JPH02229898A - Bleaching detergent composition - Google Patents
Bleaching detergent compositionInfo
- Publication number
- JPH02229898A JPH02229898A JP1230776A JP23077689A JPH02229898A JP H02229898 A JPH02229898 A JP H02229898A JP 1230776 A JP1230776 A JP 1230776A JP 23077689 A JP23077689 A JP 23077689A JP H02229898 A JPH02229898 A JP H02229898A
- Authority
- JP
- Japan
- Prior art keywords
- component
- hydrogen peroxide
- peroxide
- bleaching
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000003599 detergent Substances 0.000 title claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000012190 activator Substances 0.000 claims abstract description 18
- -1 polyoxyethylene Polymers 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000002091 cationic group Chemical group 0.000 claims abstract description 9
- 150000002978 peroxides Chemical class 0.000 claims abstract description 7
- 150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 4
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 4
- 239000007844 bleaching agent Substances 0.000 claims description 19
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000010586 diagram Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000004365 Protease Substances 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 235000006468 Thea sinensis Nutrition 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 235000020279 black tea Nutrition 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229940045872 sodium percarbonate Drugs 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- CPZRYQJPVUJHOS-UHFFFAOYSA-N [2-(2-phenylethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CCC1=CC=CC=C1 CPZRYQJPVUJHOS-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000004343 Calcium peroxide Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 108010082455 Sebelipase alfa Proteins 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 1
- 235000019402 calcium peroxide Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N isocitric acid Chemical compound OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- 229940041615 kanuma Drugs 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000002186 photoactivation Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/3927—Quarternary ammonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は特定の漂白活性化剤を含有する漂白洗剤組成物
に関する．
〔従来の技術〕
従来より漂白洗剤には過炭酸ソーダ、過硼酸ソーダなど
の酸素系漂白剤が配合されている。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to bleaching detergent compositions containing specific bleach activators. [Prior Art] Conventionally, bleaching detergents contain oxygen bleaching agents such as sodium percarbonate and sodium perborate.
酸素系漂白剤は塩素系漂白剤にくらべ漂白カが弱《各種
漂白活性化剤が併用されている。代表的な活性化剤とし
て、テトラアセチルエチレンジアミン、アセトキシベン
ゼンスルボン酸ソーダ、イソノナノイルオキシベンゼン
スルボン酸ソーダ、テトラアセチルグリコリルウリル、
グルコースベンタアセテートなどが汎用されている。Oxygen bleach has weaker bleaching power than chlorine bleach (various bleach activators are used in combination). Typical activators include tetraacetylethylenediamine, sodium acetoxybenzenesulfonate, sodium isononanoyloxybenzenesulfonate, tetraacetylglycolyluril,
Glucose bentaacetate and the like are commonly used.
本発明者らは、前述した漂白活性化剤より優れた活性化
効果を示す漂白活性化剤について研究した結果、カチオ
ン基を有する活性化剤であり、しかも過酸化水素と反応
してカチオン基を有する有機過酸を生成する活性化剤が
漂白力を著しく向上することを見い出した。衣類あるい
は汚れの多くは負に帯電しているので、これらの漂白活
性化剤が衣類又は汚れの表面上に吸着あるいは濃縮され
た状態で存在し漂白効率を高めているものと推測される
．しかしながら、さらに研究を続けた結果、カチオン基
を有する漂白活性化剤を配合した漂白洗剤は再汚染の問
題を生ずることが判明した．
（課題を解決するための手段〕
本発明者らは、漂白洗剤系にカチオン基を有する漂白活
性化剤を併用すべく鋭意研究した結果、特定の界面活性
剤併用系であれば前述の再汚染の問題を解決できること
を見い出し本発明を完成した．
即ち、本発明は、
（ａ） 水に溶解して過酸化水素を生成する過酸化物
３〜３０重量％
