JPH01296933A - Liquid-absorbing wick - Google Patents
Liquid-absorbing wickInfo
- Publication number
- JPH01296933A JPH01296933A JP8506289A JP8506289A JPH01296933A JP H01296933 A JPH01296933 A JP H01296933A JP 8506289 A JP8506289 A JP 8506289A JP 8506289 A JP8506289 A JP 8506289A JP H01296933 A JPH01296933 A JP H01296933A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- wick
- hereinafter referred
- absorbing
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 238000004513 sizing Methods 0.000 claims abstract description 7
- 239000004927 clay Substances 0.000 claims abstract description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 5
- 229920002472 Starch Polymers 0.000 claims abstract description 5
- 239000008107 starch Substances 0.000 claims abstract description 5
- 235000019698 starch Nutrition 0.000 claims abstract description 5
- 239000004375 Dextrin Substances 0.000 claims abstract description 4
- 229920001353 Dextrin Polymers 0.000 claims abstract description 4
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 4
- 241000978776 Senegalia senegal Species 0.000 claims abstract description 4
- 239000000205 acacia gum Substances 0.000 claims abstract description 4
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 4
- 239000000440 bentonite Substances 0.000 claims abstract description 4
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 4
- 235000019425 dextrin Nutrition 0.000 claims abstract description 4
- 239000010451 perlite Substances 0.000 claims abstract description 4
- 235000019362 perlite Nutrition 0.000 claims abstract description 4
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 3
- 239000005909 Kieselgur Substances 0.000 claims abstract description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 3
- 239000010425 asbestos Substances 0.000 claims abstract description 3
- 239000003365 glass fiber Substances 0.000 claims abstract description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 3
- 239000000454 talc Substances 0.000 claims abstract description 3
- 229910052623 talc Inorganic materials 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 27
- 239000002250 absorbent Substances 0.000 claims description 13
- 230000002745 absorbent Effects 0.000 claims description 13
- 239000002917 insecticide Substances 0.000 abstract description 31
- 230000000749 insecticidal effect Effects 0.000 abstract description 15
- 230000005068 transpiration Effects 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 31
- 239000011162 core material Substances 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 10
- 238000001704 evaporation Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 230000008020 evaporation Effects 0.000 description 6
- 235000013312 flour Nutrition 0.000 description 6
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 5
- -1 Pent-2-en-4-one-1-yl Chemical group 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000002023 wood Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003623 enhancer Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- MRBKEAMVRSLQPH-UHFFFAOYSA-N 3-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1 MRBKEAMVRSLQPH-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002459 sustained effect Effects 0.000 description 2
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- YATDSXRLIUJOQN-SVRRBLITSA-N (2,3,4,5,6-pentafluorophenyl)methyl (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=C(F)C(F)=C1F YATDSXRLIUJOQN-SVRRBLITSA-N 0.000 description 1
- RXCIUYPJOWHUBQ-UHFFFAOYSA-N (4-chloro-2-propan-2-ylphenyl) acetate Chemical compound CC(C)C1=CC(Cl)=CC=C1OC(C)=O RXCIUYPJOWHUBQ-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N (R)-alpha-Tocopherol Natural products OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- IMOYOUMVYICGCA-UHFFFAOYSA-N 2-tert-butyl-4-hydroxyanisole Chemical compound COC1=CC=C(O)C=C1C(C)(C)C IMOYOUMVYICGCA-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
- FCDMUZZVRLCTLQ-UHFFFAOYSA-N 4-[1,1-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C FCDMUZZVRLCTLQ-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- FSYXMFXBRJFYBS-UHFFFAOYSA-N Furamethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(CC#C)O1 FSYXMFXBRJFYBS-UHFFFAOYSA-N 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 229930003633 citronellal Natural products 0.000 description 1
- 235000000983 citronellal Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 235000019258 dehydroacetic acid Nutrition 0.000 description 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 1
- 229940061632 dehydroacetic acid Drugs 0.000 description 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- USPVNSDVCUTNJN-UHFFFAOYSA-N ethenyl cyclopropanecarboxylate Chemical compound C=COC(=O)C1CC1 USPVNSDVCUTNJN-UHFFFAOYSA-N 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229950006668 fenfluthrin Drugs 0.000 description 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- WLLGXSLBOPFWQV-OTHKPKEBSA-N molport-035-783-878 Chemical compound C([C@H]1C=C2)[C@H]2C2C1C(=O)N(CC(CC)CCCC)C2=O WLLGXSLBOPFWQV-OTHKPKEBSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- IZJDOKYDEWTZSO-UHFFFAOYSA-N phenethyl isothiocyanate Chemical compound S=C=NCCC1=CC=CC=C1 IZJDOKYDEWTZSO-UHFFFAOYSA-N 0.000 description 1
- SBNFWQZLDJGRLK-UHFFFAOYSA-N phenothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は吸液芯、更に詳しくは殺虫等を目的とする吸上
式加熱蒸散型装置に用いられる吸液芯に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a liquid-absorbing wick, and more particularly to a liquid-absorbing wick used in a suction-type heating transpiration type device for the purpose of killing insects.
従来技術とその問題点
従来より殺虫等の目的で薬剤を加熱蒸散させる方法とし
ては電気蚊取器に代表されるような装置を用いて繊維板
等の多孔質基材（固型マット）に吸着させた殺虫剤を加
熱して蒸散させる方法が汎用されている。しかしながら
該方法では一枚の固型マットに含浸させ得る殺虫剤口は
自づと制限を受け、該マットの取替え及び使用済マット
の廃棄が必須である。しかもマットに吸着させた殺虫剤
の揮散率は経時的に低下していく重大な欠点があるに加
え、マットに吸着させた殺虫剤の有効揮散率はたかだか
約５０％にすぎず、該マットの殺虫剤残存率が１０％程
度にもおよび、長時間に亘る安定した殺虫効果を持続さ
せ得ず、経済的にも尚かなりの不利を伴う。Conventional technology and its problems Traditionally, the method of heating and evaporating chemicals for the purpose of killing insects, etc. is to adsorb them onto a porous substrate (solid mat) such as fiberboard using a device such as an electric mosquito repellent. A commonly used method is to evaporate the insecticide by heating it. However, in this method, the number of insecticide ports that can be impregnated into one solid mat is naturally limited, and it is necessary to replace the mat and dispose of the used mat. Moreover, the volatilization rate of the insecticide adsorbed on the mat decreases over time, which is a serious drawback.In addition, the effective volatilization rate of the insecticide adsorbed on the mat is only about 50%; The insecticide residual rate is as high as about 10%, making it impossible to maintain a stable insecticidal effect over a long period of time, and resulting in considerable economic disadvantage.
