JPH01161100A - Packaged, high-bulk density particulate detergent - Google Patents
Packaged, high-bulk density particulate detergentInfo
- Publication number
- JPH01161100A JPH01161100A JP31962987A JP31962987A JPH01161100A JP H01161100 A JPH01161100 A JP H01161100A JP 31962987 A JP31962987 A JP 31962987A JP 31962987 A JP31962987 A JP 31962987A JP H01161100 A JPH01161100 A JP H01161100A
- Authority
- JP
- Japan
- Prior art keywords
- bulk density
- detergent
- container
- side wall
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 55
- 239000004033 plastic Substances 0.000 claims abstract description 17
- 229920003023 plastic Polymers 0.000 claims abstract description 17
- 239000002131 composite material Substances 0.000 claims abstract description 11
- 230000002093 peripheral effect Effects 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 20
- 239000000463 material Substances 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 12
- 238000003860 storage Methods 0.000 abstract description 6
- 239000004094 surface-active agent Substances 0.000 abstract description 6
- 238000000465 moulding Methods 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 102000004190 Enzymes Human genes 0.000 abstract description 2
- 108090000790 Enzymes Proteins 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract description 2
- 239000007844 bleaching agent Substances 0.000 abstract description 2
- 239000003638 chemical reducing agent Substances 0.000 abstract description 2
- 239000007850 fluorescent dye Substances 0.000 abstract description 2
- 230000003014 reinforcing effect Effects 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 230000000740 bleeding effect Effects 0.000 abstract 1
- 239000013522 chelant Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000002991 molded plastic Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 238000002386 leaching Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 125000000075 primary alcohol group Chemical group 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000003109 potassium Chemical class 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Rigid Containers With Two Or More Constituent Elements (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
技梵欽互
本発明は、保存時の容器底部における浸み出しを改善し
た特殊容器入りの高嵩密度粒状洗剤に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a high bulk density granular detergent packaged in a special container that has improved leaching at the bottom of the container during storage.
従属
従来の洗剤は、溶解性を良好にする目的で、噴霧乾燥に
より平均粒径２００〜８００μｍ程度のビーズ状中空粒
子としている。その結果、嵩密度が０．３ｇ／ｃｃ程度
と低くなり、輸送コストがかさむばかりか保管、陳列に
もかなりのスペースをさかなければならないという欠点
があった。In order to improve solubility, conventional detergents are spray-dried into bead-like hollow particles with an average particle size of about 200 to 800 μm. As a result, the bulk density is as low as about 0.3 g/cc, which not only increases transportation costs but also requires a considerable amount of space for storage and display.
そこで、このような現在の噴霧乾燥洗剤の欠点を解決し
、少ない洗剤使用量で洗浄が可能な高嵩密度洗剤の開発
がまたれていた。Therefore, there has been a need to develop a high bulk density detergent that can solve these drawbacks of current spray-dried detergents and enable cleaning with a small amount of detergent.
噴霧乾燥法によらない粒状洗剤の製造方法としては、特
公昭４６−７５８６号公報、特開昭４９−７４７０３号
公報、特公昭５５−４９５３５号公報などに、原料とし
て予め結晶水を有する物質や加熱により容易に溶融化す
る物質などを用い、熱的操作を加えて結晶水の放出ある
いは溶融化物の溶融を起させ、これをバインダーとして
数個〜数ＩＯ個を凝集造粒させる方法がある。As a method for producing granular detergents that does not involve spray drying, methods such as those disclosed in Japanese Patent Publication No. 7586/1986, Japanese Patent Publication No. 74703/1983, and Japanese Patent Publication No. 49535/1983 disclose methods for producing granular detergents using substances that have water of crystallization in advance as a raw material. There is a method of using a substance that is easily melted by heating, applying a thermal operation to release crystal water or melting the molten product, and using this as a binder, several to several IO particles are agglomerated and granulated.
しかし、これらの方法では、得られる粒状洗剤の粒度分
布が広かったり、水への溶解性が劣るなどの弊害があり
、実用的な方法とは八′えなかった。However, these methods had disadvantages such as the resulting granular detergent having a wide particle size distribution and poor solubility in water, and were not practical.
また、特開昭５３−４３７１０号公報には、無機ビルダ
ーを主体とする多孔質ビーズにノニオン界面活性剤を噴
霧する高嵩密度洗剤の製法が示されている。しかし、こ
の洗剤はノニオン界面活性剤を主体としているために低
泡性であり、日本のように高発泡性が要求される洗剤と
して不適である。Furthermore, Japanese Patent Application Laid-Open No. 53-43710 discloses a method for producing a high bulk density detergent in which a nonionic surfactant is sprayed onto porous beads containing an inorganic builder as a main component. However, since this detergent is mainly composed of nonionic surfactants, it has low foaming properties, making it unsuitable for detergents that require high foaming properties, such as those in Japan.
