JPH01208384A - China-painting - Google Patents
China-paintingInfo
- Publication number
- JPH01208384A JPH01208384A JP3246488A JP3246488A JPH01208384A JP H01208384 A JPH01208384 A JP H01208384A JP 3246488 A JP3246488 A JP 3246488A JP 3246488 A JP3246488 A JP 3246488A JP H01208384 A JPH01208384 A JP H01208384A
- Authority
- JP
- Japan
- Prior art keywords
- glaze
- weight
- emulsion
- painting
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000010422 painting Methods 0.000 title claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000178 monomer Substances 0.000 claims abstract description 21
- 125000000129 anionic group Chemical group 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 13
- 229920001577 copolymer Polymers 0.000 claims abstract description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 5
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 4
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000010304 firing Methods 0.000 claims description 13
- 239000000919 ceramic Substances 0.000 claims description 9
- 239000012874 anionic emulsifier Substances 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000012875 nonionic emulsifier Substances 0.000 claims description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000002585 base Substances 0.000 description 8
- 241000951471 Citrus junos Species 0.000 description 7
- 229910052573 porcelain Inorganic materials 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- -1 chromium-based green Chemical class 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 235000011511 Diospyros Nutrition 0.000 description 3
- 244000236655 Diospyros kaki Species 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 1
- RWXMAAYKJDQVTF-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl prop-2-enoate Chemical compound OCCOCCOC(=O)C=C RWXMAAYKJDQVTF-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical group CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- 241000512259 Ascophyllum nodosum Species 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241001061127 Thione Species 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000006063 cullet Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical group CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000009377 nuclear transmutation Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical group CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 208000037974 severe injury Diseases 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Decoration By Transfer Pictures (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
【発明の詳細な説明】
〔韮東上のオリ用分封」
不発Ｌ４Ａは、釉薬熟成と転柄央成とを同時に行なう法
灯方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Niratojo's Ori Separation] Fusatsu L4A relates to a method for carrying out glaze maturing and turning of the glaze at the same time.
〔促米蚊術」
陶磁器やほうろう等の梃付けを行なうンこは、戴属又は
締焼きし′ｆｃ陶磁器素地に生釉？施釉したのち、１０
００〜１４００℃程度で熟成してから、転写紙上に形成
した絵柄層をその上に転写し、更に５００〜１０００℃
程度で焼成し、絵柄Ｊ−に含まｎるせ成樹脂全分解挿散
させる方法がとられてきた。[Mosquito technique to promote rice] Is the pottery used to hold ceramics, enamel, etc., glazed or glazed? After glazing, 10
After aging at about 00 to 1400℃, the pattern layer formed on the transfer paper is transferred onto it, and then aged at 500 to 1000℃.
A method has been used in which the resin contained in the pattern J- is completely decomposed and dispersed by firing at a certain level.
この方法では、釉薬の焼成と絵柄層の焼成の二つの工程
が必要であジ、作業が複雑で熱効率が悪く、離断的に不
利な欠点があった。This method requires two steps: firing the glaze and firing the pattern layer, and has the drawbacks of complicated work, poor thermal efficiency, and disadvantages in terms of separation.
上記の方法を改善するために熱処理を一工程とする方式
、つ筐り合成樹脂エマルジョンｔたは水溶性高分子、筐
たはそｎらの混付物を生体とするプライマーを生釉ノー
表面に施した後、次いで転写用絵柄を密層させ、釉栄の
熟成と絵柄層の焼成とを同時に行なう方法が提案さ几た
（特公昭６０−４５０７３号）。この方法では、熱処理
工程は一回と簡略化ちルたが、生釉上に水を多く含む高
分子水溶故、つ−ｊジブライマーを塗布するために、柚
楽ノーを傷つけるおそ几が残っている。In order to improve the above method, a method in which heat treatment is one step is used, and a primer containing a mixture of synthetic resin emulsion, water-soluble polymer, and other substances as a living body is applied to the unglazed surface A method was proposed (Japanese Patent Publication No. 45073/1983) in which the glaze was applied to the glaze, and then the pattern for transfer was layered in a dense layer, and the glaze was aged and the pattern layer was fired at the same time. This method simplifies the heat treatment process to just one time, but since the polymer water-soluble polymer contains a lot of water, there is still a risk of damaging the yuzuraku no by applying diburimer on the raw glaze. There is.
父、釉薬を熟成する前の生釉に絵付を行う方法は絵柄と
の密着力が弱い。この改良に生釉中に樹脂紹せ剤の根付
や、生釉上へのプライマー堕布があるがこの方法では絵
柄ノーとの＠層性と接層性が悲ぐ、予備乾燥時および焼
灰時に絵柄の浮き、ピンホール、励み等を起し不良率が
多い欠点があった。My father, the method of painting on raw glaze before the glaze is aged has a weak adhesion to the pattern. This improvement includes attaching a resin introduction agent into the raw glaze and dropping a primer onto the raw glaze, but this method suffers from layering and contact with the pattern, and during pre-drying and burning ash. It had the drawback of sometimes causing floating patterns, pinholes, and embossed patterns, resulting in a high defective rate.
