JPH02200789A - Dewaxing detergent - Google Patents
Dewaxing detergentInfo
- Publication number
- JPH02200789A JPH02200789A JP1982589A JP1982589A JPH02200789A JP H02200789 A JPH02200789 A JP H02200789A JP 1982589 A JP1982589 A JP 1982589A JP 1982589 A JP1982589 A JP 1982589A JP H02200789 A JPH02200789 A JP H02200789A
- Authority
- JP
- Japan
- Prior art keywords
- detergent
- alcohol
- ccl
- methyl
- dewaxing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000001298 alcohols Chemical class 0.000 claims abstract description 5
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 150000002576 ketones Chemical class 0.000 claims abstract description 3
- BLOAGLDWHISXHG-UHFFFAOYSA-N 1,1,3,3-tetrachloro-2,2-difluoropropane Chemical compound ClC(Cl)C(F)(F)C(Cl)Cl BLOAGLDWHISXHG-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000005238 degreasing Methods 0.000 claims description 12
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 2
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 claims 1
- -1 acetone Chemical compound 0.000 abstract description 13
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 abstract description 4
- 150000005827 chlorofluoro hydrocarbons Chemical class 0.000 abstract 2
- ZJULYDCRWUEPTK-UHFFFAOYSA-N dichloromethyl Chemical compound Cl[CH]Cl ZJULYDCRWUEPTK-UHFFFAOYSA-N 0.000 abstract 2
- WBLIXGSTEMXDSM-UHFFFAOYSA-N chloromethane Chemical compound Cl[CH2] WBLIXGSTEMXDSM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 3
- QPRQEDXDYOZYLA-UHFFFAOYSA-N 2-methylbutan-1-ol Chemical compound CCC(C)CO QPRQEDXDYOZYLA-UHFFFAOYSA-N 0.000 description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OJVAMHKKJGICOG-UHFFFAOYSA-N 2,5-hexanedione Chemical compound CC(=O)CCC(C)=O OJVAMHKKJGICOG-UHFFFAOYSA-N 0.000 description 2
- PFNHSEQQEPMLNI-UHFFFAOYSA-N 2-methyl-1-pentanol Chemical compound CCCC(C)CO PFNHSEQQEPMLNI-UHFFFAOYSA-N 0.000 description 2
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 2
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 2
- DUPUVYJQZSLSJB-UHFFFAOYSA-N 3-ethyl-2-methylpentane Chemical compound CCC(CC)C(C)C DUPUVYJQZSLSJB-UHFFFAOYSA-N 0.000 description 2
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical compound CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 description 2
- HTSABYAWKQAHBT-UHFFFAOYSA-N 3-methylcyclohexanol Chemical compound CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 2
- VLJXXKKOSFGPHI-UHFFFAOYSA-N 3-methylhexane Chemical compound CCCC(C)CC VLJXXKKOSFGPHI-UHFFFAOYSA-N 0.000 description 2
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000010730 cutting oil Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical group CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 description 2
- XAOGXQMKWQFZEM-UHFFFAOYSA-N isoamyl propanoate Chemical compound CCC(=O)OCCC(C)C XAOGXQMKWQFZEM-UHFFFAOYSA-N 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 2
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
- VTBOTOBFGSVRMA-UHFFFAOYSA-N 1-Methylcyclohexanol Chemical compound CC1(O)CCCCC1 VTBOTOBFGSVRMA-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- XTDQDBVBDLYELW-UHFFFAOYSA-N 2,2,3-trimethylpentane Chemical compound CCC(C)C(C)(C)C XTDQDBVBDLYELW-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- RLPGDEORIPLBNF-UHFFFAOYSA-N 2,3,4-trimethylpentane Chemical compound CC(C)C(C)C(C)C RLPGDEORIPLBNF-UHFFFAOYSA-N 0.000 description 1
- HQLKZWRSOHTERR-UHFFFAOYSA-N 2-Ethylbutyl acetate Chemical compound CCC(CC)COC(C)=O HQLKZWRSOHTERR-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- AVMSWPWPYJVYKY-UHFFFAOYSA-N 2-Methylpropyl formate Chemical compound CC(C)COC=O AVMSWPWPYJVYKY-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical compound CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 description 1
- NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
- MLLAPOCBLWUFAP-UHFFFAOYSA-N 3-Methylbutyl benzoate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1 MLLAPOCBLWUFAP-UHFFFAOYSA-N 0.000 description 1
- GIEZWIDCIFCQPS-UHFFFAOYSA-N 3-ethyl-3-methylpentane Chemical compound CCC(C)(CC)CC GIEZWIDCIFCQPS-UHFFFAOYSA-N 0.000 description 1
- QMYGFTJCQFEDST-UHFFFAOYSA-N 3-methoxybutyl acetate Chemical compound COC(C)CCOC(C)=O QMYGFTJCQFEDST-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- AGUBCDYYAKENKG-UHFFFAOYSA-N Abietinsaeure-aethylester Natural products C1CC(C(C)C)=CC2=CCC3C(C(=O)OCC)(C)CCCC3(C)C21 AGUBCDYYAKENKG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- AGUBCDYYAKENKG-YVNJGZBMSA-N Ethyl abietate Chemical compound C1CC(C(C)C)=CC2=CC[C@H]3[C@@](C(=O)OCC)(C)CCC[C@]3(C)[C@H]21 AGUBCDYYAKENKG-YVNJGZBMSA-N 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- UDEWPOVQBGFNGE-UHFFFAOYSA-N benzoic acid n-propyl ester Natural products CCCOC(=O)C1=CC=CC=C1 UDEWPOVQBGFNGE-UHFFFAOYSA-N 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229960002903 benzyl benzoate Drugs 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical group CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 1
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- PCYQQSKDZQTOQG-NXEZZACHSA-N dibutyl (2r,3r)-2,3-dihydroxybutanedioate Chemical compound CCCCOC(=O)[C@H](O)[C@@H](O)C(=O)OCCCC PCYQQSKDZQTOQG-NXEZZACHSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- XAHVPYNDLCTDTE-UHFFFAOYSA-N dipentyl oxalate Chemical compound CCCCCOC(=O)C(=O)OCCCCC XAHVPYNDLCTDTE-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- GFUIDHWFLMPAGY-UHFFFAOYSA-N ethyl 2-hydroxy-2-methylpropanoate Chemical compound CCOC(=O)C(C)(C)O GFUIDHWFLMPAGY-UHFFFAOYSA-N 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940035429 isobutyl alcohol Drugs 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- OLXYLDUSSBULGU-UHFFFAOYSA-N methyl pyridine-4-carboxylate Chemical compound COC(=O)C1=CC=NC=C1 OLXYLDUSSBULGU-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- MOQRZWSWPNIGMP-UHFFFAOYSA-N pentyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCC MOQRZWSWPNIGMP-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 201000000849 skin cancer Diseases 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
[産業上の利用分野]
本発明は金属加工油剤を用いて加工した金属部品等に付
着した油類を除去するために用いる脱脂洗浄剤に関する
ものである。
[従来の技術]
精密機械部品、電気部品等の切削加工工程で、切削油類
が使われるが、これらが付着したまままでは製品とはな
らない場合が多い。従って、通常このような部品の仕上
げ工程では有機溶剤を用いて洗浄を行なっている。その
有機溶剤として次に掲げるような種々の利点から、1.
1.2−トリクロロ−1,2,2−トリフルオロエタン
(以下R113という)が広く使われている。
R113は不燃性、非曝性で毒性が低(安定性も優れて
いる。しかも、金属、プラスチック、エラストマー等の
基材を侵さず各種の汚れを選択的に溶解する性質がある
。一般に被洗物は金属、プラスチック、エラストマー等
からなる複合部品が多く、従ってこの点からもR113
が有利であった。[Industrial Field of Application] The present invention relates to a degreasing cleaning agent used to remove oils adhering to metal parts processed using a metal working fluid. [Prior Art] Cutting oils are used in the cutting process of precision mechanical parts, electrical parts, etc., but in many cases, products cannot be manufactured if these oils remain attached. Therefore, in the finishing process of such parts, organic solvents are usually used for cleaning. As an organic solvent, it has various advantages as listed below: 1.
1,2-Trichloro-1,2,2-trifluoroethane (hereinafter referred to as R113) is widely used. R113 is nonflammable, non-exposure, and has low toxicity (it also has excellent stability).In addition, it has the property of selectively dissolving various types of dirt without attacking base materials such as metals, plastics, and elastomers. Many of the products are composite parts made of metal, plastic, elastomer, etc. Therefore, from this point of view, R113
was advantageous.
