JPH01175911A - Liquid mothproofing agent - Google Patents
Liquid mothproofing agentInfo
- Publication number
- JPH01175911A JPH01175911A JP62334928A JP33492887A JPH01175911A JP H01175911 A JPH01175911 A JP H01175911A JP 62334928 A JP62334928 A JP 62334928A JP 33492887 A JP33492887 A JP 33492887A JP H01175911 A JPH01175911 A JP H01175911A
- Authority
- JP
- Japan
- Prior art keywords
- liquid
- insect repellent
- resin film
- permeable
- bag
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 47
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 10
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 claims abstract description 9
- 229920000098 polyolefin Polymers 0.000 claims abstract description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 239000000077 insect repellent Substances 0.000 claims description 49
- 238000002386 leaching Methods 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 5
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims 1
- 230000000717 retained effect Effects 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 8
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 239000012633 leachable Substances 0.000 abstract 2
- 238000004806 packaging method and process Methods 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 229920003002 synthetic resin Polymers 0.000 description 9
- 239000000057 synthetic resin Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分舒）
本発明は液体防虫剤に関し、詳しくは家庭的に、洋服ダ
ンス等の衣装ケースで使用される衣類等の防虫剤に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application) The present invention relates to a liquid insect repellent, and more particularly to an insect repellent for clothing, etc., used at home in clothing cases such as wardrobes.
（従来の技術）
一般に、衣類等を収納するいわゆる洋服ダンス等にあっ
ては、その保管中の虫食いなどを防ぐ目的で防虫剤を衣
類と共に入れるのが通常である。(Prior Art) In general, in so-called wardrobes for storing clothes, etc., insect repellents are usually placed with the clothes in order to prevent them from being eaten by insects during storage.
このような防虫剤として従来使用されるものとして代表
的なものとしてパラジクロベンゼン等を有効成分とした
固形防虫剤が知られている。Solid insect repellents containing paradiclobenzene or the like as an active ingredient are known as typical insect repellents conventionally used.
またこのような固体防虫剤に代わるものとして、近時に
おいて液体防虫剤をろ紙に含浸させた形式の防虫剤も提
案されている。In addition, as an alternative to such solid insect repellents, insect repellents in the form of filter paper impregnated with liquid insect repellents have recently been proposed.
（発明が解決しようとする問題点）
しかし上記のようなろ紙含浸タイプの防虫剤は、使用さ
れている状態が適性に防虫効果の発揮される状態である
か否かの判別が困難であるという問題のあることが指摘
される。つまりろ紙に含浸させた防虫剤が気散し消費さ
れてもその外観形状的な変化はなく、防虫効果の終点が
分りずらいのである。また固体防虫剤と同様にろ紙含浸
タイプの防虫剤に香の成分をつけることも考えられるが
、このような方式は香の気散と防虫成分の気散の速度が
異なると意味がないなど、香で上記防虫効果の終点を検
出する方式％式％
本発明は、以上の観点からなされたものであり、その目
的は、従来にない新規な液体防虫剤を提供するところに
ある。(Problem to be solved by the invention) However, with the filter paper impregnated type insect repellent as described above, it is difficult to determine whether or not the conditions in which it is being used are such that the insect repellent effect can be properly exerted. Problems are pointed out. In other words, even if the insect repellent impregnated into the filter paper is dispersed and consumed, there is no change in its appearance or shape, making it difficult to determine the end point of the insect repellent effect. It is also possible to add an incense ingredient to a filter paper-impregnated insect repellent like solid insect repellents, but such a method is meaningless if the rate of diffusion of the incense and the insect repellent ingredient are different. Method for detecting the end point of the insect repellent effect using scent % Formula % The present invention has been made from the above point of view, and its object is to provide a novel liquid insect repellent that has not existed before.
また本発明の別の目的は、目視で防虫剤の消費状態が確
認できる液体防虫剤を提供するところにある。Another object of the present invention is to provide a liquid insect repellent that allows the consumption state of the insect repellent to be visually confirmed.