この欠点を改良する方法として、水溶性高分子の水浴液
に転写紙から転与さ几る絵柄の皮膜形成剤である合成樹
脂と相溶性を有する溶剤及び／又は可塑剤を添加し、更
に所望ならば縞分子エマルジョンを添加してなる釉上転
写用プライマーに関し、更に該プライマー金生梱ノー上
に塗布し、ついで転写紙から転写用絵柄を転写した後現
成することにより、釉薬熟成と威信焼成と全同時に行な
う転性方法も提案された（％開昭５４−８１３１６号）
。この方法におい゛Ｃ１生釉（釉薬）とブライマー値布
が別々に行わｎる。As a method to improve this drawback, a solvent and/or plasticizer that is compatible with the synthetic resin that is the film forming agent for the pattern transferred from the transfer paper is added to the water bath solution of the water-soluble polymer, and Then, regarding the primer for transfer on glaze made by adding a striped molecular emulsion, the primer is further applied on the primer, and then the transfer pattern is transferred from the transfer paper and then developed, thereby achieving glaze maturation and prestige firing. A method of transmutation was also proposed in which both were performed at the same time.
. In this method, C1 raw glaze (glaze) and brimer value distribution are performed separately.
〔発明が解決しようとするａ題」
拙栄に、絵柄層と密層が良好であり、耐水性に冨む切崩
水性エマルジョンを配せした組成物音用い九ば施釉とプ
ライマー処理が一つの工程で隣まさ几ることを我々は考
えた。[Problem to be solved by the invention] A composition with a water-resistant emulsion that has a good pattern layer and dense layer and is rich in water resistance. We thought about going next door.
しかし、釉薬は、クロム系の緑、カドミウム系の黄〜赤
、コバルト糸の宵、鉄系の赤カッ色、酸化ナマリ系、ガ
ラス質系と各種の金属酸化物を含有するため、ＩｆｒＭ
ｔ中にアニオン系エマルジョンがゲル化もしくは増粘し
、塗布が困難となることが判明した。However, since the glaze contains various metal oxides such as chromium-based green, cadmium-based yellow to red, cobalt thread evening, iron-based reddish-brown, oxidized oxide, and glassy, IfrM
It was found that the anionic emulsion gelled or thickened during the t period of time, making it difficult to apply.
特公昭６１−１１９０３号公報には、アルカリ性の状態
で釉薬と佃脂水性エマルジョンを根付すると安定化し、
凝集が防げると記載されている。Japanese Patent Publication No. 61-11903 states that when a glaze and a soybean aqueous emulsion are allowed to take root in an alkaline state, it stabilizes.
It is stated that aggregation can be prevented.
しかし、経時的には安定と言えず、また、夏等の高温下
では容易にゲル化しやすい。However, it is not stable over time and tends to gel easily under high temperatures such as in summer.
不発明は、施釉とブライマー処理が一つの工程で行える
貯厭安定なエマルジョンを与えることを目的とする。The object of the invention is to provide a storage-stable emulsion in which glazing and brimering can be performed in one step.
不発明におい為では、アニオン性側脂水性エマルジョン
と拙楽根付漱のケル化防止のために、アニオンｆｆ４１
ｋ（脂水性エマルジョン中のカルボキシル基濃度ををと
し、ヒドロキシル基濃度を特定量とした。In order to prevent the anionic side fat aqueous emulsion and Kura Netsuke Sou from becoming kelp, we use anion FF41.
k (The carboxyl group concentration in the fat-aqueous emulsion was taken as , and the hydroxyl group concentration was taken as a specific amount.
即ち、本発明は、金属または１．Ｉｆｉｌ磁器の素地に
、水酸基含有不飽和ｉ量体０．３〜１０］１ｉｉ４と他
の不飽第１単量体と全乳化重合して得らｎた水酸基合有
共軍せ体のアニオン性樹脂エマルジョンに釉薬を配合し
た組成物で施釉し、ついで水スライド法により転写用絵
柄を転写し、又は、釉楽水分散欣をＭｔ２堕ジし絵付全
し、しかる後焼成することにより柚薬熱放と絵柄焼成と
全同時に杓うことを特徴とする絵付方法を提供するもの
である。That is, the present invention provides metal or 1. Anionic properties of the hydroxyl group-combined conjugate obtained by total emulsion polymerization of the hydroxyl group-containing unsaturated i-mer 0.3 to 10]1ii4 and other unsaturated first monomers on the Ifil porcelain base. Glaze with a composition containing a resin emulsion and a glaze, and then transfer the design using the water slide method, or use Mt2 to reduce the glaze water dispersion to complete the painting, and then fire to create a yuzuyaku heat effect. The present invention provides a painting method characterized by firing, firing, and lathing at the same time.
陶磁器用の素地原料としては５１０２・Ａｌ２Ｏ３が主
戚分で、カオリン、粘土、雲母、長石、ベントナイト、
珪石、滑石等が利用さ几、こ几らは脚台さｎ１秤濾さｆ
Ｌｆｃｆ＆、粉［孕機で細かく伜き（粉砕工程）、つい
で上線９し、脱泡さｎる（土材工程）。The main raw materials for ceramics are 5102.Al2O3, including kaolin, clay, mica, feldspar, bentonite,
Silica stone, talc, etc. are used, and these are used as a footrest.
