JPH02155963A - Marking ink composition for jet printer - Google Patents
Marking ink composition for jet printerInfo
- Publication number
- JPH02155963A JPH02155963A JP63309692A JP30969288A JPH02155963A JP H02155963 A JPH02155963 A JP H02155963A JP 63309692 A JP63309692 A JP 63309692A JP 30969288 A JP30969288 A JP 30969288A JP H02155963 A JPH02155963 A JP H02155963A
- Authority
- JP
- Japan
- Prior art keywords
- ink composition
- rosin
- resin
- marking ink
- maleic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 64
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 36
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 150000002688 maleic acid derivatives Chemical class 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- KSCKTBJJRVPGKM-UHFFFAOYSA-N octan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-].CCCCCCCC[O-] KSCKTBJJRVPGKM-UHFFFAOYSA-N 0.000 claims description 4
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 11
- 238000007639 printing Methods 0.000 abstract description 5
- 239000003599 detergent Substances 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 238000005299 abrasion Methods 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000000975 dye Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- -1 aqueous ammonia Chemical class 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 229920001800 Shellac Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 2
- 239000004208 shellac Substances 0.000 description 2
- 229940113147 shellac Drugs 0.000 description 2
- 235000013874 shellac Nutrition 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GJUABKCEXOMRPQ-UHFFFAOYSA-N 1-[(2,5-dimethoxyphenyl)diazenyl]naphthalen-2-ol Chemical compound COC1=CC=C(OC)C(N=NC=2C3=CC=CC=C3C=CC=2O)=C1 GJUABKCEXOMRPQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 101100201890 Caenorhabditis elegans rad-8 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- CYZWPZHRSZNWLS-UHFFFAOYSA-N chembl1994043 Chemical compound C1=CC=C2C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=CC2=C1 CYZWPZHRSZNWLS-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940101763 solvent red 4 Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、様々な被記録材上に印刷可能で、耐候性、耐
摩耗性、噴射安定性に優れたジェットプリンター用マー
キングインキ組成物に関する。Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a marking ink composition for jet printers that can be printed on various recording materials and has excellent weather resistance, abrasion resistance, and jetting stability. .
特開昭５３−１２３２１０号公報には、広範囲の基体上
に用いることを目的とした樹脂、着色剤、電解質及び溶
剤からなるインキ組成物が提案されており、その中で樹
脂としてロジン変性マレイン酸樹脂を含有するインキ組
成物が記載されている。JP-A-53-123210 proposes an ink composition consisting of a resin, a colorant, an electrolyte, and a solvent, which is intended to be used on a wide range of substrates, and includes rosin-modified maleic acid as the resin. Ink compositions containing resins are described.
特開昭５６−３６５５９号公報には、抗褪色性、耐摩耗
性及び耐光性の優れたインキ組成物として、エポキシ・
フェノール系バインダー樹脂、溶剤及び染料を含有する
インキ組成物が提案されている。JP-A No. 56-36559 describes epoxy as an ink composition with excellent anti-fading properties, abrasion resistance and light resistance.
Ink compositions containing a phenolic binder resin, a solvent, and a dye have been proposed.
特開昭５６−４９７７２号公報には、ポリオレフィン類
又はそれらの共重合体の滑らかな表面上に印刷すること
を目的とした、スチレン−アクリル系共重合体樹脂、可
塑剤、染料、蒸発遅延剤、水及びアルコールを含有する
インキ組成物が提案されている。特開昭５６−１６４１
８０号公報には、対象被記録体の材質の如何によらず使
用できるインキを提供することを目的とする、ケトン、
アルコール及び水を主成分とする溶剤、染料、イオン化
性塩類、界面活性剤及び樹脂を含むインクジェット記録
用インクにおいて界面活性剤が非イオン性界面活性剤で
あることを特徴とするインク組成物が提案されている。JP-A-56-49772 discloses a styrene-acrylic copolymer resin, a plasticizer, a dye, and an evaporation retardant intended for printing on the smooth surface of polyolefins or their copolymers. Ink compositions containing water and alcohol have been proposed. Japanese Patent Publication No. 56-1641
Publication No. 80 discloses ketone,
An ink composition is proposed in which the surfactant is a nonionic surfactant in an inkjet recording ink containing a solvent mainly composed of alcohol and water, a dye, an ionizable salt, a surfactant, and a resin. has been done.
