JPH0249050A - Vinyl chloride-based composition - Google Patents
Vinyl chloride-based compositionInfo
- Publication number
- JPH0249050A JPH0249050A JP63201742A JP20174288A JPH0249050A JP H0249050 A JPH0249050 A JP H0249050A JP 63201742 A JP63201742 A JP 63201742A JP 20174288 A JP20174288 A JP 20174288A JP H0249050 A JPH0249050 A JP H0249050A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- pts
- parts
- weight
- plasticizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 title abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 239000011342 resin composition Substances 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 230000000903 blocking effect Effects 0.000 abstract description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 abstract description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 abstract description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 abstract description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract description 2
- 229960000541 cetyl alcohol Drugs 0.000 abstract description 2
- 229940043348 myristyl alcohol Drugs 0.000 abstract description 2
- 239000001587 sorbitan monostearate Substances 0.000 abstract description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 abstract description 2
- 229940035048 sorbitan monostearate Drugs 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 2
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- -1 phosphate ester Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UZSAQAWEIQNGJT-UHFFFAOYSA-N tetracontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO UZSAQAWEIQNGJT-UHFFFAOYSA-N 0.000 description 2
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- PZQBWGFCGIRLBB-NJYHNNHUSA-N [(2r)-2-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1O PZQBWGFCGIRLBB-NJYHNNHUSA-N 0.000 description 1
- DNTMJTROKXRBDM-UUWWDYFTSA-N [(2r,3r,4s)-2-[(1r)-1-hexadecanoyloxy-2-hydroxyethyl]-4-hydroxyoxolan-3-yl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC DNTMJTROKXRBDM-UUWWDYFTSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000703 anti-shock Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- NWZZFAQUBMRYNU-UHFFFAOYSA-N n-octadecylnonadec-18-en-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC=C NWZZFAQUBMRYNU-UHFFFAOYSA-N 0.000 description 1
- LDCJGXVGWOTHSW-UHFFFAOYSA-N pentacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO LDCJGXVGWOTHSW-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Greenhouses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、ベタツキおよびブロッキング防止性に優れた
。農業フィルム用塩化ビニル系樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention has excellent anti-stickiness and anti-blocking properties. The present invention relates to a vinyl chloride resin composition for agricultural films.
近年、ａ作物の高付加価値化・収量増加を目的として、
農業用塩化ビニル系樹脂フィルムを使用したハウス栽培
等の施設栽培が盛んに行なわれている。ところでこれら
のハウス栽培においては、夏季あるいは昼間等の高温時
には、農作物の衰弱や焼けを防ぐため換気を必要とする
ことが多く、換気方法としては。In recent years, with the aim of increasing the added value and yield of A crops,
BACKGROUND ART Facility cultivation such as greenhouse cultivation using agricultural vinyl chloride resin films is being actively carried out. By the way, in greenhouse cultivation, ventilation is often required during high temperatures such as summer or daytime to prevent crops from weakening or burning.
ハウスの側面のフィルムを巻き上げ・巻きもどしする方
法が多く採用されている。しかしながら、この巻き上げ
・巻きもどしの作業において、これまでの農業用塩化ビ
ニル系樹脂フィルムにおいては、フィルムどうしのハク
リ性が悪いという、いわゆるブロッキング性が劣ってお
り１作業がはかどらなかったり、フィルムが破損すると
いう問題が存在していた。Many methods are used to wind up and unwind the film on the side of the house. However, in this winding and unwinding work, conventional agricultural vinyl chloride resin films have poor peeling properties, or so-called blocking properties, which can prevent one task from progressing or cause the film to break. There was a problem with doing so.
これまではこのブロッキング性の改良の為に、メチレン
ビスステアリルアマイドを塩化ビニル系樹脂１００重量
部に対し、０．１〜１．０重量部程度添加する場合がほ
とんどであったが、いまだに不十分であり、更にベタツ
キおよびブロッキング性の改良に効果のあるものが求め
られていた。Until now, in order to improve this blocking property, methylene bisstearylamide was added in most cases by about 0.1 to 1.0 parts by weight per 100 parts by weight of vinyl chloride resin, but this is still insufficient. Therefore, there was a need for something that was also effective in improving stickiness and blocking properties.
本発明者らはかかる現状に鑑み鋭意研究の結果、ベタツ
キおよびブロッキング性の改良に非常に優れた。農業フ
ィルム用塩化ビニル系樹脂組成物を見出すに至った。In view of the current situation, the present inventors conducted intensive research and found that the stickiness and blocking properties were significantly improved. We have now discovered a vinyl chloride resin composition for agricultural films.