上記固型マット使用に見られるマット取替えの問題及び
短時間内に殺虫効果が消失する欠点を解消し、長期に亘
り殺虫効果を持続させ得る加熱蒸散方法として、殺虫剤
を溶液形態で吸上芯（吸液芯）により吸上げつつこれを
加熱蒸散させる方法が考えられ、事実このような吸液芯
利用による殺虫剤蒸散装置が種々提案されている。これ
ら装置は適当な容器に殺虫剤の溶剤溶液を入れ、これを
フェルト等の吸液芯を利用して吸上げつつ該吸液芯上部
より加熱蒸散させるべくしたものである。As a heating evaporation method that can maintain the insecticidal effect over a long period of time, it solves the problem of replacing the mat and the disadvantage that the insecticidal effect disappears within a short period of time when using the solid mat. A method of heating and evaporating the insecticide while sucking it up with a liquid-absorbing wick has been considered, and in fact, various insecticide evaporation devices using such a liquid-absorbing wick have been proposed. In these devices, a solvent solution of an insecticide is placed in a suitable container, which is sucked up using a liquid-absorbing wick made of felt, etc., and heated and evaporated from the upper part of the liquid-absorbing wick.
しかしながらかかる吸上式加熱蒸散型装置は、実際にこ
れを用いた場合、いずれも吸液芯の加熱によって殺虫剤
液を構成する溶剤が速やかに揮散し、該芯内部で殺虫剤
液が次第に濃縮され、樹脂化したり、芯材が燻焼したり
して、目づまりを起し引続く殺虫液の吸上げ及び蒸散を
不能とし、長期に亘る持続効果は発揮できず、しかも殺
虫効果の経時的低下を避は得ず、更に有効揮散率が低く
残ひ率が高いものであった。このような吸上芯利用によ
る加熱蒸散方法に見られる各種の弊害の生ずる原因とし
ては、芯の種類及び溶剤の種類は勿論のこと、殺虫剤の
種類、ａ変、加熱条件等の多数が考えられ、上記弊害を
解消することは困難であると考えられた。However, when such suction heating evaporation type devices are actually used, the solvent constituting the insecticide liquid quickly evaporates due to the heating of the liquid absorption wick, and the insecticide liquid gradually becomes concentrated inside the wick. The insecticide may become resinous or the core material may be smoldered, causing clogging and making it impossible for the insecticidal solution to be absorbed and evaporated, making it impossible to achieve a long-term sustained effect, and furthermore, the insecticidal effect decreases over time. In addition, the effective volatilization rate was low and the residual rate was high. The causes of various adverse effects seen in such heating evaporation methods using wicks include not only the type of wick and the type of solvent, but also the type of insecticide, a-type change, heating conditions, etc. It was thought that it would be difficult to eliminate the above-mentioned disadvantages.
本発明は吸上式加熱蒸散型装置に適した吸液芯を提供す
ることを目的とする。An object of the present invention is to provide a liquid absorbent core suitable for a wicking type heating evaporation type device.
本発明はまた上記装置に利用して、目づまり等を回避し
、長期に亘る持続効果を奏し得、しかも殺虫剤総揮散量
及び有効揮散率の向上を計り得る改良された吸液芯を提
供することを目的とする。The present invention also provides an improved liquid-absorbing wick that can be used in the above-mentioned device to avoid clogging, etc., to achieve a long-lasting effect, and to improve the total amount of pesticide volatilization and effective volatilization rate. The purpose is to
問題点を解決するための手段
本発明は無機粉体をカルボキシメチルセルロース、デキ
ストリン、デンプン、アラビアゴムより選ばれる少なく
とも１種の糊剤で粘結させてなる吸液芯に係る。Means for Solving the Problems The present invention relates to a liquid-absorbing core made by caking inorganic powder with at least one type of sizing agent selected from carboxymethyl cellulose, dextrin, starch, and gum arabic.
本発明の吸液芯は、吸」二式加熱蒸散型装置に利用して
、目づまりを惹起せず、長寿命化を可能とすると共に、
これに基づき殺虫剤の蒸散性（揮散量及び有効揮散率）
を顕著に向上させ、長期間に負り優れた殺虫効果を持続
発揮させ得る。The liquid absorbent wick of the present invention can be used in a two-type heating evaporation device to prevent clogging and extend the service life.
Based on this, the transpiration property (volatilization amount and effective volatilization rate) of pesticides
It can significantly improve the insecticidal effect and maintain its excellent insecticidal effect over a long period of time.
本発明において殺虫剤としては、従来より害虫駆除に用
いられる各種薬剤をいずれも使用できる。As the insecticide in the present invention, any of the various chemicals conventionally used for exterminating pests can be used.
該薬剤には各種のピレスロイド系殺虫剤、カーバメイト
系殺虫剤、有機リン系殺虫剤等が包含される。それらの
具体例としては以下のものを例示できる。The drugs include various pyrethroid insecticides, carbamate insecticides, organophosphorus insecticides, and the like. Specific examples thereof include the following.
