JPH0144682B2 - - Google Patents
Info
- Publication number
- JPH0144682B2 JPH0144682B2 JP55035113A JP3511380A JPH0144682B2 JP H0144682 B2 JPH0144682 B2 JP H0144682B2 JP 55035113 A JP55035113 A JP 55035113A JP 3511380 A JP3511380 A JP 3511380A JP H0144682 B2 JPH0144682 B2 JP H0144682B2
- Authority
- JP
- Japan
- Prior art keywords
- chloride
- cationized
- resin
- cationic group
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000002091 cationic group Chemical group 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229920001567 vinyl ester resin Polymers 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001449 anionic compounds Chemical group 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 239000002075 main ingredient Substances 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 230000002335 preservative effect Effects 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 235000013355 food flavoring agent Nutrition 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- TZYULTYGSBAILI-UHFFFAOYSA-M trimethyl(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC=C TZYULTYGSBAILI-UHFFFAOYSA-M 0.000 description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical class CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 2
- SQTUYFKNCCBFRR-UHFFFAOYSA-N (2,4-dimethoxyphenyl)boronic acid Chemical compound COC1=CC=C(B(O)O)C(OC)=C1 SQTUYFKNCCBFRR-UHFFFAOYSA-N 0.000 description 1
- GNSQPMMGUIWQJX-UHFFFAOYSA-N 1-chloroethane-1,2-diamine Chemical compound NCC(N)Cl GNSQPMMGUIWQJX-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- ICENLAOCDMWIAT-UHFFFAOYSA-N 2-(dimethylamino)-n-methylprop-2-enamide Chemical compound CNC(=O)C(=C)N(C)C ICENLAOCDMWIAT-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- SCHZETOYDJAZMO-UHFFFAOYSA-M 3-chloropropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCCl SCHZETOYDJAZMO-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- LZBIYPIDWSGLOV-UHFFFAOYSA-N dimethyl(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC=C LZBIYPIDWSGLOV-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- HWRHHYJNAIBXPC-UHFFFAOYSA-M ethyl(trimethyl)azanium;prop-2-enamide;chloride Chemical compound [Cl-].NC(=O)C=C.CC[N+](C)(C)C HWRHHYJNAIBXPC-UHFFFAOYSA-M 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- UGVAXJOVDBUNPN-UHFFFAOYSA-M hydroxymethyl-dimethyl-[3-(2-methylprop-2-enoyloxy)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCCC[N+](C)(C)CO UGVAXJOVDBUNPN-UHFFFAOYSA-M 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QRWZCJXEAOZAAW-UHFFFAOYSA-N n,n,2-trimethylprop-2-enamide Chemical compound CN(C)C(=O)C(C)=C QRWZCJXEAOZAAW-UHFFFAOYSA-N 0.000 description 1
- VMESOKCXSYNAKD-UHFFFAOYSA-N n,n-dimethylhydroxylamine Chemical compound CN(C)O VMESOKCXSYNAKD-UHFFFAOYSA-N 0.000 description 1
- GBCKRQRXNXQQPW-UHFFFAOYSA-N n,n-dimethylprop-2-en-1-amine Chemical compound CN(C)CC=C GBCKRQRXNXQQPW-UHFFFAOYSA-N 0.000 description 1
- BGDTWOQNFJNCKH-UHFFFAOYSA-N n-ethyl-n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCN(CC)CC=C BGDTWOQNFJNCKH-UHFFFAOYSA-N 0.000 description 1
- WGESLFUSXZBFQF-UHFFFAOYSA-N n-methyl-n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCN(C)CC=C WGESLFUSXZBFQF-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
- CCVMLEHYQVSFOM-UHFFFAOYSA-N trimethyl-[2-(prop-2-enoylamino)ethyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCNC(=O)C=C CCVMLEHYQVSFOM-UHFFFAOYSA-N 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Description
【発明の詳細な説明】
本発明は新規なパツク剤に関する。フエースパ
ツクはパツク剤が次第に乾燥するにともない、皮
膚に刺激を与え皮膚の血行がよくなるとか、パツ
ク剤の吸着作用により皮膚表面が清潔になる等の
効果が認められ美容料のひとつとして使用されて
いるものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel pack agent. Face packs are used as beauty products because they stimulate the skin as the packs gradually dry, improving blood circulation in the skin, and cleanse the skin surface due to the adsorption of the packs. It is something.