（問題点を解決するための手段）
而して、かかる目的の実現のためになされた本発明より
なる液体防虫剤の特徴は、非アルコール系有機溶媒にエ
ムペントリンを防虫有効成分として溶解させた液を、液
浸出退過性の透明樹脂フィルムからなる扁平な袋容器中
に充填し、この袋容器を通気性のある外装ケース内に保
持させてなる構成をなすところにある。(Means for Solving the Problems) Therefore, the liquid insect repellent according to the present invention, which was made to achieve the above object, is characterized by a liquid in which empenthrin is dissolved as an active insect repellent ingredient in a non-alcoholic organic solvent. is filled in a flat bag container made of a transparent resin film that allows liquid to seep out and recede, and the bag container is held in an air permeable exterior case.
本発明におけるエムペントリンを防虫有効成分とする防
虫液体は、非アルコール系の有機溶媒に溶解されて使用
されるがこのような有機溶媒としては、例えばイソパラ
フィン系溶剤が好ましく例示される他、無臭及び無臭に
近い炭化水素溶剤、ハロゲン化炭化水素溶剤、エステル
類溶剤等を例示することができる。また該防虫液体には
必要に応じて香料、あるいはその他の添加剤を添加して
もよい。The insect repellent liquid containing empenthrin as an active insect repellent ingredient in the present invention is used after being dissolved in a non-alcoholic organic solvent, and examples of such organic solvents include preferably isoparaffinic solvents, as well as odorless and odorless solvents. Examples include hydrocarbon solvents similar to , halogenated hydrocarbon solvents, and ester solvents. Further, fragrances or other additives may be added to the insect repellent liquid as necessary.
上記構成における液浸出退過性の透明樹脂フィルムとし
ては、液の浸出透過性をコントロールすることができる
フィルムとして、ビニルアセテートが５〜６０％のポリ
オレフィンビニルアセテートあるいはエチルアレキレー
トが５〜６０％のポリオレフィンエチルアレキレートが
好ましく使用される。このフィルムの厚みは一般的には
２×１０〜３ Ｘ １０３μｍであることが好ましい、
液浸出退過性の透明樹脂フィルムがこれ以上薄いと破れ
たりする強度上の問題があり、厚くなりすぎると内部の
液が外部に浸出透過する速度が遅くなりすぎて目的とす
る液体防虫剤を構成することに適さない。The liquid leaching and retractable transparent resin film in the above configuration is a polyolefin vinyl acetate film containing 5 to 60% vinyl acetate or a polyolefin vinyl acetate film containing 5 to 60% ethyl acelate, which can control liquid leaching permeability. Polyolefin ethyl arechelate is preferably used. The thickness of this film is generally preferably 2 x 10 to 3 x 103 μm.
If the liquid leaching/retracting transparent resin film is thinner than this, there will be problems with its strength, such as tearing, and if it becomes too thick, the rate at which the liquid inside will leached out and permeate to the outside will be too slow, making it difficult to use the intended liquid insect repellent. Not suitable for configuration.
（発明の効果）
本発明よりなる液体防虫剤によれば、防虫剤の容器であ
る透明な袋を通して内の液体の残量すなわち防虫剤の残
量を目視で確認することができ、したがってその使用の
終点を容易に確認して防虫剤の交換等を行なうことがで
きるため、衣装ケース等の内部を常に防虫雰囲気に保つ
ことができるという効果がある。(Effects of the Invention) According to the liquid insect repellent of the present invention, it is possible to visually check the remaining amount of liquid inside the insect repellent, that is, the remaining amount of the insect repellent, through the transparent bag that is the container for the insect repellent, and therefore the use of the liquid insect repellent can be confirmed visually. Since the end point of the insect repellent can be easily confirmed and the insect repellent can be replaced, etc., the inside of the costume case etc. can be kept in an insect-proof atmosphere at all times.
また本発明により防虫効果の優れたエムペントリンを液
体のまま防虫剤として使用することが可能となり、通気
性のある剛性容器内にプラスチックの袋に詰めた形式の
防虫剤を、該袋の交換で繰返し使用することもできると
いう効果も得られる。またこのような通気性のある剛性
容器内に液体防虫剤の充填袋を収納させた形式の場合に
は、該袋が衣類等に直接接触する虞れがなく、衣類を汚
さないという実用的な利点も確保される。Furthermore, the present invention makes it possible to use empenthrin, which has an excellent insect repellent effect, as an insect repellent in its liquid form, and the insect repellent can be used repeatedly by replacing the bag with a plastic bag inside a rigid, breathable container. It also has the advantage of being usable. In addition, in the case of such a type in which a bag filled with liquid insect repellent is stored in a breathable rigid container, there is no risk that the bag will come into direct contact with clothing, etc., and it is practical because it does not stain clothing. Benefits are also secured.