【発明が解決しようとする課題]
本発明は従来使用されていたR113が種々の利点を持
つにもかかわらず、成層圏のオゾンを破壊し、ひいては
皮膚ガンの発生をひき起す原因となる疑いがあることか
らそれに対応すべ(R1,13と同様な種々の利点を有
し、同等の洗浄が行なえる新規の脱脂洗浄剤を提供する
ことを目的とするものである。
[課題を解決するための手段J
本発明は前述の目的を達成すべ(なされたものであり、
炭素数が3である特定の塩化弗化炭化水素を有効成分と
して含有する脱脂洗浄剤を提供するものである。
本発明の塩化弗化炭化水素としては
CF、CF、CHCQF (R226ea)、CCQF
−CF−CHF* (R226eb)、CC(’5CF
tC)ICG!−(R222c) 、 CCQ−FCF
*C)ICQ* (R223ea) 。
CCQsCFsCHCQF(R223eb)、CCQi
CFaCHF* (R224cc)、C)ICII)l
CF、CMQ ! (R232ca、) 、 CC(
25cFtcH2CQ (R232cb)、CCQ、F
CF 、CM * CQ (R233eb) 、 CH
C(2xcF x(:H(JF (R233ca)、C
CQ、CFlCI(IF(R233CC)、(:CG!
mcFicl1m (R242cbLC)ICQiCF
xC)IiCQ(R242ea)等の水素含有塩化弗化
炭化水素から選ばれる1種又は2種以上の混合物が好ま
しい。
本発明の脱脂洗浄剤には、各種の目的に応じてその他の
各種成分を含有させることができる。例えば、溶解力を
高めるために、炭化水素類、アルコール類、ケトン類、
塩素化炭化水素類又はエステル類等の有機溶剤から選ば
れる少なくとも1種を含有させることができる。これら
の有機溶剤の脱脂洗浄剤中の含有割合は、0〜50重量
%、好ましくは1.0〜40重量%、さらに好ましくは
20〜30重量%である。本発明の塩化炭化水素類と有
機溶剤との混合物に共沸組成が存在する場合には、その
共沸組成での使用が好ましい。
炭化水素類としては炭素数1〜15の直鎖又は環状の飽
和又は不飽和炭化水素類が好まシ、<、n−ペンタン、
イソペンタン、n−ヘキサン、イソヘキサン、2−メチ
ルペンタン、2.2−ジメチルブタン、2.3−ジメチ
ルブタン、n−へブタン、イソへブタン、3−メチルヘ
キサン、2.4−ジメチルペンタン、n−オクタン、2
−メチルへブタン、3−メチルへブタン、4−メチルへ
ブタン、2.2−ジメチルヘキサン、2.5−ジメチル
ヘキサン、3.3−ジメチルヘキサン、2−メチル−3
−エチルペンタン、3−メチル−3−エチルベンクン、
2.3.3−トリメチルペンタン、2,3.4−トリメ
チルペンタン、2,2.3−トリメチルペンタン、イソ
オクタン、ノナン、2,2.5−1−ジメチルヘキサン
、デカン、ドデンカン、■−ペンテン、2−ペンテン、
1〜ヘキセン、1−オクテン、1−ノネン、1−デセン
、シクロペンタン、メチルシクロペンタン、シクロヘキ
サン、メチルシクロヘキサン。
エチルシクロヘキサン、ビシクロヘキサン、シクロヘキ
セン、α−ピネン、ジペンテン、デカリン、テトラリン
、アミジノ、アミルナフタレン等から選ばれるものであ
る。より好ましくは、n−ペンタン、n−ヘキサン、シ
クロヘキサン、n−へブタン等である。
アルコール類としては、炭素数1〜17の鎖状又は環状
の飽和又は不飽和アルコ−゛ル類が好ましく、メタノー
ル、エタノール、n−プロピルアルコール、イソプロピ
ルアルコール、n−ブチルアルコール、5ee−ブチル
アルコール、イソブチルアルコール、tert−ブチル
アルコール、ペンチルアルコール、5ec−アミルアル
コール、1−エチル−1−プロパツール、2−メチル−
1−ブタノール、イソペンチルアルコール、tert−
ペンチルアルコール、3−メチル−2−ブタノール、ネ
オペンチルアルコール、l−ヘキサノール、2−メチル
−1−ペンタノ1−ル、4−メチル−2−ペンタノール
、2−エチル−1−ブタノール、■−ヘプタツール、2
−ヘプタツール、3−ヘプタツール、1−オクタツール
、2−オクタツール、2−エチル−】−ヘキサノール、
■−ノナノール、3.5.5− )リフチル−1−ヘキ
サノール、l−デカノール、1−ウンデカノール、I−
ドデカノール、アリルアルコール、プロパルギルアルコ
ール、ベンジルアルコール、シクロヘキサノール、1−
メチルシクロヘキサノール、2−メチルシクロヘキサノ
ール、3−メチルシクロヘキサノール、4−メチルシク
ロヘキサノール、α−テルピネオール、アビニチノール
、2.6−シメチルー4−ヘプタツール、トリメチルノ
ニルアルコール、テトラデシルアルコール、ヘプタデシ
ルアルコール等から選ばれるものである。より好ましく
はメタノール、エタノール、イソプロピルアルコール等
である。
炭素数1〜9の飽和又は不飽和炭化水素基)のいずれか
の−創成で示されるものが好ましく、アセトン、メチル
エチルケトン、2−ペンタノン、3−ペンタノン、2−
ヘキサノン、メチル−〇−ブチルケトン、メチルブチル
ケトン、2−ヘプタノン、4−ヘプタノン、ジイソブチ
ルケトン、アセトニルアセトン、メシチルオキシド、ホ
ロン、メチル−〇−アミルケトン、エチルブチルケトン
、メチルへキシルケトン、シクロヘキサノン、メチルシ
クロヘキサノン、イソホロン、21.4−ベンタンジオ
ン、ジアセトンアルコール、アセトフェノン、フエンチ
ョン等から選ばれるものである。より好ましくはアセト
ン、メチルエチルケトン等である。
塩素化炭化水素類としては、炭素数1〜2の飽和又は不
飽和、塩素化炭化水素類が好ましく、塩化メチレン、四
塩化炭素、1.1−ジクロルエタン、1.2−ジクロロ
エタン、1,1.、lトリクロルエタン、1,1.2−
トリクロルエタン、l、 1.1.2−テトラクロルエ
タン、1,1,2.2−テトラクロルエタン、ペンタク
ロルエタン、1.1−ジクロルエチレン、1,2−ジク
ロルエチレン、トリクロルエチレン、テトラクロルエチ
レン等から選ばれるものである。より好ましくは塩化メ
チレン、1、 l、 !−トリクロルエタン、トリクロ
ルエチレン、テトラクロルエチレン等である。
エステル類としては、次の一般式で示されるR3
ものが好ましく 、 R,−COO−R,、R,−C−
R,−COO−R,。
諒
C0OR。
(ここでl(i、Rs、Rs、R4,Rs、RsはH又
はOH又は炭素数1〜19の飽和ないし、不飽和結合を
有する炭化水素基、)
具体的には、ギ酸メチル、ギ酸エチル、ギ酸プロピル、
ギ酸ブチル、ギ酸イソブチル、ギ酸ペンチル、酢酸メチ
ル、酢酸エチル、酢酸プロピル、酢酸イソプロピル、酢
酸ブチル、酢酸イソブチル、酢酸ff1ec−ブチル、
酢酸ペンチル、酢酸インペンチル、3−メトキシブチル
アセテート、酢酸5ec−ヘキシル、2−エチルブチル
アセテート、2−エチルヘキシルアセテート、酢酸シク
ロヘキシル、酢酸ベンジル、プロピオン酸メチル、プロ
ピオン酸エチル、プロピオン酸ブチル、プロピオン酸イ
ソペンチル、酪酸メチル、酪酸エチル、酪酸ブチル、酪
酸イソペンチル、イソ醋酸イソブチル、2−ヒドロキシ
−2−メチルプロピオン酸エチル、ステアリン酸ブチル
、ステアリン酸ペンチル、安息香酸メチル、安息香酸エ
チル、安息香酸プロピル、安息香酸ブチル、安息香酸イ
ソペンチル、安息香酸ベンジル、アビエチン酸エチル、
アビエチン酸ベンジル、アジピン酸ビス−2−エチルヘ
キシル、γ−ブチロラクト、シェラ酸ジエチル、シェラ
酸ジブチル、シュウ酸ジペンチル、マロン酸ジエチレ、
マレイン酸ジメチル、マレイン酸ジエチル、マレイン酸
ジブチル、酒石酸ジブチル、クエン酸トリブチル、セバ
シン酸ジブチル、セバシン酸ビス−2−エチルヘキシル
、フタル酸ジメチル、フタル酸ジエチル、フタル酸ジブ
チル、フタル酸ビス−2−エチルヘキシル、フタル酸ジ
オクチル等から選ばれるものある。より好ましくは酢酸
メチル、酢酸エチル等である。
本発明の脱脂洗浄剤には、各種の洗浄助剤や安定剤ある
いはオゾン破壊に対する影響の少ない水素含有塩素化フ
ッ素化炭化水素類をさらに添加混合してもよい。洗浄方
法としては、手拭き、浸漬、スプレー法、揺動、超音波
洗浄、蒸気洗浄等通常の方法を採用することができる。
[実施例J
実施例1〜18
下記第1表に示す脱脂洗浄剤を用いて切削油の洗浄試験
を行なった。
S II S −304のテストピース(25+o+o
X 30mmX 2m111厚)をスピンドル油中に浸
漬した後、脱脂洗浄剤に5分間浸漬後取り出したテスト
ピース表面のスピンドル油の残存状況を肉眼観察した。
その結果を第1表に示す。
[発明の効果]
本発明の脱脂洗浄剤は実施例から明らかなように油脂類
の洗浄効果の優れたものである。又、従来使用されてい
たR113と同様に適度な溶解力を持−)ことから1.
金属、プラスチック及びエラストマー等から成る複合部
品に悪影響を与えることなく、脱脂洗浄することができ
る。
第
表
)内は混合比[重量%]
0;良好に除去できる
△;微量残存
○;はぼ良好
×;かなり残存[Problems to be Solved by the Invention] The present invention proposes that although conventionally used R113 has various advantages, it is suspected that it destroys ozone in the stratosphere and may even cause skin cancer. Therefore, the purpose of this invention is to provide a new degreasing detergent that has various advantages similar to R1 and R13 and can perform the same cleaning. [Means for solving the problem] J The present invention aims to achieve the above-mentioned objects.
The present invention provides a degreasing detergent containing a specific chlorofluorinated hydrocarbon having 3 carbon atoms as an active ingredient. The chlorofluorinated hydrocarbons of the present invention include CF, CF, CHCQF (R226ea), CCQF
-CF-CHF* (R226eb), CC('5CF
tC)ICG! -(R222c), CCQ-FCF
*C) ICQ* (R223ea). CCQsCFsCHCQF (R223eb), CCQi
CFaCHF* (R224cc), C)ICII)l
CF, CMQ! (R232ca,), CC(
25cFtcH2CQ (R232cb), CCQ, F
CF, CM*CQ (R233eb), CH
C(2xcF x(:H(JF (R233ca), C
CQ, CFlCI(IF(R233CC), (:CG!
mcFicl1m (R242cbLC)ICQiCF
xC) One or a mixture of two or more selected from hydrogen-containing chlorofluorinated hydrocarbons such as IiCQ (R242ea) is preferred. The degreasing detergent of the present invention can contain various other components depending on various purposes. For example, to increase the dissolving power, hydrocarbons, alcohols, ketones,
At least one kind selected from organic solvents such as chlorinated hydrocarbons and esters can be contained. The content of these organic solvents in the degreasing detergent is 0 to 50% by weight, preferably 1.0 to 40% by weight, and more preferably 20 to 30% by weight. When the mixture of the chlorinated hydrocarbon and organic solvent of the present invention has an azeotropic composition, it is preferable to use the azeotropic composition. The hydrocarbons are preferably linear or cyclic saturated or unsaturated hydrocarbons having 1 to 15 carbon atoms, <, n-pentane,
Isopentane, n-hexane, isohexane, 2-methylpentane, 2.2-dimethylbutane, 2.3-dimethylbutane, n-hebutane, isohebutane, 3-methylhexane, 2.4-dimethylpentane, n- Octane, 2
-Methylhebutane, 3-methylhebutane, 4-methylhebutane, 2.2-dimethylhexane, 2.5-dimethylhexane, 3.3-dimethylhexane, 2-methyl-3
-ethylpentane, 3-methyl-3-ethylpentane,
2.3.3-trimethylpentane, 2,3.4-trimethylpentane, 2,2.3-trimethylpentane, isooctane, nonane, 2,2.5-1-dimethylhexane, decane, dodencane, ■-pentene, 2-pentene,
1-hexene, 1-octene, 1-nonene, 1-decene, cyclopentane, methylcyclopentane, cyclohexane, methylcyclohexane. It is selected from ethylcyclohexane, bicyclohexane, cyclohexene, α-pinene, dipentene, decalin, tetralin, amidino, amylnaphthalene, and the like. More preferred are n-pentane, n-hexane, cyclohexane, n-hebutane and the like. The alcohols are preferably linear or cyclic saturated or unsaturated alcohols having 1 to 17 carbon atoms, such as methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, 5ee-butyl alcohol, Isobutyl alcohol, tert-butyl alcohol, pentyl alcohol, 5ec-amyl alcohol, 1-ethyl-1-propatol, 2-methyl-
1-butanol, isopentyl alcohol, tert-
Pentyl alcohol, 3-methyl-2-butanol, neopentyl alcohol, l-hexanol, 2-methyl-1-pentanol, 4-methyl-2-pentanol, 2-ethyl-1-butanol, ■-heptyl alcohol tools, 2
-heptatool, 3-heptatool, 1-octatool, 2-octatool, 2-ethyl-]-hexanol,
■-nonanol, 3.5.5-) riftyl-1-hexanol, l-decanol, 1-undecanol, I-
Dodecanol, allyl alcohol, propargyl alcohol, benzyl alcohol, cyclohexanol, 1-
Methylcyclohexanol, 2-methylcyclohexanol, 3-methylcyclohexanol, 4-methylcyclohexanol, α-terpineol, avinitinol, 2,6-dimethyl-4-heptatool, trimethylnonyl alcohol, tetradecyl alcohol, heptadecyl alcohol etc. More preferred are methanol, ethanol, isopropyl alcohol and the like. Acetone, methyl ethyl ketone, 2-pentanone, 3-pentanone, 2-
Hexanone, methyl-〇-butylketone, methylbutylketone, 2-heptanone, 4-heptanone, diisobutylketone, acetonylacetone, mesityl oxide, holon, methyl-〇-amylketone, ethylbutylketone, methylhexylketone, cyclohexanone, methyl It is selected from cyclohexanone, isophorone, 21.4-bentanedione, diacetone alcohol, acetophenone, fencheon, and the like. More preferred are acetone, methyl ethyl ketone and the like. The chlorinated hydrocarbons are preferably saturated or unsaturated chlorinated hydrocarbons having 1 to 2 carbon atoms, such as methylene chloride, carbon tetrachloride, 1,1-dichloroethane, 1,2-dichloroethane, 1,1. , l trichloroethane, 1,1.2-
