 50 g of isobutyl acetate, and 90 g of cyclohexanone was prepared.
このドープの23℃における粘度は480cpであった
。このドープを用いてスピンコーティング法によりフィ
ルムを作成した。即ち、スピンナーにガラス板をセット
し、70rpmで回転させつつ、その回転中心に上記ド
ープを5秒間を要して滴下した。滴下終了後直ちに回転
速度を105゜rpmに上昇(立ち上がり所要時間0.
2秒)させ、この速度で15秒間維持する間に遠心流延
させた後、回転を停止させた。The viscosity of this dope at 23°C was 480 cp. A film was prepared using this dope by spin coating. That is, a glass plate was set in a spinner, and while rotating at 70 rpm, the above-mentioned dope was dropped onto the center of rotation over a period of 5 seconds. Immediately after the completion of dripping, increase the rotation speed to 105°rpm (required start-up time: 0.
2 seconds), centrifugal casting was performed while maintaining this speed for 15 seconds, and then the rotation was stopped.
次にガラス板をスピンナーから取り外し、24時間室内
(23℃、60%RH)に放置乾燥し、さらに60℃で
1時間乾燥した。以下実施例1と同様にして水中浸漬し
、ガラス板から生成フィルムを剥離し、アルミニウム支
持枠にマウントし、接着支持させた。支持枠ごと60℃
、3時間乾燥し、平均厚み0.29μm1厚みむら0.
03μm以下の均一な緊張度で支持された硝酸セルロー
スフィルムから成るフォトマスクカバーを得た。Next, the glass plate was removed from the spinner, left to dry indoors (23° C., 60% RH) for 24 hours, and further dried at 60° C. for 1 hour. Thereafter, the glass plate was immersed in water in the same manner as in Example 1, and the resulting film was peeled off from the glass plate, mounted on an aluminum support frame, and supported by adhesive. 60℃ for each support frame
, dried for 3 hours, average thickness 0.29 μm, thickness unevenness 0.
A photomask cover consisting of a cellulose nitrate film supported with a uniform tension of 0.03 μm or less was obtained.
実施例4
硝化綿R3−120(ダイセル化学工業製、インプロパ
ツール混綿、固型分70%)10g、酢酸ブチル47.
6 g、酢酸イソブチル47.6g及びシクロへキサノ
ン94.8 gからなる硝化綿ドープを作成した。Example 4 Nitrified cotton R3-120 (manufactured by Daicel Chemical Industries, Improper Tool blended cotton, solid content 70%) 10g, butyl acetate 47.
6 g of isobutyl acetate, and 94.8 g of cyclohexanone.
このドープの23℃における粘度は300cpであった
。The viscosity of this dope at 23°C was 300 cp.
上記のドープを用い、且つ遠心流延の回転速度を780
rpmとしたほかは、実施例3と同様に操作し、平均厚
さ0.90μm1厚みむら0.005μm以下の均一な
緊張度で支持された硝酸セルロースフィルムから成るフ
ォトマスクカバーを得た。Using the above dope and rotating the centrifugal casting at a rotation speed of 780
The photomask cover was prepared in the same manner as in Example 3 except that the rotation speed was changed to 0.90 μm in average thickness and a uniform tension of 0.005 μm or less in thickness.
実施例5
酢酸綿L−20(ダイセル化学工業製、乾燥減率5%N
8.5g、エチレングリコールアセテートモノメチルエ
ーテル91.2 g 、シクロヘキサノン45、6 g
、酢酸ブチル22.8 g及び酢酸イソブチル22、
8 gからなる酢酸綿ドープを作成した。Example 5 Acetate cotton L-20 (manufactured by Daicel Chemical Industries, drying loss rate 5% N
8.5 g, ethylene glycol acetate monomethyl ether 91.2 g, cyclohexanone 45.6 g
, butyl acetate 22.8 g and isobutyl acetate 22,
An acetic acid cotton dope containing 8 g was prepared.
このドープの23℃における粘度は550CI]であっ
た。The viscosity of this dope at 23° C. was 550 CI].
上記のドープを用い、ガラス板上に滴下するときの回転
速度が20Orpm、滴下所要時間7秒間、遠心流延の
回転速度850rpmとしたほかは、実施例3と同様に
操作し、平均厚さ0.29μm1厚みむら0.03μm
以下の均一な緊張度で支持された酢酸セルロースフィル
ムから成るフォトマスクカバーを得た。Using the above dope, the same procedure as in Example 3 was carried out, except that the rotation speed when dropping onto the glass plate was 20 Orpm, the time required for dropping was 7 seconds, and the rotation speed of centrifugal casting was 850 rpm. .29μm 1 thickness unevenness 0.03μm
A photomask cover consisting of a cellulose acetate film supported with the following uniform tension was obtained.