（ｂ） 過酸化水素と反応してカチオン基を有する有
機過酸を生成する漂白活性化剤０．１〜３０重量％
（ｃ） アルキルベンゼンスルホン酸塩（ｄ） ア
ルキル硫酸塩
（ｅ） ポリオキシエチレンアルキルエーテル（ｃ）
＋ （ｄ） ＋ （ｅ） ＝ １０ 〜５０重量％（
ｃ）． （ｄ）， （ｅ）３成分の配合比は添付図面に
示す三角図表の点Ａ（ｃ成分９０％、ｄ成分９％、ｅ成
分１％）、Ｂ（ｃ成分６０％、ｄ成分３９％、ｅ成分１
％）、Ｃ（ｃ成分６０％、ｄ成分２０％、ｅ成分２０％
）、Ｄ（ｃ成分７５％、ｄ成分５％、ｅ成分２０％）、
ＥＣｃ成分９０％、ｄ成分５％、ｅ成分５％）で囲まれ
た範囲内にある
を含有することを特徴とする漂白洗剤組成物を提供する
ものである．
本発明に用いられる（ａ）成分の水に溶解して過酸化水
素を生成する過酸化物としては脊機及び無機過酸化水素
付加物である炭酸ナトリウム・過酸化水素付加物（過炭
酸ソーダ）、トリポリリン酸ナトリウム・過酸化水素付
加物、ピロリン酸ナ｝ ＩＪウム・過酸化水素付加物、
尿素・過酸化水素付加物、又は４ＮａｔＳＯ４・２Ｈｚ
Ｏｚ４８Ｃｌ等が例示される。又、過ホウ酸ナトリウム
ー水化物、過ホウ酸ナトリウム四水化物、過酸化ナトリ
ウム、過酸化カルシウム等の無機過酸化物も使用できる
。この中でも特に炭酸ナトリウム・過酸化水素付加物、
過ホウ酸ナトリウムー水化物、過ホウ酸ナトリウム四水
化物が好ましい．（ａ）成分の過酸化物は本発明の組成
物中に３〜３０重量％、好ましくは５〜１５重量％配合
される。The present inventors researched a bleach activator that has a superior activation effect than the bleach activators mentioned above, and found that it is an activator that has a cationic group, and that it reacts with hydrogen peroxide to generate a cationic group. It has been found that an activator that generates an organic peracid with a compound of the present invention significantly improves bleaching power. Since most clothing and stains are negatively charged, it is assumed that these bleach activators exist in an adsorbed or concentrated state on the surface of clothing or stains, increasing bleaching efficiency. However, further research revealed that bleach detergents containing bleach activators with cationic groups cause recontamination problems. (Means for Solving the Problems) As a result of intensive research into the use of a bleach activator having a cationic group in a bleach detergent system, the present inventors found that if a system in combination with a specific surfactant is used, the above-mentioned re-contamination can be avoided. The present invention was completed after discovering that the following problems could be solved.That is, the present invention consists of: (a) 3 to 30% by weight of peroxide that dissolves in water to produce hydrogen peroxide; (b) Reacts with hydrogen peroxide. 0.1 to 30% by weight of a bleach activator that produces an organic peracid having a cationic group (c) Alkylbenzene sulfonate (d) Alkyl sulfate (e) Polyoxyethylene alkyl ether (c)
+ (d) + (e) = 10 to 50% by weight (
c). (d), (e) The blending ratios of the three components are points A (90% c component, 9% d component, 1% e component) and B (60% c component, 39% d component) on the triangular diagram shown in the attached drawing. , e component 1
%), C (c component 60%, d component 20%, e component 20%
), D (c component 75%, d component 5%, e component 20%),
The present invention provides a bleaching detergent composition characterized in that it contains 90% of an ECc component, 5% of a d component, and 5% of an e component. Component (a) used in the present invention, a peroxide that dissolves in water to produce hydrogen peroxide, is a sodium carbonate/hydrogen peroxide adduct (soda percarbonate), which is a spinal and inorganic hydrogen peroxide adduct. , sodium tripolyphosphate/hydrogen peroxide adduct, sodium pyrophosphate} IJium/hydrogen peroxide adduct,
Urea/hydrogen peroxide adduct or 4NatSO4/2Hz
Examples include Oz48Cl. Inorganic peroxides such as sodium perborate hydrate, sodium perborate tetrahydrate, sodium peroxide, and calcium peroxide can also be used. Among these, especially sodium carbonate/hydrogen peroxide adducts,
Sodium perborate hydrate and sodium perborate tetrahydrate are preferred. Component (a), peroxide, is blended in the composition of the present invention in an amount of 3 to 30% by weight, preferably 5 to 15% by weight.
