JPH01153791A - Putrefaction inhibitor for water-soluble cutting oil - Google Patents
Putrefaction inhibitor for water-soluble cutting oilInfo
- Publication number
- JPH01153791A JPH01153791A JP31205187A JP31205187A JPH01153791A JP H01153791 A JPH01153791 A JP H01153791A JP 31205187 A JP31205187 A JP 31205187A JP 31205187 A JP31205187 A JP 31205187A JP H01153791 A JPH01153791 A JP H01153791A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- water
- inhibitor
- soluble cutting
- organic peracid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003112 inhibitor Substances 0.000 title claims abstract 5
- 239000010730 cutting oil Substances 0.000 title abstract 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 12
- 239000002173 cutting fluid Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 8
- GLVYLTSKTCWWJR-UHFFFAOYSA-N 2-carbonoperoxoylbenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1C(O)=O GLVYLTSKTCWWJR-UHFFFAOYSA-N 0.000 abstract description 2
- LJGHYPLBDBRCRZ-UHFFFAOYSA-N 3-(3-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC(S(=O)(=O)C=2C=C(N)C=CC=2)=C1 LJGHYPLBDBRCRZ-UHFFFAOYSA-N 0.000 abstract description 2
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 abstract description 2
- NHQDETIJWKXCTC-UHFFFAOYSA-N 3-chloroperbenzoic acid Chemical compound OOC(=O)C1=CC=CC(Cl)=C1 NHQDETIJWKXCTC-UHFFFAOYSA-N 0.000 abstract description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 abstract description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- ZJAFQAPHWPSKRZ-UHFFFAOYSA-N 4-nitrobenzenecarboperoxoic acid Chemical compound OOC(=O)C1=CC=C([N+]([O-])=O)C=C1 ZJAFQAPHWPSKRZ-UHFFFAOYSA-N 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 13
- 235000019645 odor Nutrition 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 2
- OYWRDHBGMCXGFY-UHFFFAOYSA-N 1,2,3-triazinane Chemical compound C1CNNNC1 OYWRDHBGMCXGFY-UHFFFAOYSA-N 0.000 description 1
- RULKYXXCCZZKDZ-UHFFFAOYSA-N 2,3,4,5-tetrachlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C(Cl)=C1Cl RULKYXXCCZZKDZ-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 241001148470 aerobic bacillus Species 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- KVSKGMLNBAPGKH-UHFFFAOYSA-N tribromosalicylanilide Chemical compound OC1=C(Br)C=C(Br)C=C1C(=O)NC1=CC=C(Br)C=C1 KVSKGMLNBAPGKH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Auxiliary Devices For Machine Tools (AREA)
- Lubricants (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は切削、研削加工時に使用する水溶性切削油剤の
腐敗の防止剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an agent for preventing spoilage of a water-soluble cutting fluid used during cutting and grinding.
［従来の技術］
切削油剤は防火対策、作業環境の改善、省資源、油剤コ
ストの観点から不水溶性切削油剤に代り、水溶化が進め
られている。水溶性切削油剤の水溶液は、不水溶性のも
のに比較して多くの利点があるが、かび、細菌が繁殖し
、腐敗し易いため、種々の好ましくない変化を起こす。[Prior Art] Water-soluble cutting fluids are being used instead of water-insoluble cutting fluids from the viewpoints of fire prevention measures, improvement of working environment, resource saving, and cost of oil. Although an aqueous solution of a water-soluble cutting fluid has many advantages over a water-insoluble solution, it is susceptible to the growth of mold and bacteria and is prone to putrefaction, resulting in various undesirable changes.
細菌、かびの主なものは好気性菌、嫌気性菌、球菌、杆
菌、芽胞菌、酵母等種々存在している。特に、嫌気性硫
酸還元菌による硫化水素等の発生は、その悪臭のため作
業環境に悪影響を与え作業の遂行が困難となる。休日の
翌日等は液が酸素不足から嫌気性菌が増え、臭気が一層
ひどくなる。その他の細菌、かびの繁殖もあるため、腐
敗が進行して、悪臭の発する液は、更新を余儀なくされ
る。There are various types of bacteria and mold, including aerobic bacteria, anaerobic bacteria, cocci, rods, spore bacteria, and yeast. In particular, the generation of hydrogen sulfide and the like by anaerobic sulfate-reducing bacteria has an adverse effect on the working environment due to its foul odor, making it difficult to carry out work. On days such as the day after a holiday, anaerobic bacteria increase due to lack of oxygen in the liquid, making the odor even worse. Due to the growth of other bacteria and mold, decomposition progresses and the foul-smelling liquid must be replaced.