すなわち本発明は、塩化ビニル系樹脂１００重量部に、
（１）可塑剤３０〜８０重量部 （２）流滴剤ｉ、ｏ〜
３．５重量部 （３）Ｒ−ＯＨ（ただしＲは炭素数１４
以上のアルキル基）で表わされる化合物の少なくとも１
種を０．０１〜３重量部、含有させることを特徴とする
農業フィルム用塩化ビニル系樹脂組成物を提供するもの
である。That is, in the present invention, 100 parts by weight of vinyl chloride resin,
(1) Plasticizer 30-80 parts by weight (2) Droplet agent i, o~
3.5 parts by weight (3) R-OH (R is 14 carbon atoms
At least one of the compounds represented by the above alkyl group)
The present invention provides a vinyl chloride resin composition for agricultural film, which contains 0.01 to 3 parts by weight of seeds.
本発明の塩化ビニル系樹脂とは、塩化ビニル単独重合体
又は塩化ビニルを主体とした樹脂等であって、例えば塩
化ビニルと、酢酸ビニル・塩化ビニリデン・エチレン・
プロピレン・メタアクリル酸エステル・ウレタン樹脂等
との共重合体やグラフト重合体、あるいはこれらの樹脂
とのブレンド物等である。The vinyl chloride resin of the present invention is a vinyl chloride homopolymer or a resin mainly composed of vinyl chloride, such as vinyl chloride, vinyl acetate, vinylidene chloride, ethylene, etc.
These include copolymers and graft polymers with propylene, methacrylic acid esters, urethane resins, etc., and blends with these resins.
次に本発明で使用される可塑剤としては、フタル酸エス
テル系、アジピン酸エステル系。Next, the plasticizers used in the present invention include phthalate esters and adipic esters.
ポリエステル系、リン酸エステル系等があるが、例えば
、ジオクチルフタレート、ジヘキシルフタレート、ジイ
ソデシルフタレート、ジオクチルアジペート、トリクレ
ジルホスフェート、トリキシレニルホスフェート等が挙
げられるが、これらは単独あるいは２種以上併用して用
いられる。There are polyester types, phosphate ester types, etc., and examples include dioctyl phthalate, dihexyl phthalate, diisodecyl phthalate, dioctyl adipate, tricresyl phosphate, and tricylenyl phosphate, which may be used alone or in combination of two or more. It is used as
次に本発明で使用される流滴剤は、水滴付着防止効果の
あるものなら何でもよいが、好適な例としては、ソルビ
タンモノステアレート、ソルビタンモノパルミテート、
ソルビタンモノラウレート、ソルビタンセスキステアレ
ート、ソルビタンジパルミテート、ポリオキシエチレン
ソルビタンモノステアレート、ポリオキシエチレンソル
ビタンジステアレート、ポリオキシプロピレンソルビタ
ンセスキステアレート、ソルビトールモノステアレート
、ジペンタエリスリトールモノパルミテート、グリセリ
ンモノステアレート、シリコン系界面活性剤、フッ素系
界面活性剤等が挙げられる。これらは単独あるいは２種
以上併用して用いられる。Next, the droplet agent used in the present invention may be any agent as long as it has an effect of preventing water droplet adhesion, but suitable examples include sorbitan monostearate, sorbitan monopalmitate,
Sorbitan monolaurate, sorbitan sesquistearate, sorbitan dipalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan distearate, polyoxypropylene sorbitan sesquistearate, sorbitol monostearate, dipentaerythritol monopalmitate , glycerin monostearate, silicone surfactants, fluorine surfactants, and the like. These may be used alone or in combination of two or more.
また本発明で使用されるＲ−ＯＨで表わされる化合物と
しては、ミリスチルアルコール、セチルアルコール、ス
テアリルアルコール、べべ手ルアルコール、トリアコン
タノール、テトラコンタノール、ペンタコンタノール等
が挙げられ、商品名としては花王−のカルコール６０（
Ｃ＝１６） ・カルコール８０（Ｃ＝１８）・カルコ
ール２２０−８０ （Ｃ＝２２） 、伊藤製油−のハイ
ソコール＃２４６（Ｃ＝２４〜２６）、東洋ペトロライ
ト■のユニリン＃４２５ （Ｃ＝３０）ユニリン＃５５
０ （Ｃ＝４０） ・ユニリン＃７００（Ｃ＝５０）
等が挙げられる。Further, the compounds represented by R-OH used in the present invention include myristyl alcohol, cetyl alcohol, stearyl alcohol, bebetal alcohol, triacontanol, tetracontanol, pentacontanol, etc., and the trade names include Kao Calkol 60 (
C = 16) - Calcol 80 (C = 18) - Calcol 220-80 (C = 22), Hysocol #246 (C = 24-26) from Ito Oil Co., Ltd., Unilin #425 (C = 30) Unirin #55
0 (C=40) ・Unilin #700 (C=50)
etc.