本発明に用いられる（ｂ）成分の過酸化水素と反応して
カチオン基を有する有機過酸を生成する漂白活性化剤と
しては、例えば、次のような化合物が挙げられる。Examples of the bleach activator used in the present invention that reacts with hydrogen peroxide, component (b), to produce an organic peracid having a cationic group include the following compounds.
Ｒｚ
？ｌ−（Ａ）Ｔ（Ｂ） ｌ，−Ｎ工（ｃ１１■）ｌ−（
０），−Ｃ−Ｌ Ｘ− （１）Ｒ３
０
式（１）中、Ｒ＋はＣｌ−Ｉｌ＋、特に０１〜，４の直
鎖又は分岐のアルキル基、Ａは一〇 − −ＮＨＣ
− −ＣＮＨ！１
Ｃ！１，
Ｉ
Ｂは−｛ＣＨｚｈ ，４０ＣＨｚＣＨｔ｝−又は−｛Ｏ
ＣＲＣＨアｈ（ｍは１〜１２、特に１〜５が好ましく、
ｎは１〜１０、特に１〜５が好ましい。）である，ａ．
ｂはａ＝Ｏ，ｂ−０であるか、又はａ＝１，ｂ＝１であ
るａ Ｒｚ＋ ”は炭素数１〜３のアルキル基又はヒド
ロキシアルキル基である。ｌは１〜ｌ２であり、ＣはＯ
又は１である。Ｌは脱Ｍ基であり、下記の（イ）〜（夕
）から選ばれる。Rz? l-(A)T(B) l,-N Engineering (c11 ■) l-(
0), -C-L X- (1) R3
0 In formula (1), R+ is Cl-Il+, especially a linear or branched alkyl group of 01 to 4, and A is 10--NHC
- -CNH! 1 C! 1, IB is -{CHzh,40CHzCHt}- or -{O
CRCHah (m is preferably 1 to 12, particularly preferably 1 to 5,
n is preferably 1 to 10, particularly preferably 1 to 5. ), a.
b is a=O, b-0, or a=1, b=1 a Rz+ '' is an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms; 1 is 1 to 12; C is O
Or 1. L is a de-M group and is selected from the following (a) to (y).
ル４、ＲｌｌはＣ３〜Ｃ４のアルキレン基、Ｒ，はフェ
ニル基又はＣ１。〜Ｃ３。のアルキル基、ＹはＩ１又は
Ｒ２
リ金属を表す。）
一般式（１）においてＸ−は無機又は有機の対イ（力）
−０−Ｒ．．（ヨ）グリセリン残基，又は
（タ）糖誘導体残基
（式中、Ｒ４はＣ，〜Ｃ２のアルキル基、Ｒｓ．Ｒｈは
Ｈ又はＣ，−Ｃｔのアルキル基、Ｒ７はＣ Ｉ− Ｃ
ｔのアルキＲ１。：炭素数１〜２０のアルキル基
ＲＩＩ＋ＲＩ＋！’炭素数１〜３のアルキル基又はヒド
ロキシアルキル基
ｌ：１〜２０
Ｙ ： Ｈ， ＣＯｚＯ，Ｓ（ｈＯ，ＣＯｔＭ又はＳＯ
Ｊ （ＭはＨ又はアルカリ金属）
？ ：アニオン（但し、ＹがＣＯ■ｅ，Ｓ■，（Ｅ）の
時番よＸはない．）
Ｒ目
■
Ｒｈｏ Ｎ ＧＨｚ ＣＮ
Ｘ０
（ＩＩＩ）
Ｌｘ
Ｒ＋ａ＋ Ｒｌｌ＋ Ｒｌｔ＋ Ｘ ’上記と同じＲ目
Ｒ＋ｏ＋ ＲＩＩ＋ Ｒｔｚ＋ Ｘ ’上記と同じｍ：
１〜３
Ｒｚ＋ Ｒ＋ｔ＋ Ｘ ：前記と同じ
Ｒ＋３ｒＲＩ４；炭素数１〜３のアルキル基又はヒドロ
キシアルキル基
ｎ ：１〜１６
Ｘ，Ｙは上記と同じ
本発明における（ｂ）成分は、これらの例に示されるよ
うに過酸化水素と反応してカチオン基を有する有機過酸
を生成する構造を有していればよく、これらの化合物に
限定されるものではない。（ｂ）成分の漂白活性化剤は
組成物中に０．１〜３０重量％、好ましくは２〜１５重
量％配合される。R4, Rll is a C3-C4 alkylene group, and R is a phenyl group or C1. ~C3. an alkyl group, Y represents I1 or R2 metal. ) In general formula (1), X- is an inorganic or organic pair (force)
-0-R. ．． (y) Glycerin residue or (t) sugar derivative residue (in the formula, R4 is a C, -C2 alkyl group, Rs.Rh is a H or C, -Ct alkyl group, R7 is a C I- C
alkyl R1 of t. : C1-C20 alkyl group RII+RI+! 'Alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms l: 1 to 20 Y: H, COzO, S (hO, COtM or SO
J (M is H or alkali metal)? : Anion (However, when Y is CO■e, S■, (E), there is no X.) Rth ■ Rho N GHz CN X0 (III) Lx R+a+ Rll+ Rlt+ X 'Same Rth as above R+o+ RII+ Rtz+X'm same as above:
1-3 Rz+ R+t+ X: Same as above R+3rRI4; C1-3 alkyl group or hydroxyalkyl group n: 1-16 The compound is not limited to these compounds as long as it has a structure that reacts with hydrogen peroxide to produce an organic peracid having a cationic group, as shown in FIG. Component (b), a bleach activator, is incorporated in the composition in an amount of 0.1 to 30% by weight, preferably 2 to 15% by weight.
本発明に用いられる（ｃ）成分のアルキルベンゼンスル
ホン酸塩としては、平均炭素数１０〜ｌ６のアルキル基
を有する直鎖又は分岐鎖アルキルベンゼンスルホン酸塩
が挙げられ、（ｄ）成分のアルキル硫酸塩としては平均
炭素数１０〜２０のアルキル基を有するアルキル硫酸塩
が挙げられる。（ｃ），（ｄ）成分の対イオンとしては
ナトリウム、カリウム等のアルカリ金属イオンが挙げら
れる。（ｅ）成分のポリオキンエチレンアルキルエーテ
ルとしては平均炭素数１０〜２０のアルキル基を存し、
１〜３０モルのエチレンオキサイドを付加したポリオキ
シエチレンアルキルエーテルが挙げられる．本発明の組
成物中の（ｃ）， （ｄ）． （ｅ）成分は前述した配
合比範囲になければならない。この範囲外ではカチオン
性の有機過酸を生成する漂白活性化剤を使用した場合再
汚染防止効果が不十分である． （ｃ）． （ｄ），
（ｅ）成分の配合比の好ましい範囲は、Ｆ（ｃ成分８５
％、ｄ成分１３％、ｅ成分２％）、Ｇ （ｃ成分６５％
、ｄ成分３３％、ｅ成分２％）、Ｈ（ｃ成分６５％、ｄ
成分２０％、ｅ成分１５％）、Ｉ（ｃ成分７５％、ｄ成
分１０％、ｅ成分１５％） 、Ｊ （ｃ成分８５％、ｄ
成分１０％、ｅ成分５％）で囲まれた範囲である． （
ｃ）． （ｄ）． （ｅ）成分は本発明の組成物中に総
量で１０〜５０重量％、好ましくは１５〜４０重量％配
合される．
本発明の組成物には次の様な漂白洗剤常用成分を必要に
応じて配合し得る。Examples of the alkylbenzene sulfonate as the component (c) used in the present invention include linear or branched alkylbenzene sulfonates having an alkyl group having an average carbon number of 10 to 16; Examples include alkyl sulfates having an alkyl group having an average carbon number of 10 to 20. Counter ions for components (c) and (d) include alkali metal ions such as sodium and potassium. (e) The polyoxine ethylene alkyl ether has an alkyl group having an average carbon number of 10 to 20,
Examples include polyoxyethylene alkyl ethers to which 1 to 30 moles of ethylene oxide are added. (c), (d) in the composition of the invention. Component (e) must be in the above-mentioned mixing ratio range. Outside this range, if a bleach activator that generates a cationic organic peracid is used, the recontamination prevention effect will be insufficient. (c). (d),
The preferred range of the blending ratio of component (e) is F (component c: 85
%, d component 13%, e component 2%), G (c component 65%
, d component 33%, e component 2%), H (c component 65%, d
component 20%, e component 15%), I (c component 75%, d component 10%, e component 15%), J (c component 85%, d
component (10%, e component 5%). (
c). (d). Component (e) is incorporated in the composition of the present invention in a total amount of 10 to 50% by weight, preferably 15 to 40% by weight. If necessary, the composition of the present invention may contain the following commonly used bleaching detergent ingredients.