従来水溶性切削油剤の水溶液の腐敗を防止する方法とし
て、予め切削油剤に、Ｏ−フェニールフェノール、テト
ラクロロフェノール、Ｐ−クロロ−ｍ−キシレノール、
ヘキサヒドロトリアジン、トリブロモサリチルアニリド
等の薬剤を数％添加する方法があるが、これらの薬剤は
続けて使用すると、徐々に耐性菌が増えその効果が現れ
なくなること、人体に対し毒性作用があること等、必ず
しも満足の行くものではない。Conventionally, as a method of preventing spoilage of an aqueous solution of a water-soluble cutting fluid, O-phenylphenol, tetrachlorophenol, P-chloro-m-xylenol, etc. are added to the cutting fluid in advance.
There is a method of adding a few percent of drugs such as hexahydrotriazine and tribromosalicylanilide, but if these drugs are used continuously, resistant bacteria will gradually increase and the effects will no longer appear, and they may have toxic effects on the human body. This is not necessarily satisfactory.
［発明が解決しようとしている問題点］本発明者は、上
記欠点のない、つまり耐性菌が出来にくく、かつ、人体
に対して無害で、尚少量の使用量で効果のある水溶性切
削油剤の腐敗防止剤を開発すべく研究を重ねた結果、本
発明を完成した。[Problems to be Solved by the Invention] The present inventor has developed a water-soluble cutting fluid that does not have the above-mentioned drawbacks, that is, does not cause the formation of resistant bacteria, is harmless to the human body, and is effective even when used in small amounts. As a result of repeated research to develop an anti-septic agent, the present invention was completed.
［問題を解決するための手段］
即ち、本発明は、有機過酸を主成分とする水溶性切削油
剤の腐敗防止に関する。[Means for Solving the Problem] That is, the present invention relates to preventing spoilage of a water-soluble cutting fluid containing an organic peracid as a main component.
本発明に用いられる有機過酸は、過蟻酸、過酢酸、過プ
ロピオン酸、過イソ酪酸、過ピバリン酸、過２エチルヘ
キサン酸、過ネオデカン酸、過安息香酸、ｍ−クロロ過
安息香酸、ｐ−ニトロ過安息香酸、過フタール酸、及び
その金属塩、若しくはそのメチル、エチル、プロピル、
イソプロピル、ブチルのエステルがある。水溶性切削油
剤の水溶液の腐敗の原因は、水溶性切削油剤の水溶液が
細菌、かびの栄養源となる炭水化物、ミネラル、蛋白を
含み、液温も細菌、かびの繁殖に適する温度となってい
るためである。The organic peracids used in the present invention include performic acid, peracetic acid, perpropionic acid, perisobutyric acid, perpivalic acid, perethylhexanoic acid, perneodecanoic acid, perbenzoic acid, m-chloroperbenzoic acid, p- - nitrobenzoic acid, perphthalic acid, and metal salts thereof, or methyl, ethyl, propyl,
There are isopropyl and butyl esters. The reason for the spoilage of aqueous solutions of water-soluble cutting fluids is that they contain carbohydrates, minerals, and proteins that are food sources for bacteria and mold, and the liquid temperature is suitable for the growth of bacteria and mold. It's for a reason.
有機過酸の殺菌力は、極めて強力でその殺菌力は細菌、
かびは云うに及ばずビールス、藻類の広範囲に亙ってい
るが、この極めて強力な殺菌力を利用し、水溶性切削油
剤の水溶液に極く少量の有機過酸を添加することによっ
て、細菌、かびの繁殖を抑制し、悪臭の発生を防止する
ことが出来るものである。水溶性切削油剤は通常１０〜
１００倍に水で希釈し、水溶液として使用する。The bactericidal power of organic peracid is extremely strong, and its bactericidal power is effective against bacteria,
Not only mold, but also viruses and algae are widespread, but by utilizing this extremely strong sterilizing power and adding a very small amount of organic peracid to an aqueous solution of water-soluble cutting fluid, bacteria, It can suppress the growth of mold and prevent the occurrence of bad odors. Water-soluble cutting fluids are usually 10~
Dilute 100 times with water and use as an aqueous solution.
