JPH0255010A - Perfumed curtain - Google Patents
Perfumed curtainInfo
- Publication number
- JPH0255010A JPH0255010A JP20661888A JP20661888A JPH0255010A JP H0255010 A JPH0255010 A JP H0255010A JP 20661888 A JP20661888 A JP 20661888A JP 20661888 A JP20661888 A JP 20661888A JP H0255010 A JPH0255010 A JP H0255010A
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- perfumed
- microcapsules
- curtain
- perfume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003094 microcapsule Substances 0.000 claims abstract description 30
- 239000011230 binding agent Substances 0.000 claims abstract description 20
- 229920002050 silicone resin Polymers 0.000 claims abstract description 10
- 239000003205 fragrance Substances 0.000 claims description 42
- 239000004744 fabric Substances 0.000 claims description 31
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 229920001296 polysiloxane Polymers 0.000 abstract description 10
- 239000000839 emulsion Substances 0.000 abstract description 6
- 239000002304 perfume Substances 0.000 abstract description 6
- 239000002759 woven fabric Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006757 chemical reactions by type Methods 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 238000009792 diffusion process Methods 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000006378 damage Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- 239000000835 fiber Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 7
- 238000001035 drying Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- -1 polysiloxane Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Curtains And Furnishings For Windows Or Doors (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、芳香性を、有するカーテン類、詳しくは織編
物に香料を含有するマイクロカプセルを付着せしめて、
耐久性のある芳香を付与した織躍物から作られたカーテ
ン類に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention provides a method of attaching microcapsules containing a fragrance to curtains having an aromatic property, specifically woven or knitted fabrics.
The present invention relates to curtains made from woven fabrics imparted with a durable fragrance.
（従来の技術）
従来から芳香性を有する衣類については、様々な開発が
なされ、市場にも多く出回っていた。ところが、これら
の多くは単に最終製品に香水をスプレーしただけのもの
、或いは香気物質を表面に塗布しただけのものであって
、香料が蒸発すれば芳香が消失してしまい、また耐洗濯
性に乏しく、１回の洗濯で完全に香料が脱落してしまう
ようなものであった。(Prior Art) Conventionally, various developments have been made regarding fragranced clothing, and many of them have been on the market. However, many of these products are simply sprayed with perfume onto the final product, or simply coated with fragrant substances on the surface, and the fragrance disappears when the fragrance evaporates, and wash resistance is affected. The fragrance was so poor that it completely disappeared after one wash.
そこで、芳香を長期間持続させるための加工方法が、特
公昭５３−４７４４０号公報、特開昭５４−１１２２８
３号公報等、多数提案されている。Therefore, processing methods to maintain the fragrance for a long period of time are disclosed in Japanese Patent Publication No. 53-47440 and Japanese Patent Application Laid-open No. 54-11228.
Many proposals have been made, including Publication No. 3.
このような中で、織編物や衣服に対しても芳香を付与す
ることが種々試みられてきた。これも、従来は、仕上の
時点で香水をスプレーするか、或いは包装時に包装袋の
中に芳香紙を封入し、または芯部を芳香紙とし、その香
りを織編物、衣服に移すというようなものであった。Under these circumstances, various attempts have been made to impart fragrance to woven and knitted fabrics and clothing. Conventionally, this has been done by spraying perfume at the time of finishing, or by enclosing aromatic paper in a packaging bag during packaging, or by using aromatic paper as the core, and transferring the scent to woven or knitted fabrics or clothing. It was something.
更に特開昭６１−６３７１６号公報には、芯部に香料が
分散混合されかつ芯部に中空部を有する芳香芯鞘型複合
繊維が提案されているが、香料は高温で揮発や変質を起
こし易く、溶融紡糸に耐えうる香料は限定されるという
問題点があった。Furthermore, JP-A No. 61-63716 proposes an aromatic core-sheath type composite fiber in which a fragrance is dispersed and mixed in the core and has a hollow part, but the fragrance volatilizes and changes in quality at high temperatures. There is a problem in that there are only a limited number of fragrances that can be easily processed and that can withstand melt spinning.
（発明が解決しようとする問題点）
しかしながら、上記のようにして得られた繊維製品は、
その芳香の耐久性に乏しいことは言うまでもなく、たっ
た１回の洗濯で完全に芳香が消失してしまい、掻めて商
品価値の低いものであった。(Problems to be solved by the invention) However, the textile products obtained as described above,
Needless to say, the fragrance was not durable, and the fragrance completely disappeared after just one wash, resulting in a product with low commercial value.
