JP7477509B2 - ハイブリッドフォーム配合物 - Google Patents
ハイブリッドフォーム配合物 Download PDFInfo
- Publication number
- JP7477509B2 JP7477509B2 JP2021532357A JP2021532357A JP7477509B2 JP 7477509 B2 JP7477509 B2 JP 7477509B2 JP 2021532357 A JP2021532357 A JP 2021532357A JP 2021532357 A JP2021532357 A JP 2021532357A JP 7477509 B2 JP7477509 B2 JP 7477509B2
- Authority
- JP
- Japan
- Prior art keywords
- polyol
- isocyanate
- functionality
- groups
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 204
- 239000006260 foam Substances 0.000 title claims description 123
- 238000009472 formulation Methods 0.000 title claims description 60
- 229920005862 polyol Polymers 0.000 claims description 230
- 150000003077 polyols Chemical class 0.000 claims description 230
- 239000004971 Cross linker Substances 0.000 claims description 71
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 67
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 54
- 229920000570 polyether Polymers 0.000 claims description 54
- 239000012948 isocyanate Substances 0.000 claims description 53
- 150000002513 isocyanates Chemical class 0.000 claims description 53
- 239000003999 initiator Substances 0.000 claims description 45
- 150000001412 amines Chemical class 0.000 claims description 27
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 25
- 239000000600 sorbitol Substances 0.000 claims description 25
- 125000000524 functional group Chemical group 0.000 claims description 17
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical group N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 9
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- INXWLSDYDXPENO-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(CO)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C INXWLSDYDXPENO-UHFFFAOYSA-N 0.000 claims description 5
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical group OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 4
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 50
- 239000003054 catalyst Substances 0.000 description 35
- 239000000047 product Substances 0.000 description 35
- 150000003254 radicals Chemical class 0.000 description 26
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 25
- 229930006000 Sucrose Natural products 0.000 description 25
- 235000011187 glycerol Nutrition 0.000 description 25
- 239000005720 sucrose Substances 0.000 description 25
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 24
- 150000002009 diols Chemical class 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 22
- 125000003118 aryl group Chemical group 0.000 description 21
- -1 for example Polymers 0.000 description 20
- 239000013518 molded foam Substances 0.000 description 19
- 229920005906 polyester polyol Polymers 0.000 description 19
