JPH02233539A - Slag block - Google Patents

Slag block

Info

Publication number
JPH02233539A
JPH02233539A JP5445889A JP5445889A JPH02233539A JP H02233539 A JPH02233539 A JP H02233539A JP 5445889 A JP5445889 A JP 5445889A JP 5445889 A JP5445889 A JP 5445889A JP H02233539 A JPH02233539 A JP H02233539A
Authority
JP
Japan
Prior art keywords
slag
binder
steel
aggregate
blast furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5445889A
Other languages
Japanese (ja)
Inventor
Yuichi Urakawa
浦川 勇一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP5445889A priority Critical patent/JPH02233539A/en
Publication of JPH02233539A publication Critical patent/JPH02233539A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08Slag cements

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Road Paving Structures (AREA)

Abstract

PURPOSE:To inexpensively provide a slag block having a high quality comprising the same compression strength and bulk density as a concrete block using the conventional ortland cement by utilizing a steel slag by-produced in a steel industry as both a binder and an aggregate and using specific slags in a specified ratio as the binder. CONSTITUTION:A block prepared by kneading prescribed amounts of a binder, a fine aggregate, a rough aggregate and a kneading water and molding the mixture is composed as follows. A ground and crushed steel slag is utilized as an alternative for all of the binder, the fine aggregate and the rough aggregate, and the steel slag as the binder comprises a blast furnace slag and a steel mill slag. A rapidly cooled blast furnace slag having a high glass content is used as the blast furnace slag for one component of the binder. A converter slag, electric furnace slag, etc., is employed as the steel mill slag for another component of the binder. The furnace slag and the steel mill stag as the binder are preferably used in a ration of approximately 20-90:80-10%.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、鉄鋼産業において発生する鉄鋼スラグを結合
材、骨材等に有効利用して得られるスラグブロックに関
するものである. (従来の技術) 従来、セメントコンクリートで製造したコンクリ−1・
ブロックは、土木用コンクリート製品、建築用コンクリ
ート製品として、多方面にわたって使用されている。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a slag block obtained by effectively utilizing steel slag generated in the steel industry as a binding material, aggregate, etc. (Conventional technology) Conventionally, concrete 1.
Blocks are used in a wide range of fields as concrete products for civil engineering and construction.

これらコンクリートブロックの主原料となっているコン
クリートは、結合材としてセメント、細骨材として天然
砂あるいは人工砂、粗骨材として砂利、砕石等の天然石
あるいは人工石等の材料を計量し、混純水として所定量
の水と共にミキサーで混練して得られる。
Concrete, which is the main raw material for these concrete blocks, is made by measuring and mixing materials such as cement as a binder, natural sand or artificial sand as a fine aggregate, and natural stone such as gravel or crushed stone or artificial stone as a coarse aggregate. It is obtained by kneading it with a predetermined amount of water in a mixer.

その後、前記混練されたコンクリートを型枠に注入して
ブロックの成形、および定められた条件で養生を行う′
ことによって、所定の強度を有するコンクリートブロッ
クが製造されている。
After that, the mixed concrete is poured into a formwork to form a block and cured under specified conditions.
By this method, concrete blocks having a predetermined strength are manufactured.

近年、これらのコンクリートブロックには、細骨材およ
び粗脅材の材料として、鉄鋼スラグ等を粉砕した人工砂
、人工石等が使用されるようになってきている。
In recent years, artificial sand, artificial stone, etc., which are obtained by crushing steel slag, etc., have been used as materials for fine aggregate and coarse aggregate in these concrete blocks.

(発明が解決しようとする課B) 上述したように、コンクリー゛トブロックの主原料であ
るコンクリートは、細骨材、粗骨材、場合によっては混
和材および補強材を相互に強固に結合させる結合材とし
て、セメントが配合されていまた、このセメントは主と
して石灰石、粘土等の原料が用いられ、原料の採掘、焼
成、粉砕、および分級作業等の複数の工程を経て生産さ
れている。従って、普通ボルトランドセメントを生産す
るにあたっては、自然界に存在する限りある資源が多量
に消費され、やがて枯渇する恐れがあるばかりでなく、
複数の工程を経て生産されるので石油、石炭、および電
力等のエネルギー消費量も多大になると云う問題がある
(Problem B to be Solved by the Invention) As mentioned above, concrete, which is the main raw material for concrete blocks, is made up of fine aggregates, coarse aggregates, and in some cases admixtures and reinforcing materials that are bonded to each other firmly. Cement is blended as a material, and this cement mainly uses raw materials such as limestone and clay, and is produced through multiple processes such as mining, firing, crushing, and classifying the raw materials. Therefore, in producing ordinary Boltland cement, not only is a large amount of limited resources that exist in nature consumed, but there is a risk that they will eventually become depleted.
Since it is produced through multiple steps, there is a problem in that it consumes a large amount of energy such as oil, coal, and electricity.

