JPH02217436A - Cylinder liner material having excellent wear resistance - Google Patents

Cylinder liner material having excellent wear resistance

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Publication number
JPH02217436A
JPH02217436A JP3703589A JP3703589A JPH02217436A JP H02217436 A JPH02217436 A JP H02217436A JP 3703589 A JP3703589 A JP 3703589A JP 3703589 A JP3703589 A JP 3703589A JP H02217436 A JPH02217436 A JP H02217436A
Authority
JP
Japan
Prior art keywords
cylinder liner
hardness
graphite
wear resistance
liner material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3703589A
Other languages
Japanese (ja)
Inventor
Yoshihiro Nakagawa
中川 義弘
Noburou Maeie
前家 信朗
Harunaga Kitamura
北村 晴祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP3703589A priority Critical patent/JPH02217436A/en
Publication of JPH02217436A publication Critical patent/JPH02217436A/en
Pending legal-status Critical Current

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  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

PURPOSE:To make hardness, strength and rigidity high while crystallizing flake graphite and to improve the wear resistance by forming cylinder liner material with the specific composition of Ni-Cr cast iron. CONSTITUTION:The cylinder liner material is constituted of 2.4-3.4wt.% C, 4.5-10.0wt.% Ni, 2.0-3.4wt.% Si, 5-10wt.% Cr, 0.15-1.5wt.% Mn, 0.4-3.0wt.% Mo and the balance substantially Fe. The flake graphite quantity crystallized in the structure is regulated to 5-20% area ratio. The molten iron having this composition is cast with the ordinary casting method or metallic mold centrifugal casting method as the cylinder liner. Then, it is better to execute inoculation with inoculant of Fe-Si, etc., to promote graphitization. By this method, a large quantity of high hardness Cr carbide can be generated and the hardness, tensile strength and Young's modulus can be made to high. Therefore, thickness of the cylinder liner can be made to thin.

Description

【発明の詳細な説明】 (産業上の利用分野) 自動車等のピストンエンジンに使用されるシリンダーラ
イナーの材料に関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to materials for cylinder liners used in piston engines such as automobiles.

(従来の技術) エンジンの主要構成部品の一つであるシリンダーライナ
ーには、耐摩耗性が良いこと、熱伝導性が良いこと、強
度・剛性が大きいこと、ピストンとのなじみが良いこと
、耐食性が良いことが必要条件とされ、近年、低NOx
対策や高出力化のため過酷な条件で使用される傾向にあ
る。このため、その耐久性を向上させる工夫が種々なさ
れている。
(Prior technology) The cylinder liner, which is one of the main components of an engine, has the following characteristics: good wear resistance, good thermal conductivity, high strength and rigidity, good compatibility with the piston, and corrosion resistance. In recent years, low NOx
They tend to be used under harsh conditions due to countermeasures and high output. For this reason, various efforts have been made to improve its durability.

材質面では、一般にP−Cr系鋳鉄が主流で、その他に
、Ni5Cr、 Cu5V等を加えたもの、あるいは、
Nb、 Bを添加したものがある。ライナー摺動面には
、片状黒鉛を晶出させ、基地をパーライトとし、更にス
テダイトおよびセメンタイト炭化物を析出させ、摺動面
の硬度は、IIRI 95〜101程度とされている。
In terms of materials, P-Cr cast iron is generally the mainstream, and other materials include Ni5Cr, Cu5V, etc.
Some contain Nb and B. On the sliding surface of the liner, flaky graphite is crystallized, pearlite is used as a base, and steadite and cementite carbide are precipitated, and the hardness of the sliding surface is approximately IIRI 95 to 101.