- 239000004604 Blowing Agent Substances 0.000 description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000004094 surface-active agent Substances 0.000 description 16
- 239000000126 substance Substances 0.000 description 14
- 239000005056 polyisocyanate Substances 0.000 description 13
- 229920001228 polyisocyanate Polymers 0.000 description 13
- 125000002947 alkylene group Chemical group 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- 238000007664 blowing Methods 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
- 229920013701 VORANOL™ Polymers 0.000 description 7
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 6
- 239000012973 diazabicyclooctane Substances 0.000 description 5
- 238000005829 trimerization reaction Methods 0.000 description 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- JIABEENURMZTTI-UHFFFAOYSA-N 1-isocyanato-2-[(2-isocyanatophenyl)methyl]benzene Chemical compound O=C=NC1=CC=CC=C1CC1=CC=CC=C1N=C=O JIABEENURMZTTI-UHFFFAOYSA-N 0.000 description 2
- ZMBQZWCDYKGVLW-UHFFFAOYSA-N 1-methylcyclohexa-3,5-diene-1,2-diamine Chemical compound CC1(N)C=CC=CC1N ZMBQZWCDYKGVLW-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 2
- FZQMJOOSLXFQSU-UHFFFAOYSA-N 3-[3,5-bis[3-(dimethylamino)propyl]-1,3,5-triazinan-1-yl]-n,n-dimethylpropan-1-amine Chemical compound CN(C)CCCN1CN(CCCN(C)C)CN(CCCN(C)C)C1 FZQMJOOSLXFQSU-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 description 2
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 2
- 229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000002666 chemical blowing agent Substances 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 150000001983 dialkylethers Chemical class 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- CDOOAUSHHFGWSA-OWOJBTEDSA-N (e)-1,3,3,3-tetrafluoroprop-1-ene Chemical compound F\C=C\C(F)(F)F CDOOAUSHHFGWSA-OWOJBTEDSA-N 0.000 description 1
- NLOLSXYRJFEOTA-UPHRSURJSA-N (z)-1,1,1,4,4,4-hexafluorobut-2-ene Chemical compound FC(F)(F)\C=C/C(F)(F)F NLOLSXYRJFEOTA-UPHRSURJSA-N 0.000 description 1
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
- DUAKCVSNUIDZMC-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluorobutane Chemical compound CC(F)(F)C(F)(F)C(F)(F)F DUAKCVSNUIDZMC-UHFFFAOYSA-N 0.000 description 1
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical compound CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- CVMVAHSMKGITAV-UHFFFAOYSA-N 1,1,1,4,4,5,5,5-octafluoropent-2-ene Chemical compound FC(F)(F)C=CC(F)(F)C(F)(F)F CVMVAHSMKGITAV-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- GFNDFCFPJQPVQL-UHFFFAOYSA-N 1,12-diisocyanatododecane Chemical compound O=C=NCCCCCCCCCCCCN=C=O GFNDFCFPJQPVQL-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- OHTRJOZKRSVAOX-UHFFFAOYSA-N 1,3-diisocyanato-2-methylcyclohexane Chemical compound CC1C(N=C=O)CCCC1N=C=O OHTRJOZKRSVAOX-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- AHBNSOZREBSAMG-UHFFFAOYSA-N 1,5-diisocyanato-2-methylpentane Chemical compound O=C=NCC(C)CCCN=C=O AHBNSOZREBSAMG-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- KHXVVWQPIQVNRH-UHFFFAOYSA-N 1-isocyanato-3-(isocyanatomethyl)-1-methylcyclohexane Chemical compound O=C=NC1(C)CCCC(CN=C=O)C1 KHXVVWQPIQVNRH-UHFFFAOYSA-N 0.000 description 1