さらに、普通ボルトランドセメントは、上述したように
複数の工程を経て生産されるので、コストが高くなると
云う問題がある。
Furthermore, since ordinary Boltland cement is produced through multiple steps as described above, there is a problem in that the cost is high.

本発明は、省資源、省エネルギーが図れる鉄鋼スラグを
主原料として、ブロックを成形することができるスラグ
ブロックを提供することを目的とする. (課題を解決するための手段) 上述した目的を達成するために本発明のスラグブロック
は、所定量の結合材、細骨材、粗骨材、および混練水と
を混練、成形して得られるブロックであって、前記結合
材、細骨材、および粗骨材の全てを粉砕及び破砕した鉄
綱スラグとすると共に、前記結合材としての鉄鋼スラグ
は高炉スラグと製鋼スラグとを配合した鉄鋼スラグを用
いた構成としている. (作用) 本発明の結合材である高炉スラグとしての高炉急冷スラ
グは、流下する高温の高炉溶融スラグに圧力水や高圧空
気を吹き付けて細粒化すれば、放射、伝熱により冷却速
度が増大し、急冷されて、ガラス化率の高いスラグとし
て得られる.このガラス賞の2、冷スラグは活性が強く
、アルカリ性水溶液の存在のもとでは、水和物を生成し
て硬化する特性がある。
An object of the present invention is to provide a slag block that can be formed into blocks using steel slag as the main raw material, which can save resources and energy. (Means for Solving the Problems) In order to achieve the above-mentioned objects, the slag block of the present invention is obtained by kneading and molding predetermined amounts of a binder, fine aggregate, coarse aggregate, and kneading water. The block is a steel slag obtained by crushing and crushing all of the binding material, fine aggregate, and coarse aggregate, and the steel slag as the binding material is a steel slag that is a mixture of blast furnace slag and steelmaking slag. It is configured using (Function) If the rapidly cooled blast furnace slag as the blast furnace slag which is the binder of the present invention is made fine by spraying pressure water or high pressure air on the flowing high temperature molten blast furnace slag, the cooling rate will increase due to radiation and heat transfer. It is then rapidly cooled and obtained as slag with a high vitrification rate. Second in this glass award, cold slag is highly active and has the property of forming hydrates and hardening in the presence of an alkaline aqueous solution.

一方、同様に結合材として用いられる製鋼スラグ中には
、可溶性カルシウムが多量に含有されており、溶解時に
はアルカリ性水溶液となる.従って、これらの性質を利
用してスラグブロックの結合材となすものである. そして、細骨材、粗骨材として所定の大きさに破砕整粒
された鉄鋼スラグと、結合材として微粉砕された高炉急
冷スラグおよび製鋼スラグとを加え、混練水と共に混練
すると流動性を有するコンクリート状のスラグ流動体が
得られる。
On the other hand, steelmaking slag, which is also used as a binder, contains a large amount of soluble calcium, which becomes an alkaline aqueous solution when dissolved. Therefore, these properties are used as a binding material for slag blocks. Then, steel slag that has been crushed and sized to a predetermined size as fine aggregate and coarse aggregate, and pulverized quenched blast furnace slag and steelmaking slag as binders are added, and when mixed with mixing water, it becomes fluid. A concrete-like slag fluid is obtained.