しかしてかかるパツク剤としては、通常ポリビ
ニルアルコール、カルボキシメチルセルローズ、
各種のゴム質などの水性粘稠液を主剤として、こ
れに種々の微量成分を配合したものが用いられて
いる。 However, such pack agents usually include polyvinyl alcohol, carboxymethyl cellulose,
The main ingredient is an aqueous viscous liquid such as various types of rubber, which is mixed with various trace ingredients.
これら従来のパツク剤はパツク剤の吸着作用が
不充分である。即ち皮膚表面に付着している脂肪
や不潔物を吸着し、皮膚表面を清掃するという働
きが弱いものであつて、パツク剤としては満足し
うるものではない。 These conventional packs have insufficient adsorption action. That is, it has a weak function of adsorbing fat and impurities adhering to the skin surface and cleaning the skin surface, and is not satisfactory as a pack agent.
本発明者らは鋭意検討を重ねた結果、特定のカ
チオン基を含有するカチオン化樹脂とグリコール
類とを主剤とするパツク剤が、前記したパツク剤
としての作用効果なかんずく優れた吸着作用にも
とづき、皮膚表面を充分に清浄するものであるこ
とを見出し、本発明にいたつた。 As a result of extensive studies, the present inventors have found that a pack agent whose main ingredients are a cationized resin containing a specific cationic group and glycols is based on the above-mentioned effects as a pack agent, especially its excellent adsorption effect. It was discovered that it sufficiently cleans the skin surface, leading to the present invention.
本発明で用いるカチオン化樹脂とは前記の特定
のカチオン基を含有するビニルエステル系の重合
体又はそのケン化物であり、通常は上記のカチオ
ン基を含有するモノマーとビニルエステルを共重
合した重合体及びそれをケン化したものをいう
が、必ずしもこれに限られるものではなく、最終
的に上記の重合体ケン化物と構造が類似するも
の、例えばポリビニルアルコールとカチオン基含
有モノマーとの後反応により製造されるもの等も
いう。 The cationized resin used in the present invention is a vinyl ester polymer containing the above-mentioned specific cationic group or a saponified product thereof, and is usually a polymer obtained by copolymerizing a monomer containing the above-mentioned cationic group with a vinyl ester. and saponified products thereof, but are not necessarily limited to this, and are ultimately produced by a post-reaction of polyvinyl alcohol and a cationic group-containing monomer that has a similar structure to the above saponified polymer. It also refers to things that are done.
以下かかる樹脂について具体的に説明する。 The resin will be specifically explained below.
本発明におけるカチオン化樹脂としては、
一般式
（但し式中R1はアルキレン又はヒドロキシア
ルキレン、R2は水素又はアルキル、R3とR4はア
ルキル、Ｘは無機アニオンを表わす）で表わされ
るカチオン基を含むポリビニルアルコール系樹脂
があり、これは該カチオン基を有する化合物とポ
リビニルアルコール系樹脂との反応によつて得ら
れる。該化合物を例示すると、３―クロロ―２―
ヒドロキシプロピルトリメチルアンモニウムクロ
ライド、３―クロロエチルトリメチルアンモニウ
ムクロライド、３―クロロプロピルトリメチルア
ンモニウムクロライド、３―クロロ―２―ヒドロ
キシエチルトリメチルアンモニウムクロライド、
２―クロロエチレンジアミン、３―クロロ―２―
ヒドロキシジメチルアミンなどがあげられる。 The cationized resin in the present invention has the general formula There is a polyvinyl alcohol resin containing a cationic group represented by the formula (wherein R 1 is alkylene or hydroxyalkylene, R 2 is hydrogen or alkyl, R 3 and R 4 are alkyl, and X is an inorganic anion). It is obtained by reacting a compound having the cationic group with a polyvinyl alcohol resin. To illustrate this compound, 3-chloro-2-
Hydroxypropyltrimethylammonium chloride, 3-chloroethyltrimethylammonium chloride, 3-chloropropyltrimethylammonium chloride, 3-chloro-2-hydroxyethyltrimethylammonium chloride,
2-chloroethylenediamine, 3-chloro-2-
Examples include hydroxydimethylamine.