即ち、ケイ酸塩、炭酸塩、セスキ炭酸塩、硫酸塩、オル
トリン酸塩、ピロリン酸塩、トリポＩＪ ＩＪン酸塩、
クエン酸塩、イソクエン酸塩、エチレンジアミン四酢酸
塩、ニトリロトリ酢酸塩、ポリアセタールカルボン酸塩
、ゼオライトなどのビルダー類が普通４０〜７５重量％
配合される。i.e. silicates, carbonates, sesquicarbonates, sulfates, orthophosphates, pyrophosphates, trypoIJIJ phosphates,
Usually 40-75% by weight of builders such as citrate, isocitrate, ethylenediaminetetraacetate, nitrilotriacetate, polyacetal carboxylate, zeolite etc.
It is blended.
又、他のア二オン界面活性剤、ノニオン界面活性剤、両
性界面活性剤なども適宜配合し得る。In addition, other anionic surfactants, nonionic surfactants, amphoteric surfactants, etc. may also be blended as appropriate.
その他ポリビニルアルコール、ポリビニルピロリドン、
カルボキシメチルセルロース、ボリエチレングリコール
、ポリアクリル酸塩などの再汚染防止剤、プロテアーゼ
、エスペラーゼ、リパーゼ、セルラーゼなどの酵素、そ
の他ケーキング防止剤、酸化防止剤、螢光染料、青味付
剤、光活性化漂白剤、香料なども配合される．〔実施例
〕
以下実施例に基づいて本発明を説明するが、本発明はこ
れら実施例に限定されるものではない．尚、実施例にお
いて、漂白率及び再汚染防止能の試験は以下に示す方法
によって行った．く漂白率の試験法〉
洗剤濃度０．０８３％の洗浄液に下記方法で調製した紅
茶汚染布（８Ｘ８ｃｄ、５枚）を入れターゴトメーター
で２０”Ｃ，１０分洗浄した後、水洗い、乾燥後、下記
方法により漂白率を求めた。Others polyvinyl alcohol, polyvinylpyrrolidone,
Recontamination inhibitors such as carboxymethyl cellulose, polyethylene glycol, and polyacrylates, enzymes such as protease, esperase, lipase, and cellulase, other caking inhibitors, antioxidants, fluorescent dyes, blue tinting agents, and photoactivation. Bleach and fragrance are also included. [Examples] The present invention will be described below based on Examples, but the present invention is not limited to these Examples. In the Examples, the bleaching rate and recontamination prevention ability were tested by the methods shown below. Test method for bleaching rate> Put black tea-stained cloth (8 x 8 cd, 5 sheets) prepared in the following method into a cleaning solution with a detergent concentration of 0.083%, wash with a tergotometer at 20"C for 10 minutes, then wash with water and dry. The bleaching rate was determined by the following method.
