JP7506181B2 - シリコーン樹脂の組み合わせを含む、ケラチン物質への塗布後に多層構造を形成することができる化粧用組成物 - Google Patents
シリコーン樹脂の組み合わせを含む、ケラチン物質への塗布後に多層構造を形成することができる化粧用組成物 Download PDFInfo
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- 230000002045 lasting effect Effects 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 235000010187 litholrubine BK Nutrition 0.000 description 1
- NEMFQSKAPLGFIP-UHFFFAOYSA-N magnesiosodium Chemical compound [Na].[Mg] NEMFQSKAPLGFIP-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical class [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- SOXAGEOHPCXXIO-DVOMOZLQSA-N menthyl anthranilate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)C1=CC=CC=C1N SOXAGEOHPCXXIO-DVOMOZLQSA-N 0.000 description 1
- 229960002248 meradimate Drugs 0.000 description 1
- WSFSSNUMVMOOMR-BJUDXGSMSA-N methanone Chemical compound O=[11CH2] WSFSSNUMVMOOMR-BJUDXGSMSA-N 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- PHLASVAENYNAOW-UHFFFAOYSA-N methyl-bis[[methyl(diphenyl)silyl]oxy]-phenylsilane Chemical compound C=1C=CC=CC=1[Si](C)(C=1C=CC=CC=1)O[Si](C=1C=CC=CC=1)(C)O[Si](C)(C=1C=CC=CC=1)C1=CC=CC=C1 PHLASVAENYNAOW-UHFFFAOYSA-N 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 125000005474 octanoate group Chemical class 0.000 description 1
- 229960003921 octisalate Drugs 0.000 description 1
- 229940048862 octyldodecyl neopentanoate Drugs 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- ZYIBVBKZZZDFOY-UHFFFAOYSA-N phloxine O Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C(O)C(Br)=C1OC1=C(Br)C(O)=C(Br)C=C21 ZYIBVBKZZZDFOY-UHFFFAOYSA-N 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical group 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229940096958 ppg-15 stearyl ether benzoate Drugs 0.000 description 1
- XLCIFRJORZNGEV-UHFFFAOYSA-N propan-2-yl 2-[dodecanoyl(methyl)amino]acetate Chemical compound CCCCCCCCCCCC(=O)N(C)CC(=O)OC(C)C XLCIFRJORZNGEV-UHFFFAOYSA-N 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 238000011158 quantitative evaluation Methods 0.000 description 1