Lfcf&, the powder is finely ground using a grinding machine (grinding process), then it is crushed and defoamed (soil material process).
この鞘軸した株主を、石・を型やろくろで望むべき形状
に成形し、乾燥させる（成形工程）。This sheathed shareholder is molded into the desired shape using a stone mold or a potter's wheel, and then dried (molding process).
乾燥′２！ｆ′した成形品素地は表面全なめらかＶこ仕
上げさｎ（生素地仕上工程）、匣結さｆｌ、１２００〜
１３００℃の高温に焼成される（峠焼工程）、次いで施
釉工程に廻さｎる。Dry '2! The entire surface of the molded product base with f' is smooth and V-finished (green base finishing process), casing fl, 1200~
It is fired at a high temperature of 1,300°C (touge firing process), and then goes to the glazing process.
施釉さ几るものは陶磁器ばかりでなく、耐熱性のある銅
、アルミニウム、鉄等の曾属、石であっても良い。The glazed object is not limited to ceramics, but may also be heat-resistant materials such as copper, aluminum, iron, etc., or stone.
（釉薬組成物）
生釉組成物は、（ａ）透明ユウ、色ユウ、結晶ユウや成
分による鉛釉、フリット柚、ブリストル柚、用途での磁
器釉、磁器釉等言われる釉薬と、（１））アニオン性樹
脂水性エマルジョンを少くとも含有する。(Glaze Composition) The raw glaze composition includes (a) glazes called transparent yu, colored yu, crystal yu, lead glaze, frit yuzu, bristol yuzu, porcelain glaze, porcelain glaze, etc. depending on the ingredients, and (1) ) Contains at least an aqueous anionic resin emulsion.
柚桑
釉薬を構成している原料を大きくわけると、■カレット
、酸化鉛、酸化状、酸化マンガン、アルミナ、シリカ、
酸化ナトリウム、酸化マグネシウム、酸化カルシウム寺
の戴属酸化物、塩化力ルシクム、［１、ドロマイト、Ｎ
ａＣ１％ Ｎａ２ Ｃ０３、硼砂、ソーダ長石、炭酸カ
リ、震母、葉長石等の融剤と、■酸化アンチモン、骨灰
、ｇＩ４［カルシウム、酸化錫、酸化ジルコニウム等の
乳濁剤と、■酸化コバルト、炭酸コバルト、酸化第２鋼
、二酸化マンガン、塩化鉄、三酸化モリブテン等の顔料
用原料にわけらｎる。これらは根付して用いられ、分類
すｎば、ＪｊＪ物の種類では、磁器釉、磁器釉等；融剤
の種類から分類すれば鉛柚、アルカリ釉、石灰釉、長石
釉、硼酸釉、アルカリ−石灰柚等；起源、産地、研死者
の名称から分類すればプリストル釉、ロツキンガム釉、
ゼーゲル磁器柚等；溶は易すさの面から低火度釉、中火
度釉、高火度稍；製遺方式あるいは釉掛けの方法から生
釉、食塩柚：特長ある性質から光沢袖、マット釉、乳濁
剤等に分類される。The raw materials that make up Yuzukuwa glaze can be roughly divided into: Cullet, lead oxide, oxidized manganese oxide, alumina, silica,
Sodium oxide, magnesium oxide, calcium oxide, chloride, [1, dolomite, N
Fluxing agents such as aC1% Na2 C03, borax, soda feldspar, potassium carbonate, seismic acid, and leaf feldspar; ■ Emulsifying agents such as antimony oxide, bone ash, gI4 [calcium, tin oxide, and zirconium oxide; ■ Cobalt oxide, Raw materials for pigments include cobalt carbonate, second steel oxide, manganese dioxide, iron chloride, and molybdenum trioxide. These are used as netsuke, and are categorized into porcelain glaze, porcelain glaze, etc.; categorized by type of flux, lead yuzu, alkali glaze, lime glaze, feldspar glaze, boric acid glaze, alkali glaze, etc. Lime yuzu, etc.; categorized based on origin, place of production, and name of the person who died: Priestl glaze, Rotskingum glaze,
Seegel porcelain yuzu, etc.; low heat glaze, medium heat glaze, high heat glaze due to ease of melting; raw glaze, salt yuzu due to the production method or glazing method: gloss sleeve, matte due to its distinctive properties It is classified into glazes, emulsifiers, etc.
例えばＳＫＩ ３の磁器釉の成分は次の通りである。For example, the components of SKI 3 porcelain glaze are as follows.