又、シリンダーライナーには、ピストンリングとのなじ
みが問題となり、摺動面にホーニング加工を行なって、
一定の深さの溝を形成させて、エンジンの潤滑油消費量
(LOC)の減少が図られている。一方、製造法として
は、普通鋳造法が主流であるが、金型遠心力鋳造法も開
発されている。
In addition, the cylinder liner had a problem with fitting in with the piston ring, so the sliding surface was honed.
By forming grooves of a certain depth, an attempt is made to reduce the lubricating oil consumption (LOC) of the engine. On the other hand, the mainstream manufacturing method is the ordinary casting method, but a mold centrifugal casting method has also been developed.

(発明が解決しようとする課H) 従来の片状黒鉛鋳鉄を硬く、強くするために合金を多く
含有させた場合は、硬度が高くなっても・、片状黒鉛が
少なくなり、摺動部材としての機能が低下する傾向があ
った。
(Problem H to be solved by the invention) When conventional flake graphite cast iron is made to contain a large amount of alloy to make it hard and strong, even if the hardness increases, the flake graphite content decreases and the sliding member There was a tendency for the function to decline.

本発明はかかる問題点に鑑みなされたもので、片状黒鉛
を晶出させながら、従来材よりも高硬度で、強度や剛性
が大きく、かつ耐摩耗性に優れたシリンダーライナー材
を提供することを目的とする。
The present invention was made in view of the above problems, and an object of the present invention is to provide a cylinder liner material that crystallizes flaky graphite and has higher hardness, greater strength and rigidity, and superior wear resistance than conventional materials. With the goal.

(課題を解決するための手段) 上記目的を達成するためになされた本発明のシリンダー
ライナー材は、化学組成が重量%で、C:2.4〜3.
4%、 Ni:4,5〜10.0%Si :  2.0
〜3.4%、 Cr:  5〜10%Mn :  0.
5〜1.5%、 Mo :  0.4〜3.0%、残部
実質的にFeから成り、組織中に片状黒鉛が面積率で5
〜20%晶出していることを発明の構成とするものであ
る。
(Means for Solving the Problems) The cylinder liner material of the present invention, which has been made to achieve the above object, has a chemical composition of 2.4 to 3.0% by weight.
4%, Ni: 4.5-10.0%Si: 2.0
~3.4%, Cr: 5-10% Mn: 0.
5 to 1.5%, Mo: 0.4 to 3.0%, the remainder substantially consists of Fe, and flake graphite in the structure has an area ratio of 5.
The composition of the invention is that ~20% crystallization occurs.

(作 用) 本発明のシリンダーライナー材の化学組成は以下の理由
により限定される。組成単位は以下すべて重量%である
(Function) The chemical composition of the cylinder liner material of the present invention is limited for the following reasons. All composition units below are weight %.

C:2.4〜3.4% CはCrと結合してCr炭化物を形成し、また後述のS
i、 Niの黒鉛生成元素により微細な黒鉛となって晶
出する。2.4%未満ではCr炭化物量が減少すると共
に黒鉛の晶出もほとんどなくなる。
C: 2.4-3.4% C combines with Cr to form Cr carbide, and also contains S as described below.
It crystallizes into fine graphite due to graphite-forming elements such as i and Ni. If it is less than 2.4%, the amount of Cr carbide decreases and crystallization of graphite almost disappears.

一方、3.4%を越えると、本発明の場合Cr含有量が
10%以下とされているので、過飽和のCが高濃度Sj
、 Niのため多量に黒鉛化し、晶出黒鉛が過剰となっ
て耐摩耗性が劣化する。
On the other hand, if it exceeds 3.4%, supersaturated C becomes a high concentration Sj
, Ni causes a large amount of graphitization, resulting in excessive crystallized graphite and deterioration of wear resistance.