更に、着用中外気に接触することにより、すぐに香料が
蒸発してしまい、着用後僅か数時間しか芳香を維持する
ことのできないものさえもあった。Furthermore, the fragrance quickly evaporates when it comes into contact with the outside air while being worn, and some products even maintain their fragrance for only a few hours after being worn.
また、包装袋の中で芳香祇の香りを繊維製品に移すもの
においては、袋密封後の経過時間によって与えられる芳
香の強さが異なり、結果的にこれが快香とならず商品自
体が欠陥品となってしまう場合があった。In addition, in the case of products that transfer the scent of Aromatic Gi to textile products in packaging bags, the strength of the fragrance imparted varies depending on the elapsed time after the bag is sealed, and as a result, the fragrance does not become pleasant and the product itself is defective. There were cases where this happened.
本発明者等は、上述のような実情に鑑み、耐久性のある
芳香をカーテン類に付与することを目的に検討を重ねた
結果、香料を含有するマイクロカプセルを用いることが
芳香加工に好適であるとの知見を得た。In view of the above-mentioned circumstances, the inventors of the present invention have conducted repeated studies with the aim of imparting a durable fragrance to curtains, and have found that using microcapsules containing a fragrance is suitable for fragrance processing. We have learned that there is.
然して、本発明は、香料を含有するマイクロカプセルを
織編物、或いはカーテン類に付着せしめることにより芳
香の持続性が得られること、そして使用中の摩擦で少し
ずつマイクロカプセルが破れて或いは意図的にＩｇ擦す
ることによって発散効果を奏することに着目したもので
ある。ところが、特開昭４９−１９１９７号公報、特開
昭５２−３１２００号公報に開示されるように、織編物
にマイクロカプセルとバインダーを単に付着せしめると
、或いは特開昭５３−１０６８８５号公報に開示される
ように、転写捺染法により付着せしめても充分に耐久性
のある芳香を付与することができない、更にバインダー
が織厖糸の中へ浸透して極めて硬い風合となってしまう
という問題点も生じた。However, the present invention provides that a fragrance can be sustained by attaching microcapsules containing a fragrance to woven or knitted fabrics or curtains, and that the microcapsules may be torn little by little due to friction during use or may be intentionally damaged. This method focuses on the fact that rubbing with Ig produces a diverging effect. However, as disclosed in JP-A-49-19197 and JP-A-52-31200, when microcapsules and a binder are simply attached to a woven or knitted fabric, or as disclosed in JP-A-53-106885, As described above, even if the binder is applied using the transfer printing method, a sufficiently durable fragrance cannot be imparted, and furthermore, the binder penetrates into the woven yarn, resulting in an extremely hard texture. also occurred.
本発明は、上述のような知見のもとでなされたものであ
って、織成物自体の風合を損なうことなく、”好ましい
香りの発ｆ＆ ”と“芳香の持続性”との効果をも満足
しうる芳香カーテン類の提供を目的とするものである。The present invention was made based on the above-mentioned knowledge, and it is possible to achieve the effects of "desirable fragrance development" and "fragrance sustainability" without impairing the texture of the fabric itself. The object of the present invention is to provide aromatic curtains that can satisfy the customer's needs.
（問題点を解決するための手段）
すなわち本発明は、香料入りマイクロカプセルを付着せ
しめたｔａｉ物であって、マイクロカプセルとシリコン
系樹脂バインダーとが２：１〜ｌ：５の割合（重量比）
で与えられ、且つこれら両者の付着量が付着部分の織編
物重量の０．３〜７．０％を占めている芳香繊編物から
作られたことを’４９ 徴とする芳香カーテン類である
。(Means for Solving the Problems) That is, the present invention is a product to which fragrance-containing microcapsules are attached, and the microcapsules and silicone resin binder are in a ratio of 2:1 to 1:5 (weight ratio). )
These aromatic curtains are characterized by being made from an aromatic fiber knitted fabric in which the amount of both of these substances is 0.3 to 7.0% of the weight of the woven or knitted fabric in the attached portion.
そして、この芳香カーテン類の好ましい加工方法として
は、予め１ａ水処理を施したｌａ編物やカーテンに香料
入りマイクロカプセルとシリコン系樹脂バインダーとを
混合した処理剤を浸漬、バフディング、コーティング法
、スプレー法或いはプリント法とくに柄部プリント法に
より付与する方法がある。Preferred processing methods for these aromatic curtains include dipping, buffing, coating, and spraying a treatment agent containing a mixture of fragranced microcapsules and a silicone resin binder onto LA knitted fabrics or curtains that have been previously treated with 1A water. Alternatively, there is a method of applying it by a printing method, particularly a pattern printing method.
本発明でいう織編物とは、公知の織編物をいい、そのｔ
ｓｌｉ編糸として天然繊維、再生繊維、合成繊維或いは
これらの混紡、合糸、混繊などによる混合糸のいずれを
使用してもよい、澄水処理との関係からは目付が大きい
程有利である。またバインダー付着との関係からは凹凸
を存する繊維例えば綿、レーヨン、マクロボイドを有す
る多孔質繊維など、或いはバインダーと親和性のある繊
維が存利である。The woven or knitted fabric in the present invention refers to a known woven or knitted fabric, and its t
As the sli knitting yarn, natural fibers, regenerated fibers, synthetic fibers, or blended yarns, doubled yarns, mixed fibers, etc., of these yarns may be used.The larger the basis weight is, the more advantageous it is in relation to clear water treatment. In addition, from the viewpoint of binder adhesion, fibers with unevenness, such as cotton, rayon, porous fibers with macrovoids, etc., or fibers that have affinity with the binder are useful.
更に本発明で用いる織編物には、バインダーが繊編糸の
中や布目へ浸透して風合いを硬くしないように、予め撥
水処理を施してお（ことが好ましく、これによってバイ
ンダーとマイクロカプセルが主として布の表面に付着し
、Ｉｎ物本来の風合いを損わない、１ａ水処理としては
公知の方法を採用できるが、澄水性を必要としない用途
については比較的小量の処理剤を単に含浸後乾燥するだ
けでよい０例えば酢酸アルミニウムとパラフィンに乳化
剤と保護コロイドを加えたエルマジッンを含浸・乾燥す
る方法、メチルハイドロジエンポリシロキサンの乳化液
と金属石けんを加えたエマルシヨンを用い含浸・乾燥後
熱処理する方法などがある。Furthermore, the woven or knitted fabric used in the present invention is preferably subjected to water-repellent treatment (preferably, in order to prevent the binder from penetrating into the fiber knitting yarns or into the fabric grains and hardening the texture, which will prevent the binder and the microcapsules from forming). Known methods can be used for 1a water treatment, which mainly adheres to the surface of the cloth and does not impair the original texture of In products, but for applications that do not require water clarity, it is possible to simply impregnate a relatively small amount of treatment agent. All you need to do is post-drying 0 For example, impregnating and drying Elumagin, which is aluminum acetate and paraffin with an emulsifier and protective colloid added, or heat treatment after impregnating and drying using an emulsion containing methylhydrodiene polysiloxane emulsion and metal soap. There are ways to do this.
本発明でいうカーテン類とは、織編物、これらの起毛品
或いはレース地を主体とするカーテン類であればよく、
トレーバリ、ケースメント、レース、プリントなどが例
示される。Curtains in the present invention may be curtains mainly made of woven or knitted fabrics, raised products thereof, or lace fabrics,
Examples include tracery, casement, lace, and print.
本発明において用いられる香料入りマイクロカプセルは
、適宜の摩擦によって壊れて芳香を発散するものであれ
ばその組成等は特に限定されないが、低ホルマリンマイ
クロカプセルが好ましい。The composition of the fragrance-containing microcapsules used in the present invention is not particularly limited as long as it can be broken by appropriate friction and emit a fragrance, but low-formalin microcapsules are preferred.
従って、粒子径は通常５〜２０μｍ程度のものを使用し
、カプセルのＩＩＸは０．３〜３μｍ好ましくは０．５
〜１．５μｍである。尚、マイクロカプセルに関しては
従来から様々な製造方法が開発されており、代表的なも
のとしては特公昭３７−７７２４号公報に記載された方
法が挙げられる。Therefore, the particle size is usually about 5 to 20 μm, and the IIX of the capsule is 0.3 to 3 μm, preferably 0.5 μm.
~1.5 μm. Various manufacturing methods have been developed for microcapsules, and a representative example is the method described in Japanese Patent Publication No. 37-7724.
バインダーとして用いるシリコン系樹脂バインダーは、
コーティング効果を奏しマイクロカプセルと織編地との
間の接着剤としての役割を果たすものであり、特に水へ
の分散性に優れ水で容易に希釈可能なシリコン系水性エ
マルジョン型例えばオルガノポリシロキサンプレポリマ
ーを主成分とし乳化剤で乳化したものが好ましい、これ
は、水の除去により硬化し、シリコンゴムの特長を存す
るゴム状皮膜を形成するものであり、耐久性のある接着
効果を奏するものである。更に、低温反応型のオルガノ
ポリシロキサンプレポリマーのエマルシランは、１５０
’Ｃ以下の温度で乾燥してマイクロカプセルを繊維に
固着せしめることができ、より好ましい、このような低
温反応型オルガノボリジロキサンプレボリマーエマルジ
ゴンとしては、例えば１分子中にケイ素原子に結合する
ヒドロキシル基を少なくとも２個有するオルガノポリシ
ロキサン及びその誘導体１００重量部に対し、アミノフ
ァンクンラナルシラン又はその加水分解物と酸無水物と
の反応生成物０．１〜１０重量部とコロイダルシリカ１
〜５０重世部からなる均一分散液をオルガノポリシロキ
サンに対して１〜６０重量部及び硬化用触媒を０．０１
〜１０重量部及びアニオン系乳化剤を０．３〜２０重量
部及び水が２５〜６００重量部からなるシリコンの水性
エマルシランが挙げられる。The silicone resin binder used as a binder is
It has a coating effect and plays a role as an adhesive between microcapsules and woven or knitted fabrics, and is particularly suitable for use in silicone-based aqueous emulsion types, such as organopolysiloxane preforms, which have excellent dispersibility in water and can be easily diluted with water. It is preferable to use a polymer-based material emulsified with an emulsifier, which hardens upon removal of water and forms a rubber-like film that has the characteristics of silicone rubber, providing a durable adhesive effect. . Furthermore, emulsilane, which is a low-temperature reaction type organopolysiloxane prepolymer, has a 150
The microcapsules can be fixed to the fibers by drying at a temperature of 'C or lower, and a more preferable low-temperature-reactive organoboridyloxane prevolimer emuldigon is, for example, one that is bonded to a silicon atom in one molecule. 100 parts by weight of an organopolysiloxane having at least two hydroxyl groups and its derivatives, 0.1 to 10 parts by weight of a reaction product of aminofancranalsilane or its hydrolyzate and an acid anhydride, and 1 part by weight of colloidal silica.
1 to 60 parts by weight of a homogeneous dispersion of ~50 parts by weight based on organopolysiloxane and 0.01 parts by weight of a curing catalyst.
Examples include aqueous silicone emulsion silanes comprising ~10 parts by weight, 0.3 to 20 parts by weight of an anionic emulsifier, and 25 to 600 parts by weight of water.
そして、このコーテイング材はマイクロカプセルの０．
５〜５倍好ましくは１〜２倍（重量比）与えられ、充分
な接着効果を発渾する。０．５倍よりも少なくするとコ
ーティング作用が極端に劣り、一方これを５倍よりも多
く与えてもマイクロカプセルの付着率はほとんど変わら
ず、逆にカーテン類の柔軟な風合において問題が引き起
こされ好ましくない、また、これら両者の付着量は、通
常付着部分°の織編物重量の０．３〜７．０％、好まし
くは０．５〜３．０％を占める。即ち、マイクロカプセ
ルは、シリコン系樹脂バインダーを上記割合で与えられ
ることにより織編物に充分に付着するものであるから、
これら両者の付着量が前記０．３％よりも少ないもので
あれば、芳香の強さ及び耐久性共に不充分であり、一方
これが７．０％よりも多くなると、織編物としての風合
面にかかわり、また−時に発散する香りがきつくなりす
ぎるという問題も存在し、いずれも不適である。つまり
、好ましい香りの発散効果と共に好適な風合及び柔軟性
を存し、且つその芳香が適宜の耐久性を有するという全
ての要件を満たすものは、上記の付着量である。This coating material is applied to the microcapsules.
It is applied 5 to 5 times, preferably 1 to 2 times (weight ratio), to develop a sufficient adhesive effect. If the amount is less than 0.5 times, the coating effect will be extremely poor, while if it is more than 5 times the amount, the adhesion rate of microcapsules will hardly change, and on the contrary, problems will be caused in the soft texture of curtains. This is not preferred, and the amount of both of these substances usually accounts for 0.3 to 7.0%, preferably 0.5 to 3.0%, of the weight of the woven or knitted fabric in the adhered area. That is, since the microcapsules are sufficiently attached to the woven or knitted fabric by being provided with the silicone resin binder in the above proportion,
If the adhesion amount of both of these is less than 0.3%, both the strength of the fragrance and the durability are insufficient. On the other hand, if it is more than 7.0%, the texture of the woven or knitted fabric will deteriorate. However, there is also the problem that the fragrance sometimes emitted is too strong, both of which are unsuitable. In other words, the above-mentioned amount of adhesion satisfies all the requirements of having a favorable fragrance dispersion effect, suitable texture and flexibility, and having appropriate durability of the fragrance.
シリコン樹脂バインダーの付与は、后工程を行わない織
編物等布帛の最終製品に行うことが好ましく、例えばシ
リコン樹脂バインダーからなる処理液槽に浸漬し、風合
を損なわない方法で脱水・乾燥すればよい。It is preferable to apply a silicone resin binder to a final fabric product such as a woven or knitted fabric that does not undergo any post-processing. For example, it can be immersed in a treatment liquid tank made of a silicone resin binder, and then dehydrated and dried in a manner that does not impair its texture. good.
（実施例）
下記３種類の染色された布帛を定法に従って邊水処理し
た（澄水柔軟剤：メチルハイドロジエンボリシロキサン
を主成分とする）、また尿素系樹脂の香料入りマイクロ
カプセル１０ｇ／ｌ（ジャスミン香気、平均粒径８μｍ
、膜ｙｔ１μｍ）をエポキシ変性ジメチルポリシロキサ
ン樹脂を主成分とするシリコン系水性エマルシラン３０
ｇ ／ ｌに混合した０次いでマイクロカプセルの付
着量が撮擺物或いは付着部分の布地の重量に対し０．４
５％となるように前記エマルジョンをｍ編物等に浸漬し
た後ピックアップ率が１００％となるよう遠心脱水し、
乾燥及び１２０〜１３０°Ｃ１分の温熱処理をした。こ
のようにして香料入りマイクロカプセルが付着せしめら
れた布帛は定法に従って乾燥、仕上セント工程へと送ら
れて芳香布帛にした。・Ｏポリエステル（たてフィラメ
ント糸２２５デニール、よこモール糸ｌ／４）の平織物
■難燃アクリル紡績系（１／ ３．７、モール糸２／６
０）のバンクサテンドビー
■ポリエステル７５デニール２４フィラメントと挿入糸
がその７本合撚糸とのラッシェル編レース
次に上記織編物■、■からトレーパリ、■からレースカ
ーテンを仕立てた後、洗）Ｖ耐久性と風合を試験した。(Example) The following three types of dyed fabrics were treated with water according to the standard method (clear water softener: mainly composed of methylhydrodiene polysiloxane), and microcapsules containing urea resin fragrance (10 g/l) (jasmine Fragrance, average particle size 8μm
, film yt 1 μm) of silicone-based aqueous emulsilane 30 whose main component is epoxy-modified dimethylpolysiloxane resin.
The adhesion amount of microcapsules mixed at g/l is 0.4 based on the weight of the photographed object or the cloth on which it is attached.
After dipping the emulsion into m-knitted fabrics etc. so that the concentration is 5%, centrifugal dehydration is performed so that the pick-up rate is 100%,
Drying and heat treatment at 120-130°C for 1 minute were performed. The fabric to which the fragrance-containing microcapsules were attached in this manner was dried according to a conventional method and sent to a finishing process to produce a fragranced fabric.・Plain woven fabric of O polyester (warp filament yarn 225 denier, weft mall thread 1/4) ■Flame-retardant acrylic spinning system (1/3.7, mall thread 2/6)
0) Bank satin dobby ■Polyester 75 denier 24 filament and the inserted yarn are raschel knit lace with its 7 twisted yarns.Next, prepare the lace curtain from the above woven and knitted fabrics ■, treparis from ■, wash) V Durability The properties and texture were tested.
尚、耐洗濯性の試験は、ＪＩＳ Ｌ０２１７１０３法
に準じて行い、芳香の消失するまでの回数で表した。ま
た、芳香の評価は、１０人で夫々５段階評価（最適な芳
香を発散しているものを０点とし、その上下で強過ぎる
ものを＋１．＋２、弱過ぎるものを−１，−２とする）
を行い、その平均点を評価点とした。また、風合につい
ては、同じ＜１０人が良好、やや劣る、劣ると感じたも
のをそれぞれ０、−１、〜２としてその平均点を評価点
とした。The washing resistance test was conducted according to the JIS L0217103 method, and was expressed as the number of times until the fragrance disappeared. In addition, the fragrance was evaluated by 10 people on a 5-point scale (0 points are given for those emitting the optimal fragrance, +1 and +2 are given for those that are too strong above and below that, and -1 and -2 are given for those that are too weak). do)
The average score was taken as the evaluation score. Regarding the feel, those that the same <10 people felt were good, slightly inferior, and inferior were set as 0, -1, and ~2, respectively, and the average score was used as the evaluation score.
この結果をみれば、本発明に係る芳香カーテン類が当所
の目的を達成していること、部ち、耐久性のある良い香
りと良好な風合を有するものとなっていることが明らか
になるであろう。Looking at these results, it is clear that the aromatic curtains according to the present invention have achieved the objectives of our laboratory, and that they have a durable, pleasant scent and a good texture. Will.
（発明の効果）
本発明は、以上に述べた構成により、次のような効果を
奏する。(Effects of the Invention) The present invention achieves the following effects with the configuration described above.
まず、カーテン類に香料入りのマイクロカプセルを付着
せしめているため、使用中或いは意図的な摩擦により少
しずつカプセルが破れて好適な香りを発散する。従って
、その香りは一気に発散されて消失してしまうものでは
なく、充分な持続性を有するものである。First, since microcapsules containing fragrance are attached to the curtains, the capsules are gradually torn during use or by intentional friction, releasing a suitable fragrance. Therefore, the fragrance does not emanate and disappear all at once, but has sufficient sustainability.
また、マイクロカプセルに対して適宜の割合でバインダ
ーとしてのシリコン系樹脂を与えることにより、接着力
及び付着性を著しく向上させて目的とする付着量及び香
りの耐久性を獲得している。In addition, by applying a silicone resin as a binder to the microcapsules in an appropriate proportion, the adhesive strength and adhesion properties are significantly improved, and the desired adhesion amount and fragrance durability are achieved.
そして、その加工方法は、煩雑な加工工程を必要とせず
、マイクロカプセルとシリコン系樹脂バインダーとを適
宜の割合で混合した処理剤を付与し、加熱処理を行うこ
とにより、本発明に係る芳香カーテン類を確実に製造し
うる方法である。The processing method does not require complicated processing steps, and the aromatic curtain according to the present invention is applied by applying a processing agent containing a mixture of microcapsules and a silicone resin binder in an appropriate ratio and performing a heat treatment. This is a method that can reliably produce similar products.
Claims (1)
であって、マイクロカプセルとシリコン系樹脂バインダ
ーとが２：１〜１：５の割合（重量比）で与えられ、且
つこれら両者の付着量が付着部分の織編物重量の０．３
〜７．０％を占めている芳香織編物から作られたことを
特徴とする芳香カーテン類。(1) A woven or knitted fabric to which fragrance-containing microcapsules are attached, in which the microcapsules and silicone resin binder are provided at a ratio (weight ratio) of 2:1 to 1:5, and the amount of these two attached is 0.3 of the weight of the woven or knitted fabric in the attached area
Aromatic curtains characterized in that they are made from aromatic woven and knitted fabrics that account for ~7.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20661888A JPH0255010A (en) | 1988-08-19 | 1988-08-19 | Perfumed curtain |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20661888A JPH0255010A (en) | 1988-08-19 | 1988-08-19 | Perfumed curtain |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0255010A true JPH0255010A (en) | 1990-02-23 |
Family
ID=16526359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20661888A Pending JPH0255010A (en) | 1988-08-19 | 1988-08-19 | Perfumed curtain |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0255010A (en) |
-
1988
- 1988-08-19 JP JP20661888A patent/JPH0255010A/en active Pending
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