JPH01215866A - Fast-drying automobile coating - Google Patents
Fast-drying automobile coatingInfo
- Publication number
- JPH01215866A JPH01215866A JP63039717A JP3971788A JPH01215866A JP H01215866 A JPH01215866 A JP H01215866A JP 63039717 A JP63039717 A JP 63039717A JP 3971788 A JP3971788 A JP 3971788A JP H01215866 A JPH01215866 A JP H01215866A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- drying
- coating
- fast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001035 drying Methods 0.000 title claims abstract description 34
- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 238000000576 coating method Methods 0.000 title abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims abstract description 6
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 3
- 239000000057 synthetic resin Substances 0.000 claims abstract description 3
- 239000011882 ultra-fine particle Substances 0.000 claims description 15
- 239000001993 wax Substances 0.000 abstract description 23
- 239000002828 fuel tank Substances 0.000 abstract description 10
- 239000010426 asphalt Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 16
- 238000009472 formulation Methods 0.000 description 13
- 239000003973 paint Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 description 10
- 239000011707 mineral Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- -1 fire extinguishers Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、速乾性自動車用塗布剤に関し、詳細には自動
車の各部で塗布する塗布剤の物性を全く損なうことなく
乾燥性に著しくすぐれた速乾性自動車用塗布剤に関する
。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a quick-drying coating agent for automobiles, and more specifically, a coating agent that has extremely excellent drying properties without impairing the physical properties of the coating agent applied to various parts of the automobile. This invention relates to a quick-drying coating agent for automobiles.
（従来の技術）
従来より、自動車の床裏面に制振性能および防錆性能を
付与するためのワックス、塗料が、更に燃料タンクには
防炎性能または防錆性能を付与するだめの塗料、ワック
ス等が塗布されている。(Prior art) Waxes and paints have been used to impart vibration damping and rust prevention properties to the underside of automobile floors, and paints and waxes have been used to impart flame retardancy and rust prevention properties to fuel tanks. etc. are applied.
（発明が解決しようとする課題）
かかる塗布剤は、各々目的とする性能には効果が見られ
るものの乾燥に時間を要し、その後の作業性および保管
性に支障を来たしており、速乾性の塗布剤が求められて
いるのが現状である。(Problems to be Solved by the Invention) Although these coating agents are effective in achieving the desired performance, they require time to dry, which impedes subsequent workability and storage. Currently, there is a demand for coating agents.
（課題を解決するための手段）
そこで、本発明者らは各々目的とする性能を何ら損なう
ことなく、乾燥性を速くした塗布剤を開発するべく鋭意
研究の結果、特定の充填材である無水シリカを乾燥促進
剤として特定量配合するこ。(Means for Solving the Problems) Therefore, the present inventors conducted intensive research to develop a coating agent that dries quickly without impairing the desired performance. A specific amount of silica is added as a drying accelerator.
とにより、従来より有する性能とともに速い乾燥性を満
足し得ることを知見し、本発明を達成するに至ったもの
である。As a result, the inventors discovered that it is possible to satisfy the conventional performance as well as fast drying properties, leading to the achievement of the present invention.
本発明の自動車用塗布剤は、ワックス成分および合成樹
脂成分のうちの１種以上と、充填材成分を必須成分とし
て含み、必要に応じて、アスファルト、ゴム成分が配合
される。The automotive coating agent of the present invention contains one or more of a wax component and a synthetic resin component and a filler component as essential components, and asphalt and a rubber component are blended as necessary.
ワックス成分としては、マイクロワックス、石油スルホ
ネート（金属塩）、酸化へトロラタム金属塩、ロウ状物
、ラノリン（脂肪酸の）金属塩、合成スルボン酸の金属
塩等を使用する。As the wax component, microwax, petroleum sulfonate (metal salt), hetrolatum oxide metal salt, waxy substance, lanolin (fatty acid) metal salt, synthetic sulfonic acid metal salt, etc. are used.
樹脂成分としては、アルキド樹脂、ウレタン樹脂、アク
リル樹脂、塩化ビニル樹脂、ポリエステル樹脂等を使用
する。As the resin component, alkyd resin, urethane resin, acrylic resin, vinyl chloride resin, polyester resin, etc. are used.
アスファルト成分を配合する場合には、ス１〜レートア
スファルト、ブロンアスファルト、セミブロンアスファ
ルト等の１種もしくは２種以上の混合物を使用する。−
船釣にはストレートアスファルト単独、ブロンアスファ
ルト単独、ストレー１〜アスフアルトとブロンアスファ
ルトの混合物を使用する。When blending an asphalt component, one type or a mixture of two or more of slate asphalt, blown asphalt, semi-brown asphalt, etc. is used. −
For boat fishing, use straight asphalt alone, blown asphalt alone, or a mixture of straight 1 to asphalt and blown asphalt.
またゴム成分を配合しても良く、配合する場合には天然
ゴムやポリブタジェン、スチレン−ブクジエンゴム、ブ
チルゴム、ネオプレンゴム、クロロブレンゴム等の合成
ゴムを選択使用する。また、再生ゴムの使用はコスト面
よりして好ましいことである。A rubber component may also be blended, and when blended, natural rubber, polybutadiene, styrene-butadiene rubber, butyl rubber, neoprene rubber, chloroprene rubber, and other synthetic rubbers are selected and used. Further, the use of recycled rubber is preferable from the viewpoint of cost.
他の主成分として含む充填材成分は硫酸バリウム、タル
ク、クレー、炭酸カルシウム、マイカ、シリカバルーン
、着色顔料等の任意の充填材の単独もしくは２種以上の
混合物であって良い。本発明の必須成分である充填材の
超微粒子（粒径２〜１５ｍμの粒子が８０重量％以上）
の無水シリカは、乾燥促進剤として使用するもので、塗
布剤成分の０．１〜１０重量％配合することを必須とし
、０，１重量％未満の場合、優れた速乾性の効果を顕現
し得す、１０重量％を超えると塗布剤が必要以上に増粘
し、塗布作業性に劣るという不具合があり、好ましくな
い。The other filler component contained as the main component may be any filler such as barium sulfate, talc, clay, calcium carbonate, mica, silica balloon, colored pigment, etc. alone or in a mixture of two or more. Ultrafine particles of filler, which is an essential component of the present invention (80% by weight or more of particles with a particle size of 2 to 15 mμ)
Anhydrous silica is used as a drying accelerator and must be included in the coating composition in an amount of 0.1 to 10% by weight. However, if it exceeds 10% by weight, the coating agent becomes thicker than necessary and the coating workability becomes poor, which is not preferable.
その他添加剤としては、無機系ダレ防止剤、改質材、発
泡剤、消火剤、分散剤等が使用できる。Other additives that can be used include inorganic anti-sag agents, modifiers, foaming agents, fire extinguishers, and dispersants.
また溶剤は、特に限定されることなく、脂肪族炭化水素
系、芳香族炭化水素系、ケトン系、アルコール系、エス
テル系の溶剤が使用できる。Further, the solvent is not particularly limited, and aliphatic hydrocarbon-based, aromatic hydrocarbon-based, ketone-based, alcohol-based, and ester-based solvents can be used.
本発明の塗布剤を調整せんとする場合には、所定の配合
原料を高速ティスパー、ニーダ−等により混練すれば良
い。When preparing the coating agent of the present invention, predetermined blended raw materials may be kneaded using a high-speed teaser, kneader, or the like.
かがる塗布剤を自動車の床裏面や燃料タンク等に塗布す
る場合、ハケ、エアースプレー、エチル＝３−
ススプレー、ローラー塗装等の手段による。When applying a glaring coating agent to the underside of a car's floor, fuel tank, etc., use methods such as brushing, air spraying, ethyl spray, and roller painting.
（実施例）
以下に実施例、比較例および試験例を挙げ本発明の詳細
な説明する。(Example) The present invention will be described in detail below with reference to Examples, Comparative Examples, and Test Examples.
当然のことながら本発明は以下の実施例のみに限定され
るものではない。Naturally, the present invention is not limited to the following examples.
酊企桝土
マイクロワックス１００重量部、石油スルホネート金属
塩１００重量部、酸化ペトロラタム金属塩５０重量部、
ロウ状物２０重量部、アスファルト６０重量部、ラノリ
ン樹脂酸の金属塩８０重量部、合成スルホン酸の金属塩
８０重量部、可塑剤２０重量部、硫酸バリウム２００重
量部、炭酸カルシウム８０重量部、無機系ダレ防止剤と
してエロジール（酸化ケイ素、日本アエロジル■製画品
名）３５重量部、改質剤としてスチレン、ブクジエンゴ
ム、ディスバージョン２０重量部、溶剤２１０重量部を
配合し、ビチューメンワックスとなした。100 parts by weight of 醊蜝杝子microwax, 100 parts by weight of petroleum sulfonate metal salt, 50 parts by weight of petrolatum oxide metal salt,
20 parts by weight of wax, 60 parts by weight of asphalt, 80 parts by weight of metal salt of lanolin resin acid, 80 parts by weight of metal salt of synthetic sulfonic acid, 20 parts by weight of plasticizer, 200 parts by weight of barium sulfate, 80 parts by weight of calcium carbonate, A bitumen wax was prepared by blending 35 parts by weight of Erosil (silicon oxide, product name manufactured by Nippon Aerosil ■) as an inorganic anti-sag agent, 20 parts by weight of styrene, Bukudiene rubber, disversion as a modifier, and 210 parts by weight of a solvent.
＝ ４−
乾燥促進剤として超微粒子（粒径２〜１５ ｍμの粒子
が８０重量％以上）の無水シリカ１．５重量部および溶
剤（酢酸エチル／ミネラルスピリット、５０１５０）５
重量部を配合し、速乾性のビチューメンワックスとなし
た。= 4- 1.5 parts by weight of anhydrous silica of ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) as a drying accelerator and a solvent (ethyl acetate/mineral spirit, 50150) 5
parts by weight were blended to form a quick-drying bitumen wax.
尖旌五Ｉ
配合例１のビチューメンワックス１００重量部に乾燥促
進剤として超微粒子（粒径２〜１５ ｍμ粒子が８０重
量％以上）の無水シリカ９重量部および溶剤３０重量部
を配合し、速乾性のヒチューメンワックスとなした。100 parts by weight of the bitumen wax of Formulation Example 1 is blended with 9 parts by weight of anhydrous silica containing ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) and 30 parts by weight of a solvent as a drying accelerator. Made with drying wax.
比較炎上 配合例１と同様のビチューメンワックスとなした。Comparison of flames The same bitumen wax as in Formulation Example 1 was prepared.
ル較槻Ｉ
配合例１のビチューメンワックス１００重量部に乾燥促
進剤として超微粒子（粒径２〜１５ ｍμの粒子が８０
重量％以上）の無水シリカ０．０５重量部および溶剤２
重量部を配合した。Le Comparison I 100 parts by weight of the bitumen wax of Formulation Example 1 was added with ultrafine particles (80 parts with a particle size of 2 to 15 mμ) as a drying accelerator.
0.05 parts by weight of anhydrous silica and solvent 2
Parts by weight were blended.
＝６一
此十ｕ」ｌ
配合例１のビチューメンワックス１００重量部に乾燥促
進剤として超微粒子（粒径２〜１５ ｍμの粒子が８０
重量％以上）の無水シリカ１１重量部および溶剤３５重
量部を配合した。= 61 this 10 u''l 100 parts by weight of the bitumen wax of Formulation Example 1 was added with ultrafine particles (80 parts with a particle size of 2 to 15 mμ) as a drying accelerator.
11 parts by weight of anhydrous silica and 35 parts by weight of a solvent were blended.
聞企炎又
石油スルボネー１−２１．０重量部、ラノリン脂肪酸の
金属塩４．０重量部、マイクロワックス６．０重量部、
アクリルゴム５．０重量部、カーボンブラック０．５重
量部、添加剤としてディスパロン４２００−２０（楠木
化成■製、商品名）１．０重量部、ミネラルスピリット
６３．０重量部を配合し、燃料タンクワックスとなした
。1-21.0 parts by weight of petroleum sulfone, 4.0 parts by weight of metal salts of lanolin fatty acids, 6.0 parts by weight of microwax,
5.0 parts by weight of acrylic rubber, 0.5 parts by weight of carbon black, 1.0 parts by weight of Disparon 4200-20 (manufactured by Kusunoki Kasei ■, trade name) as additives, and 63.0 parts by weight of mineral spirit were blended to form a fuel. Made with tank wax.
災旌±主
配合例２のガスクンワックス１００重量部に乾燥促進剤
として超微粒子（粒径２〜１５ｍμの粒子が８０重量％
以上）の無水シリカ１重量部およびミネラルスピリット
４重量部を配合し、速乾性の燃料タンクワックスとなし
た。To 100 parts by weight of Gaskun wax in the main formulation example 2, ultrafine particles (80% by weight particles with a particle size of 2 to 15 mμ) were added as a drying accelerator.
1 part by weight of anhydrous silica (above) and 4 parts by weight of mineral spirit were blended to form a quick-drying fuel tank wax.
実考ｌ帽Ｗ
配合例２のガスタンワックス１００重量部に乾燥促進剤
として超微粒子（粒径２〜１５ ｍμの粒子が８０重量
％以上）の無水シリカ９重量部およびミネラルスピリッ
ト２８重量部を配合し、速乾性の燃料タンクワックスと
なした。Practical Hat W 9 parts by weight of anhydrous silica of ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) and 28 parts by weight of mineral spirit are blended as a drying accelerator to 100 parts by weight of Gastan wax in Formulation Example 2. It has been made into a quick-drying fuel tank wax.
几較桝土 配合例２と同様の燃料タンクワックスとなした。Comparison of soil A fuel tank wax similar to Formulation Example 2 was prepared.
几較華１−
配合例２の燃料タンクワックス１００重量部に乾燥促進
剤として超微粒子（粒径２〜１５ ｍμの粒子が８０重
量％以」二）の無水シリカ０．０５重量部およびミネラ
ルスピリット１重量部を配合した。1- 100 parts by weight of the fuel tank wax of Formulation Example 2, 0.05 parts by weight of anhydrous silica containing ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) and mineral spirit as a drying accelerator. 1 part by weight was blended.
几較桝旦
配合例２の燃料タンクワックス１００重量部に乾燥促進
剤として超微粒子（直径２〜１５ｍμの微粒子が８０重
量％以上）の無水シリカ１１重量部およびミネラルスピ
リット２８重量部を配合した。To 100 parts by weight of the fuel tank wax of Comparison Example 2, 11 parts by weight of anhydrous silica of ultrafine particles (80% by weight or more of fine particles with a diameter of 2 to 15 mμ) and 28 parts by weight of mineral spirit were blended as a drying accelerator.
父企炎ニ
アクリル樹脂２０重量部、発泡剤としてジペンクー７〜
エリスリトール１０重量部、消火剤としてりん酸２水素
アンモニウム２５重量部、分散剤としてアンチテラーＵ
（ＢＹＫジャパン■製、界面活性剤）０．５重量部、
エロジール１重量部、溶剤４３．５重量部を配合し、防
炎塗料となした。20 parts by weight of acrylic resin, 10 parts by weight of Dipenku 7 to erythritol as a blowing agent, 25 parts by weight of ammonium dihydrogen phosphate as a fire extinguisher, and Antiterror U as a dispersant.
(manufactured by BYK Japan ■, surfactant) 0.5 parts by weight,
1 part by weight of Erosil and 43.5 parts by weight of a solvent were blended to prepare a flame retardant paint.
実施±）
配合例３の防炎塗料１００重量部に乾燥促進剤として超
微粒子（粒径２〜１５ ｍμの粒子が８０重量％以上）
の無水シリカ１．５重量部およびミネラルスピリット４
重量部を配合し、速乾性の防炎塗料となした。Implementation ±) Add ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) as a drying accelerator to 100 parts by weight of the flame retardant paint of Formulation Example 3.
1.5 parts by weight of anhydrous silica and 4 parts by weight of mineral spirit
parts by weight to form a quick-drying flame retardant paint.
尖旌拠旦
配合例３の防炎塗料１００重量部に乾燥促進剤として超
微粒子（粒径２〜１５ ｍμの粒子が８０重量％以上）
の無水シリカ９重量部およびミネラルスピリット３０重
量部を配合し、速乾性の防炎塗料となした。Add ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) as a drying accelerator to 100 parts by weight of the flame retardant paint in Formulation Example 3.
9 parts by weight of anhydrous silica and 30 parts by weight of mineral spirit were blended to form a quick-drying flame retardant paint.
此Ｊｕ泳亀
配合例３の防炎塗料１００重量部に乾燥促進剤として超
微粒子（粒径２〜１５ｍμの粒子が８０重量％以上）の
無水シリカ０．０５重量部およびミネラルスピリット２
重量部を配合した。0.05 parts by weight of anhydrous silica containing ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) and mineral spirit 2 as a drying accelerator to 100 parts by weight of the flame retardant paint of Ju Eikame Formulation Example 3.
Parts by weight were blended.
比較±■
配合例３の防炎塗料１００重量部に乾燥促進剤として超
微粒子（粒径２〜１５「ｍμの粒子が８０重量％以」−
）の無水シリカ１１重量部およびミネラルスピリット３
５重量部を配合した。Comparison ±■ Ultrafine particles (80% by weight or more of particles with a particle size of 2 to 15 mμ) were added to 100 parts by weight of the flame retardant paint of Formulation Example 3 as a drying accelerator.
) of 11 parts by weight of anhydrous silica and 3 parts of mineral spirit.
5 parts by weight was blended.
拭Ｕ桝
実施例１〜６および比較例１〜９の配合物につき、次に
示す試験方法により乾燥時間および塗装性を評価し、測
定結果を示す。The drying time and paintability of the formulations of Wipe-U-Match Examples 1 to 6 and Comparative Examples 1 to 9 were evaluated by the following test methods, and the measurement results are shown below.
試験方法
■乾燥時間： Ｊ Ｉ Ｓ Ｋ ５４００５．８によ
る。Test method - Drying time: According to JIS K 54005.8.
■塗装性；エアレススプレーポンプを使用して塗装圧６
０−１２０ ｋｇ／−で３００ Ｘ３００ Ｘｏ、８
ｍｍの５ｐｃｃ−ｓＩ′１鋼板にガン距離３０ｃｍ＋、
ガンスピー１”３００ ＋ｎ＋ｎ／ ｍ ｉ ｎの条件
で吹き付け、塗膜外観のテール、スケ発生の有無で評価
した。尚、塗装膜厚はビチューメンワックスで６００
μ、燃料タンクワックスで８０μ、防炎塗料で５００μ
になるよう、それぞれチップを選定した。■Paintability: Painting pressure is 6 using an airless spray pump.
0-120 kg/- 300 X300 Xo, 8
mm 5pcc-sI'1 steel plate, gun distance 30cm+,
The coating was sprayed under the conditions of 1" 300 + n + n / min and evaluated based on the presence or absence of tails and scratches on the appearance of the paint film. The thickness of the paint film was 600 mm with bitumen wax.
μ, 80μ for fuel tank wax, 500μ for flame retardant paint
Each chip was selected so that
測定結果
実施例１ 実施例２ 比較例１ 比較例２ 比較例３■
ｉ １．５Ｈｉｌｌ ３１１ ３１
１ １ｔｌ■ｉｉ −−−−−
■ ○ ○ ○ ○ ×
実施例３ 実施例４ 比較例４ 比較例５ 比較例６■
ｉ ＩＨ３０Ｍ ２Ｈ２１１３０Ｍ■ｉｉ
１５１１ ８Ｈ２４Ｈ２６１１８１１■
○ ○ ○ Ｏ×実施例５ 実施
例６ 比較例７ 比較例８ 比較例９■ｉ １５Ｍ
ＩＯＭ ３０Ｍ ３０Ｍ
ＩＯＭ■ｉｉ ４５Ｍ ３０Ｍ １．
５Ｈ２ｔｌ ３０Ｍ■ ○ ○
○ ○ ×面上記測定結果中
■ｉ：指触乾燥時間
■Ｉじ硬化乾燥時間
■ ：塗装性
○：テール、スケなく良好
△：若干のテール、スケ発生
×：テール、スケ発生
を示ず。Measurement results Example 1 Example 2 Comparative example 1 Comparative example 2 Comparative example 3■
i 1.5Hill 311 31
1 1tl■ii −−−−− ■ ○ ○ ○ ○ ×
Example 3 Example 4 Comparative example 4 Comparative example 5 Comparative example 6 ■
i IH30M 2H21130M■ii
1511 8H24H2611811■
○ ○ ○ O×Example 5 Example 6 Comparative example 7 Comparative example 8 Comparative example 9■i 15M
IOM 30M 30M
IOM■ii 45M 30M 1.
5H2tl 30M■ ○ ○
○ ○ × Among the above measurement results ■i: Dry time to the touch ■I curing dry time■: Paintability ○: Good with no tails or scratches △: Some tails or scratches occur ×: No tails or scratches.
（発明の効果）
以上説明してきたように、本発明の塗布剤は、粒径２〜
１５ ｍμの粒子を８０重量％以上含む無水シリカ超微
粒子を０．１〜１０重量％含有することにより、試験例
の結果からも明らかなように、速乾性が改善され、自動
車の床裏面、燃料タンク等に塗布する場合の作業性すこ
優れ、塗布後形成された塗膜にはテール、スケ発生が無
いという効果が得られる。(Effect of the invention) As explained above, the coating agent of the present invention has a particle size of 2 to 2.
By containing 0.1 to 10% by weight of anhydrous silica ultrafine particles containing 80% by weight or more of particles of 15 mμ, quick drying properties are improved, as is clear from the results of the test examples, and it is possible to improve It has excellent workability when applied to tanks, etc., and the coating film formed after application has the effect of being free of tails and scratches.
特許出願人 日産自動車株式会社Patent applicant: Nissan Motor Co., Ltd.
Claims (1)
の成分と充填剤成分を必須成分として含む自動車用塗布
剤であって、乾燥促進剤として超微粒子（粒径２〜１５
ｍμの粒子が８０重量％以上）の無水シリカを塗布剤成
分の０．１〜１０重量％を含有してなることを特徴とす
る速乾性自動車用塗布剤。1. An automotive coating agent containing as essential components one or more of a wax component and a synthetic resin component and a filler component, which contains ultrafine particles (particle size 2-15) as a drying accelerator.
1. A quick-drying coating agent for automobiles, characterized in that the coating agent contains 0.1 to 10% by weight of anhydrous silica (80% by weight or more of particles having a diameter of mμ) based on the coating agent components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63039717A JP2674064B2 (en) | 1988-02-24 | 1988-02-24 | Quick-drying automotive coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63039717A JP2674064B2 (en) | 1988-02-24 | 1988-02-24 | Quick-drying automotive coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01215866A true JPH01215866A (en) | 1989-08-29 |
| JP2674064B2 JP2674064B2 (en) | 1997-11-05 |
Family
ID=12560736
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63039717A Expired - Fee Related JP2674064B2 (en) | 1988-02-24 | 1988-02-24 | Quick-drying automotive coating |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2674064B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0497560A2 (en) * | 1991-01-29 | 1992-08-05 | Nihon Parkerizing Co., Ltd. | Process for forming a composite film on a metal substrate |
| CN112011202A (en) * | 2020-08-20 | 2020-12-01 | 山东北方创信防水科技集团股份有限公司 | SiO (silicon dioxide)2Preparation method of modified chloroprene rubber flame-retardant heat-insulation waterproof coating |
| JP2021525827A (en) * | 2018-12-18 | 2021-09-27 | フツクス ペトロループ ソシエタス・ヨーロピアＦｕｃｈｓ Ｐｅｔｒｏｌｕｂ Ｓｅ | Cavity protection anticorrosive and its use |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943075A (en) * | 1982-09-02 | 1984-03-09 | Kubokou Paint Kk | Rust-preventive, corrosion-resisting coating composition |
-
1988
- 1988-02-24 JP JP63039717A patent/JP2674064B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943075A (en) * | 1982-09-02 | 1984-03-09 | Kubokou Paint Kk | Rust-preventive, corrosion-resisting coating composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0497560A2 (en) * | 1991-01-29 | 1992-08-05 | Nihon Parkerizing Co., Ltd. | Process for forming a composite film on a metal substrate |
| EP0497560A3 (en) * | 1991-01-29 | 1994-01-19 | Nihon Parkerizing | |
| JP2021525827A (en) * | 2018-12-18 | 2021-09-27 | フツクス ペトロループ ソシエタス・ヨーロピアＦｕｃｈｓ Ｐｅｔｒｏｌｕｂ Ｓｅ | Cavity protection anticorrosive and its use |
| US11220607B2 (en) | 2018-12-18 | 2022-01-11 | Fuchs Petrolub Se | Anticorrosive agent for cavity preservation, and use thereof |
| CN112011202A (en) * | 2020-08-20 | 2020-12-01 | 山东北方创信防水科技集团股份有限公司 | SiO (silicon dioxide)2Preparation method of modified chloroprene rubber flame-retardant heat-insulation waterproof coating |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2674064B2 (en) | 1997-11-05 |
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