JPH01307110A - Self-lubricating insulated wire - Google Patents

Self-lubricating insulated wire

Info

Publication number
JPH01307110A
JPH01307110A JP13644788A JP13644788A JPH01307110A JP H01307110 A JPH01307110 A JP H01307110A JP 13644788 A JP13644788 A JP 13644788A JP 13644788 A JP13644788 A JP 13644788A JP H01307110 A JPH01307110 A JP H01307110A
Authority
JP
Japan
Prior art keywords
insulating layer
insulated wire
lubricating
parts
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13644788A
Other languages
Japanese (ja)
Inventor
Masakazu Mesaki
目崎 正和
Bunichi Sano
佐野 文一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Electric Co Ltd
Original Assignee
Furukawa Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Furukawa Electric Co Ltd filed Critical Furukawa Electric Co Ltd
Priority to JP13644788A priority Critical patent/JPH01307110A/en
Publication of JPH01307110A publication Critical patent/JPH01307110A/en
Pending legal-status Critical Current

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  • Paints Or Removers (AREA)
  • Organic Insulating Materials (AREA)
  • Insulated Conductors (AREA)

Abstract

PURPOSE:To improve lubricity of a self-lubricating insulated wire by painting and baking, on a conductor, the resin paint composed by applying the specified quantity of each montan wax and oxidation-deterioration inhibitor to thermosetting resin and dissolving them with solvent so as to form a lubricating insulating layer on the conductor. CONSTITUTION:A lubricating insulating layer is formed on a conductor by, directry or via another insulating layer, painting and baking the resin paint composed by applying 0.1 to 7.0 pts.wt. of montan wax and of oxidation- deterioration inhibitor to 100 pts.wt. of thermosetting resin and dissolving them with solvent. An insulated wire with self-lubrication is, thus, obtained in which coefficient of static friction is low and anti-abrasion is high. Accordingly, there is no damage on insulating membrane, even if a coil of the insulated wire is rapidly wound. Therefore, operability is improved.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は自己潤滑性に優れた絶縁電線に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an insulated wire with excellent self-lubricating properties.

(従来の技術) 近年電機機器の製造工程においては、省力化、合理化が
盛んに行われており、これらの機器に使用されるエナメ
ル線に代表される絶縁電線はその加工によって大きなダ
メージを受けることになる。
(Prior art) In recent years, labor-saving and rationalization have been actively carried out in the manufacturing process of electrical equipment, and insulated wires such as enamelled wires used in these equipments can be seriously damaged by processing. become.

これらのダメージは例えばコイル加工工程における合理
化、或は高速自動巻線機の導入による自動化及び高速化
等であシ、且つ機器自体の小型化、高性能化による占積
率の向上である。このような高速化や占積率の向上は使
用するエナメル線に対して非常に厳しい条件となる。即
ち高速化に伴ってグーリーやがイドとの摩擦力が増大す
るに伴って摩耗量が増大し、場合によっては絶縁層が破
壊されるという絶縁電線として電気的特性を著しく阻害
するものであった。従ってエナメル線の特性としてすべ
り性に代表される潤滑性は、このダメージを解消せしめ
る上において極めて重要な特性である。
These damages are caused by, for example, streamlining the coil processing process, automation and speeding up by introducing high-speed automatic winding machines, and improvements in the space factor by downsizing and improving the performance of the equipment itself. Such an increase in speed and an improvement in the space factor are very strict conditions for the enamelled wire used. In other words, as the speed increases, the amount of wear increases as the frictional force between the wire and the wire increases, and in some cases, the insulation layer is destroyed, which significantly impedes the electrical properties of the wire. . Therefore, lubricity, represented by slipperiness, is an extremely important characteristic of enameled wire in eliminating this damage.

この潤滑性を向上せしめるために従来絶縁層の表面に潤
滑油や・母ラフインを塗布するとか或は潤滑性を有する
ポリアミド樹脂等をオーバーコートする方法が行われて
いる。又絶縁層を形成する樹脂中にポリエチレン等の潤
滑成分を添加する方法も提案されている。然しなからこ
れらの方法を実施したとしても、上記の如き厳しいコイ
ル加工工程においてはこれに追従することが出来ず、生
産性の向上は期侍出来難いもので、ちった。
In order to improve this lubricity, conventional methods have been used to coat the surface of the insulating layer with lubricating oil or mother rough-in, or to overcoat with a polyamide resin or the like having lubricity. A method has also been proposed in which a lubricating component such as polyethylene is added to the resin forming the insulating layer. However, even if these methods were implemented, they would not be able to follow the above-mentioned severe coil processing process, and it would be difficult to improve productivity.

(発明が解決しようとする課題) 本発明はかかる現状に鑑み鋭意研究を行った結果、潤滑
性に浸れた絶縁層を設けた絶縁電線を開発したものであ
る。
(Problems to be Solved by the Invention) In view of the current situation, the present invention has conducted intensive research and has developed an insulated wire provided with an insulating layer soaked in lubricity.

(課題を解決するための手段) 本発明は導体上((直接又は他の絶縁物層を介して熱硬
化性樹脂100重量部に対しモンタ/酸ワックス0.1
〜7.0重量部及び酸化劣化防止剤0.1〜7.0重世
部を添加しこれを浴剤で溶解してなる樹脂塗料の塗布焼
付けによる潤滑絶縁層を形成したことを特徴とするもの
である。
(Means for Solving the Problems) The present invention provides 0.1 parts of Monta/acid wax per 100 parts by weight of thermosetting resin on a conductor (directly or via another insulating layer).
~7.0 parts by weight and 0.1 to 7.0 parts by weight of an oxidative deterioration inhibitor are added and dissolved in a bath agent to form a lubricating and insulating layer by applying and baking a resin paint. It is something.

本発明において潤滑性絶縁層の形成成分として用いられ
るモンタン酸ワックスとは例えばモンタン酸エステルワ
ックス、七/タン酸エステルヮ。
The montanic acid wax used as a forming component of the lubricating insulating layer in the present invention includes, for example, montanic acid ester wax and heptatanic acid ester wax.

クスケノ化物等が、あげられる。これらのワックスは従
来のステアリン酸やドデカン酸等と比較して潰れた潤滑
性を示すものである。
Examples include kusukeno compounds. These waxes exhibit inferior lubricity compared to conventional stearic acid, dodecanoic acid, etc.

なおワックスの市販品としてはへキストワックスE1ヘ
キストワノクスoP1ヘキストワックスP(以上へキス
トノヤ・臂ン社製商品名)、BASFワックスE (B
ASF社製商品名)がある。
Commercially available wax products include Hoechst Wax E1, Hoechst Wax OP1, Hoechst Wax P (trade names manufactured by Hoechst Noya & Tsunen), and BASF Wax E (B).
There is a product name (manufactured by ASF).

而してモンタン酸ワックスの配合量を上記の如く熱硬化
性樹脂100重量部に対して0.1〜7,0重量部に限
定した理由は0.1重量部未満の場合には形成した絶縁
層に潤滑性を附与することが出来難く、又7.0重量部
を超えて配合した場合には得られる絶縁層の表面が肌荒
れし、外観を阻害するためである。
The reason for limiting the blending amount of Montan acid wax to 0.1 to 7.0 parts by weight per 100 parts by weight of the thermosetting resin as described above is that if it is less than 0.1 part by weight, the formed insulation This is because it is difficult to impart lubricity to the layer, and when more than 7.0 parts by weight is added, the surface of the resulting insulating layer becomes rough, impairing its appearance.

又酸化劣化防止剤としては、ヒンダードフェノール系酸
化劣化防止剤を使用するものであり、例えばN 、 N
’−へキサメチン/ビス(3,5−ノーを一ブチルー4
−ヒドロキシーヒドロシ7ナムアミド)、ペンタエリス
リチル−テトラキス[3−(3,5−〕−〕t−ブチル
ー4−ヒドロキシフェニルfロビオネート〕、オクタデ
シル−3−(3,5−ジ−t−ブチル−4−ヒドロキシ
フエニル)グロビオネート等があげられる。
Further, as the oxidative deterioration inhibitor, a hindered phenol-based oxidative deterioration inhibitor is used, for example, N, N.
'-hexamethine/bis(3,5-no-butyl-4
-hydroxy-hydrocinamide), pentaerythrityl-tetrakis [3-(3,5-]-]t-butyl-4-hydroxyphenyl f robionate], octadecyl-3-(3,5-di-t-butyl -4-hydroxyphenyl)globionate and the like.

なお上記の如きヒンダードフェノール系酸化劣化防止剤
の市販品としては、イルガノックス1098、イルガノ
ックス1010、イルガノックス1076(以上チバガ
イギー社製商品名)、MARK AO−23、MARK
 AO−60(以上アデカ、アーガス化学■社製商品名
)がある。
Commercial products of the hindered phenol oxidative deterioration inhibitors mentioned above include Irganox 1098, Irganox 1010, Irganox 1076 (trade names manufactured by Ciba Geigy), MARK AO-23, and MARK.
There is AO-60 (trade name manufactured by Adeka and Argus Chemical).

なおこれらのヒンダードフェノール系酸化劣化防止剤の
配合量全熱硬化性樹脂100重量部に対してO11〜7
.0重量部に限定した理由は0.1重量部以下の配合で
は得られる絶縁皮膜の潤滑性が劣り、また7、0重量部
を越えて大量に配合すると得られる絶縁皮膜の外観が著
しく悪化するためである。
The blending amount of these hindered phenolic oxidative deterioration inhibitors is O11 to 7 per 100 parts by weight of the total thermosetting resin.
.. The reason why it is limited to 0 parts by weight is that if the amount is less than 0.1 parts by weight, the resulting insulating film will have poor lubricity, and if it is added in large quantities exceeding 7.0 parts by weight, the appearance of the resulting insulating film will deteriorate significantly. It's for a reason.

本発明絶縁電線において潤滑性を附与するためには、上
記のモンタン酸系ワックスと酸化劣化防止剤の両者を併
用することにより、はじめて発揮しうるものであり、各
々単独に便用したとしても優れた潤滑性を有する絶縁’
il#J!をうることは出来ない。
In order to impart lubricity to the insulated wire of the present invention, it can only be achieved by using both the above-mentioned montanic acid wax and oxidative deterioration inhibitor in combination, and even if each is used independently. Insulation with excellent lubricity
il#J! It is not possible to obtain

又本発明において用いる熱硬化性樹脂としては特に限定
するものではなく、例えばポリエステル、ポリウレタン
、ポリイミド、ポリアミド、ポリアミドイミド、ポリエ
ステルイミド、ポリエステルアミドイミド、ポリアミド
イミ ド、Iリビニルホルマール等である。
The thermosetting resin used in the present invention is not particularly limited, and examples include polyester, polyurethane, polyimide, polyamide, polyamideimide, polyesterimide, polyesteramideimide, polyamideimide, I-rivinyl formal, and the like.

(実施例) 実施例(1) 導体径1.0龍の銅線上に、市販のポリアミドイミド樹
脂塗料(I−II−406、日立化成(社)製、商品名
)を塗布し、500℃にて焼付けを行うことを7回繰返
して被膜厚35μの絶縁層を設け、その外側に上記樹脂
塗料中の樹脂分1001蓋部に対してヘキストワックス
OPを1.0重量部及びイルガノックス1098を1゜
Off部夫々添加した樹脂塗料を塗布し500℃にで焼
付けを行って被膜厚5μの潤滑絶縁層を設けて本発明絶
縁電線をえた。
(Example) Example (1) A commercially available polyamide-imide resin paint (I-II-406, manufactured by Hitachi Chemical Co., Ltd., trade name) was applied on a copper wire with a conductor diameter of 1.0 mm, and heated to 500°C. The baking process was repeated 7 times to form an insulating layer with a thickness of 35 μm, and on the outside of the insulating layer, 1.0 part by weight of Hoechst Wax OP and 1 part of Irganox 1098 were applied to the cover portion of 1001 resin in the resin paint. The insulated wire of the present invention was obtained by applying a resin paint containing the respective additives to the off section and baking at 500° C. to form a lubricating insulating layer with a film thickness of 5 μm.

実施例(2) 導体径1. Q u+の銅線上に実施例(1)で潤滑絶
縁層の形成に用いた樹脂塗料を塗布し500℃にて焼付
けを行うことを8回繰返して被膜厚40μの潤滑絶縁層
を設けて本発明絶縁電mをえた。
Example (2) Conductor diameter 1. The resin paint used for forming the lubricating insulating layer in Example (1) was applied on the Q u+ copper wire and baking was repeated at 500°C eight times to form a lubricating insulating layer with a film thickness of 40 μm. Obtained insulation electric m.

実施例(3) 導体(l l、 91111の銅線上に、市販のポリエ
ステル樹脂塗料(E−234、日東電工■社製商品名)
を迦布し500t?:にて焼付を行うことを7回繰返し
て被膜厚さ35μの絶縁!−を形成し、その外側に、上
記樹脂塗料中の樹脂分100重量部に対してBASFワ
ックスEを4.0重量部及びイルガノックス1098を
3重量部配合した樹脂塗料を塗布し、500℃にて焼付
けを行って被膜厚さ5μの潤滑性絶縁層を形成して本発
明絶縁電線をえた。
Example (3) A commercially available polyester resin paint (E-234, trade name manufactured by Nitto Denko Corporation) was applied on the copper wire of the conductor (l l, 91111).
500 tons? : Repeat the baking process 7 times to create an insulation film with a thickness of 35μ! A resin paint containing 4.0 parts by weight of BASF wax E and 3 parts by weight of Irganox 1098 is applied to the outside of the resin paint, and heated to 500°C. Baking was performed to form a lubricating insulating layer with a film thickness of 5 μm, thereby obtaining an insulated wire of the present invention.

実施例(4) 実施例(3)において、BASFワックスの配合量を0
.5重量部、イルガノックス1098の配合量を0.5
重量部にした樹脂塗料を用いた以外はすべて実施例(3
)と同様にして本発明絶縁電線をえた。
Example (4) In Example (3), the amount of BASF wax blended was 0.
.. 5 parts by weight, the blending amount of Irganox 1098 is 0.5
All examples (3
) An insulated wire of the present invention was obtained in the same manner.

比較例(り 導体径1. Q inの銅線上に市販のポリアミドイミ
ド樹脂(HT−406)を塗布し500℃にて焼付けを
行うことを8回繰返して被膜厚さ40μの絶縁層を形成
して比較例絶縁電線をえた。
Comparative Example (A commercially available polyamide-imide resin (HT-406) was coated on a copper wire with a conductor diameter of 1.Q in, and baking at 500°C was repeated 8 times to form an insulating layer with a thickness of 40μ. A comparative insulated wire was obtained.

比較例(2) 導体fi 1.0朋の銅線上に市販のポリエステル樹脂
塗料(E−234日東電工■製)を塗布し、500℃に
て焼付けを行うことを8回繰返し被膜厚さ40μの絶縁
層を形成して比較例絶縁電線をえた。
Comparative Example (2) A commercially available polyester resin paint (E-234 manufactured by Nitto Denko ■) was applied on a copper wire with a conductor fi of 1.0, and baking was repeated 8 times at 500°C to obtain a coating thickness of 40μ. An insulating layer was formed to obtain a comparative insulated wire.

比較例(3) 導体径1. Q snの銅線上に市販のポリエステル樹
脂塗料(E−234日東電工■製)を塗布し、500℃
にて焼付けを行うことを7回繰返して被膜厚さ35μの
絶縁層を形成し、その外側に上記ポリエステル樹脂10
0重量部にBASFワックスE3.0重量部を添加した
樹脂塗料を1回塗布し、500℃にて焼付けを行って被
膜厚さ5μの潤滑絶縁J−を設けて比較例絶縁電線をえ
た。
Comparative example (3) Conductor diameter 1. A commercially available polyester resin paint (E-234 manufactured by Nitto Denko ■) was applied on the copper wire of Q sn, and heated to 500°C.
The baking process was repeated seven times to form an insulating layer with a thickness of 35 μm, and the above polyester resin 10
A comparative insulated wire was obtained by applying a resin paint containing 0 parts by weight and 3.0 parts by weight of BASF wax E and baking at 500° C. to provide a lubricating insulation J- with a film thickness of 5 μm.

比較例(4) 潤滑絶縁層形成用樹脂塗料としてポリエステル樹脂(E
−234日東電工■製)100重量部にBASFワック
スEを10.0重量部及びイルがノックス1098を1
0重量部夫々添加した樹脂塗料を用いた以外はすべて実
施例(3)と同様にして比較例絶縁電線をえた。
Comparative Example (4) Polyester resin (E
-234 Nitto Denko ■) 100 parts by weight, 10.0 parts by weight of BASF wax E and 1 part by weight of NOX 1098.
Comparative insulated wires were obtained in the same manner as in Example (3) except that the resin paints each contained 0 parts by weight.

斯くしてえた本発明自己潤滑性絶縁電線及び比較例絶縁
電線とについて静電摩擦係数及び耐摩耗性を測定した。
The electrostatic friction coefficient and wear resistance of the self-lubricating insulated wire of the present invention and the comparative insulated wire thus obtained were measured.

その結果は第1表に示す通9である。The results are shown in Table 1.

(発明の効果) 以上詳述した如く本発明絶縁電線静摩擦係数が小さく、
高い耐摩耗性を保持しているなど自己潤滑性に優れてい
るため高速にてコイル巻きを行うも絶縁皮膜に同等損傷
を及ぼすことなく作業を行うことが出来るため者しく作
業性が向上する等工業上極めて有用である。
(Effects of the invention) As detailed above, the insulated wire of the present invention has a small coefficient of static friction,
It maintains high wear resistance and has excellent self-lubricating properties, so even when winding coils at high speeds, the work can be done without causing the same damage to the insulation film, which significantly improves work efficiency. It is extremely useful industrially.

Claims (1)

【特許請求の範囲】[Claims]  導体上に直接又は他の絶縁物層を介して熱硬化性樹脂
100重量部に対してモンタン酸ワックス0.1〜7.
0重量部及び酸化劣化防止剤0.1〜7.0重量部を添
加しこれを溶剤で溶解してなる樹脂塗料の塗布焼付けに
よる潤滑絶縁層を形成したことを特徴とする自己潤滑性
絶縁電線。
0.1 to 7.0 parts of montan acid wax per 100 parts by weight of thermosetting resin directly on the conductor or via another insulating layer.
A self-lubricating insulated wire characterized in that a lubricating insulating layer is formed by applying and baking a resin paint containing 0 parts by weight and 0.1 to 7.0 parts by weight of an oxidative deterioration inhibitor and dissolved in a solvent. .
JP13644788A 1988-06-02 1988-06-02 Self-lubricating insulated wire Pending JPH01307110A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13644788A JPH01307110A (en) 1988-06-02 1988-06-02 Self-lubricating insulated wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13644788A JPH01307110A (en) 1988-06-02 1988-06-02 Self-lubricating insulated wire

Publications (1)

Publication Number Publication Date
JPH01307110A true JPH01307110A (en) 1989-12-12

Family

ID=15175325

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13644788A Pending JPH01307110A (en) 1988-06-02 1988-06-02 Self-lubricating insulated wire

Country Status (1)

Country Link
JP (1) JPH01307110A (en)

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US6005037A (en) * 1994-10-31 1999-12-21 Hoechst Ag Molding material for processing sinterable polymers
WO2008004526A1 (en) * 2006-07-07 2008-01-10 The Furukawa Electric Co., Ltd. Insulated electric wire
EP1899987A4 (en) * 2005-05-24 2009-12-16 Southwire Co Electrical cable having a surface with reduced coefficient of friction
US7749024B2 (en) 2004-09-28 2010-07-06 Southwire Company Method of manufacturing THHN electrical cable, and resulting product, with reduced required installation pulling force
US8986586B2 (en) 2009-03-18 2015-03-24 Southwire Company, Llc Electrical cable having crosslinked insulation with internal pulling lubricant
US9200234B1 (en) 2009-10-21 2015-12-01 Encore Wire Corporation System, composition and method of application of same for reducing the coefficient of friction and required pulling force during installation of wire or cable
US9352371B1 (en) 2012-02-13 2016-05-31 Encore Wire Corporation Method of manufacture of electrical wire and cable having a reduced coefficient of friction and required pulling force
US9431152B2 (en) 2004-09-28 2016-08-30 Southwire Company, Llc Method of manufacturing electrical cable, and resulting product, with reduced required installation pulling force
US9864381B2 (en) 2007-02-15 2018-01-09 Southwire Company, Llc Integrated systems facilitating wire and cable installations
US10056742B1 (en) 2013-03-15 2018-08-21 Encore Wire Corporation System, method and apparatus for spray-on application of a wire pulling lubricant
CN109836867A (en) * 2019-01-22 2019-06-04 安徽唯楚新材料有限公司 A kind of building curtain wall aluminum veneer antioxidant coating and preparation method thereof
US10325696B2 (en) 2010-06-02 2019-06-18 Southwire Company, Llc Flexible cable with structurally enhanced conductors
US10431350B1 (en) 2015-02-12 2019-10-01 Southwire Company, Llc Non-circular electrical cable having a reduced pulling force
US11328843B1 (en) 2012-09-10 2022-05-10 Encore Wire Corporation Method of manufacture of electrical wire and cable having a reduced coefficient of friction and required pulling force

Cited By (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6005037A (en) * 1994-10-31 1999-12-21 Hoechst Ag Molding material for processing sinterable polymers
US7749024B2 (en) 2004-09-28 2010-07-06 Southwire Company Method of manufacturing THHN electrical cable, and resulting product, with reduced required installation pulling force
US11011285B2 (en) 2004-09-28 2021-05-18 Southwire Company, Llc Method of manufacturing electrical cable, and resulting product, with reduced required installation pulling force
US11776715B2 (en) 2004-09-28 2023-10-03 Southwire Company, Llc Method of manufacturing electrical cable, and resulting product, with reduced required installation pulling force
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