紅茶汚染布：
日東紅茶（黄色パッケージ）８０ｇを３２のイオン交換
水にて約１５分間煮沸後、糊抜きしたサラシ木綿でこし
、この液に木綿金巾＃２００３布を浸し、約１５分間煮
沸する。そのまま火よりおろし、２時間程度放置後自然
乾燥させ、洗液に色のつかなくなるまで水洗し、脱水、
プレス後、８Ｃ１１Ｘ８Ｃ１１の試験片とし、実験に供
した．紅茶汚染布の漂白率：
反射率は日本電色工業■製ＮＯＲ−１０１ＤＰで４６０
ｎｍフィルターを使用して測定した。Tea-contaminated cloth: Boil 80 g of Nitto black tea (yellow package) in 32 ion exchange water for about 15 minutes, strain it through desized dry cotton cloth, soak a #2003 cotton cloth in the liquid, and boil it for about 15 minutes. Remove from the heat, let stand for about 2 hours, then dry naturally. Rinse with water until the washing liquid is no longer colored, dehydrate,
After pressing, it was made into an 8C11 x 8C11 test piece and used for experiments. Bleaching rate of black tea contaminated cloth: Reflectance is 460 for NOR-101DP manufactured by Nippon Denshoku Kogyo ■
Measured using a nm filter.
〈再汚染防止能の試験法〉
（１）試験布
木綿（２００３布）を１０ Ｘ ＩＯＣＩ１に裁断し試
験布とする。<Test method for anti-recontamination ability> (1) Test cloth Cut cotton (2003 cloth) into 10 x IOCI1 pieces to use as a test cloth.
（２）汚れ
疎水性固体汚れ：カーボンブラック．平均粒径０．１μ
親水性固体汚れ；鹿沼赤玉土，２００メッシュのフルイ
にかけた通過品
（３）実験条件
温度；２０℃
硬度；４“ＤＩ
洗剤濃度； ０．０８３％
汚れ；カーボン ０．２５ｇ／Ｉｔ
泥 ２．５ｇ／／！
ターゴトメーター１０Ｏｒ． ｐ．ｍで１０分汚染、流
水すすぎ
（４）実験方法
１２のビーカーに、カーボン及び泥を指定量、サンプリ
ングし、指定濃度に溶かした洗剤液を少しずつ入れ、ガ
ラス棒で分散させ、温度を趨整し、ターゴトメーターの
試料カップに入れ、試験布３枚を投入し、１００ｒ．ｐ
．ｍで１０分間汚染させ、流水ですすぎ、プレス乾燥し
、日本電色工業■製ＮＤＲ−１０１ＤＰにて再汚染防止
率を求めた．
Ｒ（０）・・・原布の反射率
Ｒ （Ｓ）・・・汚染後の反射率
実施例１
下記配合組成を有する漂白洗剤を製造し、漂白率及び再
汚染防止率を求めた．結果を表−１に示す．
〈洗剤配合組成〉
ボリエチレングリコール（ＭＷ１３ＱＯＯ）プロテアー
ゼ
水
アルキル硫酸ソーダＣＣｌａ〜１，）表−１に示す量２
号珪酸ソーダ
炭酸ソーダ
４Ａ型ゼオライト
硫酸ソーダ
過炭酸ソーダ
実施例２
下記配合組成を有する漂白洗剤を製造し、漂白率及び再
汚染防止率を求めた。結果を表−２に示す。(2) Soil Hydrophobic solid stain: carbon black. Average particle size: 0.1μ Hydrophilic solid stain; Kanuma Akadama clay, passed through a 200 mesh sieve (3) Experimental conditions Temperature: 20°C Hardness: 4"DI Detergent concentration: 0.083% Soil; Carbon 0.25g /It Mud 2.5g//! Contaminate with Tergotometer 10 Or. p.m for 10 minutes, rinse with running water (4) In the beaker of Experimental Method 12, sample the specified amount of carbon and mud, and dissolve the detergent to the specified concentration. Pour the liquid little by little, disperse it with a glass rod, adjust the temperature, put it in the sample cup of the tergotometer, add 3 test cloths, and set it at 100 rpm.