前記高炉急冷スラグは種々の方法で得られるが、その一
つとして高温の高炉溶融スラグを、圧力水で細粒化と冷
却を同時に行って得られる高炉水砕スラグが一般的に知
られており、製鋼スラグは、転炉、電気炉等で発生する
スラグが代表的である.また、結合材としてのスラグ割
合は、高炉水砕スラグを20〜90%、製鋼スラグを1
0〜80%とするのが望ましい. そして、前記入ラグ流動体に存在する液相中のCaOは
、高炉水砕スラグから溶解してくるSiOt,八l,0
,等と結合して水和物を形成し、凝結硬化するので、こ
の反応に必要な量を確保できるように、使用する製鋼ス
ラグの量を設定する.また、前記高炉水砕スラグは、C
aO溶液等のアルカリ水溶液の刺激を受けると水和して
凝結硬化する、所謂潜在水硬性を有している.この潜在
水硬性を利用して、セメントの代用としての結合材の役
割をなさしめるものであるが、潜在水硬性を大きく発現
するために、高炉水砕スラグ粒子の比表面積は3000
cj/g以上とすることが好ましい。
The quenched blast furnace slag can be obtained by various methods, one of which is generally known as granulated blast furnace slag, which is obtained by simultaneously refining and cooling high-temperature blast furnace molten slag with pressure water. The typical steelmaking slag is the slag generated in converters, electric furnaces, etc. In addition, the ratio of slag as a binder is 20 to 90% granulated blast furnace slag and 1% steelmaking slag.
It is desirable that it be between 0 and 80%. CaO in the liquid phase existing in the incoming lag fluid is dissolved from SiOt,8l,0, which is dissolved from the granulated blast furnace slag.
, etc. to form a hydrate and solidify and harden, so the amount of steelmaking slag to be used should be set so as to ensure the amount necessary for this reaction. Furthermore, the granulated blast furnace slag contains C
It has a so-called latent hydraulic property that hydrates and solidifies when stimulated by an alkaline aqueous solution such as an aO solution. Utilizing this latent hydraulic property, it plays the role of a binder as a substitute for cement, but in order to greatly express the latent hydraulic property, the specific surface area of granulated blast furnace slag particles is 3000.
It is preferable to set it as cj/g or more.

そして、上記潮在水硬性を刺激するのに必要なアルカリ
刺激材としては、転炉スラグ、電気炉スラグ等の製鋼ス
ラグを使用する.この製鋼スラグは可溶性のカルシウム
を多量に含有するので、該製鋼スラグと混練水とを混練
すると、Ca (OH) zの高濃度アルカリ水溶液が
得られる. 従って、微粉砕した高炉水砕スラグと製澗スラグとを結
合材とし、鉄鋼スラグを原料とした細骨材、粗骨材、お
よび混練水とを一緒に混練すると、pH12以上のアル
カリ水溶液中で結合材が反応して水和物を生成し、セメ
ントを使用した場合と略同等の強度を発現するものであ
る。
Steelmaking slag such as converter slag and electric furnace slag is used as the alkaline stimulant necessary to stimulate the above-mentioned tidal hydraulic properties. Since this steelmaking slag contains a large amount of soluble calcium, when this steelmaking slag and kneading water are kneaded, a highly concentrated alkaline aqueous solution of Ca (OH) z can be obtained. Therefore, when pulverized granulated blast furnace slag and milled slag are used as a binder, and fine aggregate made from steel slag, coarse aggregate, and kneading water are kneaded together, it is possible to mix the fine aggregate, coarse aggregate, and kneading water together in an alkaline aqueous solution with a pH of 12 or higher. The binding material reacts to form a hydrate, which provides approximately the same strength as when cement is used.

また、前記製鋼スラグの溶解を促進するために、該製鋼
スラグ粒子の比表面積は3000cj/g以上とするこ
とが好ましい。さらに、製鋼スラグ中に有害量の遊離石
灰を含有していると、これが吸水してCa (OH) 
!に変化する際の体積膨張が、製品に膨張崩壊を生せし
めることがあるので、この種の転炉スラグ、電気炉スラ
グは予めエージング処理等によって、有害量の遊離石灰
を消滅(Ca (OH) tにしてしまう。)させて使
用するのが望ましい.結合材としての鉄鋼スラグについ
て上述したが、その他スラグブロックを構成する細骨材
および粗骨材等について以下に述べる。これら細骨材お
よび粗骨材の原料としては、所定の大きさに破砕整粒し
た高炉スラグ或いは製鋼スラグ、また両者を混合して共
に使用することができる。
Further, in order to promote dissolution of the steelmaking slag, the specific surface area of the steelmaking slag particles is preferably 3000 cj/g or more. Furthermore, if steelmaking slag contains harmful amounts of free lime, it will absorb water and produce Ca (OH).
! The volumetric expansion that occurs when the product changes to slag may cause the product to expand and collapse. Therefore, this type of converter furnace slag and electric furnace slag must be aged beforehand to eliminate harmful amounts of free lime (Ca(OH)). t). Although the steel slag as a binding material has been described above, other fine aggregates, coarse aggregates, etc. that constitute the slag block will be described below. As raw materials for these fine aggregates and coarse aggregates, blast furnace slag or steelmaking slag that has been crushed and sized to a predetermined size, or a mixture of both can be used.

高炉スラグのうち水砕スラグを粒度調整した細骨材は、
前述したように増在水硬性を有しているので結合材との
付着力に優れ、自らの結合力で長期にわたって硬化し、
製品の強度を増進せしめる特性がある。特に製品ブロッ
クを地下埋設物等に適用する際に、適度の湿度を製品ブ
ロックが維持できる場合は、この特性が最大に活用され
る。
Among blast furnace slag, fine aggregate made by adjusting the particle size of granulated slag is
As mentioned above, it has increased hydraulic properties, so it has excellent adhesion to binding materials, and hardens over a long period of time due to its own binding strength.
It has properties that increase the strength of the product. In particular, when applying the product block to underground objects, etc., if the product block can maintain an appropriate level of humidity, this characteristic is utilized to the maximum.

また、高炉スラグのうち徐冷したものは、細骨?、粗骨
材いずれにも使用でき、この徐冷した高炉スラグは粒子
表面に凹凸が多く、結合材との結合面積が大きいので、
特に曲げ強度が大きくなる有利な面を有している. ところで、上述した結合材、細骨材、粗骨材、および混
練水を加えて混練した後、成形、養生を行って得られる
製品は、同一形状であっても製品重量の異なるものがあ
る。これらの製品重量を調整するために、従来から重1
iJ1整用の軽量骨材を混合して、製■品の重t調整を
行っている。
Also, is the slowly cooled blast furnace slag fine bones? This slow-cooled blast furnace slag can be used as both coarse aggregate and has many irregularities on the particle surface and a large bonding area with the binder.
In particular, it has the advantage of increased bending strength. Incidentally, the products obtained by adding and kneading the above-mentioned binder, fine aggregate, coarse aggregate, and kneading water, followed by molding and curing may have different product weights even if they have the same shape. In order to adjust the weight of these products, we have traditionally
Lightweight aggregate for iJ1 is mixed to adjust the weight of the product.

そして、軽量骨材として付着力を高めるために発泡水砕
等で得られる高炉スラグを使用する場合は、結合材とし
てCaO fA度が大きくなるスラグ粉末を用い、C−
S−11系永和物の量を好ましい範囲に安定生成せしめ
ることが望ましい。
When blast furnace slag obtained by foam granulation is used as a lightweight aggregate to increase adhesion, slag powder with a high CaO fA degree is used as a binder, and C-
It is desirable to stably produce the amount of S-11 permanent products within a preferred range.

また、上記重量調整用の軽量骨材の嵩比重は、0.1 
〜1.3 g/cdの範囲が望ましい。
In addition, the bulk specific gravity of the lightweight aggregate for weight adjustment is 0.1
A range of ~1.3 g/cd is desirable.

(実施例) 本発明の一実施例を以下詳細に説明する。次に示す第1
表はスラグブロックを製造する場合の材料配合を示した
一例である. 上記第1表に示した如く、結合材として高炉水砕スラグ
粉末(ブレーン値;4500cd/g) 、転炉スラグ
粉末(ブレーン値. 3500Cd/g)及び取鍋スラ
グ粉末(ブレーン値; 3000d/g)との3種頬と
、細骨・材として高炉スラグ細骨材(FM2.3) と
、粗骨材として高炉スラグ粗骨材(5〜2h/m )と
、混練水として水道水とをミキサー内に投入して混練す
る。
(Example) An example of the present invention will be described in detail below. The first
The table is an example of the material composition for manufacturing slag blocks. As shown in Table 1 above, granulated blast furnace slag powder (Blaine value: 4500 cd/g), converter slag powder (Blaine value: 3500 Cd/g), and ladle slag powder (Blaine value: 3000 d/g) were used as binders. ), blast furnace slag fine aggregate (FM2.3) as the fine bone/material, blast furnace slag coarse aggregate (5 to 2 h/m ) as the coarse aggregate, and tap water as the mixing water. Pour into mixer and knead.

