JPH01189320A - Adsorption filter - Google Patents
Adsorption filterInfo
- Publication number
- JPH01189320A JPH01189320A JP63012821A JP1282188A JPH01189320A JP H01189320 A JPH01189320 A JP H01189320A JP 63012821 A JP63012821 A JP 63012821A JP 1282188 A JP1282188 A JP 1282188A JP H01189320 A JPH01189320 A JP H01189320A
- Authority
- JP
- Japan
- Prior art keywords
- adsorbent
- adsorption
- heater
- adsorption filter
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 43
- 239000003463 adsorbent Substances 0.000 claims abstract description 49
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 abstract description 7
- 229910052901 montmorillonite Inorganic materials 0.000 abstract description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 4
- 230000008929 regeneration Effects 0.000 abstract description 3
- 238000011069 regeneration method Methods 0.000 abstract description 3
- 210000002268 wool Anatomy 0.000 abstract description 3
- 239000008187 granular material Substances 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 21
- 230000000694 effects Effects 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000002156 adsorbate Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 210000004709 eyebrow Anatomy 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MZZINWWGSYUHGU-UHFFFAOYSA-J ToTo-1 Chemical compound [I-].[I-].[I-].[I-].C12=CC=CC=C2C(C=C2N(C3=CC=CC=C3S2)C)=CC=[N+]1CCC[N+](C)(C)CCC[N+](C)(C)CCC[N+](C1=CC=CC=C11)=CC=C1C=C1N(C)C2=CC=CC=C2S1 MZZINWWGSYUHGU-UHFFFAOYSA-J 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RJDOZRNNYVAULJ-UHFFFAOYSA-L [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Mg++].[Mg++].[Mg++].[Al+3].[Si+4].[Si+4].[Si+4].[K+] RJDOZRNNYVAULJ-UHFFFAOYSA-L 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- -1 pennite Chemical compound 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明は吸着フィルターに関する。[Detailed description of the invention] [Industrial application field] This invention relates to an adsorption filter.
従来、吸着フィルター用の吸着材として、活性炭を用い
たものがよく知られている。ところが、活性炭は、例え
ば、アンモニアのような低分子ガスに対しては十分な吸
着作用がない。Conventionally, activated carbon is well known as an adsorbent for adsorption filters. However, activated carbon does not have a sufficient adsorption effect on low molecular gases such as ammonia.
一方、吸着フィルターは、例えば、一般家庭における空
気清浄に用いられる。吸着が進んで吸着材が飽和状態に
達すると、吸着作用は停止する。On the other hand, adsorption filters are used, for example, for air purification in general households. When the adsorption progresses and the adsorbent reaches a saturated state, the adsorption action stops.
吸着作用を回復させるために、新たな吸着材と交換する
。しかし、新たな吸着材と交換していたのでは、その都
度、高価についてしまうだけでなく、手間もかかる。Replace with new adsorbent to restore adsorption effect. However, replacing the adsorbent with a new one each time is not only expensive but also time-consuming.
アンモニアのような低分子ガスが吸着できないと、利用
範囲が大幅に制限される。また、吸着作用の回復にコス
トがかかったり、手間がかかっていては、汎用性がなく
なり、やはり利用範囲が限られることになる。If low-molecular gases such as ammonia cannot be adsorbed, the range of use will be greatly limited. Furthermore, if recovery of the adsorption effect is costly or time-consuming, the product will lack versatility and its range of use will be limited.
この発明は、このような事情に鑑み、アンモニアのよう
な低分子ガスを十分に吸着することができ、吸着作用回
復が高くついたり、手間がかかったりしない吸着フィル
タを提供することを目的とする。In view of these circumstances, it is an object of the present invention to provide an adsorption filter that can sufficiently adsorb low-molecular gases such as ammonia, and does not require high cost or effort to recover the adsorption action. .
前記課題を解決するため、この発明にかかる吸着フィル
ターは、無機層状多孔質粒子からなる吸着材と同吸着材
を加熱するヒータを備え、前記吸着材が加熱により再生
させられるようになっている。また、吸着材が吸着物を
分解させる金属触媒を含んでいる。In order to solve the above problems, an adsorption filter according to the present invention includes an adsorbent made of inorganic layered porous particles and a heater that heats the adsorbent, so that the adsorbent is regenerated by heating. Additionally, the adsorbent contains a metal catalyst that decomposes the adsorbate.
請求項１．２記載の発明においては、吸着材が無機層状
多孔質粒子からなるために、アンモニアのような低分子
ガスでも十分に吸着でき、しかも、ヒータを動作させ吸
着材を加熱するだけで、劣化した吸着作用を簡単に回復
させることができるさらに、請求項２記載の発明におい
ては、吸着材に含まれる金属触媒が吸着物を分解させる
。例えば、悪臭を発する吸着物質が無臭物質に分解させ
られたり、あるいは、非吸着物質へ分解させられたりす
るため、消臭や吸着の飽和抑制ができる〔実 施 例〕
以下、この発明にかかる吸着フィルターを、その一実施
例をあられす図面を参照しながら詳しく説明する。In the invention described in claim 1.2, since the adsorbent is made of inorganic layered porous particles, it can sufficiently adsorb even a low molecular gas such as ammonia, and moreover, it can be adsorbed simply by operating the heater to heat the adsorbent. Furthermore, in the second aspect of the invention, the metal catalyst contained in the adsorbent decomposes the adsorbent. For example, adsorbed substances that emit bad odors are decomposed into odorless substances or decomposed into non-adsorbed substances, thereby deodorizing and suppressing the saturation of adsorption. An embodiment of the filter will be described in detail with reference to the accompanying drawings.
第１図は、この発明の吸着フィルターの一実施例の概略
構成をあられす。FIG. 1 shows a schematic configuration of an embodiment of an adsorption filter of the present invention.
吸着フィルター１は、２枚の吸着材２．２を備え、両吸
着材２．２の間に吸着材加熱用の電気ヒータ３を備えて
いる。吸着材２．２と電気ヒータ３の間にはセラミック
ウール（セラミックファイバー）層４．４が設けられて
いる。セラミックウール層４．４は吸着材２と電気ヒー
タ３の空隙を埋めるように設けられている。なお、これ
ら各村は、金属線（図示省略）を外側に巻きかけてひと
つに組み付けられている。The adsorption filter 1 includes two sheets of adsorbent 2.2, and an electric heater 3 for heating the adsorbent between both adsorbents 2.2. A ceramic wool (ceramic fiber) layer 4.4 is provided between the adsorbent 2.2 and the electric heater 3. The ceramic wool layer 4.4 is provided to fill the gap between the adsorbent 2 and the electric heater 3. Each of these villages is assembled into one by wrapping a metal wire (not shown) around the outside.
吸着材２は、前記のように、無機層状多孔質粒子からな
り、粒子の眉間や粒子間に数十人〜数百人程度の細孔を
多数有していて、比表面積が、例えば、６００ｒｒｆ／
ｇ程度もあり、アンモニア（ガス）等の低分子ガスでも
十分に吸着する。無機質からなるため、耐熱性も、例え
ば、６００℃と非常に高い。As mentioned above, the adsorbent 2 is made of inorganic layered porous particles, has many pores of several tens to hundreds of pores between the eyebrows of the particles and between the particles, and has a specific surface area of, for example, 600rrf. /
It can sufficiently adsorb even low-molecular gases such as ammonia (gas). Since it is made of inorganic material, its heat resistance is also very high, for example, 600°C.
無機層状多孔質粒子としては、例えば、スメクタイト型
鉱物（モンモリロナイト、ペンナイト、緑泥石、バイデ
ライト、ヘクトライト、合成マイカ、テニオライト等）
の眉間に、例えば、無機物（Ｓ ｆｏｘ 、Ｔｌ０ｉ
、Ａ１１ｓ Ｏｘ 、ＺｒＯ＊、Ｇｅ０ｔ 、Ｆｅｗ
Ｏ□等）や炭素塊等が挿入されて眉間に空隙が維持され
多孔質となっている物（インターカーレーション化合物
）がある。Examples of inorganic layered porous particles include smectite minerals (montmorillonite, pennite, chlorite, beidellite, hectorite, synthetic mica, teniolite, etc.)
For example, inorganic substances (S fox, Tl0i
, A11s Ox , ZrO*, Ge0t , Few
There are some compounds (intercalation compounds) in which a gap is maintained between the eyebrows by inserting a carbon block or the like (O□, etc.) and a porous structure.
吸着材２として、細孔径分布が数十人〜数百人の範囲の
うちの微小寸法と数μｍ〜数百μｍの範囲のうちの小寸
法のふたつの寸法でピークをもつようなものもある。こ
の吸着材２は、微小寸法の細孔で主として低分子ガス等
を吸着し、一方、小寸法の細孔で埃等を吸着する（濾し
とる）。そのため、埃等が微小径の細孔を塞ぎ低分子ガ
ス等の吸着作用を低下させるというようなことを効果的
に阻止できる。Some adsorbents 2 have pore size distributions that have two peaks: minute dimensions in the range of tens to hundreds of micrometers and small dimensions in the range of several μm to several hundred μm. . This adsorbent 2 mainly adsorbs low-molecular gas and the like through minute pores, while adsorbing (filtering) dust and the like through small pores. Therefore, it is possible to effectively prevent dust and the like from blocking the microscopic pores and reducing the adsorption effect of low-molecular gases and the like.
より具体的な吸着材２としては、無機層状多孔質粒子か
らなる成形体、あるいは、無機層状多孔質粒子とケイ藻
土やケイ酸カルシウム等の成形性のよいバインダー材か
らなる成形体、さらには、無機層状多孔質粒子がガラス
布へ担持させられたかたちのものが用いられる。More specific examples of the adsorbent 2 include molded bodies made of inorganic layered porous particles, or molded bodies made of inorganic layered porous particles and a binder material with good moldability such as diatomaceous earth or calcium silicate; , inorganic layered porous particles supported on glass cloth are used.
また、吸着材に吸着物を分解させることができる金属、
金属酸化物、あるいは、金属塩類等の金属触媒を含ませ
ておいて、有害吸着物を無害物に分解して（例えば、悪
臭物質を無臭物質に分解して）しまうようにすることも
効果的である。分解してしまうと吸着状態が解除される
ようであれば、吸着飽和も防止でき、いっそう効果的で
ある。In addition, metals that can cause the adsorbent to decompose the adsorbate,
It is also effective to include metal catalysts such as metal oxides or metal salts to decompose harmful adsorbed substances into harmless substances (for example, decompose malodorous substances into odorless substances). It is. If the adsorption state is released by decomposition, adsorption saturation can be prevented, which is even more effective.
金属触媒は、例えば、無機層状多孔質粒子の眉間に担持
させるようにする。特に限定されるものではないが、触
媒として、銀、銅、マンガン、鉄、コバルト、ニッケル
、亜鉛、クロム、白金、パラジウム、モリブデン、バナ
ジウム等の金属、これら金属の酸化物、これら金属の塩
類が具体的に挙げられる。The metal catalyst is, for example, supported on the glabella of the inorganic layered porous particles. Examples of catalysts include, but are not limited to, metals such as silver, copper, manganese, iron, cobalt, nickel, zinc, chromium, platinum, palladium, molybdenum, vanadium, oxides of these metals, and salts of these metals. Specific examples are listed.
電気ヒータ３としては、セラミックヒータ（Ｐ
−ＴＣヒータ）やニクロム線ヒータが用いられる。As the electric heater 3, a ceramic heater (P
-TC heater) or nichrome wire heater are used.
吸着が飽和に達すると、電気ヒータ３を作用させて、例
えば、２００℃といった温度にして吸着物を燃焼させ除
去して吸着作用を回復させる。つまり、吸着材２の再生
をおこなうのである。電気ヒータ３のスイッチを入れる
程度の作業であるから極めて簡単である。上述のように
、無機質であり耐熱性があるので、このような加熱によ
る吸着作用回復処理を行っても劣化の心配もない。再生
費用も、加熱用の電気代だけであるから安いものである
。具体的な電気ヒータ３としては、例えば、セラミック
ヒータ（ＴＯＴＯ製 サウナ用ヒータ）がある。When the adsorption reaches saturation, the electric heater 3 is activated to raise the temperature to 200° C., for example, to burn and remove the adsorbate, thereby restoring the adsorption effect. In other words, the adsorbent 2 is regenerated. This is an extremely simple task since it is just a matter of turning on the electric heater 3. As mentioned above, since it is inorganic and has heat resistance, there is no fear of deterioration even if such adsorption recovery treatment by heating is performed. The cost of regeneration is also low because it only costs electricity for heating. A specific example of the electric heater 3 is a ceramic heater (TOTO sauna heater).
ガラスウール層４には、例えば、セラミックファイバー
（新日鐵化学株式会社製 ニスファイバーＳＣバルク状
）が用いられる。For the glass wool layer 4, for example, ceramic fiber (varnished fiber SC bulk type manufactured by Nippon Steel Chemical Co., Ltd.) is used.
この発明は上記の実施例に限らない。例えば、電気ヒー
タが吸着材に埋め込まれているような構成のものであっ
てもよい。また、無機層状多孔質粒子やヒータは上記に
例示したちの以外のものであってもよい。This invention is not limited to the above embodiments. For example, the electric heater may be embedded in the adsorbent. Further, the inorganic layered porous particles and the heater may be other than those exemplified above.
つぎに、吸着材の作り方の一例について説明する。Next, an example of how to make an adsorbent will be explained.
無機層状化合物であるＮａ−モンモリロナイト（クニミ
ネ工業側 クニビアＦ）をあらかじめ、水等の溶媒で膨
潤させておく。水溶液中のモンモリロナイトの量は、０
．Ｆ３ｐｔＬ％である。Na-montmorillonite (Kunivia F, Kunimine Industries), which is an inorganic layered compound, is swollen in advance with a solvent such as water. The amount of montmorillonite in the aqueous solution is 0
．． F3ptL%.
ついで、膨潤させたモンモリロナイト水溶液にシリカ−
チタニアゾルを加え、約６０℃で十分に挿入反応させる
。このシリカ−チタニアゾルは、以下のようにして調製
されたものである。全屈アルコキシドのひとつであるエ
チルシリケート（半井化学■ｔりをエチルアルコールと
混合した後、塩酸で加水分解し、これにチタン酸プロポ
キシドの塩酸解こう液を加える。但し、シリカ：チタニ
ア＝１０：１（ｍｏ／比）である。Next, silica was added to the swollen montmorillonite aqueous solution.
Add titania sol and allow sufficient insertion reaction at about 60°C. This silica-titania sol was prepared as follows. After mixing ethyl silicate (Hani Kagaku ■t), which is one of the total alkoxides, with ethyl alcohol, it is hydrolyzed with hydrochloric acid, and a hydrochloric acid peptizer of titanate propoxide is added to this. However, silica: titania = 10 :1 (mo/ratio).
反応をさせた後、遠心分離・洗浄を繰り返して得られた
反応物を、ヘラ等で配向させ板状に成形させた後、凍結
乾燥すると、例えば、１３５ｍｍＸ１３５酎ｘ５Ｈの吸
着材が完成する。After the reaction, the reaction product obtained by repeating centrifugation and washing is oriented with a spatula or the like and formed into a plate shape, and then freeze-dried to complete an adsorbent of, for example, 135 mm x 135 mm x 5 H.
凍結乾燥するようにすると、無機層状多孔質粒子自体に
は小さい寸法の細孔が形成され、粒子同士の間に比較的
大きな寸法の細孔が形成されて上で説明したような、細
孔径分布がふたつの寸法でピークをもつような吸着材も
できる。凍結乾燥の後、さらに焼成するようにして吸着
材を作ってもよい。When freeze-dried, small-sized pores are formed in the inorganic layered porous particles themselves, and relatively large-sized pores are formed between the particles, resulting in the pore size distribution as explained above. It is also possible to create an adsorbent that has peaks in two dimensions. After freeze-drying, the adsorbent may be further calcined to produce the adsorbent.
上のようにして作成した吸着材を用いた吸着フィルター
の吸着効果を、以下のようにして調べた。この吸着フィ
ルターは、第１図に示すフィルターと同じ構成である。The adsorption effect of the adsorption filter using the adsorbent prepared as above was investigated as follows. This adsorption filter has the same structure as the filter shown in FIG.
吸着フィルターを家庭用空気清浄器に取り付けた。清浄
器を作動させると、第１図に実線矢印で示すように、空
気が一例の吸着材表面から入り、他側の吸着材表面に抜
けるように通る。An adsorption filter was attached to a household air purifier. When the purifier is activated, air enters from one adsorbent surface and exits to the other adsorbent surface, as shown by the solid arrow in FIG.
この清浄器を、１ｒｒｌのアクリル樹脂製のボックス内
で運転した。一方、ボックス内は、アンモニアガスが初
期濃度１１００ｐｐとなるように運転前に予め調整して
おく。清浄器の運転開始以降、ボックス内のアンモニア
ガス濃度を測定した。その結果は、第２図にみるように
、アンモニアガス濃度が急速に低下してゆき、アンモニ
アガスも、吸着フィルターで吸着除去できることが確認
されたつぎに、吸着フィルターに飽和になるまでアンモ
ニアガスを吸着させておいて、電気ヒータを作動させ約
り００℃／３０分間の再生のための加熱をおこなった。The purifier was operated in a 1 rrl acrylic box. On the other hand, the inside of the box is adjusted in advance so that the initial concentration of ammonia gas is 1100 pp. After the purifier started operating, the ammonia gas concentration inside the box was measured. As shown in Figure 2, the ammonia gas concentration rapidly decreased, and it was confirmed that ammonia gas could also be adsorbed and removed by the adsorption filter.Then, ammonia gas was added to the adsorption filter until it became saturated. After adsorption, an electric heater was activated to heat the sample at approximately 00° C. for 30 minutes for regeneration.
その後、上記と同じ実験を行い、ボックス内でのアンモ
ニアガス濃度の経時変化を測定した。その結果は、第３
図にみるように、アンモニアガス濃度が時間経過ととも
に急速に低下してゆき、吸着フィルターの再生が十分に
なされることが確認できた。Thereafter, the same experiment as above was conducted, and the change in ammonia gas concentration within the box over time was measured. The result is the third
As shown in the figure, the ammonia gas concentration rapidly decreased over time, confirming that the adsorption filter was sufficiently regenerated.
請求項１．２の発明にかかる吸着フィルターにおいては
、無機層状多孔質粒子からなる吸着材を備えているため
、アンモニア等の低分子ガスを十分に吸着することがで
き、しかも、吸着材を加熱するヒータを備えているため
、吸着フィルタ吸着材の吸着作用が劣化した場合に手間
や高いコストをかけることなく簡単に再生することがで
きるので、極めて実用的である。Since the adsorption filter according to the invention of claim 1.2 is provided with an adsorbent made of inorganic layered porous particles, it is possible to sufficiently adsorb low molecular gas such as ammonia. Since the adsorption filter is equipped with a heater, if the adsorption effect of the adsorption material of the adsorption filter deteriorates, it can be easily regenerated without requiring much effort or high cost, making it extremely practical.
さらに、請求項２の発明の吸着フィルターは、吸着材に
含まれる金属触媒により、吸着物を分解させることがで
き、消臭、あるいは、吸着飽和抑制等の機能をもたせら
れるため、いっそう有用である。Furthermore, the adsorption filter of the invention according to claim 2 is even more useful because it can decompose adsorbed matter by the metal catalyst contained in the adsorbent, and has functions such as deodorization and suppression of adsorption saturation. .
第１図は、この発明にかかる吸着フィルターの一実施例
の模式的外観斜視図、第２図、および、第３図は、この
吸着フィルターのアンモニアガスに対する吸着作用を調
べる実験におけるアンモニアガス濃度の経時変化をあら
れすグラフである。
１・・・吸着フィルター ２・・・吸着材 ３・・・電
気ヒータ
代理人 弁理士 松 本 武 彦
第１図FIG. 1 is a schematic external perspective view of an embodiment of an adsorption filter according to the present invention, and FIGS. 2 and 3 show the ammonia gas concentration in an experiment to investigate the adsorption effect of this adsorption filter on ammonia gas. This is a graph showing changes over time. 1... Adsorption filter 2... Adsorption material 3... Electric heater agent Patent attorney Takehiko Matsumoto Figure 1
Claims (1)
熱するヒータを備えていて、前記吸着材が加熱により再
生させられるようになっている吸着フィルター。 ２ 無機層状多孔質粒子からなる吸着材と同吸着材を加
熱するヒータを備えていて、前記吸着材が加熱により再
生させられるようになっているとともに吸着物を分解さ
せる金属触媒を含んでいる吸着フィルター。[Scope of Claims] 1. An adsorption filter comprising an adsorbent made of inorganic layered porous particles and a heater for heating the adsorbent, so that the adsorbent is regenerated by heating. 2. An adsorbent comprising an adsorbent made of inorganic layered porous particles and a heater for heating the adsorbent, the adsorbent being regenerated by heating and containing a metal catalyst that decomposes the adsorbed material. filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63012821A JPH01189320A (en) | 1988-01-23 | 1988-01-23 | Adsorption filter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63012821A JPH01189320A (en) | 1988-01-23 | 1988-01-23 | Adsorption filter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01189320A true JPH01189320A (en) | 1989-07-28 |
Family
ID=11816050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63012821A Pending JPH01189320A (en) | 1988-01-23 | 1988-01-23 | Adsorption filter |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01189320A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5110328A (en) * | 1989-06-07 | 1992-05-05 | Kabushiki Kaisha Kobe Seiko Sho | Solvent adsorber and solvent recovery system |
| JPH06147736A (en) * | 1993-01-22 | 1994-05-27 | Sanyo Electric Co Ltd | Heater |
| JPH0957111A (en) * | 1995-08-26 | 1997-03-04 | Seibu Giken:Kk | Catalyst carrier capable of regulating temperature or ozone decomposition element |
| WO1999010018A1 (en) * | 1997-08-25 | 1999-03-04 | Ltd. Nikki-Universal Co. | Adsorption, decomposition and deodorization element |
-
1988
- 1988-01-23 JP JP63012821A patent/JPH01189320A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5110328A (en) * | 1989-06-07 | 1992-05-05 | Kabushiki Kaisha Kobe Seiko Sho | Solvent adsorber and solvent recovery system |
| JPH06147736A (en) * | 1993-01-22 | 1994-05-27 | Sanyo Electric Co Ltd | Heater |
| JPH0957111A (en) * | 1995-08-26 | 1997-03-04 | Seibu Giken:Kk | Catalyst carrier capable of regulating temperature or ozone decomposition element |
| WO1999010018A1 (en) * | 1997-08-25 | 1999-03-04 | Ltd. Nikki-Universal Co. | Adsorption, decomposition and deodorization element |
| US6524535B1 (en) | 1997-08-25 | 2003-02-25 | Nikki-Universal Co., Ltd. | Adsorption, decomposition deodorization element |
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