しかしながら、特開昭５３−１２３２１０号公報及及特
開昭Ｓ６−１６１４８０号公報に記載のインキ組成物で
は、インキ組成物中に電解質（イオン化性塩類）を含む
ため、インキ皮膜強度が弱くなる傾向にあった。また、
上述の各糧技術では、プルカリ性の洗浄液で被記録材上
のインキ皮膜を速やかに溶解・洗浄可能なマーキングイ
ンキ組成物については何ら検討が為されていなかった。However, in the ink compositions described in JP-A-53-123210 and JP-A-S6-161480, the ink film strength tends to be weak because the ink composition contains an electrolyte (ionizable salts). It was there. Also,
In each of the above-mentioned technologies, no study has been made on a marking ink composition that can quickly dissolve and wash an ink film on a recording material with a purkari-based cleaning liquid.
一方で様々な被記録材上に印刷可能で、耐候性、耐摩耗
性、噴射安定性に優れ、更にアルカリ性の洗浄剤によ勺
、容易に溶解、洗浄可能なジェットプリンター用マーキ
ングインキ組成物が求められている。On the other hand, there is a marking ink composition for jet printers that can be printed on various recording materials, has excellent weather resistance, abrasion resistance, and jetting stability, and can be easily dissolved and cleaned by alkaline cleaning agents. It has been demanded.
本発明が解決しようとする課題は、様々な被記録材上に
印刷可能であシ、ジェットプリンターの噴射安定性に優
れ、耐候性、耐摩耗性に優れ、かつ、印刷後にアルカリ
性の洗浄剤によシ容易に溶解、洗浄可能な印刷画像を形
成し得るジェットプリンター用マーキングインキ組成物
を提供することにある。The problems to be solved by the present invention are to be able to print on various recording materials, to have excellent jet printer jetting stability, to have excellent weather resistance and abrasion resistance, and to be compatible with alkaline cleaning agents after printing. It is an object of the present invention to provide a marking ink composition for jet printers that can form printed images that are easily soluble and washable.
本発明は上記課題を解決するために、油溶性含金属染料
、樹脂、有機溶剤を含有するジェットグリンター用イン
キ組成物において、樹脂として、酸価が３０〜３００の
範囲にあるロジン変性マレイン酸樹脂を使用したジェッ
トプリンター用マーキングインキ組成物（以下、本発明
のインク組成物という。）を提供する。In order to solve the above problems, the present invention provides an ink composition for jet glitters containing an oil-soluble metal-containing dye, a resin, and an organic solvent, in which the resin is rosin-modified maleic acid having an acid value in the range of 30 to 300. A marking ink composition for jet printers (hereinafter referred to as the ink composition of the present invention) using a resin is provided.
本発明者らは、様々な被記録材上に印刷可能で。The present inventors can print on various recording materials.
耐候性、耐摩耗性、噴射安定性に優れ、更に印刷後にア
ルカリ性の洗浄剤により、容易に溶解、洗浄可能なイン
キ組成物について鋭意検討を行なった。We conducted extensive research on an ink composition that has excellent weather resistance, abrasion resistance, and jetting stability, and that can be easily dissolved and washed with an alkaline detergent after printing.
その結果、染料として油溶性の含金属染料、酸価が３０
〜３００のロジン変性マレイン酸樹脂を組み合わせる事
例より、電解質（イオン化性塩類）を加えることなく、
適度な電気伝導度（電気伝導度はコンティニュアス方式
と呼ばれるインクソエクト方弐において、噴射をコント
ロールする上で非常に重要な特性の一つである。〕を付
与することＫよシ安定し九噴射が可能となシ、様々な被
記録材に対して優れた接着性を示し、かつ耐候性に優れ
たインキ皮膜を与えることが判明した。更にアルカリ性
の洗浄剤、具体的には１％ＮａＯＨ水溶液等で容易にイ
ンキ皮膜を洗浄・溶解することが可能となった。As a result, an oil-soluble metal-containing dye with an acid value of 30
From an example of combining ~300 rosin-modified maleic acid resin, without adding electrolytes (ionizable salts),
Providing appropriate electrical conductivity (electrical conductivity is one of the very important characteristics for controlling injection in the continuous method of ink jetting) will result in more stable injection. It has been found that it is possible to provide an ink film that exhibits excellent adhesion to various recording materials and has excellent weather resistance.Furthermore, alkaline cleaning agents, specifically 1% NaOH aqueous solution It has become possible to easily wash and dissolve the ink film with etc.
