JPH01119637A - Aluminum alloy material for can end - Google Patents

Aluminum alloy material for can end

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Publication number
JPH01119637A
JPH01119637A JP27357387A JP27357387A JPH01119637A JP H01119637 A JPH01119637 A JP H01119637A JP 27357387 A JP27357387 A JP 27357387A JP 27357387 A JP27357387 A JP 27357387A JP H01119637 A JPH01119637 A JP H01119637A
Authority
JP
Japan
Prior art keywords
alloy material
rare earth
earth elements
aluminum alloy
rivet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP27357387A
Other languages
Japanese (ja)
Other versions
JP2525017B2 (en
Inventor
Satoru Shoji
了 東海林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Furukawa Aluminum Co Ltd
Original Assignee
Furukawa Aluminum Co Ltd
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Filing date
Publication date
Application filed by Furukawa Aluminum Co Ltd filed Critical Furukawa Aluminum Co Ltd
Priority to JP62273573A priority Critical patent/JP2525017B2/en
Publication of JPH01119637A publication Critical patent/JPH01119637A/en
Application granted granted Critical
Publication of JP2525017B2 publication Critical patent/JP2525017B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Rigid Containers With Two Or More Constituent Elements (AREA)

Abstract

PURPOSE:To permit the improvement of rivet moldability and thinning in the title material by incorporating specific amounts of Mg and rare earth elements to Al alloy. CONSTITUTION:The compsn. of the Al alloy material for a can end is constituted of, by weight, 2-6% Mg, 0.005-1% rare earth elements and the balance Al with inevitable impurities; and if required, one or more kinds among 0.05-1% Cu, 0.05-1.5% Zn, 0.05-1.5% Mn, 0.05-0.3% Cr and 0.05-0.3% Zr are incorporated thereto. As for rare earth elements Y, La, Ce, Pr, Nd, Sm and the mixture thereamong are suitably used. The alloy having said compsn. is formed into a thin plate by a continuous casting method, etc., and is subjected to a soaking treatment, by which the crystal grains at the time of intermediate annealing are fined. In this way, the Al alloy material for a can end having excellent rivet moldability can be obtd.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はキャンエンド用アルミニウム合金材に関し、よ
り詳しくは優れたリベット成形性な有し、痩肉化に好適
なキャンエンド用アルミニウム合金材に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an aluminum alloy material for can ends, and more particularly to an aluminum alloy material for can ends that has excellent rivet formability and is suitable for thinning. .

(従来の技術) 飲料缶として広く用いられているイージーオープン缶は
キャンボディ(缶胴)とキャンエンド(缶蓋)からなり
、キャンボディはDI成形によりカップ状に加工され、
キャンエンドはスコア加工ならびにリベット成形(多段
張出し成形)してタブが取付けられた後、キャンボディ
に巻締め接合される。キャンボディ材としては深絞り性
及びしごき加工性(DI成形性)に優れたJIS300
4合金材又はティンフリースチールか用いられ、キャン
エンド材としてはコーヒー、果汁用等にはリベット成形
性の優れたJIS  5052合金材、内圧の発生する
炭酸飲料やビール用にはさらに強度の高いJIS  5
082合金材。
(Prior art) Easy-open cans, which are widely used as beverage cans, consist of a can body (can body) and a can end (can lid).The can body is processed into a cup shape by DI molding.
The can end is scored and riveted (multi-stage stretch molding) to attach tabs, and then it is seamed and joined to the cam body. As a canvas material, JIS300 has excellent deep drawability and ironing workability (DI formability).
4 alloy material or tin-free steel is used, and the can end material is JIS 5052 alloy material with excellent rivet formability for coffee, fruit juice, etc., and JIS 5052 alloy material with higher strength is used for carbonated drinks and beer that generate internal pressure. 5
082 alloy material.

JIS  5182合金材の0.3tam程度の板厚の
ものか使用されている。
JIS 5182 alloy material with a thickness of about 0.3 tam is used.

ところで近年アルミニウム缶の需要か急速に増大してい
るが、製造価格低減のため缶体の薄肉軽量化が強く望ま
れている。
Incidentally, the demand for aluminum cans has increased rapidly in recent years, and there is a strong desire for can bodies to be thinner and lighter in order to reduce manufacturing costs.