添加量は水溶性切削油剤の水溶液に対して２０ｐｐｍ以
上で細菌、かびの繁殖を抑制することが出来た。しかし
１１０００ｐｐを超えて添加することは勿論腐敗防止作
用はあるが逆に水溶液は有機過酸酸臭のため作業環境に
好ましくない影響与え実用に適しない。添加量は２０〜
１１０００ｐｐ、好ましくは１００ ｐ ｐｍ 〜２０
０ ｐ ｐｍである。実用上は、作業環境、液温による
が、月に１回程度、液量に対し１１００ｐｐ程度の有機
過酸を周期的に添加することにより、細菌、かびによる
腐敗を防止することが出来る。It was possible to suppress the growth of bacteria and mold when the amount added was 20 ppm or more relative to the aqueous solution of water-soluble cutting fluid. However, although adding more than 11,000 pp has an anti-corrosion effect, on the other hand, the aqueous solution has an organic peracid odor that adversely affects the working environment, making it unsuitable for practical use. The amount added is 20~
11000 ppm, preferably 100 ppm to 20
0 ppm. In practical terms, depending on the working environment and liquid temperature, it is possible to prevent rot caused by bacteria and mold by periodically adding about 1100 pp of organic peracid to the liquid volume once a month.
［実施例コ
日本工作油（株）製社の乳化工作油Ｂ−４００を１０倍
の水で希釈した切削油剤２００ ｍ ｌを３゜Ｏｍｌの
エアクーラー付きフラスコに採り、過酢酸を含む製剤即
ち過酢酸１５％、過酸化水素１４％、酢酸２８％、残り
水の製剤を種々その量を変えて添加し、３５℃の恒温水
槽に浸漬し、一定期間毎の腐敗状況を臭気により判定し
た。結果を第１表に示す。過酢酸製剤を添加した時、お
よび腐敗臭時の細菌の繁殖状況を第２表に示す。[Example 200 ml of a cutting fluid prepared by diluting emulsified working oil B-400 manufactured by Nippon Machinery Oil Co., Ltd. with 10 times the amount of water was placed in a 3° Oml flask equipped with an air cooler, and a preparation containing peracetic acid, i.e. A preparation of 15% peracetic acid, 14% hydrogen peroxide, 28% acetic acid, and the remaining water was added in various amounts and immersed in a constant temperature water bath at 35°C, and the state of putrefaction was determined at regular intervals based on odor. The results are shown in Table 1. Table 2 shows the bacterial growth status when the peracetic acid preparation was added and when there was a putrid odor.
［発明の効果］
以上説明したように、本発明は極少量の有機過酸を水溶
性切削油剤の水溶液に添加することにより微生物を殺菌
し悪臭の原因となる腐敗を防止して作業環境釘改善する
と共に、切削油剤の水溶液の廃棄処分によるコストの増
加を防ぐことができる。又有機過酸は作用後は分解して
有機酸、水、酸素となり人体に対して安全無害の物質と
なる。[Effects of the Invention] As explained above, the present invention improves the working environment for nails by adding a very small amount of organic peracid to an aqueous solution of water-soluble cutting fluid to sterilize microorganisms and prevent rot that causes bad odors. At the same time, it is possible to prevent an increase in costs due to disposal of the aqueous cutting fluid solution. In addition, after the organic peracid acts, it decomposes into organic acid, water, and oxygen, and becomes a substance that is safe and harmless to the human body.
第１表 第２表Table 1 Table 2
Claims (1)
剤。 ２、有機過酸が過酢酸である特許請求の範囲第１項記載
の方法[Claims] 1. A corrosion inhibitor for a water-soluble cutting fluid containing an organic peracid as a main component. 2. The method according to claim 1, wherein the organic peracid is peracetic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31205187A JPH01153791A (en) | 1987-12-11 | 1987-12-11 | Putrefaction inhibitor for water-soluble cutting oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31205187A JPH01153791A (en) | 1987-12-11 | 1987-12-11 | Putrefaction inhibitor for water-soluble cutting oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01153791A true JPH01153791A (en) | 1989-06-15 |
Family
ID=18024631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31205187A Pending JPH01153791A (en) | 1987-12-11 | 1987-12-11 | Putrefaction inhibitor for water-soluble cutting oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01153791A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11322523A (en) * | 1998-03-23 | 1999-11-24 | Degussa Huels Ag | Aqueous germicidal agent including peracetic acid and performic acid and production of the same and its use |
-
1987
- 1987-12-11 JP JP31205187A patent/JPH01153791A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11322523A (en) * | 1998-03-23 | 1999-11-24 | Degussa Huels Ag | Aqueous germicidal agent including peracetic acid and performic acid and production of the same and its use |
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