JPH01266210A - Bactericidal and fungicidal plastic yarn - Google Patents
Bactericidal and fungicidal plastic yarnInfo
- Publication number
- JPH01266210A JPH01266210A JP9018888A JP9018888A JPH01266210A JP H01266210 A JPH01266210 A JP H01266210A JP 9018888 A JP9018888 A JP 9018888A JP 9018888 A JP9018888 A JP 9018888A JP H01266210 A JPH01266210 A JP H01266210A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- bactericidal
- plastic
- plastic yarn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 14
- 239000004033 plastic Substances 0.000 title claims abstract description 14
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 11
- 230000000855 fungicidal effect Effects 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 8
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 5
- 238000004898 kneading Methods 0.000 claims abstract description 4
- 238000009987 spinning Methods 0.000 claims abstract description 4
- 229940121375 antifungal agent Drugs 0.000 claims description 11
- 230000000843 anti-fungal effect Effects 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims 1
- 239000002519 antifouling agent Substances 0.000 abstract description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 238000009360 aquaculture Methods 0.000 abstract description 3
- 244000144974 aquaculture Species 0.000 abstract description 3
- -1 chlorothio Chemical group 0.000 abstract description 2
- WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 239000003429 antifungal agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000235527 Rhizopus Species 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- JJKSAEHNIHMQKQ-UHFFFAOYSA-N copper;quinoline Chemical compound [Cu].N1=CC=CC2=CC=CC=C21 JJKSAEHNIHMQKQ-UHFFFAOYSA-N 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は抗菌抗カビ性プラスチ、り糸に関するもので、
特に有機金属化合物以外の抗菌抗カビ性有機化合物をプ
ラスチック材料に混練して得られるプラスチック糸に関
するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to antibacterial and antifungal plastic yarn.
In particular, it relates to a plastic thread obtained by kneading an antibacterial and antifungal organic compound other than an organometallic compound into a plastic material.
従来技術
２００力イリ領海問題を契機として我が国の養殖漁業は
著しい発展をとげつつあり、そのための漁網防汚剤の使
用量も急速に増大しつつある。さらにこの漁網防汚剤は
船底塗料等としての新用途も有望視されており、将来の
使用量の増大は疑問の余地のないところと考えられてい
るが、一般に従来の漁網防汚剤にはＴＢＴＯ（）リブチ
ルスズ化合物）を始めとした重金属系防汚剤が使用され
ており、環境保全や養殖魚の安全性の観点から重大な問
題が存在し、このため既に全国かん水養漁協会や全国漁
業協同組合連合会において使用禁止とされていることも
また周知の通りである。Prior Art 200 In response to the territorial sea issue, Japan's aquaculture fisheries are undergoing remarkable development, and the amount of fishing net antifouling agents used for this purpose is rapidly increasing. Furthermore, this fishing net antifouling agent is also seen as promising for new uses such as ship bottom paint, and there is no doubt that its usage will increase in the future.However, in general, conventional fishing net antifouling agents are Heavy metal antifouling agents such as TBTO (butyltin compound) are used, and there are serious problems from the viewpoint of environmental conservation and the safety of farmed fish. It is also well known that its use is prohibited by union federations.
発明が解決しようとする問題点
従って本発明はこれらの重金属系化合物を使用した防汚
剤に代わる新規の漁網防汚手段を提供するためのもので
あり、特に防汚剤の使用を完全に不要ならしめるための
漁網用プラスチック糸の提供を目的とするものである。Problems to be Solved by the Invention Therefore, the present invention is intended to provide a new fishing net antifouling means to replace the antifouling agents using these heavy metal compounds, and in particular, to completely eliminate the use of antifouling agents. The purpose is to provide plastic thread for fishing nets for conditioning purposes.
問題点を解決するための手段
本発明者は各種抗菌抗カビ性化合物について研究の結果
、従来までの重金属系化合物系防汚剤の代わりにジ（フ
ルオロノクロロメチルチオ）−クルクルイミドやノクロ
ルフルアニド等を含有させたプラスチ、り材料を紡糸し
て得られるフィラメントから漁網を製造することによっ
て漁網の汚染問題を一挙に解決することに成功したもの
である。Means for Solving the Problems As a result of research on various antibacterial and antifungal compounds, the present inventor has developed di(fluoronochloromethylthio)-curculimide and nochlorofluanimide in place of conventional heavy metal compound-based antifouling agents. By manufacturing fishing nets from filaments obtained by spinning plasti material containing carbon dioxide, etc., the problem of contamination of fishing nets was successfully solved at once.
すなわち、本発明は重金属系化合物を使用することなく
、抗菌抗カビ性有機化合物をプラスチック材料に混合し
て紡糸したプラスチックフィラメントに関するものであ
って、これらのフィラメントから漁網を製造することに
よって防汚剤の使用を一切不要ならしめたものである。That is, the present invention relates to plastic filaments that are spun by mixing an antibacterial and antifungal organic compound with a plastic material without using heavy metal compounds, and by manufacturing fishing nets from these filaments, an antifouling agent can be obtained. This eliminates the need for the use of .
本発明で使用され得る抗菌抗カビ性化合物としては、ジ
（フルオロジクロロメチルチオ）−フルクルイミド、ジ
クロルフルアニド、Ｎ、Ｎ−ジメチル−Ｎ′フェニル−
（Ｎ−メチルフルオロジクロロチオ）−スルファミドジ
クロフルアニド、Ｎ−（メチルフルオロジクロロチオ）
−フタリジド等が特に有効であり、これらの化合物には
例えば三愛石油からサンアイゾール３００．サンアイゾ
ール４００等として市販されているものが含まれる。Antibacterial and antifungal compounds that can be used in the present invention include di(fluorodichloromethylthio)-flucruimide, dichlorofluanide, N,N-dimethyl-N'phenyl-
(N-methylfluorodichlorothio)-sulfamide dichlorofluanide, N-(methylfluorodichlorothio)
-phthalidide and the like are particularly effective, and these compounds include, for example, San-Aisol 300. These include those commercially available as Sun-Aisol 400 and the like.
実施例 以下に本発明の実施例を示す。Example Examples of the present invention are shown below.
実施例１． （Ａ）
標準型塩化ビニル樹脂波レッ）１００重景重量対して可
塑剤としてり、 Ｏ，Ｐ、 ４０重量部、潤滑剤として
ステアリン酸０．３重量部を加え、さらにＦ、Ｅ、Ｐ−
１３（紫外防止剤アデカエポキシ）４重量部、０−１３
−ＯＰ（紫外防止剤アデカエポキシ）１重量部、ＡＣ−
２１２（安定剤）２重量部、ＢＴ−２５（安定助剤）０
．２重量部と共にサンアイゾール３００（抗カビ剤）３
重量部を加えたものをフィラメントに紡糸した。Example 1. (A) Standard vinyl chloride resin wave) 40 parts by weight of O, P as a plasticizer and 0.3 parts by weight of stearic acid as a lubricant were added to 100 parts by weight of F, E, P-
13 (ultraviolet inhibitor ADEKA epoxy) 4 parts by weight, 0-13
-OP (ultraviolet inhibitor ADEKA epoxy) 1 part by weight, AC-
212 (stabilizer) 2 parts by weight, BT-25 (stabilizer) 0
．． 2 parts by weight and 3 parts of Sanaisol 300 (anti-fungal agent)
Parts by weight were added and spun into filaments.
実施例２．（Ｂ）
標準型塩化ビニル樹脂にレット１００重量部に対して可
塑剤としてり、０．Ｐ、４０重量部、潤滑剤としてステ
アリン酸０．３重量部を加え。Example 2. (B) Add 100 parts by weight of standard vinyl chloride resin as a plasticizer and add 0. P, 40 parts by weight, and 0.3 parts by weight of stearic acid were added as a lubricant.
さらＫＦ、Ｅ、Ｐ−１３（紫外防止剤アデカエボキシ）
４重量部、０−１３−ＯＰ（紫外防止剤アデカエポキシ
）１重量部、ＡＣ，−２１２（安定剤）２重量部、ＢＴ
−２５（安定助剤）０．２重量部、亜酸化銅（安定助剤
及び抗カビ剤）０．４重量部と共にサンアイゾール３０
０（抗カビ剤）２重量部、サンアイゾール４００（抗カ
ビ剤）１重量部を加えたものをフィラメントに紡糸した
。Sara KF, E, P-13 (ultraviolet inhibitor ADEKA EBOXY)
4 parts by weight, 0-13-OP (ultraviolet inhibitor Adeka epoxy) 1 part by weight, AC, -212 (stabilizer) 2 parts by weight, BT
-25 (stabilizing agent) 0.2 parts by weight, cuprous oxide (stabilizing agent and anti-mold agent) 0.4 parts by weight together with Sun Izol 30
0 (anti-fungal agent) and 1 part by weight of Sun-Isol 400 (anti-fungal agent) were added and spun into filaments.
実施例３． （Ｃ）
標準型塩化ビニル樹脂（レッ）１００重量部に対して可
塑剤としてり、Ｏ，Ｐ、４０重量部、潤滑剤としてステ
アリン酸０．３重量部を加え、さらにｒ、Ｅ、ｐ−ｘ３
（紫外防止剤アデカエポキシ）４重量部、０−１３−Ｏ
Ｐ（紫外防止剤アデカエポキシ）１重量部、ＡＣ−２１
２（安定剤）２重量部、ＢＴ−２５（安定助剤）０．２
重量部、キノリン銅（安定助剤及び抗カビ剤）０．４重
量部と共にサンアイゾール３００ （抗カビ剤）２重量
部、サンアイゾール４００（抗カビ剤）１重量部を加え
フィラメントに紡糸した。Example 3. (C) To 100 parts by weight of standard vinyl chloride resin (Re), 40 parts by weight of O, P, as a plasticizer, and 0.3 parts by weight of stearic acid as a lubricant were added, and further r, E, p- x3
(Ultraviolet inhibitor ADEKA epoxy) 4 parts by weight, 0-13-O
P (ultraviolet inhibitor ADEKA epoxy) 1 part by weight, AC-21
2 (stabilizer) 2 parts by weight, BT-25 (stabilizer) 0.2
Parts by weight, 0.4 parts by weight of quinoline copper (stabilizing agent and anti-mold agent), 2 parts by weight of San-Isol 300 (anti-mold agent) and 1 part by weight of San-Isol 400 (anti-mold agent) were added and spun into filaments.
以上の実施例１（Ａ）、実施例２（Ｂ）、及び実施例３
（Ｃ）のフィラメントについて（社）日本食品衛生協会
で抗カビ性試験した結果は以下の通りであった。Example 1 (A), Example 2 (B), and Example 3 above
The filament (C) was tested for antifungal properties by the Japan Food Hygiene Association, and the results were as follows.
試験結果
試験結果の表示方法
試験方法
１、使用菌株
ＪＩＳ Ｚ ２９１１−１９８１に規定された５群のう
ち下記に示す菌株を用いた。Test Results Method for Displaying Test Results Test Method 1, Bacterial Strains Used Among the five groups specified in JIS Z 2911-1981, the following strains were used.
Ａｓｐｅｒｇｉｌｌｕｓ ｎｉｇｅｒ
ＦＥＲＭ Ｓ５−ｌＰｅｎ１ｃｉｌｌｉｕ ｃ
ｉｔｒｉｎｕｍ ＦＥＲＭ Ｓ−５
Ｒｈｉｚｏｐｕｓ ５ｔｏｌｏｎｉｆｅｒ
ＦＥＲＭ Ｓ −７Ｃ１ａｄｏｓｐｏｒｉｕｍ
ｃｌａｄｏｓｐｏｒｉｏｉｄｅｓ ＦＥＲＭ
Ｓ −８Ｃｈａｅｔｏｍｉｕｍ ｇｌｏｂｏｓｕｍ
ＦＥＲＭ Ｓ −１１２、方 法
ＪＩＳ Ｚ ２９１１−１９８１による発明の効果
従って漁網の製造に際して本発明の抗菌抗カビ性プラス
チックフィラメントを使用することによって、これまで
養殖漁業の問題点として指摘されて来た有機金属系防汚
剤の使用を不要とすることができるばかりでな（、本発
明のフィラメントが当然のことながら靴下、肌着等の漁
網以外の各種用途に使用し得ることもまた明白である。Aspergillus niger
FERM S5-1Pen1cilliu c
itrinum FERM S-5
Rhizopus 5tolonifer
FERM S-7C1adosporium
cladosporioides FERM
S-8Chaetomium globosum
Effects of the invention according to FERM S-112, Method JIS Z 2911-1981 Therefore, by using the antibacterial and antifungal plastic filament of the present invention in the production of fishing nets, it is possible to eliminate organic matter, which has been pointed out as a problem in aquaculture fisheries. Not only can the use of metallic antifouling agents be made unnecessary, but it is also obvious that the filament of the present invention can be used in various applications other than fishing nets, such as socks and underwear.
Claims (1)
してから紡糸することによって得られることを特徴とす
る抗菌抗カビ性プラスチック糸。1. An antibacterial and antifungal plastic yarn characterized in that it is obtained by kneading an antibacterial and antifungal organic compound into a plastic material and then spinning the mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9018888A JPH01266210A (en) | 1988-04-14 | 1988-04-14 | Bactericidal and fungicidal plastic yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9018888A JPH01266210A (en) | 1988-04-14 | 1988-04-14 | Bactericidal and fungicidal plastic yarn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01266210A true JPH01266210A (en) | 1989-10-24 |
Family
ID=13991513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9018888A Pending JPH01266210A (en) | 1988-04-14 | 1988-04-14 | Bactericidal and fungicidal plastic yarn |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01266210A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8017061B2 (en) | 2004-05-28 | 2011-09-13 | Philipps-Universitat Marburg | Invention concerning agricultural active substances |
-
1988
- 1988-04-14 JP JP9018888A patent/JPH01266210A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8017061B2 (en) | 2004-05-28 | 2011-09-13 | Philipps-Universitat Marburg | Invention concerning agricultural active substances |
| US8431064B2 (en) | 2004-05-28 | 2013-04-30 | Phillips-Universitat Marburg | Method of using nanoscaled polymer fibers as carriers for agricultural substances |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004137241A (en) | Antibacterial/mildew-proofing/algicidal composition | |
| BR112014014586B1 (en) | biocidal composition of active powders, manufacturing procedure for the biocidal composition and its use | |
| JPH01266210A (en) | Bactericidal and fungicidal plastic yarn | |
| DE1542739A1 (en) | Pest repellants | |
| JP3294749B2 (en) | Bio-resistant molded article, method for producing the same, and product using the same | |
| RU2447206C1 (en) | Process of obtaining synthetic fabric with biocidal properties | |
| JP3114946B2 (en) | Uses, products and compositions of certain triazoles to protect materials from fungal attack | |
| WO2019078173A1 (en) | Antimicrobial composition | |
| DE1768686B1 (en) | Furan-3-carboxylic acid anilides and their use as a fungicide | |
| JPH09273075A (en) | Production of fiber having biological resistance | |
| JP3585059B2 (en) | Antimicrobial composition and method for producing antimicrobial resin composition | |
| JPH0381205A (en) | Industrial bactericide and antibacterial resin molded product | |
| JPH0517617A (en) | Antifungal resin composition and antifungal resin molding | |
| JPH09157112A (en) | Resin fiber composite sheet having resistance to organism | |
| US3728454A (en) | Alloxan compounds as antibacterial and antifungal agents | |
| JP2533310B2 (en) | Antibacterial and antifungal composition | |
| JP2011116919A (en) | Aromatic vinyl-based resin composition | |
| DE855550C (en) | Process for the preparation of quaternary ammonium compounds | |
| JP2008007912A (en) | Polylactic acid fiber, fabric and textile product using the same | |
| JPH07197312A (en) | Antimicrobial fiber | |
| US3059013A (en) | Organic mercurial compounds useful as germicides, bactericides and fungicides | |
| US3728453A (en) | Dialuric acid compounds as antibacterial and antifungal agents | |
| AT215085B (en) | Process for the preparation of a germicidal mixture | |
| JP2021166950A (en) | Filter medium for air filter | |
| JP2006152517A (en) | Antimicrobial and acaricidal fiber |