JPH01110612A - Pigment dispersion liquid - Google Patents
Pigment dispersion liquidInfo
- Publication number
- JPH01110612A JPH01110612A JP26748487A JP26748487A JPH01110612A JP H01110612 A JPH01110612 A JP H01110612A JP 26748487 A JP26748487 A JP 26748487A JP 26748487 A JP26748487 A JP 26748487A JP H01110612 A JPH01110612 A JP H01110612A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- pigments
- pigment dispersion
- component
- dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 63
- 239000006185 dispersion Substances 0.000 title claims abstract description 32
- 239000007788 liquid Substances 0.000 title claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002537 cosmetic Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 8
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 7
- 238000012644 addition polymerization Methods 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- -1 aliphatic alcohols Chemical class 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003380 propellant Substances 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 239000001023 inorganic pigment Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000012860 organic pigment Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000001040 synthetic pigment Substances 0.000 description 3
- 241000195940 Bryophyta Species 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000011929 mousse Nutrition 0.000 description 2
- 229940105132 myristate Drugs 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 229940029284 trichlorofluoromethane Drugs 0.000 description 2
- 235000013799 ultramarine blue Nutrition 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- WZSFTHVIIGGDOI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3-[2-methyl-3-[(4,5,6,7-tetrachloro-3-oxoisoindol-1-yl)amino]anilino]isoindol-1-one Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C2=C1C(NC1=CC=CC(NC=3C4=C(C(=C(Cl)C(Cl)=C4Cl)Cl)C(=O)N=3)=C1C)=NC2=O WZSFTHVIIGGDOI-UHFFFAOYSA-N 0.000 description 1
- DWDURZSYQTXVIN-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-methyliminocyclohexa-2,5-dien-1-ylidene)methyl]aniline Chemical compound C1=CC(=NC)C=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 DWDURZSYQTXVIN-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- JKQQZJHNUVDHKP-FQJIPJFPSA-N Flurogestone acetate Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1CC[C@@](C(C)=O)(OC(=O)C)[C@@]1(C)C[C@@H]2O JKQQZJHNUVDHKP-FQJIPJFPSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 241000755266 Kathetostoma giganteum Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- LTGPFZWZZNUIIK-LURJTMIESA-N Lysol Chemical compound NCCCC[C@H](N)CO LTGPFZWZZNUIIK-LURJTMIESA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N Nitrogen dioxide Chemical class O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 241000123069 Ocyurus chrysurus Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001348 alkyl chlorides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- MXBMODJMSXQJMT-UHFFFAOYSA-L barium(2+);carbonic acid;sulfate Chemical compound [Ba+2].OC(O)=O.[O-]S([O-])(=O)=O MXBMODJMSXQJMT-UHFFFAOYSA-L 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 229940077445 dimethyl ether Drugs 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- XJNUECKWDBNFJV-UHFFFAOYSA-N hexadecyl 2-ethylhexanoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C(CC)CCCC XJNUECKWDBNFJV-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 229940099349 liquefied petroleum gas Drugs 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- BECVLEVEVXAFSH-UHFFFAOYSA-K manganese(3+);phosphate Chemical compound [Mn+3].[O-]P([O-])([O-])=O BECVLEVEVXAFSH-UHFFFAOYSA-K 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- PYUYQYBDJFMFTH-WMMMYUQOSA-N naphthol red Chemical compound CCOC1=CC=CC=C1NC(=O)C(C1=O)=CC2=CC=CC=C2\C1=N\NC1=CC=C(C(N)=O)C=C1 PYUYQYBDJFMFTH-WMMMYUQOSA-N 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は顔料分散液に関し、更に詳細には、毛髪化粧料
等として使用することのできる分散性の向上した顔料分
散液に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a pigment dispersion, and more particularly to a pigment dispersion with improved dispersibility that can be used as a hair cosmetic or the like.
従来から、各種の化粧料にはその商品働値を高めてその
購買意欲を向上させたシ、皮膚あるいは毛゛髪に塗布し
て化粧効果を得ることを目的として種々の色素が添加さ
れている。Conventionally, various pigments have been added to various cosmetics for the purpose of increasing the product's functional value and increasing the desire to purchase it, and for the purpose of applying it to the skin or hair to obtain a cosmetic effect. .