長石 ７３．５７重量係
マグ坏サイト ５．３５厘１％
石灰石 ０．８７）ｉ重係カオリン
５．６８直ｉｔ釜石英 １４．５３ ＸＭ％
又、釉薬分散液には分散剤や粘度調歪寺の為の増粘剤や
水溶性物質を加えても良い。Feldspar 73.57 weight kaolin 5.35 weight 1% Limestone 0.87) i weight kaolin
5.68 Straight pot quartz 14.53
樹脂水性エマルジョンは、例えば
（ａ）水酸基含有不飽和単量体
０．３〜ｌＯ重ｔ％
（ｂ）アクリル酸アルキルエステル（アルキル基の炭素
数は２〜８）
４０〜５５重ｔ％
（Ｃ）メタクリル酸メチル、スチレンおよびアクリロニ
トリルより選ばれた単量体
３０〜５５重童傷
（ｄ） Ｎ−フェニルマレイミド、Ｎ−メチロールアク
リル了ミド、了クリルアミド、メタクリルアミドより選
ば九た不飽和単量体
１〜１０重漬％
よりなるビニル単量体混合物１００１ム部を、アニオン
性乳化剤０．１〜５重量都およびノニオン性乳化剤θ〜
５Ｉ盪部の＃任ＦＶｃ汐１」えば過硫酸カルシウムの様
なＭ＠雁媒全用いて乳化１仕して・寿ら几るものである
。このエマルジョンは、柚＋ｒ−の皮膜化の面、皮膜の
硬さ、ベタツキによる汚ｎ等を考慮して造膜温度が１０
℃以上のエマルジョンが好箇しＡｏ
エマルジョン中の共重合体の水酸基（−ＯＨ）は、雀属
、陶磁器への素地との密着性や釉薬の分散性を良好とす
る。The aqueous resin emulsion is made of, for example, (a) 0.3 to 10% by weight of an unsaturated monomer containing a hydroxyl group (b) 40 to 55% by weight of an acrylic acid alkyl ester (the number of carbon atoms in the alkyl group is 2 to 8) (C ) A monomer selected from methyl methacrylate, styrene, and acrylonitrile with 30 to 55 severe injuries (d) An unsaturated monomer selected from N-phenylmaleimide, N-methylol acrylamide, acrylamide, and methacrylamide 1001 parts by weight of a vinyl monomer mixture consisting of 1 to 10% by weight of anionic emulsifier and 0.1 to 5% by weight of an anionic emulsifier and a nonionic emulsifier θ~
For example, use a medium such as calcium persulfate to emulsify the emulsion. This emulsion has a film-forming temperature of 10°C, taking into consideration factors such as the film formation of Yuzu+r-, the hardness of the film, and the contamination due to stickiness.
The hydroxyl group (-OH) of the copolymer in the emulsion improves the adhesion to the ceramic base and the dispersibility of the glaze.
（ａ）成分の水酸基含有不飽和単量体としては、２−ヒ
ドロキシエチルアクリレート、２−ヒドロキシエチルア
クリレート、ペンタエリスリトールテトラアクリレート
、ジエチレングリコールモノアクリレート等のアクリレ
ートおよびこ几らのメタクリレート相当物が利用できる
。As the hydroxyl group-containing unsaturated monomer of component (a), acrylates such as 2-hydroxyethyl acrylate, 2-hydroxyethyl acrylate, pentaerythritol tetraacrylate, diethylene glycol monoacrylate, and their methacrylate equivalents can be used.
貯蔵性、顔料分散性、密着性、耐水性の而からこの不飽
和単量体は帆３〜ｉｏ重量係の割合で用いら几る。From the viewpoint of storage stability, pigment dispersibility, adhesion, and water resistance, this unsaturated monomer is used in a proportion of 3 to 10% by weight.
（ｂ）ＩＪ５１分のアクリル跋アルキルエステルは、皮
膜にｏＴ涜性乞与えるソフトモノマーで、アクリル酸エ
チル、アクリル酸イングロビル、アクリル（ｉｎ・ブチ
ル、アクリルｍｔ・ブチル、アクリル酸ｎ−フロビル、
アクリル醒２−エチルヘキシル等カ用いら几る。(b) The acrylic alkyl ester with an IJ of 51 minutes is a soft monomer that provides oT degradation to the film, including ethyl acrylate, inglovir acrylate, acrylic (in-butyl, acrylic mt-butyl, n-furovir acrylate,
The acrylic acid is purified using 2-ethylhexyl or the like.
（Ｃ）［分のメタクリル酸メチル、アクリロニトリルま
たはスチレンは皮膜に強靭さを与えるハードモノマーで
あり、こｎらの一部をメタクリル酸エチル、メタクリル
酸イソプロピル、メタクリル酸イソブチルにおきかえて
もよい。(C) Methyl methacrylate, acrylonitrile, or styrene are hard monomers that give toughness to the film, and some of these may be replaced with ethyl methacrylate, isopropyl methacrylate, or isobutyl methacrylate.
（ｄ）ＵＸ、分の一部 〇Ｎｆ（２基、メチロール基全
有するビニルモノマーは陶磁器の素焼、金属、石への密
層性を付与するために用いる。(d) Part of UX, 〇Nf (2 groups, a vinyl monomer having all methylol groups is used to impart dense layering properties to unglazed ceramics, metals, and stones.
エマルジョン樹脂の粒径は、０．０５〜１ミクロンであ
り、エマルジョン樹脂」度が２０〜５５重量％のものが
通常使用される。The particle size of the emulsion resin is 0.05 to 1 micron, and those having an emulsion resin content of 20 to 55% by weight are usually used.