- 239000010493 quinoa oil Substances 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940057910 shea butter Drugs 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- KJCLYACXIWMFCC-UHFFFAOYSA-M sodium;5-benzoyl-4-hydroxy-2-methoxybenzenesulfonate Chemical class [Na+].C1=C(S([O-])(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 KJCLYACXIWMFCC-UHFFFAOYSA-M 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 229960000368 sulisobenzone Drugs 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229940117985 trimethyl pentaphenyl trisiloxane Drugs 0.000 description 1
- SCRSFLUHMDMRFP-UHFFFAOYSA-N trimethyl-(methyl-octyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C SCRSFLUHMDMRFP-UHFFFAOYSA-N 0.000 description 1
- COXJMKGEQAWXNP-UHFFFAOYSA-N tris(14-methylpentadecyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound CC(C)CCCCCCCCCCCCCOC(=O)CC(O)(C(=O)OCCCCCCCCCCCCCC(C)C)CC(=O)OCCCCCCCCCCCCCC(C)C COXJMKGEQAWXNP-UHFFFAOYSA-N 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
本出願は、全内容が参照により本明細書に組み込まれる、2020年6月30日に出願された米国特許出願第16/916,594号及び2020年8月26日に出願されたフランス特許出願第2008714号に対する優先権の利益に基づき、かつそれを主張するものである。
本発明の様々な実施形態によれば、シリコーン樹脂の組み合わせを含む、ケラチン物質への塗布後に多層構造を形成することができる化粧用組成物が提供される。かかる組成物は、多段階塗布プロセスに携わることを必要とすることなく、多層化粧品に関連する利益を可能にする。例えば、かかる組成物は、ファンデーション、下地、アイシャドウ、及び他の皮膚用組成物として好適であり得、かつ/又はリップスティック、リップグロス、リップバーム、及び他の唇用組成物として好適であり得る。
好ましい実施形態によれば、成分A及び/又は成分Bは、60℃未満、好ましくは55℃未満、好ましくは50℃未満、好ましくは人間の正常体温(98.6°F又は37℃)未満の少なくとも1つのガラス転移温度を有するシリコーン樹脂の組み合わせを含む。
好ましい実施形態によれば、成分A及び成分Bは異なる密度特性を有し、その差異により、成分Aと成分Bとが本発明の組成物中で不混和性になる。好ましくは、成分A/層A及び成分B/層Bは、0.001~1kg/m3、好ましくは0.005~0.8kg/m3、好ましくは0.01~0.6kg/m3(それらの間の全ての範囲及び部分範囲を含む)の密度差を有する。
好ましい実施形態によれば、成分A及び成分Bは温度の影響を受け、その影響により、成分A及び成分Bが、50℃未満の温度で安定しているとみなされるエマルジョンとは異なり、当該技術分野で既知の所定の時間にわたって、かかる条件下で、本発明の組成物中で不混和性になる。
好ましい実施形態によれば、成分A及び/又は成分Bは、例えば、臨界エンタングルメント分子量(Mc)を有する皮膜形成剤などの少なくとも1つのポリマーを含み、これにより、以下のようになる。
成分A及び成分Bは、主に層A及び層Bに関連する異なる官能性に基づいて、様々な点で異なり得る。例えば、層Aが耐移り性又は付着機能を果たす場合、成分Aの成分は、耐移り性又は付着を達成するように選択することができる。同様に、層Aが色増強機能を果たす場合、少なくとも1つの着色剤が成分Aに添加され得る。また、例えば、層Bがグロス若しくは光沢増強機能を果たし、かつ/又はより良好な感触を提供し(例えば、より快適な感触を提供し)、かつ/又は色移りを阻止するバリア層を提供する場合、成分Bの成分は、グロス、光沢、快適、及び/又はバリア層特性を達成するように選択することができる。しかしながら、層A及び層Bの界面では、層Aの界面が層Bにより関連する特性(例えば、光沢)を有し得る一方で、層Bが層Aにより関連する特性(例えば、付着性)を有し得ることを理解されたい。
本発明によれば、少なくとも1つの変性MQ樹脂、少なくとも1つのMQ樹脂、及び少なくとも1つのポリプロピルシルセスキオキサン樹脂を含む組成物が提供される。
[(CH3)3SiO]x(SiO4/2)y
(RSiO3/2).x