一般に色素は染料と顔料に分けられるが、水又は溶剤に
良く溶け、配合が容易であることから、現在は色素とし
て染料の配合が良くおこなわれている。Generally, pigments can be divided into dyes and pigments, but dyes are currently commonly used as pigments because they dissolve well in water or solvents and are easy to blend.
一方、顔料は、その着色力及び隠蔽力において染料に比
べ優れているが、水や溶剤に不靜で８シ、しかも安定に
分散せしめることが困難で汎用性に劣るという欠点があ
った。On the other hand, although pigments are superior to dyes in terms of coloring power and hiding power, they have the disadvantage that they are unstable in water and solvents, are difficult to disperse stably, and are inferior in versatility.
かかる現状において、本発明者らは顔料の分散安定性を
向上させるべく檀々研究をおこなった結果、特定のポリ
オキシアルキレン化合物を顔料と併用すれば顔料の分散
性が向上し、その安定性も良好であることを見出し、本
発明を完成した。Under these circumstances, the present inventors have conducted extensive research to improve the dispersion stability of pigments, and have found that if a specific polyoxyalkylene compound is used in combination with pigments, the dispersibility of pigments can be improved, and its stability can also be improved. The present invention was completed based on this finding.
すなわち、本発明は、次の成分（Ａ）及び（Ｒ３（Ａ）
−価または多価アルコールにアルキレンオキシドを
付加重合して得られるポリオキシアルキレン系化合物、
（Ｂ） 顔料
を含有することを特徴とする顔料分散液を提供するもの
である。That is, the present invention provides the following components (A) and (R3(A)
The present invention provides a pigment dispersion characterized by containing (B) a pigment, a polyoxyalkylene compound obtained by addition polymerizing an alkylene oxide to a -hydric or polyhydric alcohol.
本発明顔料分散液の（Ａ）成分であるポリオキシアルキ
レン系化合物としては、例えば、メタノール、エタノー
ル、ブタノール、オクタツール、ラウリルアルコール等
の脂肪族−価アルコール；プロピレングリコール、グリ
セリン、２−エチル−２−ヒドロキシメチル−１、３−
テロノＱンゾオール、マンニトール、ンルビトール等の
多価アルコールにアルキレンオキシドを付加重合して得
られる化合物が使用される。アルキレンオキシドとして
は炭素数１〜５のものが挙げられるが、例えばプロピレ
ンオキシド又はエチレンオキシドとゾロピレンオキシド
の混合物が好ましく、就中プロピレンオキシドが特に好
ましい。なおエチレンオキシドとプロピレンオキシドを
混合して用いる場合には、エチレンオキシドの付加モル
数を総付加モル数の１／３以下とし、ブロック状に付加
重合させたものが好ましい。Examples of the polyoxyalkylene compound which is component (A) of the pigment dispersion of the present invention include aliphatic alcohols such as methanol, ethanol, butanol, octatool, and lauryl alcohol; propylene glycol, glycerin, and 2-ethyl alcohol; 2-hydroxymethyl-1,3-
Compounds obtained by addition polymerizing alkylene oxide to polyhydric alcohols such as telono-Q-enzool, mannitol, and nrubitol are used. Examples of the alkylene oxide include those having 1 to 5 carbon atoms, and, for example, propylene oxide or a mixture of ethylene oxide and zolopylene oxide are preferred, with propylene oxide being particularly preferred. In addition, when using a mixture of ethylene oxide and propylene oxide, it is preferable that the number of moles of ethylene oxide added is 1/3 or less of the total number of moles added, and addition polymerization is carried out in a block form.
アルキレンオキシドの総付加モル数は２〜１００モル、
好ましくは６〜１００モル、特に好ましくは８〜５０モ
ルである。The total number of moles of alkylene oxide added is 2 to 100 moles,
Preferably it is 6 to 100 mol, particularly preferably 8 to 50 mol.
斯かるポリオキシアルキレン系化合物の特に好ましいも
のとしては次の一般式（１）〜（ＩＶ）の化合物が挙げ
られる。Particularly preferable examples of such polyoxyalkylene compounds include compounds represented by the following general formulas (1) to (IV).
ＣＨ。CH.
