JPH0236287A - Master sheet for transfer printing and transfer sheet using said master sheet - Google Patents
Master sheet for transfer printing and transfer sheet using said master sheetInfo
- Publication number
- JPH0236287A JPH0236287A JP18736088A JP18736088A JPH0236287A JP H0236287 A JPH0236287 A JP H0236287A JP 18736088 A JP18736088 A JP 18736088A JP 18736088 A JP18736088 A JP 18736088A JP H0236287 A JPH0236287 A JP H0236287A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- transfer
- ionizing radiation
- master
- protective layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010023 transfer printing Methods 0.000 title claims description 21
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 19
- 239000011241 protective layer Substances 0.000 claims abstract description 17
- 239000010410 layer Substances 0.000 claims abstract description 13
- 230000005865 ionizing radiation Effects 0.000 claims abstract description 11
- 230000001678 irradiating effect Effects 0.000 claims abstract description 6
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 5
- 239000000057 synthetic resin Substances 0.000 claims abstract description 5
- 238000010030 laminating Methods 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 14
- 239000012790 adhesive layer Substances 0.000 claims description 7
- 238000007639 printing Methods 0.000 claims description 5
- -1 polyethylene terephthalate Polymers 0.000 abstract description 18
- 239000000126 substance Substances 0.000 abstract description 10
- 238000005299 abrasion Methods 0.000 abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 4
- 229920000728 polyester Polymers 0.000 abstract description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 4
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 4
- 239000000758 substrate Substances 0.000 abstract description 4
- 239000004698 Polyethylene Substances 0.000 abstract description 3
- 238000001723 curing Methods 0.000 abstract description 3
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- 239000004793 Polystyrene Substances 0.000 abstract description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 abstract description 2
- 238000003847 radiation curing Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 description 18
- 238000000034 method Methods 0.000 description 15
- 238000010894 electron beam technology Methods 0.000 description 14
- 239000002585 base Substances 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000123 paper Substances 0.000 description 9
- 229920000193 polymethacrylate Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000007756 gravure coating Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- 244000028419 Styrax benzoin Species 0.000 description 2
- 235000000126 Styrax benzoin Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229960002130 benzoin Drugs 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 235000019382 gum benzoic Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 229960000834 vinyl ether Drugs 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JNELGWHKGNBSMD-UHFFFAOYSA-N xanthone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3OC2=C1 JNELGWHKGNBSMD-UHFFFAOYSA-N 0.000 description 2
- LSUMRGHRDAUBMF-UHFFFAOYSA-N 1,2-dimethylxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=C(C)C(C)=CC=C3OC2=C1 LSUMRGHRDAUBMF-UHFFFAOYSA-N 0.000 description 1
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 description 1
- DVVXXHVHGGWWPE-UHFFFAOYSA-N 2-(dimethylamino)benzoic acid Chemical compound CN(C)C1=CC=CC=C1C(O)=O DVVXXHVHGGWWPE-UHFFFAOYSA-N 0.000 description 1
- HRGCERQFEGGWFF-UHFFFAOYSA-N 2-(dioctylamino)benzoic acid Chemical compound CCCCCCCCN(CCCCCCCC)C1=CC=CC=C1C(O)=O HRGCERQFEGGWFF-UHFFFAOYSA-N 0.000 description 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- ARXVXVOLXMVYIT-UHFFFAOYSA-N 3-methylbutyl 2-(dimethylamino)benzoate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1N(C)C ARXVXVOLXMVYIT-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- ACOGMWBDRJJKNB-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.CC(O)=O ACOGMWBDRJJKNB-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- GUUVPOWQJOLRAS-UHFFFAOYSA-N diphenyl disulphide Natural products C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 1
- JPJNCYZKRJFVAK-UHFFFAOYSA-N dodecyl 2-(dimethylamino)benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1N(C)C JPJNCYZKRJFVAK-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940052303 ethers for general anesthesia Drugs 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- KUQWZSZYIQGTHT-UHFFFAOYSA-N hexa-1,5-diene-3,4-diol Chemical compound C=CC(O)C(O)C=C KUQWZSZYIQGTHT-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 229920006284 nylon film Polymers 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 229920002601 oligoester Polymers 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical compound C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000007965 rubber solvent Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、耐摩耗性や耐薬品性に優れた保護層を有する
転写シートを得るための転写印刷用マスターシート、及
び該転写シートに関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a transfer printing master sheet for obtaining a transfer sheet having a protective layer with excellent abrasion resistance and chemical resistance, and to the transfer sheet. It is.