アニオン性樹脂水性エマルジョンは進常刀チオン・イオ
ンの混合により−ｆ：の安定性が低下するが、前出願（
特願昭６ｌ−１４７５８２）の発明では、カチオン・イ
オンであるカチオン乳化剤との混和安定性を改番する為
に、多重のノニオン乳化剤又は両性活性剤全配付するこ
とにより、その目的を、４成したが、ノニオン又は両性
乳化剤の種類及び童運びに混合手順が制限さｎる。In the anionic resin aqueous emulsion, the stability of -f: decreases due to the mixing of Shinjoto thione ions, but the previous application (
In the invention of Japanese Patent Application No. 61-147582, in order to change the miscibility with the cationic emulsifier, which is a cationic ion, by distributing multiple nonionic emulsifiers or amphoteric active agents, the purpose was achieved by four components. However, the mixing procedure is limited by the type of nonionic or amphoteric emulsifier and its handling.
本発明では、カチオンイオンを添加安定剤として用いる
ことなく直接混合できるようにするため、エマルジョン
共重含体として水酸基含有共重合体を用いた。In the present invention, a hydroxyl group-containing copolymer was used as an emulsion copolymer to enable direct mixing without using cation ions as an additive stabilizer.
このアニオン性樹脂水性エマルジョンは、釉薬と混付し
た際の粘度上昇やゲル化防止のため、共重合体を与える
（ａ）Ｉｆ分の水酸基含有不飽和単電体の便用量を０．
３〜１０重ｉ優とし、皮膜の冨層刀、耐水性、強度、エ
マルジョンの貯蔵安定性、（山系の分散性？良好とした
。This anionic resin aqueous emulsion is designed to prevent viscosity increase and gelation when mixed with a glaze, by reducing the amount of the hydroxyl group-containing unsaturated monoelectric material (a) that provides the copolymer to 0.
The weight of the film was rated as 3 to 10, and the film was evaluated as having good layer strength, water resistance, strength, emulsion storage stability, and (mountain dispersibility).
このエマルジョンは、釉薬組成物の粘度調整と、水スラ
イド法Ｖこよる転写紙を用いて釉薬層へ転写する際及び
ａ＃による絵付する際の釉薬層の耐水性同上による、ぐ
ずｎを防止するとともにエマルジョン樹脂皮膜による釉
薬ｊ−強度の向上、施釉後の商品の移動、作業時の釉薬
面の鶴付き防止、脱洛防止寺の釉薬面保護効果並びに、
絵柄層との密層性を良好とする。This emulsion adjusts the viscosity of the glaze composition, and prevents the water resistance of the glaze layer from fading when transferred to the glaze layer using transfer paper using the water slide method and when painting with A#. In addition, the emulsion resin film improves the strength of the glaze, prevents the movement of the product after glazing, prevents the glaze surface from sticking during work, protects the glaze surface to prevent deterioration, and
Good layer density with the pattern layer.
釉薬と通常のアニオン性樹脂エマルジョンは単に混付し
、た７ビちＶｃ２用すｎば、何ら問題はない。If you simply mix the glaze and a normal anionic resin emulsion and use Vc2, there will be no problem.
しかしながら工場では釉薬液を全景便め切るものでもな
く、後日便用や、まえもってあらかじめ調侵したり１．
＠に便用しない場せがよくある。こｎらのａＩ４＠液は
工場内や屋外に貯蔵さｎ日光や、熱の影響を受けるが、
この時、調せ液の粘度が上昇したり、ゲル化等の現象が
認められ、正常な施釉が出来なくなる。However, in the factory, the glaze liquid is not completely disposed of, but it is used at a later date, or it is mixed in advance.
There are many situations where @ is not conveniently used. These aI4@ liquids are stored in factories or outdoors and are affected by sunlight and heat.
At this time, phenomena such as an increase in the viscosity of the prepared liquid and gelation are observed, making it impossible to apply the glaze normally.
不発明においてはこの釉薬とアニオン性樹脂エマルジョ
ン調曾液の増粘化防止の目的で水酸基含有共重合体のエ
マルジョンを用いる。In the present invention, an emulsion of a hydroxyl group-containing copolymer is used for the purpose of preventing thickening of the glaze and the anionic resin emulsion preparation.
調製
生釉は、釉薬ｘｏｏｍｔ部に対し水、分散剤を加えボー
ルミルで混合し、アニオン性ｇＲ脂水性エマルジョンが
４〜２０這櫨部（樹脂固型分量）の割付で配付し、必要
により消泡剤を添加し、混合する。生釉の水分含ｊ」ぼ
、４５〜６５ｉ重係がよい。The prepared raw glaze is prepared by adding water and a dispersant to the xoomt part of the glaze, mixing in a ball mill, distributing the anionic gR fat aqueous emulsion at 4 to 20 parts (resin solid content), and defoaming if necessary. Add agent and mix. The moisture content of raw glaze should be between 45 and 65 degrees.
施釉
締焼された陶磁器素地や−ｉ属への施釉は吹掛け、攪し
掛け、流し掛は等の方法で行わ几、素地に生釉、１−が
形底される。The glaze is applied to the glazed ceramic base or ceramic base using methods such as spraying, stirring, and pouring.
生釉は樹脂エマルジョンにより耐水性が賦与さｎるので
、転写νこ水を用いる絵付時に生釉層が溶は出すことが
ない。Since the raw glaze is given water resistance by the resin emulsion, the raw glaze layer will not dissolve during painting using transfer water.