Si:2.0〜3.4% Siは高クロム材質に黒鉛を晶出させるために必要で、
2.0%未満ではこの効果がほとんどなく、3.4%を
越えると黒鉛量が過多となり耐摩耗性を劣化させる。な
おSiの添加については、鋳込前のSi量を上記限定範
囲よりも低目にしておき、鋳込時に接種を行い最終製品
の組成で上記範囲に入るように調整する方が黒鉛の晶出
に有効である。
Si: 2.0-3.4% Si is necessary to crystallize graphite in high chromium materials.
If it is less than 2.0%, this effect will hardly be achieved, and if it exceeds 3.4%, the amount of graphite will be excessive and will deteriorate the wear resistance. Regarding the addition of Si, it is better to keep the amount of Si before casting lower than the above limited range, inoculate it during casting, and adjust the composition of the final product so that it falls within the above range to prevent graphite crystallization. It is effective for

Mn : 0.5〜1.5% Mnは溶湯の脱酸のためにSi と共に積極的に添加す
る。0.5%未満ではこの効果が不足し、1.5%を越
えると機械的性質特に靭性の劣化が著しくなる。
Mn: 0.5-1.5% Mn is actively added together with Si to deoxidize the molten metal. If it is less than 0.5%, this effect is insufficient, and if it exceeds 1.5%, the deterioration of mechanical properties, particularly toughness, becomes significant.

Ni : 4.5〜10% 旧は基地組織の改良と黒鉛を晶出させるために積極的に
含有させるもので、4.5%未満では黒鉛の晶出が困難
となる。一方、10%を越えるとStの場合と同様、晶
出黒鉛が過多となる。また、残留オーステナイトが増加
して、耐肌荒性の面で問題となる。
Ni: 4.5 to 10% In the old case, it was actively included to improve the matrix structure and crystallize graphite, but if it is less than 4.5%, it becomes difficult to crystallize graphite. On the other hand, if it exceeds 10%, as in the case of St, too much crystallized graphite will occur. In addition, retained austenite increases, which poses a problem in terms of skin roughness resistance.

Cr : 5〜10% CrはCと結合してCr炭化物を形成するが、5%未満
では該炭化物が少なく耐摩耗性の点で劣り、10%を越
えると上記Ni、 Stの組成範囲では黒鉛が晶出困難
となる。
Cr: 5 to 10% Cr combines with C to form Cr carbide, but if it is less than 5%, there are few carbides and the wear resistance is poor, and if it exceeds 10%, it will become graphite in the above Ni and St composition ranges. becomes difficult to crystallize.

Mo : 0.4〜3.0% Moは焼入焼戻し抵抗を高めると共に、炭化物中に入り
、炭化物硬度を高めると同時に焼戻軟化抵抗を向上させ
るのに有効である。その含有量が0.4%未満ではこの
ような効果が少なく、一方3.0%を越えると白銑化傾
向が強く黒鉛の晶出が困難となる。
Mo: 0.4 to 3.0% Mo increases the quenching and tempering resistance, enters into the carbide, and is effective in increasing the hardness of the carbide and simultaneously improving the tempering and softening resistance. If the content is less than 0.4%, such effects will be small, while if it exceeds 3.0%, there will be a strong tendency to white iron, making it difficult to crystallize graphite.

本発明の鋳鉄材は以上の成分のばか残部実質的にFeで
形成される。尚、Sは成分を脆くするので少ない程望ま
しく、s:o、、oe%以下に止めておくのがよい。一
方、Pも一般的に材質を脆くするので少ない程望ましい
が、摺動耐摩耗材としては、P共晶組織を出すことによ
り、耐焼付性、耐摩耗性を向上させるため、0.8%程
度以下の含有が許容される。
The cast iron material of the present invention is formed essentially of Fe, with the remainder of the above components being substantially Fe. Incidentally, since S makes the component brittle, it is preferable to have a small amount, and it is preferable to keep it at s:o,, oe% or less. On the other hand, P generally makes the material brittle, so it is desirable to have less P, but as a sliding wear-resistant material, it is about 0.8% because it improves seizure resistance and wear resistance by creating a P eutectic structure. The following contents are allowed.

