JPH02292380A - Adhesive - Google Patents
AdhesiveInfo
- Publication number
- JPH02292380A JPH02292380A JP1113933A JP11393389A JPH02292380A JP H02292380 A JPH02292380 A JP H02292380A JP 1113933 A JP1113933 A JP 1113933A JP 11393389 A JP11393389 A JP 11393389A JP H02292380 A JPH02292380 A JP H02292380A
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- microcapsules
- component
- adhesion
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 97
- 239000000853 adhesive Substances 0.000 title claims abstract description 93
- 239000003094 microcapsule Substances 0.000 claims abstract description 45
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 239000002245 particle Substances 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims 1
- 239000002775 capsule Substances 0.000 abstract description 8
- 230000000903 blocking effect Effects 0.000 abstract description 6
- 238000013329 compounding Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 11
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 11
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 238000012695 Interfacial polymerization Methods 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000004202 carbamide Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920006173 natural rubber latex Polymers 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QOJQBWSZHCKOLL-UHFFFAOYSA-N 2,6-dimethylbenzaldehyde Chemical compound CC1=CC=CC(C)=C1C=O QOJQBWSZHCKOLL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 241000669298 Pseudaulacaspis pentagona Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000000227 bioadhesive Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007640 computer printing Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KRWWZDVIEFSIOT-UHFFFAOYSA-N ethenyl acetate;furan-2,5-dione Chemical compound CC(=O)OC=C.O=C1OC(=O)C=C1 KRWWZDVIEFSIOT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- MEFJMBSAHDEPGF-UHFFFAOYSA-N hexanedioic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)CCCCC(O)=O MEFJMBSAHDEPGF-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ARQTVSWBVIWYSF-UHFFFAOYSA-N prop-2-enamide;prop-2-enenitrile Chemical compound C=CC#N.NC(=O)C=C ARQTVSWBVIWYSF-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明はマイクロカプセルを含有する接着剤および該接
着剤を塗布した接着シートに関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an adhesive containing microcapsules and an adhesive sheet coated with the adhesive.
従来の技術
近年、コンピューターのプリント用シートに部分的に接
着剤を塗布し、データのプリントアウト後シートを接着
剤塗布部分で接着する方法が普及している。この方法は
特に金融機関から顧客への預貯金金額の通知、給与通知
、受験産業の採点通知等、個人の秘密情報の通知とその
コンピューター管理と云う二つの要請を満足させる手段
として今後共益々発展するものと思われる。BACKGROUND OF THE INVENTION In recent years, a method has become popular in which adhesive is partially applied to a computer printing sheet, and after data is printed out, the sheet is adhered at the adhesive-applied portions. This method will develop more and more in the future as a means to satisfy the two demands of notification of personal confidential information and computer management, especially for notifications from financial institutions to customers of deposit amounts, salary notifications, score notifications in the exam industry, etc. It seems to be.
一方、上記のごとき接着剤を塗布したプリント用シート
は、保管時、接着剤塗布部分で粘着し、プリンターへの
シート給送がスムーズに行なえない、プリンターへ接着
剤が付着し、プリンター損傷の原因となる等の問題があ
った。On the other hand, when the printing sheets coated with the adhesive described above stick to the adhesive-applied area during storage, the sheet cannot be fed smoothly to the printer, and the adhesive adheres to the printer, causing damage to the printer. There were problems such as.
この様な問題を解決するために接着剤に無機微粉末を配
合して、シートの積載による粘着やプリンターへの粘着
を防止する技術が提案されているが無機微粉末の配合は
同時に接着力自体を低下させることとなるため好ましく
ない。In order to solve this problem, a technology has been proposed in which fine inorganic powder is blended into the adhesive to prevent the sheets from sticking due to stacking and sticking to the printer. This is not preferable because it reduces the
また接着剤をマイクロカプセル化し、粘着を防止した上
でこれを適当なバインダーでプリント用シートの所用部
分に付着させる方法もあるが、この方法も、マイクロカ
プセルの殼成分やバインダー成分により接着力が低下す
るため問題がある。Another method is to microcapsule the adhesive to prevent it from sticking, and then attach it to the desired area of the printing sheet using a suitable binder, but this method also has a strong adhesive force due to the shell components and binder components of the microcapsules. There is a problem because it decreases.