Trichloroethane, l, 1.1.2-tetrachloroethane, 1,1,2.2-tetrachloroethane, pentachloroethane, 1.1-dichloroethylene, 1,2-dichloroethylene, trichlorethylene, It is selected from tetrachlorethylene and the like. More preferably methylene chloride, 1, l, ! - trichloroethane, trichlorethylene, tetrachlorethylene, etc. The esters are preferably those represented by the following general formula: R, -COO-R,, R, -C-
R, -COO-R,. Ryo C0OR. (Here, l (i, Rs, Rs, R4, Rs, Rs are H, OH, or a hydrocarbon group having 1 to 19 carbon atoms and having a saturated or unsaturated bond.) Specifically, methyl formate, ethyl formate , propyl formate,
Butyl formate, isobutyl formate, pentyl formate, methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate, isobutyl acetate, ff1ec-butyl acetate,
Pentyl acetate, impentyl acetate, 3-methoxybutyl acetate, 5ec-hexyl acetate, 2-ethylbutyl acetate, 2-ethylhexyl acetate, cyclohexyl acetate, benzyl acetate, methyl propionate, ethyl propionate, butyl propionate, isopentyl propionate , methyl butyrate, ethyl butyrate, butyl butyrate, isopentyl butyrate, isobutyl isoacetate, ethyl 2-hydroxy-2-methylpropionate, butyl stearate, pentyl stearate, methyl benzoate, ethyl benzoate, propyl benzoate, benzoic acid Butyl, isopentyl benzoate, benzyl benzoate, ethyl abietate,
Benzyl abietate, bis-2-ethylhexyl adipate, γ-butyrolact, diethyl chelate, dibutyl chelate, dipentyl oxalate, diethyl malonate,
Dimethyl maleate, diethyl maleate, dibutyl maleate, dibutyl tartrate, tributyl citrate, dibutyl sebacate, bis-2-ethylhexyl sebacate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, bis-2-ethylhexyl phthalate , dioctyl phthalate, etc. More preferred are methyl acetate, ethyl acetate and the like. The degreasing detergent of the present invention may further be mixed with various cleaning aids, stabilizers, or hydrogen-containing chlorinated fluorinated hydrocarbons that have little effect on ozone destruction. As a cleaning method, conventional methods such as hand wiping, dipping, spraying, shaking, ultrasonic cleaning, and steam cleaning can be used. [Example J Examples 1 to 18 A cutting oil cleaning test was conducted using the degreasing detergent shown in Table 1 below. S II S-304 test piece (25+o+o