1つ以上の実施形態では、本発明の組成物は、少なくとも1つのシリコーン化合物を含む。好ましくは、成分Bは、皮膜形成剤ではない1つ以上のシリコーン化合物を含む。また、好ましくは、少なくとも1つのシリコーン化合物は、別の成分中の皮膜形成剤の表面エネルギーよりも低い表面エネルギーを有する。したがって、例えば、成分Bが皮膜形成剤ではない少なくとも1つのシリコーン化合物を含む場合、シリコーン化合物は、好ましくは、成分A中の皮膜形成剤よりも低い表面エネルギーを有する。
本発明の好ましい実施形態によれば、少なくとも1つの光沢増強剤を、成分A、成分B、又はそれらの両方に添加することができる。好ましくは、光沢増強剤は、層のセルフレベリングを容易にする薬剤、高屈折率を有する薬剤剤、及びそれらの混合物からなる群から選択される。以下に記載されるように、かかる光沢増強剤は、上述のシリコーン化合物であり得る。
R7、R8、R11、及びR12は同一又は異なるものであり、各々、1~6個の炭素原子を含むアルキルラジカルから選択され、
R9及びR10は同一又は異なるものであり、各々、1~6個の炭素原子を含むアルキルラジカル及びアリールラジカルから選択され、
Xは、1~6個の炭素原子を含むアルキルラジカル、ヒドロキシルラジカル、及びビニルラジカルから選択され、
n及びpは、シリコーンゴムに、350cSt~50,000,000cSt、好ましくは500cSt~40,000,000cSt、好ましくは750cSt~30,000,000cSt、好ましくは850cSt~20,000,000cSt、好ましくは950cSt~18,000,000cSt、好ましくは1000cSt~10,000,000cSt(それらの間の全ての範囲及び部分範囲を含む)の粘度を与えるように選択される。
置換基R7~R12及びXがメチル基を表し、pが0であり、nが2,700である、例えば、SE30という名称でGeneral Electric社により販売されているか、又は製造された製品、
置換基R7~R12及びXがメチル基を表し、pが0であり、nが2,300である、例えば、AK 500 000という名称でWacker社により販売されているか、又は製造された製品、
置換基R7~R12がメチル基を表し、置換基Xがヒドロキシル基を表し、pが0であり、nが2,700である(シクロペンタシロキサン中13%溶液)、例えば、Dow Corning社によりQ2-1401の名称で販売されているか、又は製造された製品、
置換基R7~R12がメチル基を表し、置換基Xがヒドロキシル基を表し、pが0であり、nが2,700である(ポリジメチルシロキサン中13%溶液)、例えば、Dow Corning社によりQ2-1403の名称で販売されているか、又は製造された製品、並びに
置換基R7、R8、R11、R12、及びXはメチル基を表し、置換基R9及びR10はアリール基を表し、これにより、ゴムの分子量が約600,000になる、例えば、Rhone-Poulenc(Rhodia Chimie)社により761の名称で販売されているか、又は製造された製品。
本発明の好ましい実施形態によれば、少なくとも1つのマット増強剤を、成分A、成分B、又はそれらの両方に添加することができる。成分Bに関して、成分Bがセルフレベリングではないか、かつ/又は層Bが上記の組成物にマット特性を付与する屈折特性を有するかにかかわらず、少なくとも1つのマット増強剤を添加することができる。
本発明の1つ以上の実施形態によれば、少なくとも1つの着色剤を更に含む組成物が提供される。好ましくは、かかる着色組成物は、例えば、ファンデーション又はアイシャドウなどの化粧用組成物であり得る。かかる実施形態によれば、少なくとも1つの着色剤は、顔料、染料、真珠顔料、及び真珠光沢化剤から選択され得る。
-グリセロール脂肪酸エステルからなる高トリグリセリド含有量を有する炭化水素ベースの植物油(その脂肪酸は様々な鎖長を有し得、これらの鎖は直鎖状又は分岐状及び飽和又は不飽和である可能性があり、これらの油は、特に、小麦胚芽油、トウモロコシ油、ヒマワリ油、カリテバター、ヒマシ油、スイートアーモンド油、マカダミア油、アプリコット油、大豆油、菜種油、綿実油、アルファルファ油、ケシ油、カボチャ油、ゴマ油、マロー油、アボカド油、ヘーゼルナッツ油、ブドウ種子油、ブラックカラント種子油、マツヨイグサ油、キビ油、大麦油、キノア油、オリーブ油、ライ麦油、サフラワー油、キャンドルナッツ油、トケイソウ油、若しくはジャコウバラ油、又はカプリル酸/カプリン酸トリグリセリド、例えば、Stearineries Dubois社から販売されているもの若しくはDynamit Nobel社からMiglyol 810、812、及び818という商標名で販売されているものである)、
-式R5COOR6の合成油又はエステル(式中、R5が、7~19個の炭素原子などの1~40個の炭素原子を有する直鎖状又は分岐状高級脂肪酸残基を表し、R6が、3~20個の炭素原子などの1~40個の炭素原子を有する分岐状炭化水素ベースの鎖を表し、R6+R7が10以上であり、例えば、パーセリンオイル(オクタン酸セトステアリル)、イソノナン酸イソノニル、ネオペンタン酸オクチルドデシル、C12~C15安息香酸アルキル、ミリスチン酸イソプロピル、2-パルミチン酸エチルヘキシル、及びオクタン酸、デカン酸、又はリシノール酸アルコール又はポリアルコール、水酸化エステル、例えば、乳酸イソステアリル又はリンゴ酸ジイソステアリル、並びにペンタエリスリトールエステルである)、
-10~40個の炭素原子を有する合成エーテル、
-C8~C26脂肪族アルコール、例えば、オレイルアルコール、セチルアルコール、ステアリルアルコール、及びセタリーアルコール、並びに
-それらの混合物。
好ましい実施形態によれば、存在する場合、少なくとも1つの油は、組成物の総重量に基づいて約5~約60重量%、より好ましくは約10~約50重量%、最も好ましくは約15~約35重量%の範囲(それらの間の全ての範囲及び部分範囲を含む)の量で本発明の組成物中に存在する。
好ましい実施形態によれば、本発明の組成物は、皮膚又は唇などのケラチン物質に塗布するための組成物である。これらの実施形態によれば、本発明の組成物は、例えば、水、活性成分、保湿剤、界面活性剤、及び充填剤などの化粧用組成物中で典型的に見つけられる成分を含むことができる。したがって、本発明の組成物は、考慮されている分野で通常使用されているいずれの添加剤も含むことができる。例えば、ポリ(12-ヒドロキシステアリン酸)などの分散剤、抗酸化剤、精油、日焼け止め剤、防腐剤、香料、充填剤、中和剤、化粧用皮膚科活性剤、例えば、皮膚軟化剤、保湿剤、ビタミン、必須脂肪酸、界面活性剤、シリコーンエラストマー、増粘剤、ゲル化剤、粒子、ペースト状化合物、粘度増加剤などを添加することができる。かかる成分の非包括的な一覧は、全内容が参照により本明細書に組み込まれる米国特許出願公開第2004/0170586号で見つけることができる。好適な追加の成分の更なる例は、参照により本出願に組み込まれている他の参考文献で見つけることができる。かかる追加の成分のなお更なる例は、International Cosmetic Ingredient Dictionary and Handbook(9th ed.2002)で見つけることができる。
i.難溶性UVフィルター(水又は油のいずれにも認識できるほどに溶解しない)、例えば、メチレンビス-ベンゾトリアゾリルテトラメチルブチルフェノール、トリス-ビフェニルトリアジン、メタノン、1,1’-(1,4-ピペラジンジイル)ビス[1-[2-[4-(ジエチルアミノ)-2-ヒドロキシベンゾイル]フェン-イル]-、及びそれらの混合物、
ii.油溶性有機UVフィルター(油又は有機溶媒に少なくとも部分的に溶解する)、例えば、ビス-エチルヘキシルオキシフェノールメトキシフェニルトリアジン、ブチルメトキシジベンゾイルメタン(BMBM)、オキシベンゾン、スリソベンゾン、ジエチルヘキシルブタミドトリアゾン(DBT)、ドロメトリゾールトリシロキサン、エチルヘキシルメトキシシンナメート(EHMC)、エチルヘキシルサリチレート(EHS)、エチルヘキシルトリアゾン(EHT)、ホモサラート、イソアミルp-メトキシシンナメート、4-メチルベンジリデンカンファーオクトクリレン(OCR)、ポリシリコーン-15、及びジエチルアミノヒドロキシベンゾイルヘキシルベンゾエート(DHHB)、
iii.無機UVフィルター、例えば、酸化チタン及び酸化亜鉛、酸化鉄、酸化ジルコニウム、及び酸化セリウム、並びに
iv.水溶性UVフィルター、例えば、フェニルベンズイミダゾールスルホン酸(PBSA)、スリソベンゾンナトリウム塩、ベンジジレンカンファースルホン酸、カンファーベンザルコニウムメトスルフェート、シノキサート、フェニルジベンジルミダゾールテトラスルホン酸二ナトリウム、テレフタリリデンジカンファースルホン酸、PABA、及びPEG-25 PABA。
本発明の好ましい実施形態によれば、ケラチン物質、例えば、皮膚又は唇を手入れする、ケアする、及び/又はメークアップするのに十分な量で、本発明の組成物をケラチン物質に塗布することによる、ケラチン物質を手入れする、ケアする、及び/又はメークアップする方法が提供される。好ましくは、ケラチン物質を「メークアップする」ことは、ケラチン物質に色を提供するのに十分な量で、少なくとも1つの着色剤をケラチン物質に塗布することを含む。
1.ケラチン物質への塗布後に多層構造を形成することができる化粧用組成物であって、
化粧用組成物が少なくとも2つの不混和性成分A及びBを含み、
成分Aが、少なくとも1つのMQ樹脂、少なくとも1つのポリプロピルシルセスキオキサン、及び少なくとも1つの変性MQ樹脂を含み、変性MQ樹脂が、少なくとも1つのT単位を含み、
成分Bが、組成物の総重量に対して約0.01重量%~90重量%の1つ以上のシリコーン化合物を、約1,000cSt~22,000,000cStの粘度を達成するのに十分な量で含む、化粧用組成物。
2.少なくとも1つの着色剤、好ましくは無機顔料を更に含む、先行実施形態に記載の化粧用組成物。
3.組成物が、組成物の総重量に対して1重量%未満の着色剤を含む、先行実施形態のいずれか1つに記載の化粧用組成物。
4.少なくとも1つの揮発性炭化水素油、好ましくはイソドデカンを更に含む、先行実施形態のいずれか1つに記載の化粧用組成物。
5.シリコーン化合物が、シリコーンゴム、シリコーン流体、及びそれらの混合物からなる群から選択される少なくとも1つの化合物を含む、先行実施形態のいずれか1つに記載の化粧用組成物。
6.変性MQ樹脂がポリメチルシルセスキオキサン/トリメチルシロキシシリケートである、先行実施形態のいずれか1つに記載の化粧用組成物。
7.(MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂重量比に対する重量比が約10:1~約1:10である、先行実施形態のいずれか1つに記載の化粧用組成物。
8.(a)先行実施形態のいずれか1つに記載の化粧用組成物と、(b)化粧用組成物を収容する少なくとも1つの容器と、(c)少なくとも1つのアプリケータと、を含む、キット。
9.容器が成分Aと成分Bとを混合するように構成されている、先行実施形態に記載のキット。
10.上記の実施形態1~7のいずれか1つに記載の化粧用組成物、好ましくは、上記の実施形態8又は9に記載のキットの一部をケラチン物質に塗布する方法であって、化粧用組成物を混合して、混合された組成物を形成することであって、組成物中で、成分Aと成分Bとが一時的に混和している、形成することと、混合された組成物をケラチン物質に塗布することと、を含む、方法。
実施例1からの組成物を長持ち特性について試験した。オリーブ油、人工唾液、及び酢酸が長持ち特性に及ぼす影響について、以下のように定量的評価を行った。
Claims (14)
- ケラチン物質への塗布後に多層構造を形成することができる化粧用組成物であって、
前記化粧用組成物が少なくとも2つの不混和性成分A及びBを含み、
成分Aが、少なくとも1つのMQ樹脂、少なくとも1つのポリプロピルシルセスキオキサン、及び少なくとも1つの変性MQ樹脂を含み、前記変性MQ樹脂が、少なくとも1つのT単位を含み、
成分Bが、前記化粧用組成物の総重量に対して0.01重量%~90重量%の1つ以上のシリコーン化合物を、1,000cSt~22,000,000cStの粘度を達成するのに十分な量で含み、
ケラチン物質への塗布前に、前記化粧用組成物は混合され、ケラチン物質への塗布後、成分Aは成分Bから分離して、ケラチン物質上に、成分Aに相当する層A及び成分Bに対応する層Bを含む多層構造を形成する、化粧用組成物であって、
(MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂に対する重量比が3:1~1:3である、化粧用組成物。 - 少なくとも1つの着色剤を更に含む、請求項1に記載の化粧用組成物。
- 前記組成物が、前記組成物の総重量に対して0重量%超及び1重量%未満の着色剤を含む、請求項1又は2に記載の化粧用組成物。
- 前記組成物が、着色剤を含まない、請求項1に記載の化粧用組成物。
- 少なくとも1つの揮発性炭化水素油を更に含む、請求項1から4のいずれか一項に記載の化粧用組成物。
- 前記シリコーン化合物が、シリコーンゴム、シリコーン流体、及びそれらの混合物からなる群から選択される少なくとも1つの化合物を含む、請求項1から5のいずれか一項に記載の化粧用組成物。
- 前記変性MQ樹脂がポリメチルシルセスキオキサン/トリメチルシロキシシリケートである、請求項1から6のいずれか一項に記載の化粧用組成物。
- (a)請求項1から7のいずれか一項に記載の化粧用組成物と、(b)前記化粧用組成物を収容する少なくとも1つの容器と、(c)少なくとも1つのアプリケータと、を含む、キット。
- 前記容器が成分Aと成分Bとを混合するように構成されている、請求項8に記載のキット。
- 請求項1~7のいずれか一項に記載の化粧用組成物をケラチン物質に塗布する方法であって、前記化粧用組成物を混合して、混合された組成物を形成することであって、前記混合後に成分が層に視覚的に分離されない、形成することと、前記混合された組成物を前記ケラチン物質に塗布することと、を含む、方法。
- (MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂に対する重量比が2:1~1:3である、請求項1に記載の化粧用組成物。
- (MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂に対する重量比が2:1~1:2である、請求項1に記載の化粧用組成物。
- (MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂に対する重量比が1:1~1:2である、請求項1に記載の化粧用組成物。
- (MQ樹脂+ポリプロピルシルセスキオキサン)の変性MQ樹脂に対する重量比が1:1~2:1である、請求項1に記載の化粧用組成物。
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