JPH02237688A - Urolith dissolving agent having quick effect - Google Patents
Urolith dissolving agent having quick effectInfo
- Publication number
- JPH02237688A JPH02237688A JP5602089A JP5602089A JPH02237688A JP H02237688 A JPH02237688 A JP H02237688A JP 5602089 A JP5602089 A JP 5602089A JP 5602089 A JP5602089 A JP 5602089A JP H02237688 A JPH02237688 A JP H02237688A
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- JP
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- genus
- bacteria
- water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- 208000008281 urolithiasis Diseases 0.000 description 34
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Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、微生物ベースの速効性尿石溶解剤に関する．
即ち、トイレ便器及びその周辺に付着した尿石を微生物
やその分泌物の作用により速やか鎧分解除去して、尿尿
臭を抑えるとともに、香料を配合して芳香性を持たせた
速効性尿石溶解剤に関する．
［従来の技術］
従来の尿石除去法としては、（１）酸又はアルカリを主
剤とした化学薬品を用いて、溶解又は剥離させようとい
う試みがある。（２）機械的に外力を加えて削り取る試
みがある．ｃ３》微生物及び酵素を混合した製剤により
、分解又は除去しようという試みがある．又は（荀前記
の（１）と（ク又は■とＧ）などの併用する試みがある
．
このような従来の方法では、（１）＃又はアルカリを主
剤とした化学薬品を用いたものは、便器やタイル等を浸
食したり、清掃者の皮膚や衣服等を侵す危険性が高い．
また、最近、化学反応による有毒ガスの発生の可能性が
認められ、人命を脅かす危険もでてきた。（２）機械的
に外力を加えて削り取るには多大な労働力を必要とする
上に、清掃後にキズを発生させることもあり、好ましい
方法とは言えない．ａ１）従来の微生物及び酵素を混合
した製剤では、分解に時間がかかり、速やかに尿石を除
去することができない．（荀では、（υ〜０）を併用し
ても、いずれかの欠点が足を引っ張り充分な清掃効果を
産まない．
［発明が解決しようとする問題点］
従って、本発明では、従来の問題点を解決するように、
鋭意研究を行なった結果、微生物とともに、微生物の生
育に必要な次素源としての糖類、窒素源としての水溶性
窒素化合物を水と共に２０〜４０℃の温度範囲で、酸素
を供給しながら２０〜６０時間反応させることにより、
微生物の増殖を促進して、尿石の溶解に必要な分泌物の
量を増加させることを可能にし、尿石分解能を高め、処
理時間を大幅に短縮することができた．従って、本発明
は、便器等のこびり付いた尿石等を速やかに分解除去す
ることができ、臭気を殆ど無くした微生物ベースの尿石
分解剤を提供することを目的とする．
［問題点を解決するための手段］
本発明の要旨とするものは、微生物、培地、担体から構
成される微生物成分１０重量部に対し、糖類を１０〜１
０００重量部、水溶性窒素化合物１０〜５００重量部、
香料成分１〜１００重量部、界面活性剤５〜２００重量
部及び水３００００重量部未満から構成され、該微生物
成分、糖類、水溶性窒素化合物及び水が温度２０〜４５
℃、酸素供給量０．１〜２．０ｌ／分の条件下で２４〜
６０時間攪拌反応して得られるものであることを特徴と
する速効性尿石溶解剤である．そして、使用微生物成分
は、バチルス（Ｂａｃｉｌｌｕｓ）ｊＫ、ストレブトフ
ッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ ）属の菌、エン
テロバクタ−（Ｅｎｔｅｒｏｂａｃｔｅｒ）属の菌、リ
ゾーブス（Ｒｈｉｚｏｐｕｓ）属の菌、ニトロソモナス
（Ｎｉｔｒｏｓｏｍｏｎａｓ ）属の菌、ニトロバクタ
−（Ｎｉｔｒｏｂａｃｔｅｒ）属の菌、シュードモナス
（Ｐｓｅｕｄｏｓｏｎａｓ）属の菌、セルロモナス（Ｃ
ｅｌｌｕｌｏ霞ｏｎａｓ ）属の菌、アスペルギルス（
Ａｓｐｅｒｇｉｌｌｕｓ）属の菌からなることが好適で
ある．
更に、微生物成分だけでは、処理しきれない臭気を香料
で補足し、完全な悪臭発生防止と汚物分解機能を有する
尿石分解剤体を提供するものである．
本発明の微生物ベースの尿石分解剤に用いる微生物とし
ては、（１）バチルス（Ｂａｃｉｌｌｕｓ）属の菌、（
クストレブトフッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ
）属の菌、Ｏ）エンテロバクタ−（Ｅｎｔｅｒｏｂａｃ
ｔａｒ ）属の菌、（荀リゾーブス（Ｒｈｉｚｏｐｕｓ
）属の菌、（９ニトロソモナス（Ｎｉｔｒｏｓｏｍｏ
ｎａｓ ）属の菌、（６）ニトロバクタ−（ｌｉｔｒｏ
ｂａｃｔｅｒ）属の菌、（７）シュードモナス（Ｐｓｅ
ｕｄｏ簡ｏｎａｓ ）属の閾、（８）ｔ！ルロモナス（
Ｃｅｌｌｕｌｏｍｏｎａｓ）属の菌、（９）アスペルギ
ルス（Ａｓｐｅｒｇｉｌｌｕｓ）ｊ％の菌を含有せしめ
たものである．
本発明の微生物ベースの尿石分解剤の微生物成分は、微
生物、培地及び担体から構成されるが、その培地として
は、使用微生物の食料となるもので、ある程度組成が明
らかである一定の大豆カスやフスマ、バガスなどの農業
製品副産物が使用され、或いは、牛乳など飲料の腐敗し
たものを用い、場合により、酵母エキスや麦芽エキス及
びその他薬品を併用することができる．
また、本発明に用いる担体としては、使用微生物の住居
となるものであり、好適には、無機質の粉体（多孔体も
含む）の場合は、炭酸カルシウム、炭酸マグネシウム、
珪酸カルシウムの粉末を用い、有機質の粉体の場合は、
才ガクズ等を用いることができる．
この微生物成分１０重量部に対して、糖類１０〜１００
０重量部を含有させ、尿石分解効果を完全にする．糖類
１０重量部未満では、微生物の育成を効果的に促進しな
く、不都合であり、また、１０００重量部を超えると、
パチルス属やシュードモナス属の菌数が増え過ぎて、他
種の菌との共存が不可能になる．用いる糖類としては、
何でも良いが、特に乳糖、果糖、シヨ糖が好適である．
本発明の＾石分解剤体では、更に、微生物成分１０重Ｉ
ｋ部に対して、水溶性窒素化合物１０〜５００重量部、
香料成分１〜１００重量部を含有する．
用いる水溶性窒素化合物としては、何でも良いが、ここ
では塩化アンモニウムで説明する．また、使用香料成分
は、微生物自体のにおいをマスクするために、補助的に
添加する．一般には、アビエチン酸の誘導体、ラウリル
メタアクリレート、葉緑素等を用いる．
水溶性窒素化合物が１０重量部未満では、微生物の生育
を効果的に促進しなく、不都合であり、また、５００重
量部を超えると、尿石の分解能を低下させるとともに、
アンモニア臭の原因となる．
また、香料成分が、１重量部未満では、微生物成分の臭
いをマスクできなく、不都合であり、１００重量部を超
えると、香料臭が強くなり過ぎ、かえって、不快臭の原
因となる．
更に、界面活性剤を添加する、それは微生物や微生物が
産出する酵素や有機酸など尿石を分解、溶解きせる成分
を均一に分散させ、且つ、尿石など悪臭源の隙間や便器
と尿石との界面に浸透させるために必要である．これに
は、アニ才冫系、カチ才ン系、非イオン系などで浸潤性
の強いものが好適である．例えば、アルキルアリル・ポ
リエーテルアルコール、ナトリウム・ジ才クチルスルホ
サクシネート及びナトリウム・才レイルタウレート等が
好適である．そして、界面活性剤は、微生物成分１００
重量部に対して、５〜２００重量部添加する．５重量部
未満では、浸透に対して効果がなく、２００重量部を超
えて添加しても、浸透能力は増加しないためにこのよう
な添加量範囲にする．
更に、使用する水としては、脱イオンや蒸留水が好適で
あり、微生物成分１０重量部に対して、３００００重量
部未満添加する．３００００重量部を超えると、尿石な
ど悪臭源の物質を分解又は溶解させることができない．
また、微生物成分中の微生物は、９属からなり、その微
生物成分１ｇ当りの菌数が、バチルス（Ｂａｃｉｌｌｕ
ｓ）Ｘの菌で、１ｏ” 〜ｔ ｏ”／ｇ，ストレブトコ
７カス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ ）［ｉ＋の菌で
、１０′〜１０１＠／ｇ５エンテロバクタ−（Ｅｎｔｅ
ｒｏｂａｃｔｅｒ）属の菌で１ ０ ’ 〜１ ０ ”
／ｇ，リゾーブス（Ｒｈｉｚｏｐｕｓ）属の菌で、１
０’ 〜１ ０”／ｇ，ニトロソモナス（Ｎｉｔｒｏｓ
ｏｍｏｎａｓ ）属の菌で、１０６〜１０’／ｇ，ニト
ロバクタ−（Ｎｉセｒｏｂａｃｔｅｒ）属の菌で、そし
て１０’ 〜１０”／ｇ， シュードモナス（Ｐｓｅｕ
ｄｏｍｏｎａｓ）属の菌で、１ｏ’ 〜ｔ Ｏ”／ｇ，
セルｔｆｆ−Ｔ−ナス（Ｃｅｌｌｕｌｏ＋ｍｏｎａｓ
）属の菌で、１０’ 〜１０’／ｇ，アスペルギルス（
Ａｓｐｅｒｇｉｌｌｕｓ）属の菌で、１０’〜１０１／
ｇ含有する．
即ち、バチルス（Ｂａｃｉｌｌｕｓ）属の菌が、１０″
／ｇ未満では尿石成分を分解する能力が不足し、１０８
７ｇを超えると、他の種の菌との共存での増殖の限界に
なり、また、悪臭の原因となる．また、ストレブトフッ
カス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ ）属の菌が、１０
’／ｇ未満では、尿石成分を分解する能力が不充分であ
り、１０′＠／ｇを超えると、分解処理能力がこれ以上
必要でなく、他の種の菌との共存での増殖の限界になる
．
そして，エンテロバクタ−（Ｅｎｔｅｒｏｂａｃｔａｒ
）属の菌が， １ ０ ”／ｇ未満では尿石成分を分
解する能力が不足し １ ０ １ ｍ ／ｇを超えると
、他の種の菌との共存での増殖の限界になり、また、悪
臭の原因となる．
添加のリゾープス（Ｒｈｉｚｏｐｕｓ）Ｎの菌は、大変
強力な糖化酵素を分泌するため尿石中の炭水化物を急速
に糖順に変え、バチルス（Ｂａｃｉｌｌｕｓ）の効果を
大幅に強めることができる．これにより得られた糖類や
戻化水素を、ストレブトフッカス（Ｓｔｒｅｐｔｏｃｏ
ｃｃｕｓ ）属の菌が分解するため、リゾーブス（Ｒｈ
ｉｚｏｐｕｓ ）属の菌を混入すると極めて短時間で汚
物や悪臭源の分解を終了きせることができる．リゾ−プ
ス（Ｒｈｉｚｏｐｕｓ ）属の菌が、ｔｏ’，’ｇ未満
−ｃ”＋ｔ、尿石の分解能力が不充分で、ｔ０１ｆｆｉ
／ｇを超えると、他の種の菌との共存での増殖の限界に
なる．ニトロソモナス（Ｎｉｔｒｏｓｏｓｏｎａｓ ）
属の菌が、１０１／ｇ未満では、アンモニアをＮＯ，−
に変化きせるには不充分で，１０’／ｇを超えると．他
の種の菌との共存での増殖の限界になる．
また、ニトロバクター（Ｎｉｔｒｏｂａｃｔｅｒ）属の
菌が１０’／ｇ未満では、Ｎｏ．一をＮ Ｏ ｘ−に変
化させるに不充分であり、１０”／ｇを超えると，他の
種の菌との共存での増殖の限界になる．シュードモナス
（Ｐｓａｕｄｏｍｏｎａｓ）属の菌が、１０６／ｇ未満
では、ＮＯ．をＮ，に変化させるには不充分であり、１
０ ”／ ｇを超えると、他の種の菌との共存での増
殖の限界になる．
セルロモナス（Ｃｅ１１ｕｌｏｍｏｎａｓ）ＩＥの菌が
、１０’／ｇ未満では、尿石を分解する能力が不足で、
１０’／ｇを超えると．他の種の菌との共存での増殖の
限界になる．
アスペルギルス（Ａｓｐａｒｇｉｌｌｕｓ）属の菌は、
１０４／ｇ未満では尿石成分を分解する能力が不足し、
１０”／ｇを超えると、他の種の菌との共存での増殖の
限界になる．
本発明ではこれら９属の菌を混入して、尿石の速やかな
分解、除去を図るものである．即ち、（υバチルス（Ｂ
ａｃｉｌｌｕｓ）属の菌体■ストレブトフッカス（Ｓｔ
ｒｅｐｔｏｃｏｃｃｕｓ ）属の菌体（３）エンテロバ
クタ（Ｅｎｔｅｒｏｂａｃｔｅｒ）属の菌体（４）リゾ
ーブス（Ｒｈｉｚｏｐｕｓ ）属の菌、ニトロソモナス
（Ｎｉｔｒｏｓｏｓｏｎｍｓ ）属の菌体は、尿石や悪
臭源中の普通の有機物の分解に寄与するもので、尿石の
剥離を容易にする．次に、（９ニトロソモナス（Ｎｉｔ
ｒｏｓｏ鋤ｃ）ｎａｓ）属の菌体（ｅニトロバクタ−（
Ｎｉｔｒｏｂａｃｔｅｒ）属の菌体■シュードモナス（
ｐｓｅｕｄｏ醜ｏｎａｓ ）属の菌体は、トイレ便器表
面から多量に発生するアンモニアの分解に寄与するもの
であり、組合わせて、アンモニアの悪臭を除去する作用
を有する．即ち、（■ニトＵソモナス（Ｎｉｔｒｏｓｏ
ｍｏｎａｓ ）属の菌は、アンモニア→Ｎｏ．−に、■
二トロバクター（Ｎｉｔｒｏｂａｃｔ＠ｒ）属の菌は、
ＮＯ，−→Ｎｏ．−に、そして、（Ｄシュードモナス（
Ｐｓｅｕｄｏｅｒｏｎａｓ ）属の菌は、Ｎ Ｏ ｓ−
→Ｎ，に変換し、アンモニアによる悪臭を抑えようとす
るものである．そして、■ストレブトコッカス（Ｓｔｒ
ｅｐｔｏｃｏｃｃｕＳ）属の菌（荀リゾーブス（Ｒｈｉ
ｚｏｐｕｓ）属の菌■アスペルギルス（Ａｓｐｅｒｇｉ
ｌｌｕｓ）属の菌は、糖類やアルコールを乳酸やクエン
酸などの有機酸に変換したり、酵素（アミラーゼ、プロ
テアーゼ、リバーゼなど）を産出して、尿石を分解する
主役となり得る．
また、（８）セルロモナス（Ｃｅｌｌｕｌｏｓｏｎａｓ
）属の菌は、尿石中のセルロース成分をある程度分解
し、尿石のＨ離に役立つものである．以上のように、（
１）〜（９）の菌が各々の機能を果たすことにより、尿
石や悪臭源を分解、溶解したり、それらの一部を芳香物
質へと変換させることもできる．以上のように、本発明
の尿石分解剤体では、これらの９属の菌を混入し、総合
的にバランスの取れた尿石成分の分解を志向するもので
ある．そして、以上の９ｆｆ１の菌は、各々の機能を果
たすことによって、尿石成分を分解し、剥離し易くする
ものである．また、同時に生成する芳香を有する香料成
分のために尿石分解剤中の悪臭をマスク減少させること
ができる．
また、本発明の微生物ベースの尿石分解剤に用１１％
ル（１）バｆ ルス（Ｂａｃｉｌｌｕｓ）ｉＥは、特に
、パチルス・ズプチルス（Ｂ．ｓｕｂｔｉｌｉｓ）［Ｉ
ＡＭ（Ｉｎｓｔｉｔｕｔｅ ｏｆ Ａｐｐｌｉｅｄ Ｍ
ｉｃｒｏｂｉｏｌｏｇｙ；東京大学応用微生物研究所有
用菌株保存施設の略称；以下同様にこの略称で示す）１
１６８］が好適であるが、この他に、バチルス●ナット
ウ（Ｂ． ｎａｔｔｏ）［ＩＦＯ（Ｉｎｓｔｉｔｕｔ＠
ｆｏｒ Ｆｅｒｓ＋ａｎｔａｔｉｏｎ Ｏｓａｋａ ：
財団法人発酵研究所：の略称；以下同様にこの略称で示
す） ３００９］菌、バチルス・コアギュラ／Ｃ （Ｂ
．ｃｏａｇｕｌａｎｓ）［ＩＡｌｌＩ １１１５１、バ
チルス−ｖセランス（Ｂ．ｍａｃｅｒａｎｓ）［ＩＡＭ
１２４３］を併用してもよい．
■ストレプトコッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ
）属の菌としては、何でも良いが、ストルブトコッカス
・フ７カリス（Ｓ．ｆａｅｃａｌｉｓ）［ＩＡＭ １１
１９］、ストレブトコッカス・タレモリス（Ｓ．ｃｒａ
ｓｏｒｉｓ）［ＩＡＭ １１５０］及びラクチス（５．
ｌａｃｔｉｓ）［ＩＡＭ １１９８］などを用いるこ
とができる．
■エンテロバクタ−（Ｅｎｔｅｒｏｂａｃｔｅｒ ）属
の菌としては、特に、エンテロパクター・サカザキイ（
Ｅ． ｓａｋａｚａｋｉｉ）［ＩＡＭ １２６６０１、
エンテロバクター・アグロメランス（Ｅ． ａｇｇｌｏ
ｍａｒａｏｓ）［ＩＡＭ １２６５９］、エンテロバク
ター・アエロゲネス（Ｅ．ａｅｒｏｇｅｎｅｓ）ＩＩＡ
Ｍ １１８３及び１２３４８］などを用いることができ
る．また、カビの１種の（荀リゾーブス（Ｒｈｉｚｏｐ
ｕｓ ）属の菌としては、リゾーブス・フ才ルモサエン
シス（Ｒｈｉｚｏｐｕｓ ｆｏｒｍｏｓａｅｎｓｉｓ）
［ＩＡｌ１ ６２５０１、リゾープス−才リザｚ（Ｒｈ
ｉｚｏｐｕｓ ｏｒｙｚａｅ）［ＩＡＭ ６００６］、
リゾーブス・シュードシネンシス（Ｒｈｉｚｏｐｕｓ
ｐｓｅｕｄｏｃｈｉｎｅｎｓｉｓ）［ＩＡＭ ６Ｇ４２
］などを用いることができる．
（９ニトロソモナス（Ｎｉｔｒｏｓｏｍｏｎａｓ ）属
の菌としては、ニトロソモナス●ヨーロパエア（Ｎ．ｅ
ｕｒｏｐａａａ）［ＩＦ０ １４２９ｇ］などを用いる
ことができる．（ｅニトロバクター（Ｎｉｔｒｏｂａｃ
ｔａｒ）属の菌としては、ニトロバクター・アギリス（
Ｎ．ａｇｉｌｉｓ）［ＩＦＯ １４２９７］などを用い
ることができる．■シュードモナス（ｐｓｅｕｄｏ霞ｏ
ｎａｓ ）属の菌としては、シュードモナスーニトロレ
デュセンス（ｐ． ｎｉｔｒｏｒｅｄｕｃｅｎｓ）［Ｕ
ＦＯ １２６９４］、シュードモナス・キ〜り才フィリ
ス（Ｐ．ｃａｒｙｏｐｈｉｌｌｉｓ）［ＩＦＯ １２９
５０１、’／ユードモナス−スチュトセリ（Ｐ． ｓｔ
ｕｔｚｅｒｉ）［ＩＦＯ３７７３］を用いることができ
る．
そして（■セルロモナス（Ｃｅｌｌｕｌｏｍｏｎａｓ）
属の菌としては、セルロモナス・ビアゾテア（Ｃ． ｂ
ｉａｚｏｔｅａ ）［ＩＦ０ １２６８０］、セルロモ
ナス・セラセア（Ｃ． ｃｅｌｌａｓｅａ）［ＩＦ０
３７５３］、セルロモナス・ウダ（Ｃ．Ｕｄａ）［ＩＦ
Ｏ３７４７］などを用いることができる．また■アスベ
ルギルス（Ａｓｐｅｒｇｉｌｌｕｓ）属の菌としては、
アスペルギルス・才リザエ（Ｅ， ｏｒｙｚａｅ）［Ｉ
ＦＯ ４１７６］、アスベルギルス・ニガー（Ｅ． ｎ
ｉｇｅｒ）［ＩＦ０ ４０６６］、アスペルギノレス・
ウサミイ（Ｅ． ｕｓａｍｉｉ）［ＩＦ０ ６０８２］
などを用いることができる．また、本発明の微生物成分
に用いる培地は、大豆カスやフスマなどの農産物廃棄物
を用い、場合により、酵母エキスや麦芽エキスを併用す
ることができる．また、その微生物成分に用いる担体と
しては、炭酸カルシウム、Ｒｒｌｌマグネシウム、ケイ
酸カルシウムなどの粉末が用いられる．［作用］
本発明の微生物ベースの速効性尿石分解剤体の汚水処理
のメカニズムは次のようなものと考えられる．
即ち、バチルス（３ａｃｉｌｌｕｓ）属の菌が、尿石成
分中の悪臭を発する主に澱粉質や蛋白質など有機物を分
解し、その分解により生成した糖類、炭化水素をストレ
ブトフッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ ）属菌体
及びリゾーブス（Ｒｈｉｚｏｐｕｓ ）属菌体が急速に
更に分解し、発酵を促進し、悪臭物質を取り除くもので
ある．そして、バチルス（Ｂａｃｉｌｌｕｓ）３Ｋ菌体
、ストレブトコッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ
）属菌体、アスペルギルス（Ａｓｐ＠ｒｇｉｌｌｕｓ）
属菌体及びリゾープス（Ｒｈｉｚｏｐｕｓ ）属菌体は
、尿石成分を分解する．また、本発明により利用される
ニトロソモナス（Ｎｉｔｒｏｓｏｍｏｎａｓ ）属菌体
、ニトロバクタ−（Ｎｉｔｒｏｂａｃｔｅｒ ）属菌体
、シュードモナス（Ｐｓｅｕｄｏｍｏｎａｓ ）属菌体
は、尿石成分中に多量に発生するアンモニアの分解に寄
与するもので、ニトロソモナス属菌体は、アンモニア→
ＮＯ．−にし、ニトロバクター属菌体は、ＮＯ．−→Ｎ
Ｏ ｓ−にし、シュードモナス属菌体は、Ｎ Ｏ ｓ
−→Ｎ，にし、これらの３つの属菌体でアンモニアの悪
臭の問題を解決できたものである．
そして、セルロモナス（Ｃｅｌｌｕｌｏｍｏｎａｓ ）
属菌体により、尿石成分中に有るセルロース成分を一部
分解する．
本発明の尿石分解剤は、次のようにして製造できる．即
ち、本発明では、その構成成分中に微生物の菌数や、そ
の微生物の産出する酵素や有機酸などの産出、分泌する
量を通常の方法では考えられない程の多数、大量とする
ために、製造に際しては、先ず、上記の微生物成分（微
生物＋培地十担体）、糖類、水溶性窒素化合物及び水を
適量計量し、ジャーファーメンターに入れて、温度を２
０〜４５℃とし、酸素を０．１〜２．Ｏｌｌ分の割合で
通気しながら、２４〜６０時間攪拌する．得られた溶液
に、香料成分と界面活性剤を適当量混合して、尿石分解
剤製品とする．
次に、本発明の尿石分解剤の使用法は、便器に付いた尿
石成分に対して使用すると、微生物の活性が高く、悪臭
を生じないようにでき、尿石を剥離し易くするものであ
る．
尿石分解剤では、多量の微生物が存在し、活性化させ、
悪臭や***物を完全に分解発酵する．本発明の微生物ベ
ースの尿石分解剤は、特に、速効性があり、短時間でズ
石成分の分解に適するものである．更に、他の汚水や排
水処理にも好適である．
次に、本発明の微生物ベースの尿石分解剤について具体
例により説明するが、本発明は、次の実施例に限定され
るものではない．
［実施例］
バチルス（Ｂａｃｉｌｌｕｓ）属のバチルス・ズブチル
ス（Ｂ．ｓｕｂｔｉｌｉｓ）［ＩＡＭ １１６８］菌を
Ｉｇ，バチルス・コアギュランス（Ｂ．Ｃｏａｇｕｌａ
ｎｓ）［ＩＡＭ １１１５］菌を０．４ｇ，ストレブト
コツカス（ Ｓｔｒｅｐｔｏｃｏｃｃｕｓ ）属のスト
レブトコッカス●ファカルス（Ｓ． ｆａｅｃａｌｉｓ
）［ＩＡＭ １１１９］菌をｉｇ，エンテロバクタ−
（Ｅｎｔａｒｏｂａｃｔｅｒ）ｆｉのエンテロパクター
・サカザキイ（｝：．ｓａｋａｚａｋｉｉ）［ＩＡＭ
１２６６０］を０．４ｇ， リゾーブス（Ｒｈｉｚｏｐ
ｕｓ ）１４のりゾーブス・フ才ノレモサエシス（Ｒ．
ｆｏｒｇｏｓａｅｎｓｉｓ＞［ＩＡＭ ６２５０］菌
、ニトロソモナス（Ｎｉｔｒｏｓｏｓｏｎａｓ）ＩＸの
ニトロンモナス・ヨーロパエア（ｌ．ｅｕｒｏｐａｅａ
）［ＩＦ０ １４２９８］菌、ニトロバクタ−（Ｎｉｔ
ｒｏｂａｃｔａｒ ）属のニトロバクター・アギリス（
Ｎ，ａｇｉｌｉｓ）［ＩＦ０ １４２９７］菌、シュー
ドモナス（Ｐｓｅｕｄｏｍｏｎａｓ ）属のシュードモ
ナス・アエルギノサ（Ｐ， ａｅｒｏｇｉｎｏｓａ）［
ＩＦ０ ３０８０１菌を各々０．６ｇ，アスペルギルス
（Ａｓｐｅｒｇｉｌｌｕｓ）属のアスペルギルス・才リ
ザエ（Ａ． ｏｒｙｚａｓ）［ＩＦ０ ４１７６］菌を
０．５ｇ，アスペルギルス・ニガー（Ｅ．ｎｉｇｅｒ）
［ＩＦＯ ４０６６］を１ｇ計量し、これにシヨ糖２
０ ０ ｇ，塩化アンモニウム８ｇ及び１５０００ｃｃ
の蒸留水をジャーファーメンター中に計り取り、３０゜
Ｃで４８時間、０．２１７分で酸素を吹き込みながら攪
拌を行なった．
その結果得られた溶液の生菌数は、バチルス属の菌が、
７Ｘ１Ｇ’″／ｇ，ストレブトコッカス属の菌が、２
． ｌ Ｘ １ ０＋１７ ｇ，エンテロバクター属の
菌が７．２ｘｔｏ”／ｇｓ リゾープス属の菌が、ｓ．
ｚｘｔＯｌ４／ｇ，が存在していた．また、更に、ニト
ロソモナス属の菌が、２。４×１ｏ Ｉ ＊ ／ ｇ１
ニトロバクター属の菌が、４．３Ｘ１０１／ｇ及びシ
ュードモナス属の菌が、３．３×１ ０ １ １ ７
ｇ１ セルロモナス（Ｃｅｌｌｕｌｏｍｏｎａｓ ）属
の菌が、２。１ｘｌＯ’／ｇ，アスペルギルス属の菌が
、９．２Ｘ１０”／ｇとなり、大きな数字を示した．
また、酵素の産出量も大きく、全ての酵素（アミラーゼ
、プロテアーゼ、リパーゼなど）を合計して０．００１
５％であった．更に、変換きれたと思われる有機酸も１
％であった．
このような組成の溶液１０００ｇ当り０．１５ｇのアビ
エチン酸ソーダと０．４ｇのナトリウム・ジ才クチルス
ルホサクシネートを混合し、本発明の速効性尿石溶解剤
とした．
このようにして得られた微生物ベースの尿石溶解剤につ
いて、次の試験を行なった．
即も、この溶解剤を用いて男子便器の内部（目皿の下）
や外部（ヘリ）、周辺に付着した尿石が取れ易くなるか
を観察した．
男子便器の内部（目皿の下）については、目皿下部を密
栓し、水溶液を張り込むことにより、外Ｎ（ヘリ）や周
辺については、水溶液を吸水性の紙にしみ込ませて、そ
れを付着した尿石の上に置くことにより行なった．各々
試験開始後一定時間即ち、１、２、４、６時間経過後に
、ドライバーや薬さしを用いて、尿石の剥離性を調査し
た．また、同時に、ｐＨやアンモニア量を測定した．対
照試験として、従来の微生物、酵素製剤のもの（対照Ａ
）、水温３０″Ｃ程度の蒸留水（盲検）を用いて同様の
試験を行なった１
以上の試験条件と試験結果を第１表にまとめて示す．尚
、未処理の場合のアンモニア量は、２６０ｐｐｍ以上で
、ｐＨ９．１であった．第１表から、つぎのことか明ら
かである．尿石の剥離性は、対照Ａが試験開始１２０分
後から効果を示したのに対し、本発明の尿石溶解剤は、
１０分後に明らかな効果を示し、同時に、アンモニアの
発生を抑え、ｐＨ値も中性となったものである．
［発明の効果］
本発明の微生物ベースの尿石溶解剤は、とかく悪臭を発
生し易い尿石の処理剤として、９属の微生物を添加し、
それら微生物の生物活性を高めるために栄養源として、
糖類と水溶性窒素化合物を添加し、しから、反応時に供
給される酸素の存在下で極めて活発に増殖し、尿石の分
解に有効な酵素や有機酸を大量に産出及び生成できるの
で、極めて短時間、例えば１０分後で、尿石を分解でき
るようになった．尿石の場合にはかなり多くの成分から
構成され、その成分もまちまちであるので、このように
種々の菌の作用がなければ分解する力が大きくならない
ものである．従って、本発明は、
第１に、トイレ清掃に際して、除去し難く悪臭の原因と
もなる尿石を速やかに除去する尿石溶解剤を提供したこ
と、
第２に、微生物成分に含有されるバチルス（Ｂａｃｉ１
１ｕｓ）Ｍ，ストレプトフッカス（Ｓｔｒｅｐｔｏｃｏ
ｃｃｕｓ ）属、アスペルギルス（Ａｓｐｅｒｇｉｌｌ
ｕｓ）属、セルロモナス（Ｃｅｌｌｕｌｏｓｏｎａｓ）
属、リゾーブス（Ｒｈｉｚｏｐｕｓ）属の菌は、尿石の
主要成分である尿酸や尿石表面に付着している有機物を
分解するが、本発明により特別に含有している糖類と水
溶性窒素化合物を栄養源として活発に増殖し、短時間の
うちに、その能力を発揮できるので、従来の微生物酵素
製剤と比較して、尿石をきれいに且つ容易に除去するた
めに必要とする処理時間を大幅に短縮することが可能に
なったこと、
第３に、更に、微生物成分に含有されるニトロソモナス
（Ｎｉｔｒｏｓｏｍｏｎａｓ ）属の菌、ニトロバクタ
−（Ｎｉｔｒｏｂａｃｔｅｒ）属の菌、シュードモナス
（Ｐｓｅｕｄｏｍｏｎａｓ ）属菌の組合わせによって
、ニトロソモナス属菌は、アンモニア→Ｎｏｔ−、ニト
ロバクター属菌は、ＮＯ１−→ＮＯ＊−、シュードモナ
ス属菌は、ＮＯ，−→Ｎ，と変換させることができ、こ
れらの菌の作用が本発明の添加物や酸素の存在下で強め
られ、従来品．よりも短時間でアンモニア分解が可能と
なったこと、
このように本発明では、特定の微生物の組合わせ、糖類
、水溶性窒素化合物の添加及び酸素の吹き込みにより増
殖、育成反応で、従来の微生物、酵素製品では、予想も
できない程の尿石の分解、溶解性を発揮したこと
などの著しい技術的効果が得られた．
特許出願人 三菱鉱業セメント株式会社代理人 弁
理士 倉 持 裕DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a microorganism-based fast-acting urinary stone dissolving agent.
In other words, it is a fast-acting urinary stone that quickly decomposes and removes urinary stones attached to the toilet bowl and its surroundings by the action of microorganisms and their secretions, suppresses the urine odor, and has a fragrance added to it. Regarding solubilizing agents. [Prior Art] As a conventional method for removing urinary stones, there is an attempt (1) to dissolve or exfoliate them using a chemical agent based on acid or alkali. (2) There is an attempt to scrape it off by mechanically applying external force. c3》There are attempts to degrade or remove it using preparations containing microorganisms and enzymes. There have been attempts to combine (1) and (1) and (1) and (1) and (1) and (3) and (G). There is a high risk that it will erode the toilet bowl, tiles, etc., and the skin and clothes of the person cleaning it.
In addition, it has recently been recognized that chemical reactions can generate toxic gases, posing a threat to human life. (2) Mechanically applying external force to scrape off requires a large amount of labor and may cause scratches after cleaning, so it is not a desirable method. a1) Conventional formulations containing microorganisms and enzymes take time to decompose and cannot quickly remove urinary stones. (In Xun, even if (υ~0) is used in combination, one of the drawbacks will hinder the cleaning effect and will not produce a sufficient cleaning effect. [Problems to be solved by the invention] Therefore, the present invention solves the conventional problems. Like solving a point,
As a result of intensive research, we found that together with microorganisms, sugars as a secondary element source necessary for the growth of microorganisms, and water-soluble nitrogen compounds as a nitrogen source were added together with water at a temperature range of 20 to 40 degrees Celsius while supplying oxygen. By reacting for 60 hours,
By promoting the growth of microorganisms, it was possible to increase the amount of secretion required to dissolve urinary stones, thereby increasing the ability to decompose urinary stones and significantly shortening processing time. Therefore, an object of the present invention is to provide a microorganism-based urinary stone decomposer that can quickly decompose and remove urinary stones stuck in toilet bowls and the like, and has almost no odor. [Means for Solving the Problems] The gist of the present invention is that 10 to 1 part of saccharide is added to 10 parts by weight of a microorganism component consisting of a microorganism, a culture medium, and a carrier.
000 parts by weight, 10 to 500 parts by weight of a water-soluble nitrogen compound,
It is composed of 1 to 100 parts by weight of a fragrance component, 5 to 200 parts by weight of a surfactant, and less than 30,000 parts by weight of water, and the microbial component, saccharide, water-soluble nitrogen compound, and water are heated at a temperature of 20 to 45%.
℃, under conditions of oxygen supply rate of 0.1 to 2.0 l/min.
This is a fast-acting urinary stone dissolving agent characterized by being obtained by a stirring reaction for 60 hours. The microorganism components used are Bacillus jK, Streptococcus, Enterobacter, Rhizopus, and Nitrosomonas. , Nitrobacter genus, Pseudomonas genus, Cellulomonas (C
fungi of the genus Aspergillus (
Preferably, the microorganism is made of bacteria of the genus Aspergillus. Furthermore, the present invention provides a urinary stone decomposer that completely prevents the generation of bad odors and has the function of decomposing filth by supplementing odors that cannot be completely treated with microbial components alone. The microorganisms used in the microorganism-based urinary stone decomposing agent of the present invention include (1) bacteria of the genus Bacillus;
Streptococcus
) bacteria of the genus O) Enterobacter
tar) genus, (Rhizopus
) bacteria of the genus (9 Nitrosomonas
bacteria of the genus Nas, (6) Nitrobacter (litro
(7) Pseudomonas (Pse)
udo simpleonas ) genus threshold, (8) t! Luromonas (
(9) Aspergillus j%. The microbial component of the microorganism-based urolith decomposer of the present invention is composed of microorganisms, a culture medium, and a carrier. Agricultural by-products such as rice bran, wheat bran, and bagasse are used, or spoiled beverages such as milk are used, and yeast extract, malt extract, and other chemicals may be used in combination. In addition, the carrier used in the present invention is a carrier for the microorganisms used, and in the case of inorganic powder (including porous materials), calcium carbonate, magnesium carbonate,
Using calcium silicate powder, in the case of organic powder,
You can use talented people, etc. For 10 parts by weight of this microbial component, 10 to 100 parts of sugar
Contains 0 parts by weight to achieve complete urinary stone decomposition effect. If the sugar content is less than 10 parts by weight, it will not effectively promote the growth of microorganisms, which is inconvenient; if it exceeds 1000 parts by weight,
The number of bacteria of the genus Pacillus and Pseudomonas increases so much that it becomes impossible for them to coexist with other species of bacteria. The sugars used are
Any sugar may be used, but lactose, fructose, and sucrose are particularly suitable.
In the stone decomposer body of the present invention, the microbial component 10
10 to 500 parts by weight of a water-soluble nitrogen compound per part k;
Contains 1 to 100 parts by weight of fragrance ingredients. Any water-soluble nitrogen compound may be used, but ammonium chloride will be used here. In addition, the fragrance ingredients used are added as supplements to mask the odor of the microorganisms themselves. Generally, abietic acid derivatives, lauryl methacrylate, chlorophyll, etc. are used. If the water-soluble nitrogen compound is less than 10 parts by weight, it will not effectively promote the growth of microorganisms, which is inconvenient; if it exceeds 500 parts by weight, it will reduce the ability to decompose urinary stones and
Causes ammonia odor. Further, if the fragrance component is less than 1 part by weight, it is inconvenient because it cannot mask the odor of microbial components, and if it exceeds 100 parts by weight, the fragrance odor becomes too strong, causing an unpleasant odor. Furthermore, a surfactant is added, which uniformly disperses microorganisms and components that can decompose and dissolve urinary stones, such as enzymes and organic acids produced by microorganisms, and is effective in cleaning the gaps between the sources of bad odors such as urinary stones, and between the toilet bowl and urinary stones. It is necessary to penetrate the interface of For this purpose, highly infiltrating agents such as anionic type, active type and non-ionic type are suitable. For example, alkylaryl polyether alcohol, sodium chloride sulfosuccinate, sodium chloride taurate, and the like are suitable. And, the surfactant contains 100% of the microbial component.
Add 5 to 200 parts by weight. If it is less than 5 parts by weight, there is no effect on penetration, and if it is added in excess of 200 parts by weight, the penetration ability will not increase, so the amount added is in this range. Further, the water used is preferably deionized or distilled water, and is added in an amount of less than 30,000 parts by weight per 10 parts by weight of the microbial component. If it exceeds 30,000 parts by weight, it will not be possible to decompose or dissolve substances that cause bad odors such as urinary stones. In addition, the microorganisms in the microbial component consist of nine genera, and the number of bacteria per gram of the microbial component is Bacillus (Bacillus).
s) X bacteria, 1o" to t o"/g, Streptococcus [i+ bacteria, 10' to 101@/g5 Enterobacter
10' to 10'' for bacteria of the genus Robacter.
/g, a fungus of the genus Rhizopus, 1
0' to 10"/g, Nitrosomonas
bacteria of the genus Nitrobacter, and 10' to 10''/g of bacteria of the genus Pseudomonas.
Domonas) genus bacteria, 1o' to t O"/g,
Cell tff-T-Eggplant (Cellulo+monas)
) bacteria of the genus, 10' to 10'/g, Aspergillus (
Aspergillus), 10' to 101/
Contains g. That is, bacteria of the genus Bacillus are
If it is less than /g, the ability to decompose urinary stone components is insufficient, and 108
If it exceeds 7g, there will be a limit to its growth in coexistence with other species of bacteria, and it will also cause a bad odor. In addition, bacteria of the genus Streptococcus
If it is less than 10'/g, the ability to decompose urinary stone components is insufficient, and if it exceeds 10'/g, there is no need for any more decomposition processing ability, and growth in coexistence with other species of bacteria is not possible. There will be a limit. And Enterobacter
) bacteria of the genus lack the ability to decompose urinary stone components when the concentration is less than 10"/g, and when it exceeds 101 m2/g, there is a limit to their growth in coexistence with other species of bacteria, and The added Rhizopus N bacterium secretes a very powerful saccharifying enzyme, which rapidly converts carbohydrates in urinary stones into sugars, greatly enhancing the effect of Bacillus. The saccharides and reconstituted hydrogen obtained in this way are then treated with Streptofuccus.
Rhizobacteria (Rh) is decomposed by bacteria of the genus Ccus.
When bacteria of the genus Izopus are mixed in, the decomposition of filth and the source of bad odors can be completed in an extremely short period of time. Bacteria of the genus Rhizopus have insufficient ability to decompose urinary stones, and t01ffi
/g, there is a limit to growth in coexistence with other species of bacteria. Nitrosomonas
When bacteria of the genus are less than 101/g, ammonia is converted into NO, -
If it exceeds 10'/g, it is insufficient to cause a change. This is the limit for growth in coexistence with other species of bacteria. In addition, if the Nitrobacter genus bacteria is less than 10'/g, No. If it exceeds 10"/g, it will be the limit for growth in coexistence with other species of bacteria. If it is less than 1 g, it is insufficient to change NO. to N.
If it exceeds 0''/g, there will be a limit to its growth in coexistence with other species of bacteria.If the cellulomonas IE bacteria is less than 10'/g, it will lack the ability to decompose urinary stones,
If it exceeds 10'/g. This is the limit for growth in coexistence with other species of bacteria. Bacteria of the genus Aspergillus are
If it is less than 104/g, the ability to decompose urinary stone components is insufficient,
If it exceeds 10"/g, there is a limit to the growth of bacteria in coexistence with other species of bacteria. In the present invention, bacteria from these nine genera are mixed in to rapidly decompose and remove urinary stones. ．That is, (υ Bacillus (B
acillus) ■ Strebutofuccus (St
Bacteria of the genus Reptococcus (3) Bacteria of the genus Enterobacter (4) Bacteria of the genus Rhizopus and Bacteria of the genus Nitrososonms are common organic substances in urinary stones and malodor sources. It contributes to the decomposition of urinary stones, making it easier to remove them. Next, (9 Nitrosomonas
Nitrobacter (e.g.
Nitrobacter) genus Pseudomonas (
Bacterial cells of the genus Pseudoonas) contribute to the decomposition of ammonia generated in large amounts from the surface of toilet bowls, and in combination have the effect of removing the foul odor of ammonia. That is, (■ Nitroso somonas
Bacteria of the genus Monas) are ammonia→No. -to,■
Bacteria of the genus Nitrobacter are
NO, -→No. −, and (D Pseudomonas (
Bacteria of the genus Pseudoeronas are NOs-
→N, to suppress the bad odor caused by ammonia. And ■Streptococcus (Str
Bacteria of the genus eptococcus (Rhi
Fungi of the genus Aspergillus
Bacteria of the genus S. llus convert sugars and alcohols into organic acids such as lactic acid and citric acid, and produce enzymes (amylase, protease, revertase, etc.), and can play a major role in decomposing urinary stones. In addition, (8) Cellulosonas
) bacteria decompose cellulose components in urinary stones to some extent and are useful in removing H from urinary stones. As mentioned above, (
By fulfilling their respective functions, the bacteria 1) to (9) can decompose and dissolve urinary stones and sources of bad odors, and can also convert some of them into aromatic substances. As described above, the urinary stone decomposition agent of the present invention contains bacteria from these nine genera and is intended to achieve a comprehensively balanced decomposition of urinary stone components. The above-mentioned 9ff1 bacteria decompose urinary stone components and make them easier to peel off by fulfilling their respective functions. In addition, the odor contained in the urinary stone decomposer can be masked and reduced due to the aromatic fragrance components that are simultaneously produced. In addition, 11%
(1) Bacillus iE, especially B. subtilis [I
AM (Institute of Applied M
icrobiology; Abbreviation for the Preservation Facility for Useful Bacterial Strains, Institute of Applied Microbiology, University of Tokyo; hereinafter referred to as this abbreviation) 1
Bacillus natto [IFO (Institut@
for Fers+antation Osaka:
3009] Bacillus, Bacillus coagula/C (B
．． coagulans) [IAllI 11151, Bacillus v. macerans [IAM
1243] may be used in combination. ■Streptococcus
) may be any bacteria of the genus S. faecalis [IAM 11
19], Streptococcus talemorris (S. cra
soris) [IAM 1150] and lactis (5.
lactis) [IAM 1198]. ■As bacteria of the genus Enterobacter, especially Enteropacter sakazakii (
E. sakazakii) [IAM 126601,
Enterobacter agglomerans (E. agglo)
maraos) [IAM 12659], Enterobacter aerogenes (E. aerogenes) IIA
M 1183 and 12348], etc. can be used. In addition, a type of mold (Rhizobus)
As a fungus of the genus Rhizopus formosaensis, Rhizopus formosaensis
[IAl1 62501, Rhizopus-Sairizaz (Rh
izopus oryzae) [IAM 6006],
Rhizopus pseudosinensis
pseudochinensis) [IAM 6G42
] etc. can be used. (9 Bacteria of the genus Nitrosomonas include Nitrosomonas *Europaea (N.e.
uropaaa) [IF0 1429g], etc. can be used. (eNitrobacter
As bacteria of the genus tar), Nitrobacter agilis (
N. Agilis) [IFO 14297], etc. can be used. ■Pseudomonas
As a fungus of the genus Pseudomonas nas ), Pseudomonas nitroreducens (p.
FO 12694], Pseudomonas caryophyllis [IFO 129
501,'/Eudomonas stutoseli (P. st.
utzeri) [IFO3773] can be used. and (■Cellulomonas)
As a fungus of the genus, Cellulomonas biazotea (C. b.
iazotea) [IF0 12680], Cellulomonas cellasea (C. cellasea) [IF0
3753], Cellulomonas uda (C. Uda) [IF
O3747] etc. can be used. Also, as a fungus of the Aspergillus genus,
Aspergillus oryzae (E, oryzae) [I
FO 4176], Asbergillus niger (E. n.
iger) [IF0 4066], Asperginoles
Usamii (E. usamii) [IF0 6082]
etc. can be used. In addition, the culture medium used for the microbial component of the present invention may be made of agricultural waste such as soybean residue or bran, and yeast extract or malt extract may be used in combination as the case requires. Powders of calcium carbonate, Rll magnesium, calcium silicate, etc. are used as carriers for the microbial components. [Effect] The mechanism of wastewater treatment by the microorganism-based fast-acting urinary stone decomposer of the present invention is thought to be as follows. That is, bacteria of the genus Bacillus decompose mainly organic substances such as starch and proteins that emit bad odors in the urinary stone components, and the sugars and hydrocarbons produced by the decomposition are absorbed by bacteria of the genus Streptococcus. The microorganisms and Rhizopus genus bacteria rapidly decompose further, promoting fermentation and removing malodorous substances. Then, Bacillus 3K bacterial cells, Streptococcus
), Aspergillus (Asp@rgillus)
Microbial cells of the genus Rhizopus and microbial cells of the genus Rhizopus decompose urinary stone components. Furthermore, the bacteria of the genus Nitrosomonas, Nitrobacter, and Pseudomonas used in the present invention contribute to the decomposition of ammonia that occurs in large amounts in urinary stone components. Nitrosomonas bacteria are ammonia →
No. -, and Nitrobacter cells are NO. −→N
O s -, Pseudomonas cells are N O s
−→N, and the problem of the bad odor of ammonia could be solved with the bacteria of these three genera. And Cellulomonas
The cells of this genus partially decompose the cellulose components present in urinary stone components. The urinary stone decomposing agent of the present invention can be produced as follows. That is, in the present invention, in order to increase the number of microorganisms in the constituent components and the amount of enzymes, organic acids, etc. produced by the microorganisms, and the amount secreted by the microorganisms, it is possible to For production, first, weigh appropriate amounts of the above microbial components (microorganisms + medium and carrier), sugars, water-soluble nitrogen compounds, and water, place them in a jar fermenter, and set the temperature to 2.
The temperature was 0 to 45°C, and the oxygen was 0.1 to 2. Stir for 24 to 60 hours while aerating the mixture at a rate of 1/2 inch. Add appropriate amounts of fragrance ingredients and surfactant to the resulting solution to prepare a urinary stone decomposer product. Next, the method of using the urinary stone decomposing agent of the present invention is that when used on urinary stone components attached to a toilet bowl, microorganisms have high activity, can prevent the generation of bad odor, and can easily remove urinary stones. It is. In the urinary stone decomposer, a large amount of microorganisms exist and are activated.
Completely decomposes and ferments bad odors and excrement. The microorganism-based urolith decomposer of the present invention is particularly fast-acting and suitable for decomposing urinary stone components in a short period of time. Furthermore, it is suitable for other sewage and wastewater treatment. Next, the microorganism-based urinary stone decomposing agent of the present invention will be explained using specific examples, but the present invention is not limited to the following examples. [Example] Ig Bacillus subtilis [IAM 1168] bacteria belonging to the genus Bacillus, B. Coagula
ns) [IAM 1115] 0.4 g of bacteria, S. faecalis of the genus Streptococcus
) [IAM 1119] Ig bacteria, Enterobacter
(Enterobacter) fi Enteropacter sakazakii (}:.sakazakii) [IAM
12660], 0.4g, Rhizop
us) 14 Norbus sapiensis (R.
forgosaensis > [IAM 6250] Bacterium, Nitrosomonas IX, Nitromonas europaea (l.europaea)
) [IF0 14298] Bacteria, Nitrobacter (Nit
Nitrobacter agilis (robactar) genus
N. agilis) [IF0 14297] Bacteria, Pseudomonas aeruginosa of the genus Pseudomonas [P.
0.6 g each of IF0 30801 bacteria, 0.5 g of A. oryzas [IF0 4176] bacteria of the genus Aspergillus, and 0.5 g of E. niger.
Weigh 1g of [IFO 4066] and add 2 sucrose to it.
0 0 g, ammonium chloride 8 g and 15000 cc
of distilled water was weighed into a jar fermenter and stirred at 30°C for 48 hours while blowing oxygen at 0.217 minutes. The number of viable bacteria in the resulting solution indicates that bacteria of the genus Bacillus are
7X1G'''/g, Streptococcus bacteria, 2
．． l X 1 0+17 g, Enterobacter genus bacteria 7.2xto''/gs Rhizopus genus bacteria s.
zxtOl4/g was present. Furthermore, bacteria of the genus Nitrosomonas have a concentration of 2.4×1o I*/g1
Bacteria of the genus Nitrobacter are 4.3 x 101/g and bacteria of the genus Pseudomonas are 3.3 x 1 0 1 1 7
g1 Bacteria of the genus Cellulomonas showed a large value of 2.1 x lO'/g, and bacteria of the genus Aspergillus showed a large value of 9.2 amylase, protease, lipase, etc.) totaling 0.001
It was 5%. Furthermore, the organic acid that seems to have been converted is also 1
%Met. 0.15 g of sodium abietate and 0.4 g of sodium dicutyl sulfosuccinate were mixed per 1000 g of the solution having the above composition to prepare the fast-acting urinary stone dissolving agent of the present invention. The following tests were conducted on the microorganism-based urinary stone dissolving agent obtained in this way. Immediately, use this dissolving agent to clean the inside of the men's toilet bowl (under the perforated plate).
We observed whether it was easier to remove urinary stones attached to the body, the outside (edge), and the surrounding area. For the inside of the men's toilet bowl (below the perforated plate), seal the bottom of the perforated plate and fill it with an aqueous solution.For the outside N (edge) and surrounding area, soak the aqueous solution into water-absorbing paper and apply it. This was done by placing it on top of the attached urinary stone. After a certain period of time, that is, 1, 2, 4, and 6 hours after the start of each test, the removability of the urinary stones was investigated using a screwdriver or a medicine ruler. At the same time, the pH and ammonia content were measured. As a control test, conventional microorganisms and enzyme preparations (Control A
), a similar test was conducted using distilled water (blind test) at a water temperature of about 30"C.1 The test conditions and test results are summarized in Table 1.The amount of ammonia in the untreated case is , 260 ppm or more, and pH 9.1. From Table 1, it is clear that the following is true. Regarding the removability of urinary stones, Control A showed its effect from 120 minutes after the start of the test, while this The urinary stone dissolving agent of the invention is
It showed a clear effect after 10 minutes, and at the same time, the generation of ammonia was suppressed and the pH value became neutral. [Effects of the Invention] The microorganism-based urinary stone dissolving agent of the present invention is a treatment agent for urinary stones that tend to generate bad odors, by adding microorganisms of nine genera.
As a nutrient source to enhance the biological activity of these microorganisms,
By adding sugars and water-soluble nitrogen compounds, it grows extremely actively in the presence of oxygen supplied during the reaction, and can produce and produce large amounts of enzymes and organic acids that are effective in decomposing urinary stones. Urinary stones can now be broken down in a short period of time, for example 10 minutes. In the case of urinary stones, they are composed of quite a large number of components, and these components vary, so the ability to decompose them would not be great without the action of various bacteria. Therefore, the present invention provides, firstly, a urinary stone dissolving agent that quickly removes urinary stones that are difficult to remove and cause a bad odor during toilet cleaning; and secondly, Bacillus ( Baci1
1us) M, Streptococcus
ccus) genus, Aspergillus
us) genus, Cellulosonas
Bacteria of the genus Rhizopus decompose uric acid, which is the main component of urinary stones, and organic matter attached to the surface of urinary stones. As it actively multiplies as a nutrient source and can demonstrate its ability in a short period of time, the processing time required to cleanly and easily remove urinary stones is significantly reduced compared to conventional microbial enzyme preparations. Thirdly, due to the combination of bacteria of the genus Nitrosomonas, bacteria of the genus Nitrobacter, and bacteria of the genus Pseudomonas contained in the microbial component, , Nitrosomonas bacteria can convert ammonia → Not-, Nitrobacter bacteria can convert NO1- → NO*-, and Pseudomonas bacteria can convert NO, - → N. It is strengthened in the presence of inventive additives and oxygen, making it a conventional product. In this way, the present invention is able to decompose ammonia in a shorter time than conventional microorganisms. , Enzyme products have achieved remarkable technical effects, such as unexpected decomposition and solubility of urinary stones. Patent applicant: Mitsubishi Mining and Cement Co., Ltd. Representative: Hiroshi Kuramochi, patent attorney
Claims (2)
０重量部に対し、糖類を１０〜１０００重量部、水溶性
窒素化合物１０〜５００重量部、香料成分１〜１００重
量部、界面活性剤５〜２００重量部及び水３００００重
量部未満から構成され、該微生物成分、糖類、水溶性窒
素化合物及び水が温度２０〜４５℃、酸素供給量０．１
〜２．０ｌ／分の条件下で２４〜６０時間攪拌反応して
得られるものであることを特徴とする速効性尿石溶解剤
。(1) Microbial component 1 consisting of microorganisms, culture medium, and carriers
0 parts by weight, 10 to 1000 parts by weight of saccharides, 10 to 500 parts by weight of water-soluble nitrogen compounds, 1 to 100 parts by weight of fragrance ingredients, 5 to 200 parts by weight of surfactants, and less than 30,000 parts by weight of water, The microbial components, sugars, water-soluble nitrogen compounds, and water are heated at a temperature of 20 to 45°C and an oxygen supply amount of 0.1.
A fast-acting urinary stone dissolving agent characterized in that it is obtained by a stirring reaction for 24 to 60 hours under conditions of ~2.0 l/min.
９属から構成され、バチルス（Ｂａｃｉｌｌｕｓ）属、
ストレフトコッカス（Ｓｔｒｅｐｔｏｃｏｃｃｕｓ）属
の菌、エンテロバクター（Ｅｎｔｅｒｏｂａｃｔｅｒ）
属の菌、リゾープス（Ｒｈｉｚｏｐｕｓ）属の菌、ニト
ロソモナス（Ｎｉｔｒｏｓｏｍｏｎａｓ）属の菌、ニト
ロバクター（Ｎｉｔｒｏｂａｃｔｅｒ）属の菌、シュー
ドモナス（Ｐｓｅｕｄｏｍｏｎａｓ）属の菌、セルロモ
ナス（Ｃｅｌｌｕｌｏｍｏｎａｓ）属の菌、アスペルギ
ルス（Ａｓｐｅｒｇｉｌｌｕｓ）属の菌からなることを
特徴とする請求項第１項記載の速効性尿石溶解剤。(2) The microorganism component according to claim 1 is comprised of nine genera of microorganisms, including the genus Bacillus,
Enterobacter, a member of the Streptococcus genus
Fungi of the genus Rhizopus, fungi of the genus Nitrosomonas, fungi of the genus Nitrobacter, fungi of the genus Pseudomonas, fungi of the genus Cellulomonas, and Aspergillus. (illus) 2. The fast-acting urinary stone dissolving agent according to claim 1, characterized in that it consists of bacteria of the genus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5602089A JPH02237688A (en) | 1989-03-10 | 1989-03-10 | Urolith dissolving agent having quick effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5602089A JPH02237688A (en) | 1989-03-10 | 1989-03-10 | Urolith dissolving agent having quick effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02237688A true JPH02237688A (en) | 1990-09-20 |
Family
ID=13015382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5602089A Pending JPH02237688A (en) | 1989-03-10 | 1989-03-10 | Urolith dissolving agent having quick effect |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02237688A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006077051A (en) * | 2004-09-07 | 2006-03-23 | Rifure:Kk | Slow-soluble medicinal agent of urolith adhesion inhibitor, and the like |
| JP2013043988A (en) * | 2011-08-26 | 2013-03-04 | Toshi Kakugyo Kk | Urinary calculus removing agent |
-
1989
- 1989-03-10 JP JP5602089A patent/JPH02237688A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006077051A (en) * | 2004-09-07 | 2006-03-23 | Rifure:Kk | Slow-soluble medicinal agent of urolith adhesion inhibitor, and the like |
| JP4541076B2 (en) * | 2004-09-07 | 2010-09-08 | 京都リフレ新薬株式会社 | Urine stone adhesion inhibitor |
| JP2013043988A (en) * | 2011-08-26 | 2013-03-04 | Toshi Kakugyo Kk | Urinary calculus removing agent |
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