JPH02142721A - Preparation of solid bathing agent - Google Patents
Preparation of solid bathing agentInfo
- Publication number
- JPH02142721A JPH02142721A JP29561688A JP29561688A JPH02142721A JP H02142721 A JPH02142721 A JP H02142721A JP 29561688 A JP29561688 A JP 29561688A JP 29561688 A JP29561688 A JP 29561688A JP H02142721 A JPH02142721 A JP H02142721A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- polyethylene glycol
- mold
- melted
- bathing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007787 solid Substances 0.000 title abstract description 11
- 238000003287 bathing Methods 0.000 title abstract description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000013040 bath agent Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 7
- 238000002347 injection Methods 0.000 abstract description 4
- 239000007924 injection Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000011782 vitamin Substances 0.000 abstract description 2
- 229940088594 vitamin Drugs 0.000 abstract description 2
- 229930003231 vitamin Natural products 0.000 abstract description 2
- 235000013343 vitamin Nutrition 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract 2
- 230000008023 solidification Effects 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 150000003722 vitamin derivatives Chemical class 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 239000000654 additive Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 4
- 239000013041 solid bath agent Substances 0.000 description 4
- 239000003788 bath preparation Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 241000410518 Cyrano Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241001282110 Pagrus major Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940116298 l- malic acid Drugs 0.000 description 1
- WAHQBNXSPALNEA-UHFFFAOYSA-L lithium succinate Chemical compound [Li+].[Li+].[O-]C(=O)CCC([O-])=O WAHQBNXSPALNEA-UHFFFAOYSA-L 0.000 description 1
- 229960004254 lithium succinate Drugs 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000014860 sensory perception of taste Effects 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は外観形状が複雑な趣味感の高い浴用剤を得よう
とするものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention aims to provide a highly tasteful bath additive with a complex external shape.
従来の技術
従来の固形浴用剤は、浴用剤原料を型打ちすることによ
り製品化するものであるため、二角型、四角型等の単純
形状で有ればその製品化に問題は無いが、それ以上に複
雑な、例えば花、動物７Ｌ、状等を得ようとすると、ワ
レなりカケたりするものとなり、製品には成り得ないも
のであった。Conventional technology Conventional solid bath additives are manufactured by stamping raw materials for bath additives, so if they have a simple shape such as a square or square, there is no problem in commercializing the product. If an attempt was made to obtain a more complex shape, such as a flower, animal, shape, etc., the result would be cracking or chipping, and it would not be possible to produce a product.
また固形浴用剤にポリエチレングリコールを添加する先
行技術として、特開昭５８−
１０５９１０号、特開昭６２ ２１２３１．８号なとか
示されているか、これらの公報はいずれもポリエチレン
グリコールを安定剤として配合するものて、本発明のよ
うに任意形状の固形浴用剤を製造リーるためのものでは
ない。In addition, as prior art techniques for adding polyethylene glycol to solid bath preparations, Japanese Patent Application Laid-Open No. 105910/1982 and Japanese Patent Application Laid-open No. 21231.8/1987 are disclosed, and these publications both incorporate polyethylene glycol as a stabilizer. However, it is not intended for manufacturing solid bath additives of arbitrary shapes as in the present invention.
発明が解決しようとする課題
本発明は」−述のごとき課題を解決しようとするもので
あって、ワレなりカケたりすることなく複雑な形状の固
形浴用剤を簡易に得ようとするものである。Problems to be Solved by the Invention The present invention attempts to solve the problems as described above, and aims to easily obtain a solid bath preparation having a complex shape without cracking or chipping. .
課題を解決するための手段
本発明は上述のごとき課題を解決するなめ、乾燥粉末状
！ぶの浴用剤原料２０ｕ＋ｔ％〜８０ｗｔ％ｕ＋ｔ％に
、平均分子ｉ ３０００〜１００００のポリエチレング
リコール２０制Ｌ％〜８０ＬｌｌＬ９＋３を添加して加
熱溶融し、これを成形型に注型後、冷却固化して成形す
ることを特徴とし”（成るものである。Means for Solving the Problems The present invention solves the above-mentioned problems in the form of a dry powder! Polyethylene glycol 20% L9+3 with an average molecular i of 3000 to 10000 is added to 20u+t% to 80wt%u+t% of the raw materials for the bath agent of Buno and melted by heating, and after casting this into a mold, it is cooled and solidified. It is characterized by being molded.