本発明で使用する油溶性合金属染料としては。The oil-soluble metal alloy dye used in the present invention includes:
インキ組成物に可溶性のものであれば使用可能であシ、
例えば、
Ｃ，１，５ｏｌｖｅｎｔ Ｂｌａｃｋ ２２，２３，
２７，２９．３４＋４Ｌ４７．１２３Ｃ０１，５ｏｌｖ
ｅｎｔ Ｙｅｌｌｏｗ １９，２１．３２＋６＋、８０
．７９，８ｔ、８２Ｃ，１，５ｏｌｖ＠ｎｔ Ｒａｄ
８．ａ５．８３．８４，１００，１０９，１１８，
１１９゜１２１．１２２．１６０
Ｃ，１，５ｏｌｖａｎｔ Ｂｌｕｅ ２５ｓ５５
ｅ７０等が挙げられる。It can be used as long as it is soluble in the ink composition.
For example, C, 1, 5olvent Black 22, 23,
27,29.34+4L47.123C01,5olv
ent Yellow 19,21.32+6+,80
．． 79,8t, 82C,1,5olv@nt Rad
8. a5.83.84, 100, 109, 118,
119゜121.122.160 C, 1,5olvant Blue 25s55
Examples include e70.
これらの油溶性含金属染料のインキ組成物中の含有量は
、０．１〜１５重量％の範囲が好ましい。The content of these oil-soluble metal-containing dyes in the ink composition is preferably in the range of 0.1 to 15% by weight.
ロジン変性マレイン酸樹脂は、ロジンと無水マレイン酸
を含有する樹脂構成材料を開放がま又はオートクレーブ
中で、強酸又は過酸化物を触媒として、１６０〜２５０
℃に加熱することによって得られる。The rosin-modified maleic acid resin is prepared by heating resin constituent materials containing rosin and maleic anhydride in an open kettle or autoclave using a strong acid or peroxide as a catalyst.
Obtained by heating to ℃.
本発明で使用するロジン変性マレイン酸樹脂としては、
酸価が３０〜３００の範囲にあるものを使用する。The rosin-modified maleic acid resin used in the present invention includes:
Use one with an acid value in the range of 30 to 300.
酸化が３０より低い場合には、インキ乾燥皮膜の強度が
強くなるが、インキ乾燥皮膜をアルカリ性の洗浄剤によ
って溶解、洗浄されにくくなる傾向にあるので好ましく
ない、酸価が３００よシ高い場合には、インキ乾燥皮膜
は、アルカリ性の洗浄剤によって容易に溶解、洗浄され
るが、インキ乾燥皮膜が脆くなる傾向忙あるので好まし
くない。If the oxidation value is lower than 30, the strength of the dry ink film will be strong, but the dry ink film will tend to be difficult to dissolve and wash with alkaline detergents, which is undesirable.If the acid value is higher than 300, Although the ink dry film is easily dissolved and washed by an alkaline detergent, the dry ink film tends to become brittle, which is not preferable.
ロジン変性マレイン酸樹脂のインキ組成物中の含有量は
、５〜５０重量％の範囲が好ましい。The content of the rosin-modified maleic acid resin in the ink composition is preferably in the range of 5 to 50% by weight.
本発明のインキ組成物中に、必要に応じて、エポキシ系
・フェノール系・アクリル系・シェラツクのような天然
樹脂等、ロジン変性マレイン酸樹脂と相溶性のある溶剤
可溶性樹脂を併用することも可能である。この場合、ア
ルカリ洗浄性を維持するためには、併用する樹脂として
は、アルカリ可溶性樹脂が好ましい。In the ink composition of the present invention, solvent-soluble resins that are compatible with the rosin-modified maleic acid resin, such as epoxy, phenol, acrylic, and natural resins such as shellac, may be used in combination, if necessary. It is. In this case, in order to maintain alkaline washability, the resin used in combination is preferably an alkali-soluble resin.
