JPH0224138A - Manufacture of decorative sheet - Google Patents
Manufacture of decorative sheetInfo
- Publication number
- JPH0224138A JPH0224138A JP17418188A JP17418188A JPH0224138A JP H0224138 A JPH0224138 A JP H0224138A JP 17418188 A JP17418188 A JP 17418188A JP 17418188 A JP17418188 A JP 17418188A JP H0224138 A JPH0224138 A JP H0224138A
- Authority
- JP
- Japan
- Prior art keywords
- film
- coating
- pattern
- decorative sheet
- printed pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 15
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 15
- 229920006267 polyester film Polymers 0.000 claims abstract description 12
- 239000012508 resin bead Substances 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims description 19
- 238000010030 laminating Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 20
- 238000000576 coating method Methods 0.000 abstract description 20
- 239000002904 solvent Substances 0.000 abstract description 10
- 239000011230 binding agent Substances 0.000 abstract description 9
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 7
- -1 polyethylene terephthalate Polymers 0.000 abstract description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 3
- 230000009021 linear effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000011324 bead Substances 0.000 description 9
- 239000011120 plywood Substances 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- 238000004049 embossing Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は建装材、連装部材、家具、家電機器、車輌内装
等の表面材として用いられる化粧シートの製造方法に関
する。更に詳しくは、耐擦傷性に優れた艶消し状表面を
持ち、しかも絵柄の直線性や寸法安定性に優れた柔軟性
の化粧シートの製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method for manufacturing a decorative sheet used as a surface material for building materials, connecting members, furniture, home appliances, vehicle interiors, etc. More specifically, the present invention relates to a method for producing a flexible decorative sheet that has a matte surface with excellent scratch resistance, and also has excellent linearity and dimensional stability in patterns.
〈従来の技術〉
柔軟性のある艶消しの化粧シートとしてはポリ塩化ビニ
ルフィルム等の表面に細かいエンボスを施したもの、ポ
リ塩化ビニルフィルム等の表面にシリカ等の体質顔料を
混合したマット塗料を塗布したものが一般的である。し
かし、エンボスによるものは、基材へのラミネート等の
後加工時の熱又は圧によりエンボスがもどって光沢が上
がる。<Conventional technology> Flexible matte decorative sheets include polyvinyl chloride films with fine embossing on the surface, and matte paints mixed with extender pigments such as silica on the surface of polyvinyl chloride films. Painted ones are common. However, when embossing is used, the embossing is restored by heat or pressure during post-processing such as lamination to the base material, and the gloss increases.
また、いずれの場合も耐擦傷性がなく、擦傷部分の光沢
が上がる。Furthermore, in either case, there is no scratch resistance, and the gloss of the scratched area increases.
一方、弾性球状樹脂ビーズを混合した艶消し用塗料が耐
擦傷性の高い塗料として知られているが、樹脂ビーズを
均一に分散するため、キジロール等の高沸点溶剤を用い
る必要があり、塗布時にこの溶剤を乾燥するために８０
″Ｃ以上の熱を必要とする。On the other hand, matte paints mixed with elastic spherical resin beads are known as paints with high scratch resistance, but in order to uniformly disperse the resin beads, it is necessary to use a high boiling point solvent such as Kijiroll, and during application. 80 to dry this solvent
Requires heat of ``C or higher.
この結果、塗布基材たるポリ塩化ビニルフィルムに伸縮
が生じ、絵柄の直線性や化粧シートの寸法安定性が損な
われる。なお、本発明において絵柄の直線性とは直線状
又は格子状の絵柄が左右にぶれないことをいい、直接性
が損なわれるとはすなわち、熱と張力によって絵柄が左
右にぶれて歪むことをいう。As a result, the polyvinyl chloride film serving as the coating base material expands and contracts, impairing the linearity of the pattern and the dimensional stability of the decorative sheet. In addition, in the present invention, the linearity of a pattern refers to the fact that a linear or lattice-like pattern does not shift from side to side, and loss of directness means that the pattern is distorted by moving from side to side due to heat and tension. .
〈発明が解決しようとする課題〉
本発明は、耐擦傷性の高い弾性球状樹脂ビーズ混合の塗
料を用いて、しかも絵柄の直線性や寸法安定性に優れた
柔軟性のある艶消しの化粧シートの製造方法を提供する
ことを目的とする。<Problems to be Solved by the Invention> The present invention provides a flexible matte decorative sheet that uses a paint mixed with elastic spherical resin beads with high scratch resistance and has excellent linearity and dimensional stability of the pattern. The purpose is to provide a manufacturing method for.