(発明が解決しようとする問題点) ′ルかしながら、上記従来合金材では薄肉化した場合、
リベット成形性が不十分となり、リベット成形割れが発
生しやすいという欠点があった。すなわち、リベツ成形
は通常3段階の張出し成形により最終的に直径3mm程
度のリベットを形成させた後タブを取付ける(リベット
打ちする)のであるが、この張出し成形は板厚が薄くな
ればなるほど困難になるため、上記従来材では0.25
m1程度までの薄肉化が限度であった。
(Problems to be solved by the invention) However, when the conventional alloy material mentioned above becomes thinner,
There was a drawback that rivet formability was insufficient and rivet forming cracks were likely to occur. In other words, rivet forming usually involves three stages of stretch forming to form a final rivet with a diameter of about 3 mm, and then attaching tabs (riveting), but this stretch forming becomes more difficult as the board becomes thinner. Therefore, the above conventional material has a value of 0.25
The limit was to reduce the thickness to about ml.

したがって、本発明はリベット成形性に優れ、厚さ0.
20m+s程度までの薄肉化が可能なキャンエンド用ア
ルミニウム合金材を提供することを目的とする。
Therefore, the present invention has excellent rivet formability and has a thickness of 0.
The purpose of the present invention is to provide an aluminum alloy material for can ends that can be made thin up to about 20 m+s.

(問題点を解決するための手段) 本発明者は上記の問題点を解決するため鋭意研究を重ね
た結果、所定量のMg及び希土類元素を含有させたアル
ミニウム合金により上記目的が達成されること及びさら
にこのアルミニウム合金に機械的強度を向上させる金属
元素を添加するとより好ましい合金材が得られることを
見出した0本発明はこの知見に基づいてなされるに至っ
たものである。
(Means for Solving the Problems) As a result of extensive research in order to solve the above problems, the inventors of the present invention have found that the above objects can be achieved by using an aluminum alloy containing a predetermined amount of Mg and rare earth elements. Furthermore, it has been discovered that a more preferable alloy material can be obtained by adding a metal element that improves mechanical strength to this aluminum alloy. The present invention has been made based on this knowledge.

すなわち本発明は、(1)Mg2〜6重量%(以下重量
%を単に%と記す。)、希土類元素0.005〜1%を
含有し、残部がAlと不可避不純物からなることを特徴
とするキャンエンド用アルミニウム合金材、及び(2)
Mg 2〜6%、希土類元素0.005〜1%を含有し
、さらにCu0.05〜1%、 Zn 0.05〜1.
s%、 Mn 0.05〜0.5%、Cr  0.05
〜0.3%、Z r 0.05〜0.3%(以上重量%
)のうち1種以上を含有することを特徴とするキャンエ
ンド用アルミニウム合金材を提供するものである。
That is, the present invention is characterized in that (1) it contains 2 to 6% by weight of Mg (hereinafter, % by weight is simply referred to as %), 0.005 to 1% of rare earth elements, and the balance consists of Al and unavoidable impurities. Aluminum alloy material for can end, and (2)
Contains 2 to 6% Mg, 0.005 to 1% of rare earth elements, and further contains 0.05 to 1% of Cu, and 0.05 to 1% of Zn.
s%, Mn 0.05-0.5%, Cr 0.05
~0.3%, Zr 0.05~0.3% (more than weight%
) An aluminum alloy material for can ends is provided, which is characterized by containing one or more of the following.

本発明においてキャンエンド用アルミニウム合金材の含
有成分及びその成分含有量を限定した理由は次の通りで
ある。
The reasons for limiting the components and the component contents of the aluminum alloy material for can ends in the present invention are as follows.

Mgの含有量は2〜6%とする。Mgはアルミニウム合
金材に強度を付与する重要な元素である。Mg含有量が
2%未満では強度向上が不十分であり、Mgを6%を越
えて含有させると圧延性が悪くなるとともに成形性も劣
化する。
The content of Mg is 2 to 6%. Mg is an important element that provides strength to aluminum alloy materials. If the Mg content is less than 2%, strength improvement is insufficient, and if the Mg content exceeds 6%, rollability and formability deteriorate.

希土類元素の含有量は0.005〜1%とする。希土類
元素は、その種類が特に限定されるものではないが、具
体的には例えばY、La。
The content of rare earth elements is 0.005 to 1%. The rare earth elements are not particularly limited in type, but specific examples include Y and La.