After immersing a test piece (30 mm x 2 m 111 thick) in spindle oil, the test piece was immersed in a degreasing detergent for 5 minutes and then taken out, and the residual state of spindle oil on the surface of the test piece was visually observed. The results are shown in Table 1. [Effects of the Invention] As is clear from the Examples, the degreasing detergent of the present invention has an excellent cleaning effect on oils and fats. In addition, like the conventionally used R113, it has a moderate dissolving power.
Composite parts made of metal, plastic, elastomer, etc. can be degreased and cleaned without adversely affecting them. Figures in Table 1) indicate the mixing ratio [wt%] 0; Good removal △; Trace amount remaining ○; Very good ×; Significant residual
Claims (2)
_2CHF_2、CCl_3CF_2CHCl_2、C
Cl_2FCF_2CHCl_2、CCl_3CF_2
CHClF、CCl_3CF_3CHF_2、CHCl
_2CF_2CHCl_2、CCl_3CF_3CH_
2Cl、CCl_3FCF_3CH_2Cl、CHCl
_2CF_2CHClF、CCl_3CF_2CH_2
F、CCl_3CF_2CH_3、CHCl_2CF_
2CH_2Clの群から選ばれる少なくとも1種を有効
成分として含有する脱脂洗浄 剤。(1) CF_3CF_2CHClF, CClF_2CF
_2CHF_2, CCl_3CF_2CHCl_2, C
Cl_2FCF_2CHCl_2, CCl_3CF_2
CHClF, CCl_3CF_3CHF_2, CHCl
_2CF_2CHCl_2, CCl_3CF_3CH_
2Cl, CCl_3FCF_3CH_2Cl, CHCl
_2CF_2CHClF, CCl_3CF_2CH_2
F, CCl_3CF_2CH_3, CHCl_2CF_
A degreasing detergent containing at least one member selected from the group 2CH_2Cl as an active ingredient.
ケトン類、塩素化炭化水素類又はエステル類から選ばれ
る少なくとも1種が含まれている請求項1記載の脱脂洗
浄剤。(2) Degreasing detergents contain hydrocarbons, alcohols,
The degreasing detergent according to claim 1, containing at least one selected from ketones, chlorinated hydrocarbons, and esters.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1982589A JPH02200789A (en) | 1989-01-31 | 1989-01-31 | Dewaxing detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1982589A JPH02200789A (en) | 1989-01-31 | 1989-01-31 | Dewaxing detergent |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02200789A true JPH02200789A (en) | 1990-08-09 |
Family
ID=12010079
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1982589A Pending JPH02200789A (en) | 1989-01-31 | 1989-01-31 | Dewaxing detergent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02200789A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05185045A (en) * | 1992-01-16 | 1993-07-27 | Nissan Motor Co Ltd | Composition for removing deposit attached to inside of coated pipe and method therefor |
US8021490B2 (en) | 2007-01-04 | 2011-09-20 | Eastman Chemical Company | Substrate cleaning processes through the use of solvents and systems |
-
1989
- 1989-01-31 JP JP1982589A patent/JPH02200789A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05185045A (en) * | 1992-01-16 | 1993-07-27 | Nissan Motor Co Ltd | Composition for removing deposit attached to inside of coated pipe and method therefor |
US8021490B2 (en) | 2007-01-04 | 2011-09-20 | Eastman Chemical Company | Substrate cleaning processes through the use of solvents and systems |
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