JPH01197547A - Heat-resistant resin composition - Google Patents
Heat-resistant resin compositionInfo
- Publication number
- JPH01197547A JPH01197547A JP1949188A JP1949188A JPH01197547A JP H01197547 A JPH01197547 A JP H01197547A JP 1949188 A JP1949188 A JP 1949188A JP 1949188 A JP1949188 A JP 1949188A JP H01197547 A JPH01197547 A JP H01197547A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- styrene
- compatibilizer
- weight
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 12
- 229920006015 heat resistant resin Polymers 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims abstract description 25
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920000642 polymer Polymers 0.000 claims abstract description 22
- 125000003118 aryl group Chemical group 0.000 claims abstract description 16
- 229920000570 polyether Polymers 0.000 claims abstract description 13
- 239000004793 Polystyrene Substances 0.000 abstract description 9
- -1 (substituted) styrene Chemical class 0.000 abstract description 8
- 229920010524 Syndiotactic polystyrene Polymers 0.000 abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 5
- 229920001577 copolymer Polymers 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 4
- 229920000578 graft copolymer Polymers 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract description 2
- 125000005843 halogen group Chemical group 0.000 abstract description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 229920002223 polystyrene Polymers 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- 229920005992 thermoplastic resin Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 4
- 150000003440 styrenes Chemical class 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 229920012753 Ethylene Ionomers Polymers 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- FUKUFMFMCZIRNT-UHFFFAOYSA-N hydron;methanol;chloride Chemical compound Cl.OC FUKUFMFMCZIRNT-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000003011 styrenyl group Polymers [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920001576 syndiotactic polymer Polymers 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、優れた耐熱性を有する熱可塑性樹脂組成物に
関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a thermoplastic resin composition having excellent heat resistance.
従来の技術
スチレン系樹脂と芳香族ポリエーテル系樹脂からなる熱
可塑性樹脂組成物は、その優れた物性と、特に優れた成
形性のために自動車、電子・電気、機械又は家庭用部品
などとして広く使用されている。そして近年その用途の
拡大に伴い、さらに高い性能、特に耐熱性向上の要求が
強くなってきている。Conventional technology Thermoplastic resin compositions made of styrene resins and aromatic polyether resins are widely used as automobile, electronic/electrical, mechanical, and household parts due to their excellent physical properties and particularly excellent moldability. It is used. In recent years, with the expansion of its uses, there has been a strong demand for even higher performance, especially improved heat resistance.
これまで、耐熱性の改良された上記熱可塑性樹脂組成物
としては、例えば該組成物に芳香族リン酸エステルを配
合したものが知られているが（特公昭５３−４１８号公
報、特開昭５１−７３２４１１号公報）、このものは芳
香族ポリエーテル系樹脂の含有量が少なくなるほど多量
の芳香族リン酸エステルを配合する必要があり、その結
果該リン酸エステルによる芳香族ポリエーテル系樹脂の
可塑化作用が増大するのを免れないという欠点がある。Hitherto, as the thermoplastic resin composition with improved heat resistance, for example, a composition containing an aromatic phosphoric acid ester has been known (Japanese Patent Publication No. 53-418, Japanese Patent Application Laid-Open No. 51-732411), it is necessary to blend a large amount of aromatic phosphoric acid ester as the content of aromatic polyether resin decreases, and as a result, the aromatic polyether resin is The disadvantage is that the plasticizing effect is inevitably increased.
また、有機ハロゲン化物と三酸化アンチモンを併用して
配合したものも知られているが（特開昭４８−７９４５
号公報、特開昭５１−７４０３１１号公報、特開昭５２
−１０９４６号公報）、このものは樹脂の耐衝撃性を低
下させると共に、ハロゲン化水素の発生により成形金型
を腐食させるなどの問題がある。In addition, compounds containing organic halides and antimony trioxide are also known (Japanese Unexamined Patent Publication No. 48-7945
Publication No. 1974-740311, Japanese Patent Application Laid-open No. 1987-740311
10946), this product has problems such as lowering the impact resistance of the resin and corroding the molding die due to the generation of hydrogen halide.