本発明で使用する有機溶剤としては、メチルエチルケト
ン、メタノール又はエタノールを含有する溶剤が、染料
溶解性、インキ組成物の電気伝導度、インキ乾燥特性等
の面から好ましい０本発明で使用する有機溶剤に、樹脂
又は染料の溶解性、並びにインキ乾燥特性を改善するた
めに１例えば、水。As the organic solvent used in the present invention, a solvent containing methyl ethyl ketone, methanol or ethanol is preferable in terms of dye solubility, electrical conductivity of the ink composition, ink drying characteristics, etc. 1, e.g., water to improve the solubility of the resin or dye, as well as the ink drying properties.
アンモニア水、フロ／ＩＰノールの如キ他のアルコール
類；ジメチルケトン、ソエチルケトンの如き他のケトン
類；グリコール及びグリコールエーテル・エステル類；
炭化水素類ニアミド類；アミノアルコール類；モルホリ
ン、ピリジンの如き含窒素化合物等の有機溶剤全併用し
てもよい。仁の場合、インキ乾燥皮膜をアルカリ性の洗
浄剤によって効果的に洗浄するために、これらの溶剤は
、インキ組成物と被記録材とが相溶しないような組み合
わせが好ましい。Other alcohols such as aqueous ammonia, Furo/IP Nor; other ketones such as dimethyl ketone, soethyl ketone; glycols and glycol ether esters;
Organic solvents such as hydrocarbon niamides; amino alcohols; and nitrogen-containing compounds such as morpholine and pyridine may all be used in combination. In the case of ink, in order to effectively clean the dried ink film with an alkaline cleaning agent, these solvents are preferably combined in such a way that the ink composition and the recording material are not compatible with each other.
インキ乾燥皮膜が脆くなる傾向を防ぎ、インキ乾燥皮膜
の耐摩耗性を高めるために、本発明のインク組成物に、
オレイン酸プミド、セバシン酸ジエチル又はフッ素系界
面活性剤を添加することがよシ好ましい。これらの添加
量は０．Ｏ１〜５！ｔ％の範囲が好ましい。但し、フッ
素系界面活性剤を用いるとインキの泡立ちが噴射特性に
悪影響を及ぼす場合があり、この場合には、消泡剤を併
用する必要がある。消泡剤としては、消泡効果、インキ
の安定性、噴射安定性の点から最適なものを選択する必
要があシ、具体的にはシリコン系の消泡剤が有効である
。In order to prevent the tendency of the dry ink film to become brittle and increase the abrasion resistance of the dry ink film, the ink composition of the present invention includes:
It is more preferable to add oleic acid pumide, diethyl sebacate or a fluorine surfactant. The amount of these additions is 0. O1~5! A range of t% is preferred. However, if a fluorine-based surfactant is used, the foaming of the ink may adversely affect the jetting characteristics, and in this case, it is necessary to use an antifoaming agent in combination. As the antifoaming agent, it is necessary to select the most suitable antifoaming agent in terms of antifoaming effect, ink stability, and jetting stability. Specifically, silicone-based antifoaming agents are effective.
以下、実施例及び比較例により本発明を更に詳しく説明
する。なお、製造例、実施例及び比較例における「％」
及び「部」は、各々「重量％」及び「重量部」を表わす
。耐摩耗性は、得られた印刷画像に「セロテープ」にチ
バン（世製七ｑファン粘着テープ）を貼シ１次いで「セ
ロテープ」を剥離することによる印刷画像の定着性、及
び印刷画像を爪による引っ掻きテストによシ判断した。Hereinafter, the present invention will be explained in more detail with reference to Examples and Comparative Examples. In addition, "%" in production examples, examples, and comparative examples
and "parts" represent "% by weight" and "parts by weight", respectively. Abrasion resistance is determined by the fixation of the printed image by pasting Chiban (Seisei Seven Q Fan Adhesive Tape) on "Cellotape" and then peeling off the "Cellotape", and by peeling off the "Cellotape", and by applying the printed image to the printed image by applying it with a fingernail. This was determined by a scratch test.
合成例１〜８
第１表に示した各組成の化合物を室温で混合した後、徐
々に温度を上げ、２４０℃で５時間反応させて、第１表
に示した酸価を有するロジン変性マレイン酸樹脂を各々
得た。Synthesis Examples 1 to 8 After mixing the compounds of each composition shown in Table 1 at room temperature, the temperature was gradually raised and the reaction was carried out at 240°C for 5 hours to produce rosin-modified malein having the acid value shown in Table 1. Each acid resin was obtained.
実施例１
Ｃ，Ｌソルベント ブラック２９
５部製造例１のロジン変性マレイン酸樹脂 ３０
部メチルエチルケトン ４３部メチル
アルコール ２０部上記配合を十分
に攪拌、＃解した後、この溶液を１．２ミクロンのメン
ブランフィルタ−を用いて濾過することによってインキ
組成物を得た。Example 1 C, L Solvent Black 29
5 parts Rosin-modified maleic acid resin of Production Example 1 30
Parts Methyl ethyl ketone 43 parts Methyl alcohol 20 parts The above formulation was thoroughly stirred and dissolved, and the solution was filtered using a 1.2 micron membrane filter to obtain an ink composition.
このインキ組成物を用い、コンティニュアス・インクジ
ェットプリンターを用いてステンレス板上に印刷を行な
った結果、噴射安定性に優れていた。得られた印刷画ｇ
ＲＶｉ耐候性、耐摩耗性に優れていた。次に、得られた
印刷画像ｔ−１％水酸化ナトリウム水溶液を用いて洗浄
したところ、１分間の洗浄で印刷画像を容易に洗い流す
ことができた。When this ink composition was printed on a stainless steel plate using a continuous inkjet printer, it was found to have excellent jetting stability. Obtained print image
RVi weather resistance and abrasion resistance were excellent. Next, when the obtained printed image was washed using t-1% aqueous sodium hydroxide solution, the printed image could be easily washed away by washing for 1 minute.
実施例２
Ｃ，１，ソルベント ブラック ２９ ５
部製造例１のロジン変性マレイン酸樹脂 ３０部
オレイン酸アミド ２部メチルエ
チルケトン ４３部メチルアルコール
２０部上記配合を用いて、実施
例１と同様にしてインキ組成物を得た。Example 2 C, 1, Solvent Black 29 5
Part Rosin-modified maleic acid resin of Production Example 1 30 parts Oleic acid amide 2 parts Methyl ethyl ketone 43 parts Methyl alcohol 20 parts An ink composition was obtained in the same manner as in Example 1 using the above formulation.
このインキ組成物を用い、コンティニュアス・インクジ
ェットプリンターを用いてステンレス板上に印刷を行な
った結果、噴射安定性に優れていた。得られた印刷画像
は耐候性、耐摩耗性に優れていた。次Ｋ、得られた印刷
画像を１％水酸化ナトリウム水溶液を用いて洗浄したと
ころ、１分間の洗浄で印刷画像を容易に洗い流すことが
できた。When this ink composition was printed on a stainless steel plate using a continuous inkjet printer, it was found to have excellent jetting stability. The obtained printed image had excellent weather resistance and abrasion resistance. Next, when the obtained printed image was washed with a 1% aqueous sodium hydroxide solution, the printed image could be easily washed away after washing for 1 minute.
実施例３
Ｃ０！、ソルベント ブラック４３ １００
部製造２のロジン変性マレイン酸樹脂 ２５部セ
バシン酸ジエチル ２部メチルエチ
ルケトン ５５部エチルアルコール
８部上記配合を用いて、実施例１
と同様にしてインキ組成物を得た。Example 3 C0! , Solvent Black 43 100
Part rosin-modified maleic acid resin of Production 2 25 parts Diethyl sebacate 2 parts Methyl ethyl ketone 55 parts Ethyl alcohol
Example 1 Using the above formulation: 8 parts
An ink composition was obtained in the same manner as above.
このインキ組成物を用い、コンティニュアス・インクジ
ェットプリンターを用いてガラス板上に印刷を行なった
結果、噴射安定性に優れていえ。When this ink composition was used to print on a glass plate using a continuous inkjet printer, it showed excellent jetting stability.
得られた印刷画像は耐候性、耐摩耗性に優れていた。次
Ｋ、得られ現印刷画像を１％水酸化す）ＩＪウム水溶液
を用いて洗浄したところ、１分間の洗浄で印刷画像を容
易に洗い流すことができた。The obtained printed image had excellent weather resistance and abrasion resistance. Next, when the resulting printed image was washed with a 1% hydroxide (IJ) aqueous solution, the printed image could be easily washed away in 1 minute of washing.
実施例４
Ｃ，１，ソルベント ブラック ２７ ５
部製造例３０ロソン変性マレイン酸樹脂 １ｏ部
オレイン酸アミド １，５部セバ
シン酸ジエチル ０．５部メチルエチ
ルケトン ７８部上記配合を用いて、
実施例１と同様にしてインキ組成物を得た。Example 4 C, 1, Solvent Black 27 5
Part Production Example 30 Roson modified maleic acid resin 10 parts Oleic acid amide 1.5 parts Diethyl sebacate 0.5 parts Methyl ethyl ketone 78 parts Using the above formulation,
An ink composition was obtained in the same manner as in Example 1.
このインキ組成物を用い、コンティニュアス・インクジ
ェットプリンターを用いて鉄板上に印刷を行なった結果
、噴射安定性に優れていた。得られた印刷画像は耐候性
、耐摩耗性に優れていた。When this ink composition was used to print on a steel plate using a continuous inkjet printer, it was found to have excellent jetting stability. The obtained printed image had excellent weather resistance and abrasion resistance.
次に、得られた印刷画像を１％水酸化ナトリウム水溶液
を用いて洗浄したところ、１分間の洗浄で印刷画像を容
易に洗い流すことができた。Next, when the obtained printed image was washed using a 1% aqueous sodium hydroxide solution, the printed image could be easily washed away by washing for 1 minute.
実施例５
Ｃ１１，ソルベント ！ラック２９ ５部
製造例４のロジン変性マレイン酸樹脂 ４０部メ
チルエチルケトン １０部エチルアル
コール ４４．４部上記配合を用い
て、実施例１と同様にしてインキ組成物を得た。Example 5 C11, Solvent! Lac 29 5 parts Rosin-modified maleic acid resin of Production Example 4 40 parts Methyl ethyl ketone 10 parts Ethyl alcohol 44.4 parts An ink composition was obtained in the same manner as in Example 1 using the above formulation.
このインキ組成物を用い、オンデマンド・インクジェッ
トプリンターを用いてステンレス板上に印刷を行なった
結果、噴射安定性に優れていた。When this ink composition was used to print on a stainless steel plate using an on-demand inkjet printer, it was found to have excellent jetting stability.
得られた印刷画像は耐候性、耐摩耗性に優れていた。次
Ｋ、得られた印刷画像を１％水酸化ナトリウム水溶液を
用いて洗浄したところ、１分間の洗浄で印刷画像を容易
に洗い流すことができた。The obtained printed image had excellent weather resistance and abrasion resistance. Next, when the obtained printed image was washed with a 1% aqueous sodium hydroxide solution, the printed image could be easily washed away after washing for 1 minute.
実施例６
Ｃ，１，ソルベント レッド８０ ３
部製造例５のロジン変性マレイン酸樹脂 ５部
シェラツク（酸価７２） １５部オレイ
ン酸アミド ２部メチルエチルケ
トン ２５部エチルアルコール
５０部上記配合を用いて、実施例１と同
様にしてインキ組成物を得た。Example 6 C, 1, Solvent Red 80 3
Part rosin-modified maleic acid resin of Production Example 5 5 parts Shellac (acid value 72) 15 parts Oleic acid amide 2 parts Methyl ethyl ketone 25 parts Ethyl alcohol
An ink composition was obtained in the same manner as in Example 1 using 50 parts of the above formulation.
このインキ組成物を用い、コンティニュアス・インクジ
ェットプリンターを用いてプリエチレンフィルム上に印
刷を行なった結果、噴射安定性に優れていた。得られた
印刷画像は耐候性、耐摩耗性に優れていた。次に、得ら
れた印刷画像１ｋ１％水酸化ナトリウム水溶液を用いて
洗浄したところ、１分間の洗浄で印刷画像を容易に洗い
流すことができた。When this ink composition was printed on a polyethylene film using a continuous inkjet printer, it was found to have excellent jetting stability. The obtained printed image had excellent weather resistance and abrasion resistance. Next, when the obtained printed image 1K was washed using a 1% aqueous sodium hydroxide solution, the printed image could be easily washed away by washing for 1 minute.