又、本発明においてはその他必要に応じて。In addition, in the present invention, other requirements may apply.
金属石ケン、滑剤、震防止剤、保温性改良剤、酸性リン
酸エステル又はその金属塩、有機亜リン酸エステル、紫
外線吸収剤、酸化防止剤。Metal soap, lubricant, anti-shock agent, heat retention improver, acid phosphate or its metal salt, organic phosphite, ultraviolet absorber, antioxidant.
着色防止剤、顔料、エポキシ化合物、ヒンダードアミン
系光安定化剤、プレートアウト防止剤、赤外線吸収剤、
強化剤、加工助剤等の従来から塩化ビニル系樹脂に用い
られている添加剤を適宜使用してよいことはいうまでも
ない。以下実施例により具体的に説明する。Anti-coloring agents, pigments, epoxy compounds, hindered amine light stabilizers, plate-out inhibitors, infrared absorbers,
It goes without saying that additives conventionally used for vinyl chloride resins, such as reinforcing agents and processing aids, may be used as appropriate. This will be explained in detail below using examples.
実施例１
表１の配合物を１８０℃のロールにて５分間混練し、厚
さ０．１ｍのフィルムとした。得られたフィルムを巾３
ｃＭ長さ２０ａａに切り取り、これを１０枚重ね合わせ
て、温度５０℃湿度９０％の条件下で２ケ月間保存した
のち、フィルムどうしを引きはがすのに要する力を測定
し。Example 1 The formulation shown in Table 1 was kneaded for 5 minutes using a roll at 180°C to form a film with a thickness of 0.1 m. The width of the obtained film is 3
The films were cut into 20 cm lengths of 20 aa, stacked together and stored for two months at a temperature of 50° C. and humidity of 90%, and then the force required to peel the films apart was measured.
ブロッキング性を評価した。Blocking properties were evaluated.
Claims (1)
８０重量部（２）流滴剤１．０〜３．５重量部（３）Ｒ
−ＯＨ（ただしＲは炭素数１４以上のアルキル基）で表
わされる化合物の少なくとも１種を０．０１〜３重量部
、含有させることを特徴とする農業フィルム用塩化ビニ
ル系樹脂組成物。100 parts by weight of vinyl chloride resin, (1) 30 to 30 parts of plasticizer
80 parts by weight (2) Droplet agent 1.0-3.5 parts by weight (3) R
A vinyl chloride resin composition for agricultural film, characterized in that it contains 0.01 to 3 parts by weight of at least one compound represented by -OH (where R is an alkyl group having 14 or more carbon atoms).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63201742A JPH0249050A (en) | 1988-08-11 | 1988-08-11 | Vinyl chloride-based composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63201742A JPH0249050A (en) | 1988-08-11 | 1988-08-11 | Vinyl chloride-based composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0249050A true JPH0249050A (en) | 1990-02-19 |
Family
ID=16446186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63201742A Pending JPH0249050A (en) | 1988-08-11 | 1988-08-11 | Vinyl chloride-based composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0249050A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998024848A1 (en) * | 1996-11-22 | 1998-06-11 | Mitsui Chemicals, Inc. | Thermoplastic resin composition and film made from the composition |
| JP2010519359A (en) * | 2007-02-23 | 2010-06-03 | ビーエーエスエフ ソシエタス・ヨーロピア | Mixture of n-alkanol and method of using the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111254A (en) * | 1975-03-26 | 1976-10-01 | C I Kasei Co Ltd | Polyvinylchloride film for agricultural use |
| JPS5497648A (en) * | 1978-01-19 | 1979-08-01 | Sakai Chem Ind Co Ltd | Halogen-containing resin composition |
| JPS5853937A (en) * | 1981-09-25 | 1983-03-30 | Chisso Corp | Vinyl chloride resin composition |
-
1988
- 1988-08-11 JP JP63201742A patent/JPH0249050A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111254A (en) * | 1975-03-26 | 1976-10-01 | C I Kasei Co Ltd | Polyvinylchloride film for agricultural use |
| JPS5497648A (en) * | 1978-01-19 | 1979-08-01 | Sakai Chem Ind Co Ltd | Halogen-containing resin composition |
| JPS5853937A (en) * | 1981-09-25 | 1983-03-30 | Chisso Corp | Vinyl chloride resin composition |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998024848A1 (en) * | 1996-11-22 | 1998-06-11 | Mitsui Chemicals, Inc. | Thermoplastic resin composition and film made from the composition |
| JP2010519359A (en) * | 2007-02-23 | 2010-06-03 | ビーエーエスエフ ソシエタス・ヨーロピア | Mixture of n-alkanol and method of using the same |
| JP2014148678A (en) * | 2007-02-23 | 2014-08-21 | Basf Se | Mixtures of n-alkanols and their use |
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