本出願人は、このような要求に答えるべく洗剤組成物を
緊密捏和、混合して得た捏和物を解砕したのち、平均−
次位径１０μｍ以下の水不溶性微粉体でコーティングす
る高嵩密度洗剤の製造法を提案した（特開昭６０−９６
６９８号公報）。In order to meet such demands, the applicant has proposed that after crushing the kneaded product obtained by intimately kneading and mixing detergent compositions, the average -
We proposed a method for producing high bulk density detergents by coating them with water-insoluble fine powder with a sub-diameter of 10 μm or less (Japanese Unexamined Patent Publication No. 60-96
Publication No. 698).
ところで、従来の粒状洗剤では、容器として、低価格の
点や製造、成形の容易さ、印刷性などの点から、加工紙
を材料とする箱型容器が一般に用いられていた。Incidentally, in conventional granular detergents, box-shaped containers made of processed paper have generally been used because of their low cost, ease of manufacture and molding, and printability.
しかし、このような従来の箱型紙容器を、高嵩密度洗剤
にそのまま適用しても満足のいく結果は得られない。高
嵩密度粒状洗剤は、界面活性剤の含有量が多く、かつ嵩
密度が高いため、従来の紙容器に収納・保管した場合に
はわずかな吸湿によって固化を生じ、更には含有する界
面活性剤と水とが作用し、粘着性物質が容器の外に浸出
する言わゆる″浸み出し″を生じる。この浸み出しは、
外観を損ねるばかりでなく、容器を置いた床等を汚し、
商品として問題が太きν蒐。However, if such conventional box-shaped paper containers are applied as is to high bulk density detergents, satisfactory results cannot be obtained. High bulk density granular detergents contain a large amount of surfactant and have a high bulk density, so if they are stored in conventional paper containers, they will solidify due to slight moisture absorption, and the surfactants they contain will The action of the adhesive and water causes the sticky substance to seep out of the container. This seepage is
Not only does it spoil the appearance, but it also stains the floor where the container is placed.
There are major problems with the product.
浸み出し防止のために、通常の紙容器底部に樹脂の皿を
別途接着させた例もあるが、この場合隙間から水が浸入
してしまい、また、外観」二も好ましくない。箱型の紙
容器と樹脂器とを上記問題が起こることのないような精
度で作成することはコストや工業的な観点からは実質上
不可能である。In order to prevent seepage, there are examples in which a resin plate is separately attached to the bottom of a normal paper container, but in this case water can seep in through the gaps, and the appearance is also undesirable. From a cost and industrial perspective, it is virtually impossible to manufacture box-shaped paper containers and resin containers with such precision that the above-mentioned problems do not occur.
見■段■攻
本発明は、経口による浸み出しを改善した容器入り高嵩
密度粒状洗剤を提供するものである。Summary of the Invention The present invention provides a packaged high bulk density granular detergent with improved oral leaching.
見匪夏堡双
本発明の容器入り高嵩密度粒状洗剤は、底抜、側壁下部
および該側壁下部から上方に延設される少なくとも２つ
の立設片部が一体成形されたプラスチック成形体と、該
側壁下部と立設片部との外周面に結合されて容器側壁部
の大半を構成する紙シート体とから一体的に形成された
複合材料容器に、嵩密度０．５〜Ｌ２ｇ／ｃｃの粒状洗
剤を収納したことを特徴とする。The high bulk density granular detergent packaged in a container of the present invention includes a plastic molded body integrally formed with a bottom, a lower side wall, and at least two upright pieces extending upward from the lower side wall; A composite material container integrally formed from the lower part of the side wall and a paper sheet body that constitutes most of the container side wall by being joined to the outer peripheral surface of the upright piece is coated with a material having a bulk density of 0.5 to L2 g/cc. It is characterized by storing granular detergent.
以下、本発明について更に詳細に説明する。The present invention will be explained in more detail below.
第１図は、本発明で用いられる複合材料容器の容器本体
１１の構成例を示す分解斜視図であり、第２図は、蓋体
３３を合わせて示す第１図の線Ａ−八力方向沿った断面
図である。FIG. 1 is an exploded perspective view showing a configuration example of a container body 11 of a composite material container used in the present invention, and FIG. FIG.
