JPH0263890A - Resistance layer film for electrothermal recording - Google Patents
Resistance layer film for electrothermal recordingInfo
- Publication number
- JPH0263890A JPH0263890A JP21675988A JP21675988A JPH0263890A JP H0263890 A JPH0263890 A JP H0263890A JP 21675988 A JP21675988 A JP 21675988A JP 21675988 A JP21675988 A JP 21675988A JP H0263890 A JPH0263890 A JP H0263890A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- film
- layer
- polycarbonate resin
- resistance layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 21
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 21
- 239000006229 carbon black Substances 0.000 claims abstract description 15
- 229920001971 elastomer Polymers 0.000 claims abstract description 12
- 239000000806 elastomer Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 abstract description 20
- 238000007639 printing Methods 0.000 abstract description 20
- 238000012805 post-processing Methods 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 32
- 229910052799 carbon Inorganic materials 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 238000012546 transfer Methods 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000020169 heat generation Effects 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- -1 bisphenol compound Chemical class 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- XDGXPHFWSPGAIB-UHFFFAOYSA-N 4-[1-(4-hydroxy-3-methylphenyl)ethyl]-2-methylphenol Chemical compound C=1C=C(O)C(C)=CC=1C(C)C1=CC=C(O)C(C)=C1 XDGXPHFWSPGAIB-UHFFFAOYSA-N 0.000 description 1
- OPSUNPUMLMJDTH-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-2,2-diphenylethyl]phenol Chemical compound C1=CC(O)=CC=C1CC(C=1C=CC(O)=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 OPSUNPUMLMJDTH-UHFFFAOYSA-N 0.000 description 1
- KANXFMWQMYCHHH-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-3-methylbutan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(C(C)C)C1=CC=C(O)C=C1 KANXFMWQMYCHHH-UHFFFAOYSA-N 0.000 description 1
- VHLLJTHDWPAQEM-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-4-methylpentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CC(C)C)C1=CC=C(O)C=C1 VHLLJTHDWPAQEM-UHFFFAOYSA-N 0.000 description 1
- WCUDAIJOADOKAW-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)pentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CCC)C1=CC=C(O)C=C1 WCUDAIJOADOKAW-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
- Laminated Bodies (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は通電窓外記録用抵抗層フィルムに関する。詳し
くは無騒音タイプライタ−、コンピューターのアウトプ
ット、ファクシミリの印字記録用として有用な通電感熱
記録用抵抗層フィルムに関わるものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a resistive layer film for recording outside an energized window. More specifically, the present invention relates to a resistive layer film for electrically conductive heat-sensitive recording, which is useful for use in noiseless typewriters, computer output, and facsimile print recording.
現在、広く用いられている溶融型インクリボンを用いた
溶融転写記録方式又は、感熱紙を用いた感熱発色記録方
式は、熱ヘツドの蓄熱効果のために印字速度に限界があ
り、高速化が不可能である。Currently, the melt transfer recording method using a melt-type ink ribbon or the heat-sensitive color recording method using thermal paper, which are widely used, has a limit in printing speed due to the heat storage effect of the thermal head, and it is difficult to increase the printing speed. It is possible.
更にヘッド内のドツトが大きく微細な印字は困難である
。Furthermore, the dots inside the head are large, making it difficult to print fine print.
通電感熱記録方式は従来の一般的な熱へ・ノドによる熔
融転写記録方式に比べ、へ・ノドによる蓄熱効果が少な
いため、より高速な印字が可能となる。Compared to the conventional melt transfer recording method that uses heat and gutter, the current thermal recording method has less heat accumulation effect due to heat and gutter, making it possible to print at higher speeds.
又、一つの電極の面積が従来の熱へ・ノドの面積に比べ
て１／４と小さく、より微細な印字が可能となる。In addition, the area of one electrode is 1/4 smaller than the area of a conventional heat gutter, allowing for finer printing.
通電感熱記録用抵抗層フィルムとしては従来ポリカーボ
ネート樹脂にカーボンブランクを機械的に分散し、キャ
スティング法、押出法などでフィルム化したものが用い
られている。Conventionally, as a resistance layer film for electrically conductive heat-sensitive recording, a film in which a carbon blank is mechanically dispersed in a polycarbonate resin and formed into a film by a casting method, an extrusion method, or the like has been used.