その後、従来のコンクリート供試体を製造する方法と同
じ方法で成形および養生を経て、嵩比重が0.5〜2.
5 g / c m Zのスラグコンクリートが得られ
る。但し、結合材、細骨材、および粗骨材ともに鉄鋼ス
ラグを使用しているため、蒸気養生、オートクレープ養
生の温度並びに養生時間については、独自の基準を設け
て行う。
Thereafter, it is formed and cured using the same method as for manufacturing conventional concrete specimens, until the bulk specific gravity is 0.5 to 2.
A slag concrete of 5 g/cm Z is obtained. However, since steel slag is used as the binder, fine aggregate, and coarse aggregate, unique standards are set for the temperature and curing time of steam curing and autoclave curing.

また、次に示す第2表は従来のコンクリートの配合を示
したものであり、本発明のスラグコンクリートと比較試
験を行う比較例である。
Further, Table 2 shown below shows the formulation of conventional concrete, and is a comparative example for conducting a comparison test with the slag concrete of the present invention.

尚、結合材のセメントは普通ボルトランドセメントを使
用し、細骨材として海砂(FM2.6)を使用し、粗骨
材として砕石の大きさは5〜20s/mのものを使用し
た. (以下、余白) 次に、鉄鋼スラグを配合した本発明のスラグコンクリー
トと、従来のコンクリートとの試験結果を以下第3表に
示す. (以下、余白) 尚、上記圧縮強度の単位はkg f / caである.
また、上記試験結果は、直径10cm、高さ20C1m
のテストビースを用いて、20゜C水中養生を行ったも
ので、上記数値は前記テストピース3本の平均値である
. 第3表からも明らかなように、鉄鋼スラグで横成する本
発明のスラグコンクリートと、結合材としてセメントを
使用した従来のコンクリートとを比較しても、圧縮強度
等において何ら遜色がない(発明の効果) 本発明によれば、潜在水硬性を有する高炉スラグと、可
溶性カルシウムを多量に含有する製鋼スラグとを配合し
た鉄鋼スラグを結合材として使用することにより、得ら
れるスラグブロックは、セメントを結合材とするコンク
リートブロックと比較しても、圧縮強度、嵩比重が変わ
らない高品質の製品となる. また、鉄鋼産業において発生する鉄綱スラグを結合材並
びに骨材として利用するので、省資源、省エネルギーを
図ることができ、低廉なスラグブロックが得られる. 特許出願人 株式会社 神戸製鋼所 代理人   弁理士  金丸 章一
Normal Boltland cement was used as the cement for the binding material, sea sand (FM2.6) was used as the fine aggregate, and crushed stone with a size of 5 to 20 s/m was used as the coarse aggregate. (Hereinafter, blank space) Next, the test results of the slag concrete of the present invention containing steel slag and conventional concrete are shown in Table 3 below. (Hereinafter, blank space) The unit of the above compressive strength is kgf/ca.
In addition, the above test results are 10cm in diameter and 20C1m in height.
The test beads were cured in water at 20°C, and the above values are the average values of the three test pieces. As is clear from Table 3, even when comparing the slag concrete of the present invention formed laterally with steel slag and the conventional concrete using cement as a binder, there is no difference in compressive strength etc. (invention According to the present invention, a slag block obtained by using steel slag, which is a mixture of blast furnace slag having latent hydraulic properties and steelmaking slag containing a large amount of soluble calcium, as a binder, This is a high-quality product with the same compressive strength and bulk specific gravity compared to the concrete block used as a binding material. In addition, since steel slag generated in the steel industry is used as a binder and aggregate, resource and energy savings can be achieved, and an inexpensive slag block can be obtained. Patent applicant: Kobe Steel, Ltd. Representative Patent attorney: Shoichi Kanemaru

Claims (1)

【特許請求の範囲】[Claims] 所定量の結合材、細骨材、粗骨材、および混練水とを混
練、成形して得られるブロックであって、前記結合材、
細骨材、および粗骨材の全てを粉砕及び破砕した鉄鋼ス
ラグとすると共に、前記結合材としての鉄鋼スラグは高
炉スラグと製鋼スラグとを配合した鉄鋼スラグを用いた
ことを特徴とするスラグブロック。
A block obtained by kneading and molding predetermined amounts of a binder, fine aggregate, coarse aggregate, and kneading water, the block comprising the binder,
A slag block characterized in that all of the fine aggregate and the coarse aggregate are crushed and crushed steel slag, and the steel slag as the binding material is a mixture of blast furnace slag and steelmaking slag. .
JP5445889A 1989-03-06 1989-03-06 Slag block Pending JPH02233539A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5445889A JPH02233539A (en) 1989-03-06 1989-03-06 Slag block

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5445889A JPH02233539A (en) 1989-03-06 1989-03-06 Slag block

Publications (1)

Publication Number Publication Date
JPH02233539A true JPH02233539A (en) 1990-09-17

Family

ID=12971232

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5445889A Pending JPH02233539A (en) 1989-03-06 1989-03-06 Slag block

Country Status (1)

Country Link
JP (1) JPH02233539A (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06305789A (en) * 1993-04-27 1994-11-01 Fuwa Sangyo Kk Hydraulic composition for construction and building
WO1998014410A1 (en) * 1996-09-30 1998-04-09 N.V. Union Miniere S.A. Process for the conversion of iron bearing residues into a synthetic rock
JP2001261387A (en) * 2000-03-24 2001-09-26 Kawasaki Steel Corp Solidification method for steelmaking slag
WO2001072653A1 (en) * 2000-03-28 2001-10-04 Kawasaki Steel Corporation Method for producing hardened slag product
KR100406318B1 (en) * 2000-10-17 2003-11-19 김진만 Manufacture and product of High strength whangtoh Block
KR100415641B1 (en) * 1998-11-13 2004-03-19 주식회사 포스코 Formed material using slag sand
KR100415640B1 (en) * 1998-11-12 2004-03-19 주식회사 포스코 Formed material using slag of iron and steel works
KR100451821B1 (en) * 1999-11-12 2004-10-08 주식회사 포스코 Improvement Method of Incipient Strength of Concrete Using BF Slag Cement
JP2004292201A (en) * 2003-03-26 2004-10-21 Denki Kagaku Kogyo Kk Admixture for concrete and concrete composition
JP2007146438A (en) * 2005-11-25 2007-06-14 Ooshima Design Sekkei:Kk Paving stone block
JP2007210848A (en) * 2006-02-10 2007-08-23 Jfe Steel Kk Hydration-hardening body
JP2007269562A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269561A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269558A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269557A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269559A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269560A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
KR100954155B1 (en) * 2009-10-01 2010-04-20 한국철도기술연구원 Concrete composition for prestressed concrete sleeper
CN104016599A (en) * 2014-05-22 2014-09-03 韶关学院 Adjusting material for carrying out high temperature activation treatment on electric furnace white slag, and application thereof
CN104058648A (en) * 2014-05-29 2014-09-24 安徽华塑股份有限公司 Slag concrete and preparation method thereof
CN108083697A (en) * 2017-11-27 2018-05-29 广东省建筑材料研究院 A kind of large dosage steel slag concrete building block and preparation method thereof