複合材料容器は、容器本体１および蓋体３１とからなっ
ており、容器本体】１の係止突起２５を介して手提用の
帯を付けることができる。容器１１および蓋体３１は、
特に材料は限定されないが、可撓性プラスチック材料か
ら形成することが望ましい。容器本体１１は、プラスチ
ック成形体１３と紙シート状体３１とから構成されてい
る。プラスチック成形体１３は、底板１５、側壁下部１
７、立設片１９．１９および側壁上部２３とが一体成形
されている。立設片１９．１９には補強用のリブ２１，
２１が設けられている。側壁下部１７．立設片１９，１
９および側壁上部２３の外周面の大部分には紙シート休
３１の裏面が隙間を設けることなく、しっかりと結合さ
れており、この紙シート状体３１が容器側壁部の外周面
の大半を形成する。即ち、容器本体１１の側壁部のほと
んどは紙シート状体３１の外表面で覆われることとなる
。The composite material container consists of a container body 1 and a lid 31, and a strap for carrying can be attached via a locking projection 25 of the container body 1. The container 11 and the lid 31 are
Although the material is not particularly limited, it is preferably formed from a flexible plastic material. The container body 11 is composed of a plastic molded body 13 and a paper sheet-like body 31. The plastic molded body 13 includes a bottom plate 15 and a side wall lower part 1.
7. The standing pieces 19, 19 and the side wall upper part 23 are integrally molded. The standing piece 19.19 has reinforcing ribs 21,
21 are provided. Lower side wall 17. Standing piece 19,1
9 and most of the outer circumferential surface of the side wall upper part 23, the back surface of a paper sheet 31 is firmly joined without any gap, and this paper sheet-like body 31 forms most of the outer circumferential surface of the container side wall part. do. That is, most of the side wall portion of the container body 11 is covered with the outer surface of the paper sheet-like body 31.
紙シート状体３１とプラスチックから形成される側壁下
部１７とは一体的に構成されており、両者の間から水が
浸入することはなく、また、紙シート状体３１が側壁の
ほとんど下端部までを覆っているので、外観上の不都合
もなく、紙のもつ印刷特性を利用して、任意の意匠効果
を施したり、情報を印刷することができる。プラスチッ
ク成形体１３と紙シート状体３１との結合は、通常の接
着により行うこともできるが、紙シート状体３１をイン
ジェクション等の成形金型内に装填し、この中に溶融、
流動化したプラスチック材料を流し込み、プラスチック
成形体１３の成形と同時に容器本体１１を形成すること
が望ましい。The paper sheet-like body 31 and the lower side wall 17 made of plastic are integrally constructed, so that water does not enter between the two, and the paper sheet-like body 31 extends almost to the lower end of the side wall. Since it covers the surface of the paper, there is no problem with the appearance, and the printing characteristics of paper can be used to apply any design effect or print information. The plastic molded body 13 and the paper sheet-like body 31 can be joined together by ordinary adhesion, but the paper sheet-like body 31 is loaded into a mold such as an injection mold, and the paper sheet-like body 31 is melted and
It is desirable to form the container body 11 simultaneously with the molding of the plastic molded body 13 by pouring the fluidized plastic material.
これにより１本発明の複合材料容器の一体性をいっそう
高めると共に、製造も容易となる。This further enhances the integrity of the composite material container of the present invention and facilitates its manufacture.
第３図の容器本体横断面図に示すように、容器本体１１
の側壁の４つのコーナー２９は曲率を有することが望ま
しい。高嵩密度粒状洗剤は、既に述べたように界面活性
剤の含有量が多く、しかも嵩密度が高いため、容器のコ
ーナ一部、特に底部に近い部分で圧密を受け、同化が生
じやすい。従来の加工紙を用いた箱型容器はコーナ一部
が曲率を有せず、直角であり、また曲率をもたせること
も困難であり、上記のような同化を有効に防止すること
が難しかった。−変面化を生じた洗剤は取り出しにくく
、また、商品イメージからも問題がある。さらに、曲率
を設けることで、容器内の洗剤がスプーン等で取り出し
やすくもなる。このようにコーナ一部に曲率を設けるこ
とにより、圧密による固化が防止でき、長期保存しても
問題が生じない。この曲率としては、曲率半径１〜２０
ｍｍの範囲が好ましい。As shown in the cross-sectional view of the container body in FIG.
Preferably, the four corners 29 of the sidewalls of the four corners 29 of the sidewalls have curvature. As mentioned above, high bulk density granular detergents contain a large amount of surfactant and have a high bulk density, so they are likely to be compacted and assimilated in some corners of the container, particularly in areas near the bottom. In conventional box-shaped containers using processed paper, some of the corners have no curvature and are at right angles, and it is also difficult to provide curvature, making it difficult to effectively prevent the above-mentioned assimilation. - Discolored detergent is difficult to remove, and there are also problems with the product image. Furthermore, the curvature makes it easier to take out the detergent inside the container with a spoon or the like. By providing a curvature in a part of the corner in this way, it is possible to prevent solidification due to compaction, and no problem occurs even when stored for a long period of time. This curvature has a radius of 1 to 20
A range of mm is preferred.