高速で印字するためにはフィルムの導電性を高くする必
要があり、そのために、カーボンブランクを高濃度にす
る方が望ましい。しかし、ポリカーボネート樹脂にカー
ボンブランクを高濃度で配合し、使用する場合には、フ
ィルムの機械的物性は、特に降伏点を示さず、破断点伸
度が小さい。In order to print at high speed, it is necessary to increase the conductivity of the film, and for this purpose, it is desirable to use a carbon blank with a high concentration. However, when a polycarbonate resin is blended with a carbon blank at a high concentration and used, the mechanical properties of the film do not particularly show a yield point and have a small elongation at break.
従って、スリット、蒸着、インク塗布等の後加工時及び
通電感熱記録用リボンとして使用しているとき、切断し
てしまう欠点を有していた。Therefore, it has the disadvantage that it may break during post-processing such as slitting, vapor deposition, ink application, etc., or when it is used as a ribbon for electrically conductive heat-sensitive recording.
そこで本発明者らは、かかる上記の問題点を解決すべく
鋭意検討した結果、ポリカーボネート樹脂とカーボンブ
ラックにエラストマーを添加した系からなる通電感熱記
録用爪抗層フィルムが降伏点を示し、破断点伸度が向上
し、更に後加工時、またはリボンとしての使用時に切断
しにくいことを見出して本発明に至った。As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention found that a nail anti-layer film for electrically conductive heat-sensitive recording, which is made of a polycarbonate resin and carbon black with an elastomer added thereto, shows a yield point. The inventors have discovered that the elongation is improved and that it is difficult to cut during post-processing or when used as a ribbon, leading to the present invention.
本発明は即ちポリカーボネート樹脂５０重量％〜８５重
量％、カーボンブランク１５重量％〜５０重鼠％及びポ
リカーボネート樹脂１００重量部に対し０．１〜２５重
看部のエラストマーからなる通電感熱記録用抵抗層フィ
ルムである。In other words, the present invention comprises a resistive layer for electrically conductive heat-sensitive recording comprising 50% to 85% by weight of polycarbonate resin, 15% to 50% by weight of carbon blank, and 0.1 to 25 parts by weight of elastomer per 100 parts by weight of polycarbonate resin. It's a film.
以下本発明の詳細な説明する。The present invention will be explained in detail below.
本発明で言うポリカーボネート樹脂とは具体的には、１
種類以上のビスフェノール化合物と、ホスゲンまたはジ
フェニルカーボネートのような炭酸エステルを反応させ
ることによって製造されるものである・ビスフェノール
化合物としては、具体的には、ビス−（４−ヒドロキシ
フェニル）メタン、１．１−ビス−（４−ヒドロキシフ
ェニル）メタン、１．１−ビス−（４−ヒドロキシフェ
ニル）プロパン、２．２−ビス−（４−ヒドロキシフェ
ニル）プロパン即ちビスフェノールＡ、 ２２−ビス−
（４−ヒドロキシフェニル）ブタン、２．２−ビス−（
４−ヒドロキシフェニル）ペンタン、２．２−ビス−（
４−ヒドロキシフェニル）−３−メチルブタン、２．２
−ビス−（４−ヒドロキシフェニル）ヘキサン、２，２
−ビス−（４〜ヒドロキシフエニル）−４−メチルペン