施釉後、１５０〜２００℃に予備乾燥して生釉中の水分
を除去する。なお、より低くても良いが時間が必要とな
る。ただしエマルジョンの造膜温度より高いことが必要
である。After glazing, it is pre-dried at 150-200°C to remove moisture in the raw glaze. Note that it may be lower, but it will require more time. However, it is necessary that the temperature is higher than the film forming temperature of the emulsion.
転性
転与２紙は紙表面に水溶性高分子を堕布し、その上に台
底樹脂に顔料を混不口したインキによ！７絵柄全印刷し
て絵柄層を形成させ、更にその上に甘酸樹脂の補強層を
＆けたものであり、上記転写厭全ノＫＶｃ浸直すると水
溶性高分子が溶解して絵柄層は補強層と共に紙から剥離
さｎｌこＡ全上記の生釉ｊ−表面上に転写する。この方
法は一般にスライド法と呼ば九、この際、梃柄増は水分
を多重合盾し７’Ｃ−ｆ＼で生釉Ｊ−衣表面転写さ九る
が＠成剖１指エマルジョン成分により耐水件全Ｍするか
ら生ｍ層のぐず′ｎぽ確実に防止さ几る。こＩＬは転写
紙？用いず、直接上絵付釉を塗布する重甘も同様である
。Converter 2 paper is made by dropping water-soluble polymer onto the paper surface, and then applying ink made by mixing pigments into base resin! 7 All patterns are printed to form a pattern layer, and a reinforcing layer of sweet acid resin is added on top of the pattern layer.When the above transfer is completely immersed in KVc, the water-soluble polymer dissolves and the pattern layer becomes a reinforcing layer. The raw glaze above is then peeled off from the paper and transferred onto the surface. This method is generally called the slide method.At this time, the lever is multi-polymerized with water and transferred to the surface of the raw glaze with 7'C-f\, but the emulsion component makes it water resistant. Since all the matters are M, it will definitely prevent the nuisance of the M class. Is this IL transfer paper? The same is true for juama, which is not used and is directly applied with overglaze.
父、絵付用転写紙の顔料補強用甘酸樹脂に不発明のアニ
オン甘酸樹脂エマルジョンを使用しても良釉焼
絵付後は、必要により陶磁器に仕上りを美しくするため
に線引を行なったり、模様を加え、１０００〜１４００
℃の温度で第二焼成（釉焼）する。My father said that even if an uninvented anionic sweet acid resin emulsion was used as the pigment-reinforcing sweet acid resin on the transfer paper for painting, it would produce a good result. In addition, 1000-1400
Second firing (glaze firing) at a temperature of ℃.
この際、エマルジョン中の樹脂、界面活性剤は分解揮散
し、絵付が完成する。At this time, the resin and surfactant in the emulsion are decomposed and volatilized, completing the painting.
不発明の方法によ几ば、生釉ノー上にプライマーを処理
する工程が省けるとともＫ１１ｉｔ水性の低い生釉上に
直接水系組底物を塗布することによる生釉の欠落の心配
が無くかつ、−回の焼成により釉薬の熟成と絵柄の焼成
とが同時に行なわ几るため、熱効峯が向上しかつ工程が
廿理化される。By using the uninvented method, it is possible to eliminate the step of treating the raw glaze with a primer, and there is no need to worry about the raw glaze missing due to applying a water-based composition directly onto the raw glaze, which has a low water base. The glaze is matured and the design is fired at the same time by firing for , - times, which improves thermal efficiency and streamlines the process.
さらに粕桑調せ液の長期貯蔵ができ、経断的である。Furthermore, the mulberry lees preparation can be stored for a long period of time.
実施態様
以下、本発明を実施例によジ更に詳細に説明する。なお
、例中の部および係は特に倒起しない限り■憧基準であ
る。EMBODIMENTS The present invention will now be explained in more detail with reference to Examples. In addition, the departments and sections in the example are based on the standard ■ unless otherwise specified.
温度調節器、いかＶ形攪拌器、還流冷却器、供給容器、
温度計及び窒素導入管を備えた反応容器内に、下記の原
料を装入した。Temperature controller, squid V-shaped stirrer, reflux condenser, supply container,
The following raw materials were charged into a reaction vessel equipped with a thermometer and a nitrogen inlet tube.
水 ２００
部エチレンオキシド２０モルと反応
させたｐ−ノニルフェノールの懺
酸半エステルのナトリウム塩（ア
ニオン性乳化剤）の３５％水浴孜 ５部エチ
レンオキシド２５モルト反応
させたｐ−ノニルフェノール（非
イオン性乳化剤）の２０％溶液 ２０部。water 200
A 35% water bath solution of the sodium salt of the phosphoric acid half ester of p-nonylphenol (anionic emulsifier) reacted with 20 moles of ethylene oxide; 5 parts 20% solution of p-nonylphenol (nonionic emulsifier) reacted with 25 moles of ethylene oxide; 20 copies.
次いで、反応容器内を窒素ガスで置侯したのち、仄に示
す供給物Ｉの１０％を加え、根付物を９０℃に刀口序Ａ
しｌヒ。Next, after filling the reaction vessel with nitrogen gas, 10% of the feed I shown below was added, and the roots were heated to 90°C under the conditions of A.