（実施例） 以下本発明を図面に示す実施例に基づいて説明する。(Example) The present invention will be described below based on embodiments shown in the drawings.
第１図ないし第３図は、易破壊性のアルミ袋に液体防虫
剤を充填してこれを透明な合成樹脂製の袋容器１に内装
させ、更に該透明な合成樹脂製の袋をプラスチック製の
通気性ある外装ケースである剛性容器２内に収納させる
形式で構成した本発明の詳細な説明するためのものであ
り、この図において、非アルコール系有機溶媒にエムペ
ントリンを防虫有効成分として溶解させた液は、易破壊
性のアルミ袋１１に充填され、使用に際して該アルミ袋
１１は指で押圧することで破壊され、内部の充填液は合
成樹脂製の透明袋１２内部に満ちる。Figures 1 to 3 show an easily breakable aluminum bag filled with a liquid insect repellent, placed inside a bag container 1 made of transparent synthetic resin, and then the transparent synthetic resin bag filled with a plastic bag. This is a detailed explanation of the present invention, which is housed in a rigid container 2 which is an air-permeable exterior case. The liquid is filled in an easily breakable aluminum bag 11, and when used, the aluminum bag 11 is broken by pressing with a finger, and the filled liquid fills the transparent bag 12 made of synthetic resin.
この合成樹脂製の透明袋１２は、上述の如くポリオレフ
ィンビニルアセテートあるいはポリオレフィンエチルア
レキレートによりフィルムを通しての液の浸出透過がで
きる他は外部から封止されて好ましく形成される。The transparent bag 12 made of synthetic resin is preferably formed by being sealed from the outside with polyolefin vinyl acetate or polyolefin ethyl acelate, as described above, except that the liquid can be permeated through the film.
なお本例の合成樹脂製の透明袋１２には、後記するプラ
スチック製の通気性ある剛性容器２内部に概ね垂直の姿
勢で保持されるように、該剛性容器２内の吊突起に係合
する孔部１３，１３が設けられている。なお本例の透明
袋１２にはアルミ袋１１のズレ止めをなすシール部１４
．１４が形成されている。Note that the transparent bag 12 made of synthetic resin in this example is engaged with a hanging protrusion inside the rigid container 2, which will be described later, so that it is held in a generally vertical position inside the rigid container 2, which is made of air permeable plastic and will be described later. Holes 13, 13 are provided. Note that the transparent bag 12 in this example has a seal portion 14 that prevents the aluminum bag 11 from slipping.
．． 14 is formed.
上記プラスチック製の通気性ある剛性容器２は、本例で
は第２図で示しているように、衣装ケース等での使用が
便利であるように吊下げ式とできるように上部にフック
部２１が形成されていると共に、通気のための中央の開
口２２が太きく開けられている。そして上記合成樹脂製
の透明袋１２をその偏平な状態で概ね垂直の姿勢を保持
できるように全体として薄いケースをなしていると共に
、開口２２には袋保持のための多数のリブ２３が設けら
れている。なお２４は中央開口の側方に形成された側方
開口であり、容器の通気性を一層高めるためのものであ
る。In this example, the air permeable rigid container 2 made of plastic has a hook portion 21 at the top so that it can be hung so that it can be conveniently used as a costume case, etc., as shown in FIG. The central opening 22 for ventilation is wide open. The transparent bag 12 made of synthetic resin is formed into a thin case as a whole so that it can be maintained in a generally vertical position in its flat state, and the opening 22 is provided with a large number of ribs 23 for holding the bag. ing. Note that 24 is a side opening formed on the side of the central opening, and is for further increasing the air permeability of the container.
また容器内部の上方位置には、上記合成樹脂製の透明袋
１２を概ね垂直の姿勢で保持するための孔部１３．１３
に係合する吊突起２５が一対に設けられている。Further, at an upper position inside the container, there is a hole 13.13 for holding the transparent bag 12 made of synthetic resin in a generally vertical position.