コーナ一部に曲率を設けることは、プラスチック成形体
１３のコーナ一部２１に対応する曲率を設けることによ
り実現でき、従来の紙容器と比べて曲率の形成は極めて
容易である。Providing a curvature at a part of the corner can be achieved by providing a curvature corresponding to the part 21 of the corner of the plastic molded body 13, and forming the curvature is extremely easy compared to conventional paper containers.
紙シート状体３１は、その裏面をプラスチック成形体１
３の側壁下部１７、立設片］、 ９ 、 ］、 ９およ
び側壁上部２３の外表面に固定することにより、容器と
して十分な強度を実現できる。また、大面積を占め、か
つ、使用者から見えやすい部分に当る側壁部を紙材料で
形成できるので、容器の低コスト化が可能となるばかり
か、紙のもつ印刷特性等を十二分に活用することができ
る。紙シート状体３１は、加工紙などの紙材料で形成で
きるが、ポリプロピレンシートなどを圧着させて防湿性
を高めることもできる。The paper sheet-like body 31 has its back side covered with the plastic molded body 1.
By fixing it to the outer surface of the side wall lower part 17, the standing pieces], 9, ], 9 and the side wall upper part 23 of No. 3, sufficient strength as a container can be achieved. In addition, since the side wall portion, which occupies a large area and is easily visible to the user, can be made of paper material, it is possible to reduce the cost of the container, and to fully utilize the printing characteristics of paper. It can be utilized. The paper sheet-like body 31 can be formed of a paper material such as processed paper, but it can also be made of a polypropylene sheet or the like to improve moisture resistance.
側壁上部２３を、立設片１９．１９、側壁下部１７およ
び底板１５と共に一体形成することは、プラスチック成
形体１３の強度の点から、ひいては容器本体１１の強度
の観点から望ましいことである。It is desirable to integrally form the side wall upper part 23 with the upright piece 19, 19, the side wall lower part 17, and the bottom plate 15 from the viewpoint of the strength of the plastic molded body 13 and, in turn, from the viewpoint of the strength of the container body 11.
また、側壁上部２３をプラスチック材料から形成し、そ
こに嵌合用突起２７を設け、さらに蓋体３１もプラスチ
ック材料から形成して対応する嵌合凹入部を設けること
により、プラスチック材料のもつ可撓性を利用して、密
封シールを形成することが可能となる。これにより、保
存時の吸湿をより有効に防止できる。In addition, by forming the side wall upper part 23 from a plastic material and providing the fitting protrusion 27 therein, and by also forming the lid body 31 from a plastic material and providing a corresponding fitting recess, the flexibility of the plastic material can be achieved. can be used to form a hermetic seal. Thereby, moisture absorption during storage can be more effectively prevented.
上記複合材料容器には、嵩密度
０．５〜１．２ｇ／ｃｃの高嵩密度粒状洗剤組成物が収
納される。このような洗剤組成物は、必要な洗剤成分を
造粒して、中空粒子ではなく内部まで洗剤成分が詰まっ
た粒子とすることにより得られる。この造粒法としては
、前述の特開昭６０−９６６９８号公報に記載されたよ
うに、各洗剤原料をニーダで捏和、混合し、カッターミ
ルタイプ等の解砕機で解砕造粒し、さらにこの解砕物を
平均粒径１１０７ｚ以下の水不溶性微粉体でコーティン
グすることにより行なわれる。また、洗剤成分を予め噴
霧乾燥し、この噴霧乾燥品とノニオン界面活性あるいは
さらに他の洗剤成分とを捏和、混合、解砕して高嵩密度
粒状洗剤を製造することもできる。The composite material container contains a high bulk density granular detergent composition having a bulk density of 0.5 to 1.2 g/cc. Such a detergent composition can be obtained by granulating the necessary detergent components to form particles that are filled with the detergent components instead of hollow particles. As described in the above-mentioned Japanese Patent Application Laid-Open No. 60-96698, this granulation method involves kneading and mixing each detergent raw material in a kneader, crushing and granulating it with a crusher such as a cutter mill type, and Further, this crushed material is coated with water-insoluble fine powder having an average particle size of 1107z or less. Alternatively, a high bulk density granular detergent can also be produced by spray-drying detergent components in advance and kneading, mixing, and crushing the spray-dried product with nonionic surfactant or other detergent components.
本発明の洗剤組成物で用いられる洗剤成分としては、ア
ニオン界面活性剤、ノニオン界面活性剤等の界面活性剤
；洗液中の硬度成分を捕捉するキレートビルダーとして
、ゼオライト、クエン酸ソーダ、ニトリロトリ酢酸ソー
ダ（ＮＴＡ）、エチレンジアミンテトラ酸（ＥＤＴＡ）
、ポリアクリル酸塩、ポリアセタール力ルポキシレ−１
〜など；アルカリビルダーとして珪酸ソーダ、炭酸ソー
ダ、炭酸カリウム、メタ珪酸ソーダ、ホウ酸ソーダなど
；その他、プロテアーゼ、アミラーゼ、リパーゼ、セル
ラーゼ等の酵素、過炭酸ソーダ。Detergent components used in the detergent composition of the present invention include surfactants such as anionic surfactants and nonionic surfactants; Soda (NTA), ethylenediaminetetraic acid (EDTA)
, polyacrylate, polyacetal lupoxylate-1
etc.; alkaline builders such as sodium silicate, soda carbonate, potassium carbonate, sodium metasilicate, and sodium borate; other enzymes such as protease, amylase, lipase, and cellulase; and sodium percarbonate.