本発明に用いられる浴用剤原料とは、炭酸ナトリウム、
炭酸水素ナトリウム、炭酸マダイ・シラノ１、炭酸カル
シウム、乾燥コハク酸、コハク酸すｌ・リウム、クエン
酸、酒石酸、芒硝、硼砂、食ｔζｌ’９１るとの浴用剤
の原料として知られているものてあり、これらの原料の
内から１種または２種１゛ノ十かｊ２択して使用される
。The bath agent raw materials used in the present invention include sodium carbonate,
Sodium hydrogen carbonate, red sea bream cyrano 1 carbonate, calcium carbonate, dry succinic acid, sulfur and lithium succinate, citric acid, tartaric acid, mirabilite, borax, and edible tζl'91, which are known as raw materials for bath additives. One or two of these raw materials are selected and used.
浴用剤原料グ）固形浴用剤中の足は２０ｕ＋Ｌ９Ｈ；’
ヘ８０ｕ＋１％であり、２０…ｔ％以下では浴用剤と
１．てＪ）効果を発揮せず、８（Ｊｕｔ％以上ては成形
性か悪くなる。Bathing agent raw material g) The foot in the solid bathing agent is 20u + L9H;'
80u+1%, and 20...t% or less is a bath agent and 1. J) No effect is exhibited, and if it exceeds 8 (Jut%), the moldability deteriorates.
また本発明に用いられるポリエチレンクリ：１−ルは平
均分子量か３，０００〜１０，０００のもので、一般的
にＰ Ｅ Ｇ ３，００＋１とかｌ二’ Ｅ Ｇ １０
．０００と叶はれるポリエチレングリコールてあり、こ
れらのＰ Ｅ Ｇの一種または２種以」−が混合して使
用される。これらポリエチレンクリ−７−ルの固形浴用
剤への配音量は２０ｗｔ％〜Ｂｏｗ１％てあり、２（ｈ
ｊ％に満たないと溶融時の粘度が高く、流動性か小さい
ため成形型への注入性が悪く、また８０１％を超えると
浴槽の湯に対する溶解性が悪くなり々ｆましくない、Ｖ
だポリエチレングリコールの平均分−ｒ−ｖ−が３ （
ｌ ＯＯに満なないと、製品にヘタ付きを牛し、製品価
値を著しく低下させるものとなり、また１ ００００を
超えると溶融時の粘度か高く、流動性か小さいため、成
形型Ｉ＼の注入性か悪いものとなる。Furthermore, the polyethylenecryl used in the present invention has an average molecular weight of 3,000 to 10,000, and is generally PEG 3,00+1 or l2'EG 10.
．． 000 polyethylene glycol, and one or more of these PEGs can be used in combination. The proportion of these polyethylene crele-7-ols in solid bath preparations is 20wt% to Bow1%, and 2(h
If it is less than 801%, the viscosity when melted is high and the fluidity is low, making it difficult to pour into the mold, and if it exceeds 801%, the solubility in hot water in the bathtub may be poor.V
The average content of polyethylene glycol -r-v- is 3 (
If it is less than 100, the product will become sticky and the product value will be significantly reduced. If it exceeds 10,000, the viscosity when melted will be high and the fluidity will be low, making it difficult to inject into the mold I\. It becomes a bad thing.
また、１−８記浴川剤原セ］とポリエチレングリコール
は、それぞれ所望量選択した後、撹拌機等を用いて均一
に混合し、さらに加熱溶融を行う。加熱溶融はポリエチ
レングリコールがほど良く溶融する温度が選はれ、６５
°Ｃから１００°Ｃの範囲好ましくは７０℃から９０℃
の温度か使用てきる。６５℃以下ては溶融性か悪く、１
００°Ｃ以上ではポリエチレングリコールか劣化してし
まう。溶融した固形浴用剤は溶融した状態で成形型に注
入される。成形型への注入は、公知のインジェクション
装置等を使用しても手作業てテカント笠によってもＬ１
的を達成することができる。なお成形型は、一般に使用
されるステンレスなとの金属性の成形型でも良いが複雑
な形状の固形浴用剤には、ポリプロピレン、シリコン等
で作った樹脂製の成形型がコスト、成形性の点て優れて
いる。成形型に溶融状態の固形浴用剤を注入した後、一
定時間（３０〜６０分） ｂｒ ＞ＡＡて放置して冷却
固化を行い、成形型を分割して製品を得る。冷却固化は
室温放置ジノ外の方法、例えは水冷、空冷なとの方法を
用いても同一の結束を得ることができる。また製品の成
形型からの離ｊ（１ｊ ｌ’ｌ−を高めるために、離を
剤等も使用することかできる。In addition, after selecting the desired amounts of 1-8 Yugawa Agent Base] and polyethylene glycol, they are mixed uniformly using a stirrer or the like, and then heated and melted. For heating and melting, a temperature at which the polyethylene glycol melts properly is selected, and 65
Range from °C to 100 °C, preferably 70 °C to 90 °C
It can be used at a temperature of Below 65°C, the meltability is poor and 1
At temperatures above 00°C, polyethylene glycol deteriorates. The molten solid bath agent is poured into a mold in a molten state. Injection into the mold can be done manually by using a known injection device, etc., or by hand using a Tecant Kasa.