タン、１．１−ビス−（４−ヒドロキシフェニル）シク
ロペンクン、１．１−ビス−（４−ヒドロキシフェニル
）シクロヘキサン、ビス−（４−ヒドロキシ−３−メチ
ルフェニル）メタン、１，１−ビス−（４−ヒドロキシ
−３−メチルフェニル）エタン、２．２−ビス−（４−
ヒドロキシ−３−メチルフェニル）プロパン、２．２−
ビス−（４−ヒドロキシ−３−エチルフェニル）プロパ
ン、２゜２−ビス−（４−ヒドロキシ−３−ｉｓｏプロ
ピルフェニル）プロパン、２．２−ビス−（４−ヒドロ
キシ−３−ｓｅｃブチルフェニル）プロパン・’：：−
スー（４−ヒドロキシフェニル）フェニルメタ７．１．
１−ビス＝（４−ヒドロキシフェニル）１−フェニルエ
タン、１．１−ビス−（４−ヒドロキシフェニル１−１
−フェニルプロパン、ビス−（４−ヒドロキシフェニル
）ジフェニルエタン、ビス−（４−ヒドロキシフェニル
）ジヘンジルメタン、４，４° −ジヒドロキシジフェ
ニルエーテル、４，４゛ −ジヒドロキシジフェニルス
ルフォン、４，４−ジヒドロキシジフェニルスルフィド
、フェノールフタレイン等が挙げられる。Specifically, the polycarbonate resin referred to in the present invention includes 1
It is produced by reacting more than one type of bisphenol compound with a carbonate ester such as phosgene or diphenyl carbonate.Specifically, bisphenol compounds include bis-(4-hydroxyphenyl)methane, 1. 1-bis-(4-hydroxyphenyl)methane, 1.1-bis-(4-hydroxyphenyl)propane, 2.2-bis-(4-hydroxyphenyl)propane or bisphenol A, 22-bis-
(4-hydroxyphenyl)butane, 2,2-bis-(
4-hydroxyphenyl)pentane, 2,2-bis-(
4-hydroxyphenyl)-3-methylbutane, 2.2
-bis-(4-hydroxyphenyl)hexane, 2,2
-bis-(4-hydroxyphenyl)-4-methylpentane, 1.1-bis-(4-hydroxyphenyl)cyclopenkune, 1.1-bis-(4-hydroxyphenyl)cyclohexane, bis-(4-hydroxyphenyl) -3-methylphenyl)methane, 1,1-bis-(4-hydroxy-3-methylphenyl)ethane, 2,2-bis-(4-
Hydroxy-3-methylphenyl)propane, 2.2-
Bis-(4-hydroxy-3-ethylphenyl)propane, 2゜2-bis-(4-hydroxy-3-isopropylphenyl)propane, 2.2-bis-(4-hydroxy-3-secbutylphenyl) Propane・'：：−
Su(4-hydroxyphenyl)phenylmeth 7.1.
1-bis=(4-hydroxyphenyl)1-phenylethane, 1.1-bis-(4-hydroxyphenyl 1-1
-phenylpropane, bis-(4-hydroxyphenyl)diphenylethane, bis-(4-hydroxyphenyl)dihenzylmethane, 4,4°-dihydroxydiphenyl ether, 4,4°-dihydroxydiphenylsulfone, 4,4-dihydroxydiphenylsulfide, Examples include phenolphthalein.
ポリカーボネート樹脂の分子量としては、粘度平均分子
量（Ｍｖ）として通常２万〜２ｏ万（好ましくは２．５
万〜８万）のものが使用される。The molecular weight of the polycarbonate resin is usually 20,000 to 20,000 (preferably 2.5 million) as a viscosity average molecular weight (Mv).
80,000 to 80,000) are used.
本発明では、このようなポリカーボネート樹脂をカーボ
ンブラックとの合計量に対し通常５０重量％〜８５重量
％、望ましくは５５重量％〜８０重量％使用する。In the present invention, such polycarbonate resin is used generally in an amount of 50% to 85% by weight, preferably 55% to 80% by weight, based on the total amount with carbon black.
一方カーボンブランクとしては界雷性カーボンブラック
をはじめとして、通常のカーボンブランクのいずれかを
単独或は２種類以上を混合して使用できるが、特に好ま
しくは水銀ポロシーメーター法による細孔容積が２．５
ｃ ｃ ／ ｇ以下であって、また水銀ボロシーメー
ター法による細孔分布の最大ピーク位置が２００オング
ストロ一ム以上でかつＤＢＰ吸収量が２０〜２５０ ｍ
ｌ ／ １００ ｇのカーボンブラックである。この
カーボンブランクを１５重量％〜５０重量％、望ましく
は２０重壇％〜４５重量％配合する。カーボンブランク
の配合量が１５重量％より少ないと十分な４電性が発現
せずまた、カーボンブラックの配合量が５０重量％を越
えるとフィルムとして成形することが困難となり好まし
くない。On the other hand, as a carbon blank, any of ordinary carbon blanks including Kairai carbon black can be used alone or in combination of two or more types, but it is particularly preferable that the pore volume as measured by the mercury porosimeter method is 2. .5
c c / g or less, the maximum peak position of the pore distribution according to the mercury borosimetry method is 200 angstroms or more, and the DBP absorption amount is 20 to 250 m
l/100 g of carbon black. This carbon blank is blended in an amount of 15% to 50% by weight, preferably 20% to 45% by weight. If the amount of carbon blank is less than 15% by weight, sufficient tetraelectricity will not be exhibited, and if the amount of carbon black is more than 50% by weight, it will be difficult to form a film, which is not preferred.
更に、本発明で使用するエラストマーは例えばポリスチ
レン系、ポリオレフィン系、ポリウレタン系、ポリエス
テル系、ポリアミド系、１．２ポリブタジエン系、ポリ
塩化ビニル系、エチレン−酢酸ビニル系、天然ゴム系、
フッ素ゴム系、ポリイソブレン系、アクリル系等のいず
れのエラストマーも使用できる。このうち、特に弾性率
（ＪＩＳ、に６３０１）が１〜１００ＭＰ、のエラスト
マーが好ましい。エラストマーの添加量はポリカーボネ
ート樹脂１００重量部に対して０．１重量部〜２５重量
部、好ましくは１重量部〜１５重量部添加する。添加量
が０．１重量部より少ないと破断点伸度向上の効果がな
くなり、２５重量部より多く添加すると体積固有抵抗値
が高くなり高速での印字が不可能となる。Furthermore, the elastomers used in the present invention include, for example, polystyrene-based, polyolefin-based, polyurethane-based, polyester-based, polyamide-based, 1.2 polybutadiene-based, polyvinyl chloride-based, ethylene-vinyl acetate-based, natural rubber-based,
Any elastomer such as fluororubber-based, polyisoprene-based, acrylic-based, etc. can be used. Among these, elastomers having an elastic modulus (JIS 6301) of 1 to 100 MP are particularly preferred. The amount of the elastomer added is 0.1 to 25 parts by weight, preferably 1 to 15 parts by weight, per 100 parts by weight of the polycarbonate resin. If the amount added is less than 0.1 parts by weight, the effect of improving the elongation at break is lost, and if it is added more than 25 parts by weight, the volume resistivity becomes high, making high-speed printing impossible.
本発明のフィルムには、本組成へポリカーボネート樹脂
、カーボンブラック、エラストマーの他に熱安定剤、等
の各種添加剤を場合に応じ添加含有せしめたものも含ま
れる事は言うまでもない。It goes without saying that the films of the present invention include those in which various additives such as polycarbonate resins, carbon black, elastomers, and heat stabilizers are optionally added to the present composition.
本発明の抵抗層フィルムは上記カーボンブラックとポリ
カーボネート樹脂を均一混合した後、好ましくは溶液流
延法により厚さ３０μｍ以下好ましくは２０μｍ以下の
フィルム状に製膜して得られる。The resistance layer film of the present invention is obtained by uniformly mixing the carbon black and polycarbonate resin, and then forming the film into a film having a thickness of 30 μm or less, preferably 20 μm or less, preferably by a solution casting method.
溶液流延法は樹脂を溶解した有機溶剤系の中にカーボン
ブラック及びエラストマーを入れ、ボールミルなどで十
分混合し、カーボンブラックを分散させた粘ちょう溶液
をリバースコーターや、グラビアコーター ドクターブ
レード等を用いてポリエステルフィルムやガラス板等支
持体上に塗布し、溶剤を蒸発乾燥後、支持体から剥離し
た抵抗層フィルムを得る。In the solution casting method, carbon black and elastomer are placed in an organic solvent system in which resin has been dissolved, mixed thoroughly using a ball mill, etc., and a viscous solution in which carbon black is dispersed is poured using a reverse coater, gravure coater, doctor blade, etc. The film is coated on a support such as a polyester film or a glass plate, and after the solvent is evaporated and dried, a resistive layer film is obtained by peeling from the support.
本発明の抵抗層フィルムは、以下の（Ａ）ないしくＤ）
のいずれの方法にも用いることができる。The resistance layer film of the present invention has the following (A) or D)
It can be used in any of the following methods.
即ち、通電感熱記録方式には感熱転写記録方式として、
インク層／導電層／抵抗層の３層からなるリボン（Ａ）
を用いて、抵抗層側に印字用通電電極、導電層側に帰路
電極を取ることで回路を形成し、通電して抵抗層の抵抗
発熱を利用してインク層を紙に転写記録する方法。In other words, the current-carrying thermal recording system includes a thermal transfer recording system.
Ribbon (A) consisting of three layers: ink layer/conductive layer/resistance layer
A method of forming a circuit by placing a current-carrying electrode for printing on the resistive layer side and a return electrode on the conductive layer side, and transferring the ink layer to paper using the resistance heat generation of the resistive layer by applying electricity.
インク層／抵抗層の２層からなるリボン（Ｂ）を用いて
抵抗層側に印字用通電電極の２点以上の電掘間ので通電
して、抵抗層の抵抗発熱を利用してインク層を紙に転写
する方法。Using a ribbon (B) consisting of two layers, an ink layer and a resistive layer, electricity is applied between two or more electric holes of the current-carrying electrode for printing on the resistive layer side, and the ink layer is made using the resistance heat generation of the resistive layer. How to transfer onto paper.
又、感熱紙を使った感熱発色記録方式として、導電層／
抵抗層の２層からなるリボン（Ｃ）を用いて、抵抗層側
に印字用通電電極、導電層側に帰路電極を取ることで回
路を形成し、通電して抵抗層の抵抗発熱を利用して感熱
紙を発色させる方法。In addition, as a thermosensitive color recording method using thermal paper, a conductive layer/
Using a ribbon (C) consisting of two layers of resistive layers, a circuit is formed by placing a current-carrying electrode for printing on the resistive layer side and a return electrode on the conductive layer side, and conducts electricity to utilize the resistance heat generation of the resistive layer. How to make thermal paper color.
及び、抵抗層のみからなるリボン（Ｄ）を用いて印字用
通電電極の２点以上の電極間の通電による抵抗発熱を利
用して、感熱紙を発色させる方法などがあり、いずれの
方法も抵抗発熱を利用することが特徴である。There is also a method of coloring thermal paper by using a ribbon (D) consisting only of a resistive layer and utilizing the resistive heat generated by passing current between two or more electrodes of the current-carrying electrode for printing. It is characterized by the use of heat generation.
本発明の抵抗層フィルムは上記の各方法に対応して、そ
のまま単独で或は、導電層及びまたはインク層等を積層
形成して通電感熱転写に用いられる。The resistive layer film of the present invention can be used for electrical thermal transfer in accordance with each of the above-mentioned methods, either alone as it is or by forming a laminate with a conductive layer and/or an ink layer.
例えば、抵抗層、導電層及びインク層の三層からなる通
電感熱転写記録材料を作製する場合、上記方法にて得た
抵抗層フィルム上に導電層としてアルミニウム等の良導
電性物質の約５００〜１０００オングストロームの薄膜
を薄着等の方法により形成する。そして、約３〜５μｍ
のインク層をホットメルト法或は溶液法により導電層の
上に塗工する。For example, when producing an electrically conductive heat-sensitive transfer recording material consisting of three layers: a resistive layer, a conductive layer, and an ink layer, a conductive layer of about 50 to A thin film of 1000 angstroms is formed by a method such as thin deposition. And about 3-5 μm
An ink layer is applied onto the conductive layer by a hot melt method or a solution method.
該インク層は、公知の通電感熱転写記録材料に用いられ
ているものであれば特に限定されるものではなく、その
成分構成は例えば、パラフィンワックス、カルナバワッ
クス、変性ワックス等のワックスを約６０重量％、色材
顔料または染料を約２０重量％、樹脂を約２０重量％と
するのがよい。The ink layer is not particularly limited as long as it is used in known electrically conductive thermal transfer recording materials, and its component composition is, for example, approximately 60% by weight of wax such as paraffin wax, carnauba wax, modified wax, etc. %, the color pigment or dye should be about 20% by weight, and the resin should be about 20% by weight.
以上の様に各々各層を形成するが、各層の厚さは、イン
ク層／導電層／抵抗層が、それぞれ１〜１０、ｃｒｍｌ
ｏ、０１〜０．２．ｃｚｍ／３０層ｍ以下、好ましくは
、２〜５μｍ１０．０５〜０．１μｍ／２０μｍ以下と
するのがよい。Each layer is formed as described above, and the thickness of each layer is 1 to 10 crml for the ink layer/conductive layer/resistance layer, respectively.
o, 01-0.2. czm/30 layer m or less, preferably 2 to 5 μm10.05 to 0.1 μm/20 μm or less.
以下、実施例により本発明の詳細な説明するが、本発明
はその要旨を越えない限り下記の実施例に限定されるも
のではない。Hereinafter, the present invention will be explained in detail with reference to examples, but the present invention is not limited to the following examples unless it exceeds the gist thereof.
なお、実施例中本通電感熱記録用抵抗層フィルムの機械
的物性（降伏点強度（ＹＳ）、破断点強度（ＵＳ）、破
断点伸度（ＵＥ））は■インテスコ製Ｍｏｄｅｌ ２
００５を使用しＡＳＴＭ Ｄ８８２に準拠し測定した
。In addition, the mechanical properties (yield point strength (YS), breaking point strength (US), breaking point elongation (UE)) of the present resistance layer film for current-carrying heat-sensitive recording in the examples are ■ Intesco Model 2
005 in accordance with ASTM D882.
導電性は三菱油化■製Ｌａｒｅｓｔａ ＡＰＭＣＰ−
Ｔ４００を使用し、サンプル面積２５ｃｎ（、四探針法
にて体積固有抵抗を測定した。ガラス転位点温度（Ｔｇ
）はオリエンチック社自動動的粘弾性測定器ＲＨＥＯＶ
ＩＢＲＯＮ ＤＤＶＩＩ−ＥＡ型で測定周波数１１０
Ｈｚで測定した。The conductivity is Laresta APMCCP- manufactured by Mitsubishi Yuka ■.
Using T400, the sample area was 25cn, and the volume resistivity was measured by the four-probe method.The glass transition temperature (Tg
) is an automatic dynamic viscoelasticity measuring instrument RHEOV manufactured by Orientic Co., Ltd.
Measured frequency 110 with IBRON DDVII-EA type
Measured in Hz.
又、印字評価はできあがったリボンを印加電圧１２Ｖ、
パルス周波数１００ Ｈｚ 、パルス幅２ｍ５ｅｃ、ヘ
ッド走行速度１６ ｍｍ／ ｍ ｅ ｃの条件でｔ通紙
上に印字した結果を目視判定した。In addition, for printing evaluation, the completed ribbon was applied with an applied voltage of 12V,
The results of printing on t-passed paper under the conditions of a pulse frequency of 100 Hz, a pulse width of 2 m5 ec, and a head running speed of 16 mm/m ec were visually judged.
○実施例−１
ポリカーボネート樹脂（三菱化成−ノハレソクス ７０
３０Ａ Ｍｖ＝３万 グラニユール状）７２．５重量
％（１２，８０ｇ）、導電性カーボンブランク（三菱化
成ｎ３電性カーボンブラツク＃３２５０Ｂ）２７．５重
量％（４，８５ｇ＞、アクリルエラストマー（Ｒｏｈｍ
＆ Ｈａａｓ社ＫＭ３３０）をポリカーボネート樹脂
１００重量部に対して５重量部Ｃ０，６４ｇ）、溶媒と
してジクロロメタン１００ｇ、更に直径２．３８ｍｍの
クロムビーズ（■アシザワ製）５０ｍｌを２００ｍ１ガ
ラス瓶に仕込み密栓をした後、東洋精機社製試験分散機
で３時間振とうし、ポリカーボネート樹脂の溶解、導電
性カーボンブランクの分散を行った。○Example-1 Polycarbonate resin (Mitsubishi Kasei-Noharesox 70
30A Mv = 30,000 granules) 72.5% by weight (12.80g), conductive carbon blank (Mitsubishi Kasei n3 conductive carbon black #3250B) 27.5% by weight (4.85g>), acrylic elastomer (Rohm
& Haas KM330) to 100 parts by weight of polycarbonate resin, 100 g of dichloromethane as a solvent, and 50 ml of chromium beads with a diameter of 2.38 mm (manufactured by Ashizawa) in a 200 ml glass bottle, and the bottle was sealed tightly. The mixture was shaken for 3 hours using a test dispersion machine manufactured by Toyo Seiki Co., Ltd. to dissolve the polycarbonate resin and disperse the conductive carbon blank.
３時間後、振とうを止めガラス瓶を室温まで放置冷却し
た後、導電性カーボンブランクを分散した粘ちょう性樹
脂溶液を乾燥窒素雰囲気中でクリアランス１５０μｍの
ドクターナイフで７５μｍ厚のＰＥＴフィルム状に塗工
製膜した。After 3 hours, the shaking was stopped and the glass bottle was left to cool down to room temperature, and then the viscous resin solution in which the conductive carbon blank was dispersed was applied onto a 75 μm thick PET film using a doctor knife with a clearance of 150 μm in a dry nitrogen atmosphere. A film was formed.
塗工品は直ちに１００℃熱風循環式オーブンで５分間乾
燥し、溶媒を十分に乾燥させＰＥＴフィルムより抵抗層
用フィルムを剥離した。剥離したフィルムは機械的強度
、体積固有抵抗値を測定した。The coated product was immediately dried in a hot air circulation oven at 100° C. for 5 minutes to thoroughly dry the solvent, and the resistive layer film was peeled off from the PET film. The mechanical strength and volume resistivity of the peeled film were measured.
その結果、ＹＳ−７３０ｋｇ／ｃ１１１． ＵＳ＝ ７
２０ｋｇ／ｃａｔ、 Ｕ Ｅ ＝ ９．２％、体積固有
抵抗＝ １． ｌ ９Ω・１となった。印字評価では、
裂け、破断など発生せず、良好な印字が得られた。As a result, YS-730kg/c111. US=7
20kg/cat, U E = 9.2%, volume resistivity = 1. l It became 9Ω・1. In print evaluation,
Good printing was obtained without any tearing or breakage.
○比較例−１，２
実施例−１に於てカーボンブラック濃度を５５重量％及
び１０重量％とする以外は同様にして製膜した。Comparative Examples 1 and 2 Films were formed in the same manner as in Example 1 except that the carbon black concentrations were changed to 55% by weight and 10% by weight.
カーボンブランク濃度５５重足％では乾燥後は脆く、フ
ィルム状物を得ることができなかった。When the carbon blank concentration was 55% by weight, it was brittle after drying and a film-like product could not be obtained.
又、カーボンブラック濃度１０重量％では降伏点及び破
断点伸度の改良効果は認められたものの、体積固有抵抗
値が高く、本試験速度での印字は不可能だった。Further, at a carbon black concentration of 10% by weight, although the yield point and elongation at break were improved, the volume resistivity was high and printing at this test speed was impossible.
○実施例−２，３
実施例−１に於てＫＭ−３３０の添加量をポリカーボネ
ート樹脂１００重量部に対して１０重量部及び１５重量
部とする以外は同様にして製膜した。Examples 2 and 3 Films were formed in the same manner as in Example 1, except that the amount of KM-330 added was 10 parts by weight and 15 parts by weight based on 100 parts by weight of the polycarbonate resin.
得られたフィルムの物性の測定結果を表１に示した。印
字評価では、裂け、破断など発生せず、良好な印字が得
られた。Table 1 shows the measurement results of the physical properties of the obtained film. In the printing evaluation, good printing was obtained with no tearing or breakage.