カチオン基(b)として一般式
（但し式中R1はアルキレン又はヒドロキシア
ルキレン、R2とR5は水素又はアルキル、R3とR4
はアルキル、Ｘは無機アニオン、Ａアミド窒素又
は酸素を表わす）で表わされるカチオン基を有す
るカチオン化樹脂は、該カチオン基を有する化合
物とビニルエステルなかんずく酢酸ビニルとを共
重合した共重合体、及び該共重合体のケン化物が
あげられ好ましくは該共重合体ケン化物である。
該カチオン基を有する化合物としては、Ｎ―アク
リルアミドトリメチルアンモニウムクロライド、
Ｎ―アクリルアミドエチルトリメチルアンモニウ
ムクロライド、Ｎ―アクリルアミドプロピルトリ
メチルアンモニウムクロライド、３―アクリルア
ミド、―３―メチルブチルトリメチルアンモニウ
ムクロライド、２―アクリロキシエチルトリメチ
ルアンモニウムクロライド、２―メタクリロキシ
エチルトリメチルアンモニウムクロライド、２―
ヒドロキシ―３―メタクロイルオキシプロピルト
リメチルアンモニウムクロライド、Ｎ―メチルジ
メチルアミノアクリルアミド、ジエチルアミノエ
チルメタクリレートなどがあげられる。 General formula for cationic group (b) (However, in the formula, R 1 is alkylene or hydroxyalkylene, R 2 and R 5 are hydrogen or alkyl, R 3 and R 4
is an alkyl, X is an inorganic anion, A amide nitrogen or oxygen) A cationized resin having a cationic group is a copolymer obtained by copolymerizing a compound having the cationic group with a vinyl ester, particularly vinyl acetate, and Among these are saponified products of the copolymer, preferably saponified products of the copolymer.
As the compound having the cationic group, N-acrylamide trimethylammonium chloride,
N-acrylamidoethyltrimethylammonium chloride, N-acrylamidopropyltrimethylammonium chloride, 3-acrylamide, -3-methylbutyltrimethylammonium chloride, 2-acryloxyethyltrimethylammonium chloride, 2-methacryloxyethyltrimethylammonium chloride, 2-
Examples include hydroxy-3-methacroyloxypropyltrimethylammonium chloride, N-methyldimethylaminoacrylamide, and diethylaminoethyl methacrylate.
カチオン基(c)として一般式
（但し式中R2とR5は水素又はアルキル、R3と
R4はアルキル、Ｘは無機アニオン、ｎ＝１〜10
を表わす）で表わされるカチオン基を有するカチ
オン化樹脂は、該カチオン基を有する化合物とビ
ニルエステルなかんずく酢酸ビニルとを共重合し
た共重合体、及び該共重合体のケン化物があげら
れるが、好ましくは該共重合体ケン化物である。
該カチオン基を有する化合物としては、アリルト
リメチルアンモニウムクロライド、メタアリルト
リメチルアンモニウムクロライド、３―ブテント
リメチルアンモニウムクロライド、ジメチルアリ
ルアミン、ジメチルメタアクリルアミンなどがあ
げられる。 General formula for cationic group (c) (However, in the formula, R 2 and R 5 are hydrogen or alkyl, R 3 and
R 4 is alkyl, X is an inorganic anion, n = 1 to 10
Examples of the cationized resin having a cationic group represented by ) include a copolymer obtained by copolymerizing a compound having the cationic group with a vinyl ester, especially vinyl acetate, and a saponified product of the copolymer. is the saponified copolymer.