A pair of hanging protrusions 25 are provided to engage with.
２６は、合成樹脂製の透明袋１２を収納して剛性容器２
を閉じた時に該透明袋１２に内装のアルミ袋を外部から
押圧して破壊させるための押圧舌片である。26 is a rigid container 2 that stores a transparent bag 12 made of synthetic resin.
This is a pressing tongue piece for pressing the aluminum bag inside the transparent bag 12 from the outside to destroy it when the transparent bag 12 is closed.
なお本発明は上記実施例のものに限定されるものではな
く、例えば外装ケースは弾性のあるケースであってもよ
いし、第４図に示すように容器の通気性を考慮して小さ
な開口２７を多数形成した形式の構成のものであっても
よい（第４図の剛性容器のその他の構成は第２図および
第３図で示したものと同じである）。Note that the present invention is not limited to the above-mentioned embodiments; for example, the outer case may be an elastic case, or a small opening 27 may be formed in consideration of the air permeability of the container as shown in FIG. (The other structure of the rigid container shown in FIG. 4 is the same as that shown in FIGS. 2 and 3).
実施例１
上述した図面に示したアルミ袋内部に、次の組成の防虫
液体をｊｉｇを充填した。Example 1 A jig was filled with an insect repellent liquid having the following composition into the aluminum bag shown in the above drawing.
エムペントリン １５重量部
イソパラフィン系溶剤 ８５重量部
（沸点範囲７３〜３５２℃）
主成分は炭素数１７〜１８・・・３０９６炭素数１９〜
２０・・・３０を
炭素数２１〜２２・・・２５零
その他炭素数の異なるものを含む
香料 １０重量部
このアルミ袋をエチルアルキレート１５％のポリエチル
アルキレート（フィルム厚み１００μｍ）の合成樹脂製
の透明袋に内装し、これを第２図に示した剛性容器に収
納させた。収納後押圧舌片２６の押圧によりアルミ袋を
破壊し、透明袋内に液を充満させた。この状態で６力月
使用したところ、次第に液の減少が目視で確認され、交
換時期に至ったことが容易に分った。Empenthrin 15 parts by weight Isoparaffinic solvent 85 parts by weight (boiling point range 73-352°C) Main component has 17-18...3096 carbon atoms 19-3096 carbon atoms
10 parts by weight of fragrances containing 20...30, 21 to 22...25 zero carbon atoms, and other substances with different carbon numbers.This aluminum bag is made of synthetic resin of polyethyl alkylate (film thickness 100 μm) containing 15% ethyl alkylate. This was placed inside a transparent bag, and this was stored in a rigid container shown in FIG. After storage, the aluminum bag was broken by pressing with the pressing tongue piece 26, and the transparent bag was filled with liquid. After using it in this condition for 6 months, it was visually confirmed that the liquid level gradually decreased, and it was easy to see that it was time to replace it.
実施例２
防虫液体を次の組成のものに変更し、また透明袋を次の
ものに変更した以外は実施例１と同様にして液体防虫剤
を作成した。Example 2 A liquid insect repellent was prepared in the same manner as in Example 1, except that the insect repellent liquid was changed to the one with the following composition and the transparent bag was changed to the one shown below.
エムペントリン １５重量部
イソパラフィン系溶剤 １０５重量部
（沸点範囲７３〜３５２℃）
香料 ２０重量部
エチルアルキレート１８％のポリエチルアルキレート（
フィルム厚み２００μｍ）
実施例３
防虫液体を次の組成のものに変更し、また透明袋を次の
ものに変更した以外は実施例１と同様にして液体防虫剤
を作成した。Empenthrin 15 parts by weight Isoparaffinic solvent 105 parts by weight (boiling range 73-352°C) Fragrance 20 parts by weight Ethyl alkylate 18% polyethyl alkylate (
Example 3 A liquid insect repellent was prepared in the same manner as in Example 1, except that the insect repellent liquid was changed to the one with the following composition and the transparent bag was changed to the one shown below.