過炭酸ソーダなどの漂白剤、亜硫酸塩などの還元剤、蛍
光剤、香料などを必要に応じて使用することができろ。Bleach agents such as soda percarbonate, reducing agents such as sulfites, fluorescent agents, fragrances, etc. may be used as necessary.
アニオン界面活性剤の具体例としては、平均炭素数８〜
１６のアルキル八を有する直鎖アルキルベンゼンスルホ
ン酸塩、
平均炭素数１０〜２０のオレフィンスルホン酸塩、平均
炭素数１０〜２０のアルキル硫酸塩、平均炭素数１０〜
２０のアルコールに平均０．５〜８モルのエチレンオキ
サイドを付加させたアルキルエーテル硫酸塩、
などが例示される。これらアニオン界面活性剤における
塩としては、ナトリウム、カリウム、エタノールアミン
、アンモニウム塩等が使用でき、溶解性の面からはカリ
ウム塩が好ましい。Specific examples of anionic surfactants include an average carbon number of 8 to
Straight-chain alkylbenzene sulfonate having 16 alkyl atoms, olefin sulfonate having an average carbon number of 10 to 20, alkyl sulfate having an average carbon number of 10 to 20, an average carbon number of 10 to 20
An example is an alkyl ether sulfate in which an average of 0.5 to 8 moles of ethylene oxide is added to 20 alcohols. As salts for these anionic surfactants, sodium, potassium, ethanolamine, ammonium salts, etc. can be used, and potassium salts are preferred from the viewpoint of solubility.
アニオン界面活性剤は、洗剤組成物中に２０〜５０重ｆ
ｆ１％以上、好ましくは２５〜４０重量Ｘ配合すること
が好適である。The anionic surfactant may be present in the detergent composition at 20 to 50 wt.
It is suitable to incorporate f1% or more, preferably 25 to 40 weight X.
アニオン界面活性剤の中でも、平均炭素数８〜１６のア
ルキル基を有する直鎖アルキルベンゼンスルホン酸のカ
リウム塩が好ましい。このアルキルベンゼンスルホン酸
カリウムは、洗剤組成物中に１０重量２以上含まれるよ
うに配合することが望ましい。Among the anionic surfactants, potassium salts of linear alkylbenzenesulfonic acids having an alkyl group having an average of 8 to 16 carbon atoms are preferred. This potassium alkylbenzene sulfonate is desirably blended into the detergent composition in an amount of 10% by weight or more.
界面活性剤としては、以下の（ａ）成分と（ｂ）成分と
を重量比で（ａ）／（ｂ）＝２０７１〜３／１、好まし
くは１０／４〜４／１の範囲で含むことが望ましく、こ
れにより優れた洗浄力および超泡性と溶解性とが得られ
る。The surfactant should contain the following components (a) and (b) in a weight ratio of (a)/(b) = 2071 to 3/1, preferably 10/4 to 4/1. is desirable, as this provides excellent detergency, super foaming properties, and solubility.
（ａ）アルキル基の炭素数が８〜Ｉ６の直鎖アルキルベ
ンゼンスルホン酸のカリウム塩を洗剤組成物に対し少な
くとも１０重址％以上含むアニオン界面活性剤：２０〜
５０重量％、好ましくは２５〜４０重量％。(a) Anionic surfactant containing at least 10% by weight or more of a potassium salt of a linear alkylbenzenesulfonic acid whose alkyl group has 8 to 16 carbon atoms based on the detergent composition: 20 to
50% by weight, preferably 25-40% by weight.
（ｂ）炭素数８〜１８の一級または二級アルコールにエ
チレンオキサイド（ＥＯ）を平均８〜３０モル付加させ
たＥＯ−付加型ノニオン界面活性剤、または、炭素数８
〜１８の一級または二級アルコールにエチレンオキサイ
ド（ＥＯ）を平均８〜２０モルおよびプロピレンオキサ
イド（ＰＯ）を平均３〜１５モル付加させたＥＯ−ＰＯ
付加型ノニオン界而面性剤：１〜７重量％。(b) EO-addition type nonionic surfactant with an average of 8 to 30 moles of ethylene oxide (EO) added to a primary or secondary alcohol with 8 to 18 carbon atoms, or an EO-added nonionic surfactant with 8 to 18 carbon atoms
EO-PO obtained by adding an average of 8 to 20 moles of ethylene oxide (EO) and an average of 3 to 15 moles of propylene oxide (PO) to a primary or secondary alcohol of ~18
Additive nonionic surfactant: 1 to 7% by weight.