- LYDHLGJJJAWBDY-UHFFFAOYSA-N 1-isocyanato-4-[2-(4-isocyanatocyclohexyl)propan-2-yl]cyclohexane Chemical compound C1CC(N=C=O)CCC1C(C)(C)C1CCC(N=C=O)CC1 LYDHLGJJJAWBDY-UHFFFAOYSA-N 0.000 description 1
- CXBDYQVECUFKRK-UHFFFAOYSA-N 1-methoxybutane Chemical compound CCCCOC CXBDYQVECUFKRK-UHFFFAOYSA-N 0.000 description 1
- BFXXDIVBYMHSMP-UHFFFAOYSA-L 2,2-diethylhexanoate;tin(2+) Chemical compound [Sn+2].CCCCC(CC)(CC)C([O-])=O.CCCCC(CC)(CC)C([O-])=O BFXXDIVBYMHSMP-UHFFFAOYSA-L 0.000 description 1
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 1
- ZLBFMYQIKPWYBC-UHFFFAOYSA-N 2-benzofuran-1,3-dione;2-(2-hydroxyethoxy)ethanol Chemical compound OCCOCCO.C1=CC=C2C(=O)OC(=O)C2=C1 ZLBFMYQIKPWYBC-UHFFFAOYSA-N 0.000 description 1
- BSXGCUHREZFSRY-UHFFFAOYSA-N 3-[[1-amino-2-[[1-amino-1-(2-carboxyethylimino)-2-methylpropan-2-yl]diazenyl]-2-methylpropylidene]amino]propanoic acid;tetrahydrate Chemical compound O.O.O.O.OC(=O)CCNC(=N)C(C)(C)N=NC(C)(C)C(=N)NCCC(O)=O BSXGCUHREZFSRY-UHFFFAOYSA-N 0.000 description 1
- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
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- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/026—Crosslinking before of after foaming
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
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- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
アミン開始ポリオール(トルエンジアミン開始ポリオール、平均官能価4.0、数平均分子量476g/モル、当量119g/当量、平均ヒドロキシル価471mg KOH/g)。アミン開始ポリオールは、トルエンジアミン、プロピレンオキシド、およびエチレンオキシドを利用して形成された。
VORANOL(商標)2110TB(ポリエーテルジオール、平均官能価2.0、数平均分子量1020g/モル、当量510g/当量、平均ヒドロキシル価110mg KOH/g、The Dow Chemical Companyから入手可能)、
STEPANPOL PS 2352(芳香族ポリエステルポリオール、平均官能価2.0、数平均分子量468g/モル、当量234g/当量、平均ヒドロキシル価240mg KOH/g、Stepan Chemicalから入手)、
DOW(商標)P-425(グリコール、平均官能価2.0、数平均分子量425g/モル、当量212.5g/当量、平均ヒドロキシル価264mg KOH/g、The Dow Chemical Companyから入手)、
VORANOL(商標)225(グリセリン開始ポリエーテルポリオール、平均官能価3.0、数平均分子量225g/モル、当量85g/当量、平均ヒドロキシル価660mg KOH/g、The Dow Chemical Companyから入手可能)、
高官能性架橋剤(ジペンタエリスリトールペンタ-/ヘキサ-アクリレート(DPPA)、Sigma-Aldrich/MilliporeSigmaから入手)、
POLYCAT 5(触媒、PMDETA-N,N,N’,N’‘,N’‘-ペンタメチルジエチレントリアミン、Evonikから入手)、
POLYCAT 41(触媒、N,N’,N’‘-トリス(3-ジメチルアミノプロピル)ヘキサヒドロ-S-トリアジン、Evonikから入手)、
POLYCAT 8(触媒、N,N-ジメチルシクロ-ヘキシルアミン、Evonikから入手)、
SPE界面活性剤EP-A-98(界面活性剤、シリコーンポリエーテル界面活性剤、Evonikから入手)、
Solstice 1233zd液体発泡剤(物理発泡剤、トランス-1-クロロ-3,3,3-トリフルオロプロペン、Honeywellから入手)、
LuperoxATC50フリーラジカル開始剤(リン酸トリクレジル中50重量%の過酸化ベンゾイル、Sigma-Aldrich/MilliporeSigmaから入手)、