発明が解決しようとする課題
本発明は接着剤による粘着性にもとづくシートどうしの
粘着やプリンター等への粘着が軽減され、加えて接着後
は十分な接着強度が得られる接着剤塗布シートおよびそ
れに適した接着剤を提供することを目的とする。Problems to be Solved by the Invention The present invention provides an adhesive-coated sheet that reduces adhesion between sheets due to the adhesiveness of the adhesive and adhesion to a printer, etc., and also provides sufficient adhesive strength after adhesion, and is suitable therefor. The purpose is to provide adhesives that
課題を解決するだめの手段
本発明は（１）接着成分および（２）接着補助剤含有マ
イクロカプセルを含有する接着剤および基材シート上の
少なくとも一部に（１）接着成分および（２）接着補助
剤を含むマイクロカプセルが付着しているシートに関す
る。Means for Solving the Problems The present invention provides an adhesive containing (1) an adhesive component and (2) microcapsules containing an adhesion auxiliary agent, and at least a portion of the base sheet. The present invention relates to a sheet to which microcapsules containing an adjuvant are attached.
本発明接着剤塗布シートは接着成分に粉末状のマイクロ
カプセルが配合されているため保存中や未使用時には、
粘着性を示さないが、使用に際してマイクロカプセルを
破壊するとマイクロ力ブセル中の接着補助剤が浸出して
接着成分と接触し、接着成分か粘着性を発現する。Since the adhesive-coated sheet of the present invention contains powdered microcapsules as an adhesive component, it will
Although it does not exhibit tackiness, when the microcapsules are destroyed during use, the adhesion aid in the microcapsules leaches out and comes into contact with the adhesive component, causing the adhesive component to develop tackiness.
本発明に用いる接着成分は、従来ンート類の接着や粘着
に一般に使用されている。天然ゴム、ブチルゴム、スチ
レンブタジエンゴム、インプレンゴム等のゴム系接着剤
、アクリル系ポリマー、酢酸ビニル系ポリマー、ポリビ
ニルアルコー４，ポリビニルピロリドン、水溶性セルロ
ース誘導体、塩化ビニル／酢酸ビニル共重合体等の合成
接着剤、α−でん粉、にかわ、デキストリン、カゼイン
、大豆グルー等の天然接着剤等が例示される。The adhesive component used in the present invention has been generally used for adhesion and adhesion of sheets. Synthesis of rubber adhesives such as natural rubber, butyl rubber, styrene-butadiene rubber, imprene rubber, acrylic polymers, vinyl acetate polymers, polyvinyl alcohol 4, polyvinylpyrrolidone, water-soluble cellulose derivatives, vinyl chloride/vinyl acetate copolymers, etc. Examples include natural adhesives such as adhesives, α-starch, glue, dextrin, casein, and soybean glue.
これらの接着成分は必らずしもそれ自体粘着性を示す必
要はないが接着補助剤と接触することにより粘着性およ
び接着性を発現するようなものであればよい。These adhesive components do not necessarily have to exhibit tackiness per se, but may be ones that exhibit tackiness and adhesion upon contact with the adhesion auxiliary agent.
接着補助剤は接着成分と接触して粘着性および接着性を
発現するようなものであり、それ自体が接着成分であっ
てもよく、あるいは、全く接着性も粘着性も示さないも
のであってもよい。The adhesion aid is one that develops tackiness and adhesion upon contact with the adhesive component, and may itself be an adhesive component, or it may exhibit no adhesive or tackiness at all. Good too.
この様な接着補助剤の例は、接着成分用の溶剤可塑剤、
軟化剤、粘着付与剤、粘着剤あるいはそれ自体接着成分
であってもよい。例えばマイクロカプセルの外にある接
着成分が水溶性のポリマーあるいは水と接して接着性を
発現するような成分、例えばポリビニルアルコーノ呟に
かわ、デキストリン等の場合マイクロカプセル化される
接着補助剤は水であってもよい。また溶剤で軟化する接
着成分に対しては接着補助剤は溶剤であってよい。Examples of such adhesion aids are solvent plasticizers for adhesive components;
It may be a softener, a tackifier, an adhesive or an adhesive component itself. For example, if the adhesive component outside the microcapsules is a water-soluble polymer or a component that develops adhesive properties when in contact with water, such as polyvinyl alcohol glue, dextrin, etc., the adhesion aid to be microencapsulated is water-soluble. There may be. Also, for adhesive components that are softened by solvents, the adhesion aid may be a solvent.
粘着付与剤としてはロジン、ロジンエステル、水添ロジ
ン、水添ロジンエステル、重合口ジン、重合口ジンエス
テル、変性口ジンエステル、芳香族系石油樹脂、クマロ
ンインデン樹脂、ｍ−キシレンーホルムアルデヒド樹脂
、フェノール樹脂、脂肪酸系石油樹脂、脂環族飽和炭化
水素樹脂、テルベン樹脂等が例示される。Tackifiers include rosin, rosin ester, hydrogenated rosin, hydrogenated rosin ester, polymerized gin, polymerized gin ester, modified gin ester, aromatic petroleum resin, coumaron indene resin, m-xylene-formaldehyde resin. , phenol resin, fatty acid petroleum resin, alicyclic saturated hydrocarbon resin, terbene resin, and the like.