また、α−オレフィンスルホン酸塩は、高嵩密度粒状洗
剤組成物の保存安定性を向上し、保存時にブロッキング
が生じることを防止する働きをもっている。この効果を
十分に発揮せしめるためには、洗剤組成物中にα−オレ
フィンスルホン酸塩が少なくとも５重量％含まれるよう
に配合することが好ましい。Further, the α-olefin sulfonate has the function of improving the storage stability of the high bulk density granular detergent composition and preventing blocking from occurring during storage. In order to fully exhibit this effect, it is preferable that the detergent composition contains at least 5% by weight of α-olefin sulfonate.
ツ緋
本発明によれば、特定構造のプラスチック材料と紙材料
との複合容器に嵩密度０．５〜１．２ｇ／ｃｃの高嵩密
度粒状洗剤組成物を収納することにより、長期保存にお
ける粒状洗剤組成物の浸み出しを有効に防止することが
できる。According to the present invention, by storing a high bulk density granular detergent composition having a bulk density of 0.5 to 1.2 g/cc in a composite container made of a plastic material and paper material having a specific structure, the granular detergent composition can be stored for a long period of time. Leaching of the detergent composition can be effectively prevented.
さらに、側壁コーナ一部に曲率をもたせれば、粒状洗剤
組成物の圧密固化も有効に防止でき。Furthermore, if a portion of the side wall corner is provided with curvature, compaction and solidification of the granular detergent composition can be effectively prevented.
しかも上記複合容器とすることにより、適切なコーナ一
部を容器に形成することができる。Moreover, by forming the above-mentioned composite container, an appropriate corner part can be formed in the container.
実施例１
後記表−１に示した組成がらノニオン界面活性剤を除い
た各成分を用いて固型分４５％の洗剤スラリーを調製し
た。この洗剤スラリーを、向流式噴霧乾燥塔を用い、熱
風温度３８０℃で、水分５％となるように乾燥して、噴
霧乾燥品を得た。Example 1 A detergent slurry with a solid content of 45% was prepared using each component shown in Table 1 below except for the nonionic surfactant. This detergent slurry was dried using a countercurrent spray drying tower at a hot air temperature of 380° C. to a moisture content of 5% to obtain a spray-dried product.
この噴霧乾燥品は、平均粒径３５０μｍ、嵩密度０．３
５ｇ／ｃｃ、安息角４５度と流動性も良好であった。This spray-dried product has an average particle size of 350 μm and a bulk density of 0.3.
The fluidity was also good, with an angle of repose of 5 g/cc and 45 degrees.
ついで、上記乾燥品、ノニオン界面活性剤および水を、
連続ニーダ（栗本鉄工所製、ＫＲＣニーダ１２型）に導
入し、緻密で均一な捏和物を得た。Next, the above dried product, nonionic surfactant and water were added,
The mixture was introduced into a continuous kneader (manufactured by Kurimoto Iron Works, KRC Kneader Model 12) to obtain a dense and uniform kneaded product.
このニーダの排出口に５＋ｎｍφの穴径を８０個有した
多孔板（厚さ１０ｍ）を設置し、捏和物を約５薗φＸ
１０ｍｎの円筒状ペレットとした。A perforated plate (10 m thick) with 80 holes with a diameter of 5 + nmφ was installed at the outlet of this kneader, and the kneaded material was
It was made into a cylindrical pellet of 10 mm.
このペレットを２倍量（重量比）の１５℃の冷却空気と
ともに粉砕機（スピードミルＮＤ−１０型、岡田精工曲
）へと導入した。この時、同時に粉砕助剤として１１均
−成粒径１μのゼオライト（水分１５））を、ペレット
１００重量部に対して４重量部添加した。This pellet was introduced into a pulverizer (Speed Mill ND-10 model, Okada Seiko Gaku) together with twice the amount (weight ratio) of 15° C. cooling air. At this time, 4 parts by weight of 11 zeolite (moisture 15) having a uniform particle diameter of 1 micron (water content: 15) was added as a grinding aid to 100 parts by weight of the pellets.