発明が解決しようとする課題
本発明は、このような欠点を有する従来のリン酸エステ
ルやハロゲン化物などの難燃剤等の特殊な添加物を用い
ることなく、安価で耐熱性の優れた熱可塑性樹脂組成物
を提供するためになされたものである。Problems to be Solved by the Invention The present invention aims to produce thermoplastic resins that are inexpensive and have excellent heat resistance, without using special additives such as conventional flame retardants such as phosphoric acid esters and halides, which have these drawbacks. This was done to provide a composition.
課題を解決するための手段
本発明者らは、これらの欠点を改善するため種々研究を
重ねた結果、特定の立体規則性をもつスチレン系重合体
に、芳香族ポリエーテル系重合体及び相容化剤又はこれ
らにさらに耐衝撃強度向上剤を特定の割合で配合するこ
とにより、樹脂組成物の耐熱性が改善されることを見出
し、この知見に基づいて本発明をなすに至った。Means for Solving the Problems The present inventors have conducted various studies to improve these drawbacks, and as a result, we have added aromatic polyether polymers and compatible polymers to styrene polymers with specific stereoregularity. It has been discovered that the heat resistance of the resin composition can be improved by blending a curing agent or an impact strength improver in a specific ratio to these, and based on this finding, the present invention has been completed.
すなわち、本発明は、実質上、シンジオタクチック構造
を有するスチレン系重合体と芳香族ポリエーテル系重合
体とを重量比１：１０ないし１０：ｌの割合で含有し、
さらに組成物全量に基づき１〜２０重量％の相容化剤を
配合して成る耐熱性樹脂組成物及びそれに対し、さらに
組成物全量に基づき５０重量％を超えない割合で耐衝撃
強度向上剤を配合して成る耐熱性樹脂組成物を提供する
ものである。That is, the present invention substantially contains a styrenic polymer having a syndiotactic structure and an aromatic polyether polymer in a weight ratio of 1:10 to 10:1,
Furthermore, a heat-resistant resin composition comprising a compatibilizer in an amount of 1 to 20% by weight based on the total amount of the composition, and an impact strength improver in a proportion not exceeding 50% by weight based on the total amount of the composition. The present invention provides a heat-resistant resin composition comprising the following.
本発明組成物においては、その成分の１つとして、実質
上、シンジオタクチック構造を有するスチレン系重合体
が用いられるが、これは、分子鎖中に存在するフェニル
基が主鎖に沿って交互に立体配置している構造を有する
スチレン重合体又は置換スチレン重合体から主として構
成されているもので、これは１３Ｃ−ＮＭＲ解析によっ
て容易に知ることができる。このような構造を有するス
チレン系重合体としては、例えばチーグラー触媒を用い
て重合させたポリスチレン、ポリ（アルキルスチレン）
、ポリ（ハロゲン化スチレン）、ポリ（アルコキシスチ
レン）、ポリ（ベンゾイルスチレン）や、スチレン、ア
ルキルスチレン、ハロゲン化スチレンを主成分とする共
重合体などを挙げることができる。In the composition of the present invention, a styrenic polymer having a substantially syndiotactic structure is used as one of its components, and this is because the phenyl groups present in the molecular chain alternate along the main chain. It is mainly composed of a styrene polymer or a substituted styrene polymer having a structure having a steric configuration, and this can be easily determined by 13C-NMR analysis. Examples of styrenic polymers having such a structure include polystyrene polymerized using a Ziegler catalyst and poly(alkylstyrene).
, poly(halogenated styrene), poly(alkoxystyrene), poly(benzoylstyrene), and copolymers containing styrene, alkylstyrene, and halogenated styrene as main components.
本発明組成物の成分の１つとして用いられる芳香族ポリ
エーテル系重合体とは、二価の芳香族残基例えばフェニ
レン基、ビフェニレン基、ナフチレン基などを主鎖中に
含んでいるポリエーテルであって、最も好適なものとし
て、一般式（式中、Ｒ１、Ｒ２はそれぞれ水素原子、ハ
ロゲン原子、アルキル基又はアリール基であって、両者
は互いに同一であってもまた異なっていてもよい）で示
される構成単位から成る重合体、共重合体及びこれとス
チレン系化合物とのグラフト共重合体を挙げることがで
きる。The aromatic polyether polymer used as one of the components of the composition of the present invention is a polyether containing a divalent aromatic residue such as a phenylene group, a biphenylene group, or a naphthylene group in its main chain. The most preferred one is the general formula (wherein R1 and R2 are each a hydrogen atom, a halogen atom, an alkyl group, or an aryl group, and they may be the same or different from each other) Polymers and copolymers consisting of structural units represented by the above and graft copolymers of these and styrene compounds can be mentioned.
本発明組成物においては、実質的にシンジオタクチック
構造を有するスチレン系重合体と芳香族ポリエーテル系
重合体とを、重量比１：ＬＯないし１０：ｌの割合で含
有していることが必要である。シンジオタクチック構造
を有するスチレン系重合体の量がこれよりも少なかった
り、あるいはこれよりも多くなると耐熱性の改善が不十
分になる。両者の特に好適な割合は、ｌ：４ないし４：
１の範囲である。The composition of the present invention must contain a styrene polymer having a substantially syndiotactic structure and an aromatic polyether polymer in a weight ratio of 1:LO to 10:l. It is. If the amount of the styrenic polymer having a syndiotactic structure is less than or greater than this, the improvement in heat resistance will be insufficient. A particularly preferred ratio of both is 1:4 to 4:
The range is 1.
本発明組成物においては、前記した成分にさらに相容化
剤を組成物の全量に基づき１〜２０重量％好ましくは２
〜１５重量％配合することが必要である。この特定配合
量の相容化剤を用いることにより、シンジオタクチック
構造を有するスチレン系重合体と芳香族ポリエーテル系
重合体とを単純にブレンドしても相客しにくく、成形時
に相分離を起こしやすく、この両者のみからなる組成物
では外観や性能の点で必ずしも満足しうるちのが得られ
なかったのを改善し、初めて一方の成分を他方の成分に
均一に微分散することが可能となり、優れた外観と物性
の組成物を得ることができる。In the composition of the present invention, a compatibilizer is further added to the above-mentioned components in an amount of 1 to 20% by weight, preferably 2% by weight based on the total amount of the composition.
It is necessary to mix it in an amount of ~15% by weight. By using this specific amount of compatibilizer, even if a styrene polymer with a syndiotactic structure and an aromatic polyether polymer are simply blended, it is difficult to mix them, and phase separation is prevented during molding. This improves the problem of the fact that compositions consisting only of the two did not always give satisfactory results in terms of appearance and performance, and for the first time made it possible to uniformly and finely disperse one component in the other. , a composition with excellent appearance and physical properties can be obtained.
相容化剤の量がこれよりも少ないと両成分の相客化が不
十分になり、またこれよりも多くなると耐熱性の改善が
不十分になる。If the amount of the compatibilizer is less than this, the compatibilization of both components will be insufficient, and if it is more than this, the improvement in heat resistance will be insufficient.
この相容化剤としては、各重合体に親和性を有する官能
基及び／又は連鎖を同一分子内に有する化合物、共重合
体などが挙げられ、例えばシンジオタクチックポリスチ
レンとポリマーパーオキサイド又は、無水マレイン酸、
グリシジルメタクリレート等をラジカル発生剤共存下に
溶融混練した変性重合体又は、これらをベースにしたグ
ラフト共重合体などが適している。Examples of this compatibilizing agent include compounds and copolymers that have functional groups and/or chains in the same molecule that have an affinity for each polymer, such as syndiotactic polystyrene and polymer peroxide, or anhydrous maleic acid,
Modified polymers obtained by melt-kneading glycidyl methacrylate or the like in the coexistence of a radical generator, or graft copolymers based on these are suitable.
本発明組成物においては、前記した成分及び相容化剤に
さらに耐衝撃強度向上剤を組成物全量に基づき５０重量
％を超えない割合で好ましくは３〜２０重量部％置部す
ることにより、耐熱性と共に耐衝撃性を改善することが
できる。In the composition of the present invention, an impact strength improver is further added to the above-mentioned components and compatibilizer in a proportion not exceeding 50% by weight based on the total amount of the composition, preferably 3 to 20 parts by weight. It is possible to improve impact resistance as well as heat resistance.
この際に用いる耐衝撃強度向上剤としては、例えばブタ
ジェン系重合体、水素化ブタジェン系重合体、スチレン
−ブタジェンブロック共重合体、水素化スチレン−ブタ
ジェンブロック共重合体、エチレン−プロピレンエラス
トマー、エチレン系アイオノマー、アクリル酸エステル
系エラストマー及びそれらの変性体などかある。Examples of impact strength improvers used in this case include butadiene polymers, hydrogenated butadiene polymers, styrene-butadiene block copolymers, hydrogenated styrene-butadiene block copolymers, ethylene-propylene elastomers, Examples include ethylene ionomers, acrylic ester elastomers, and modified products thereof.
この耐衝撃強度向上剤の割合が組成物全量に対して５０
重量％よりも多いと耐熱性が著しく損なわれる。The proportion of this impact strength improver is 50% of the total amount of the composition.
If the amount is more than 1% by weight, heat resistance will be significantly impaired.
本発明の組成物には必要に応じて、本発明の効果を損な
わない範囲で、一般の熱可塑性樹脂に通常用いられる添
加剤、すなわち滑剤、可塑剤、各種安定剤、染料、顔料
、有機又は無機光てん剤などを加えることができる。The composition of the present invention may contain additives commonly used in thermoplastic resins, such as lubricants, plasticizers, various stabilizers, dyes, pigments, organic or Inorganic photonic agents and the like can be added.
本発明の組成物は、所要の各成分をブレンドして製造さ
れるが、ブレンドの方法としては一般に用いられている
方法、例えば押出機による溶融混練、バンバリーミキサ
−、ロールなどによる混練などの方法が使用できる。The composition of the present invention is produced by blending the required components, and the blending method may be any commonly used method, such as melt kneading using an extruder, kneading using a Banbury mixer, rolls, etc. can be used.
発明の効果
本発明の熱可塑性樹脂組成物は、従来の熱可塑性樹脂に
比較して著しく耐熱性が改善されている上に、難燃性等
の優れた特性を有する樹脂を与え、自動車、電子・電気
、機械又は家庭用部品などの素材としての用途に好適で
ある。Effects of the Invention The thermoplastic resin composition of the present invention has significantly improved heat resistance compared to conventional thermoplastic resins, and also provides a resin with excellent properties such as flame retardancy, and is used in automobiles, electronics, etc. - Suitable for use as a material for electrical, mechanical, or household parts.
実施例 次に実施例によって本発明をさらに詳細に説明する。Example Next, the present invention will be explained in more detail with reference to Examples.
参考例１
不活性ガスで置換した内容積１０ｔのオートクレーブに
、トルエン４１１．トリメチルアルミニウムクロペンタ
ジェニル）チタニウムジクロリドＯｏ５ｍｍｏｌを加え
た。次にスチレンｌｌｌを加え５０℃で６時間重合反応
を行った。反応終了後、反応物を塩酸−メタノールに投
入することで反応を停止し、生成ポリマーをろ別、乾燥
した。この結果得られたポリスチレンは７２ｇであった
。このポリスチレンのメチルエチルケトン不溶部は９０
重量％であり、この不溶部の立体規則性は１３Ｃ−ＮＭ
Ｒスペクトル解析の結果、９９％以上のシンジオタクチ
ック構造であった。Reference Example 1 Toluene 411.1% was placed in an autoclave with an internal volume of 10 tons that was purged with inert gas. 5 mmol of trimethylaluminum clopentadienyl) titanium dichloride was added. Next, 1 liter of styrene was added and a polymerization reaction was carried out at 50° C. for 6 hours. After the reaction was completed, the reaction product was poured into hydrochloric acid-methanol to stop the reaction, and the resulting polymer was filtered and dried. The resulting polystyrene weighed 72 g. The methyl ethyl ketone insoluble area of this polystyrene is 90
% by weight, and the stereoregularity of this insoluble part is 13C-NM
As a result of R spectrum analysis, it was found to have a syndiotactic structure of 99% or more.
参考例２ 相容化剤■の合成
参考例１で得たシンジオタクチックポリスチレン１００
重量部と（アタクチック）ポリスチレンパーオキサイド
５０重量部とを溶融混練してスチレングラフトシンジオ
タクチックポリスチレンを得た。Reference Example 2 Synthesis of Compatibilizer ■ Syndiotactic polystyrene 100 obtained in Reference Example 1
Part by weight and 50 parts by weight of (atactic) polystyrene peroxide were melt-kneaded to obtain styrene-grafted syndiotactic polystyrene.
参考例３ 相容化剤■の合成
参考例１で得たシンジオタクチックポリスチレン１００
重量部、アタクチックポリスチレン１００重量部、無水
マレイン酸２０重量部及びベンゾイルパーオキサイド２
重量部を溶融混練して変性シンジオタクチックポリスチ
レンを得た。Reference Example 3 Synthesis of Compatibilizer ■ Syndiotactic polystyrene 100 obtained in Reference Example 1
Parts by weight, 100 parts by weight of atactic polystyrene, 20 parts by weight of maleic anhydride, and 2 parts by weight of benzoyl peroxide.
Parts by weight were melt-kneaded to obtain modified syndiotactic polystyrene.
実施例１
参考例１で得たシンジオタクチック構造を有するポリス
チレン１００重量部、ηｓｐ／ｃー０．６４のポリ（２
．６−シメチルフエニレンー１．４−エーテル）１００
重量部及び参考例２で得られた相容化剤１２０重量部よ
りなる混合物を２５０〜３１０℃で２軸押用機を用いて
溶゛融混練し、樹脂組成物を得た。これを射出成形して
得た試料について測定した物性を第１表に示す。Example 1 100 parts by weight of polystyrene having a syndiotactic structure obtained in Reference Example 1, poly(2
．． 6-dimethylphenylene-1,4-ether) 100
A mixture consisting of parts by weight and 120 parts by weight of the compatibilizer obtained in Reference Example 2 was melt-kneaded at 250 to 310°C using a twin screw extruder to obtain a resin composition. Table 1 shows the physical properties measured for samples obtained by injection molding.
実施例２〜９
第１表に示した重合体成分を用い、実施例１と同様にし
て各種組成物を得た。これを射出成形して得た試料につ
いて測定した物性を第１表に示す。Examples 2 to 9 Various compositions were obtained in the same manner as in Example 1 using the polymer components shown in Table 1. Table 1 shows the physical properties measured for samples obtained by injection molding.
比較例１．２．３
第１表に示した重合体成分を用い、実施例１と同様にし
て各種組成物を得た。これを射出成形して得た試料につ
いて測定した物性を第１表に示す。Comparative Example 1.2.3 Various compositions were obtained in the same manner as in Example 1 using the polymer components shown in Table 1. Table 1 shows the physical properties measured for samples obtained by injection molding.
実施例５
１ ｓｐ／ ｃ −０，６４のポリ（２，６−シメチル
フエニレン用、４−エーテル）１００重量部、アククチ
ツクポリスチレン１００重量部及びベンゾイルパーオキ
サイド２重量部を溶融混練してスチレングラフトポリ（
２，６−シメチルフエニレンー１．４−エーテル）ヲ得
り。Example 5 100 parts by weight of 1 sp/c -0,64 poly(2,6-dimethylphenylene, 4-ether), 100 parts by weight of acid polystyrene, and 2 parts by weight of benzoyl peroxide were melt-kneaded. Styrene grafted poly(
2,6-dimethylphenylene-1,4-ether) was obtained.
ポリ（２，６−シメチルフエニレン刊、４−エーテル）
の代わりにスチレングラフトポリ（２，６−シメチルフ
エニレンー１．４−エーテル）を用いた他ハ実施例１と
同様にして得た組成物を射出成形して得た試料について
測定した物性を第１表に示す。Poly(2,6-dimethylphenylene, 4-ether)
Physical properties measured on a sample obtained by injection molding a composition obtained in the same manner as in Example 1 except that styrene-grafted poly(2,6-dimethylphenylene-1,4-ether) was used instead of are shown in Table 1.
実施例１０
参考例１で得たシンジオタクチック構造を有するポリス
チレンとポリ（２，６−シメチルフエニレンー１．４−
エーテル）とを、それぞれ重量比２：１１４：１．８：
ｌ、１：２．１：４の割合で含有し、さらに相容化剤Ｉ
をそれぞれの組成物全量に基づき９重量％配合して成る
組成物を用い、実施例１と同様にして溶融混練し、射出
成形した。このようにして得た試料について測定した物
性を第２表に示す。Example 10 Polystyrene having a syndiotactic structure obtained in Reference Example 1 and poly(2,6-dimethylphenylene-1,4-
ether) in a weight ratio of 2:114:1.8:
l, in a ratio of 1:2.1:4, and further contains a compatibilizer I
A composition containing 9% by weight based on the total amount of each composition was melt-kneaded and injection molded in the same manner as in Example 1. Table 2 shows the physical properties measured for the sample thus obtained.
Claims (1)
系重合体と芳香族ポリエーテル系重合体とを重量比１：
１０ないし１０：１の割合で含有し、さらに組成物全量
に基づき１〜２０重量％の相容化剤を配合して成る耐熱
性樹脂組成物。 ２ 実質上、シンジオタクチック構造を有するスチレン
系重合体と芳香族ポリエーテル系重合体とを重量比１：
１０ないし１０：１の割合で含有し、さらに組成物全量
に基づき１〜２０重量％の相容化剤及び５０重量％を超
えない割合で耐衝撃強度向上剤を配合して成る耐熱性樹
脂組成物。[Claims] 1. A styrenic polymer having a substantially syndiotactic structure and an aromatic polyether polymer in a weight ratio of 1:1.
A heat-resistant resin composition containing a compatibilizer in a ratio of 10 to 10:1 and further containing a compatibilizer in an amount of 1 to 20% by weight based on the total amount of the composition. 2 Substantially, the styrene polymer having a syndiotactic structure and the aromatic polyether polymer are mixed in a weight ratio of 1:1.
A heat-resistant resin composition containing a compatibilizer in a ratio of 10 to 10:1 and further containing a compatibilizer in an amount of 1 to 20% by weight and an impact strength improver in a ratio not exceeding 50% by weight based on the total amount of the composition. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63019491A JP2752627B2 (en) | 1988-02-01 | 1988-02-01 | Heat resistant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63019491A JP2752627B2 (en) | 1988-02-01 | 1988-02-01 | Heat resistant resin composition |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8788997A Division JPH1025382A (en) | 1997-04-07 | 1997-04-07 | Impact-resistant resin composition |
| JP32509297A Division JPH10130444A (en) | 1997-11-27 | 1997-11-27 | Heat-resistant resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01197547A true JPH01197547A (en) | 1989-08-09 |
| JP2752627B2 JP2752627B2 (en) | 1998-05-18 |
Family
ID=12000830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63019491A Expired - Lifetime JP2752627B2 (en) | 1988-02-01 | 1988-02-01 | Heat resistant resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2752627B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0264140A (en) * | 1988-08-31 | 1990-03-05 | Idemitsu Kosan Co Ltd | Styrene-based resin composition |
| EP0591823A1 (en) * | 1992-10-08 | 1994-04-13 | Idemitsu Kosan Company Limited | Thermoplastic resin composition |
| EP0611802A2 (en) * | 1988-08-31 | 1994-08-24 | Idemitsu Kosan Company Limited | Styrene-based polymer compositions |
| JPH11236474A (en) * | 1997-12-19 | 1999-08-31 | Sumitomo Chem Co Ltd | Poly(phenylene ether)-based resin composition and its production |
| EP1290046A4 (en) * | 2000-06-02 | 2006-09-13 | Samsung Atofina Co Ltd | Method of preparing monomer-grafted syndiotactic polystyrene with polarity |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01279944A (en) * | 1988-01-13 | 1989-11-10 | Idemitsu Kosan Co Ltd | Thermoplastic resin composition |
-
1988
- 1988-02-01 JP JP63019491A patent/JP2752627B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01279944A (en) * | 1988-01-13 | 1989-11-10 | Idemitsu Kosan Co Ltd | Thermoplastic resin composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0264140A (en) * | 1988-08-31 | 1990-03-05 | Idemitsu Kosan Co Ltd | Styrene-based resin composition |
| EP0611802A2 (en) * | 1988-08-31 | 1994-08-24 | Idemitsu Kosan Company Limited | Styrene-based polymer compositions |
| EP0611802A3 (en) * | 1988-08-31 | 1995-04-12 | Idemitsu Kosan Co | Styrene-based polymer compositions. |
| EP0591823A1 (en) * | 1992-10-08 | 1994-04-13 | Idemitsu Kosan Company Limited | Thermoplastic resin composition |
| JPH11236474A (en) * | 1997-12-19 | 1999-08-31 | Sumitomo Chem Co Ltd | Poly(phenylene ether)-based resin composition and its production |
| EP1290046A4 (en) * | 2000-06-02 | 2006-09-13 | Samsung Atofina Co Ltd | Method of preparing monomer-grafted syndiotactic polystyrene with polarity |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2752627B2 (en) | 1998-05-18 |
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