Ｒ，Ｏ（ＣＨ２ＣＩＯ）ｌＨ（＋）
（式中％ Ｒ１は炭素数１〜２２のアルキル基を示し、
プロピレンオキシド平均付加モル数ｔは１０〜１００で
ある）
胃■３
〔式中、プロピレンオキシド平均付加モル数（ｉ−４−
ｂ）は２〜１００である〕
ＣＨ３
〔式中、プロピレンオキシド平均付加モル数（ｅ＋ｄ十
〇）は３〜１００である〕
ＣＨｓ
〔式中、プロピレンオキシド平均付加モル数（ｆ＋ｇ＋
ｈ＋ｉ＋ｊ＋ｋ）は２〜１００である〕
（Ａ）成分の配合量は、顔料分散液の用途によっても異
なるが、一般には全組成の１〜５０重量％（以下単に「
％」で示す）とすることが好ましい。R, O(CH2CIO)lH(+) (in the formula, % R1 represents an alkyl group having 1 to 22 carbon atoms,
The average number of moles of propylene oxide added is 10 to 100) Stomach ■3 [In the formula, the average number of moles of propylene oxide added (i-4-
b) is 2 to 100] CH3 [In the formula, the average number of added moles of propylene oxide (e+d10) is 3 to 100] CHs [In the formula, the average number of added moles of propylene oxide (f+g+
h+i+j+k) is 2 to 100] The amount of component (A) to be blended varies depending on the use of the pigment dispersion, but is generally 1 to 50% by weight of the total composition (hereinafter simply "
%) is preferable.
また、本発明の（Ｂ）成分である顔料は、公知の顔料の
いずれをも用いることができる。すなわち、顔料には天
然顔料と合成顔料があり。Further, as the pigment which is the component (B) of the present invention, any known pigment can be used. In other words, there are two types of pigments: natural pigments and synthetic pigments.
天然顔料は更に鉱物顔料（クレー、重炭酸カルシウム、
古代の顔料等）及び天然染料レーキ（マダーレーキ、コ
チ二一ルレ一キ等）ニ分けられ、合成顔料は、無機顔料
及び有機顔料（レーキ顔料、不溶性色素顔料等）に分け
られるが、そのいずれをも使用することができる。この
顔料のうち、合成顔料について例示すれば次の通りであ
る。Natural pigments also include mineral pigments (clay, calcium bicarbonate,
Synthetic pigments can be divided into inorganic pigments and organic pigments (lake pigments, insoluble color pigments, etc.) and natural dye lakes (madder lake, flathead color pigment, etc.). can also be used. Among these pigments, examples of synthetic pigments are as follows.
無機顔料
酸化物 亜鉛華、二酸化チタン、べんがら、酸化クロム
、コバルトブルー、鉄
黒
水酸化物 アルミナホワイト、黄色酸化鉄硫化物、セレ
ン化物 硫化亜鉛、朱、カドミウム二ロー、カド
ミラムレラド
フェロシアン化物 紺青
クロム酸塩 黄鉛、シンククロメート、モリブデンレッ
ド
硫酸塩 沈降性硫酸バリウム
炭酸塩 沈降性炭酸カルシウム
硅酸塩 含水硅酸塩、群青
燐酸塩 マンガンバイオレット
炭 素 カーボンブラック
金属粉 アルミニウム粉、ブロンズ粉、亜鉛末
その他 雲母チタン
有機顔料
ニトロソ顔料 す７トールグリーンＢ
ニトロ顔料 ナフトールエローＳ
アゾ顔料
アゾレーキ顔料 リソールレツド、レーキレッドＣ１ブ
リリア
ントカーミン６Ｂ、 ウ
ォッチヤングレッド、
ボルドー１０Ｂ
不溶性アゾ顔料 ファストエロー、シスアゾエロー、ビ
ラゾロ
ンオレンゾ、ノ９ラレッ
ド、レーキレッド４Ｒ。Inorganic pigment oxides Zinc white, titanium dioxide, red iron, chromium oxide, cobalt blue, iron black hydroxide Alumina white, yellow iron oxide sulfide, selenide Zinc sulfide, vermilion, cadmium dilo, cadmium relado ferrocyanide, dark blue Chromates Yellow lead, synchromate, molybdenum red sulfate Precipitated barium sulfate carbonate Precipitated calcium carbonate silicate Hydrous silicate, ultramarine phosphate Manganese violet carbon Carbon black metal powder Aluminum powder, bronze powder, zinc powder Others Mica titanium organic pigments Nitroso pigments Su7 Tall Green B Nitro pigments Naphthol Yellow S Azo pigments Azo Lake pigments Lysol Red, Lake Red C1 Brilliant Carmine 6B, Watch Young Red, Bordeaux 10B Insoluble azo pigments Fast Yellow, Cisazo Yellow, Virazolone Orenzo, No 9 La Red, Lake Red 4R.
ナフトールレッド
縮合アゾ顔料 クロモフタールエロー、レッド
染付レーキ顔料
酸性染料レーキ ピーコックブルーレーキ、アルカリブ
ルーレ
ーキ
塩基性染料レーキ ローダミンレーキ、メチルバイオレ
ット
レーキ、マラカイト
グリーンレーキ
７タロシアニン顔料 フタロシアニンブルー、ファス
トスカイ
ブルー、フタロシア
ニングリーン
縮合多環顔料
スレン顔料 アントラビリミシンエロー、ペリノンオレ
ンジ、ペリレ
ンレッド、チオインゾゴレ
ラド、インダントロンブル
ーナクリドン顔料 キナクリドンレッド、キナクリドン
バイオ
レット
ジオキサジン顔料 ジオキサジンバイオレット
イソインドリノン顔料 イソインドリノンエロー
その他
染料樹脂固溶体 昼光螢光顔料
これら顔料のうち、顔料分散液を毛髪化粧料として用い
る場合により好ましいものとしては、ベンガラ、紺青、
群青、カーボンブラック等の無機顔料及びアゾ顔料、フ
タロシアニン顔料等の有機顔料が挙げられ、このうち特
にカーボンブラックと群青が好ましい。Naphthol Red Condensed Azo Pigment Chromophthal Yellow, Red Dyeing Lake Pigment Acid Dye Lake Peacock Blue Lake, Alkaline Blue Lake Basic Dye Lake Rhodamine Lake, Methyl Violet Lake, Malachite Green Lake 7 Talocyanine Pigment Phthalocyanine Blue, Fast Sky Blue, Phthalocyanine Green condensed polycyclic pigment Thren pigment Antravirimicin Yellow, Perinone Orange, Perylene Red, Thioinzogolerad, Indanthrone Blue Nacridone Pigment Quinacridone Red, Quinacridone Violet Dioxazine Pigment Dioxazine Violet Isoindolinone Pigment Isoindolinone Yellow Other dye resin solid solutions Daylight fluorescent pigments Among these pigments, those that are more preferable when the pigment dispersion is used as a hair cosmetic are red iron, dark blue,
Examples include inorganic pigments such as ultramarine and carbon black, and organic pigments such as azo pigments and phthalocyanine pigments, among which carbon black and ultramarine are particularly preferred.
（Ｂ）成分である顔料の粒径は、顕微鏡法によって００
０５〜１００μｍの範囲にあることが好ましく、特に０
．０１〜１０μｍであることが好ましい。The particle size of the pigment (B) component was determined by microscopy.
It is preferably in the range of 05 to 100 μm, especially 0
．． It is preferable that it is 01-10 micrometers.
本発明の顔料分散液中への（Ｂ）成分の配合量は、０．
００５〜１０％、特に００１〜１％とすることが好まし
い。（Ｂ）成分の配合量が０００５％未満では十分な効
果は得られず％また、１０％を超えた場合には安定に分
散せしめる仁とが困難となる。The amount of component (B) blended into the pigment dispersion of the present invention is 0.
It is preferably from 0.005% to 10%, particularly from 0.001% to 1%. If the amount of component (B) is less than 0.005%, no sufficient effect will be obtained, and if it exceeds 10%, it will be difficult to achieve stable dispersion.
本発明の顔料分散液は、ヘアリキッド、ヘアクリーム、
セットローション、ヘアスプレー、ヘアフオーム、シェ
ル等の毛髪化粧料及びアイシャドウ、マスカラ等の皮膚
化粧料等とすることができる。毛髪化粧料とする場合は
、上記必須成分（Ａ）及び（Ｂ）、必要によシ後述の任
意成分を水、低級アルコール、水−低級アルコール混合
溶媒等の溶剤に常法によって混合し、所望の剤型とすれ
ば良い。特にエアゾールとする場合には、噴射剤として
クロルアルカン系噴射剤、例えばトリクロルモノフルオ
ロメタン、ジクロルジフルオロメタン、ジクロルテトラ
フルオロエタン等のクロルフルオロアルカン噴射剤、液
化石油ガス、ジメチルエーテル又はこれらの混合物を用
いるのが好ましく、この噴射剤は充填後のエアゾール缶
の内圧が２．０ ＝ ４０ ｋｇ ／ ｔｏ” Ｇとな
るよう調整充填するのが好ましい。噴射剤は霧状エアゾ
ールとした毛髪化粧料の場合には５０〜８０％以上含有
することが好ましい。The pigment dispersion of the present invention can be used in hair liquid, hair cream,
It can be used as hair cosmetics such as setting lotions, hair sprays, hair foams and shells, and skin cosmetics such as eye shadows and mascara. When preparing a hair cosmetic, the above-mentioned essential components (A) and (B) and optional components described below are mixed in a solvent such as water, lower alcohol, water-lower alcohol mixed solvent, etc. by a conventional method, and the desired composition is prepared. It is sufficient to use the following dosage form. Particularly when preparing an aerosol, the propellant may be a chloroalkane propellant, such as a chlorofluoroalkane propellant such as trichloromonofluoromethane, dichlorodifluoromethane, or dichlorotetrafluoroethane, liquefied petroleum gas, dimethyl ether, or a mixture thereof. The propellant is preferably adjusted and filled so that the internal pressure of the aerosol can after filling is 2.0 = 40 kg/to''G. In some cases, the content is preferably 50 to 80% or more.
また、泡状エアゾールとした毛髪化粧料の場合には１０
〜３０％以下含有することが好ましい。In addition, in the case of hair cosmetics made into foamy aerosols, 10
It is preferable to contain up to 30%.
本発明の顔料分散液を毛髪化粧料とする場合には上記必
須成分の他に、本発明の効果を妨げない限度内で、ヒマ
シ油、カカオ油、ミンク油、アボガド油、オリーブ油の
如きグリセライド類：ミツロウ、鯨ロウ、ラノリン、カ
ルナウノでロウの如きロウ類：セチルアルコール、オレ
イルアルコール、ラウリルアルコール、ステアリルアル
コール、テロピレングリコール、ポリプロピレングリコ
ール、クリセリンの如きアルコール類：ミリスチン酸イ
ンプロピル、ラウリン酸ヘキシル、乳酸セチル、モノス
テアリン酸テロピレングリコール、オレイン酸オレイル
、２−エチルヘキサン酸ヘキサデシル、ミリスチン酸オ
ク伽チルドデシル等のエステル類：ゾメチルボリシロキ
サン、メチルフェニルポリシロキサン、ポリエーテル変
性シリコーンオイル、エポキシ変性シリコーンオイル、
アミン変性シリコーンオイル、アルキル変性シリコーン
オイル等のシリコーン誘導体等の化粧用油脂類を添加す
ることができる。更に乳化安定化するために乳化剤を添
加することができる。また商品価値を高めるために香料
あるいは染料を添加しても良い。When the pigment dispersion of the present invention is used as a hair cosmetic, in addition to the above-mentioned essential ingredients, glycerides such as castor oil, cacao oil, mink oil, avocado oil, and olive oil may be added to the extent that does not impede the effects of the present invention. : Waxes such as beeswax, spermaceti, lanolin, and carnauno: Alcohols such as cetyl alcohol, oleyl alcohol, lauryl alcohol, stearyl alcohol, teropylene glycol, polypropylene glycol, and chrycerin: Impropyl myristate, hexyl laurate, Esters such as cetyl lactate, telopylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, octyldododecyl myristate, etc.: zomethylborisiloxane, methylphenylpolysiloxane, polyether-modified silicone oil, epoxy-modified silicone oil,
Cosmetic fats and oils such as silicone derivatives such as amine-modified silicone oil and alkyl-modified silicone oil can be added. Furthermore, an emulsifier can be added to stabilize the emulsion. Additionally, fragrances or dyes may be added to increase the commercial value.
さらに組成物の経日的変質防止のため防腐剤あるいは酸
化防止剤を添加することができる。Furthermore, a preservative or an antioxidant may be added to prevent deterioration of the composition over time.
斜上の如く、本発明は（Ａ）成分を併用することにより
（Ｂ）成分である顔料を安定に分散することができるの
で、顔料を配合する組成物、例えば毛髪化粧料、皮膚化
粧料等において有利に利用することができるものである
。As mentioned above, in the present invention, by using component (A) in combination, the pigment as component (B) can be stably dispersed, so it can be used in compositions containing the pigment, such as hair cosmetics, skin cosmetics, etc. It can be used advantageously in
以下に実施例を挙げて本発明を更に詳しく説明する。 The present invention will be explained in more detail with reference to Examples below.
実施例１
次に示す処方の顔料分散液を調製し、その分散状態並び
に１週間及び１力月経過後の分散安定性を調べた。この
結果を第１表に示す。Example 1 A pigment dispersion having the following formulation was prepared, and its dispersion state and dispersion stability after one week and one month were examined. The results are shown in Table 1.
処方：
本発明分散液ｌ
カーボンブラック（０，０２５μｍ） ０
５部エタノール １００部
水 ４００部
上記各成分を攪拌機で混合し、顔料分散液を得た。以下
の分散液も同様に調製した。Prescription: Dispersion of the present invention l Carbon black (0,025 μm) 0
5 parts Ethanol 100 parts Water 400 parts The above components were mixed using a stirrer to obtain a pigment dispersion. The following dispersions were also prepared in the same manner.
本発明分散液２
群青（０２μｍ） ０２部エタノール
ａＯ部水
ｌａｏ部比較分散液１
カーボンブラック（ＱＯ２５μｎ１） ０．
５部ソルビタンモノラウレート５．．０部
エタノール ＩＱＯ部水
、。。部比較分散
液２
群″＊ （０，２μｍ ） ０．２部
ンルビタンモヅノＱルミテート ａｏ部エ
タノール ａＯ部水
、５、。部測定方法
：
（１） 分散状態
顕微鏡による肉眼測定。Dispersion of the present invention 2 Ultramarine blue (02 μm) 02 parts ethanol
aO part water
Lao part comparative dispersion 1 Carbon black (QO25μn1) 0.
5 parts sorbitan monolaurate 5. ．． 0 parts ethanol IQO part water
,. . Part Comparison Dispersion 2 Group''* (0.2μm) 0.2 parts Rubitan Moduno Q Lumitate ao part ethanol aO part water
,5. Measurement method: (1) Visual measurement using a dispersion microscope.
（２）分散安定性
１００ｘ／沈降管に顔料分散液を入れ、室温にて放置し
１分散質の沈降量を観察し評価した。(2) Dispersion Stability A pigment dispersion was placed in a 100x/sedimentation tube, left to stand at room temperature, and the amount of sedimentation of one dispersoid was observed and evaluated.
（評価基準）
○ 沈降なし０
× 沈降あり０
結果：
第１表
実施例２
カラームース＝
（組成）
群 青（０，３μｒｎ ） ０．１ソフタ
ノール９０ ０５（日本
触媒化学工業■製）
９０ｖ／マ幅エタノール ＩＧＯ香
料 ０２
水 バランス
計１００
（製法）
上記各成分全混合して溶液となし原液を調製する。この
原液９０重量部を耐圧型容器に分注し、液化石油ガス１
０重量部を充填してカラームースを調製した。(Evaluation criteria) ○ No sedimentation 0 × Sedimentation 0 Results: Table 1 Example 2 Color mousse = (Composition) Ultramarine blue (0.3μrn) 0.1 Softanol 90 05 (manufactured by Nippon Shokubai Chemical Co., Ltd.) 90v/ma Width Ethanol IGO fragrance 02 Water Balance meter 100 (Manufacturing method) All of the above ingredients are mixed to prepare a solution and a stock solution. Dispense 90 parts by weight of this stock solution into a pressure-resistant container, and
A color mousse was prepared by filling 0 parts by weight.
実施例３
カラースプレー二
（組成）
カーピンブラック（０，０２５μｍ） ０８ユ
力フオーマーＡＭ７５ １０．０
（三菱油化■製）
メチルフェニルポリシロキサン ０１香
料 ０２
無水エタノール バランス計１０
０
（製法）
上記各成分を混合して溶液となし、原液を調製する。こ
の原液４０重量部を耐圧型容器に分注し、ゾクロルゾフ
ルオロメタン３６重量部及びトリクロロフルオロメタン
２４重量部を充填してカラースプレーを調製した。Example 3 Color Spray 2 (Composition) Carpin Black (0,025 μm) 08 Yukiformer AM75 10.0
(Mitsubishi Yuka ■) Methylphenylpolysiloxane 01 Fragrance 02 Absolute ethanol Balance meter 10
0 (Production method) The above components are mixed to form a solution to prepare a stock solution. 40 parts by weight of this stock solution was dispensed into a pressure-resistant container and filled with 36 parts by weight of zochlorozofluoromethane and 24 parts by weight of trichlorofluoromethane to prepare a color spray.
以上that's all
Claims (1)
を付加重合して得られるポリオキシアルキレン系化合物
、 （Ｂ）顔料 を含有することを特徴とする顔料分散液。 ２、ポリオキシアルキレン系化合物の含有量が、全組成
の１〜５０重量％である特許請求の範囲第１項記載の顔
料分散液。 ３、顔料の含有量が、全組成の０．００５〜１０重量％
である特許請求の範囲第１項記載の顔料分散液。 ４、顔料分散液が毛髪化粧料である特許請求の範囲第１
項ないし第３項のいずれかの項記載の顔料分散液。[Claims] 1. Contains the following components (A) and (B): (A) a polyoxyalkylene compound obtained by addition polymerizing an alkylene oxide to a monohydric or polyhydric alcohol; (B) a pigment; A pigment dispersion liquid characterized by: 2. The pigment dispersion according to claim 1, wherein the content of the polyoxyalkylene compound is 1 to 50% by weight of the total composition. 3. Pigment content is 0.005 to 10% by weight of the total composition
The pigment dispersion according to claim 1. 4. Claim 1 in which the pigment dispersion is a hair cosmetic
The pigment dispersion liquid according to any one of Items 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26748487A JPH01110612A (en) | 1987-10-22 | 1987-10-22 | Pigment dispersion liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26748487A JPH01110612A (en) | 1987-10-22 | 1987-10-22 | Pigment dispersion liquid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01110612A true JPH01110612A (en) | 1989-04-27 |
Family
ID=17445490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26748487A Pending JPH01110612A (en) | 1987-10-22 | 1987-10-22 | Pigment dispersion liquid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01110612A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4918917A (en) * | 1972-06-15 | 1974-02-19 | ||
| JPS50129628A (en) * | 1974-02-26 | 1975-10-14 | ||
| JPS50131879A (en) * | 1974-03-06 | 1975-10-18 | ||
| JPS5130828A (en) * | 1974-07-04 | 1976-03-16 | Ugine Kuhlmann | |
| JPS5662538A (en) * | 1979-10-25 | 1981-05-28 | Kao Corp | Water-base dispersion stabilizer of fine powder |
| JPS6136370A (en) * | 1984-07-11 | 1986-02-21 | エンゲルハード・コーポレーシヨン | Treated clay |
-
1987
- 1987-10-22 JP JP26748487A patent/JPH01110612A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4918917A (en) * | 1972-06-15 | 1974-02-19 | ||
| JPS50129628A (en) * | 1974-02-26 | 1975-10-14 | ||
| JPS50131879A (en) * | 1974-03-06 | 1975-10-18 | ||
| JPS5130828A (en) * | 1974-07-04 | 1976-03-16 | Ugine Kuhlmann | |
| JPS5662538A (en) * | 1979-10-25 | 1981-05-28 | Kao Corp | Water-base dispersion stabilizer of fine powder |
| JPS6136370A (en) * | 1984-07-11 | 1986-02-21 | エンゲルハード・コーポレーシヨン | Treated clay |
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