粉砕機は長さ１５Ｃ！１１のカッターをクロス４段で有
しており、３０００ｒｐｍで回転し、スクリーンは３６
０度パンチングメタルがらなっている。この粉砕機を連
続で３段接続し、各段スクリーンの穴径を１段目； ３
．５ｍｍφ、２段目；２ｍφ、３段目；］、、５５ｍｍ
とした。粉砕機を３段通過した粒子を冷却空気から分離
し、後記表−】に示した根組成を有し、平均粒径ｓｏｏ
μｍ、嵩密度０．８ｇ／ｃｃの高嵩密度粒状洗剤組成物
を得た。The length of the crusher is 15C! It has 11 cutters in 4 stages, rotates at 3000 rpm, and has a screen of 36
It is made of 0 degree punched metal. Three stages of this crusher are connected in succession, and the hole diameter of each stage screen is set to the first stage;
．． 5mmφ, 2nd stage; 2mφ, 3rd stage; ], 55mm
And so. The particles that have passed through the three stages of the crusher are separated from the cooling air and have the root composition shown in the table below, and the average particle size is soo
A high bulk density granular detergent composition with a bulk density of 0.8 g/cc was obtained.
上記の方法で調製した高嵩密度洗剤組成物１．５ｋｇを
後記の各容器に収納し、これを３５℃−８５％ＲＨの条
件下で１ケ月間放置したのち取り出し、底部の浸み出し
度合いを、次の基準により目視判定し、その結果を表−
２に示した。1.5 kg of the high bulk density detergent composition prepared by the above method was stored in each container described below, and after being left for one month under the conditions of 35°C and 85% RH, it was taken out and the degree of seepage at the bottom was measured. is visually judged according to the following criteria, and the results are shown in the table.
Shown in 2.
○：浸み出しが認められない。○: No oozing is observed.
△：浸み出しがわずかに認められる。Δ: Slight seepage is observed.
×：浸み出しが認められた。×: Seepage was observed.
（以下余白）
表−１：嵩密度洗剤の組成
直鎖Ｃ工。〜１４アルキルベンゼン
スルホン酸ナトリウム ８
直ｇｔ ｃ 、、、〜、４アルキルベンゼンスルホン酸
カリウム １３
牛脂脂肪酸すトリウム ２
Ｃ１□〜０，１級アルコールのＩＥＯβ＝１５付加物
５Ａ級ゼオライト
２゜炭酸ナトリウム
】０炭酸カリウム
１゜珪酸ナトリウム
５亜硫酸ナトリウム
２水分
１゜芒硝・微量成分
バランス※１）使用容器Ａ：第１図に示し
た本発明の容器使用容器Ｂ：底部も紙で形成した以外は
第１図に示した同様の容器
使用容器Ｃ：市販の加工紙製箱型小サイズカートン（２
２印ｘ １５．５ ｘ ５．５）
参考例１
実施例１で調製した高嵩密度粒状洗剤組成物を表−２中
の各使用容器に３． 、５ ｋｇ収納し、これを３５°
Ｃ−８ＳＲＨの条件下に１ケ月放置して取り出した。こ
の容器の」二部を開き、４メツシユの篩上に注意深く移
し、篩を穏やかに振動したのち、篩上の重量と総重量と
を求め、下記の式から固化率を算出し、表−３に示した
。(Left below) Table 1: Composition of bulk density detergent Linear C process. 〜14 Sodium alkylbenzene sulfonate 8 Direct gt c , 〜, Potassium 4 alkylbenzene sulfonate 13 Sodium tallow fatty acid 2
C1□~IEOβ=15 adduct of 0, primary alcohol
5A class zeolite
2゜Sodium carbonate
】0 potassium carbonate
1゜Sodium silicate
5 Sodium sulfite
2 water
1゜mirabilite/trace ingredients
Balance *1) Container A: Container of the present invention shown in Figure 1 Container B: Same container as shown in Figure 1 except that the bottom was also made of paper Container C: Commercially available box type made of processed paper Small carton (2
2 marks x 15.5 x 5.5) Reference Example 1 The high bulk density granular detergent composition prepared in Example 1 was placed in each container shown in Table-2. , 5 kg, and hold it at 35°
It was left under C-8SRH conditions for one month and then taken out. Open the second part of this container, carefully transfer it onto a 4-mesh sieve, and after gently vibrating the sieve, calculate the weight on the sieve and the total weight, calculate the solidification rate from the following formula, and Table 3 It was shown to.
第１図は、本発明で用いられる複合材料容器の容器本体
について示す分解斜視図である。
第２図は、第１図の線Ａ−Ａ方向に沿った断面図である
（但し、蓋体を取付けた状態で示しである。）。
第３図は、容器本体の上方から見た横断面図である。
１１・・・容器本体 １３・・・プラスチック成型体１
５・・・底板 １７・・・側壁下部１９・・・
立設片 ２１・・・リブ２３・・・側壁上部
２５・・・係止突起２７・・嵌合用突起 ２９・・
・コーナ一部３１・・・紙シート状体 ３３・・・蓋体
第１図
Ｊ
第３図FIG. 1 is an exploded perspective view showing a container body of a composite material container used in the present invention. FIG. 2 is a sectional view taken along the line A-A in FIG. 1 (however, the lid is shown with the lid attached). FIG. 3 is a cross-sectional view seen from above the container body. 11... Container body 13... Plastic molded body 1
5... Bottom plate 17... Lower side wall 19...