．． The sample was contaminated with water for 10 minutes, rinsed with running water, press dried, and the recontamination prevention rate was determined using NDR-101DP manufactured by Nippon Denshoku Kogyo ■. R(0)...Reflectance of original fabric R(S)...Reflectance after staining Example 1 A bleaching detergent having the following composition was manufactured, and the bleaching rate and re-staining prevention rate were determined. The results are shown in Table 1. <Detergent composition> Polyethylene glycol (MW13QOO) Protease water alkyl sulfate sodium CCla~1,) Amount shown in Table 1 2
Sodium silicate soda Sodium carbonate Type 4A zeolite Sodium sulfate Sodium percarbonate Example 2 A bleaching detergent having the following composition was produced, and the bleaching rate and re-staining prevention rate were determined. The results are shown in Table-2.
〈洗剤配合組成〉
アルキル硫酸ソーダ（ｃ＋ｚ〜１，）８牛脂脂肪酸ソー
ダ
２号珪酸ソーダ
炭酸ソーダ
４Ａ型ゼオライト
硫酸ソーダ
過炭酸ソーダ
漂白活性化剤（表−２）
ポリエチレングリコール（？ＩＷ６０００）プロテアー
ゼ
水
４．<Detergent composition> Sodium alkyl sulfate (c+z~1,) 8 Beef tallow fatty acid soda No. 2 Sodium silicate Sodium carbonate 4 A type zeolite Sodium sulfate Sodium percarbonate Bleach activator (Table 2) Polyethylene glycol (?IW6000) Protease water 4 ．．
第１図は本発明の（ｃ）、 （ｄ）、 （ｅ）３成分の配合比 を示す三角図である。 FIG. 1 shows (c) of the present invention. (d), (e) Mixing ratio of three components FIG.
Claims (1)
３〜３０重量％ （ｂ）過酸化水素と反応してカチオン基を有する有機過
酸を生成する漂白活性化剤０．１〜３０重量％ （ｃ）アルキルベンゼンスルホン酸塩 （ｄ）アルキル硫酸塩 （ｅ）ポリオキシエチレンアルキルエーテル（ｃ）＋（
ｄ）＋（ｅ）＝１０〜５０重量％（ｃ）、（ｄ）、（ｅ
）３成分の配合比は添付図面に示す三角図表の点Ａ（ｃ
成分９０％、ｄ成分９％、ｅ成分１％）、Ｂ（ｃ成分６
０％、ｄ成分３９％、ｅ成分１％）、Ｃ（ｃ成分６０％
、ｄ成分２０％、ｅ成分２０％）、Ｄ（ｃ成分７５％、
ｄ成分５％、ｅ成分２０％）、Ｅ（ｃ成分９０％、ｄ成
分５％、ｅ成分５％）で囲まれた範囲 内にある を含有することを特徴とする漂白洗剤組成物。[Claims] 1. (a) 3 to 30% by weight of peroxide that dissolves in water to produce hydrogen peroxide (b) Reacts with hydrogen peroxide to produce an organic peracid having a cationic group. Bleach activator 0.1-30% by weight (c) Alkylbenzene sulfonate (d) Alkyl sulfate (e) Polyoxyethylene alkyl ether (c) + (
d) + (e) = 10-50% by weight (c), (d), (e
) The blending ratio of the three components is determined by point A (c) on the triangular diagram shown in the attached drawing.
component 90%, d component 9%, e component 1%), B (c component 6
0%, d component 39%, e component 1%), C (c component 60%
, d component 20%, e component 20%), D (c component 75%,
A bleaching detergent composition, characterized in that it contains within the range of (5% component d, 20% component e) and E (90% component c, 5% component d, 5% component e).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1230776A JPH02229898A (en) | 1988-09-22 | 1989-09-06 | Bleaching detergent composition |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63-237929 | 1988-09-22 | ||
| JP23792988 | 1988-09-22 | ||
| JP1230776A JPH02229898A (en) | 1988-09-22 | 1989-09-06 | Bleaching detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02229898A true JPH02229898A (en) | 1990-09-12 |
Family
ID=26529531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1230776A Pending JPH02229898A (en) | 1988-09-22 | 1989-09-06 | Bleaching detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02229898A (en) |
-
1989
- 1989-09-06 JP JP1230776A patent/JPH02229898A/en active Pending
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