く課題を解決するための手段〉
この目的を達成するため、本発明は、透明ポリエステル
フィルムに絵柄を印刷し、弾性球状樹脂ビーズを含む塗
料を塗布した後、ポリエステルフィルム面にポリ塩化ビ
ニルフィルムを貼り合せることを特徴とする柔軟性艶消
し化粧シートの製造方法を提供する。In order to achieve this object, the present invention prints a pattern on a transparent polyester film, coats it with a paint containing elastic spherical resin beads, and then applies a polyvinyl chloride film on the surface of the polyester film. To provide a method for producing a flexible matte decorative sheet characterized by lamination.
〈作用〉
ポリエステルフィルムは耐熱性の高いフィルムであり、
このため上記塗料を塗布して高温で乾燥してもフィルム
に伸縮は起こらず、絵柄の直線性や寸法安定性が損なわ
れない、この後の貼り合わせは常法によって可能である
から、高温は必要とせず、やはり絵柄の直線性と寸法安
定性は損なわれない。結果として、耐擦傷性に優れて絵
柄の直線性と寸法安定性に優れた柔軟性があって艶消し
の化粧シートが得られる。<Function> Polyester film is a highly heat resistant film,
For this reason, even if the above paint is applied and dried at high temperatures, the film will not expand or contract, and the linearity and dimensional stability of the pattern will not be impaired.The subsequent lamination can be done by conventional methods, so high temperatures are not required. It is not necessary, and the linearity and dimensional stability of the pattern are not impaired. As a result, a flexible, matte decorative sheet with excellent scratch resistance, linearity and dimensional stability of the pattern is obtained.
〈実施例〉
以下、図面を参照して本発明の詳細な説明する０図面の
第１図は本発明に係わる化粧シートの断面説明図である
。<Example> Hereinafter, the present invention will be described in detail with reference to the drawings. FIG. 1 of the drawings is a cross-sectional explanatory view of a decorative sheet according to the present invention.
第１図において、２はポリエステルフィルムであり、こ
の片面に印刷絵柄３、他の片面に塗料１が施されている
。そして、この印刷絵柄３面が、接着剤４を介してポリ
塩化ビニル５面に接着されている。なお、印刷絵柄３は
、図のように塗料１の反対の面に形成することが望まし
いが、塗料１の塗布前にフィルム２に形成し、この絵柄
３面に塗料１を塗布しても良い。いずれの場合も、塗料
１が表面となるように、ポリ塩化ビニルフィルム５に貼
り合わされる。In FIG. 1, 2 is a polyester film, on one side of which a printed pattern 3 is applied, and on the other side a paint 1. Three sides of the printed pattern are adhered to five sides of polyvinyl chloride via an adhesive 4. Although it is desirable to form the printed pattern 3 on the opposite side of the paint 1 as shown in the figure, it is also possible to form it on the film 2 before applying the paint 1 and then apply the paint 1 to the 3rd side of the pattern. . In either case, it is bonded to the polyvinyl chloride film 5 so that the paint 1 is on the surface.
ポリエステルフィルム２は、塗料１乾燥時の絵柄３の伸
縮や歪みを防ぐと共に、化粧シート加工時にポリ塩化ビ
ニルフィルムの伸びについていき、加工に耐える伸びを
有するためのもので、二軸延伸し、ヒートセットした厚
さ１２〜５０μのポリエチレンテレフタレートフィルム
が使用できる。The polyester film 2 is used to prevent the pattern 3 from expanding, contracting or distorting when the paint 1 dries, as well as to keep up with the elongation of the polyvinyl chloride film during processing of the decorative sheet and to have elongation that can withstand processing. A set polyethylene terephthalate film having a thickness of 12 to 50 microns can be used.
印刷絵柄３は化粧シートとしての意匠性を担保するもの
で、ポリエステル用の周知のグラビアインキが使用でき
る。The printed pattern 3 ensures the design of the decorative sheet, and a well-known gravure ink for polyester can be used.
塗料１は化粧シート表面を耐擦傷性に優れた艶消し状と
するもので、粒径２０〜７０μの弾性球状樹脂ビーズを
バインダーと共に溶剤中に分散したものである。弾性球
状樹脂ビーズとしてはポリウレタン製又はゴム製のビー
ズがあり、着色することもできる。バインダーとしては
二液硬化型のポリウレタンの外、アクリル等の樹脂を用
いることができる。ビーズの均一な分散のため、溶剤と
してはキジロール等の高沸点の溶剤を用いる必要がある
。ビーズとバインダーは、塗膜にビーズが強固に固着さ
れて、しかもビーズが良好に表面に露出して艶消し表面
を形成する必要のため、ビーズ：バインダー＝５：５〜
７：３の重量比で混合する。Paint 1 gives the surface of the decorative sheet a matte finish with excellent scratch resistance, and is made by dispersing elastic spherical resin beads with a particle size of 20 to 70 microns in a solvent together with a binder. The elastic spherical resin beads include beads made of polyurethane or rubber, and can also be colored. As the binder, in addition to two-component curing polyurethane, resins such as acrylic can be used. In order to uniformly disperse the beads, it is necessary to use a high boiling point solvent such as Kijirol as the solvent. Beads and binder should be used in a ratio of 5:5 to 5:5 to 5:5 to 5:5 to 5:5 to 5:5 to 5:5 to 5:5.
Mix at a weight ratio of 7:3.
このビーズとバインダーの合計型Ｉ：溶剤の比は、均一
分散のため、３ニア〜５：５である。The total bead to binder Type I:solvent ratio is between 3 and 5:5 for uniform dispersion.
この塗料ｌは、大橋化学工業■から「ラビ」の商品名で
市販されている外、藤倉化成■から「ベルペックスＪ、
東亜ペイント■から「ネクステル」武藏塗料■から「ポ
ンスウエード」の商品名でそれぞれ市販されている。This paint l is commercially available under the trade name ``Lavi'' from Ohashi Chemical Industry ■, and under the trade name ``Velpex J'' from Fujikura Kasei ■.
They are commercially available under the trade names of ``Nextel'' from Toa Paint ■ and ``Pons Suede'' from Muso Paint ■.
この塗料１はコンマコーター カーテンフローコーター
リバースロールコータ−等の方法で塗布できるが、大
小の粒径のビーズをフィルム２上に均一かつ強固に定着
できる点からコンマコーターで塗布することが望ましい
。コンマコーターとカーテンロールコータ−ではスリッ
トのクリアランスで塗布量を決定し、リバースロールコ
ースタ−ではコーティングロールとドクターロールのク
リアランスで塗布量を決定するが、粒径３０μのビーズ
を塗布可能とするために、クリアランスを３０μ以上と
る必要がある。また、ビーズをフィルム２に定着するた
めに、バインダーの厚みを５μ以上とする必要がある。The coating material 1 can be applied using a comma coater, a curtain flow coater, a reverse roll coater, or the like, but it is preferable to use a comma coater because beads of various sizes can be uniformly and firmly fixed on the film 2. For comma coaters and curtain roll coaters, the amount of coating is determined by the clearance between the slits, and for reverse roll coasters, the amount of coating is determined by the clearance between the coating roll and doctor roll. , it is necessary to provide a clearance of 30μ or more. Further, in order to fix the beads on the film 2, the thickness of the binder needs to be 5 μm or more.
固形分の３３％がビーズ、残りがバインダーである場合
、塗布量は１０ｇ／ｒｒｒ（ｄｒｙ）以上必要である。When 33% of the solid content is beads and the rest is binder, the coating amount needs to be 10 g/rrr (dry) or more.
溶剤の乾燥は８０℃以上の高温で行なう。例えば８０°
Ｃ１５分間、あるいは１５０’Ｃｌ２Ｏ秒間である。The solvent is dried at a high temperature of 80° C. or higher. For example 80°
C15 minutes or 150'Cl2O seconds.
こうして得られる塗料ｌの塗膜は、ベルベット調あるい
はスウェード調の艶消し状の透明な塗膜であり、この塗
膜とフィルム２を透して絵柄３を見ることができ、しか
もこの塗膜は弾性ビーズのため、極めて耐擦傷性に優れ
ている。The coating film of the paint 1 obtained in this way is a velvet-like or suede-like matte transparent coating film, and the pattern 3 can be seen through this coating film and the film 2. Because it is an elastic bead, it has excellent scratch resistance.
ポリ塩化ビニルフィルム５は、化粧シートを合板等に張
り合わせた後、この合板を折曲げ加工する場合、あるい
は曲面に化粧シートを貼り合せ場合等において、化粧シ
ートとしての伸びと強度を担保するもので、厚さ７０〜
２００ μの半硬質の着色したポリ塩化ビニルシートを
用いる。The polyvinyl chloride film 5 ensures the elongation and strength as a decorative sheet when the decorative sheet is pasted onto plywood or the like and then the plywood is bent, or when the decorative sheet is pasted onto a curved surface. , thickness 70~
A 200 micron semi-rigid colored polyvinyl chloride sheet is used.
接着剤４は、周知のもので良（、例えば２液硬化型のウ
レタン系接着剤を使用し、上記フィルム１又はポリ塩化
ビニルフィルム５の一方に塗布し、圧着して積層一体化
する。The adhesive 4 may be a well-known adhesive (for example, a two-component curing type urethane adhesive is used, and it is applied to either the film 1 or the polyvinyl chloride film 5, and the adhesive is pressed and laminated into one piece.
本発明に係わる化粧シートは、例えば合板等に貼り合せ
、この合板裏面をＶ字状に削り取って、この部分から折
り曲げる（■カット加工）等の加工をしたり、あるいは
曲面もしくは巻込みを有する建装材等の表面に貼り合わ
せ、る等の方法で使用する。The decorative sheet according to the present invention can be processed by, for example, pasting it on plywood or the like, scraping off the back side of the plywood in a V-shape, and folding it from this part (■cutting process), or by applying a structure having a curved surface or curling. It can be used by attaching it to the surface of a covering material, etc.
〈試験例〉
厚さ２５μの二輪延伸したポリエチレンテレフタレート
フィルム（ヒートセット済み）の片面に、グラビア印刷
機で３色柄のバイアスストライプ柄をウレタン系インキ
を用いて印刷し、もう一方の面に艶消し塗膜を形成した
。艶消し塗膜は大橋化学工業■のラビを用い、コンマコ
ーターで塗布した後、１５０″Ｃ５２０秒間の条件で乾
燥し、巻き取った。用いたラビは数種３０〜５０μのウ
レタン製球状ヒースヲ、二液硬化型ウレタンのバインダ
ーとキジロールの溶剤中に分散したもので、ビーズ：バ
インダー：溶剤の 比は２７：２１：５２であり、塗布
量は４０ｇ／ボ（ｄｒｙ） である。<Test example> A 3-color bias stripe pattern was printed using urethane ink using a gravure printing machine on one side of a 25μ thick two-wheel stretched polyethylene terephthalate film (heat set), and the other side was glossy. An eraser coating was formed. The matte coating film was applied with a comma coater using a ravi manufactured by Ohashi Chemical Industry ■, dried under conditions of 150"C for 520 seconds, and rolled up. It is dispersed in a two-component curable urethane binder and a Kijiroll solvent, with a bead:binder:solvent ratio of 27:21:52, and a coating amount of 40g/bo (dry).
このフィルムを巻戻しながら検品したところ、塗膜の裏
移りもなく、また印刷絵柄の直線性や寸法安定性も優れ
ていた。When this film was inspected while being rewound, there was no set-off of the coating film, and the linearity and dimensional stability of the printed pattern were excellent.
次にこのフィルムの印刷絵柄面に二液硬化型ウレタン系
接着剤を厚さ５μに塗布し、１００°Ｃ１１５秒間の条
件で乾燥し、厚さ１００ μのグレー色半硬化質塩化ビ
ニルフィルムを重ね、７０°Ｃに保持した圧着ロールで
押圧して巻取った。Next, a two-component curable urethane adhesive is applied to a thickness of 5μ on the printed image side of this film, dried at 100°C for 115 seconds, and a 100μ thick gray semi-hardened vinyl chloride film is layered. , and was rolled up by pressing with a pressure roll maintained at 70°C.
エージングの後、得られた化粧シートは、表面が艶消し
状で耐擦傷性に優れ、印刷絵柄の直線性にも優れていた
。また、印刷絵柄の長さを測定したところ、本来の長さ
がそのまま維持されており、寸法安定性にも優れている
ことが分かった。After aging, the decorative sheet obtained had a matte surface, excellent scratch resistance, and excellent linearity of the printed pattern. Furthermore, when the length of the printed pattern was measured, it was found that the original length was maintained as it was, indicating that it had excellent dimensional stability.
次いでこの化粧シートを合板に貼り合わせ、合板裏面か
ら化粧シートに達するまでｖ字状に削り取って溝をつく
った。このｖ字状の溝を角とし、化粧シートを外側とし
ながら折り曲げたところ、化粧シートは折曲部に沿って
良好に伸び、美しい化粧材が得られた。Next, this decorative sheet was attached to plywood, and a V-shaped groove was created from the back of the plywood until it reached the decorative sheet. When this V-shaped groove was used as the corner and the decorative sheet was bent as the outside, the decorative sheet stretched well along the bent portion, and a beautiful decorative material was obtained.
〈効果〉
以上のように、本発明によれば、耐擦傷性に優れた艶消
し状の表面を持つ化粧シートであって、しかも絵柄の直
線性や寸法安定性を維持した化粧シートが製造可能であ
るという効果を存する。<Effects> As described above, according to the present invention, it is possible to produce a decorative sheet that has a matte surface with excellent scratch resistance and that maintains the linearity and dimensional stability of the pattern. There is an effect that
図面は本発明の実施例を示し−、第１図は化粧シートの
断面説明図。
ｌ・・・塗料 ２・・・ポリエステルフィルム
３・・・印刷絵柄 ４・・・接着剤５・・・ポリ塩
化ビニルフィルム
特 許 出 願 人
凸版印刷株式会社
代表者
鈴木和夫The drawings show embodiments of the present invention, and FIG. 1 is a cross-sectional explanatory view of a decorative sheet. l...Paint 2...Polyester film 3...Printed pattern 4...Adhesive 5...Polyvinyl chloride film Patent application Hitotoppan Printing Co., Ltd. Representative Kazuo Suzuki
Claims (1)
球状樹脂ビーズを含む塗料を塗布した後、ポリエステル
フィルム面にポリ塩化ビニルフィルムを貼り合わせるこ
とを特徴とする柔軟性艶消し化粧シートの製造方法。(1) A method for producing a flexible matte decorative sheet, which comprises printing a pattern on a transparent polyester film, applying a paint containing elastic spherical resin beads, and then laminating a polyvinyl chloride film on the polyester film surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63174181A JP2658212B2 (en) | 1988-07-13 | 1988-07-13 | Manufacturing method of decorative sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63174181A JP2658212B2 (en) | 1988-07-13 | 1988-07-13 | Manufacturing method of decorative sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0224138A true JPH0224138A (en) | 1990-01-26 |
| JP2658212B2 JP2658212B2 (en) | 1997-09-30 |
Family
ID=15974132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63174181A Expired - Lifetime JP2658212B2 (en) | 1988-07-13 | 1988-07-13 | Manufacturing method of decorative sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2658212B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0539973U (en) * | 1991-10-28 | 1993-05-28 | 凸版印刷株式会社 | Printed matter |
| KR100404508B1 (en) * | 2001-02-13 | 2003-11-05 | 주식회사 엘지화학 | Polyvinylchloride Sheet with Excellent Scratch-Resistence and the Method of Manufacturing therof |
| JP2010194903A (en) * | 2009-02-26 | 2010-09-09 | Toppan Cosmo Inc | Decorative material for floor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55156059A (en) * | 1979-05-25 | 1980-12-04 | Sanpo Jiyushi Kogyo Kk | Compound sheet |
| JPS62263040A (en) * | 1986-05-12 | 1987-11-16 | 国際化工株式会社 | Thermosetting resin molded form |
-
1988
- 1988-07-13 JP JP63174181A patent/JP2658212B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55156059A (en) * | 1979-05-25 | 1980-12-04 | Sanpo Jiyushi Kogyo Kk | Compound sheet |
| JPS62263040A (en) * | 1986-05-12 | 1987-11-16 | 国際化工株式会社 | Thermosetting resin molded form |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0539973U (en) * | 1991-10-28 | 1993-05-28 | 凸版印刷株式会社 | Printed matter |
| KR100404508B1 (en) * | 2001-02-13 | 2003-11-05 | 주식회사 엘지화학 | Polyvinylchloride Sheet with Excellent Scratch-Resistence and the Method of Manufacturing therof |
| JP2010194903A (en) * | 2009-02-26 | 2010-09-09 | Toppan Cosmo Inc | Decorative material for floor |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2658212B2 (en) | 1997-09-30 |
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