（従来の技術）
従来から転写印刷は、プラスチック、ガラス、金属等の
表面に転写層を図柄を形成する方法として利用されてい
る。しかし、転写により形成された図柄は、耐摩耗性や
耐薬品性などが充分でないため、図柄が傷ついたり、溶
剤等により図柄が損なわれるなどの問題点を有している
。(Prior Art) Transfer printing has conventionally been used as a method for forming patterns on the surface of plastic, glass, metal, etc. using a transfer layer. However, designs formed by transfer do not have sufficient abrasion resistance or chemical resistance, so they have problems such as being scratched or damaged by solvents and the like.
該問題点を解決するために、紫外線の照射で硬化するイ
ンキを用いて図柄を描き、転写後に紫外線を照射する方
法（特公昭５５−６５１５号公報等）、紫外線または電
子線硬化性樹脂を基材フィルム上に設け、図柄を印刷し
、転写したのち紫外線或いは電子線を照射する方法（特
開昭６１−９８５９９号等）などが出願されている。ま
た、保護層に熱硬化性樹脂を含む組成分とし、転写後加
熱処理を施す方法もある。In order to solve this problem, we have developed a method of drawing designs using ink that hardens when irradiated with ultraviolet rays, and then irradiating them with ultraviolet rays after transfer (Japanese Patent Publication No. 55-6515, etc.), a method based on ultraviolet curable or electron beam curable resin, etc. A method has been proposed in which a pattern is printed on a material film, transferred, and then irradiated with ultraviolet rays or electron beams (Japanese Patent Laid-Open No. 61-98599, etc.). There is also a method in which the protective layer is made of a composition containing a thermosetting resin and is subjected to heat treatment after transfer.
しかし、これらの方法は、紫外線等の照射処理の場合、
特殊なインキでしか印刷できないため、通常のインキで
印刷できない。また、転写後に紫外線や電子線の照射を
処理を行うため、大掛かりな装置が必要となるなどの点
で、手軽に転写印刷を行うことができない。加熱処理の
場合も、被転写体がプラスチック等の非耐熱性基材には
適用できないと言う欠点を有していた。However, in the case of irradiation treatment such as ultraviolet rays, these methods
It cannot be printed with regular ink because it can only be printed with special ink. Furthermore, since irradiation with ultraviolet rays or electron beams is performed after the transfer, a large-scale device is required, making transfer printing difficult to perform easily. Heat treatment also has the disadvantage that it cannot be applied to non-heat resistant substrates such as plastics.
（発明が解決しようとする課題）
本発明は、装置も大掛かりでなく、しかも耐摩耗性や耐
薬品性に優れた保護層を有する転写シートを得るための
転写印刷用マスターシート、及び該転写シートを提供す
ることを目的とするものである。(Problems to be Solved by the Invention) The present invention provides a transfer printing master sheet for obtaining a transfer sheet having a protective layer with excellent abrasion resistance and chemical resistance without requiring a large-scale apparatus, and the transfer sheet. The purpose is to provide the following.
（課題を解決するための手段）
本発明者は、上記目的を達成するため鋭意検討した結果
、以下の構成からなる転写印刷用マスターシートを見出
した。(Means for Solving the Problems) As a result of intensive studies to achieve the above object, the inventors of the present invention discovered a transfer printing master sheet having the following configuration.
即ち本発明は、転写印刷用マスターシート（１）の構成
が、合成樹脂からなるシート基材（２）と、該シート基
材と剥離可能で、電離放射線硬化樹脂に電離放射線の照
射を行うことにより硬化せしめた転写保８ＩＮ（３）を
積層したことを特徴とする転写印刷用マスターシート、
及び転写シート（４）の構成が、該転写印刷用マスター
シート（１）の転写保護層（３）側に、印刷層（５）及
び接着剤Ｎ（６）を設けたことを特徴とする転写シート
である。That is, the present invention provides a transfer printing master sheet (1) having a structure including a sheet base material (2) made of a synthetic resin, which is separable from the sheet base material, and in which the ionizing radiation-cured resin is irradiated with ionizing radiation. A master sheet for transfer printing, characterized by laminating a transfer adhesive 8IN (3) cured by
and a transfer sheet (4) characterized in that a printing layer (5) and an adhesive N (6) are provided on the transfer protective layer (3) side of the transfer printing master sheet (1). It is a sheet.
（作用）
上記の構成において、合成樹脂からなるシート基材（２
）としては、ポリエチレンテレフタレート、ポリプロピ
レン、ポリスチレン、ポリ塩化ビニル、ポリエチレン等
の無延伸ないし延伸フィルム、更にこれらにフィルムに
離型剤処理したもの等が使用される。(Function) In the above configuration, the sheet base material (2
) used are unstretched or stretched films of polyethylene terephthalate, polypropylene, polystyrene, polyvinyl chloride, polyethylene, etc., as well as films treated with a release agent.
このフィルムは、透明、半透明或いは顔料又は染料等が
含有されている不透明のものであっても良い。This film may be transparent, translucent, or opaque containing pigments or dyes.
このシートの厚みは４〜２００μｍ程度、コスト面及び
これに電離放射線硬化型樹脂を塗布するときの塗布適性
を考慮すると８〜８０μｍ程度のものを使用するのが望
ましい。The thickness of this sheet is approximately 4 to 200 .mu.m, and in view of cost and suitability for coating with ionizing radiation curable resin, it is desirable to use a thickness of approximately 8 to 80 .mu.m.
転写保護層（３）は、上記合成樹脂からなるシート基材
に、電離放射線硬化型樹脂を塗布し、電離放射線を照射
して硬化せしめた層よりなるが、この電離放射線硬化型
樹脂の種類としては、以下の如きプレポリマーやモノマ
ーによって形成される。The transfer protective layer (3) is made of a sheet base material made of the above-mentioned synthetic resin, coated with an ionizing radiation-curable resin, and cured by irradiating it with ionizing radiation. is formed from the following prepolymers and monomers.
プレポリマーとしては
（１）、脂肪族、脂環族、芳香脂肪族、芳香族２〜６価
の多価アルコール及びポリアルキルキレングリコールの
ポリ（メタ）アクリレート；（２）、脂肪族、脂環族、
芳香脂肪族、芳香族２〜６価の多価アルコールにアルキ
レンオキサイドを付加させた形の多価アルコールのポリ
（メタ）アクリレート；
（３）、ポリ （メタ）アクリロイルオキシアルキリン
酸エステル；
（４）、ポリエステルポリ （メタ）アクリレート；（
５）、エポキシポリ （メタ）アクリレート；（６）、
ポリウレタン（メタ）アクリレート；（７）、ポリアミ
ドポリ （メタ）アクリレート；（８）、ポリシロキサ
ンポリ （メタ）アクリレート；（９）、側鎖及び／又
は末端に（メタ）アクリロイルオキシ基を有するビニル
系又はジエン系低重合体；
００）、前記（１）〜（９）記載のオリゴエステル（メ
タ）アクリレート変成物；
等のプレポリマー
ｂ モノマーとしては、
（１）、エチレン性不飽和モノ又はポリカルボン酸等で
代表されるカルボキシル基台を単量体及びそれらのアル
カリ金属塩、アンモニウム塩、アミン塩等のカルボン酸
塩基含有単量体；（２）、エチレン性不飽和（メタ）ア
ルキルアミド又はアルキル置換（メタ）アクリルアミド
、Ｎ−ビニルピロリドンのようなビニルラクタム類で代
表されるアミド基含有単量体；（３）、脂肪族又は芳香
族ビニルスルホン酸類で代表されるスルホン酸基含有単
量体及びそれらのアルカリ金属塩、アンモニウム塩、ア
ミン塩等のスルホン酸塩基含有単量体；
（４）、エチレン性不飽和エーテル等で代表される水酸
基含有単量体；
（５）、ジメチルアミノエチル（メタ）アクリレート−
２−ビニルピリジン等のアミノ基含有単量体；（６）、
４級アンモニウム塩基含有単量体；（７）、エチレ
ン性不飽和カルボン酸のアルキルエステル；
（８）、 （メタ）アクリロニトリル等のニトリル基
含有単量体；
（９）、スチレン；
ＧＯ）、酢酸ビニル、酢酸（メタ）アリル等のエチレ７
性ＴＪｌアルコールのエステル；
ＣＩり、活性水素を含有する化合物のアルキレンオキシ
ド付加重合体のモノ（メタ）アクリレート類；ａ２）、
多塩基酸と不飽和アルコールとのジエステルで代表され
るエステル基含有２官能単量体；ｑ３）、活性水素を含
有する化合物のアルキレンオキシド付加重合体と（メタ
）アクリル酸とのジエステルよりなる２官能単量体；
Ｑ駅 Ｎ−Ｎ−メチレンビスアクリルアミド等のビスア
クリルアミド；
０５）、ジビニルベンゼン、ジビニルエチレングリコー
ル、ジビニルエーテル、ジビニルケトン等の２官能単量
体；
０６）、活性水素を含有する化合物のアルキレンオキシ
ド付加重合体と（メタ）アルリル酸とのポリエステルよ
りなる多官能単量体；
０７）、 ｌ−ジビニルベンゼンのような多官能不飽
和単量体；
等のモノマー
これらのプレポリマーやモノマーは併用してもよい。更
に、着色染料、蛍光染料、着色顔料、蛍光顔料、界面活
性剤、消泡剤、熱可塑性樹脂、レベリング剤、滑剤、紫
外線吸収剤等を適宜添加してもよい。また、必要に応じ
て水や溶剤に希釈して使用したり、水中油滴型の樹脂エ
マルジョンとして調整したものを使用することも可能で
あるが、乾燥工程を必要とするため、樹脂１００％での
使用が望ましい。Prepolymers include (1) poly(meth)acrylates of aliphatic, alicyclic, araliphatic, aromatic di- to hexavalent polyhydric alcohols and polyalkylkylene glycol; (2) aliphatic, alicyclic; family,
Poly(meth)acrylate of polyhydric alcohol in the form of alkylene oxide added to araliphatic, aromatic di- to hexavalent polyhydric alcohol; (3), poly(meth)acryloyloxyalkyphosphate ester; (4) ), polyester poly(meth)acrylate; (
5), epoxy poly(meth)acrylate; (6),
Polyurethane (meth)acrylate; (7); Polyamide poly (meth)acrylate; (8); Polysiloxane poly (meth)acrylate; (9); Vinyl type having (meth)acryloyloxy groups in side chains and/or terminals or diene-based low polymer; 00), oligoester (meth)acrylate modified products described in (1) to (9) above; etc. Prepolymer b monomers include (1), ethylenically unsaturated mono- or polycarbon Monomers with carboxyl bases represented by acids, and monomers containing carboxylic acid groups such as their alkali metal salts, ammonium salts, and amine salts; (2), ethylenically unsaturated (meth)alkylamides or alkyl Amide group-containing monomers represented by vinyl lactams such as substituted (meth)acrylamides and N-vinylpyrrolidone; (3) Sulfonic acid group-containing monomers represented by aliphatic or aromatic vinyl sulfonic acids and sulfonic acid group-containing monomers such as alkali metal salts, ammonium salts, and amine salts thereof; (4), hydroxyl group-containing monomers represented by ethylenically unsaturated ethers; (5), dimethylaminoethyl ( Meta)acrylate-
Amino group-containing monomer such as 2-vinylpyridine; (6),
Quaternary ammonium base-containing monomer; (7), alkyl ester of ethylenically unsaturated carboxylic acid; (8), nitrile group-containing monomer such as (meth)acrylonitrile; (9), styrene; GO), acetic acid Ethylene 7 such as vinyl, (meth)allyl acetate, etc.
esters of TJl alcohol; mono(meth)acrylates of alkylene oxide addition polymers of compounds containing active hydrogen; a2);
An ester group-containing bifunctional monomer represented by a diester of a polybasic acid and an unsaturated alcohol; q3), a diester of an alkylene oxide addition polymer of an active hydrogen-containing compound and (meth)acrylic acid; Functional monomer; Q station Bisacrylamide such as N-N-methylenebisacrylamide; 05), difunctional monomer such as divinylbenzene, divinylethylene glycol, divinyl ether, divinyl ketone; 06), containing active hydrogen A polyfunctional monomer consisting of a polyester of an alkylene oxide addition polymer of a compound and (meth)alrylic acid; 07), a polyfunctional unsaturated monomer such as l-divinylbenzene; Monomers may be used in combination. Furthermore, colored dyes, fluorescent dyes, colored pigments, fluorescent pigments, surfactants, antifoaming agents, thermoplastic resins, leveling agents, lubricants, ultraviolet absorbers, etc. may be added as appropriate. It is also possible to use it diluted with water or a solvent or prepared as an oil-in-water resin emulsion if necessary, but since it requires a drying process, it is not possible to use 100% resin. It is recommended to use
これらの樹脂はシート基材に塗布するが、塗布方法とし
ては例えばバーコーター、ロールコ〜り、グラビアコー
ター等通常の塗布手段が適宜使用され、塗布量は、乾燥
重量で０．５〜４０ｇ／ｒ＋（、より好ましくは２〜２
０ｇ／ｎ（の範囲が望ましい。These resins are applied to the sheet base material, and the application method is as appropriate, such as a bar coater, roll coater, gravure coater, etc., and the application amount is 0.5 to 40 g/r+ on a dry weight basis. (, more preferably 2 to 2
A range of 0 g/n (is desirable).
因に、０．５ｇ／ｎ？未満では本発明の所望の効果は得
られず、また４０ｇ／ｒｄ以上は目的とする効果の点か
らして必要性に乏しい。Incidentally, 0.5g/n? If it is less than 40 g/rd, the desired effect of the present invention cannot be obtained, and if it is more than 40 g/rd, it is not necessary in terms of the desired effect.
本発明の方法では、上述のようにして形成された塗布組
成物の塗工層を電離放射線の照射により硬化させるが、
電離放射線としては、例えば電子線、紫外線、α線、β
線、Ｔ線、Ｘ線等が挙げられる。α線、β線、Ｔ線及び
Ｘ線は人体への危険性といった問題が付随するため、取
扱が容易で、工業的にもその利用が普及している電子線
や紫外線が好ましく用いられる。In the method of the present invention, the coating layer of the coating composition formed as described above is cured by irradiation with ionizing radiation.
Examples of ionizing radiation include electron beams, ultraviolet rays, alpha rays, and beta rays.
rays, T-rays, X-rays, etc. Since α-rays, β-rays, T-rays, and X-rays are associated with the problem of danger to the human body, electron beams and ultraviolet rays are preferably used because they are easy to handle and are widely used industrially.
電子線を使用する場合、照射する電子線の量は０．１〜
２０ Ｍｒａｄ程度の範囲で調節するのが望ましい。０
．１ Ｍｒａｄ未満では十分な照射効果が得られず、２
０Ｍｒａｄを越えるような照射はある種のプラスチック
フィルムを劣化させる恐れがあるため好ましくない。When using an electron beam, the amount of electron beam irradiated is 0.1~
It is desirable to adjust within a range of about 20 Mrad. 0
．． If it is less than 1 Mrad, sufficient irradiation effect cannot be obtained;
Irradiation exceeding 0 Mrad is not preferred because it may deteriorate some types of plastic films.
電子線の照射方法としては、例えばスキャニング方式、
カーテンビーム方式、ブロードビーム方式等が採用され
、電子線を照射する際の加速電圧は１００〜３００ｋｖ
程度が適当である。尚、電子線照射方式は、紫外線照射
に比べて生産性が窩く、増感剤添加による臭気、着色の
問題がなく、さらに均一な架橋構造をとりやすいといっ
た利点がある。Examples of electron beam irradiation methods include scanning method,
Curtain beam method, broad beam method, etc. are adopted, and the acceleration voltage when irradiating the electron beam is 100 to 300 kv.
The degree is appropriate. The electron beam irradiation method has advantages over ultraviolet irradiation in that productivity is lower, there is no problem of odor or coloring caused by the addition of a sensitizer, and it is easier to form a uniform crosslinked structure.
紫外線を使用する場合には、塗布組成物中に増感剤を配
合する必要があり、例えばチオキサントン、ベンゾイン
、ベンゾインアルキルエーテルキサントン、ジメチルキ
サントン、ベンゾフェノン、アントラセン、２．２−ジ
ェトキシアセトフェノン、ベンジルジメチルケタール、
ベンジルジフェニルジスルフィド、アントラキノン、１
−クロロアントラキノン、２−エチルアントラキノン、
２− ｔｅｒ−ブチルアントラキノン、Ｎ、Ｎ’ −テ
トラエチル−４，４″−ジアミノベンゾフェノン、１．
１−ジクロロアセトフェノン等の増感剤の一種以上が適
宜配合される。When using ultraviolet light, it is necessary to incorporate a sensitizer into the coating composition, such as thioxanthone, benzoin, benzoin alkyl ether xanthone, dimethylxanthone, benzophenone, anthracene, 2,2-jethoxyacetophenone, benzyldimethyl. ketal,
Benzyl diphenyl disulfide, anthraquinone, 1
-chloroanthraquinone, 2-ethylanthraquinone,
2-ter-butylanthraquinone, N,N'-tetraethyl-4,4''-diaminobenzophenone, 1.
One or more sensitizers such as 1-dichloroacetophenone are appropriately blended.
尚、増感剤の使用量は塗布組成物中の電離放射線硬化型
のモノマー及び／又はオリゴマー（プレポリマー）に対
して０．２〜１０重量％、好ましくは０．５〜５重量％
程度の範囲で調節するのが望ましい。さらに、このよう
な増感剤に加えて硬化を促進するために、例えばトリエ
タノールアミン、２−ジメチルアミノエタノール、ジメ
チルアミノ安息香酸、ジメチルアミノ安息香酸イソアミ
ル、ジオクチルアミノ安息香酸、ジメチルアミノ安息香
酸ラウリル等の第三級アミン類を塗布組成物中の電離放
射線硬化型上ツマ−及び／又はオリゴマー（プレポリマ
ー）に対して０．０５〜３重量％程度配合することもで
きる。The amount of the sensitizer used is 0.2 to 10% by weight, preferably 0.5 to 5% by weight, based on the ionizing radiation-curable monomer and/or oligomer (prepolymer) in the coating composition.
It is desirable to adjust within a range of degrees. Furthermore, in addition to such sensitizers, to accelerate curing, e.g. triethanolamine, 2-dimethylaminoethanol, dimethylaminobenzoic acid, isoamyl dimethylaminobenzoate, dioctylaminobenzoic acid, lauryl dimethylaminobenzoate, It is also possible to blend tertiary amines such as 0.05 to 3% by weight based on the ionizing radiation-curable upper layer and/or oligomer (prepolymer) in the coating composition.
紫外線照射用の光源としては、１〜５０個の紫外線ラン
プ（例えば数ｎｍＨｇから約１０気圧までの動作圧力を
有する低圧、中圧、高圧水銀ランプ）、キセノンランプ
、タングステンランプ等が用いられ、５０００〜８００
０ ｕＷｉｃｉ程度の強度を有する紫外線が好ましく照
射される。As a light source for ultraviolet irradiation, 1 to 50 ultraviolet lamps (for example, low-pressure, medium-pressure, high-pressure mercury lamps with operating pressures from several nmHg to about 10 atmospheres), xenon lamps, tungsten lamps, etc. are used, and 5000 ~800
Ultraviolet light having an intensity of about 0 uWici is preferably irradiated.
上記の構成によってシート基村上に電離放射線硬化樹脂
からなる保護層を保有した転写印刷用マスターシート（
１）が得られる。With the above configuration, a transfer printing master sheet (
1) is obtained.
なお、シート基材と保護層とは剥離を必要とする場合に
は容易に剥離できる程度に接着していることが必要であ
り、例えば、転写シートが接着剤層と剥離紙からなる場
合、シート基材と保護層の間における接合力は、保護層
上に形成される接着剤層と剥離紙との間における接合力
よりも強くなければならない。何故なら、もし該接着剤
層と剥離紙との間の接合力の方が、シート基材と保護層
との間の接合力よりも強いと、剥離紙を剥ぐ際にシート
基材と保護層との間が先に剥がれることになり実用適性
を欠くことになるからである。Note that the sheet base material and the protective layer must be adhered to such an extent that they can be easily peeled off if peeling is required. For example, if the transfer sheet consists of an adhesive layer and release paper, the sheet The bonding force between the substrate and the protective layer must be stronger than the bonding force between the adhesive layer formed on the protective layer and the release paper. This is because if the bonding force between the adhesive layer and the release paper is stronger than the bonding force between the sheet base material and the protective layer, when the release paper is peeled off, the sheet base material and the protective layer This is because the gap between the two ends will peel off first, making it impractical for practical use.
接合力を弱めるには、シート基材と保護層の間に、弗素
化合物やシリコン化合物等の離型剤からなる離型剤層を
設ければよく、逆に、接合力を付与するためには、電離
放射線硬化樹脂層にアミノ基、水酸基、カルボキシル基
等を有する密着性向上剤を混入えばよい。To weaken the bonding force, it is sufficient to provide a mold release agent layer made of a mold release agent such as a fluorine compound or silicone compound between the sheet base material and the protective layer. , an adhesion improver having an amino group, a hydroxyl group, a carboxyl group, etc. may be mixed into the ionizing radiation-curable resin layer.
次いで転写シート（４）として使用する場合について説
明する。Next, the case where it is used as a transfer sheet (4) will be explained.
まず、印刷層（５）は、通常のインキが使用でき、グラ
ビア印刷、スクリーン印刷、オフセット印刷等の方法で
図柄を形成できる。また、接着性インキを使用すれば、
印刷後接着剤を塗布する工程が省略できる。図柄の代わ
りに感熱染料、フォトクロミック物質等を機能性物質を
含む層であってもよい。First, for the printing layer (5), ordinary ink can be used, and patterns can be formed by methods such as gravure printing, screen printing, and offset printing. Also, if you use adhesive ink,
The process of applying adhesive after printing can be omitted. Instead of a pattern, it may be a layer containing a functional substance such as a heat-sensitive dye or a photochromic substance.
接着剤層（６）としては、アクリル系エマルジョン型、
アクリル系溶剤、アクリル系ホットメルト型等のアクリ
ル系の接着剤、ゴム系エマルジョン型、ゴム系溶剤型、
ゴム系ホットメルト型等のゴム系接着剤、シリコーン系
溶剤型、ウレタン系溶剤型又はビニルエーテル系等の一
般に知られている接着剤からなる層である。As the adhesive layer (6), acrylic emulsion type,
Acrylic solvent, acrylic adhesive such as acrylic hot melt type, rubber emulsion type, rubber solvent type,
This layer is made of a generally known adhesive such as a rubber hot melt adhesive, a silicone solvent adhesive, a urethane solvent adhesive, or a vinyl ether adhesive.
また、接着剤層を保護するなどの目的で、剥離紙を用い
てもよい。該剥離紙は、グラシン紙、クレーコート紙、
クラフト紙、上質紙、中質紙或いはこれらにポリエチレ
ン等をバリヤーコート或いはラミネートしたもの等に、
シリコン化合物や弗素化合物の如き離型剤を塗布又は含
浸したものを使用することが出来る。Further, a release paper may be used for purposes such as protecting the adhesive layer. The release paper is glassine paper, clay coated paper,
Kraft paper, high-quality paper, medium-quality paper, or those coated with a barrier coat or laminated with polyethylene, etc.
A material coated with or impregnated with a mold release agent such as a silicon compound or a fluorine compound can be used.
か（して得られた本発明に係る転写シートは、転写復電
子線硬化樹脂の保護層が図柄をカバーするため耐摩耗性
、耐薬品性等に優れてた転写図柄が得られる。In the transfer sheet according to the present invention obtained in this manner, the protective layer of the transfer electron beam curing resin covers the pattern, so that a transferred pattern with excellent abrasion resistance, chemical resistance, etc. can be obtained.
（実施例）
以下、本発明の実施例を記載するが、本発明がこれらの
実施例のみに限定されるものでないことは勿論である。(Examples) Examples of the present invention will be described below, but it goes without saying that the present invention is not limited only to these Examples.
なお、例中の部および％は、特に断らない限りそれぞれ
重量部および重量％を示す。Note that parts and % in the examples indicate parts by weight and % by weight, respectively, unless otherwise specified.
実施例１゜
■電子線硬化樹脂の調製
ポリエステルアクリレート ７０部ウレタン
アクリレート ２０部トリメチロール
プロパントリアクリレート１０部
を混合した。Example 1 Preparation of electron beam curable resin 70 parts of polyester acrylate 20 parts of urethane acrylate 10 parts of trimethylolpropane triacrylate were mixed.
■転写印刷用マスターシートの形成
厚さ３８μｍのポリエチレンテレフタレートフィルムの
上に、■で調製された電離放射線硬化型樹脂を乾燥重量
でｌ１ｇ／ｎ（となるようグラビアコート法により塗布
し、エレクトロンカーテン型電子線照射装置（ＣＢ １
５０型、ＥＳＩ社製）により、加速電圧が１７５ＫＶ、
照射線Ｗｋ ３０ Ｍｒａｄで電子線照射を行ない、樹
脂成分を硬化させて、転写印刷用マスターシートを得た
。■ Formation of master sheet for transfer printing On top of a polyethylene terephthalate film with a thickness of 38 μm, the ionizing radiation-curable resin prepared in (■) was applied by gravure coating to a dry weight of 11 g/n (electron curtain type). Electron beam irradiation device (CB 1
50 type, manufactured by ESI), the acceleration voltage is 175KV,
Electron beam irradiation was performed with irradiation radiation Wk 30 Mrad to harden the resin component to obtain a master sheet for transfer printing.
実施例２゜
■電子線硬化樹脂の調製
エポキシアクリレート ８０部ペアエ
リスリトールトリアクリレート １０部ヒドロキシエチ
ルアクリレート １０部ベンゾフェノン
３部を混合した。Example 2 Preparation of electron beam curable resin Epoxy acrylate 80 parts Pair Erythritol triacrylate 10 parts Hydroxyethyl acrylate 10 parts Benzophenone
Three parts were mixed.
■転写印刷用マスターシートの形成
厚さ３０μｍのナイロンフィルム上に、■で調製された
電離放射線硬化型樹脂を乾燥重量で１１ｇ／ｒｄとなる
ようグラビアコート法により塗布し、８０Ｗ／Ｃｌ１１
の高圧水銀灯で、３秒間紫外線照射を行ない転写印刷用
マスターシートを得た。■ Formation of master sheet for transfer printing On a nylon film with a thickness of 30 μm, the ionizing radiation curable resin prepared in (■) was applied by gravure coating to a dry weight of 11 g/rd.
A master sheet for transfer printing was obtained by irradiating ultraviolet rays for 3 seconds using a high-pressure mercury lamp.
比較例１
厚さ３８μｍのポリエチレンテレフタレートフィルムを
使用した。Comparative Example 1 A polyethylene terephthalate film with a thickness of 38 μm was used.
以上の如くして得られた３種類の転写印刷用マスターシ
ートに図柄をグラビア印刷し、接着剤をグラビアコート
法により塗布し転写シートを得、これらを耐摩耗性、耐
薬品性について評価を行い、その結果を表１に示した。Designs were gravure printed on the three types of master sheets for transfer printing obtained as described above, adhesive was applied by gravure coating method to obtain transfer sheets, and these were evaluated for abrasion resistance and chemical resistance. The results are shown in Table 1.
サンドペーパーでこすり、図柄の表面を観察した。 I rubbed it with sandpaper and observed the surface of the design.
○・・・画像表面に全く損傷がなかった。○: There was no damage to the image surface at all.
×・・・画像表面に著しく損傷した。x: The image surface was significantly damaged.
エチルアルコールを表面に滴下して指でこすり図柄の表
面を観察した。Ethyl alcohol was dropped onto the surface and rubbed with a finger to observe the patterned surface.
○・・・図柄の離脱は全くなかった。○...There was no pattern separation at all.
×・・・図柄が離脱し、著しく損傷した。×: The design came off and was significantly damaged.
（効果）
本発明の転写印刷マスターシートは、耐摩耗性、耐薬品
性等に優れてた転写シートを得ることができる。(Effects) The transfer printing master sheet of the present invention can provide a transfer sheet with excellent abrasion resistance, chemical resistance, and the like.
第 ／ 図Figure/Figure
第１図は本発明である転写印刷用マスターシートの層構
成を、第２図は本発明である転写シートの層構成をそれ
ぞれ説明するための横断面図である。
：転写印刷用マスターシート
：シート基材
：転写保護層
：転写シート
：印刷層
：接着剤層FIG. 1 is a cross-sectional view for explaining the layer structure of a master sheet for transfer printing according to the present invention, and FIG. 2 is a cross-sectional view for explaining the layer structure of a transfer sheet according to the present invention. : Master sheet for transfer printing: Sheet base material: Transfer protective layer: Transfer sheet: Printing layer: Adhesive layer
Claims (2)
樹脂からなるシート基材（２）と、該シート基材と剥離
可能で、電離放射線硬化樹脂に電離放射線の照射を行う
ことにより硬化せしめた転写保護層（３）を積層したこ
とを特徴とする転写印刷用マスターシート。(1) The master sheet for transfer printing (1) is composed of a sheet base material (2) made of synthetic resin, which can be peeled off from the sheet base material, and is cured by irradiating the ionizing radiation curable resin with ionizing radiation. A transfer printing master sheet characterized by laminating a transfer protective layer (3).
転写印刷用マスターシート（１）の転写保護層（３）側
に、印刷層（５）及び接着剤層（６）を設けたことを特
徴とする転写シート。(2) The configuration of the transfer sheet (4) includes a printing layer (5) and an adhesive layer (6) on the transfer protective layer (3) side of the transfer printing master sheet (1) according to claim (1). A transfer sheet characterized by the following.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18736088A JPH0236287A (en) | 1988-07-27 | 1988-07-27 | Master sheet for transfer printing and transfer sheet using said master sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18736088A JPH0236287A (en) | 1988-07-27 | 1988-07-27 | Master sheet for transfer printing and transfer sheet using said master sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0236287A true JPH0236287A (en) | 1990-02-06 |
Family
ID=16204633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18736088A Pending JPH0236287A (en) | 1988-07-27 | 1988-07-27 | Master sheet for transfer printing and transfer sheet using said master sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0236287A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9718023B2 (en) | 2010-11-04 | 2017-08-01 | Ube Industries, Ltd. | Gas separation membrane module and gas separation method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56166090A (en) * | 1980-05-26 | 1981-12-19 | Dainippon Printing Co Ltd | Manufacture of transfer sheet |
-
1988
- 1988-07-27 JP JP18736088A patent/JPH0236287A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56166090A (en) * | 1980-05-26 | 1981-12-19 | Dainippon Printing Co Ltd | Manufacture of transfer sheet |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9718023B2 (en) | 2010-11-04 | 2017-08-01 | Ube Industries, Ltd. | Gas separation membrane module and gas separation method |
| US10369515B2 (en) | 2010-11-04 | 2019-08-06 | Ube Industries, Ltd. | Gas separation membrane module and method for gas separation |
| US10765992B2 (en) | 2010-11-04 | 2020-09-08 | Ube Industries, Ltd. | Gas separation membrane module and method for gas separation |
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