一方、組織中の片状黒鉛量は面積%で5〜20%に規制
される。5%未満では耐焼付性に劣り、方20%を越え
ると、強度、ヤング率が低下し、ひいては剛性も低下す
る。
On the other hand, the amount of flaky graphite in the structure is regulated to 5 to 20% by area. If it is less than 5%, the seizure resistance will be poor, and if it exceeds 20%, the strength and Young's modulus will decrease, and the rigidity will also decrease.

本発明の鋳鉄材は、前記化学組成の溶湯を普通鋳造法又
は金型遠心力鋳造法によりシリンダーライナーとして鋳
造する。その際、Fe−3i等の接種材によって接種を
行ない、黒鉛化を促進するのがよい。
The cast iron material of the present invention is produced by casting a molten metal having the above chemical composition into a cylinder liner by a normal casting method or a die centrifugal casting method. At that time, it is preferable to inoculate with an inoculant such as Fe-3i to promote graphitization.

(実施例) 〈実施例A〉 (1)下記第1表の化学組成(重量%)の鋳鉄材を溶製
し、砂型鋳造を行なって試験素材を得た。
(Example) <Example A> (1) A cast iron material having the chemical composition (wt%) shown in Table 1 below was melted and sand cast to obtain a test material.

尚、同表中Nα1〜3が本発明実施例、NIIL4が比
較例、阻5が従来例である。
In the same table, Nα1 to Nα3 are examples of the present invention, Nα4 is a comparative example, and Nα5 is a conventional example.

第1表 (2)  (1)の素材より試料を採取し、引張試験お
よび焼付性試験に供した。その結果を第1表に示す。
Samples were taken from the materials shown in Table 1 (2) (1) and subjected to a tensile test and a seizure test. The results are shown in Table 1.

また、実施例中代表的成分であるNα2および比較例N
α4について、光学顕微鏡による組織観察を行った。そ
の結果を随2については、第1図(1)および(2)に
、Nα4については第2図(1)および(2)に示す。
In addition, Nα2, which is a typical component in Examples, and Comparative Example N
Regarding α4, the structure was observed using an optical microscope. The results are shown in FIG. 1 (1) and (2) for Aki 2, and in FIG. 2 (1) and (2) for Nα4.

各組織写真とも50倍であり、図中(1)は腐食なし、
(2)は腐食後のものである。また、Nα2および漱5
について、熱的特性を調べた結果を第2表に併せて示す
Each structure photograph is 50x magnified, and (1) in the figure shows no corrosion;
(2) is after corrosion. In addition, Nα2 and Sō5
Table 2 also shows the results of examining the thermal properties of

第2表中、焼付性試験は下記のファレックス試験により
、判定したものであり、Oは焼付発生有、×は無を意味
する。
In Table 2, the seizure property test was determined by the Falex test described below, where O means seizure occurrence and x means no seizure occurrence.

■ ファレックス試験は、第3図に示すように、テスト
ビン11の一端を回転機12にシアービン13によって
固定し、その他端を一定荷重Pの下で一対の■ブロック
14.14により挾み付けながらテストピース11を回
転させ、回転に要したトルクにより焼付の有無、程度を
調べるものである。
■ As shown in Fig. 3, the Farex test is carried out by fixing one end of the test bin 11 to the rotary machine 12 with a shear bin 13, and holding the other end between a pair of ■ blocks 14 and 14 under a constant load P. The test piece 11 is rotated, and the presence or absence and degree of seizure is examined based on the torque required for rotation.

■ 試験条件は下記の通りであった。■ The test conditions were as follows.