粘着成分としては酢酸ビニルー無水マレイン酸共重合樹
脂、アクリル系共重合樹脂、酢酸ビニルーアクリル系共
重合樹脂、天然ゴム、ＳＢＲ等が例示される。Examples of the adhesive component include vinyl acetate-maleic anhydride copolymer resin, acrylic copolymer resin, vinyl acetate-acrylic copolymer resin, natural rubber, and SBR.
ロジン類は適区な溶剤に稀釈して用いてもよい。Rosins may be used after being diluted with an appropriate solvent.
マイクロカプセルには接着補助剤に加えて適当な添加剤
、例えば水や溶剤のマイクロカプセルを容易にし保存性
を向上させるだめの有機また無機の吸着剤、粘度調整剤
、酸化防止剤、香料等を加えてもよい。In addition to adhesion aids, the microcapsules may contain suitable additives, such as organic or inorganic adsorbents, viscosity modifiers, antioxidants, fragrances, etc. that facilitate microcapsule formation in water or solvents and improve storage stability. May be added.
接着補助剤のマイクロカプセル化は、成書゛′マイクロ
カプセル その製法性質応用″（近藤保、小石真純著）
等に例示されているインサイチュ法や界面重合法等の方
法により行えばよい。Microencapsulation of adhesion aids has been described in the book ``Microcapsules: Application of their manufacturing method and properties'' (written by Tamotsu Kondo and Masumi Koishi).
This may be carried out by an in-situ method or an interfacial polymerization method as exemplified by et al.
特に耐熱性に優れＩ；インサイチコ，法でのカプセル化
が良好である。In particular, it has excellent heat resistance and can be encapsulated well in situ.
界面重合法でのカプセルはポリイソシアネートとポリア
ミン、ポリイソシアネートとグリコール類との反応によ
るポリウレタン壁カプセル、多塩基酸ハライドとポリア
ミンとの反応によるポリアミド壁カプセル等がある。Capsules produced by the interfacial polymerization method include polyurethane wall capsules produced by the reaction of polyisocyanate and polyamine, polyisocyanate and glycols, and polyamide wall capsules produced by the reaction of polybasic acid halide and polyamine.
インサイチュ法でのカプセルは、尿素又はメラミンと縮
合反応による尿素又はメラミンホルムアルデヒド壁カプ
セルがある。又ラジカル重合反応を利用したアクリルモ
ノマーの共重合反応によるアクリル樹脂壁カプセル等が
ある。In-situ capsules include urea or melamine formaldehyde wall capsules produced by condensation reaction with urea or melamine. There are also acrylic resin wall capsules produced by a copolymerization reaction of acrylic monomers using a radical polymerization reaction.
本発明に用いられるマイクロカプセルの大きさは、１〜
５００μｍ程度、特に３〜５０μｍが適当である。The size of the microcapsules used in the present invention is 1 to 1.
Approximately 500 μm, particularly 3 to 50 μm is appropriate.
本発明接着剤は、さらに必要ならば無機または宵機微粉
末を配合し、接着剤の粘着性を調節してもよい。無機微
粉末の例としてはシリカゲル、活性白土、白鱗、銀鱗、
カオリン、タルク、カオリンクレー、炭酸カルシウム、
ベントナイト、けいそう土、ガラスビーズ等、有機微粉
末の例としては、コンスターチ、精製でん粉、樹脂ビー
ズ等が例示される。The adhesive of the present invention may further contain an inorganic or organic fine powder, if necessary, to adjust the tackiness of the adhesive. Examples of inorganic fine powders include silica gel, activated clay, white scale, silver scale,
Kaolin, talc, kaolin clay, calcium carbonate,
Examples of organic fine powders such as bentonite, diatomaceous earth, and glass beads include corn starch, purified starch, and resin beads.
さらに塗布を容易にするための稀釈剤や軟化剤等を配合
してもよい。Furthermore, a diluent, a softener, etc. may be added to facilitate application.