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06305789A (en) * 1993-04-27 1994-11-01 Fuwa Sangyo Kk Hydraulic composition for construction and building
CN1073057C (en) * 1996-09-30 2001-10-17 联合矿业有限公司 Process for the conversion of iron bearing residues into a synthetic rock
AU728319B2 (en) * 1996-09-30 2001-01-04 N.V. Union Miniere S.A. Process for the conversion of iron bearing residues into a synthetic rock
US6284038B1 (en) 1996-09-30 2001-09-04 N.V. Union Miniere S.A. Process for the conversion of iron bearing residues into a synthetic rock
WO1998014410A1 (en) * 1996-09-30 1998-04-09 N.V. Union Miniere S.A. Process for the conversion of iron bearing residues into a synthetic rock
KR100415640B1 (en) * 1998-11-12 2004-03-19 주식회사 포스코 Formed material using slag of iron and steel works
KR100415641B1 (en) * 1998-11-13 2004-03-19 주식회사 포스코 Formed material using slag sand
KR100451821B1 (en) * 1999-11-12 2004-10-08 주식회사 포스코 Improvement Method of Incipient Strength of Concrete Using BF Slag Cement
JP2001261387A (en) * 2000-03-24 2001-09-26 Kawasaki Steel Corp Solidification method for steelmaking slag
WO2001072653A1 (en) * 2000-03-28 2001-10-04 Kawasaki Steel Corporation Method for producing hardened slag product
CN100360450C (en) * 2000-03-28 2008-01-09 杰富意钢铁株式会社 Method for producing hardened slag product
KR100406318B1 (en) * 2000-10-17 2003-11-19 김진만 Manufacture and product of High strength whangtoh Block
JP2004292201A (en) * 2003-03-26 2004-10-21 Denki Kagaku Kogyo Kk Admixture for concrete and concrete composition
JP2007146438A (en) * 2005-11-25 2007-06-14 Ooshima Design Sekkei:Kk Paving stone block
JP4660695B2 (en) * 2005-11-25 2011-03-30 株式会社オーシマ・デザイン設計 Paving blocks
JP2007210848A (en) * 2006-02-10 2007-08-23 Jfe Steel Kk Hydration-hardening body
JP2007269562A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269561A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269558A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269557A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269559A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
JP2007269560A (en) * 2006-03-31 2007-10-18 Jfe Steel Kk Hydrated hardened body having reinforcing rod excellent in neutralization resistance and salt damage resistance
KR100954155B1 (en) * 2009-10-01 2010-04-20 한국철도기술연구원 Concrete composition for prestressed concrete sleeper
CN104016599A (en) * 2014-05-22 2014-09-03 韶关学院 Adjusting material for carrying out high temperature activation treatment on electric furnace white slag, and application thereof
CN104058648A (en) * 2014-05-29 2014-09-24 安徽华塑股份有限公司 Slag concrete and preparation method thereof
CN108083697A (en) * 2017-11-27 2018-05-29 广东省建筑材料研究院 A kind of large dosage steel slag concrete building block and preparation method thereof

Similar Documents

Publication Publication Date Title
JPH02233539A (en) Slag block
EP0809613B1 (en) Fly ash cementitious material
KR101591275B1 (en) Ultra-high strength concrete for improving construct ability, and manufacturing method for the same
CN110423057A (en) Gangue base geological polymer and preparation method thereof
CN107344840A (en) A kind of preparation method of phosphorus base grouting material
CN106927701A (en) A kind of special composite gelled material of maritime concrete and its production method and purposes
CN111620624A (en) Self-compacting concrete and preparation method thereof
WO2017085565A2 (en) Portland cement free activation of ground granulated blast furnace slag
JP2000211956A (en) Cement composition
EP1888480B1 (en) High performance concrete with a quick resistance development lacking added materials with latent hydraulic activity
JP2011132111A (en) Hydraulic composition
CN1283597A (en) High-activity fine steelslag powder as additive of concrete and process for preparing concrete
JP2019014617A (en) Geopolymer composition and geopolymer-cured body
CN115893888A (en) Lithium slag-based early-strength high-strength cementing material and preparation method thereof
CN110183167A (en) A kind of high-density concrete and preparation method thereof of doping metals aggregate
KR100876143B1 (en) High strength silica mortar composition and method of manufacturing the same
JP5464663B2 (en) Calcium aluminate clinker and quick-hardening material and quick-hardening admixture for injection
CN107721209A (en) A kind of portland cement and preparation method
CN101125739A (en) High-activity alkali ore slag fly ash inorganic polymer gel material and manufacturing method thereof
CN112429993A (en) Steel slag pervious concrete and preparation process thereof
CN113716928A (en) Road, water-stable layer thereof and preparation process
CN112225485A (en) Nucleating agent, copper tailing autoclaved aerated concrete product, preparation method and application
JPH0826794A (en) Production of cement
CN1097404A (en) With flyash is that filler is produced the gypsum lightweight brick
JPH06115998A (en) Production of hydraulic composition