Examples of the compound having the cationic group include allyltrimethylammonium chloride, methalyltrimethylammonium chloride, 3-butenetrimethylammonium chloride, dimethylallylamine, and dimethylmethacrylamine.
カチオン基(d)として一般式
（但し式中R2とR5は水素又はアルキル、R3は
アルキル、Ｘは無機アニオンを表わす）で表わさ
れるカチオン基を有するカチオン化樹脂は、該カ
チオン基を有する化合物とビニルエステルなかん
ずく酢酸ビニルとを共重合した共重合体、及び該
共重合体のケン化物があげられるが、好ましくは
該共重合体ケン化物である。該カチオン基を有す
る化合物としては、ジメチルジアリルアンモニウ
ムクロライド、ジエチルアリルアンモニウムクロ
ライド、エチルジアリルアミン、メチルジアリル
アミンなどがあげられる。 General formula for cationic group (d) (However, in the formula, R 2 and R 5 are hydrogen or alkyl, R 3 is alkyl, and X is an inorganic anion). Examples include a copolymer obtained by copolymerizing and a saponified product of the copolymer, and preferably a saponified product of the copolymer. Examples of the compound having the cationic group include dimethyldiallylammonium chloride, diethylallylammonium chloride, ethyldiallylamine, methyldiallylamine, and the like.
また前記化合物とビニルエステルとを共重合す
る際に、ビニルエステルのほかに他の共重合性単
量体を少量併用しうる。 Further, when copolymerizing the above compound and vinyl ester, a small amount of other copolymerizable monomers may be used in addition to the vinyl ester.
本発明におけるカチオン化樹脂、即ち一般式
(a)，(b)，(c)，(d)で表わされるカチオン基を含むカ
チオン化樹脂のなかで、一般式(a)で表わされるカ
チオン基を含むカチオン化樹脂は、前記のような
カチオン基を有する化合物とポリビニルアルコー
ル系樹脂との付加反応によつて得られるものであ
つてこの反応は苛酷な条件を必要とし、導入され
るカチオン基量も限度があり且つ少ない。これに
対して一般式(b)，(c)，(d)で表わされるカチオン基
を含むカチオン化樹脂は、前記した如くビニルエ
ステルなかんずく酢酸ビニルと該カチオン基含有
化合物との共重合体及び該共重合体のケン化物で
あるから、容易にしかも導入されるカチオン基量
も多いものが得られる。従つて一般式(a)で表わさ
れるカチオン基含有カチオン化樹脂よりも一般式
(b)，(c)，(d)で表わされるカチオン基含有カチオン
化樹脂の方が好適であつて、その使用が望まれ
る。 The cationized resin in the present invention, that is, the general formula
Among the cationized resins containing the cationic groups represented by (a), (b), (c), and (d), the cationic resins containing the cationic groups represented by the general formula (a) are as described above. It is obtained by an addition reaction between a compound having a cationic group and a polyvinyl alcohol resin, and this reaction requires harsh conditions, and the amount of cationic groups introduced is limited and small. On the other hand, cationized resins containing cationic groups represented by general formulas (b), (c), and (d) are copolymers of vinyl esters, especially vinyl acetate, and compounds containing cationic groups, as described above. Since it is a saponified product of a copolymer, it can be easily introduced and a large amount of cationic groups can be obtained. Therefore, the general formula
The cationized resins containing cationic groups represented by (b), (c), and (d) are more suitable and their use is desired.