テストビン寸法−・−・・−φ6.5 X40f■ブロ
ック寸法・・・−・・φ12(材質SUS 430)テ
ストビン回転数・−300rp11 負荷荷重P−・−−−−−−−−−−35kg f試験
環境−・〜−−−−−−−−−−・−・−大気中無潤滑
第2表 (3)評価 従来例No、5は、片状黒鉛が多量に発生し、基地はパ
ーライトの軟らかい組織であり、硬度は11s34 (
ills 99)、ヤング率は9900kgf/mm”
であったが、実施例は、第1図のように片状黒鉛と、多
くのCr炭化物、基地から成り、硬度も、11!170
〜75、ヤング率18000 kgf/am”程度あっ
た。
Test bin dimensions: -φ6.5 Test environment ----------------------In the atmosphere without lubrication Table 2 (3) Evaluation Conventional example No. 5 generates a large amount of flaky graphite, and the base is made of pearlite. It is a soft tissue with a hardness of 11s34 (
ills 99), Young's modulus is 9900 kgf/mm”
However, as shown in Fig. 1, the example consists of flaky graphite, many Cr carbides, and a base, and the hardness is 11!170.
~75, Young's modulus was approximately 18,000 kgf/am''.

また、焼付試験の結果には、従来例、実施例(Nal〜
3)では、黒鉛が片状であり、面積が6%以上あるので
、焼付は生じなかった。しかし、比較例Nα4の如く、
黒鉛が粒状で面積が4%程度では、焼付が発生した。
In addition, the results of the seizure test include conventional examples, examples (Nal to
In 3), the graphite was flaky and had an area of 6% or more, so no seizure occurred. However, as in Comparative Example Nα4,
Seizing occurred when the graphite was granular and had an area of about 4%.

また、引張強さは、実施例は従来例の2倍以上もあり、
ヤング率も1.8倍に達している。−方、熱伝導率は、
従来の片状黒鉛鋳鉄に比べてやや悪いが、引張強さ、ヤ
ング率が格段に大きいので、シリンダーライナーの厚さ
を薄くすることが可能となり、熱放散効果については何
ら問題がない。
In addition, the tensile strength of the example is more than twice that of the conventional example,
Young's modulus also reached 1.8 times. - On the other hand, the thermal conductivity is
Although it is slightly worse than conventional flake graphite cast iron, it has much higher tensile strength and Young's modulus, so it is possible to reduce the thickness of the cylinder liner, and there is no problem with heat dissipation.

〈実施例B〉 (1)第1表Nα2の溶湯を遠心力金型鋳造により、外
径119mmφ、内径104waφ、肉厚7.5鴫、長
さ1835mmの円筒素材を鋳造した。鋳造に際して接
種材としてCa−5iを1.2%(Si分として0.6
%)取鍋および鋳込中に添加した。
<Example B> (1) A cylindrical material having an outer diameter of 119 mmφ, an inner diameter of 104 mm, a wall thickness of 7.5 mm, and a length of 1835 mm was cast from the molten metal Nα2 in Table 1 by centrifugal force die casting. During casting, 1.2% Ca-5i (0.6% Si content) was added as an inoculum.
%) added during ladle and pouring.

(2)  その後、該素材に550’CX 15tlr
の歪除去熱処理を施した後、目標の寸法のシリンダーラ
イナーに加工した。硬度を測定したところHs71であ
った、また、組織観察したところ、基地中に片状黒鉛が
面積率で7.5%晶出していた。尚、硬度については、
機械加工の面からあまり高くできない場合は、歪取温度
を高くして低硬度にすることも可能である。
(2) Then, apply 550'CX 15tlr to the material.
After applying strain removal heat treatment, it was processed into a cylinder liner with the target dimensions. When the hardness was measured, it was Hs71, and when the structure was observed, flaky graphite was crystallized in the matrix at an area ratio of 7.5%. Regarding hardness,
If the hardness cannot be increased too high from the viewpoint of machining, it is also possible to lower the hardness by increasing the strain relief temperature.

(3)該シリンダーライナーを組み込んだエンジンを用
いて試験運転したところ、耐久性の著しい向上が見られ
、期待通りの効果が得られた。
(3) When a test run was conducted using an engine incorporating the cylinder liner, a remarkable improvement in durability was observed, and the expected effects were obtained.

