JPH0257572A - Plastic film for wrapping - Google Patents
Plastic film for wrappingInfo
- Publication number
- JPH0257572A JPH0257572A JP265789A JP265789A JPH0257572A JP H0257572 A JPH0257572 A JP H0257572A JP 265789 A JP265789 A JP 265789A JP 265789 A JP265789 A JP 265789A JP H0257572 A JPH0257572 A JP H0257572A
- Authority
- JP
- Japan
- Prior art keywords
- food
- film
- plastic film
- water
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002985 plastic film Substances 0.000 title claims abstract description 19
- 229920006255 plastic film Polymers 0.000 title claims abstract description 19
- 238000004806 packaging method and process Methods 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 8
- 235000013305 food Nutrition 0.000 abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 12
- 239000005977 Ethylene Substances 0.000 abstract description 12
- 239000004698 Polyethylene Substances 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000000034 method Methods 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Bag Frames (AREA)
- Wrappers (AREA)
Abstract
Description
【発明の詳細な説明】
（発明の技術分野）
本発明は無数の微小孔を有する包装用プラスチックフィ
ルムに関する。DETAILED DESCRIPTION OF THE INVENTION (Technical Field of the Invention) The present invention relates to a packaging plastic film having numerous micropores.
（従来技術とその問題点）
非親水性のプラスチックフィルム、たとえば、ポリエチ
レン系フイルム、塩化ビニリデン系フイルム、塩化ビニ
ル系フイルムは良く知られており、包装用、特に食品包
装用として広く使用されている。これらのフイルムで食
品、特に生鮮食品を包装封閉（以後包装容器と称する）
すると、保存中に短時間で鮮度が悪化する欠点がある。(Prior art and its problems) Non-hydrophilic plastic films, such as polyethylene films, vinylidene chloride films, and vinyl chloride films, are well known and widely used for packaging, especially for food packaging. . These films are used to package and seal foods, especially fresh foods (hereinafter referred to as packaging containers).
This has the disadvantage that freshness deteriorates within a short period of time during storage.
これは包装容器内で生鮮食品が少し変質して、エチレン
ガス、アンモニアガスが発生し、包装容器内に次第に蓄
積し、このガスが変質を更に大きくし、発生ガスは加速
的に増大して包装容器内に充満するため、食品の鮮度が
短時間で著しく悪化するものと思れる。This is because the fresh food deteriorates a little inside the packaging container, generating ethylene gas and ammonia gas, which gradually accumulate inside the packaging container.This gas further increases the deterioration, and the generated gas increases at an accelerated pace. The freshness of the food is likely to deteriorate significantly in a short period of time as the container is filled with water.
（問題点を解決するための手段）
本発明はこの問題を解決するために、食品、特に生鮮食
品を包装封閉し、包装容器内の水分は保持し、発生する
エチレンガス、アンモニアガス等は包装容器外に排除す
る方法を創案することにより成功したものである。(Means for solving the problem) In order to solve this problem, the present invention packages and seals foods, especially fresh foods, retains moisture in the packaging container, and removes generated ethylene gas, ammonia gas, etc. This success was achieved by devising a method to remove it from the container.
即ち、本発明は非親水性のプラスチックフィルムに無数
の微小孔を設けることを特徴とするものである。That is, the present invention is characterized in that a non-hydrophilic plastic film is provided with numerous micropores.
更に非親水性のプラスチックフィルムに６〜１４ミクロ
ンの波長の遠赤外線を放射しやすいセラミックス又は（
および）ゼオライト微粉末を含有する前記プラスチック
フィルムに無数の微小孔を設けることを特徴とするもの
である。Furthermore, non-hydrophilic plastic films are made of ceramics or (
and) the plastic film containing fine zeolite powder is provided with numerous micropores.
本発明は、従来の非親水性のプラスチックフィルムに無
数の微小孔を設けているため、このフイルムで食品、特
に生鮮食品を包装封閉すると、食品から発生するエチレ
ンガス、アンモニアガス、水分等が包装容器の無数の微
小孔を通して外部に逸散する。しかし、無数の微小孔は
極めて小さいため、直ぐに微小孔には水膜が形成される
。そして、その後はエチレンガス、アンモニアガスは微
小孔に形成された水膜を通して引き続き外部に逸散して
蓄積することがなく、水分は水膜に遮ぎられて包装容器
外に逸散することが殆どなくなる。In the present invention, a conventional non-hydrophilic plastic film is provided with countless micropores, so when food, especially fresh food, is wrapped and sealed with this film, ethylene gas, ammonia gas, moisture, etc. generated from the food are removed from the packaging. It escapes to the outside through numerous micropores in the container. However, since the countless micropores are extremely small, a water film is immediately formed in the micropores. After that, ethylene gas and ammonia gas will continue to escape to the outside through the water film formed in the micropores and will not accumulate, and the water will be blocked by the water film and will not escape outside the packaging container. Almost disappears.
このため、包装容器内の食品の水分は減少することが殆
どなく乾燥することがない。しかも、包装容器内には、
発生したエチレンガス、アンモニアガスが殆ど存在しな
いため、食品特に生鮮食品の保存性は著しく大になる
プラスチックフィルムに６〜１４ミクロンの波長の遠赤
外線を放射しやすいセラミックス微粉末が加えられてい
る場合は、この遠赤外線が絶えず食品に放射しており、
食品の外部と内部に均一に同時に浸透し、食品内部の水
分を活性化して、食品を殺菌すると共に熟成して美味に
なる。Therefore, the moisture content of the food in the packaging container hardly decreases and the food does not dry out. Moreover, inside the packaging container,
Since there is almost no generated ethylene gas or ammonia gas, the shelf life of food, especially fresh food, is significantly increased.When fine ceramic powder, which easily emits far infrared rays with a wavelength of 6 to 14 microns, is added to the plastic film. This far infrared rays are constantly emitted to food,
It permeates both the outside and the inside of food at the same time, activating the moisture inside the food, sterilizing the food, and ripening it to make it more delicious.
しかも、前記のようにプラスチックフィルムに無数の微
小孔が設けられているため、発生したエチレンガス、ア
ンモニアガスは包装容器外に逸散して熟成は殆ど進行せ
ず、保存性は更に著しく大になる。Moreover, as mentioned above, the plastic film has countless micropores, so the generated ethylene gas and ammonia gas escape outside the packaging container, and aging hardly progresses, resulting in significantly longer shelf life. Become.
次に前記セラミックス微粉末の代りにゼオライト微粉末
を使用する場合は、ゼオライト微粉末が殺菌性、吸ガス
性、吸湿性、イオン交換性を有しているため、保存中に
食品から発生するエチレンガス、アンモニアガスはゼオ
ライトに吸着されて保存性が大になる。しかも、プラス
チックフィルムに無数の微小孔が設けられているため、
相乗効果を表し、前記のように発生したエチレンガス、
アンモニアガスは包装容器外に更に逸散させて排除し、
保存性は更に著しく大になる。Next, when using zeolite fine powder instead of the ceramic fine powder, zeolite fine powder has bactericidal, gas-absorbing, hygroscopic, and ion-exchanging properties, so ethylene is generated from foods during storage. Gas and ammonia gas are adsorbed by zeolite and have a long shelf life. Moreover, because the plastic film has countless micropores,
Representing a synergistic effect, the ethylene gas generated as described above,
Ammonia gas is further dissipated outside the packaging container and eliminated.
Preservability is also significantly increased.
又前記セラミックスとゼオライト微粉末を併用すると、
更に大きな効果が現れる。Also, when the ceramics and zeolite fine powder are used together,
An even greater effect will appear.
非水性のプラスチックフィルムは、ポリオレフィン系、
塩化ビニリデン系、塩化ビニル系のレジンが普通である
が、生産的にも、経済的にも、効果の面からもポリオレ
フィン系、特にポリエチレンが最も好しい。Non-aqueous plastic films are polyolefin-based,
Vinylidene chloride-based and vinyl chloride-based resins are common, but polyolefin-based resins, particularly polyethylene, are most preferred from the viewpoints of production, economy, and effectiveness.
無数の微小孔は小さくなければならない。大きくなると
、微小孔に水膜が形成されにくくなり、水分も発生した
エチレンガス、アンモニアガスと共に包装容器外に逸散
してしまい、本発明の目的を達成することが難しくなる
からである。The countless micropores must be small. This is because if the size of the pores becomes large, it becomes difficult to form a water film in the micropores, and moisture also escapes to the outside of the packaging container together with the generated ethylene gas and ammonia gas, making it difficult to achieve the object of the present invention.
プラスチックフィルムに無数の微小孔を設ける方法は、
本発明の目的を達成することができる方法ならば任意で
あるが、たとえば、無数の微細な針を有するロール又は
板で押すことによって設けるのが普通である。The method of creating countless micropores in a plastic film is as follows.
Although any method can be used as long as the object of the present invention can be achieved, it is usually provided by pressing with a roll or plate having numerous fine needles, for example.
遠赤外線を放射しやすいセラミックス微粉末は天然又は
合成のものが普通であり、多孔質のものはより好しい。Ceramic fine powders that easily emit far-infrared rays are usually natural or synthetic, and porous ones are more preferable.
ジルコン、アルミナ、シリカ等を主成分としたものが好
しく、６〜１４ミクロン、好しくは、８〜１２ミクロン
の波長の遠赤外線を放射しやすいものが適当であり、（
株）新生バイオ、日本セラム（株）のものが一般的であ
る。Those mainly composed of zircon, alumina, silica, etc. are preferred, and those that easily emit far infrared rays with a wavelength of 6 to 14 microns, preferably 8 to 12 microns, are suitable.
Products from Shinsei Bio Co., Ltd. and Nippon Serum Co., Ltd. are common.
６ミクロン未満でも、１４ミクロンを超える波長のもの
でも本効果が小さくなる。This effect becomes small even if the wavelength is less than 6 microns or exceeds 14 microns.
ゼオライト微粉末は天然又は合成ゼオライト、大谷石又
はその類似物が適当である。これに２価以上の金属、た
とえば、Ｎｉ，Ｃｏ，Ａｇ，Ｃａ，Ｚｎ，Ｚｒ，Ａｕ等
のイオンを吸着させてイオン交換させたものが殺菌性が
強い。The fine zeolite powder is suitably natural or synthetic zeolite, Oya stone, or its analogues. A product obtained by adsorbing and ion-exchanging ions of divalent or higher-valent metals, such as Ni, Co, Ag, Ca, Zn, Zr, and Au, has strong sterilizing properties.
セラミックス又は（および）ゼオライト微粉末をプラス
チックフィルムに含有する方法はプラスチック粉末と混
合又は加熱混合して常法により作るのが普通である。The method for incorporating ceramics or (and) zeolite fine powder into a plastic film is usually to mix it with plastic powder or to mix it with heat, using a conventional method.
その量はレジンフイルムに対して、０．５％以上が適当
である。The amount thereof is suitably 0.5% or more based on the resin film.
実施例
ポリエチレンを常法によりポリエチレンフイルムにする
。これをＡとする。Example Polyethylene is made into a polyethylene film by a conventional method. Let this be A.
ポリエチレンに合成ゼオライト微粉末３％、８〜１２ミ
クロンの波長の遠赤外線を放射しやすいセラミックス微
粉末２％を加えて常法によりポリエチレンフイルムにす
る。これをＢとする。3% synthetic zeolite fine powder and 2% ceramic fine powder that easily emits far infrared rays with a wavelength of 8 to 12 microns are added to polyethylene to form a polyethylene film by a conventional method. Let this be B.
次にこれらを夫々無数の微細針を植えつけたロールに通
過させてフイルムに無数の微小孔を造る。Next, each film is passed through rolls in which countless fine needles are planted, creating countless micropores in the film.
この微小孔は極めて小さく、フイルムの片面に水を加え
たが、水は漏れなかった。The micropores were so small that water did not leak out even when water was added to one side of the film.
次に、生野菜を無数の微小孔を有するＡとＢのフイルム
で夫々包装封閉した。Next, the raw vegetables were wrapped and sealed with films A and B each having numerous micropores.
比較のため、無数の微小孔を有しないＡフイルムで生野
菜を同様に包装封閉した。For comparison, raw vegetables were similarly wrapped and sealed with A film that did not have numerous micropores.
次にこれらを室温で保存した。These were then stored at room temperature.
このテストを５回繰り返した。This test was repeated five times.
この結果、無数の微小孔を有しない従来のＡフイルムの
鮮度保持性を１とすると、無数の微小孔を有するＡフイ
ルムは、２即ち、２倍と大になり、無数の微小孔を有す
るＢフイルムは、３、即ち、３倍となり、明らかに優れ
ていた。As a result, if the freshness retention of the conventional A film, which does not have countless micropores, is 1, then the A film, which has countless micropores, is 2 times larger, and the B film, which has countless micropores, is twice as large. The film increased by 3, or 3 times, and was clearly superior.
Claims (1)
設けた包装用プラスチックフィルム。 ２、非親水性のプラスチックフィルムに６〜１４ミクロ
ンの波長の遠赤外線を放射しやすいセラミックス又は（
および）ゼオライト微粉末を含有する前記プラスチック
フィルムに無数の微小孔を設けた包装用プラスチックフ
ィルム。[Scope of Claims] 1. A plastic film for packaging in which numerous micropores are provided in a non-hydrophilic plastic film. 2. Ceramics or (
and) A plastic film for packaging, wherein the plastic film containing fine zeolite powder is provided with countless micropores.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP265789A JPH0257572A (en) | 1989-01-10 | 1989-01-10 | Plastic film for wrapping |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP265789A JPH0257572A (en) | 1989-01-10 | 1989-01-10 | Plastic film for wrapping |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63207513A Division JPH0257140A (en) | 1988-08-22 | 1988-08-22 | Preservation of food |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0257572A true JPH0257572A (en) | 1990-02-27 |
Family
ID=11535414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP265789A Pending JPH0257572A (en) | 1989-01-10 | 1989-01-10 | Plastic film for wrapping |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0257572A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5603997A (en) * | 1991-10-28 | 1997-02-18 | Nobel Ab | Packaging material process for producing same and use thereof |
-
1989
- 1989-01-10 JP JP265789A patent/JPH0257572A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5603997A (en) * | 1991-10-28 | 1997-02-18 | Nobel Ab | Packaging material process for producing same and use thereof |
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