本発明において用いるカチオン化樹脂はカチオ
ン基含量が0.1〜30モル％の範囲のものが適当で
あり、パツク剤中のカチオン化樹脂の配合量は、
前記カチオン基含有の吸着作用にもとづく皮膚清
浄効果との関係を考慮して適宜適量を用いること
が望ましい。 The cationized resin used in the present invention has a cationic group content in the range of 0.1 to 30 mol%, and the amount of the cationized resin in the pack is as follows:
It is desirable to use an appropriate amount in consideration of the relationship with the skin cleansing effect based on the adsorption effect of the cationic group-containing substance.
グリコール類は、パツク剤に可塑性を付与し、
皮膚との接触をなめらかにするために不可欠なも
のであり、カチオン化樹脂100重量部に対して20
〜200重量部の範囲で用いる。 Glycols add plasticity to pack agents,
It is essential for smooth contact with the skin, and 20 parts per 100 parts by weight of cationized resin.
Used in a range of ~200 parts by weight.
該グリコール類としては、エチレングリコー
ル、プロピレングリコール、１，４―ブチレング
リコール、ジエチレングリコール、トリエチレン
グリコール、グリセリン、ポリエチレングリコー
ルなどがあげられる。 Examples of the glycols include ethylene glycol, propylene glycol, 1,4-butylene glycol, diethylene glycol, triethylene glycol, glycerin, and polyethylene glycol.
本発明におけるパツク剤は、乾燥時間を短縮す
るために適量のアルコール、適度の粘性と皮膚と
の剥離性を補なうためのセルロース誘導体、その
他香料、殺菌剤、皮膚栄養剤、填料等を適量配合
し、さらに水を加えて使用に適した粘度に調製し
て得られる。 The pack agent of the present invention contains an appropriate amount of alcohol to shorten drying time, a cellulose derivative to provide appropriate viscosity and peelability from the skin, and appropriate amounts of other fragrances, disinfectants, skin nutrients, fillers, etc. It is obtained by blending and then adding water to adjust the viscosity suitable for use.
次に実施例によつて本発明を具体的に説明す
る。尚例中「部」とあるのは特にことわりのない
限り重量基準である。 Next, the present invention will be specifically explained with reference to Examples. In the examples, "parts" are based on weight unless otherwise specified.
実施例 １
３―クロロ―２―ヒドロキシプロピルトリメチ
ルアンモニウムクロライドとポリビニルアルコー
ル（平均重合度1800、ケン化度98モル％）との反
応物であるカチオン化度（カチオン化樹脂中のカ
チオン基量のモル％表示）３モル％のカチオン化
樹脂―ａを用い、以下のような配合でパツク剤を
得た。Example 1 Degree of cationization (molar amount of cation groups in cationized resin) which is a reaction product of 3-chloro-2-hydroxypropyltrimethylammonium chloride and polyvinyl alcohol (average degree of polymerization 1800, degree of saponification 98 mol%) A pack agent was obtained using 3 mol % of cationized resin-a (expressed as %) with the following formulation.
カチオン化樹脂―ａ ５部
ヒドロキシエチルセルローズ ５
グリセリン ５
アルコール ５
香料、防腐剤 適量
精製水を適量加えて全量を100部とした。この
パツク剤を用いてパツクしたところ、皮膚はつや
やかになつた。Cationized resin-a 5 parts Hydroxyethyl cellulose 5 Glycerin 5 Alcohol 5 Fragrance, preservative Appropriate amount An appropriate amount of purified water was added to bring the total amount to 100 parts. When I used this pack agent, my skin became shiny.
実施例 ２
アリルトリメチルアンモニウムクロライドと酢
酸ビニルとの共重合体ケン化物（ケン化度87モル
％）であるカチオン化度１モル％のカチオン化樹
脂―ｂを用い、以下のような配合でパツク剤を得
た。Example 2 Using cationized resin-b with a degree of cationization of 1 mol%, which is a saponified copolymer of allyltrimethylammonium chloride and vinyl acetate (degree of saponification 87 mol%), a pack agent was prepared with the following formulation. I got it.