Able to achieve target. The mold may be a commonly used metal mold such as stainless steel, but for complex-shaped solid bath additives, resin molds made of polypropylene, silicone, etc. are recommended in terms of cost and moldability. It's excellent. After pouring the molten solid bath agent into the mold, it is left to cool and solidify for a certain period of time (30 to 60 minutes), and the mold is divided to obtain products. The same bond can be obtained by cooling and solidifying by a method other than leaving the product at room temperature, such as water cooling or air cooling. Furthermore, a release agent or the like may be used to increase the release of the product from the mold.
さらに、本発明の固形浴用剤は前述した浴用剤原料とポ
リエチレングリコールの必須成分以外にも、必要に応し
て香料、色素、薬剤、ビタミン等を１種以上加えること
ができる。Furthermore, in addition to the above-mentioned essential components of bath agent raw materials and polyethylene glycol, the solid bath agent of the present invention may contain one or more types of fragrances, pigments, drugs, vitamins, etc., if necessary.
実施例１
ポリエチレングリコール（分子量４０００）
４０田ｔ％炭酸すＦリュウム
３０ｗｔ％ＤＬ−リン
ゴ酸 ：１０ ｌ１ｌＬ ９１
て上記組成を７５°Ｃで６０分加熱溶融する。そＬ２、
これを良く撹はんして、樹脂、で形成した成形（□ｊに
注型後、冷却固化して成形するものである。Example 1 Polyethylene glycol (molecular weight 4000)
40t% carbonate F rhium
30wt%DL-malic acid: 10 11L 91
The above composition was heated and melted at 75°C for 60 minutes. SoL2,
This is stirred well and molded with resin (after casting into □j, it is cooled and solidified to be molded).
実施例２
ポリエチレングリコール（分 ｒ量４０００）
２０ｗｔ％ポリエチレングリコール（分’ｆ
Ｉｆ！、６０００） ２０＋ｕｔ％
炭酸ナトリュウム
３０ｗｔ％ＤＬ−リンゴ酸
３（Ｊｕｔ％上記組成を８３χ゛て３０分加
熱溶融する。そし、これを良く撹はんして、樹脂、て形
成した成形型に注型後、冷却固化して成形するものであ
る。Example 2 Polyethylene glycol (min r amount 4000)
20wt% polyethylene glycol (min'f
If! , 6000) 20+ut%
sodium carbonate
30wt%DL-malic acid
3 (Jut%) The above composition is heated and melted at 83x2 for 30 minutes.Then, this is well stirred, poured into a mold made of resin, and then cooled and solidified to be molded.
実施例 ３
ボリエナレシクリコ・−ル（分子ｉ ６０００）
４０ｕ＋ｔ％炭酸ナトリュウム
３（ｈｔ％Ｄ
Ｌ−リンゴ酸 ３０ｗｔ％−Ｆ
記組成を８３℃て５０分加熱溶融する。そし、これを良
く撹はんして、樹脂、で形成した成形型に注型後、冷却
固化して成形するものである。Example 3 Borienare cyclool (molecule i 6000)
40u+t% sodium carbonate
3(ht%D
L-malic acid 30wt%-F
The above composition was heated and melted at 83° C. for 50 minutes. This is then thoroughly stirred, poured into a mold made of resin, and then cooled and solidified to be molded.