エムペントリン １５重量部
イソパラフィン系溶剤 ７５重量部
（沸点範囲７３〜３５２℃）
香料 ２０重量部
エチルアルキレート１０％のポリエチルアルキレート（
フィルム厚み２００μｍ）Empenthrin 15 parts by weight Isoparaffinic solvent 75 parts by weight (boiling range 73-352°C) Fragrance 20 parts by weight Ethyl alkylate 10% polyethyl alkylate (
Film thickness 200μm)
図面第１図は、液体防虫剤を易破壊性のアルミ袋に充填
し該アルミ袋を液浸出透過性の透明樹脂フィルムからな
る扁平な袋容器内に内装させた本発明の実施例の構成概
要−例を示す図、第２図は上記液浸出透過性の透明樹脂
フィルムからなる扁平な袋容器を収納するプラスチック
製の剛性容器を開いた状態を示した斜視図、第３図は同
剛性容器を閉じた状態の正面図を示した図、第４図は剛
性容器の他の実施例を示した図である。
１１：透明袋 １２ニアルミ袋２：剛性容器
２２：中央開口 ２６：押圧舌片第３図Figure 1 is a schematic diagram of an embodiment of the present invention, in which a liquid insect repellent is filled into an easily breakable aluminum bag, and the aluminum bag is placed inside a flat bag container made of a transparent resin film that is permeable to liquid leaching. - Figures illustrating an example; Figure 2 is a perspective view showing an open state of a plastic rigid container that houses the flat bag container made of the liquid leaching permeable transparent resin film; Figure 3 is a perspective view of the same rigid container; FIG. 4 is a diagram showing another embodiment of the rigid container. 11: Transparent bag 12 Aluminum bag 2: Rigid container 22: Center opening 26: Pressing tongue piece Fig. 3
Claims (4)
有効成分として溶解させた液を、液浸出透過性の透明樹
脂フィルムからなる扁平な袋容器中に充填し、この袋容
器を通気性のある外装ケース内に保持させてなることを
特徴とする液体防虫剤。(1) A solution in which empenthrin is dissolved as an active insect repellent ingredient in a non-alcoholic organic solvent is filled into a flat bag container made of a transparent resin film that is permeable to liquid leaching, and the bag container is enclosed in a breathable exterior case. A liquid insect repellent characterized by being retained in a liquid insect repellent.
アセテートが５〜６０％のポリオレフィンビニルアセテ
ートであることを特徴とする特許請求の範囲第（１）項
記載の液体防虫剤。(2) The liquid insect repellent according to claim (1), wherein the liquid leaching permeable transparent resin film is polyolefin vinyl acetate containing 5 to 60% vinyl acetate.
アレキレートが５〜６０％のポリオレフィンエチルアレ
キレートであることを特徴とする特許請求の範囲第（１
）項記載の液体防虫剤。(3) The liquid leaching permeable transparent resin film is a polyolefin ethyl arekylate containing 5 to 60% ethyl arekylate.
Liquid insect repellent described in ).
２×１０〜３×１０＾３μｍであることを特徴とする特
許請求の範囲第（１）項ないし第（３）項のいずれかに
記載の液体防虫剤。(4) The thickness of the liquid leaching permeable transparent resin film is
The liquid insect repellent according to any one of claims (1) to (3), characterized in that the particle size is 2×10 to 3×10^3 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62334928A JPH082768B2 (en) | 1987-12-28 | 1987-12-28 | Liquid insect repellent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62334928A JPH082768B2 (en) | 1987-12-28 | 1987-12-28 | Liquid insect repellent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01175911A true JPH01175911A (en) | 1989-07-12 |
| JPH082768B2 JPH082768B2 (en) | 1996-01-17 |
Family
ID=18282808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62334928A Expired - Lifetime JPH082768B2 (en) | 1987-12-28 | 1987-12-28 | Liquid insect repellent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH082768B2 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6156109A (en) * | 1984-08-25 | 1986-03-20 | Dainippon Jiyochiyuugiku Kk | Insecticide for cloth |
| JPS62175001U (en) * | 1986-04-23 | 1987-11-06 |
-
1987
- 1987-12-28 JP JP62334928A patent/JPH082768B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6156109A (en) * | 1984-08-25 | 1986-03-20 | Dainippon Jiyochiyuugiku Kk | Insecticide for cloth |
| JPS62175001U (en) * | 1986-04-23 | 1987-11-06 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH082768B2 (en) | 1996-01-17 |
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