カチオン化樹脂―ｂ 15部
ポリエチレングリコール（＃1500） ４
水溶性ラノリン １
アルコール 10
香料、防腐剤 適量
精製水を適量加えて全量を100部とした。この
パツク剤を用いてパツクしたところ、皮膚はつや
やかになつた。Cationized resin-b 15 parts Polyethylene glycol (#1500) 4 Water-soluble lanolin 1 Alcohol 10 Flavor, preservative Appropriate amount Add an appropriate amount of purified water to make the total amount 100 parts. When I used this pack agent, my skin became shiny.
実施例 ３
Ｎ―アクリルアミドプロピル―３―トリメチル
アンモニウムクロライドと酢酸ビニルとの共重合
体ケン化物（ケン化度89モル％）であるカチオン
化度５モル％のカチオン化樹脂―Ｃを用い、以下
のような配合でパツク剤を得た。Example 3 Using cationized resin-C with a degree of cationization of 5 mol%, which is a saponified copolymer of N-acrylamidopropyl-3-trimethylammonium chloride and vinyl acetate (degree of saponification 89 mol%), the following was carried out. A pack agent was obtained with the following formulation.
カチオン化樹脂―Ｃ ５部
ヒドロキシプロピルセルローズ ５
プロピレングリコール ５
アルコール ５
香料、防腐剤 適量
精製水を適量加えて全量を100部とした。この
パツク剤を用いてパツクしたところ、皮膚はつや
やかになつた。Cationized resin-C 5 parts Hydroxypropyl cellulose 5 Propylene glycol 5 Alcohol 5 Flavoring agent, preservative Appropriate amount An appropriate amount of purified water was added to bring the total amount to 100 parts. When I used this pack agent, my skin became shiny.
実施例 ４
ジメチルアリルアンモニウムクロライドと酢酸
ビニルとの共重合体であるカチオン化度４モル％
のカチオン化樹脂―ｄを用い、以下のような配合
でパツク剤を得た。Example 4 Copolymer of dimethylallylammonium chloride and vinyl acetate with cationization degree of 4 mol%
A pack agent was obtained using the cationized resin-d in the following formulation.
カチオン化樹脂―ｄ ５部
ヒドロキシプロピルセルローズ ５
グリセリン ４
アルコール ５
水溶性ビタミンＡ 0.1
香料、防腐剤 適量
精製水を適量加えて全量を100部とした。この
パツク剤を用いてパツクしたところ、皮膚はつや
やかになつた。Cationized resin-d 5 parts Hydroxypropyl cellulose 5 Glycerin 4 Alcohol 5 Water-soluble vitamin A 0.1 Flavoring agent, preservative Appropriate amount Add an appropriate amount of purified water to bring the total amount to 100 parts. When I used this pack agent, my skin became shiny.
実施例 ５
アリルトリメチルアンモニウムクロライドとＮ
―アクリルアミドエチルトリメチルアンモニウム
クロライドと酢酸ビニルとの共重合体ケン化物
（ケン化度85モル％）であるカチオン化度2.5モル
％のカチオン化樹脂―ｅを用い、以下のような配
合でパツク剤を得た。Example 5 Allyltrimethylammonium chloride and N
-A cationized resin with a cationization degree of 2.5 mol%, which is a saponified copolymer of acrylamide ethyltrimethylammonium chloride and vinyl acetate (saponification degree of 85 mol%), was used to create a pack agent with the following formulation. Obtained.
カチオン化樹脂―ｅ 15部
チタンホワイト １
ベントナイト 1.5
酸化亜鉛 ７
グリセリン ５
アルコール 10
香料、防腐剤 適量
精製水を適量加えて全量を100部とした。この
パツク剤を用いてパツクしたところ、皮膚はつや
やかになつた。Cationized resin-e 15 parts Titanium white 1 Bentonite 1.5 Zinc oxide 7 Glycerin 5 Alcohol 10 Flavoring agent, preservative Appropriate amount Add an appropriate amount of purified water to bring the total amount to 100 parts. When I used this pack agent, my skin became shiny.
対照例
実施例１においてカチオン化樹脂に替えて、ポ
リビニルアルコールを用いたほかは同様にしてパ
ツク剤を得た。このパツク剤にてパツクしたとこ
ろ、皮膚のつややかさは実施例のパツク剤より劣
るものであつた。Control Example A pack agent was obtained in the same manner as in Example 1 except that polyvinyl alcohol was used instead of the cationized resin. When this pack was applied to the skin, the gloss of the skin was inferior to that of the pack of Examples.
Claims (1)
ルキレン、R2とR5は水素又はアルキル、R3とR4
はアルキル、Ｘは無機アニオン、Ａはアミド窒素
又は酸素を表す）で表されるカチオン基の群(a)，
(b)，(c)，(d)から選ばれた１種又は２種以上のカチ
オン基を0.1〜30モル％を含むビニルエステル系
重合体又は該重合体のケン化物の少なくとも１種
から選ばれるカチオン化樹脂とグリコール類とを
主剤としてなるパツク剤。[Claims] 1. The following general formula (However, in the formula, R 1 is alkylene or hydroxyalkylene, R 2 and R 5 are hydrogen or alkyl, R 3 and R 4
is alkyl, X is an inorganic anion, A is amide nitrogen or oxygen),
Selected from at least one vinyl ester polymer containing 0.1 to 30 mol% of one or more cationic groups selected from (b), (c), and (d), or a saponified product of the polymer. A pack agent whose main ingredients are cationized resin and glycols.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3511380A JPS56131511A (en) | 1980-03-18 | 1980-03-18 | Pack agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3511380A JPS56131511A (en) | 1980-03-18 | 1980-03-18 | Pack agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56131511A JPS56131511A (en) | 1981-10-15 |
| JPH0144682B2 true JPH0144682B2 (en) | 1989-09-29 |
Family
ID=12432869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3511380A Granted JPS56131511A (en) | 1980-03-18 | 1980-03-18 | Pack agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56131511A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6045511A (en) * | 1983-08-23 | 1985-03-12 | Kobayashi Kooc:Kk | Jellylike pack cosmetic |
| US5512277A (en) | 1991-05-15 | 1996-04-30 | Kao Corporation | Keratotic plug remover |
| JP3578776B2 (en) * | 1992-02-12 | 2004-10-20 | 花王株式会社 | Square plug removal method |
| JP3987286B2 (en) | 1999-05-12 | 2007-10-03 | 花王株式会社 | Square plug remover |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5157837A (en) * | 1974-11-12 | 1976-05-20 | Shiseido Co Ltd | HIFUHIFUKU SEIIKESHORYONO SEIZOHO |
| JPS5254035A (en) * | 1975-10-30 | 1977-05-02 | Idemitsu Kosan Co Ltd | Cosmetic pack |
| JPS5279034A (en) * | 1975-12-23 | 1977-07-02 | Pola Kasei Kogyo Kk | Packing agent |
| JPS53139734A (en) * | 1977-03-15 | 1978-12-06 | Oreal | Keratin treating composition |
| JPS5495739A (en) * | 1977-09-23 | 1979-07-28 | Oreal | Hair and skin cosmetics composition |
-
1980
- 1980-03-18 JP JP3511380A patent/JPS56131511A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5157837A (en) * | 1974-11-12 | 1976-05-20 | Shiseido Co Ltd | HIFUHIFUKU SEIIKESHORYONO SEIZOHO |
| JPS5254035A (en) * | 1975-10-30 | 1977-05-02 | Idemitsu Kosan Co Ltd | Cosmetic pack |
| JPS5279034A (en) * | 1975-12-23 | 1977-07-02 | Pola Kasei Kogyo Kk | Packing agent |
| JPS53139734A (en) * | 1977-03-15 | 1978-12-06 | Oreal | Keratin treating composition |
| JPS5495739A (en) * | 1977-09-23 | 1979-07-28 | Oreal | Hair and skin cosmetics composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56131511A (en) | 1981-10-15 |
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