本発明接着剤は、接着剤成分中に接着補助剤含有マイク
ロカプセルを分散させることにより調製してもよい。接
着剤成分はそれ自体水またはマイクロカプセルを溶解ま
たは軟化しない揮発性の溶剤に溶解もしくは分散したも
のでもよく、あるいは、マイクロカプセルを軟化または
溶融しない温度で液化する接着成分であってもよい。The adhesive of the invention may be prepared by dispersing microcapsules containing an adhesion aid in the adhesive component. The adhesive component itself may be dissolved or dispersed in water or a volatile solvent that does not dissolve or soften the microcapsules, or it may be an adhesive component that liquefies at a temperature that does not soften or melt the microcapsules.
接着剤の付着したシートは、上記接着成分中にマイクロ
カプセルが分散混合した溶剤型または溶融型組成物をシ
ートの所望部分に塗布または印刷した後、溶剤を揮発さ
せるか、冷却することにより製造してもよく、あるいは
接着成分を予め塗布した後マイクロカプセルを付着乾燥
して製造してもよい。シートとしては、紙、布、プラス
チックフィルム、金属箔等様々のものが例示されるが、
紙が最も一般的である。The adhesive-attached sheet is produced by applying or printing a solvent-type or melt-type composition in which microcapsules are dispersed and mixed in the above-mentioned adhesive component on a desired part of the sheet, and then evaporating the solvent or cooling it. Alternatively, the adhesive component may be applied in advance and then the microcapsules are attached and dried. Examples of the sheet include paper, cloth, plastic film, metal foil, etc.
Paper is the most common.
塗布量は特に限定的ではないが３〜１００ｇ／ｍ”、特
に５〜３０ｇ／ｍ”が適当である。The coating amount is not particularly limited, but 3 to 100 g/m'', particularly 5 to 30 g/m'' is appropriate.
本発明接着剤は、感熱または感圧接着剤等として用い得
るが特に感圧接着剤として有用である。The adhesive of the present invention can be used as a heat-sensitive or pressure-sensitive adhesive, and is particularly useful as a pressure-sensitive adhesive.
近年、シートにコンピューター等に入力されている情報
を記録する際、ゼログラフィ一方式等のノンインパクト
プリンターが多く使用されるようになって来ており、こ
のノンインパクトプリンターのうち、トナーを用いてプ
リント像を形成するものにあってはプリント像の定着を
加熱方式によって行なっている。従ってプリント用シー
トにプリント後封着或は綴じ合わせシートにするために
予め封着部に熱により軟化し接着性を示す感熱接着剤を
塗布するかあるいは熱によりマイクロカプセルが破壊し
て、内部の接着剤が浸出して接着性を示す型の感熱接着
剤を塗布したものに於では、定着の際の加熱によって接
着剤が軟化してプリンターに付着する傾向がある。同様
に、シートが連続紙の場合、積み重ねによってシートど
うしの粘着がおこりプリンターへのシート送給が困難と
なる。In recent years, non-impact printers such as xerographic printers have been increasingly used to record information entered into computers, etc. on sheets. In those that form a printed image, the printed image is fixed by a heating method. Therefore, in order to seal or stitch the printing sheet after printing, it is necessary to apply a heat-sensitive adhesive that softens and exhibits adhesive properties to the sealing part in advance, or the microcapsules are destroyed by heat and the internal parts are removed. When a type of heat-sensitive adhesive that exhibits adhesive properties by leaching out of the adhesive is applied, the adhesive tends to soften due to heating during fixing and adhere to the printer. Similarly, when the sheets are continuous paper, stacking causes the sheets to stick together, making it difficult to feed the sheets to the printer.
これを防止するため無機粉末等を多量に用いると接着性
が低下する。本発明では、定着時の加熱により、マイク
ロカプセル外の接着成分が軟化しても、粘着性を示さな
いだけの多量のマイクロカプセルを配合することができ
る。多量のマイクロカプセルを配合してもカプセル中に
接着補助剤（必要なら接着成分）を含んでいるため、接
着時マイクロカプセルを破壊することにより、外部にあ
る接着成分を活性化し得るので接着性や粘着性を損うこ
とがない。To prevent this, if a large amount of inorganic powder or the like is used, the adhesiveness will be reduced. In the present invention, even if the adhesive component outside the microcapsules is softened by heating during fixing, a large amount of microcapsules can be blended so as not to exhibit tackiness. Even if a large amount of microcapsules are blended, since the capsules contain an adhesion aid (adhesive component if necessary), by destroying the microcapsules during adhesion, the external adhesive component can be activated, resulting in poor adhesion. No loss of adhesion.