Standing piece 21...Rib 23...Top of side wall
25... Locking protrusion 27... Fitting protrusion 29...
・Corner part 31... Paper sheet-like body 33... Lid body Fig. 1 J Fig. 3
Claims (1)
れる少なくとも２つの立設片部が一体成形されたプラス
チック成形体と、該側壁下部と立設片部との外周面に結
合されて容器側壁部の大半を構成する紙シート体とから
一体的に形成された複合材料容器に、嵩密度 ０．５〜１．２ｇ／ｃｃの粒状洗剤を収納したことを特
徴とする容器入り高嵩密度粒状洗剤。[Claims] 1. A plastic molded body in which a bottom plate, a lower part of a side wall, and at least two upright pieces extending upward from the lower part of the side wall are integrally molded; A granular detergent having a bulk density of 0.5 to 1.2 g/cc is housed in a composite material container that is integrally formed with a paper sheet that is bonded to the outer peripheral surface and forms most of the side wall of the container. High bulk density granular detergent in a container.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62319629A JP2542521B2 (en) | 1987-12-17 | 1987-12-17 | High bulk density granular detergent in a container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62319629A JP2542521B2 (en) | 1987-12-17 | 1987-12-17 | High bulk density granular detergent in a container |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01161100A true JPH01161100A (en) | 1989-06-23 |
| JP2542521B2 JP2542521B2 (en) | 1996-10-09 |
Family
ID=18112421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62319629A Expired - Fee Related JP2542521B2 (en) | 1987-12-17 | 1987-12-17 | High bulk density granular detergent in a container |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2542521B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0555514A3 (en) * | 1992-02-14 | 1994-10-19 | Ecosan Hygiene Gmbh | Re-usable receptacle containing washing, cleaning, desinfecting and/or preserving agents |
| CN100455434C (en) * | 2004-09-30 | 2009-01-28 | 冷鹭浩 | Plastic clad plate and its production method |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5386233U (en) * | 1976-12-17 | 1978-07-15 | ||
| JPS5530450A (en) * | 1978-08-25 | 1980-03-04 | Nikka Chemical Ind Co Ltd | Fastness enhancing agent of dyed article |
| JPS5930538A (en) * | 1982-08-12 | 1984-02-18 | Fc Seisakusho:Kk | Developing machine of disc film for photography |
| JPS59133419U (en) * | 1983-02-28 | 1984-09-06 | 本州製紙株式会社 | Sealed composite container |
| JPS6015807U (en) * | 1983-07-09 | 1985-02-02 | 大日本印刷株式会社 | composite molded container |
| JPS6142598A (en) * | 1984-08-06 | 1986-03-01 | 花王株式会社 | High density powder detergent |
| JPS6157699A (en) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | Super-concentrated particulate detergent product in weighingdevice built-in container |
| JPS6157700A (en) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | Unit pack detergent product using water-soluble film |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6015807B2 (en) * | 1980-04-17 | 1985-04-22 | 日産自動車株式会社 | engine mounting device |
-
1987
- 1987-12-17 JP JP62319629A patent/JP2542521B2/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5386233U (en) * | 1976-12-17 | 1978-07-15 | ||
| JPS5530450A (en) * | 1978-08-25 | 1980-03-04 | Nikka Chemical Ind Co Ltd | Fastness enhancing agent of dyed article |
| JPS5930538A (en) * | 1982-08-12 | 1984-02-18 | Fc Seisakusho:Kk | Developing machine of disc film for photography |
| JPS59133419U (en) * | 1983-02-28 | 1984-09-06 | 本州製紙株式会社 | Sealed composite container |
| JPS6015807U (en) * | 1983-07-09 | 1985-02-02 | 大日本印刷株式会社 | composite molded container |
| JPS6142598A (en) * | 1984-08-06 | 1986-03-01 | 花王株式会社 | High density powder detergent |
| JPS6157699A (en) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | Super-concentrated particulate detergent product in weighingdevice built-in container |
| JPS6157700A (en) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | Unit pack detergent product using water-soluble film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0555514A3 (en) * | 1992-02-14 | 1994-10-19 | Ecosan Hygiene Gmbh | Re-usable receptacle containing washing, cleaning, desinfecting and/or preserving agents |
| US5474184A (en) * | 1992-02-14 | 1995-12-12 | Ecosan Hygiene Gmbh. | Process for producing detergent and the like in reusable and recyclable receptacles, recyclable and reusable receptacles and apparatus for use of filled receptacles |
| CN100455434C (en) * | 2004-09-30 | 2009-01-28 | 冷鹭浩 | Plastic clad plate and its production method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2542521B2 (en) | 1996-10-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |