JPH0259777B2 - - Google Patents

Info

Publication number
JPH0259777B2
JPH0259777B2 JP9144684A JP9144684A JPH0259777B2 JP H0259777 B2 JPH0259777 B2 JP H0259777B2 JP 9144684 A JP9144684 A JP 9144684A JP 9144684 A JP9144684 A JP 9144684A JP H0259777 B2 JPH0259777 B2 JP H0259777B2
Authority
JP
Japan
Prior art keywords
paper
resin
matting agent
adhesives
recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP9144684A
Other languages
Japanese (ja)
Other versions
JPS60234880A (en
Inventor
Hiroshi Takeda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kimoto Co Ltd
Original Assignee
Kimoto Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimoto Co Ltd filed Critical Kimoto Co Ltd
Priority to JP9144684A priority Critical patent/JPS60234880A/en
Publication of JPS60234880A publication Critical patent/JPS60234880A/en
Publication of JPH0259777B2 publication Critical patent/JPH0259777B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports

Description

【発明の詳細な説明】 本発明は、コンピユーターのアウトプツト用
紙、各種証券類及び預金通帳等として有効な記録
用紙に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a recording paper useful as a computer output paper, various securities, a deposit passbook, and the like.

最近のOA機器の発展に伴つて、各種の伝票
類、証券類及び預金通帳等の記入はコンピユータ
ーによつて行なわれることが多くなつている。
With the recent development of office automation equipment, entries in various documents, securities, bankbooks, etc. are increasingly performed using computers.

特にキヤツシユカード化の普及によつて預金通
帳などは、その記録の頻度が非常に増加してい
る。前記の預金通帳を例にとれば、簡単に破損し
ないようにするため、一般にその記録用紙は、比
較的厚手のものが使用されているので、紙の枚数
が少なく、直ぐに余白がなくなつてしまい、その
都度新規な通帳に書き改めなければならず、その
ための事務手続に大変手間かかかる欠陥があつ
た。
In particular, with the spread of cash cards, the frequency of recording in bankbooks and the like has increased significantly. Taking the above-mentioned bankbook as an example, in order to prevent it from being easily damaged, relatively thick recording paper is generally used, so the number of sheets is small and the margins quickly run out. , each time a new passbook had to be written, and there was a flaw in the clerical procedures that required a lot of time and effort.

前記した通帳用紙等を薄くして丈夫な材料に転
換するためにポリエステル等のプラスチツクフイ
ルムの使用も試みられているが、ポリエステルフ
イルムをそのまま使用すると薄くて強度のあるも
のが得られるが、反りが出てしまつてコンピユー
ター等で記録することができない欠陥を生じた。
Attempts have been made to use plastic films such as polyester to make passbook paper thinner and more durable. However, if polyester film is used as is, a thin and strong product can be obtained, but it tends to warp. This resulted in a defect that could not be recorded on a computer, etc.

更にまた前記のプラスチツクフイルムを静電記
録用等として使用すると複写機の熱などによつて
フイルム表面に凹凸が生じたり、静電気障害によ
るごみ等が付着して鮮明な画像記録が得られな
く、作業性も悪いものであつた。
Furthermore, when the above-mentioned plastic film is used for electrostatic recording, etc., the film surface becomes uneven due to the heat of the copying machine, etc., and dust etc. adhere to it due to electrostatic damage, making it difficult to record clear images. The sex was also bad.

本発明者等は前記に鑑みて、温度、湿度の影響
により反つたり、しわが発生することなく、しか
も静電記録用紙として使用した場合トナーの密着
性がよく、鮮明な画像記録が得られるような薄い
記録用紙を提供すべく種々研究を進めた結果、ポ
リエステルフイルムの両面に薄い和紙を貼着し、
該和紙の上に白色顔料入り樹脂マツト層、更にそ
の上に導電層を設けることによつて、反りがな
く、記録し易く、トナーの密着性が良好な記録用
紙が得られることを知見して本発明に到達した。
In view of the above, the inventors of the present invention have found that the paper does not warp or wrinkle due to the effects of temperature and humidity, and when used as electrostatic recording paper, has good toner adhesion and provides clear image recording. As a result of various research efforts to provide a thin recording paper like this, we pasted thin Japanese paper on both sides of a polyester film.
It was discovered that by providing a white pigmented resin mat layer on the washi paper and further providing a conductive layer thereon, a recording paper that does not warp, is easy to record on, and has good toner adhesion can be obtained. We have arrived at the present invention.

すなわち、本発明は、ポリエステルフイルムの
両面に接着剤を介して薄い和紙をラミネートし、
前記和紙の上に白色顔料もしくは体質顔料を含有
する合成樹脂マツト剤層を設け、更にその上に導
電層を形成せしめて成ることを特徴とする記録用
紙である。
That is, the present invention laminates thin Japanese paper on both sides of a polyester film with an adhesive,
The recording paper is characterized in that a synthetic resin matting agent layer containing a white pigment or an extender pigment is provided on the Japanese paper, and a conductive layer is further formed thereon.

本発明で使用するポリエステルフイルムはその
厚さが10〜188μのものである。
The polyester film used in the present invention has a thickness of 10 to 188μ.

前記のポリエステルフイルムにラミネートする
薄い和紙とは、例えば楮(こうぞ)、麻、三椏
(みつまた)、雁皮(がんぴ)等を原料として、こ
れを機械漉きによつて製造したものであり、その
厚さは約8〜20g/m2で、好ましくは10〜15g/
m2なある。
The thin Japanese paper to be laminated to the polyester film mentioned above is manufactured by machine-making using, for example, paper mulberry, hemp, mitsumata, ganpi, etc. as raw materials. Its thickness is about 8-20g/ m2 , preferably 10-15g/m2.
It's m 2 .

前記した和紙をポリエステルフイルムにラミネ
ートするために使用される接着剤としては、例え
ば尿素樹脂系接着剤、フエノール系接着剤、レゾ
ルシノール系接着剤、エポキシ系接着剤、ポリウ
レタン系接着剤、ポリエステル系接着剤、イソシ
アネート系接着剤、酢酸ビニル系接着剤、アクリ
ル系接着剤、シアノアクリレート系接着剤、共重
合ナイロン系接着剤および変性ゴム系接着剤等が
挙げられる。
Examples of adhesives used to laminate the above-mentioned Japanese paper to a polyester film include urea resin adhesives, phenol adhesives, resorcinol adhesives, epoxy adhesives, polyurethane adhesives, and polyester adhesives. , isocyanate adhesives, vinyl acetate adhesives, acrylic adhesives, cyanoacrylate adhesives, copolymerized nylon adhesives, and modified rubber adhesives.

そしてまた前記の和紙の上に設ける白色顔料を
含有する合成樹脂マツト剤層は、二酸化チタン、
亜鉛華、酸化アンチモン、硫化亜鉛等の隠蔽力の
ある白色顔料を、微粉末シリカ、アルミナ、炭酸
カルシウム等の体質顔料としてマツト剤と混合
し、この混合物もしくはマツト剤単独を塩化ビニ
ル樹脂、塩化ビニル−酢酸ビニル共重合体、アク
リル樹脂、ポリエステル樹脂、ニトロセルロース
樹脂、塩化ビニリデン樹脂等の合成樹脂に配合し
て塗工剤としたものを塗工することによつて設け
られる。
Furthermore, the synthetic resin matting agent layer containing white pigment provided on the above-mentioned Japanese paper is made of titanium dioxide,
White pigments with hiding power such as zinc white, antimony oxide, and zinc sulfide are mixed with matting agents as extender pigments such as finely powdered silica, alumina, and calcium carbonate, and this mixture or the matting agent alone is mixed with vinyl chloride resin, vinyl chloride, etc. - It is provided by coating a coating agent mixed with a synthetic resin such as a vinyl acetate copolymer, acrylic resin, polyester resin, nitrocellulose resin, or vinylidene chloride resin.

更にまた本発明に於いて前記マツト剤層の上に
設ける導電層は、トナーの接着性のよい導電層で
あり、具体的にはポリ(2−メタクリロイルオキ
シエチルトリメチルアンモニウムクロライド、ポ
リ(N−アクリルアミドプロピル−3−トリメチ
ルアンモニウムクロライド)、ポリ(N、N−ジ
メチル−3.5−メチレンピペリジウムクロライド)
ポリアリルトリメチルアンモニウムクロライド、
ポリビニルベンジルトリメチルアンモニウムクロ
ライド等の導電剤をアクリル系樹脂、エチレン−
酢酸ビニル共重合体、ポリビニルブチラール樹
脂、ポリスチレン樹脂、シリコーン樹脂、ポリエ
ステル樹脂、塩化ビニル−酢酸ビニル共重合体、
セルロース誘導体樹脂に配合し、この配合物を水
又は有機溶媒に溶解または分散せしめた塗工液を
塗工、乾燥することによつて設けることができ
る。
Furthermore, in the present invention, the conductive layer provided on the matting agent layer is a conductive layer with good toner adhesion, and is specifically made of poly(2-methacryloyloxyethyltrimethylammonium chloride, poly(N-acrylamide), etc.). propyl-3-trimethylammonium chloride), poly(N,N-dimethyl-3.5-methylenepiperidium chloride)
polyallyltrimethylammonium chloride,
A conductive agent such as polyvinylbenzyltrimethylammonium chloride is used with acrylic resin, ethylene-
Vinyl acetate copolymer, polyvinyl butyral resin, polystyrene resin, silicone resin, polyester resin, vinyl chloride-vinyl acetate copolymer,
It can be provided by blending it with a cellulose derivative resin, applying a coating liquid in which this blend is dissolved or dispersed in water or an organic solvent, and drying.