Ce、Pr、Nd、Sm及びその混合物を好適に使用す
ることができる。希土類元素はリベット成形性を向上す
る作用を有する。すなわち、希土類元素はごく微量添加
するだけでも張出し成形時におけるリベット部分の加工
硬化量を減少させ、しかも板厚分布を均一にするので、
加工硬化や局所的な板厚減少(ネッキング)によるタブ
取付は時の割れの発生を防止する。希土類元素の含有量
の総量が0.005%未満ではその効果が少なく、1%
を越えて含有されると粗大な金属間化合物を形成し、リ
ベット成形性が逆に劣化する。希土類元素の好ましい含
有量範囲は、コスト面も考慮した場合、0.05〜0.
5%程度である。
Ce, Pr, Nd, Sm and mixtures thereof can be suitably used. Rare earth elements have the effect of improving rivet formability. In other words, adding even a very small amount of rare earth elements can reduce the amount of work hardening of the rivet part during stretch forming, and also make the plate thickness distribution uniform.
Tab attachment through work hardening or local thickness reduction (necking) prevents cracking over time. If the total content of rare earth elements is less than 0.005%, the effect will be small;
If the content exceeds this amount, a coarse intermetallic compound will be formed and the rivet formability will deteriorate. The preferable content range of rare earth elements is 0.05 to 0.05, considering cost.
It is about 5%.

上記のMg及び希土類元素を含有することにより、リベ
ット成形性は大いに向上するか、機械的強度等をさらに
改善するためには以下の元素をさらに添加するのか有効
である。
By containing the above Mg and rare earth elements, the rivet formability is greatly improved, or in order to further improve mechanical strength etc., it is effective to further add the following elements.

Cuの含有量は0.05〜1%とするaCuは強度を付
与する元素である。Cu含有量が0.05%未満ではそ
の効果が少なく、1%を越えると成形性及び耐食性が劣
化する。
The content of Cu is 0.05 to 1%.Cu is an element that imparts strength. If the Cu content is less than 0.05%, the effect will be small, and if it exceeds 1%, the moldability and corrosion resistance will deteriorate.

Mnの含有量は0.OS〜0.5%とする。The content of Mn is 0. OS ~ 0.5%.

Mnは強度を付与し、集合組織(耳)の安定化に寄与す
る。Mn含有量か0.05%未満では効果が不十分であ
り、0.5%を越えると成形性か劣化する。
Mn provides strength and contributes to stabilizing the texture (ear). If the Mn content is less than 0.05%, the effect is insufficient, and if it exceeds 0.5%, the moldability deteriorates.

Cr及びZrの含有量はともに0.05〜0.3%とす
る。Cr及びZrは結晶粒を微細化し、成形性を向上さ
せる。Cr及びZrの含有量かそれぞれ0.05%未満
では効果か不十分であり、それぞれ0.3%を越えると
成形性が劣化する。
The contents of Cr and Zr are both 0.05 to 0.3%. Cr and Zr refine crystal grains and improve formability. If the content of Cr and Zr is less than 0.05% each, the effect is insufficient, and if the content exceeds 0.3% each, the moldability deteriorates.

本発明のアルミニウム合金材において、上記の組成の他
に含有される不純物としてのFe、Siは、それぞれ0
.5%未満であれば特に問題がないが、リベット成形性
の改善のためには0.2%未満にする方が好ましい、ま
た、鋳塊組織の微細化剤として通常添加されるTi、B
は各々0.05%未満、0.01%未満の範囲内で添加
するのが好ましい。
In the aluminum alloy material of the present invention, Fe and Si as impurities contained in addition to the above composition are each 0.
.. There is no particular problem if it is less than 5%, but it is preferably less than 0.2% in order to improve rivet formability.
are preferably added within a range of less than 0.05% and less than 0.01%, respectively.

次に本発明のキャンエンド用アルミニウム合金材の製造
方法について説明する。
Next, a method of manufacturing an aluminum alloy material for can ends according to the present invention will be explained.