Shilhi.
り尖氷］堅σ ■
水 ２００
部前記アニオン性乳化剤の３５％水溶ｇ ２５部メ
タクリル酸メチル １９５部アクリ
ル醒１１−ブチル １８９邪２−ヒ
ドロキシプロピルアクリレート ２部アクリル
アミド ８部。risha ice] solid σ ■ water 200
Part: 35% aqueous solution of the anionic emulsifier 25 parts Methyl methacrylate 195 parts Acrylic acid 11-butyl 189 parts 2-hydroxypropyl acrylate 2 parts Acrylamide 8 parts.
更に、８５部の水に２．５部の過硫酸カリウムを溶解し
たもの（供給物■）の１０％を容器内に装入後、残ジの
供給物Ｉ全ておよび供給物■の４０ｑｂを３．５時間か
けて容器内に供給し、供給終了後、２時間、同温度に保
って供給物■を重合させてアニオン性＜ａｔ脂水性エマ
ルジョン金得た。Furthermore, after charging 10% of 2.5 parts of potassium persulfate dissolved in 85 parts of water (Feed ■) into the container, all of the remaining Feed I and 40 qb of Feed ■ The mixture was fed into the container over a period of 5 hours, and after the feeding was completed, the feed was kept at the same temperature for 2 hours to polymerize the feed (2) to obtain an anionic <at fat-water emulsion gold.
例２〜７
ビニル単重体の組成を表１のように変更する他は１４Ｊ
１と同様にしてアニオン性樹脂水性エマルジョン？得
た。Examples 2 to 7 14J except that the composition of the vinyl monomer was changed as shown in Table 1.
Anionic resin aqueous emulsion as in 1? Obtained.
実施例１
市販の鉛釉１００重量部に水７０重量部を加え、ボール
ミルで粉砕根付し之（固型分約５８憾、ｐＨ９，３）。Example 1 70 parts by weight of water was added to 100 parts by weight of a commercially available lead glaze, and ground with a ball mill (solid content: about 58, pH 9.3).
この分散釉薬孜１００重盆部に、例１で得友アニオン性
樹脂水性エマルジョン（固型分５０重量係、ｐＨ６，０
） ｋｌ ０重量部配付し、生釉とした。Into this dispersion glaze, the aqueous anionic resin emulsion prepared in Example 1 (solid content 50% by weight, pH 6.0) was added.
) 0 parts by weight of kl was distributed to make a raw glaze.
この生柿のＳＯＣ雰囲気での貯蔵時の粘度変化は次の通
りである。The viscosity change of this raw persimmon during storage in an SOC atmosphere is as follows.
Ｚ、２００ Ｃで締焼した陶磁器素焼皿の表面に、備付
して１日＃ｉ過した生柿を吹き付は塗装し、１５０℃で
予備乾燥した後、この生柿層の表面ＶＣ転写紙上に印刷
した絵柄層を水スライド法により転写し、この做付した
皿上１２５０℃で第二焼成（釉焼）したときの転倒は、
綱のくずｎやピンホールもなく、−郭のすつ＠ジした艮
好な、滅柄であつた。On the surface of a ceramic bisque plate baked at 200 C, fresh persimmon that had been prepared for 1 day was spray painted, and after pre-drying at 150 C, the surface of this raw persimmon layer was painted on VC transfer paper. The pattern layer printed on the plate was transferred using the water slide method, and when the second firing (glaze firing) was performed on this plate at 1250°C, the fall occurred.
There were no rope shavings or pinholes, and the pattern was clean and neat.
実施例２〜５．比較例１〜２
生釉に配付したアニオン住エマルジョ：／トｔ、”？：
、例２〜７で得たエマルジョンを用いる他は同様にして
絵付を行った。Examples 2-5. Comparative Examples 1-2 Anion-based emulsion distributed to raw glaze:/tot,”?:
, Painting was carried out in the same manner except that the emulsions obtained in Examples 2 to 7 were used.
結果を表２に示す。The results are shown in Table 2.
実施例６
陶磁器素焼皿の化９ＶＣ肉厚２■の銅板を用いる他は実
施例１と同様にして良好な転倒を得た。Example 6 Good tipping was obtained in the same manner as in Example 1, except that a copper plate having a thickness of 2 cm and having a thickness of 9VC was used.
