JPH01210488A - Blowoff method of volatile matter - Google Patents
Blowoff method of volatile matterInfo
- Publication number
- JPH01210488A JPH01210488A JP63034563A JP3456388A JPH01210488A JP H01210488 A JPH01210488 A JP H01210488A JP 63034563 A JP63034563 A JP 63034563A JP 3456388 A JP3456388 A JP 3456388A JP H01210488 A JPH01210488 A JP H01210488A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- volatile matter
- energy
- volatile
- volatile substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 25
- 239000000126 substance Substances 0.000 claims description 42
- 239000003094 microcapsule Substances 0.000 claims description 25
- 238000000638 solvent extraction Methods 0.000 abstract 1
- 239000003205 fragrance Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 6
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 6
- 239000002775 capsule Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229930007503 menthone Natural products 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- -1 cyclodextrin Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 description 3
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 3
- QGLVWTFUWVTDEQ-UHFFFAOYSA-N 2-chloro-3-methoxyphenol Chemical compound COC1=CC=CC(O)=C1Cl QGLVWTFUWVTDEQ-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052918 calcium silicate Inorganic materials 0.000 description 3
- 239000000378 calcium silicate Substances 0.000 description 3
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 3
- WJSDHUCWMSHDCR-VMPITWQZSA-N cinnamyl acetate Natural products CC(=O)OC\C=C\C1=CC=CC=C1 WJSDHUCWMSHDCR-VMPITWQZSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 description 3
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229920000858 Cyclodextrin Polymers 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 241000207840 Jasminum Species 0.000 description 2
- 235000010254 Jasminum officinale Nutrition 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- JLQFVGYYVXALAG-CFEVTAHFSA-N yasmin 28 Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1.C([C@]12[C@H]3C[C@H]3[C@H]3[C@H]4[C@@H]([C@]5(CCC(=O)C=C5[C@@H]5C[C@@H]54)C)CC[C@@]31C)CC(=O)O2 JLQFVGYYVXALAG-CFEVTAHFSA-N 0.000 description 1
Landscapes
- Seasonings (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、揮発性物質の放出方法に関し、揮発性物質を
自動的に変えることが出来、放出量を自由に調節するこ
とが出来る方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for releasing volatile substances, and relates to a method in which volatile substances can be automatically changed and the amount released can be freely adjusted. .
（従来技術）
香料の様な揮発性物質の放出方法としては、香料等をプ
ラスチックの容器に収納したり、又はプラスチックに直
接線り込んだもの、ケイ酸カルシウム等の無機物に吸着
させたもの、或いはシクロデキストリンの様な包接化合
物に包含させたものをカード状或いはシート状に成型し
、室温下で徐放させる方法がある。しかし、これらの方
法には次の様な問題がある。(Prior art) Methods for releasing volatile substances such as fragrances include storing fragrances in plastic containers or directly inserting them into plastic, adsorbing them on inorganic materials such as calcium silicate, etc. Alternatively, there is a method in which the compound is encapsulated in an inclusion compound such as cyclodextrin, molded into a card or sheet, and then released slowly at room temperature. However, these methods have the following problems.
■ 使用初期には、大量に放出され、経時的に放出量が
少なくなる。■ At the beginning of use, a large amount is released, and the amount released decreases over time.
■ −度使い始めると同一の香りが長期間続く。■ Once you start using it, the same scent will last for a long time.
■ 必要のない時も放出され続ける。■Continues to be emitted even when it is not needed.
例えば揮発性物質が香料の場合、同一の香りを嗅ぎ続け
ると、嗅覚が鈍くなるため、上記の問題は、香りを楽し
むという観点からは一層不都合となる。For example, if the volatile substance is a fragrance, the sense of smell becomes dull if one continues to smell the same fragrance, so the above problem becomes even more inconvenient from the perspective of enjoying the fragrance.
従来香料をケイ酸カルシウムに吸着させたものをカード
状に成形し、カードを加熱して必要な時だけ放出させる
方法も提案されている。しかし、この方法においても匂
いの種類を変えるには、その都度人手によりカードを差
し換える必要があり、また使用の初期のみに揮発性物質
が大量に放出されるという欠点がある。Conventionally, a method has also been proposed in which fragrance is adsorbed on calcium silicate, formed into a card, and the curd is heated to release the fragrance only when necessary. However, this method also has the disadvantage that it is necessary to manually replace the card each time to change the type of odor, and that a large amount of volatile substances are released only at the initial stage of use.
（発明が解決しようとする課題）
本発明は、使用初期に大量に放出され、また不要な時も
一律に揮発性物質が放出されるという従来の放出方法の
問題を解決すると同時に適宜異なる物質を自動的に放出
させる方法を提供することを目的とする。(Problems to be Solved by the Invention) The present invention solves the problems of the conventional release method in which a large amount of volatile substances are released at the initial stage of use, and also uniformly releases volatile substances even when unnecessary. The purpose is to provide a method for automatic release.
（課題を解決するための手段）
本発明は、シートを複数の領域に区分けし、各領域に異
なる揮発性物質を含有させ、該シートにエネルギーを与
えながらエネルギー付与装置の付与部分に対して該シー
トを移動させることにより異なる揮発性物質を順次放出
させるか、又は異なる揮発性物質をそれぞれ含有させた
複数のシートの内から、順次目的とする揮発性物質を含
有するシートにエネルギーを与えながらエネルギー付与
装置の付与部分に対して該目的とするシートを移動させ
ることにより異なる揮発性物質を放出させる方法である
。(Means for Solving the Problems) The present invention divides a sheet into a plurality of regions, each region contains a different volatile substance, and while applying energy to the sheet, applies the volatile substance to the applying portion of an energy applying device. By moving the sheets, different volatile substances are sequentially released, or from among a plurality of sheets each containing a different volatile substance, energy is sequentially applied to the sheet containing the desired volatile substance. This is a method in which different volatile substances are released by moving the target sheet relative to the application section of the application device.
（作用）
本発明においては、例えば異なる揮発性物質を同一シー
トの異なる箇所に区分けして含有させ、該シートを駆動
装置で移動させながら加熱等により揮発性物質を順次放
出させるが（第１図）、又は異なる揮発性物質を含有さ
せた複数のシートを準備し、必要なシートを移動させな
がら加熱等して、各シートから順次揮発性物質を適宜放
出させ、或いは全シートを移動させながらサーマルヘッ
ド等により必要なシートのみを加熱して揮発性物質を順
次放出する（第２図）。(Function) In the present invention, for example, different volatile substances are contained in different parts of the same sheet, and while the sheet is moved by a drive device, the volatile substances are sequentially released by heating or the like (see Fig. 1). ), or by preparing multiple sheets containing different volatile substances and heating them while moving the necessary sheets to release the volatile substances from each sheet in turn, or by thermal heating while moving all the sheets. Only the necessary sheets are heated by a head or the like to sequentially release volatile substances (Figure 2).
揮発性物質を支持体に含有させる方法としては揮発性物
質を■マイクロカプセルに内包して支持体に含有させる
。■ケイ酸カルシウム等に吸着して支持体に含有させる
。■シクロデキストリン等の包接化合物に包含して支持
体に含有させる。■そのままの状態で支持体に吸着或い
は含浸する等積々の態様で行うことができる。この内で
も、■マイクロカプセルを利用する方法は、不要な時に
揮発性物質を全く放出させず、必要な時にのみ放出させ
ることが出来（即ち０Ｎ１０ＦＦ機能を有する）、又シ
ートの保存中に飛散して無くなることがないため特に好
ましい。As a method for incorporating a volatile substance into a support, the volatile substance is encapsulated in microcapsules and incorporated into the support. ■ Adsorb onto calcium silicate, etc., and incorporate it into the support. (2) Include it in a clathrate compound such as cyclodextrin and incorporate it into a support. (2) It can be carried out in a number of ways, such as by adsorbing or impregnating it on a support as it is. Among these methods, ■method using microcapsules does not release volatile substances at all when unnecessary, but releases them only when necessary (i.e., has a 0N10FF function), and also prevents volatile substances from scattering during storage of the sheet. It is particularly preferable because it will not run out.
本発明では揮発性物質含有シートに熱、圧、光等のエネ
ルギーを付与することにより揮発性物質を放出させるが
、特に熱を利用した場合、揮発性物質の蒸発を促進出来
る利点がある。熱エネルギーの付与方法としては、シー
トを熱板、熱ロール等の熱付与装置に押し付けたり、サ
ーマルヘッドにより付与する方法などがあり、加熱時間
、加熱温度により放出量を調整することができる。通常
５０℃〜３００℃の熱板等で加熱する。In the present invention, volatile substances are released by applying energy such as heat, pressure, light, etc. to a volatile substance-containing sheet, and in particular, when heat is used, there is an advantage that evaporation of volatile substances can be accelerated. Methods for applying thermal energy include pressing the sheet against a heat applying device such as a hot plate or a heating roll, or applying it using a thermal head, and the amount of heat energy released can be adjusted by adjusting the heating time and heating temperature. It is usually heated with a hot plate or the like at 50°C to 300°C.
揮発性物質をマイクロカプセル中に包含させた場合熱、
圧、光等いずれのエネルギーでもカプセルを崩壊或いは
カプセル壁膜を透過性として、揮発性物質を放出できる
。また吸着剤、包接化合物を利用した場合及び単にシー
トに含浸等した場合は熱、光が有効である。When volatile substances are encapsulated in microcapsules, heat,
Any energy such as pressure or light can disintegrate the capsule or make the capsule wall transparent and release volatile substances. Heat and light are also effective when using an adsorbent or clathrate compound, or when simply impregnating a sheet.
本発明゛においては熱板等の熱エネルギー付与装置、加
圧ロール等の加圧装置、ランプ等の投光装置と揮発性物
質含をシートを相対的に移動させながら、シートの異な
る部分より香料等を放出させるため経時的に放出量が減
少する欠点がない。In the present invention, while the sheet is relatively moved with a thermal energy applying device such as a hot plate, a pressure device such as a pressure roll, a lighting device such as a lamp, and a volatile substance-containing device, fragrance is applied from different parts of the sheet. etc., so there is no drawback that the amount released decreases over time.
熱や圧力で崩壊或いは壁膜が透過性となるマイクロカプ
セルについては各種のものが知られており、公知のマイ
クロカプセルのうちから適宜選択して使用することがで
きる。Various types of microcapsules are known that disintegrate with heat or pressure or whose walls become permeable, and can be appropriately selected from known microcapsules for use.
具体的には、ポリウレタン、ポリウレア、ポリアミド、
ポリエステル、ポリカーボネート、尿素−ホルムアルデ
ヒド樹脂、メラミン−ホルムアルデヒド樹脂、塩化ビニ
リデン−アクリロニトリル共重合体、ポリスチレン、ゼ
ラチン、ポリビニルアルコール等の壁膜を有するマイク
ロカプセルが挙げられるが、なかでもポリウレタン、ポ
リウレア、ポリアミド、ポリエステル、ポリカーボネー
ト、ゼラチン、メラミン−ホルムアルデヒド樹脂を壁膜
とするマイクロカプセルは内包物保持性に優れるため好
ましく用いられる。Specifically, polyurethane, polyurea, polyamide,
Examples include microcapsules with wall membranes such as polyester, polycarbonate, urea-formaldehyde resin, melamine-formaldehyde resin, vinylidene chloride-acrylonitrile copolymer, polystyrene, gelatin, polyvinyl alcohol, among others, polyurethane, polyurea, polyamide, polyester. Microcapsules having walls made of polycarbonate, gelatin, or melamine-formaldehyde resin are preferably used because of their excellent ability to retain inclusions.
光により崩壊するマイクロカプセルとしては特開昭６２
−５７６４６．特開昭６２−５７６４７に記載の光によ
り酸を発生する化合物とシリルウレイド結合を有する重
合膜から成るマイクロカプセル、光により酸を発生する
化合物とシリルエーテル結合を有する重合膜から成るマ
イクロカプセル等がある。As a microcapsule that disintegrates when exposed to light, JP-A-62
-57646. Microcapsules made of a compound that generates an acid when exposed to light and a polymer film having a silyl ureide bond, and microcapsules that are made of a compound that generates an acid when exposed to light and a polymer membrane that has a silyl ether bond, as described in JP-A No. 62-57647. be.
本発明においては支持体シートとして紙、合成紙、フィ
ルム等を用いる事ができ、含有させる方法としては、マ
イクロカプセル、吸着剤、包接化合物等を支持体シート
表面に塗布する方法、紙に抄き込む方法、フィルムに練
り込む方法等がある。In the present invention, paper, synthetic paper, film, etc. can be used as the support sheet. Methods for incorporating microcapsules, adsorbents, clathrate compounds, etc. include methods of applying microcapsules, adsorbents, clathrate compounds, etc. to the surface of the support sheet; There are several methods, such as embedding and kneading into film.
この中でも、工程の簡単さ、揮発性物質の安定性、保持
性の面から塗布する方法が好ましい。塗布する場合には
、マイクロカプセル、包接体、吸着体などの揮発性物質
含有物を支持体に固定する為の接着剤、及びその他必要
に応じて塗工性を付与する為の界面活性剤、流動性調整
剤、各種助剤を添加して塗工液を調製し、塗布を行う。Among these, the coating method is preferred from the viewpoint of simplicity of process, stability of volatile substances, and retention. When coating, adhesives are used to fix volatile substance-containing substances such as microcapsules, clathrates, adsorbents, etc. to the support, and other surfactants are used to impart coating properties as necessary. , a fluidity modifier, and various auxiliary agents are added to prepare a coating solution, and the coating is performed.
接着剤としては例えばポリビニルアルコール及びその誘
導体、澱粉及びその誘導体、カゼイン、ポリアクリル酸
共重合体等水溶性高分子や、スチレン−ブタジェン共重
合体ポリ （メタ）アクリル酸エステル共重合体、エチ
レン−酢酸ビニル共重合体等高分子エマルジョン等が用
いられる。Examples of adhesives include polyvinyl alcohol and its derivatives, starch and its derivatives, casein, water-soluble polymers such as polyacrylic acid copolymers, styrene-butadiene copolymers, poly(meth)acrylic acid ester copolymers, and ethylene-butadiene copolymers. Polymer emulsions such as vinyl acetate copolymers are used.
接着剤は通常揮発性物質を含有するマイクロカプセル、
包接化合物、吸着剤等１００重量部に対して１〜１００
重量部用いるのが好ましい。マイクロカプセル等が多い
と充分な接着性が得られず、少ないと放出量が少なくな
る。Adhesives usually contain microcapsules containing volatile substances,
1 to 100 per 100 parts by weight of clathrate compounds, adsorbents, etc.
Preferably, parts by weight are used. If there are too many microcapsules, sufficient adhesion cannot be obtained, and if there are too few, the amount released will be small.
揮発性物質の含有量は、用途により異なるが、香料の場
合では、通常シートに１ ｇ／ｒｄ〜５０ｇ／ｄ含有さ
せる。１ ｇ／ｃｄより少ないと放出量が少なく、５０
ｇ／ｎｌより多いと放出量が多過ぎて不快になったり、
放出効率が悪くなる。The content of volatile substances varies depending on the use, but in the case of fragrances, the sheet usually contains 1 g/rd to 50 g/d. If it is less than 1 g/cd, the amount released is small, and 50
If it is more than g/nl, the amount released may be too large and cause discomfort.
Release efficiency deteriorates.
本発明における揮発性物質としては、メントン、酢酸ゲ
ラニル、酢酸シンナミル、プロピオン酸ベンジル等の香
料、ピレトリン等の殺（防）主剤等があり、単独でも併
用して用いることもできる。Volatile substances in the present invention include fragrances such as menthone, geranyl acetate, cinnamyl acetate, and benzyl propionate, and main killing (preventive) agents such as pyrethrin, which can be used alone or in combination.
以下、実施例を挙げて本発明を説明するがこれに限定さ
れるものではない。尚、部及び％は重量部、重量％を表
す。The present invention will be explained below with reference to Examples, but the present invention is not limited thereto. Note that parts and % represent parts by weight and % by weight.
（実施例）
実施例１
〔香料含有マイクロカプセルの調製〕
調製例−１
メントン１００部に、ヘキサメチレンジイソシアネート
とトリメチロールプロパンの付加物（商品名：タケネー
）Ｄ１６ＯＮ、武田薬品工業社製）６０部を溶解して内
相液（芯物質）を調製した。(Examples) Example 1 [Preparation of fragrance-containing microcapsules] Preparation example-1 100 parts of menthone and 60 parts of an adduct of hexamethylene diisocyanate and trimethylolpropane (trade name: Takene D16ON, manufactured by Takeda Pharmaceutical Company Limited) An internal phase liquid (core material) was prepared by dissolving the following.
部分ケン化ポリビニルアルコール（商品名：ＰＶＡ−２
１７ＥＥ、クラレ社製）の１０％水溶液１８０部に水２
２０部を加え、これに上記内相液を添加し、２０℃で乳
化し、平均粒子径２μｍの乳化液を得た。この乳化液を
攪拌しながら６０℃に昇温し、そのまま３時間反応させ
てメントンを内包するマイクロカプセル分散液Ａを得た
。Partially saponified polyvinyl alcohol (product name: PVA-2
180 parts of a 10% aqueous solution of 17EE (manufactured by Kuraray) and 2 parts of water.
20 parts were added thereto, and the above-mentioned internal phase liquid was added thereto and emulsified at 20°C to obtain an emulsion having an average particle size of 2 μm. This emulsion was heated to 60° C. while stirring, and reacted for 3 hours to obtain a microcapsule dispersion A containing menthone.
調製例−２
メントン１００部の代わりに酢酸ゲラニル１００部を使
用し、タケネートＤ１６ＯＮの使用量を４０部とした以
外は調製例１と同様にして、平均粒子径２．５μｍの酢
酸ゲラニルを内包したマイクロカプセル分散液Ｂを得た
。Preparation Example-2 Geranyl acetate with an average particle size of 2.5 μm was encapsulated in the same manner as Preparation Example 1, except that 100 parts of geranyl acetate was used instead of 100 parts of menthone, and the amount of Takenate D16ON was changed to 40 parts. Microcapsule dispersion B was obtained.
亘敦勇二主
メントン１００部の代わりに酢酸シンナミル１００部を
、又タケネートＤ１６ＯＮの量を８０部にした以外は調
製例１と同様にして、平均粒子径３μｍの酢酸シンナミ
ルを内包したマイクロカプセル分散液Ｃを得た。Yuji Wataru Atsushi A microcapsule dispersion containing cinnamyl acetate with an average particle size of 3 μm was prepared in the same manner as in Preparation Example 1, except that 100 parts of cinnamyl acetate was used instead of 100 parts of main menthone, and the amount of Takenate D16ON was changed to 80 parts. I got a C.
皿翌斑二↓
メントン１００部の代わりにプロピオン酸ベンジル１０
０部を、又タケネートＤ１６ＯＮの量を８０部にした以
外は調製例１と同様にして、平均粒子径３μｍのプロピ
オン酸ベンジルを内包したマイクロカプセル分散液りを
得た。Madaraji after the dish ↓ 10 parts of benzyl propionate instead of 100 parts of menthone
A microcapsule dispersion containing benzyl propionate with an average particle diameter of 3 μm was obtained in the same manner as in Preparation Example 1 except that the amount of Takenate D16ON was changed to 80 parts.
調製例１〜４で得られたマイクロカプセル分散液を坪量
４０ｇ／イの上質紙に乾燥塗布量１５ｇ／ｍ′になる様
にスクリーン印刷した。第１図に示す様にマイクロカプ
セル分散液Ａ−Ｄを塗布領域がシートの移動方向に対し
各１０ｃｍの長さで、それぞれが５ｃｍの間隔を保つよ
うに印刷した。The microcapsule dispersions obtained in Preparation Examples 1 to 4 were screen printed on high-quality paper with a basis weight of 40 g/m' to a dry coating weight of 15 g/m'. As shown in FIG. 1, microcapsule dispersions A to D were printed in such a manner that the coated areas each had a length of 10 cm in the direction of movement of the sheet and were spaced apart by 5 cm.
香料含有マイクロカプセル塗布シートを２０ｃｍ／時間
の速度で移動させ、１６０℃の熱板（１１で加熱した。The perfume-containing microcapsule-coated sheet was moved at a speed of 20 cm/hour and heated on a hot plate (11) at 160°C.
その結果、ハツカ様、バラ様、ニッキ様、ジャスミン様
の香りが１５分の間隔をおいてそれぞれ３０分間発せら
れた。As a result, the scents of honey, rose, Nikki, and jasmine were emitted for 30 minutes at 15-minute intervals.
実施例２
実施例１で得られたマイクロカプセルを４枚の上質紙（
坪量５０ ｇ／ｒｄ）に、乾燥塗布量が２５ｇ／ｒｄに
なる様にメイヤーバーで塗布した。Example 2 The microcapsules obtained in Example 1 were placed on four sheets of high-quality paper (
It was applied with a Mayer bar to a dry coating amount of 25 g/rd (basis weight 50 g/rd).
第２図に示す様にサーマルヘッド（２）のａ、ｂ。As shown in FIG. 2, a and b of the thermal head (2).
ｃ、ｄの各ブロック順に熱を付与しながら４枚のシート
を１０ｃｍ／時間の速度で移動させた（ａブロックで熱
を付与している時は他のブロックに熱は掛かっていない
）。The four sheets were moved at a speed of 10 cm/hour while applying heat to each block c and d in order (when heat was applied to block a, no other blocks were applied with heat).
その結果、ハツカ様、バラ様、ニソキ様、ジャスミン様
の香りが順次発せられた。As a result, the scents of Hatsuka, rose, Nisoki, and jasmine were emitted in sequence.
（効果）
本発明は特定量の揮発性物質を特定時間自動的に放出す
ることが出来、更に揮発性物質の種類も自動的に変える
ことが出来る優れた放出方法であった。(Effects) The present invention is an excellent release method that can automatically release a specific amount of a volatile substance for a specific time, and can also automatically change the type of volatile substance.
第１図は、実施例１の方法を示す斜視図である。Ａ、Ｂ
、Ｃ，Ｄで示された部分にそれぞれカプセル分散液Ａ、
Ｂ、Ｃ，Ｄを塗布した一枚のシートを熱板に対して移動
させながら熱によりカプセル内包物を揮発させた。
第２図は、実施例２の方法を示す斜視図である。Ａ、Ｂ
、Ｃ，Ｄで示されたシートにそれぞれカプセル分散液Ａ
、Ｂ、Ｃ，Ｄを塗布し、各シートを移動させながらサー
マルヘッドの各ブロック（ａ〜ｄ）に熱を掛けてカプセ
ル内包物を揮発させた。FIG. 1 is a perspective view showing the method of Example 1. A, B
Capsule dispersion A,
A sheet coated with B, C, and D was moved against a hot plate to volatilize the capsule contents by heat. FIG. 2 is a perspective view showing the method of Example 2. A, B
Capsule dispersion A is applied to the sheets indicated by , C, and D, respectively.
, B, C, and D were applied, and while moving each sheet, heat was applied to each block (a to d) of the thermal head to volatilize the capsule contents.
Claims (2)
揮発性物質を含有させ、該シートにエネルギーを与えな
がらエネルギー付与装置の付与部分に対して該シートを
移動させることにより異なる揮発性物質を順次放出させ
るか、又は異なる揮発性物質をそれぞれ含有させた複数
のシートの内から、順次目的とする揮発性物質を含有す
るシートにエネルギーを与えながらエネルギー付与装置
の付与部分に対して該目的とするシートを移動させるこ
とにより異なる揮発性物質を放出させる方法。(1) A sheet is divided into a plurality of regions, each region is made to contain a different volatile substance, and the sheet is moved relative to the application part of the energy application device while applying energy to the sheet, whereby different volatile substances are added. or sequentially release energy to sheets containing a desired volatile substance from among a plurality of sheets each containing a different volatile substance, while applying energy to the application part of the energy application device for the purpose. A method of emitting different volatile substances by moving a sheet.
ことを特徴とする請求項（１）記載の方法。(2) The method according to claim (1), wherein the volatile substance is encapsulated in microcapsules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63034563A JPH01210488A (en) | 1988-02-17 | 1988-02-17 | Blowoff method of volatile matter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63034563A JPH01210488A (en) | 1988-02-17 | 1988-02-17 | Blowoff method of volatile matter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01210488A true JPH01210488A (en) | 1989-08-24 |
Family
ID=12417784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63034563A Pending JPH01210488A (en) | 1988-02-17 | 1988-02-17 | Blowoff method of volatile matter |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01210488A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999066791A1 (en) | 1998-06-22 | 1999-12-29 | S.C. Johnson & Son, Inc. | Volatile carrier for use with a heating device |
| US6419898B1 (en) | 2000-09-14 | 2002-07-16 | S.C. Johnson & Son, Inc. | Insect coil |
| WO2011077491A1 (en) * | 2009-12-25 | 2011-06-30 | 大栄工業株式会社 | Substrate for evaporating volatile component and method for evaporating volatile component |
| JP2014507193A (en) * | 2010-12-30 | 2014-03-27 | コーウェイ カンパニー リミテッド | Sterilization pad, sterilization pad manufacturing method, toilet seat having sterilization pad, and toilet bowl sterilization method |
| WO2015129510A1 (en) * | 2014-02-28 | 2015-09-03 | 大王製紙株式会社 | Method of producing scented tissue paper product |
| WO2019039385A1 (en) * | 2017-08-21 | 2019-02-28 | 富士フイルム株式会社 | Microcapsule, composition, and sheet for cosmetics |
-
1988
- 1988-02-17 JP JP63034563A patent/JPH01210488A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999066791A1 (en) | 1998-06-22 | 1999-12-29 | S.C. Johnson & Son, Inc. | Volatile carrier for use with a heating device |
| US6078728A (en) * | 1998-06-22 | 2000-06-20 | S. C. Johnson & Son, Inc. | Volatile carrier for use with a heating device |
| US6419898B1 (en) | 2000-09-14 | 2002-07-16 | S.C. Johnson & Son, Inc. | Insect coil |
| WO2011077491A1 (en) * | 2009-12-25 | 2011-06-30 | 大栄工業株式会社 | Substrate for evaporating volatile component and method for evaporating volatile component |
| JP2014507193A (en) * | 2010-12-30 | 2014-03-27 | コーウェイ カンパニー リミテッド | Sterilization pad, sterilization pad manufacturing method, toilet seat having sterilization pad, and toilet bowl sterilization method |
| WO2015129510A1 (en) * | 2014-02-28 | 2015-09-03 | 大王製紙株式会社 | Method of producing scented tissue paper product |
| JP2015160652A (en) * | 2014-02-28 | 2015-09-07 | 大王製紙株式会社 | Manufacturing method of tissue paper product having aroma |
| CN106029521A (en) * | 2014-02-28 | 2016-10-12 | 大王制纸株式会社 | Method of producing scented tissue paper product |
| US10106929B2 (en) | 2014-02-28 | 2018-10-23 | Daio Paper Corporation | Method of producing scented tissue paper product |
| WO2019039385A1 (en) * | 2017-08-21 | 2019-02-28 | 富士フイルム株式会社 | Microcapsule, composition, and sheet for cosmetics |
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