本発明においてポリエステルフイルムに和紙を
ラミネートするには、ポリエステルフイルム面に
接着剤をロールコート法、リバースロールコート
法、メイヤバーコート法又はグラビアコート法等
の通常の塗布方法で塗布し、その接着剤塗布面に
和紙を両面からラミネートし、常温ないし50〜80
℃乾風乾燥することによつてなされる。
In the present invention, in order to laminate Japanese paper to a polyester film, an adhesive is applied to the surface of the polyester film using a conventional coating method such as roll coating, reverse roll coating, Mayer bar coating, or gravure coating. Laminate Japanese paper on both sides of the coated surface and heat at room temperature or 50~80℃.
It is done by air drying at ℃.

更にこのラミネートした和紙の上に設ける合成
樹脂マツト剤層及び導電層も、接着剤を塗工する
のと同様と塗工法によつて各々の塗工剤を塗工、
乾燥することによつて設けることができる。
Furthermore, the synthetic resin matting agent layer and conductive layer to be provided on the laminated Japanese paper are coated with each coating agent using the same coating method as that used for applying adhesive.
It can be provided by drying.

以上の構成から得られる本発明の記録用紙は、
ポリエステルフイルムをサンドウチツチとしてそ
の両面に薄い和紙がラミネートしてあるためベー
ス厚プラス40〜80μで、例えばベース厚12μ使用
の場合は50〜60μとなり、薄いにもかかわらず非
常に強靭で、温度、湿度の影響によつて反ること
がない。
The recording paper of the present invention obtained from the above configuration is as follows:
Since the polyester film is used as a sandwich and thin Japanese paper is laminated on both sides, the base thickness is plus 40 to 80μ.For example, if a base thickness of 12μ is used, it will be 50 to 60μ.Although it is thin, it is extremely strong and can withstand temperature and humidity. It will not warp under the influence of

またポリエステルフイルム単独と違いフイルム
面に和紙が貼着してあり、しかもその和紙の上に
は、白色顔料、もしくは体質顔料、マツト剤を含
有する合成樹脂マツト剤層が設けてあるため、文
字や数字の印字が鮮明に行なえ、加筆も可能であ
り、裏に記録した文字等が透けて見える心配がな
い。白色顔料を混合しないでマツト剤を単独に使
用してマツト剤層が設けてあるものは透明度を有
するため記録材料として使用したもののコピー性
も付加される。
Also, unlike polyester film alone, Japanese paper is attached to the film surface, and a synthetic resin matting agent layer containing white pigment, extender pigment, and matting agent is provided on top of the Japanese paper. Numbers can be clearly printed, additions can be made, and there is no need to worry about characters recorded on the back showing through. A material in which a matting agent layer is provided by using a matting agent alone without mixing a white pigment has transparency, which improves copyability when used as a recording material.

従つて、本発明に記録用紙を、例えば預金通帳
等の用紙として使用すると、従来の預金通帳より
大幅に枚数を増やすことができる。
Therefore, if the recording paper of the present invention is used as a paper for a deposit passbook, for example, the number of sheets can be significantly increased compared to conventional deposit passbooks.

又、コピー性を有する記録材料として使用する
場合は加筆も容易となり、例えば、現況図を記録
し計画線を加筆するとか、機械図面を記録し、一
部加筆もしくは消去後加筆することにより図面の
修正追加が容易となり、製図材料としての使用も
可能となる。
In addition, when used as a recording material that can be copied, it is easy to make additions to the drawing. For example, by recording the current state drawing and adding planned lines, or by recording a mechanical drawing and adding a part or erasing it and then adding it. It becomes easy to make corrections and additions, and it also becomes possible to use it as a drafting material.

更にまた、表面には導電層が設けてあるため、
乾式電子写真機を用いて複写したとき、静電障害
にもとづく画像の乱れや転写不良がなく、しかも
給紙トレイからの重送が起らず、複写用紙として
も優れた性能を示し、作業性も極めて良好であつ
た。以下、実施例により本発明を具体的に説明す
る。
Furthermore, since a conductive layer is provided on the surface,
When copying using a dry type electrophotographic machine, there is no image distortion or transfer failure due to electrostatic interference, there is no double feeding from the paper feed tray, and the paper exhibits excellent performance as a copying paper, making it easy to work with. It was also very good. Hereinafter, the present invention will be specifically explained with reference to Examples.

実施例 厚さ25μのポリエステルフイルムの両面にアク
リル樹脂エマルジヨン型接着剤をロールコーター
にて3g/m2(ドライ)位なるように塗布し、指
触乾燥後、その両面に和紙(13g/m2)をラミネ
ートし、45℃で3分間乾風乾燥する。
Example: Apply an acrylic resin emulsion type adhesive to both sides of a 25μ thick polyester film using a roll coater to a coating thickness of about 3g/m 2 (dry), and after drying to the touch, apply Japanese paper (13g/m 2 ) to both sides. ) and dry with dry air at 45℃ for 3 minutes.

次いで、ラミネートした和紙の表面に、塩化ビ
ニル−酢酸ビニル共重合体7重量部、スチレン樹
脂2重量部、シリコン樹脂1重量部、微粉末シリ
カ2重量部、二酸化チタン5重量部およびメチル
エチルケトン60重量部/トルオール40重量部から
塗工液を1g/m2(ドライ)塗布して白色顔料を
含有する合成樹脂マツト剤層を設けた。
Next, 7 parts by weight of vinyl chloride-vinyl acetate copolymer, 2 parts by weight of styrene resin, 1 part by weight of silicone resin, 2 parts by weight of fine powder silica, 5 parts by weight of titanium dioxide, and 60 parts by weight of methyl ethyl ketone were then applied to the surface of the laminated Japanese paper. A coating solution containing 40 parts by weight of toluene was applied at 1 g/m 2 (dry) to provide a synthetic resin matting agent layer containing a white pigment.

次いで前記マツト剤層の表面にポリビニルベン
ジルトリメチルアンモニウムクロライド3.4重量
部、ポリビニルブチラール樹脂3重量部、および
トルエン80重量部から成る塗工液1g/m2を塗
布、乾燥して導電層を設けることによつて記録用
紙を得た。
Next, 1 g/m 2 of a coating solution consisting of 3.4 parts by weight of polyvinylbenzyltrimethylammonium chloride, 3 parts by weight of polyvinyl butyral resin, and 80 parts by weight of toluene was applied to the surface of the matting agent layer and dried to form a conductive layer. I then obtained a recording sheet.

この記録用紙は、反りがなく、コンピユーター
出力端末による印字性にも優れており、しかも薄
いので、預金通帳に用いるとボリユームが従来の
ものと同じで紙の枚数を大幅に増やすことができ
る利点がある。
This recording paper does not warp, has excellent printability on computer output terminals, and is thin, so when used in a bankbook, it has the advantage of being able to significantly increase the number of sheets of paper with the same volume as conventional paper. be.

Claims (1)

【特許請求の範囲】[Claims] 1 ポリエステルフイルムの両面に接着剤を介し
て薄い和紙をラミネートし、前記和紙の上に白色
顔料もしくは体質顔料を含有する合成樹脂マツト
剤層を設け、更にその上に導電層を形成せしめて
成ることを特徴とする記録用紙。
1. Thin Japanese paper is laminated on both sides of a polyester film via an adhesive, a synthetic resin matting agent layer containing a white pigment or an extender pigment is provided on the Japanese paper, and a conductive layer is further formed on top of the matting agent layer. Recording paper featuring.
JP9144684A 1984-05-08 1984-05-08 Recording paper Granted JPS60234880A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9144684A JPS60234880A (en) 1984-05-08 1984-05-08 Recording paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9144684A JPS60234880A (en) 1984-05-08 1984-05-08 Recording paper

Publications (2)

Publication Number Publication Date
JPS60234880A JPS60234880A (en) 1985-11-21
JPH0259777B2 true JPH0259777B2 (en) 1990-12-13

Family

ID=14026589

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9144684A Granted JPS60234880A (en) 1984-05-08 1984-05-08 Recording paper

Country Status (1)

Country Link
JP (1) JPS60234880A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH064315B2 (en) * 1988-12-01 1994-01-19 ソマール株式会社 Synthetic resin film / paper laminate

Also Published As

Publication number Publication date
JPS60234880A (en) 1985-11-21

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