○比較例−３，４
実施例−１に於てＫＭ−３３０の添加量をポリカーボネ
ート樹脂１００重量部に対して０ （無添加）及び３０
重量部とする以外は同様にして製膜した。○Comparative Examples-3 and 4 In Example-1, the amount of KM-330 added was 0 (no addition) and 30 parts by weight per 100 parts by weight of polycarbonate resin.
A film was formed in the same manner except for using parts by weight.
得られたフィルムの物性の測定結果を表１に示した。Ｋ
Ｍ−３３０の添加量を０重量部（無添加）にするとフィ
ルムの破断点伸度は小さく、降伏点強度を示さなかった
。一方ＫＭ−３３０の添加量を３０重量部にすると降伏
点強度を示し、破断点伸度の向上が認められたものの、
体積固有抵抗値が高く高速での印字が不可能だった。又
、印字後のフィルムに熱収縮のためと思われるしわの発
生が認められた。Table 1 shows the measurement results of the physical properties of the obtained film. K
When the amount of M-330 added was 0 parts by weight (no addition), the elongation at break of the film was small and no strength at yield was exhibited. On the other hand, when the amount of KM-330 added was 30 parts by weight, the yield point strength was exhibited and the elongation at break was improved.
High-speed printing was impossible due to the high volume resistivity. In addition, wrinkles were observed on the film after printing, which was thought to be due to heat shrinkage.
○実施例−４
実施例−１に於いてＫＭ−３３０の代わりにスチレン系
エラストマーとしてタフプレンＡ（旭化成社）を使用す
る以外は同様にして製膜し、得られたフィルムの機械的
強度体積固有抵抗値を測定した。○Example-4 A film was formed in the same manner as in Example-1 except that Tuffprene A (Asahi Kasei Co., Ltd.) was used as the styrene elastomer instead of KM-330, and the resulting film had mechanical strength and volume-specific properties. The resistance value was measured.
その結果、ＹＳ−７００ｋｇ／ｃｎｔ、 ＵＳ＝６８０
ｋｇ／ｃｒｌ、 Ｕ Ｅ ＝ ８．０％、体積固有抵抗
＝１．１０Ω・印となった。印字評価では、裂け、破断
など発生せず、良好な印字が得られた。As a result, YS-700kg/cnt, US=680
kg/crl, U E = 8.0%, and volume resistivity = 1.10Ω·mark. In the printing evaluation, good printing was obtained with no tearing or breakage.
度で配合したフィルムに於いても後加工時、印字時に破
断しに（い高速での通電感熱転写記録が得られる。Even with a film formulated at high speed, high-speed electrical thermal transfer recording can be obtained without breaking during post-processing or printing.
表１Table 1
Claims (1)
ンブラック１５〜５０重量％及びポリカーボネート樹脂
１００重量部に対し０．１〜２５重量部のエラストマー
からなる通電感熱記録用抵抗層フィルム。(1) A resistive layer film for electrical heat-sensitive recording comprising 50-85% by weight of polycarbonate resin, 15-50% by weight of carbon black, and 0.1-25 parts by weight of elastomer per 100 parts by weight of polycarbonate resin.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21675988A JPH0263890A (en) | 1988-08-31 | 1988-08-31 | Resistance layer film for electrothermal recording |
| EP19890115835 EP0356962A3 (en) | 1988-08-31 | 1989-08-28 | Film for a resistance layer for an electric-thermal print system |
| US07/399,005 US5013606A (en) | 1988-08-31 | 1989-08-28 | Film for a resistance layer for an electric-thermal print system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21675988A JPH0263890A (en) | 1988-08-31 | 1988-08-31 | Resistance layer film for electrothermal recording |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0263890A true JPH0263890A (en) | 1990-03-05 |
Family
ID=16693466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21675988A Pending JPH0263890A (en) | 1988-08-31 | 1988-08-31 | Resistance layer film for electrothermal recording |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0263890A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5366110A (en) * | 1990-11-29 | 1994-11-22 | Kabushiki Kaisha Ace Denken | Game token dispenser |
-
1988
- 1988-08-31 JP JP21675988A patent/JPH0263890A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5366110A (en) * | 1990-11-29 | 1994-11-22 | Kabushiki Kaisha Ace Denken | Game token dispenser |
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