Claims (1)
ル薄膜よりなるフォトマスクカバーにおいて、セルロー
スエステルに可塑剤が添加されていないことを特徴とす
るフォトマスクカバー。A photomask cover comprising a non-oriented cellulose ester thin film held in a uniform tension state, characterized in that no plasticizer is added to the cellulose ester.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1089136A JPH0263A (en) | 1989-04-07 | 1989-04-07 | Photomask cover |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1089136A JPH0263A (en) | 1989-04-07 | 1989-04-07 | Photomask cover |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57103488A Division JPS58219023A (en) | 1982-06-15 | 1982-06-15 | Manufacture of resin membrane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0263A true JPH0263A (en) | 1990-01-05 |
JPH0544017B2 JPH0544017B2 (en) | 1993-07-05 |
Family
ID=13962464
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1089136A Granted JPH0263A (en) | 1989-04-07 | 1989-04-07 | Photomask cover |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0263A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001201845A (en) * | 1999-11-09 | 2001-07-27 | Asahi Kasei Electronics Co Ltd | Large-sized pellicle |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI288443B (en) | 2002-05-17 | 2007-10-11 | Semiconductor Energy Lab | SiN film, semiconductor device, and the manufacturing method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5480082A (en) * | 1977-12-05 | 1979-06-26 | Ibm | Mask for projecting print |
JPS5544841A (en) * | 1978-09-26 | 1980-03-29 | Mitsubishi Gas Chem Co Inc | Method of producing laminated plates |
JPS58196501A (en) * | 1981-12-02 | 1983-11-16 | アドバンスド セミコンダクタ プロダクツ | Optical thin film body |
-
1989
- 1989-04-07 JP JP1089136A patent/JPH0263A/en active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5480082A (en) * | 1977-12-05 | 1979-06-26 | Ibm | Mask for projecting print |
JPS5544841A (en) * | 1978-09-26 | 1980-03-29 | Mitsubishi Gas Chem Co Inc | Method of producing laminated plates |
JPS58196501A (en) * | 1981-12-02 | 1983-11-16 | アドバンスド セミコンダクタ プロダクツ | Optical thin film body |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001201845A (en) * | 1999-11-09 | 2001-07-27 | Asahi Kasei Electronics Co Ltd | Large-sized pellicle |
Also Published As
Publication number | Publication date |
---|---|
JPH0544017B2 (en) | 1993-07-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6325932B2 (en) | ||
US4861402A (en) | Method of making a cellulose acetate butyrate pellicle | |
JP4686846B2 (en) | Protective film for polarizing plate, polarizing plate using the same, and display device | |
US5008156A (en) | Photochemically stable mid and deep ultraviolet pellicles | |
JPH0263A (en) | Photomask cover | |
JPH0262A (en) | Photomask cover | |
JPH0264A (en) | Production of photomask cover | |
JPS6038130A (en) | Preparation of polymeric film bonded fixedly to frame | |
US4796973A (en) | Pellicle structure for transmission of mid ultraviolet light | |
JP2790946B2 (en) | Method of manufacturing pellicle film | |
JP2003183417A (en) | Cellulose ester film and protective film for polarizing plate | |
KR100346062B1 (en) | Method For Manufacturing Semiconductor Device | |
KR20120081667A (en) | Pelicle membrane and method of forming pelicle membrane | |
JPH0465764B2 (en) | ||
JP4378739B2 (en) | Manufacturing method of polarizing plate | |
EP0084221B1 (en) | Method for the manufacture of a thin optical membrane | |
KR20100116105A (en) | Method of forming pelicle membrane using substrate having realising layer | |
GB2165545A (en) | Pellicle structure for transmission of mid ultraviolet light | |
JPH06230560A (en) | Pellicle | |
JPH0768576A (en) | Manufacture of fluororesin thin film | |
JPH06222551A (en) | Releasable substrate for formation of film and production of pellicle film | |
JPH01166045A (en) | Pellicle peeling method | |
JPH0477739A (en) | Manufacture of pellicle | |
BE820396A (en) | COATED FILMS | |
JPH02230245A (en) | Pellicle for lithography |