実施例 ４
ポリエチレングリコール（分子Ｊｔ４０００）
３０ｕ＋ｔ％炭酸ナトリュウム
３０ＩＩＩ１％
ＤＬ−リンニを酸 ３０
ｗｔ％ポウ酸 １０ｕ＋ｔ
％上記組成を７８℃で４５分加熱溶融する。そＬ７、こ
れを良く撹はんして、樹脂、て形成した成形型に注型後
、冷却固化して成形するものである。Example 4 Polyethylene glycol (molecule Jt4000)
30u+t% sodium carbonate
30III1%
DL-Linni acid 30
wt% poric acid 10u+t
% The above composition is heated and melted at 78°C for 45 minutes. L7: This is thoroughly stirred, poured into a mold made of resin, and then cooled and solidified to be molded.
実施例 ５
ポリエチレングリコール（分子量４０００）
５０ｗｔ％炭酸ナトリュウム
２５＋ｕＬ％ＤＬ
−リンゴ酸 ２５ｗｔ％上記
組成を８０℃で３５分加熱溶融する。そし、これを良く
撹はんして、樹脂、で形成した成形型に注型後、冷却固
化して成形するものである。Example 5 Polyethylene glycol (molecular weight 4000)
50wt% sodium carbonate
25+uL%DL
- Malic acid 25 wt% The above composition is heated and melted at 80°C for 35 minutes. This is then thoroughly stirred, poured into a mold made of resin, and then cooled and solidified to be molded.
発明の効果
本発明は上述のごとく構成したちのであるから、複雑な
形状の固形浴用剤を形成するのに、ワレなりカケたりす
ることなく、これを簡易に得ることができる。また従来
単純な形状しか得られなかったものが、複雑な形状の固
形浴用剤を可能とし、趣味感を向上するとともに商品価
値を高めることが可能となるものである。Effects of the Invention Since the present invention is constructed as described above, a solid bath agent having a complicated shape can be easily obtained without cracking or chipping. In addition, solid bath additives with complex shapes, which could only be obtained in the past in simple shapes, can now be made into solid bath additives, thereby improving the sense of taste and increasing the commercial value.
Claims (1)
％に、平均分子量３０００〜１００００のポリエチレン
グリコール２０ｗｔ％〜８０ｗｔ％を添加して加熱溶融
し、これを成形型に注型後、冷却固化して成形すること
を特徴とする浴用剤の製造方法。(1) 20wt% to 80wt of bath agent raw materials in dry powder form
% and 20 wt % to 80 wt % of polyethylene glycol having an average molecular weight of 3,000 to 10,000 is added thereto, heated and melted, poured into a mold, cooled and solidified, and molded.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29561688A JPH02142721A (en) | 1988-11-22 | 1988-11-22 | Preparation of solid bathing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29561688A JPH02142721A (en) | 1988-11-22 | 1988-11-22 | Preparation of solid bathing agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02142721A true JPH02142721A (en) | 1990-05-31 |
Family
ID=17822937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29561688A Pending JPH02142721A (en) | 1988-11-22 | 1988-11-22 | Preparation of solid bathing agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02142721A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1147220A (en) * | 1997-07-30 | 1999-02-23 | Kao Corp | Composition of granular bath medicine |
| JP2005336060A (en) * | 2004-05-24 | 2005-12-08 | Kimi Kasei Kk | Granular bathing agent composition |
| JP2006249027A (en) * | 2005-03-11 | 2006-09-21 | Kanebo Ltd | Cosmetic of foamed molded product, cosmetic composition and makeup method |
| JP2006249026A (en) * | 2005-03-11 | 2006-09-21 | Kanebo Ltd | Bathing agent of foamed molded product, composition for bathing agent of foamed molded product and bathing method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58105910A (en) * | 1981-12-17 | 1983-06-24 | Mai Sukinkeaa Lab:Kk | Solid bath composition |
-
1988
- 1988-11-22 JP JP29561688A patent/JPH02142721A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58105910A (en) * | 1981-12-17 | 1983-06-24 | Mai Sukinkeaa Lab:Kk | Solid bath composition |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1147220A (en) * | 1997-07-30 | 1999-02-23 | Kao Corp | Composition of granular bath medicine |
| JP2005336060A (en) * | 2004-05-24 | 2005-12-08 | Kimi Kasei Kk | Granular bathing agent composition |
| JP2006249027A (en) * | 2005-03-11 | 2006-09-21 | Kanebo Ltd | Cosmetic of foamed molded product, cosmetic composition and makeup method |
| JP2006249026A (en) * | 2005-03-11 | 2006-09-21 | Kanebo Ltd | Bathing agent of foamed molded product, composition for bathing agent of foamed molded product and bathing method |
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