（以ド余白）(Less blank space)
Claims (1)
０．３〜１０重量％と他の不飽和単量体とを乳化重合し
て得られた水酸基を有する共重合体のアニオン性樹脂エ
マルジョンに釉薬を配合した組成物で施釉し、アニオン
性樹脂水性エマルジョンを乾燥固化し、ついで水スライ
ド法により転写用絵柄を転写し、又は釉薬水分散液を重
ね塗りし絵付をし、しかる後焼成することにより釉薬熱
成と絵柄焼成とを同時に行うことを特徴とする絵付方法
。 ２）、アニオン性樹脂水性エマルジョンの共重合体は、 （ａ）水酸基含有不飽和単量体 ０．３〜１０重量％ （ｂ）アクリル酢アルキルエステル（アルキル基の炭素
数は２〜８） ４０〜５５重量％ （ｃ）メタクリル酸メチル、スチレン、アクリロニトリ
ルより選ばれた単量体 ３０〜５５重量％ （ｄ）Ｎ−フェニルマレイミド、Ｎ−メチロールアクリ
ルアミド、アクリルアミド、メ タクリルアミドより選ばれた不飽和単量 体１０重量％ よりなるビニル単量体混合物１００重量部を、アニオン
性乳化剤０．１〜５重量部およびノニオン性乳化剤０〜
５重量部の存在下に乳化重合して得られた共重合体であ
る特許請求の範囲第１項記載の絵付方法。[Claims] 1) Having hydroxyl groups obtained by emulsion polymerization of 0.3 to 10% by weight of a hydroxyl group-containing unsaturated monomer and other unsaturated monomers on a metal or ceramic base. Glaze is applied with a composition containing a glaze mixed with an anionic resin emulsion of a copolymer, the anionic resin aqueous emulsion is dried and solidified, and then a pattern for transfer is transferred by a water slide method, or an aqueous glaze dispersion is overcoated. A painting method characterized in that the glaze is heated and the pattern is fired at the same time by painting and then firing. 2) The copolymer of the anionic resin aqueous emulsion consists of (a) 0.3 to 10% by weight of a hydroxyl group-containing unsaturated monomer (b) Acrylic acetic acid alkyl ester (the number of carbon atoms in the alkyl group is 2 to 8) 40 ~55% by weight (c) 30~55% by weight of a monomer selected from methyl methacrylate, styrene, and acrylonitrile (d) Unsaturated monomer selected from N-phenylmaleimide, N-methylolacrylamide, acrylamide, and methacrylamide 100 parts by weight of a vinyl monomer mixture consisting of 10% by weight, 0.1 to 5 parts by weight of an anionic emulsifier and 0 to 5 parts by weight of a nonionic emulsifier.
The painting method according to claim 1, which is a copolymer obtained by emulsion polymerization in the presence of 5 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3246488A JPH01208384A (en) | 1988-02-15 | 1988-02-15 | China-painting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3246488A JPH01208384A (en) | 1988-02-15 | 1988-02-15 | China-painting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01208384A true JPH01208384A (en) | 1989-08-22 |
| JPH0569074B2 JPH0569074B2 (en) | 1993-09-30 |
Family
ID=12359691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3246488A Granted JPH01208384A (en) | 1988-02-15 | 1988-02-15 | China-painting |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01208384A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0599106A1 (en) * | 1992-11-25 | 1994-06-01 | Cerdec Aktiengesellschaft Keramische Farben | Method of glazing non-metallic sustrates |
| ES2368961A1 (en) * | 2009-08-21 | 2011-11-24 | José Francisco Méndez Herrero | Method of aging combined for a smooth surface of pottery material. (Machine-translation by Google Translate, not legally binding) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59195589A (en) * | 1983-04-20 | 1984-11-06 | 三井東圧化学株式会社 | Glazing process |
-
1988
- 1988-02-15 JP JP3246488A patent/JPH01208384A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59195589A (en) * | 1983-04-20 | 1984-11-06 | 三井東圧化学株式会社 | Glazing process |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0599106A1 (en) * | 1992-11-25 | 1994-06-01 | Cerdec Aktiengesellschaft Keramische Farben | Method of glazing non-metallic sustrates |
| ES2368961A1 (en) * | 2009-08-21 | 2011-11-24 | José Francisco Méndez Herrero | Method of aging combined for a smooth surface of pottery material. (Machine-translation by Google Translate, not legally binding) |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0569074B2 (en) | 1993-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS59142257A (en) | Lime paint dispersion and manufacture | |
| JPS60176966A (en) | Colored alumina ceramic composition | |
| JPH01208384A (en) | China-painting | |
| JPH0220595B2 (en) | ||
| US4533573A (en) | Anti-scaling or marking composition for application to metal products and method of making and using the composition | |
| JPH01308891A (en) | Graze composition and method for painting with said composition | |
| KR20200119163A (en) | Glaze Composition Comprising Urine Sludge and Method For Preparing Same | |
| JPH0745351B2 (en) | How to paint ceramics | |
| JPH01239049A (en) | Binder | |
| JP2855451B2 (en) | Manufacturing method of ceramics | |
| SU806642A1 (en) | Binder | |
| SU947143A1 (en) | Composition for refractory coating | |
| SU718467A1 (en) | Ceramic dye binder | |
| SU1404496A1 (en) | Charge for producing refractories | |
| JPS5958067A (en) | Writing material | |
| JPS5844628B2 (en) | Inorganic paint composition | |
| JPH0891884A (en) | Production of crystalline artificial stone | |
| SU814951A1 (en) | Suspension for producing enameled sand | |
| SU963975A1 (en) | Refractory composition | |
| JPS6399859A (en) | Mold | |
| RU2165818C2 (en) | Aqueous nonstick paste for molds and mold cores | |
| JPH0345580A (en) | Glaze for pottery roof tile and pottery roof tile making | |
| CN101973731B (en) | Method for producing luminous attapulgite polymer clay | |
| JPS60251151A (en) | Glass colorant composition | |
| SU1507507A1 (en) | Composition for coatings of moulds and cores |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |