JPH0255750A - Polyolefin resin composition - Google Patents
Polyolefin resin compositionInfo
- Publication number
- JPH0255750A JPH0255750A JP20637688A JP20637688A JPH0255750A JP H0255750 A JPH0255750 A JP H0255750A JP 20637688 A JP20637688 A JP 20637688A JP 20637688 A JP20637688 A JP 20637688A JP H0255750 A JPH0255750 A JP H0255750A
- Authority
- JP
- Japan
- Prior art keywords
- silica
- polyolefin
- polyolefin resin
- weight
- average particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005672 polyolefin resin Polymers 0.000 title claims abstract description 13
- 239000011342 resin composition Substances 0.000 title claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 29
- 229920000098 polyolefin Polymers 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract description 8
- 239000008116 calcium stearate Substances 0.000 abstract description 8
- 235000013539 calcium stearate Nutrition 0.000 abstract description 8
- 239000001993 wax Substances 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 239000012188 paraffin wax Substances 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- -1 Polypropylene Polymers 0.000 description 11
- 239000004743 Polypropylene Substances 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 9
- 239000002981 blocking agent Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 241000251468 Actinopterygii Species 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000012748 slip agent Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012785 packaging film Substances 0.000 description 3
- 229920006280 packaging film Polymers 0.000 description 3
- 239000002530 phenolic antioxidant Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 229920005630 polypropylene random copolymer Polymers 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 102220536504 THAP domain-containing protein 1_P78A_mutation Human genes 0.000 description 1
- 241000860832 Yoda Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- ZTXLZPNGKWQASW-UHFFFAOYSA-L dicalcium octadecanoate Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Ca+2].C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Ca+2] ZTXLZPNGKWQASW-UHFFFAOYSA-L 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- BJZBHTNKDCBDNQ-UHFFFAOYSA-L magnesium;dodecanoate Chemical compound [Mg+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BJZBHTNKDCBDNQ-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は包装フィルムなどとして有用なポリオレフィン
樹脂組成物に関し、詳しくは特定の処理を行なフた微粉
シリカをポリオレフィン樹脂に配合することにより、優
れた透明性を維持しつつ、分散性、耐ブロッキング性を
改良した良品質のポリオレフィン樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a polyolefin resin composition useful as a packaging film, etc. Specifically, by carrying out a specific treatment and blending fine powder silica into a polyolefin resin, This invention relates to a high-quality polyolefin resin composition that has improved dispersibility and blocking resistance while maintaining excellent transparency.
カコ゛
［従来技術および発明譚解決しようとする課題］従来か
らポリプロピレンフィルムは優れた透明性、剛性２強度
を生かして包装フィルムなどに用いられている。Background Art [Prior Art and Problems to be Solved by the Invention] Polypropylene films have traditionally been used for packaging films and the like, taking advantage of their excellent transparency, rigidity, and strength.
しかしながらフィルム間でブロッキングを起し易く、作
業性が損われるだけでなくフィルムの破損を生じ易い。However, blocking tends to occur between the films, which not only impairs workability but also tends to cause damage to the films.
そこでポリプロピレンフィルムに微粉シリカなどのアン
チブロッキング剤を添加することが行なわれている。こ
のアンチブロッキング剤の添加により耐ブロッキング性
はある程度改良されるものの、ポリプロピレンフィルム
の本来有していた透明性を損うという欠点があった。Therefore, anti-blocking agents such as finely divided silica are added to polypropylene films. Although the anti-blocking property is improved to some extent by adding this anti-blocking agent, there is a drawback that the inherent transparency of the polypropylene film is impaired.
この為に、従来から種々の方法が提案されているが、ア
ンチブロッキング剤として微粉シリカをそのまま用いた
場合、シリカ表面の水酸基により、あるいはその表面の
多孔性の為に、分散性が悪く、その結果シリカがポリプ
ロピレン中にフィッシュアイとして残り、外観や印刷性
、ラミネート性等の物性を悪化させたり、透明性に劣る
などの問題があり、十分満足しつるものは得られていな
いのが現状である。Various methods have been proposed for this purpose, but when finely divided silica is used as an anti-blocking agent, its dispersibility is poor due to the hydroxyl groups on the silica surface or the porosity of the surface. As a result, silica remains in the polypropylene as fish eyes, which causes problems such as deterioration of physical properties such as appearance, printability, lamination properties, and poor transparency, and it is currently not possible to obtain a fully satisfactory and durable product. be.
すなわち、たとえば微粉シリカのマスターバッチをつく
り２段階にて溶融混練する方法が提案されている（特開
昭５８−６１４４４号公報）。この方法ではシリカをフ
ィルム中にマクロ的に分散することはできるがミクロ的
に分散が完全でなく、従フてフィルム物性はアンチブロ
ッキング性は改善されるがフィッシュアイ、ヘイズ等に
関してはむしろ悪化するという問題がある。That is, for example, a method has been proposed in which a master batch of finely powdered silica is prepared and melt-kneaded in two stages (Japanese Patent Laid-Open No. 58-61444). In this method, silica can be dispersed macroscopically in the film, but microscopically it is not completely dispersed, and as a result, although the anti-blocking properties of the film are improved, fish-eye, haze, etc. are rather worsened. There is a problem.
また、超微粉の疎水性シリカと無機粉体をポリプロピレ
ンに混合してなる組成物が提案されている（特開昭５４
−１４５７４９号公報）。この組成物によれば透明性は
維持しつるものの、耐ブロツキング性は必ずしも良好で
はなく、またアンチブロッキング剤同士を予備混合して
おく必要があり作業性に劣り、さらにフィッシュアイの
改善も不十分である。Furthermore, a composition made by mixing ultrafine hydrophobic silica powder and inorganic powder with polypropylene has been proposed (Japanese Patent Laid-Open No. 54
-145749). Although this composition maintains transparency, its anti-blocking properties are not necessarily good, and the anti-blocking agents must be pre-mixed, resulting in poor workability, and the improvement of fish eyes is also insufficient. It is.
［課題を解決するための手段］
本発明者は、このような従来の問題点を解決するために
鋭意研究を進めた結果、特定の処理を行なった微粉シリ
カをポリオレフィン樹脂に配合することにより、シリカ
の分散性が改良した結果種々の物性に優れたポリオレフ
ィン樹脂組成物が得られることを見出し、ここに本発明
を完成した。[Means for Solving the Problems] As a result of intensive research in order to solve these conventional problems, the present inventor has achieved the following by blending finely divided silica that has undergone a specific treatment into a polyolefin resin. It was discovered that a polyolefin resin composition with excellent various physical properties could be obtained as a result of improved dispersibility of silica, and the present invention was thus completed.
すなわち本発明は［ＡＩポリオレフィン１００ ｉ工部
に対し、［Ｂ］平均粒径が１〜ｌＯμｍで、かつ有機物
にて表面を２〜２０重量％の割合でコーティングされた
微粉シリカを０．０１〜１．０重量部配合してなるポリ
オレフィン樹脂組成物を提供するものである。That is, the present invention uses [B] 0.01 to 0.01 to 0.01 to 20% by weight of finely powdered silica having an average particle size of 1 to 10 μm and whose surface is coated with an organic substance at a ratio of 2 to 20% by weight, to [100 parts of AI polyolefin]. The object of the present invention is to provide a polyolefin resin composition containing 1.0 part by weight.
本発明において［Ａ］酸成分して用いるポリオレフィン
としては、ポリプロピレン系樹脂およびポリエチレン系
樹脂が挙げられる。ここでポリプロピレン系樹脂として
はプロピレン単独重合体の他、プロピレンとエチレン、
ブタジェンなどのオレフィンとの共重合体が用いられる
。またポリエチレン系樹脂としてはエチレン単独重合体
の他、エチレンと炭素数３〜１０のα−オレフィンとの
共重合体が用いられる。本発明における［Ａ］酸成分し
ては、ポリプロピレン系樹脂が好ましい。In the present invention, polyolefins used as the [A] acid component include polypropylene resins and polyethylene resins. Here, polypropylene resins include propylene homopolymer, propylene and ethylene,
Copolymers with olefins such as butadiene are used. In addition to ethylene homopolymer, copolymers of ethylene and α-olefin having 3 to 10 carbon atoms are used as the polyethylene resin. The [A] acid component in the present invention is preferably a polypropylene resin.
また、本発明において［６］成分として用いる微粉シリ
カは、平均粒径が１〜ｌＯμｍで、かつ有機物にて表面
をコーティングされたものである。Further, the finely divided silica used as component [6] in the present invention has an average particle size of 1 to 10 μm and is coated on the surface with an organic substance.
ここで微粉シリカの平均粒径が１μｍ未満であるとブロ
ッキング防止効果が悪くなる°ため好ましくない。一方
、１０μｍを超えると透明性が悪くなるため好ましくな
い。If the average particle diameter of the finely divided silica is less than 1 μm, the anti-blocking effect will deteriorate, which is not preferable. On the other hand, if it exceeds 10 μm, transparency deteriorates, which is not preferable.
なお、微粉シリカの平均粒径としては２〜５μｍのもの
が特に好ましい。Note that the average particle diameter of the finely divided silica is particularly preferably 2 to 5 μm.
次に、微粉シリカの表面のコーティングに用いる有機物
としては（１）−数式＋４ （ＣＱＯＲ） ２ ［式
中、Ｍは周期律表第！！族の金属を示し、Ｒは炭素数６
〜２３のアルキル基を示す。］で表わされる金属石けん
、（２）融点６０〜９０℃のパラフィンワックスおよび
（３）融点８０〜１４０℃のポリオレフィンワックスが
挙げられる。Next, the organic substance used for coating the surface of fine silica powder is (1) - formula + 4 (CQOR) 2 [where M is from the periodic table! ! group metal, R is 6 carbon atoms
~23 alkyl groups are shown. ], (2) paraffin wax with a melting point of 60 to 90°C, and (3) polyolefin wax with a melting point of 80 to 140°C.
上記−数式中において、Ｍは上記した如くカルシウム、
マグネシウム、バリウム等の周期律表第１Ｉ族の金属を
示し、Ｒは炭素数６〜２３、好ましくは１１〜２１のア
ルキル基を示す。上記−数式で表わされる金属石けんと
して具体的にはステアリン酸カルシウム、ラウリン酸マ
グネシウム、ステアリン酸亜鉛等が挙げられ、特にステ
アリン酸カルシウムが好ましい。In the above formula, M is calcium as described above;
It represents a metal of Group 1I of the periodic table such as magnesium or barium, and R represents an alkyl group having 6 to 23 carbon atoms, preferably 11 to 21 carbon atoms. Specific examples of the metal soap represented by the above-mentioned formula include calcium stearate, magnesium laurate, zinc stearate, etc., with calcium stearate being particularly preferred.
次にパラフィンワックスとしては融点６０〜９０℃のも
のが好ましい。Next, the paraffin wax preferably has a melting point of 60 to 90°C.
また、ポリオレフィンワックスとしては融点８０〜１４
０℃のものが好ましい。このポリオレフィンワックスと
して具体的にはポリエチレンワックス、ポリプロピレン
ワックス等が挙げられ、特にグ量は、シリカに対し２〜
２０重量％であり、好ましくは４〜１２重量％である。In addition, as a polyolefin wax, the melting point is 80 to 14.
Preferably, the temperature is 0°C. Specific examples of this polyolefin wax include polyethylene wax, polypropylene wax, etc. In particular, the amount of
The amount is 20% by weight, preferably 4 to 12% by weight.
このコーテイング量が２％より少ないと分散性が悪くな
り、多すぎるとアンチブロッキング剤としてのシリカの
物性を損ない好ましくない。また、コーティングではな
く単にこれら有機物を添加しただけでは微粉シリカの分
散性が悪くなり、フィッシュアイが多くなり好ましくな
い。If the coating amount is less than 2%, the dispersibility will be poor, and if it is too large, the physical properties of the silica as an anti-blocking agent will be impaired, which is not preferable. In addition, simply adding these organic substances instead of coating is not preferable because the dispersibility of the finely divided silica becomes poor and fish eyes increase.
上記の如き［Ｂ］酸成分、たとえば平均粒径が１〜１０
ｉ調整された合成シリカと、加熱して溶融状態にした有
機物を攪拌混合してシリカの表面に有機物をコーティン
グした後冷却固化することにより得ることができる。[B] Acid component as described above, for example, an average particle size of 1 to 10
It can be obtained by stirring and mixing the i-adjusted synthetic silica and an organic substance that has been heated to a molten state, coating the surface of the silica with the organic substance, and then cooling and solidifying it.
本発明の組成物は、［Ａ］酸成分あるポリオレフィンｉ
ｏｏ 重量部に対し、上記の如き［Ｂ］酸成分０．０１
〜１．０重量部、好ましくは０．０５〜０．５ ｊ！ｉ
量部配合してなるものである。［Ｂ］酸成分配合量が０
．０１重量部より少ないと耐ブロッキング性が改善され
ず、一方１．０重量部を超すと耐ブロッキング性は良い
がフィッシュアイなどが生じ、透明性が劣るなどフィル
ム外観が悪化するため好ましくない。The composition of the present invention comprises [A] a polyolefin i having an acid component;
oo 0.01 of [B] acid component as above per part by weight
~1.0 part by weight, preferably 0.05-0.5 j! i
It is made by blending a certain amount. [B] Acid component content is 0
．． If the amount is less than 1.0 parts by weight, the blocking resistance will not be improved, while if it exceeds 1.0 parts by weight, the blocking resistance will be good but fish eyes will occur and the appearance of the film will deteriorate, such as poor transparency, which is not preferred.
本発明の組成物は基本的には上記［Ａ］ 、 ［Ｂ］両
酸成分りなるものであるが、必要に応じて常用のスリッ
プ剤や酸化防止剤、紫外線吸収剤などを添加することが
できる。The composition of the present invention basically consists of the above-mentioned [A] and [B] both acid components, but if necessary, commonly used slip agents, antioxidants, ultraviolet absorbers, etc. may be added. can.
叙上の如き本発明゛のポリオレフィン樹脂組成物は、公
知のフィルム製造法によって、各種フィルムに成形する
ことができる。The polyolefin resin composition of the present invention as described above can be formed into various films by known film manufacturing methods.
［実施例］ 次に本発明を実施例により詳しく説明する。[Example] Next, the present invention will be explained in detail with reference to examples.
実施例１〜１１
ポリプロピレンランダム共重合体（メルトインデックス
（Ｍ Ｉ ） ６．９ｇ７１０分、エチレン含量３．
５％）に第１表に示すように表面コーティングしたアン
チブロッキング剤とスリップ剤及びその他の安定剤（Ｂ
ＨＴ０．０５重量部、ステアリン酸カルシウム０．１重
量部、フェノール系酸化防止剤０．０５１］ｉｉ部）を
配合した。これを用田製作所製スーパーフロータ−（Ｓ
ＦＣ−５０）にて攪拌混合し、次にこの混合物を神戸製
鋼所混練機（２ＦＣＭ）にてペレット化し、更にこのベ
レットを用いて田辺プラスチツク社製４０ｍｍキャスト
成形機にて溶融押出して、厚さ３０μのフィルム製膜を
行ない、２４時間状態調整を行なった後物性を測定した
。結果を第１表に示す。Examples 1 to 11 Polypropylene random copolymer (melt index (M I ) 6.9 g 710 min, ethylene content 3.
5%), anti-blocking agents, slip agents and other stabilizers (B
0.05 parts by weight of HT, 0.1 parts by weight of calcium stearate, and 0.051 parts of a phenolic antioxidant were blended. This is a Super Floater manufactured by Yoda Seisakusho (S
FC-50), the mixture was then pelletized using a Kobe Steel kneader (2FCM), and the pellets were melt-extruded using a 40 mm cast molding machine manufactured by Tanabe Plastics Co., Ltd. to obtain a thickness of A film of 30 μm was formed, and after conditioning for 24 hours, the physical properties were measured. The results are shown in Table 1.
なおこの際に用いたスリップ剤は日木精化社製ＮＥＵＴ
ＲＯＮ−５（エルカ酸アミド）、その他の安定剤のうち
ＢＨＴとしては住友化学社製スミライザーＢＨＴ、ステ
アリン酸カルシウムとしては日本油脂社製カルシウムス
テアレートＧ、フェノール系酸化防止剤としてはチバガ
イギー社製のイルガノックス１０１０を用いた（以下、
同様）。The slip agent used at this time was NEUT manufactured by Hiki Seika Co., Ltd.
Among other stabilizers, BHT is Sumilizer BHT manufactured by Sumitomo Chemical, calcium stearate is Calcium Stearate G manufactured by NOF Corporation, and phenolic antioxidant is Iruga manufactured by Ciba Geigy. Nox 1010 was used (hereinafter,
similar).
実施例１２
直鎖状低密度ポリエチレン（Ｍ Ｉ ２．０ｇ／１０
分。Example 12 Linear low density polyethylene (M I 2.0g/10
Minutes.
密度０．９１５呂／ｃｍ３． α−オレフィンとして
オクテン−１１１％含有。）にステアリン酸カルシウム
を表面コーティングしたシリカ、スリップ剤（実施例１
に同じ）及びその他の安定剤（イルガノックス１ｏｔｏ
ｏ、ｏ［を全部およびイルガノックス１６８０．１
２重量部；いずれもチバガイギー社製）を配合し、以下
実施例１〜１１と同様にしてフィルムを得、その物性を
測定した。結果を第１表に示す。Density 0.915 l/cm3. Contains 111% octene as α-olefin. ) with calcium stearate surface coating, slip agent (Example 1)
) and other stabilizers (Irganox 1toto) and other stabilizers (Irganox 1toto
o, o [all and Irganox 1680.1
2 parts by weight; both manufactured by Ciba Geigy) were blended, and films were obtained in the same manner as in Examples 1 to 11, and their physical properties were measured. The results are shown in Table 1.
比較例１〜１４
実施例１〜１１で用いたポリプロピレンランダム共重合
体に、第１表に示すようにアンチブロッキング剤および
スリップ剤及びその他の安定剤（実施例１〜１１で用い
たＢＨＴ０．０５ｆｆｉ量部、ステアリン酸カルシウム
０．１重量部、フェノール系酸化防止剤０，０５重量部
）を使用した他は実施例１〜１１と同様にしてフィルム
を得、その物性を測定した。結果を第１表に示す。Comparative Examples 1-14 The polypropylene random copolymer used in Examples 1-11 was added with an anti-blocking agent, a slip agent, and other stabilizers (BHT0.05ffi used in Examples 1-11) as shown in Table 1. Films were obtained in the same manner as in Examples 1 to 11, except that 0.1 parts by weight of calcium stearate and 0.05 parts by weight of phenolic antioxidant were used, and their physical properties were measured. The results are shown in Table 1.
なお、その他の安定剤としては、実施例４〜１１で用い
たと同じものを同量使用した。In addition, as other stabilizers, the same ones used in Examples 4 to 11 were used in the same amounts.
◆ｌシリカ
商品名： ５２４４ＳＴ、富士デヴイソン社製中２ステ
アリン酸カルシウム
カルシウムステアレートＧ３日本油脂社製◆３ポリエチ
レンワックス
融点１１０℃
中４パラフィンワックス
融点８５℃
中５ ＋８粉シリカＡ
商品名： ５２４４．富士デヴイソン社製傘６微粉シリ
カＢ
商品名：Ｓ６Ｂ、富士デヴイソン社製
◆７微粉シリカＣ
商品名： Ｐ７８Ａ、水滓化学社製
＊８ゼオライトＡ
商品名：シルトンＭ（平均粒径２．６μｍ）。◆l Silica product name: 5244ST, manufactured by Fuji Davison Co., Ltd. 2 Calcium stearate Calcium Stearate G3 manufactured by NOF Corporation ◆ 3 Polyethylene wax melting point 110°C Medium 4 Paraffin wax melting point 85°C Medium 5 +8 Powder Silica A Product name: 5244. Umbrella 6 fine powder silica B manufactured by Fuji Davison Product name: S6B, 7 fine powder silica C manufactured by Fuji Davison Product name: P78A, manufactured by Suiko Kagaku *8 Zeolite A Product name: Silton M (average particle size 2.6 μm) .
水滓化学社製 ＊９ゼオライトＢ 商品名：シルトンＭ（平均粒径３．０μｍ）。Manufactured by Suikagaku Co., Ltd. *9 Zeolite B Product name: Silton M (average particle size 3.0 μm).
水滓化学社製
中１２フィッシュアイ
ポリオレフィンフィルム１０００ｃｌｕ２における直径
０．１ｍｍ以上のフィッシュアイでアンチブロッキング
剤の分散不良に起因するものの数を示す。すなわち行中
システム機器社製フィッシュアイ検出装置にて０．１ｍ
ｍ以上のフィッシュアイをカウントする。次に顕微フー
リエ変換赤外分光光度計（ＦＴＩＲ）と波長分散型Ｘ線
マイクロアナライザー（ＥＰＭ＾）にてシリカのＳｉと
０を検出し分散不良フィッシュアイの数を算定した。The number of fish eyes with a diameter of 0.1 mm or more in Medium 12 Fish Eye Polyolefin Film 1000clu2 manufactured by Suiko Kagaku Co., Ltd. due to poor dispersion of the anti-blocking agent is shown. In other words, 0.1m using a fisheye detection device manufactured by Gyochu System Instruments.
Count fisheyes of m or more. Next, Si and 0 in the silica were detected using a microscope Fourier transform infrared spectrophotometer (FTIR) and a wavelength dispersive X-ray microanalyzer (EPM^), and the number of fisheyes with poor dispersion was calculated.
◆１３ 滑り ＾ＳＴＭ ０１８９４に準拠して測定した。◆13 Slip ^ Measured in accordance with STM 01894.
◆１４ブロッキング性
ポリオレフィンフィルム２枚を重ね、３６ｇ／ｃｍ２の
圧力下、６０℃で３時間状態調整した後、この２枚のフ
ィルムを２０ｃｍ／分の引張速度ではく離し、１００ｃ
ｍ２をはく離するのに要する荷重を測定した。◆14 Two blocking polyolefin films were stacked and conditioned at 60°C for 3 hours under a pressure of 36 g/cm2, and then these two films were peeled off at a tensile speed of 20 cm/min.
The load required to peel off m2 was measured.
＊１５ヘイズ ＪＩＳに７１０５に準拠して測定した。*15 haze Measured in accordance with JIS 7105.
［発明の効果〕
本発明のポリオレフィン樹脂組成物はフィルムに成形し
た場合、分散性が改良された結果、フィルム中のフィッ
シュアイが減少することにより、外観が改良され、ピン
ホールが少なく、しかも印刷特性、ラミネート特性、蒸
着性に優れたフィルムとなる。[Effects of the Invention] When the polyolefin resin composition of the present invention is molded into a film, the dispersibility is improved, and as a result, fish eyes in the film are reduced, resulting in improved appearance, fewer pinholes, and printability. The result is a film with excellent properties, lamination properties, and vapor deposition properties.
しかも本発明のポリオレフィン樹脂組成物はフィルムに
成形した場合、ポリオレフィン樹脂の本来有する透明性
を維持しつつ、耐ブロッキング性も改良されたフィルム
となる。Moreover, when the polyolefin resin composition of the present invention is molded into a film, the resulting film maintains the inherent transparency of the polyolefin resin and has improved blocking resistance.
したがって、本発明は食品包装分野をはじめ、各種包装
分野における包装用フィルムとして有効に用いることが
できる。Therefore, the present invention can be effectively used as a packaging film in various packaging fields including the food packaging field.
Claims (1)
粒径が１〜１０μｍで、かつ有機物にて表面を２〜２０
重量％の割合でコーティングされた微粉シリカを０．０
１〜１．０重量部配合してなるポリオレフィン樹脂組成
物。[A] For 100 parts by weight of polyolefin, [B] The average particle size is 1 to 10 μm, and the surface is coated with an organic substance of 2 to 20 μm.
Fine powder silica coated in a proportion of 0.0% by weight
A polyolefin resin composition containing 1 to 1.0 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20637688A JPH0255750A (en) | 1988-08-22 | 1988-08-22 | Polyolefin resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20637688A JPH0255750A (en) | 1988-08-22 | 1988-08-22 | Polyolefin resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0255750A true JPH0255750A (en) | 1990-02-26 |
Family
ID=16522308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20637688A Pending JPH0255750A (en) | 1988-08-22 | 1988-08-22 | Polyolefin resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0255750A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04220443A (en) * | 1990-12-21 | 1992-08-11 | Sumitomo Chem Co Ltd | Polyolefin resin composition for film |
| JPH04220446A (en) * | 1990-12-21 | 1992-08-11 | Sumitomo Chem Co Ltd | Stabilized polyethylene resin composition for film |
| WO1996022326A1 (en) * | 1995-01-19 | 1996-07-25 | Grace Gmbh | Use of a composition based on polyol-treated silicon dioxide as antiblocking agent, antiblocking agent and process for its production |
-
1988
- 1988-08-22 JP JP20637688A patent/JPH0255750A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04220443A (en) * | 1990-12-21 | 1992-08-11 | Sumitomo Chem Co Ltd | Polyolefin resin composition for film |
| JPH04220446A (en) * | 1990-12-21 | 1992-08-11 | Sumitomo Chem Co Ltd | Stabilized polyethylene resin composition for film |
| WO1996022326A1 (en) * | 1995-01-19 | 1996-07-25 | Grace Gmbh | Use of a composition based on polyol-treated silicon dioxide as antiblocking agent, antiblocking agent and process for its production |
| US5609679A (en) * | 1995-01-19 | 1997-03-11 | W. R. Grace & Co.-Conn. | Polyol-treated antiblocking aid |
| DE19502629C2 (en) * | 1995-01-19 | 1998-11-05 | Grace Gmbh | Use of a composition based on polyol-treated silicon dioxide as an anti-blocking agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0242055B1 (en) | Film of crystalline propylene polymer | |
| EP0796884B1 (en) | Masterbatch formulation for polyolefin applications | |
| JP3396303B2 (en) | Masterbatch for polyolefin film and composition for polyolefin film | |
| US5847042A (en) | Polyolefin resin composition containing anti-blocking agent | |
| JP2781979B2 (en) | Polypropylene film | |
| JPH0255750A (en) | Polyolefin resin composition | |
| EP0099251A2 (en) | Polypropylene resin film suitable for the deposition of aluminium thereon | |
| EP0659823B1 (en) | Polypropylene resin composition and the film manufactured therefrom | |
| JP3738489B2 (en) | Polyolefin resin composition and film | |
| JP2859003B2 (en) | Resin composition for bumper | |
| JPH01247427A (en) | Polypropylene film | |
| JP2887708B2 (en) | Polypropylene film | |
| JP3119691B2 (en) | Resin composition for bumper | |
| CA2158093C (en) | Method for producing a polyolefin composition and method for producing apolyolefin film | |
| WO2001040358A1 (en) | Polypropylene blends and films prepared therewith | |
| JPH073437A (en) | Film for metal vapor deposition and laminated film | |
| JPH10296930A (en) | Laminated polyolefin film | |
| JP3424362B2 (en) | Olefin polymer composition | |
| KR100194286B1 (en) | Resin composition of porous film | |
| JPH05339446A (en) | Polypropylene film | |
| JPH08104977A (en) | Metal vapor-deposited polypropylene film | |
| JPH04220443A (en) | Polyolefin resin composition for film | |
| JPH05279522A (en) | Polypropylene resin composition for water-cooled inflation | |
| JPH0439343A (en) | Polypropylene composition | |
| JP2003292687A (en) | Polyolefin resin composition and its film |