０３−アリル−２−メチルシクロペンター２−エン−４
−オン−１−イル ｄＱ−シス／トランスークリサンテ
マート（一般名アレスリン：商品名ピナミン：住友化学
工業株式会社製、以下ＡＡという）
０３−アリル−２−メチルシクロペンタ−２−エン−４
−オン−１−イル ｄ−シス／トランスークリサンテマ
ート（商品名ピナミンフォルテ：住友化学工業株式会社
製、以下ＡＢという）Ｏｄ−３−アリル−２−メチルシ
クロペンタ−２−ニンー４−オン−１−イル ｄ−トラ
ンスークリサンテマート（商品名エキスリン：住友化学
工業株式会社製、以下ＡＣという）
Ｏ３−アリル−２−メチルシクロペンタ−２−エン−４
−オン−１−イル ｄ−ｈランスークリサンテマート（
一般名パイオアレスリン、以下ＡＤという）
ｏＮ−（３，４，５，６−チトラヒドロフタリミド）−
、メチル ｄＱ−シス／トランスークリサンテマート（
−船名フタルスリン：商品名ネオピナミン：住友化学工
業株式会社製、以下ＡＥという）
０２−メチル−４−オキソ−３−（２−プロピニル）シ
クロベント−２−エニルークリサンテマート
ｏ （Ｓ）−２−メチル−４−オキソ−３−（２−プロ
ピニル）シクロベント−２−エニル（ＩＲ）−シス／ト
ランスークリサンテマート（−船名プラレトリン：特公
昭５２−４５７６８号公報参照）
０５−ベンジル−３−フリルメチル ｄ−シス／トラン
スークリサンテマート（−船名レスメトリン：商品名り
リスロンフォルテ：住友化学工業株式会社製、以下ＡＰ
という）
０５−（２−プロパルギル）−３−フリルメチルクリサ
ンテマート（−船名フラメトリン、以下ＡＧという）
０３−フェノキシベンジル ２，２−ジメチル−３−（
２’ 、２’−ジクロロ）ビニルシクロプロパン カル
ボキシレート（−船名ベルメトリン：商品名エクスミン
：住友化学工業株式会社製、以下ＡＨという）
０３−フェノキシベンジル ｄ−シス／トランスークリ
サンテマート（−船名フエツトリン：商品名スミスリン
：住友化学工業株式会社製、以下ＡＩという）
Ｏα−シアノフェノキシベンジル イソプロピル−４−
クロロフェニルアセテート（−船名フエンバレレート：
商品名スミサイジン：住友化学工業株式会社製、以下Ａ
Ｊという）
０ （Ｓ）−α−シアノ−３−フェノキシベンジル（Ｉ
Ｒ，シス）−３−（２，２−ジクロロビニル）−２，２
−ジメチルシクロプロパンカルボキシレート（以下ＡＬ
という）
０ （Ｒ，Ｓ）−α−シアノ−３−フェノキシベンジル
（ＩＲ，ｌ５）−シス／トランス−３−（２，２−ジ
クロロビニル）−２，２−ジメチルシクロプロパンカル
ボキシレート（以下ＡＭという）
Ｏα−シアノ−３−フェノキシベンジル ｄ−シス／ト
ランスークリサンテマート（以下ＡＮという）
０１−エチニル−２−メチル−２−ペンテニルシス／ト
ランスークリサンテマート（以下ＡＯという）
０１−エチニル−２−メチル−２−ペンテニル２．２−
ジメチル−３−（２−メチル−１−プロペニル）シクロ
プロパン−１−カルボキシレート（以下ＡＰという）
ｏｌ−エチニル−２−メチル−２−ペンテニル２．２．
３．３−テトラメチルシクロプロパンカルボキシレート
（以下ＡＱという）
ｏｌ−エチニル−２−メチル−２−ペンテニル２．２−
ジメチル−３−（２，２−ジクロロビニル）シクロプロ
ピン−１−カルボキシレート（以下ＡＲという）
０ ［（Ｒ，Ｓ’）−α−シアノ−３−フェノキシベン
ジル）−（Ｒ）−２−［２−クロロ−４−（トリフルオ
ロメチル）アニリノツー３−メチル−ブタノエート（−
船名フルバリネート）ＯＯｌｏ−ジメチル ０− （２
，２−ジクロロ）ビニルホスフェート（以下ＡＳという
）ＯＱ−イソプロポキシフェニル メチルカーバメート
（以下ＡＴという）
ＯＯｌｏ−ジメチル ０−（３−メチル−４−二トロフ
ェニル）チオノフォスフェ−１・（以下ＡＵという）
００．０−ジエチル ０−２−イソプロピル−４−メチ
ル−ピリミジル−（６）−チオフォスフェート
ｏＯｌｏ−ジメチル Ｓ−（１，２−ジカルボエトキシ
エチル）−ジオチフオスフェート０３−アリル−２−メ
チルシクロペンタ−２−エン−４−オン−１−イル ２
．２，３．３−テトラメチルシクロプロパンカルボキシ
レート（−船名テラレトリン）
Ｏ〔（ペンタフルオロフェニル）−メチル〕−ＩＲ，３
Ｒ−３−（２，２−ジクロロエチニル）−２，２−ジメ
チル−シクロプロパンカルボキシレート（−船名フエン
フルスリン）
０２−（４−エトキシフェニル）−２−メチルプロピル
３−フェノキシベンジルエーテル（−船名工トフエン
ブロックス）
上記殺虫剤には、通常用いられている効力増強剤、揮散
率向」二剤、消臭剤、香料等の各種添加剤を任意に添加
することができる。効力増強剤としては、ビペロニルブ
トキサイド、Ｎ−プロビルイゾーム、ＭＧＫ−２６４、
サイネビリン２２２、勺イネピリン５００、リーセン３
８４、Ｉ ＢＴＡ。03-allyl-2-methylcyclopent-2-ene-4
-on-1-yl dQ-cis/trans-chrysanthemate (generic name allethrin; trade name pinamine; manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AA) 03-allyl-2-methylcyclopent-2-ene-4
-on-1-yl d-cis/trans-chrysanthemate (trade name: Pinamine Forte, manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AB) Od-3-allyl-2-methylcyclopent-2-nin-4- O3-allyl-2-methylcyclopent-2-ene-4
-on-1-yl dh lansu chrysanthemate (
oN-(3,4,5,6-titrahydrophthalimide)-
, methyl dQ-cis/trans-chrysanthemate (
- Ship name Phthalthrin: Trade name Neopinamine: Manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AE) 02-Methyl-4-oxo-3-(2-propynyl)cyclobent-2-enyl chrysanthemate o (S)-2- 05-Benzyl-3- Furylmethyl d-cis/trans-chrysantemate (-Ship name: Resmethrin: Product name: Lithronforte: Manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AP
05-(2-propargyl)-3-furylmethylchrysanthemate (-Ship name: Furamethrin, hereinafter referred to as AG) 03-phenoxybenzyl 2,2-dimethyl-3-(
2',2'-dichloro)vinylcyclopropane carboxylate (-ship name Vermethrin; trade name Exmin: manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AH) 03-phenoxybenzyl d-cis/trans-crisantemate (-ship Fetuthrin: Trade name Sumitrin: Manufactured by Sumitomo Chemical Co., Ltd., hereinafter referred to as AI) Oα-cyanophenoxybenzyl isopropyl-4-
Chlorophenyl acetate (-Ship name Fuenvalerate:
Product name Sumicidin: Manufactured by Sumitomo Chemical Co., Ltd., hereinafter A
0 (S)-α-cyano-3-phenoxybenzyl (I
R, cis)-3-(2,2-dichlorovinyl)-2,2
-dimethylcyclopropanecarboxylate (hereinafter AL
0 (R,S)-α-cyano-3-phenoxybenzyl (IR,l5)-cis/trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as AM Oα-cyano-3-phenoxybenzyl d-cis/trans-chrysanthemate (hereinafter referred to as AN) 01-ethynyl-2-methyl-2-pentenyl cis/trans-chrysanthemate (hereinafter referred to as AO) 01-ethynyl -2-methyl-2-pentenyl 2.2-
Dimethyl-3-(2-methyl-1-propenyl)cyclopropane-1-carboxylate (hereinafter referred to as AP) ol-ethynyl-2-methyl-2-pentenyl 2.2.
3.3-Tetramethylcyclopropanecarboxylate (hereinafter referred to as AQ) ol-ethynyl-2-methyl-2-pentenyl 2.2-
Dimethyl-3-(2,2-dichlorovinyl)cyclopropyne-1-carboxylate (hereinafter referred to as AR) 0 [(R,S')-α-cyano-3-phenoxybenzyl)-(R)-2-[2 -Chloro-4-(trifluoromethyl)anilino-3-methyl-butanoate (-
Ship name Fluvalinate) OOlo-dimethyl 0- (2
,2-dichloro)vinyl phosphate (hereinafter referred to as AS) OQ-isopropoxyphenyl methyl carbamate (hereinafter referred to as AT) OOlo-dimethyl 0-(3-methyl-4-nitrophenyl)thionophosphate-1 (hereinafter referred to as AU) 00 .0-diethyl 0-2-isopropyl-4-methyl-pyrimidyl-(6)-thiophosphate oOlo-dimethyl S-(1,2-dicarboethoxyethyl)-diotyphosphate 03-allyl-2-methylcyclo Pent-2-en-4-one-1-yl 2
．． 2,3.3-Tetramethylcyclopropanecarboxylate (-ship name telarethrin) O[(pentafluorophenyl)-methyl]-IR, 3
R-3-(2,2-dichloroethynyl)-2,2-dimethyl-cyclopropanecarboxylate (-ship name fenfluthrin) 02-(4-ethoxyphenyl)-2-methylpropyl 3-phenoxybenzyl ether ( - Funako Tofuenbrox) Various commonly used additives such as efficacy enhancers, volatilization rate enhancers, deodorants, fragrances, etc. can be optionally added to the above insecticides. Potency enhancers include biperonyl butoxide, N-probylisome, MGK-264,
Cynevirin 222, Tsugoinepirin 500, Reisen 3
84, I BTA.
Ｓ−４２１等を、揮散率向上剤どしてはフェネチルイソ
チオシアネート、パイミックス酸ジメチル等を、消臭剤
としてはラウリル酸メタクリレ−１・（ＬＭＡ）等を、
香料としてはシトラール、シトロネラール等を夫々例示
できる。S-421, etc., volatilization rate improvers such as phenethyl isothiocyanate, dimethyl pymixate, etc., deodorants such as methacrylate-1 lauryl acid (LMA), etc.
Examples of fragrances include citral and citronellal.
上記殺虫剤は溶液形態に調製される。該殺虫剤溶液を調
製するための溶剤としては、各種の有機溶剤、代表的に
は炭化水素系溶剤をいずれも使用できるが、特に沸点範
囲が１５０〜３５０℃の脂肪族系炭化水素（パラフィン
系炭化水素及び不飽和脂肪族炭化水素）は好ましく、上
記沸点範囲のｎ−パラフィン中には炭素数１０〜１８の
ものが包含される［Ｄｉｅｔｉｏｎａｒｙ ｏｆ Ｏｒ
ｇａｎｉｅ Ｃｏｍｐｏｕｎｄｓ。The above insecticides are prepared in solution form. As the solvent for preparing the insecticide solution, various organic solvents, typically hydrocarbon solvents, can be used, but in particular aliphatic hydrocarbons (paraffinic solvents) with a boiling point range of 150 to 350°C Hydrocarbons and unsaturated aliphatic hydrocarbons) are preferred, and the n-paraffins having the boiling point range above include those having 10 to 18 carbon atoms.
ganie compounds.
５ｔｈ ｅｄ、１９８２年参照］。之等のうちで特にｎ
−パラフィン、イソパラフィン等は、実用−ヒ毒性がな
く、臭いがなくしかも火災の危険も極めて少ない点にお
いて好適である。上記炭化水素系以外の有機溶剤として
は、例えばグリセリン、プロピレングリコール、メタノ
ール、イソプロパツール、１−オクタツール、１−ドデ
カノール等のアルコール類、アセトン、アセトフェノン
等のケトン類、ジヘキシルエーテル、ジエチレングリコ
ールジエチルエーテル等のエーテル類、アジピン酸ジオ
クチル、マロン酸ジエチル、フタル酸ジエチル等のエス
テル類、キシレン、クロルセン、クロロホルム、シリコ
ーンオイル等を例示できる。5th ed, 1982]. Among these, especially n
- Paraffin, isoparaffin, etc. are suitable for practical use because they are non-toxic, odorless, and pose a very low risk of fire. Examples of organic solvents other than the above hydrocarbons include alcohols such as glycerin, propylene glycol, methanol, isopropanol, 1-octatool, and 1-dodecanol, ketones such as acetone and acetophenone, dihexyl ether, and diethylene glycol diethyl ether. Examples include ethers such as dioctyl adipate, diethyl malonate, and diethyl phthalate, xylene, chlorcene, chloroform, and silicone oil.
Ｌ記殺虫剤の溶剤溶液は、用いるべき殺虫剤の種類に応
じて適宜決定でき特に限定されるものではないが、通常
殺虫剤濃度が約１〜１０重量％、好ましくは３〜８重量
％となるように調製されるのがよい。The solvent solution of the L insecticide can be determined as appropriate depending on the type of insecticide to be used and is not particularly limited, but it usually has an insecticide concentration of about 1 to 10% by weight, preferably 3 to 8% by weight. It is best to prepare it so that
上記殺虫剤の釘機溶媒溶液中には、以下の化合物群から
選ばれた少なくとも１種を添加配合されるのが好ましい
。At least one compound selected from the following compound group is preferably added to the nail machine solvent solution of the above insecticide.
３．５−ジ−ｔ−ブチル−４−ヒドロキシトルエン（以
下ＣＡという）
３−ｔ−ブチル−４−ヒドロキシアニソール（以下ＣＢ
という）
３．５−ジ−ｔ−ブチル−４−ヒドロキシアニソール（
以下ＣＣという）
メルカプトベンズイミダソール（以下ＣＤという）ジラ
ウリル−チオ−ジ−プロピオネート（以下ＣＥという）
２．２′ −メチレン−ビス−（６−ｔ−ブチル−４−
メチルフェノール）（以下ＣＦという）２．２′−メチ
レン−ビス−（Ｃ，−ｔ−ブチル−４−エチルフェノー
ル）（以下ＣＧという）４．４′−メチレン−ビス−（
２，６−ジーを一ブチルフェノール）（以下ＣＩという
）４．４′ −ブチリデン−ビス−（６−ｔ−ブチル−
３−メチルフェノール）（以下ＣＩという）４．４’−
−チオ−ビス−（６−ｔ−ブチル−３−メチルフェノー
ル）（以下ＣＪという）１、〕−〕ビスー４−ヒドロキ
シフェニル）シクロへ１サン（以下Ｃ１〜という）
１．３．５−トリメチル−２，４，６−トリス（３，５
−ジ−ｔ−ブチル−４−ヒドロキシベンジル）ベンゼン
（以下ＣＬという）
トリス（２−メチル−４−ヒドロキシ−５−ｔ−ブチル
フェニル）ブタン（以下ＣＭという）テトラキス［メチ
レン（３，５−ジ−ｔ−ブチル−４−ヒドロキシヒドロ
シンナメーｉ−：Ｎ メタン（以下ＣＮという）
オクタデシル−３，５−ジ−ｔ−ブチル−４−ヒドロキ
シヒドロシンナメート（以下Ｃｏという）フェニル−β
−ナフチルアミン（以下ＣＰという）Ｎ、Ｎ’ −ジフ
ェニル−ｐ−フェニレンジアミン（以下ＣＱという）
２．２．４−）リフチル−１，３−ジヒドロキノリンポ
リマー（以下ＣＲという）
６−ニトキシー２．２．４−トリメチル−１，３−ジヒ
ドロキノリン（以下Ｃ８という）２−ｔ−ブチル−４−
メトキシフェノール（以下Ｃ・Ｔという）
３−ｔ−ブチル−４−メトキシフェノール（以下ＣＵと
いう）
２．６−ジーｔ−ブチル−４−エチルフェノール（以下
Ｃｖという）
ステアリル−β−（３，５−ジ−ｔ−ブチル−４−ヒド
ロキシフェニル）プロピオネート（以下ＣＷという）
α−トコフェロール（以下ＣＸという）アスコルビン酸
（以下ＣＹという）及びエリソルビン酸（以下ＣＺとい
う）。3.5-di-t-butyl-4-hydroxytoluene (hereinafter referred to as CA) 3-t-butyl-4-hydroxyanisole (hereinafter referred to as CB)
) 3.5-di-t-butyl-4-hydroxyanisole (
Mercaptobenzimidazole (hereinafter referred to as CD) dilauryl-thio-di-propionate (hereinafter referred to as CE) 2.2'-methylene-bis-(6-t-butyl-4-
methylphenol) (hereinafter referred to as CF) 2.2'-methylene-bis-(C,-t-butyl-4-ethylphenol) (hereinafter referred to as CG) 4.4'-methylene-bis-(
2,6-di-butylphenol) (hereinafter referred to as CI)4.4'-butylidene-bis-(6-t-butyl-
3-methylphenol) (hereinafter referred to as CI) 4.4'-
-thio-bis-(6-t-butyl-3-methylphenol) (hereinafter referred to as CJ) 1,]-]bis-4-hydroxyphenyl)cyclohe1san (hereinafter referred to as C1~) 1.3.5-trimethyl -2,4,6-tris(3,5
-di-t-butyl-4-hydroxybenzyl)benzene (hereinafter referred to as CL) Tris(2-methyl-4-hydroxy-5-t-butylphenyl)butane (hereinafter referred to as CM) Tetrakis[methylene(3,5-di -t-Butyl-4-hydroxyhydrocinnamate i-:N Methane (hereinafter referred to as CN) Octadecyl-3,5-di-t-butyl-4-hydroxyhydrocinnamate (hereinafter referred to as Co) Phenyl-β
-Naphthylamine (hereinafter referred to as CP) N,N'-diphenyl-p-phenylenediamine (hereinafter referred to as CQ) 2.2.4-) Riftyl-1,3-dihydroquinoline polymer (hereinafter referred to as CR) 6-Nitoxy 2.2 .4-trimethyl-1,3-dihydroquinoline (hereinafter referred to as C8) 2-t-butyl-4-
Methoxyphenol (hereinafter referred to as C/T) 3-t-butyl-4-methoxyphenol (hereinafter referred to as CU) 2.6-di-t-butyl-4-ethylphenol (hereinafter referred to as Cv) Stearyl-β-(3,5 -di-t-butyl-4-hydroxyphenyl) propionate (hereinafter referred to as CW) α-tocopherol (hereinafter referred to as CX) ascorbic acid (hereinafter referred to as CY) and erythorbic acid (hereinafter referred to as CZ).
上記化合物ＣＡ−ＣＺは、１種単独でも２種以上併用し
てもよく、その使用量は得られる吸液芯用殺虫液組成物
中に約１．０重量％以下となる量、通常的０．２〜１．
０重量％、好ましくは０．３〜０．９重量％含有される
量とするのがよく、その配合によれば、本発明所期の吸
液芯の目づまり防止効果がより一層確実なものとなり、
長期に亘る持続的殺虫効果が奏される。The above compound CA-CZ may be used alone or in combination of two or more, and the amount used is about 1.0% by weight or less in the resulting insecticidal liquid composition for liquid absorbent cores, and the amount used is usually 0. .2-1.
The content is preferably 0% by weight, preferably 0.3 to 0.9% by weight, and according to this formulation, the effect of preventing clogging of the liquid absorbent wick as expected in the present invention is even more reliable. Then,
It has a long-lasting insecticidal effect.
本発明の吸液芯は、無機粉体を糊剤で粘結させてなる無
機質多孔質成型芯であり、その具体例としては磁器多孔
質、グラスファイバー、石綿等の無機繊維を石膏やベン
トナイ！・等の結合剤で固めたものや、カオリン、活性
白土、タルク、ケイソウ土、クレー、パーライト、ベン
トナイト、アルミナ、シリカ、アルミナシリカ、チタニ
ウム、ガラス質火山岩焼成粉末、ガラス質火山灰焼成粉
末等の鉱物質粉末を単独で又は木粉、戻粉、活性炭等と
共に、デキストリン、デンプン、アラビアゴム、合成糊
カルボキシメチルセルロース（ＣＭＣ）等の糊剤で固め
たものを例示できる。特に好ましい吸液芯は、上記鉱物
質粉末単独或いはその１００重量部と木粉もしくは該木
粉に等重量までの戻粉及び／又は活性炭を混合した混合
物１０〜３００重量部とに、糊剤を全吸液芯重量の５〜
２５重量％となるまで配合し、更にこれらに水を加えて
練合後、押出成型し乾燥することにより製造される。該
吸液芯は吸液速度が１〜４０時間、好ましくは８〜２１
時間であるのが望ましい。この吸液速度とは、液温２５
℃のｎ−パラフィン液中に直径７ｍｍＸ長さ７０ｍｍの
吸液芯をその下部より１５ａｕｎまで浸漬し、恋煩にｎ
−パラフィンが達するまでの時間を測定することにより
求められた値を意味する。また上記吸液芯中には、上記
鉱物質粉末、木粉及び糊剤の他更に必要に応じてマカラ
イトグリーン等の色素、ソルビン酸及びその塩類、デヒ
ドロ酢酸等のカビ止め剤等をも配合できる。The liquid absorbent core of the present invention is an inorganic porous molded core made by binding inorganic powder with a sizing agent. Specific examples thereof include porous porcelain, glass fiber, asbestos, and other inorganic fibers such as gypsum, bentonite, etc. - Those hardened with binders such as kaolin, activated clay, talc, diatomaceous earth, clay, perlite, bentonite, alumina, silica, alumina silica, titanium, glassy volcanic rock fired powder, glassy volcanic ash fired powder, etc. Examples include solidified powder alone or together with wood flour, rehydrated flour, activated carbon, etc., and hardened with a sizing agent such as dextrin, starch, gum arabic, or synthetic glue carboxymethyl cellulose (CMC). A particularly preferred liquid-absorbing core is a sizing agent mixed with 10 to 300 parts by weight of the mineral powder alone or 100 parts by weight of the mineral powder and 10 to 300 parts by weight of wood flour or a mixture of the wood flour and an equal weight of back powder and/or activated carbon. Total liquid absorbent core weight 5~
It is manufactured by blending the mixture until it reaches 25% by weight, then adding water to the mixture, kneading, extrusion molding, and drying. The liquid absorption core has a liquid absorption rate of 1 to 40 hours, preferably 8 to 21 hours.
Preferably time. This liquid absorption rate means that the liquid temperature is 25
A liquid absorbent wick with a diameter of 7 mm and a length of 70 mm is immersed in an n-paraffin solution at
- means the value determined by measuring the time it takes for the paraffin to arrive. Furthermore, in addition to the mineral powder, wood flour, and sizing agent mentioned above, pigments such as macarite green, sorbic acid and its salts, and mold inhibitors such as dehydroacetic acid can also be added to the liquid-absorbing core. .
本発明吸液芯は、従来公知の各種吸上式加熱蒸散型装置
に適用して、いずれも所期の優れた効果を奏し得る。本
発明芯の適用できる上記装置は、例えば特公昭５２−１
２１０６号公報、実開昭５８−４５６７０号公報等に記
載されている。その−具体例を添附図面に示す。The liquid absorbent wick of the present invention can be applied to various conventionally known wicking type heating evaporation devices, and can produce the desired excellent effects in all of them. The above device to which the core of the present invention can be applied is, for example, Japanese Patent Publication No. 52-1
It is described in Japanese Utility Model Publication No. 2106, Japanese Utility Model Application Publication No. 58-45670, etc. A specific example thereof is shown in the attached drawings.
第１図は本発明吸液芯を適用するに適した吸」二式加熱
蒸散型装置の概略図であり、該装置は吸液芯（１）を支
持するための芯支持体（２）をａする殺虫剤液収容容器
（３）と、上記容器内にその−Ｌ部を突出して挿入され
た吸液芯（１）と、その上側面部を間接的に加熱するた
めの中空円板状発熱体（４）、該発熱体（４）を支持す
るための支持部（５）及び支持脚（６）を有する発熱体
支持台（７）とから成っており、上記発熱体（４）は、
これに通電して発熱させるためのコード（図示せず）を
有している。FIG. 1 is a schematic diagram of a two-type heating evaporation device suitable for applying the liquid absorbent wick of the present invention, and the device includes a wick support (2) for supporting the liquid absorbent wick (1). an insecticide liquid storage container (3), a liquid-absorbing wick (1) inserted into the container with its -L portion protruding, and a hollow disc-shaped container for indirectly heating the upper side surface thereof; It consists of a heating element (4), a heating element support stand (7) having a support part (5) and support legs (6) for supporting the heating element (4), and the heating element (4) is ,
It has a cord (not shown) for energizing it to generate heat.
またに記装置に利用される発熱体としては、通常通電に
より発熱する発熱体が汎用されているが、これに限定さ
れることなく、例えば空気酸化発熱材、白金触媒等を利
用した発熱材等の公知のいかなる発熱体であってもかま
わない。In addition, as the heating element used in the above-mentioned device, a heating element that generates heat when energized is commonly used, but is not limited to this, for example, a heating element using an air oxidation heating material, a heating material using a platinum catalyst, etc. Any known heating element may be used.
本発明吸液芯を上記装置に適用して殺虫を行なう方法は
、従来のこの種装置の利用法と同様でよく、殺虫液組成
物が吸液芯より蒸散し得る適当な温度に該吸液芯を加熱
すればよい。この加熱温度は、殺虫剤の種類等に応じて
適宜に決定され、特に限定されないが、通常約７０〜１
５０℃、好ましくは１３５〜１４５℃の範囲の発熱体表
面温度とされ、これは吸液芯表面温度的６０〜１３５℃
、好ましくは約１２０〜１３０℃に相当する。The method for killing insects by applying the liquid absorbent wick of the present invention to the above device may be the same as the conventional method of using this type of device. Just heat the core. This heating temperature is appropriately determined depending on the type of insecticide, etc., and is not particularly limited, but is usually about 70 to 1
The surface temperature of the heating element is 50°C, preferably 135 to 145°C, which is 60 to 135°C in terms of the surface temperature of the liquid absorbent core.
, preferably about 120-130°C.
かくして本発明の吸液芯利用によれば、その目づまりを
確実に回避して、充分な殺虫効果を奏し得る殺虫剤濃度
をもって殺虫剤を長期間持続して揮散させ得る。Thus, by using the liquid-absorbing wick of the present invention, clogging of the wick can be reliably avoided, and the insecticide can be volatilized for a long period of time with an insecticide concentration that provides a sufficient insecticidal effect.
実施例 以下本発明を更に詳しく説明するため実施例を挙げる。Example Examples will be given below to explain the present invention in more detail.
実施例１
パーライト６０重量部及び木粉２０重量部に澱粉２０重
量部と水を加えて練合後、押出成型乾燥して、本発明多
孔質吸液芯（直径７ｍｍＸ長さ７０１１１ｆｆｌ、吸油
速度約１４時間）を調製した。Example 1 20 parts by weight of starch and water were added to 60 parts by weight of perlite and 20 parts by weight of wood flour, and after kneading, extrusion molding and drying were carried out to form a porous liquid absorbing core of the present invention (diameter 7 mm x length 70111 ffl, oil absorption rate of approx. 14 hours) was prepared.
下記第１表に示す殺虫剤Ｎｏ、ＡＡ−ＡＵ及び有機溶剤
の夫々を所定割合で用い、之等に化合物ＣＡ−ＣＺの夫
々を所定量添加混合するか又は混合することなく、殺虫
液組成物（Ｎｏ、１〜７８）を得た。An insecticidal liquid composition is prepared by using each of insecticide No., AA-AU, and an organic solvent shown in Table 1 below in a predetermined ratio, and adding and mixing a predetermined amount of each of the compounds CA-CZ, or without mixing. (No. 1 to 78) were obtained.
第 １ 表
尚、第１表中溶剤の項における記号は以下のものを示す
。Table 1 The symbols in the solvent section of Table 1 indicate the following.
Ｂ Ａ ・・・沸点１５０〜１８０℃／７６０ｍｍＨｇ
の脂肪族炭化水素
Ｂ Ｂ−・・沸点１８０〜２１０℃／７６０ｍｍＨＨの
脂肪族炭化水素
Ｂ Ｃ・・・沸点２１０〜２４０℃／７６０ｍａ＋Ｈｇ
の脂肪族炭化水素
ＢＤ・・・沸点２４０〜２７０℃／７６０ｍａ＋Ｈｇの
脂肪族炭化水素
Ｂ Ｅ−・・沸点２７０〜３００℃／７６０ｍｍＨｇの
脂肪族炭化水素
ＢＦ・・・沸点３００〜３５０℃／７６０ｍｍＨＨの脂
肪族炭化水素
上記で調製した殺虫液組成物の夫々５０或を、第１図に
示す容器（３）に入れ、発熱体（４）に通電して吸液芯
（１）の上側面部を温度１３５℃に加熱し、該加熱によ
る組成物試料中の殺虫剤の蒸散試験を行なった。尚、発
熱体（４）としては内径１０ＩＩＩ１１及び厚さ１０ｍ
ｍの中空円板状発熱体を用いた。B A...Boiling point 150-180℃/760mmHg
Aliphatic hydrocarbon B B-...Aliphatic hydrocarbon with a boiling point of 180-210°C/760mmHH B-...Aliphatic hydrocarbon with a boiling point of 210-240°C/760ma+Hg
Aliphatic hydrocarbon BD...Aliphatic hydrocarbon B with a boiling point of 240-270℃/760mmHg E-...Aliphatic hydrocarbon with a boiling point of 270-300℃/760mmHg BF...Aliphatic hydrocarbon with a boiling point of 300-350℃/760mmHH Aliphatic hydrocarbons Fifty grams of each of the above-prepared insecticidal liquid compositions were placed in the container (3) shown in FIG. The composition was heated to a temperature of 135° C., and a transpiration test of the insecticide in the composition sample was conducted by heating. In addition, the heating element (4) has an inner diameter of 10III11 and a thickness of 10 m.
A hollow disc-shaped heating element of m was used.
殺虫剤の揮散量は揮散蒸気を毎時間毎にシリカゲルカラ
ムに吸引捕集し、このシリカゲルをクロロホルムで抽出
し、濃縮後、ガスクロマトグラフにて定量分析した。The amount of volatilized insecticide was determined by suctioning and collecting the volatilized vapor into a silica gel column every hour, extracting the silica gel with chloroform, concentrating it, and quantitatively analyzing it using a gas chromatograph.
殺虫液組成物試料の加熱開始より１０時間後、１００時
間後、２００時間後、３００時間後及び４００時間後の
１時間当りの殺虫剤揮散ｆｆ１ｍｇ／ｈｒを求めた結果
を下記第２表に示す。The results of the insecticide volatilization ff1mg/hr per hour 10, 100, 200, 300 and 400 hours after the start of heating the insecticidal liquid composition sample are shown in Table 2 below. .
弔 つ 表
上記第２表より、本発明によれば、向Ｊ−された殺虫剤
揮散量を長期に亘り持続１７得ることが明白である。From Table 2 above, it is clear that according to the present invention, the reduced amount of pesticide volatilization can be sustained over a long period of time.
第１図は本発明吸液芯を適用するに適した装置の一例の
概略図であり、該図中（１）は本発明吸液芯、（３）は
殺虫液組成物収容容器及び（４）は発熱体を夫々示す。
（以 」−）FIG. 1 is a schematic diagram of an example of a device suitable for applying the liquid-absorbing wick of the present invention, in which (1) is the liquid-absorbing wick of the present invention, (3) is an insecticidal liquid composition storage container, and (4) is a device suitable for applying the liquid-absorbing wick of the present invention. ) indicate heating elements. (hereafter ”-)
Claims (2)
トリン、デンプン、アラビアゴムより選ばれる少なくと
も１種の糊剤で粘結させてなる吸液芯。(1) A liquid-absorbing core made by binding inorganic powder with at least one type of sizing agent selected from carboxymethyl cellulose, dextrin, starch, and gum arabic.
ウ土、クレー、パーライト、ベントナイト、グラスファ
イバー、石綿である請求項１記載の吸液芯。(2) The liquid absorbent core according to claim 1, wherein the inorganic powder is kaolin, activated clay, talc, diatomaceous earth, clay, perlite, bentonite, glass fiber, or asbestos.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8506289A JPH01296933A (en) | 1989-04-03 | 1989-04-03 | Liquid-absorbing wick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8506289A JPH01296933A (en) | 1989-04-03 | 1989-04-03 | Liquid-absorbing wick |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1676084A Division JPS60161902A (en) | 1984-01-31 | 1984-01-31 | Insecticidal solution composition for core to suck up solution |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4116163A Division JP2519629B2 (en) | 1992-05-08 | 1992-05-08 | Container for heating evaporation type equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01296933A true JPH01296933A (en) | 1989-11-30 |
Family
ID=13848151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8506289A Pending JPH01296933A (en) | 1989-04-03 | 1989-04-03 | Liquid-absorbing wick |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01296933A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998009517A1 (en) * | 1995-03-02 | 1998-03-12 | Sumitomo Chemical Company, Limited | Liquid absorbent core for thermal transpiration |
| ES2149701A1 (en) * | 1998-08-11 | 2000-11-01 | Sumitomo Chemical Co | Wick absorbing liquid, for evaporation of this by heat, for lighting systems |
| US9547000B2 (en) | 2012-08-29 | 2017-01-17 | 7905122 Canada Inc. | Chromogenic absorbent material for animal litter and related chromogenic solution |
| WO2017130921A1 (en) * | 2016-01-25 | 2017-08-03 | 大日本除蟲菊株式会社 | Pest control product and pest control method |
| US10175231B2 (en) | 2014-02-27 | 2019-01-08 | 7905122 Canada Inc. | Chromogenic absorbent material for animal litter |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5557502A (en) * | 1978-10-23 | 1980-04-28 | Earth Chem Corp Ltd | Heat volatilization destroying of insect |
| JPS5558047A (en) * | 1978-10-27 | 1980-04-30 | Earth Chemical Co | Liquid sucking core |
-
1989
- 1989-04-03 JP JP8506289A patent/JPH01296933A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5557502A (en) * | 1978-10-23 | 1980-04-28 | Earth Chem Corp Ltd | Heat volatilization destroying of insect |
| JPS5558047A (en) * | 1978-10-27 | 1980-04-30 | Earth Chemical Co | Liquid sucking core |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998009517A1 (en) * | 1995-03-02 | 1998-03-12 | Sumitomo Chemical Company, Limited | Liquid absorbent core for thermal transpiration |
| ES2149701A1 (en) * | 1998-08-11 | 2000-11-01 | Sumitomo Chemical Co | Wick absorbing liquid, for evaporation of this by heat, for lighting systems |
| US9547000B2 (en) | 2012-08-29 | 2017-01-17 | 7905122 Canada Inc. | Chromogenic absorbent material for animal litter and related chromogenic solution |
| US10175231B2 (en) | 2014-02-27 | 2019-01-08 | 7905122 Canada Inc. | Chromogenic absorbent material for animal litter |
| US10908150B2 (en) | 2014-02-27 | 2021-02-02 | 7905122 Canada Inc. | Chromogenic absorbent material for animal litter |
| WO2017130921A1 (en) * | 2016-01-25 | 2017-08-03 | 大日本除蟲菊株式会社 | Pest control product and pest control method |
| CN108289453A (en) * | 2016-01-25 | 2018-07-17 | 大日本除虫菊株式会社 | Control of insect product and insect pest control method |
| JPWO2017130921A1 (en) * | 2016-01-25 | 2018-09-27 | 大日本除蟲菊株式会社 | Pest control product and pest control method |
| AU2017213296B2 (en) * | 2016-01-25 | 2019-04-18 | Dainihon Jochugiku Co., Ltd. | Insect pest control product and insect pest control method |
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