実施例７
Ｃ，１，ソルベント プルーフ０ ５部
製造例６０ロジン変性マレイン酸樹脂 １５部「
メガ７アツクＦ−１８３Ｊ Ｏ，５
部「アンチフオームＦＳ−９０Ｊ Ｑ
、１部１〜メトキシ−２−プロノ譬ノール
ｌ０ＩＢメチルエチルケトン ２０部
エチルアルコール ４９．４部上記配
合を用いて、実施例１と同様にしてインキ組成物を得た
。Example 7 C,1, Solvent Proof 0 5 parts Production Example 60 Rosin modified maleic acid resin 15 parts
Mega 7 Atsuku F-183J O,5
Department “Antiform FS-90J Q
, 1 part 1 ~ methoxy-2-pronomonol
10IB Methyl ethyl ketone 20 parts Ethyl alcohol 49.4 parts An ink composition was obtained in the same manner as in Example 1 using the above formulation.
このインキ組成物を用い、オンデマンド・インクジェッ
トプリンターを用いてステンレス板上に印刷を行なった
結果、噴射安定性に優れていた。When this ink composition was used to print on a stainless steel plate using an on-demand inkjet printer, it was found to have excellent jetting stability.
得られた印刷画像は耐候性、耐摩耗性に優れていた。次
に、得られた印刷画像を１％水酸化ナトリウム水溶液を
用いて洗浄したところ、１分間の洗浄で印刷画像を容易
に洗い流すことができた。The obtained printed image had excellent weather resistance and abrasion resistance. Next, when the obtained printed image was washed using a 1% aqueous sodium hydroxide solution, the printed image could be easily washed away by washing for 1 minute.
比較例１
実施例３において、製造例２のロジン変性マレイン酸樹
脂に代えて、製造例７のロジン変性マレイン酸樹脂を用
いた以外は、実施例３と同様にしてインキ組成物を得九
。Comparative Example 1 An ink composition was obtained in the same manner as in Example 3, except that the rosin-modified maleic acid resin of Production Example 7 was used in place of the rosin-modified maleic resin of Production Example 2.
実施例３と同様の評価方法に従って、このインキ組成物
の評価を行なったところ、実施例３のインキ組成物と比
較して印刷画像の耐摩耗性に劣っていた。When this ink composition was evaluated according to the same evaluation method as in Example 3, it was found that the abrasion resistance of the printed image was inferior to that of the ink composition of Example 3.
比較例２
実施例４において、製造例３０ロジン変性マレイン酸樹
脂に代えて、製造例８のロジン変性マレイン酸樹脂を用
いた以外は、実施例４と同様にしてインキ組成物を得た
。Comparative Example 2 An ink composition was obtained in the same manner as in Example 4, except that the rosin-modified maleic acid resin of Production Example 8 was used in place of the rosin-modified maleic acid resin of Production Example 30.
実施例４と同様の評使方法に従って、このインキ組成物
の評価を行なったところ、印刷画像は。When this ink composition was evaluated according to the same evaluation method as in Example 4, the printed images were as follows.
１％水酸化ナトリウム水溶液を用いた１分間の洗浄で洗
い流すことができなかった。It could not be washed away by washing with a 1% aqueous sodium hydroxide solution for 1 minute.
比較例３
実施例６において、Ｃ，１，ソルベント レツＰ８０に
代えて、ローダミン系のＣ，１，ソルベントレッド ４
３を用いた以外は、実施例６と同様にしてインキ組成物
を得た。Comparative Example 3 In Example 6, rhodamine-based C,1, Solvent Red 4 was used instead of C,1, Solvent Red P80.
An ink composition was obtained in the same manner as in Example 6 except that No. 3 was used.
実施例６と同様の評価方法に従って、このインキ組成物
の評価を行なったところ、実施例６のインキ組成物と比
較して印刷画像の鮮明性及び耐候性に著しく劣っていた
。When this ink composition was evaluated according to the same evaluation method as in Example 6, it was found to be significantly inferior to the ink composition of Example 6 in the sharpness of the printed image and the weather resistance.
比較例４
実施例７において、［アンチフオーム ＦＳ−９０Ｊを
使用しなかった以外は、実施例７と同様にしてインキ組
成物を得た。Comparative Example 4 An ink composition was obtained in the same manner as in Example 7, except that Antiform FS-90J was not used.
実施例７と同様の評価方法に従って、このインキ組成物
の評価を行なったところ、噴射安定性に著しく劣ってい
た〇
〔発明の効果〕
本発明のジェットプリンター用マーキンクインキ組成物
を用いると、ノエクトプリンターの噴射安定性に優れ、
耐候性、耐摩耗性に優れ、かつ、アルカリ性の洗浄列に
より溶解、洗浄可能な印刷画像を様々な被記録材上に形
成することができる。When this ink composition was evaluated according to the same evaluation method as in Example 7, it was found that the jetting stability was significantly inferior. [Effects of the Invention] When the marking ink composition for jet printers of the present invention was used, Ecto printer has excellent jetting stability,
It is possible to form printed images on various recording materials that have excellent weather resistance and abrasion resistance, and can be dissolved and washed by an alkaline washing train.
代理人 弁理士 高 橋 勝 利Agent: Patent Attorney Katsutoshi Takahashi
Claims (1)
ットプリンター用インキ組成物において、樹脂として、
酸価が３０〜３００の範囲にあるロジン変性マレイン酸
樹脂を使用することを特徴とするジェットプリンター用
マーキングインキ組成物。 ２、ロジン変性マレイン酸樹脂の含有量が５〜５０重量
％の範囲にあることを特徴とする請求項１記載のジェッ
トプリンター用マーキングインキ組成物。 ３、含金属染料の含有量が０．１〜１５重量％の範囲に
あることを特徴とする請求項１記載のジェットプリンタ
ー用インキ組成物。 ４、有機溶剤がメチルエチルケトン、メタノール又はエ
タノールを含有する請求項１記載のジェットプリンター
用マーキングインキ組成物。 ５、オレイン酸アミド及び／又は、セバシン酸ジエチル
を０．０１〜５重量％含有することを特徴とする請求項
１記載のジェットプリンター用マーキングインキ組成物
。 ６、フッ素系界面活性剤を０．１〜５重量％含有するこ
とを特徴とする請求項１記載のジェットプリンター用マ
ーキングインキ組成物。[Scope of Claims] 1. In an ink composition for jet printers containing an oil-soluble metal-containing dye, a resin, and an organic solvent, as the resin,
A marking ink composition for jet printers, characterized in that a rosin-modified maleic acid resin having an acid value in the range of 30 to 300 is used. 2. The marking ink composition for jet printers according to claim 1, wherein the content of the rosin-modified maleic acid resin is in the range of 5 to 50% by weight. 3. The ink composition for jet printers according to claim 1, wherein the content of the metal-containing dye is in the range of 0.1 to 15% by weight. 4. The marking ink composition for jet printers according to claim 1, wherein the organic solvent contains methyl ethyl ketone, methanol or ethanol. 5. The marking ink composition for jet printers according to claim 1, containing 0.01 to 5% by weight of oleic acid amide and/or diethyl sebacate. 6. The marking ink composition for jet printers according to claim 1, which contains 0.1 to 5% by weight of a fluorine-based surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309692A JPH02155963A (en) | 1988-12-08 | 1988-12-08 | Marking ink composition for jet printer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63309692A JPH02155963A (en) | 1988-12-08 | 1988-12-08 | Marking ink composition for jet printer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02155963A true JPH02155963A (en) | 1990-06-15 |
Family
ID=17996134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63309692A Pending JPH02155963A (en) | 1988-12-08 | 1988-12-08 | Marking ink composition for jet printer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02155963A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014047235A (en) * | 2012-08-29 | 2014-03-17 | Fujifilm Corp | Inkjet ink composition and method for producing the same, inkjet recording method, and pigment dispersion and method for producing the same |
| JP2020516736A (en) * | 2017-04-14 | 2020-06-11 | ヴィデオジェット テクノロジーズ インコーポレイテッド | Quick-dry ink composition for continuous inkjet coating |
-
1988
- 1988-12-08 JP JP63309692A patent/JPH02155963A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014047235A (en) * | 2012-08-29 | 2014-03-17 | Fujifilm Corp | Inkjet ink composition and method for producing the same, inkjet recording method, and pigment dispersion and method for producing the same |
| US9080071B2 (en) | 2012-08-29 | 2015-07-14 | Fujifilm Corporation | Inkjet ink composition and method for producing the same, inkjet recording method, pigment dispersion for inkjet ink and method for producing the same |
| JP2020516736A (en) * | 2017-04-14 | 2020-06-11 | ヴィデオジェット テクノロジーズ インコーポレイテッド | Quick-dry ink composition for continuous inkjet coating |
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