まず前述のような成分を含有するアルミニウム合金溶湯
な常法に従って鋳造する。この鋳造法としては半連続鋳
造法が一般的であるが、省エネルギーや機械的性質の向
上等から薄板連続鋳造を行ってもよい、得られた鋳塊は
均熱処理(均質化処理)を行う、この均熱処理条件は、
中間焼鈍時の結晶粒を微細化させるために−、均熱温度
を450〜600℃、均熱保持時間を48時間以内とす
ることが好ましい、均熱温度が450℃未満では中間焼
鈍の結晶粒微細化が困難であり、電気化学的粗面化を均
一、かつ微細に行うことが困難となる。また、均熱温度
が600℃を越えたり、均熱保持時間か48時間を越え
る条件ては、これら効果が飽和してしまい。エネルギー
コストの増大を招くだけである。
First, a molten aluminum alloy containing the above-mentioned components is cast according to a conventional method. Semi-continuous casting is generally used as this casting method, but continuous thin plate casting may also be used to save energy and improve mechanical properties.The obtained ingot is subjected to soaking treatment (homogenization treatment). This soaking treatment condition is as follows:
In order to refine the crystal grains during intermediate annealing, it is preferable to set the soaking temperature to 450 to 600°C and the soaking time to within 48 hours.If the soaking temperature is less than 450°C, the crystal grains of intermediate annealing will be fine. It is difficult to miniaturize the surface, and it is difficult to uniformly and finely roughen the surface electrochemically. Furthermore, if the soaking temperature exceeds 600°C or the soaking time exceeds 48 hours, these effects will be saturated. This will only lead to increased energy costs.

均熱処理後は熱間圧延を行うが、この熱間圧延に関して
は特に厳密に管理する必要はなく、常法に従って400
〜550℃で加熱して熱間圧延を行えばよい。
After the soaking treatment, hot rolling is performed, but there is no need to strictly control this hot rolling.
Hot rolling may be performed by heating at ~550°C.

熱間圧延終了後は、1次冷間圧延を施した後、中間焼鈍
を施し、さらに最終冷間圧延を行うのが通常であるが、
場合によっては中間焼鈍を2回以上挟んで冷間圧延を行
ってもよい。
After completion of hot rolling, it is usual to perform first cold rolling, then intermediate annealing, and then final cold rolling.
In some cases, cold rolling may be performed with intermediate annealing performed two or more times.

この中間焼鈍における焼鈍温度は300〜600°Cが
適当である。300℃未満では完全に再結晶せず、60
0℃を越えると表面の酸化が激しくなり表面の色が変色
し、好ましくない。またこの中間焼鈍は1通常のバッチ
焼鈍(平均加熱速度20〜50℃/ h r )でも、
連続焼鈍(平均加熱速度数℃〜数十℃/sec )でも
よいが、ベーキング後強度をさらに向上させ、しかも最
終冷間圧延以前の平均再結晶粒径を微細、均一にするた
めには、バッチ焼鈍よりも連続焼鈍を適用することが好
ましい、なお連続焼鈍の場合は中間焼鈍温度を480℃
以上にすることがCuなとの固溶促進の点でさらに望ま
しい。
The appropriate annealing temperature in this intermediate annealing is 300 to 600°C. At temperatures below 300°C, complete recrystallization does not occur;
If the temperature exceeds 0°C, oxidation of the surface becomes intense and the color of the surface changes, which is not preferable. In addition, this intermediate annealing is performed even in one normal batch annealing (average heating rate 20 to 50°C/hr).
Continuous annealing (average heating rate of several degrees Celsius to several tens of degrees Celsius/sec) may be used, but in order to further improve the strength after baking and to make the average recrystallized grain size fine and uniform before final cold rolling, batch annealing is recommended. It is preferable to apply continuous annealing rather than annealing. In the case of continuous annealing, the intermediate annealing temperature should be 480°C.
It is more desirable to do the above from the viewpoint of promoting solid solution with Cu.

続く最終冷間圧延は薄肉キャンエンド材として必要な強
度を得るために、中間焼鈍を施した後に行うが、その圧
延率は30〜90%の範囲でよい、また最終冷間圧延を
終了した後に、所望の強度、延性を得るための調質焼鈍
(200〜300℃、1〜10時間、H2n処理)1強
度の経時変化を防止するための安定化焼鈍(ioo”c
〜200℃、1〜10時間、H3n)を施してもよい。
The subsequent final cold rolling is performed after intermediate annealing in order to obtain the strength required as a thin can end material, but the rolling rate may be in the range of 30 to 90%. , temper annealing to obtain the desired strength and ductility (200 to 300°C, 1 to 10 hours, H2n treatment), stabilization annealing to prevent changes in strength over time (ioo"c),
H3n) may be applied at ~200°C for 1 to 10 hours.

このようにして得られた本発明のアルミニウム合金材は
脱脂等の処理をうけたのち、200”C程度の温度で数
分間の塗装、焼付け(ベーキング)してからキャンエン
ドとして成形、加工される。
The aluminum alloy material of the present invention thus obtained is subjected to treatments such as degreasing, then painted and baked at a temperature of about 200"C for several minutes, and then formed and processed as a can end. .

(実施例) 次に本発明を実施例に基づきさらに詳細に説明する。(Example) Next, the present invention will be explained in more detail based on examples.

実施例 第1表に示す組成を有するアルミニウム合金(No、1
〜No、10)を溶解し、半連続鋳造法により厚さ50
0璽−の鋳塊とした。これを面削した後500℃、5時
間の均熱処理後、厚さ3■まで熱間圧延した。続いて冷
間圧延した後、連続焼鈍炉により520℃、10秒間の
中間焼鈍を施してから最終冷間圧延により、それぞれ0
.30゜0.28.0.26.0.24.0.22.0
.20mmの6種の板厚の板に仕上げた。このとき最終
冷間圧延率がいずれも60%となるように前述の条件の
中間焼鈍を施す位置を設定した。
Example Aluminum alloy (No. 1) having the composition shown in Table 1
~ No. 10) is melted and cast to a thickness of 50 mm using a semi-continuous casting method.
It was made into an ingot of 0. This was face-milled, soaked at 500°C for 5 hours, and then hot-rolled to a thickness of 3cm. Subsequently, after cold rolling, intermediate annealing was performed at 520°C for 10 seconds in a continuous annealing furnace, and final cold rolling was performed to achieve a temperature of 0.
.. 30°0.28.0.26.0.24.0.22.0
.. Finished in six different thicknesses of 20 mm. At this time, the positions where intermediate annealing was performed under the above-mentioned conditions were set so that the final cold rolling reduction was 60% in each case.

得られたそれぞれの最終冷間圧延板を脱脂後、200℃
、20分間のベーキングを施してから外径60■膳のキ
ャンエンドに成形し、リベット成形性を評価した。リベ
ット成形は3段階張出し加工により外径31のリベット
を成形した後、タブを接合し、このときのリベット割れ
発生の有無を観察した。この試験におけるリベット割れ
発生状況の評価は各1000缶成形したうち、割れの発
生が皆無であったものを○(リベット成形性良好)、1
〜5缶の割れが発生したものを△(やや良)、6缶以上
の割れが発生したものを×(不阜)て示した。結果を第
2表に示す。
After degreasing each final cold-rolled plate obtained, the plate was heated at 200°C.
After baking for 20 minutes, it was molded into a can end with an outer diameter of 60 mm, and the rivet formability was evaluated. After forming a rivet with an outer diameter of 31 by a three-step stretching process, the tabs were joined, and the presence or absence of rivet cracking at this time was observed. The evaluation of the occurrence of rivet cracking in this test was as follows: Out of 1000 cans molded, those with no cracks were evaluated as ○ (good rivet formability), 1
Those in which ~5 cans were cracked were rated △ (slightly good), and those in which 6 or more cans were cracked were rated × (poor). The results are shown in Table 2.

第2表の結果から明らかなように1本発明のキャンエン
ド用アルミニウム合金材(No、1〜No、5)は、い
ずれも0.20mmまで薄肉化してもリベット割れが発
生せずリベット成形性が極めて良好である。これに対し
て比較例はリベット成形性が劣り、0.24〜0.26
m+s以下の薄肉化が困難である。
As is clear from the results in Table 2, all of the aluminum alloy materials for can ends (No. 1 to No. 5) of the present invention do not cause rivet cracking even when the wall thickness is reduced to 0.20 mm, and the rivet formability is good. is extremely good. On the other hand, the comparative example had poor rivet formability, with 0.24 to 0.26
It is difficult to reduce the thickness to m+s or less.

(発明の効果) このように、本発明によればリベット成形性の優れたキ
ャンエンド用アルミニウム合金材か提供される。したが
って本発明によれば、キャンエンド材の一層の薄肉化が
可能(板厚0.20mm)てあり、アルミニウム缶の軽
量化、コストダウンに顕著な効果を奏する。
(Effects of the Invention) As described above, according to the present invention, an aluminum alloy material for can ends having excellent rivet formability is provided. Therefore, according to the present invention, it is possible to further reduce the thickness of the can end material (plate thickness: 0.20 mm), which has a significant effect on reducing the weight and cost of aluminum cans.

Claims (2)

【特許請求の範囲】[Claims] (1)Mg2〜6%、希土類元素0.005〜1%を含
有し、残部がAlと不可避不純物(以上重量%)からな
ることを特徴とするキャンエンド用アルミニウム合金材
(1) An aluminum alloy material for can ends containing 2 to 6% Mg and 0.005 to 1% of rare earth elements, with the remainder consisting of Al and unavoidable impurities (the above weight %).
(2)Mg2〜6%、希土類元素0.005〜1%を含
有し、さらにCu0.05〜1%、Zn0.05〜1.
5%、Mn0.05〜0.5%、Cr0.05〜0.3
%、Zr0.05〜0.3%(以上重量%)のうち1種
以上を含有することを特徴とするキャンエンド用アルミ
ニウム合金材。
(2) Contains 2-6% Mg, 0.005-1% rare earth elements, and further contains 0.05-1% Cu, 0.05-1% Zn.
5%, Mn0.05-0.5%, Cr0.05-0.3
%, Zr0.05 to 0.3% (by weight) or more.
JP62273573A 1987-10-30 1987-10-30 Aluminum alloy material for can ends Expired - Lifetime JP2525017B2 (en)

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JPH01119637A true JPH01119637A (en) 1989-05-11
JP2525017B2 JP2525017B2 (en) 1996-08-14

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03114389U (en) * 1990-03-08 1991-11-25
JPH05230583A (en) * 1992-02-25 1993-09-07 Mitsubishi Alum Co Ltd High strength al alloy sheet excellent in formability
JP2007023340A (en) * 2005-07-15 2007-02-01 Sumitomo Light Metal Ind Ltd Aluminum alloy sheet for positive-pressure can top, and method for producing the same
CN102828075A (en) * 2012-08-17 2012-12-19 南昌大学 Al-Cu-Sm rare earth cast aluminium alloy and preparation method thereof
CN106957977A (en) * 2017-05-24 2017-07-18 中国科学院金属研究所 A kind of nonheat-treatable Antibacterial aluminum alloy and its preparation technology
WO2023202588A1 (en) * 2022-04-19 2023-10-26 宝山钢铁股份有限公司 Aluminum alloy plate for tank and manufacturing method therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6050141A (en) * 1983-08-27 1985-03-19 Kobe Steel Ltd Hard aluminum alloy sheet for can end and its production
JPS6244549A (en) * 1985-08-22 1987-02-26 Showa Alum Corp Structural aluminum alloy having superior cold workability
JPS6254054A (en) * 1985-09-02 1987-03-09 Showa Alum Corp Aluminum alloy excellent in cold workability

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6050141A (en) * 1983-08-27 1985-03-19 Kobe Steel Ltd Hard aluminum alloy sheet for can end and its production
JPS6244549A (en) * 1985-08-22 1987-02-26 Showa Alum Corp Structural aluminum alloy having superior cold workability
JPS6254054A (en) * 1985-09-02 1987-03-09 Showa Alum Corp Aluminum alloy excellent in cold workability

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03114389U (en) * 1990-03-08 1991-11-25
JPH05230583A (en) * 1992-02-25 1993-09-07 Mitsubishi Alum Co Ltd High strength al alloy sheet excellent in formability
JP2007023340A (en) * 2005-07-15 2007-02-01 Sumitomo Light Metal Ind Ltd Aluminum alloy sheet for positive-pressure can top, and method for producing the same
CN102828075A (en) * 2012-08-17 2012-12-19 南昌大学 Al-Cu-Sm rare earth cast aluminium alloy and preparation method thereof
CN106957977A (en) * 2017-05-24 2017-07-18 中国科学院金属研究所 A kind of nonheat-treatable Antibacterial aluminum alloy and its preparation technology
WO2023202588A1 (en) * 2022-04-19 2023-10-26 宝山钢铁股份有限公司 Aluminum alloy plate for tank and manufacturing method therefor

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