本発明接着剤を上記のごときプリント像の定着を加熱で
行なう記録方式に用いるときは、マイクロカプセルが圧
力によって破壊する感圧接着剤として調製するのが好ま
しい。感圧接着剤を調製する上で特に有用な接着成分は
は天然ゴムを主剤とする接着成分である。天然ゴムは熱
による軟化が小さく、熱安定性に優れているため、本発
明マイクロカプセルの効果と相俟って一層優れた結果が
得られる。感圧接着剤として有用なその他の接着成分の
例はスチレンプタジエンゴム、アクリル系ポリマー、酢
酸ビニル系ポリマー、ポリビニルアルコール等である。When the adhesive of the present invention is used in the above-mentioned recording system in which the fixation of a printed image is carried out by heating, it is preferably prepared as a pressure-sensitive adhesive whose microcapsules are destroyed by pressure. A particularly useful adhesive component in preparing pressure sensitive adhesives is a natural rubber-based adhesive component. Since natural rubber is less susceptible to softening due to heat and has excellent thermal stability, in combination with the effects of the microcapsules of the present invention, even more excellent results can be obtained. Examples of other adhesive components useful as pressure sensitive adhesives include styrene-ptadiene rubber, acrylic polymers, vinyl acetate polymers, polyvinyl alcohol, and the like.
本発明接着剤を感圧接着剤として用いるときの特に好ま
しいマイクロカプセルの殼形成成分は、アクリロニトリ
ルを主成分とする共重合樹脂あるいは尿素又はメラミン
ホルムアルデヒド樹脂である。When the adhesive of the present invention is used as a pressure-sensitive adhesive, a particularly preferred microcapsule shell-forming component is a copolymer resin containing acrylonitrile as a main component, or a urea or melamine formaldehyde resin.
感圧接着剤として用いる上で特に有用な接着補助剤は接
着成分がゴム系接着剤の場合は、ロジン、ロシンエステ
ル、水添ロジン、水添ロジンエステル、変性口ジンエス
テル、重合口ジンエステノ呟芳香族系又は脂肪族系石油
樹脂、クマロンインデン樹脂、ｍ−キシレンホルムアル
デヒド樹脂、フェノール樹脂、テルペン樹脂およびトル
エン、キシレン、酢酸エチル溶解液等である。接着成分
がアクリル系ポリマーおよび酢酸ビニル系ポリマーのと
きは、トルエン、キシレン、酢酸エチル、酢酸ブチル、
メチルエチルケトン等の溶剤又は上記溶剤に溶解したア
クリル系接着剤等である。Particularly useful adhesion aids for use as pressure-sensitive adhesives include rosin, rosin ester, hydrogenated rosin, hydrogenated rosin ester, modified rosin ester, polymerized rosin ester, and polymerized rosin ester when the adhesive component is a rubber adhesive. These include group-based or aliphatic-based petroleum resins, coumaron indene resins, m-xylene formaldehyde resins, phenol resins, terpene resins, and toluene, xylene, and ethyl acetate solutions. When the adhesive component is acrylic polymer or vinyl acetate polymer, toluene, xylene, ethyl acetate, butyl acetate,
The adhesive may be a solvent such as methyl ethyl ketone or an acrylic adhesive dissolved in the above solvent.
接着補助剤をマイクロカプセル化するには従来公知のマ
イクロカプセル化法を適宜使用すればよく、あるいは下
記のごとき特殊な方法を採用してもよい。In order to microcapsule the adhesion auxiliary agent, conventionally known microencapsulation methods may be used as appropriate, or special methods such as those described below may be employed.
接着補助剤が粘着剤の場合は例えば粘着成分用モノマー
を予め非粘着性シェルでマイクロカプセル化し、次いで
上記七ノマーをマイクロカプセル内部で重合させる方法
、粘着成分用七ノマーを予めエマルジョン重合し、次い
で非粘着性シェル形成用七ノマーを上記エマルジョン中
で重合させ、粘着剤をマイクロカプセル化する方法、シ
ェル形成と粘着成分の重合を同時に行なう方法等がある
。When the adhesion auxiliary agent is an adhesive, for example, the monomer for the adhesive component is microencapsulated in advance with a non-adhesive shell, and then the above heptanomer is polymerized inside the microcapsules, or the heptanomer for the adhesive component is emulsion polymerized in advance, and then There is a method in which a heptanomer for forming a non-adhesive shell is polymerized in the above emulsion to microcapsule the adhesive, and a method in which shell formation and polymerization of the adhesive component are performed simultaneously.
補助剤が溶剤や可塑剤の場合は、溶剤や可塑剤にンニル
形成用モノマーを溶解させ、重合用触媒を溶解した水性
媒体でエマルジョンを形成させて、界面重合を行なわせ
てもよい。When the auxiliary agent is a solvent or a plasticizer, interfacial polymerization may be carried out by dissolving the polymer-forming monomer in the solvent or plasticizer and forming an emulsion in an aqueous medium containing a polymerization catalyst dissolved therein.
あるいはまた補助剤か水の場合は例えば特願昭６３−３
１８８８５号に記載のごとく、水または水溶性物質をそ
れに不溶性の無機粉末の存在下に、水または水溶性物質
を溶解しない媒体中に乳化させ、この乳化系中で七ノマ
ーを重合させることによって得ればよい。Or, in the case of auxiliary agent or water, for example, Japanese Patent Application No. 63-3
18885, by emulsifying water or a water-soluble substance in the presence of an inorganic powder insoluble therein in a medium that does not dissolve the water or water-soluble substance, and polymerizing the heptanomer in this emulsion system. That's fine.
以下、実施例をあげて本発明を説明する。The present invention will be explained below with reference to Examples.
実施例！
アクリロニトリル
アクリルアミド
アゾビスイソブチルニトリル
イオン交換水
９０部
１０部
３部
４００部
食塩
４５部
アジピン酸ジエタノールアミン縮金物 ２部を
ホモミクサー（特殊機化工業（株）製）にて８０００回
転でＩＯ分間乳化分散した後、窒素気流中にて、８０′
Ｃで２０時間インサイチュ重合を行い、平均粒径１０μ
のマイクロカプセルを２３０重量部を得た。Example! Acrylonitrile acrylamide azobisisobutyl nitrile 90 parts of ion-exchanged water 10 parts 3 parts 400 parts of common salt 45 parts of adipic acid diethanolamine condensate 2 parts were emulsified and dispersed in a homomixer (manufactured by Tokushu Kika Kogyo Co., Ltd.) at 8000 rpm for IO minutes. , in a nitrogen stream, 80'
In-situ polymerization was carried out at C for 20 hours, and the average particle size was 10μ.
230 parts by weight of microcapsules were obtained.
（２）感圧接着剤ｌの調製：
上で得たマイクロカプセルを用い以下の処方でエマルジ
ョン型の感圧接着剤ｌを得た。(2) Preparation of pressure-sensitive adhesive 1: Using the microcapsules obtained above, an emulsion-type pressure-sensitive adhesive 1 was obtained according to the following formulation.
処方 重量部天然ゴムラテッ
ク？ ８０マイクロカプセル（中心粒径
ｌＯμ）１８分１１１（ＰＯＥアルキルフエニル
２エーテル）
＊ｌ：日本フラー株式会社製、ＪＦ−５０５有効固形分
３５重量％
（３）感圧接着シートの調製：
上記接着剤１をＯＣＲ紙（７０ｇ／ｍり上に７ｇ／ｍ”
の量で塗布し、１００’Ｃ！で１分間乾燥し、感圧接着
シートを得た。Prescription Parts by weight Natural rubber latex? 80 microcapsules (center particle size lOμ) 18 minutes 111 (POE alkyl phenyl
2 ether) *l: JF-505 manufactured by Nippon Fuller Co., Ltd. Effective solid content 35% by weight (3) Preparation of pressure-sensitive adhesive sheet: The above adhesive 1 was coated on OCR paper (70 g/m"
Apply at 100'C! The mixture was dried for 1 minute to obtain a pressure-sensitive adhesive sheet.
接着剤塗布部は指で触っても全く粘着性を示さず、これ
を１０枚積み重ねて全体に３ ０ ０ ｇ／ｍ２の荷重
をかけ温度６０゜Ｃ１相対湿度８０％ＲＨで３０日間保
存したが紙どうしの粘着は全く生じなかった（プロツキ
ング性）。The adhesive-applied area did not show any stickiness when touched with a finger, and 10 sheets were stacked and a load of 300 g/m2 was applied to the whole and stored for 30 days at a temperature of 60° C. and a relative humidity of 80% RH. There was no adhesion between the papers (blocking property).
この感圧接着シートｌを表裏重ねてｌ Ｏ Ｏ ｋｇ／
ｍ２のローラー圧をかけたところ、接着ノート上のマイ
クロカプセルが破壊しンートは完全に接着した。Layer this pressure-sensitive adhesive sheet l on the front and back to make l O O kg/
When a roller pressure of m2 was applied, the microcapsules on the adhesive notebook were destroyed and the notebook was completely adhered.
実施例２
（１）マイクロカプセルの調製：
日石ネオポリマーＬ−９０ （日本石油化学（株）製
）キシレン
を予め、溶解し、スクリソブセット５２０（モンサンド
社製、スチレンー無水マレイン酸共重合体）１００部と
水酸化ナトリウム８部をイオン交換水１９００部に加熱
溶解したスチレンー無水マレイ７０部
７０部
ン酸共重合体の部分加水分解物の５重量％水溶液中にて
５０゜Ｃの温度でホモミ久サ−（特殊機化工業（株）製
）で７０００回転でｌＯ分間乳化分散した後、５０°Ｃ
の温度でコーラミンＴ−３３（三井東圧化学（株）製
メチル化メチロールメラミン樹脂水溶液）８０部を滴下
混合し、２Ｎ塩酸にてＰＨを５．５に調製し、５０゜Ｃ
の温度で１２時間反応し、平均粒径ｌ５μのマイクロカ
プセルを１８０重量部得た。Example 2 (1) Preparation of microcapsules: Nisseki Neopolymer L-90 (manufactured by Nippon Petrochemicals Co., Ltd.) xylene was dissolved in advance, and Scrisobuscet 520 (manufactured by Monsando Co., Ltd., styrene-maleic anhydride copolymer) was dissolved in advance. ) and 8 parts of sodium hydroxide were heated and dissolved in 1,900 parts of ion-exchanged water. 70 parts of styrene-male anhydride and 70 parts of hydrochloric acid copolymer were dissolved in a 5% by weight aqueous solution of a partial hydrolyzate at a temperature of 50°C. After emulsifying and dispersing for 10 minutes at 7,000 rotations using Homomi Kusa (manufactured by Tokushu Kika Kogyo Co., Ltd.), the temperature was 50°C.
Colamine T-33 (manufactured by Mitsui Toatsu Chemical Co., Ltd.) at a temperature of
80 parts of methylated methylolmelamine resin aqueous solution were mixed dropwise, the pH was adjusted to 5.5 with 2N hydrochloric acid, and the mixture was heated at 50°C.
The mixture was reacted for 12 hours at a temperature of 180 parts by weight of microcapsules with an average particle size of 15 μm.
得られたマイクロカプセルの中心粒径は１５μであった
。The center particle size of the obtained microcapsules was 15μ.
（２）感圧接着剤２の調製：
以下の処方で各成分を均一に混合し、エマルジョン型の
感圧接着剤２を調製した。(2) Preparation of pressure-sensitive adhesive 2: Each component was mixed uniformly according to the following formulation to prepare an emulsion-type pressure-sensitive adhesive 2.
処方 重量部天然ゴムラテッ
クス＊８５
マイクロカプセル（中心粒径ｌ５μ）１３分散剤
２（３）感圧接着シート２の
調製：
上記感圧接着剤２を用い実施例ｌと同様にして感圧接着
シート２を調製した。この感圧接着シート２は表面粘着
性は示さず優れたブロッキング性を示すがこれを実施例
ｌと同様に加圧すると優れた接着性を示した。Formula Parts by weight Natural rubber latex *85 Microcapsules (center particle size 15μ) 13 Dispersant
2(3) Preparation of pressure-sensitive adhesive sheet 2: A pressure-sensitive adhesive sheet 2 was prepared using the pressure-sensitive adhesive 2 described above in the same manner as in Example 1. This pressure-sensitive adhesive sheet 2 exhibited no surface tackiness and exhibited excellent blocking properties, but when pressed in the same manner as in Example 1, it exhibited excellent adhesion.
比較例ｌおよび２
以下の処方を用いる以外実施例１と同様にして感圧接着
シートを調製し、実施例ｌと同様に表面粘着性、ブロッ
キング性および接着性を評価した。Comparative Examples 1 and 2 Pressure-sensitive adhesive sheets were prepared in the same manner as in Example 1, except that the following formulations were used, and the surface tackiness, blocking properties, and adhesive properties were evaluated in the same manner as in Example 1.
処方 比較例１２
（重量部） （重量部）
＊ｌ
天然ゴムラテックス ７０ ８５ベントナイ
ト ２８
（中心粒径ｌＯμ）
スチレンビーズ ー ｌ３（中心粒径
３０μ）
分散剤（ＰＯＥアルキル ２２
フェニルエーテル）
比較例ｌおよび２の感圧接着シートはいずれも表面粘着
性を示さず、ブロッキング性を有していたが、加圧後の
接着性が著しく劣っていた。Formulation Comparative Example 12 (Parts by weight) (Parts by weight) *l Natural rubber latex 70 85 Bentonite 28 (center particle size lOμ) Styrene beads - l3 (center particle size 30μ) Dispersant (POE alkyl 22 phenyl ether) Comparative example l and None of the pressure-sensitive adhesive sheets No. 2 exhibited surface tackiness and had blocking properties, but the adhesiveness after pressurization was significantly poor.
発明の効果
本発明接着剤を塗布して得られる接着シートは表面粘着
性を示さず、優れたブロッキング性を有すると同時に加
圧または加熱によりマイクロカプセルを破壊すると優れ
た接着性を示す。従って、個人の秘密情報等を打出しそ
のまま封緘するコンピューター打出用のシートまたはそ
れ用の接着剤として特に有用である。Effects of the Invention The adhesive sheet obtained by applying the adhesive of the present invention exhibits no surface tackiness, has excellent blocking properties, and at the same time exhibits excellent adhesion when the microcapsules are destroyed by pressure or heating. Therefore, it is particularly useful as a sheet for embossing computers or as an adhesive therefor, in which personal secret information is stamped out and then sealed.
特許出願人松本油脂製薬株式会社Patent applicant Matsumoto Yushi Pharmaceutical Co., Ltd.
Claims (1)
マイクロカプセルを含有する接着剤。 ２、接着補助剤が接着成分、粘着剤、接着成分用溶剤、
または接着成分用可塑剤である請求項１に記載の接着剤
。 ３、マイクロカプセルが粒径５〜５００μｍである請求
項１に記載の接着剤。 ４、接着成分（１）とマイクロカプセルとの配合比（重
量）が９７：３〜５：９５である請求項１に記載の接着
剤。 ５、請求項１に記載の接着剤を基材シートの少なくとも
一部分に塗布した接着シート。[Claims] 1. An adhesive containing microcapsules containing (1) an adhesive component and (2) an adhesion auxiliary agent. 2. The adhesion aid is an adhesive component, an adhesive, a solvent for the adhesive component,
The adhesive according to claim 1, which is a plasticizer for adhesive components. 3. The adhesive according to claim 1, wherein the microcapsules have a particle size of 5 to 500 μm. 4. The adhesive according to claim 1, wherein the blending ratio (weight) of the adhesive component (1) and the microcapsules is 97:3 to 5:95. 5. An adhesive sheet comprising at least a portion of a base sheet coated with the adhesive according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1113933A JPH02292380A (en) | 1989-05-02 | 1989-05-02 | Adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1113933A JPH02292380A (en) | 1989-05-02 | 1989-05-02 | Adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02292380A true JPH02292380A (en) | 1990-12-03 |
Family
ID=14624833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1113933A Pending JPH02292380A (en) | 1989-05-02 | 1989-05-02 | Adhesive |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02292380A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5322731A (en) * | 1993-03-09 | 1994-06-21 | Minnesota Mining And Manufacturing Company | Adhesive beads |
| WO1996007708A1 (en) * | 1994-09-07 | 1996-03-14 | The Mead Corporation | Microcapsule-containing cohesive coating |
| US6084010A (en) * | 1997-02-05 | 2000-07-04 | H.B. Fuller Licensing & Financing, Inc. | Hot melt adhesive comprising an encapsulated ingredient |
| JP2001219487A (en) * | 2000-02-10 | 2001-08-14 | Mitsubishi Heavy Ind Ltd | Method and apparatus for manufacturing paper product, paper bonding paste and method for manufacturing microcapsule of paper bonding paste |
| JP2019508139A (en) * | 2016-03-01 | 2019-03-28 | ケーシーアイ ライセンシング インコーポレイテッド | Drapes used with medical treatment systems |
-
1989
- 1989-05-02 JP JP1113933A patent/JPH02292380A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5322731A (en) * | 1993-03-09 | 1994-06-21 | Minnesota Mining And Manufacturing Company | Adhesive beads |
| US5536786A (en) * | 1993-03-09 | 1996-07-16 | Minnesota Mining And Manufacturing Company | Adhesive beads |
| US5625006A (en) * | 1993-03-09 | 1997-04-29 | Minnesota Mining And Manufacturing Company | Adhesive beads |
| WO1996007708A1 (en) * | 1994-09-07 | 1996-03-14 | The Mead Corporation | Microcapsule-containing cohesive coating |
| US6084010A (en) * | 1997-02-05 | 2000-07-04 | H.B. Fuller Licensing & Financing, Inc. | Hot melt adhesive comprising an encapsulated ingredient |
| JP2001219487A (en) * | 2000-02-10 | 2001-08-14 | Mitsubishi Heavy Ind Ltd | Method and apparatus for manufacturing paper product, paper bonding paste and method for manufacturing microcapsule of paper bonding paste |
| JP2019508139A (en) * | 2016-03-01 | 2019-03-28 | ケーシーアイ ライセンシング インコーポレイテッド | Drapes used with medical treatment systems |
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