(発明の効果) 以上説明した通り、本発明のシリンダーライナー材は特
定組成のニッケル・クロム鋳鉄材で形成したので、基地
中に片状黒鉛を晶出させると共に多量の高硬度Cr炭化
物を生成させることができ、硬度、引張強さおよびヤン
グ率を大きくすることができ、そのためシリンダーライ
ナーの厚さを薄くすることができ、しかも耐摩耗性に優
れる。また片状黒鉛晶出量を所定量に規定しているので
、優れた耐焼付を具備している。更に、ヤング率が大き
いため、機械加工時のチャックによる保持に対しても変
形が少なく、寸法精度の向上効果も期待することができ
る。
(Effects of the Invention) As explained above, since the cylinder liner material of the present invention is formed from a nickel-chromium cast iron material with a specific composition, flaky graphite is crystallized in the matrix and a large amount of high hardness Cr carbide is generated. It is possible to increase the hardness, tensile strength and Young's modulus, and therefore the thickness of the cylinder liner can be reduced, and it also has excellent wear resistance. Furthermore, since the amount of flaky graphite crystallization is regulated to a predetermined amount, it has excellent seizure resistance. Furthermore, since the Young's modulus is large, there is little deformation when held by a chuck during machining, and an improvement in dimensional accuracy can be expected.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(1)および(2)は実施例のシリンダーライナ
ー材の金属組織写真、第2図(1)および(2)は比較
例のニッケルクロム鋳鉄材の金属組繊写真、第3図はフ
ァレックス試験要領説明図を示す。 第3 図 2閏(1)
Figures 1 (1) and (2) are photographs of the metal structure of the cylinder liner material of the example, Figures 2 (1) and (2) are photographs of the metal structure of the nickel chromium cast iron material of the comparative example, and Figure 3 is the metal structure photograph of the cylinder liner material of the example. An explanatory diagram of Falex test procedure is shown. 3 Figure 2 Leap (1)

Claims (1)

【特許請求の範囲】[Claims] (1)化学組成が重量%で、 C:2.4〜3.4%、Ni:4.5〜10.0%Si
:2.0〜3.4%、Cr:5〜10%Mn:0.5〜
1.5%、Mo:0.4〜3.0%、残部実質的にFe
から成り、組織中に片状黒鉛が面積率で5〜20%晶出
していることを特徴とする耐摩耗性に優れたシリンダー
ライナー材。
(1) Chemical composition in weight%: C: 2.4-3.4%, Ni: 4.5-10.0%Si
:2.0~3.4%, Cr:5~10%Mn:0.5~
1.5%, Mo: 0.4-3.0%, remainder substantially Fe
A cylinder liner material with excellent wear resistance characterized by having flaky graphite crystallized in the structure in an area ratio of 5 to 20%.
JP3703589A 1989-02-15 1989-02-15 Cylinder liner material having excellent wear resistance Pending JPH02217436A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3703589A JPH02217436A (en) 1989-02-15 1989-02-15 Cylinder liner material having excellent wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3703589A JPH02217436A (en) 1989-02-15 1989-02-15 Cylinder liner material having excellent wear resistance

Publications (1)

Publication Number Publication Date
JPH02217436A true JPH02217436A (en) 1990-08-30

Family

ID=12486367

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3703589A Pending JPH02217436A (en) 1989-02-15 1989-02-15 Cylinder liner material having excellent wear resistance

Country Status (1)

Country Link
JP (1) JPH02217436A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108048732A (en) * 2017-11-29 2018-05-18 马鞍山市恒特重工科技有限公司 A kind of processing method of impact-resistant abrasion-proof lining board

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108048732A (en) * 2017-11-29 2018-05-18 马鞍山市恒特重工科技有限公司 A kind of processing method of impact-resistant abrasion-proof lining board
CN108048732B (en) * 2017-11-29 2020-11-24 马鞍山市恒特重工科技有限公司 Processing method of impact-resistant wear-resistant lining plate

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