アゾ系ラジカル開始剤(2,2’アゾビス(イソブチロニトリル、Sigma-Aldrich/MilliporeSigmaから入手)、および
イソシアネート(MDIを含有し、約31.4重量%のNCO含有量および134のイソシアネート当量分子量を有するPAPI(商標)27ポリメチレンポリフェニルイソシアネート、the Dow Chemical Companyから入手)。
本出願が提供する発明として例えば以下のものが挙げられる。
[1] ポリオール組成物であって、前記ポリオール組成物の総ポリオールに基づいて3.7~5.7の平均ヒドロキシル官能価、前記ポリオール組成物の総ポリオールに基づいて370~550mg KOH/gの平均ヒドロキシル価、および前記ポリオール組成物の総ポリオールに基づいて400~750g/モルの数平均分子量を有する、ポリオール組成物と、
3.0以上の平均官能価を有する高官能性架橋剤であって、前記高官能性架橋剤の官能基が、アクリレート基、アリル基、OH基、NH 2 基、COOH基、およびそれらの組み合わせから選択され、前記高官能性架橋剤の前記官能基の10~99パーセントが、アクリレート基、アリル基、またはそれらの組み合わせである、高官能性架橋剤と、を含む、イソシアネート反応性組成物。
[2] 高官能性架橋剤が、前記ポリオール組成物の総ポリオールと前記高官能性架橋剤との組み合わせの100部に基づいて、前記イソシアネート反応性組成物の2~40部である、上記[1]に記載のイソシアネート反応性組成物。
[3] 前記高官能性架橋剤が、100~1500g/モルの数平均分子量を有する、上記[1]~[2]のいずれか一項に記載のイソシアネート反応性組成物。
[4] 前記高官能性架橋剤が、ジペンタエリスリトールペンタアクリレート、ジペンタエリスリトールペンタ-/ヘキサ-アクリレート、ペンタエリスリトールトリアクリレート、およびそれらの組み合わせから選択される、上記[1]~[3]のいずれか一項に記載のイソシアネート反応性組成物。
[5] 上記[1]~[4]のいずれか一項に記載のイソシアネート反応性組成物と、
アゾ系ラジカル開始剤と、
イソシアネートと、を含む、ハイブリッドフォーム配合物。
[6] 前記アゾ系ラジカル開始剤が、前記ポリオール組成物の総ポリオールと前記高官能性架橋剤との組み合わせの100部に基づいて、前記ハイブリッドフォーム配合物の0.01~5.0部である、上記[5]に記載のハイブリッドフォーム配合物。
[7] 前記アゾ系ラジカル開始剤が、0℃~135℃の0.10時間半減期温度を有する、上記[5]~[6]のいずれか一項に記載のフォーム配合物。
[8] 前記アゾ系ラジカル開始剤が、2,2’-アゾビス(イソブチロニトリル)である、上記[5]~[7]のいずれか一項に記載のフォーム配合物。
[9] 上記[5]~[8]のいずれか一項に記載のハイブリッドフォーム配合物を硬化させることによって形成される、フォーム製品。
[10] フォーム製品を形成する方法であって、
ポリオール組成物であって、前記ポリオール組成物の総ポリオールに基づいて3.7~5.7の平均ヒドロキシル官能価、前記ポリオール組成物の総ポリオールに基づいて370~550mg KOH/gの平均ヒドロキシル価、および前記ポリオール組成物の総ポリオールに基づいて400~750g/モルの数平均分子量を有するポリオール組成物と、
3.0以上の平均官能価を有する高官能性架橋剤であって、前記高官能性架橋剤の官能基が、アクリレート基、アリル基、OH基、NH 2 基、COOH基、およびそれらの組み合わせから選択され、前記高官能性架橋剤の前記官能基の10~99パーセントが、アクリレート基、アリル基、またはそれらの組み合わせである、高官能性架橋剤と、
アゾ系ラジカル開始剤と、
イソシアネートと、を組み合わせて、ハイブリッドフォーム配合物を形成することと、
前記ハイブリッドフォーム配合物を硬化させて前記フォーム製品を形成することと、を含む、方法。
Claims (10)
- ポリオール組成物であって、前記ポリオール組成物の総ポリオールに基づいて3.7~5.7の平均ヒドロキシル官能価、前記ポリオール組成物の総ポリオールに基づいて370~550mg KOH/gの平均ヒドロキシル価、および前記ポリオール組成物の総ポリオールに基づいて400~750g/モルの数平均分子量を有し、ソルビトール開始ポリエーテルポリオールとアミン開始ポリオールとを含む、ポリオール組成物と、
3.0以上の平均官能価を有する高官能性架橋剤であって、前記高官能性架橋剤の官能基が、アクリレート基、アリル基、OH基、NH2基、COOH基、およびそれらの組み合わせから選択され、前記高官能性架橋剤の前記官能基の10~99パーセントが、アクリレート基、アリル基、またはそれらの組み合わせである、高官能性架橋剤と、
を含む、イソシアネート反応性組成物。 - 高官能性架橋剤が、前記ポリオール組成物の総ポリオールと前記高官能性架橋剤との組み合わせの100部に基づいて、前記イソシアネート反応性組成物の2~40部である、請求項1に記載のイソシアネート反応性組成物。
- 前記高官能性架橋剤が、100~1500g/モルの数平均分子量を有する、請求項1~2のいずれか一項に記載のイソシアネート反応性組成物。
- 前記高官能性架橋剤が、ジペンタエリスリトールペンタアクリレート、ジペンタエリスリトールペンタ-/ヘキサ-アクリレート、ペンタエリスリトールトリアクリレート、およびそれらの組み合わせから選択される、請求項1~3のいずれか一項に記載のイソシアネート反応性組成物。
- 請求項1~4のいずれか一項に記載のイソシアネート反応性組成物と、
アゾ系ラジカル開始剤と、
イソシアネートと、
を含む、ハイブリッドフォーム配合物。 - 前記アゾ系ラジカル開始剤が、前記ポリオール組成物の総ポリオールと前記高官能性架橋剤との組み合わせの100部に基づいて、前記ハイブリッドフォーム配合物の0.01~5.0部である、請求項5に記載のハイブリッドフォーム配合物。
- 前記アゾ系ラジカル開始剤が、0℃~135℃の0.10時間半減期温度を有する、請求項5~6のいずれか一項に記載のフォーム配合物。
- 前記アゾ系ラジカル開始剤が、2,2’-アゾビス(イソブチロニトリル)である、請求項5~7のいずれか一項に記載のフォーム配合物。
- 請求項5~8のいずれか一項に記載のハイブリッドフォーム配合物を硬化させることによって形成される、フォーム製品。
- フォーム製品を形成する方法であって、
ポリオール組成物であって、前記ポリオール組成物の総ポリオールに基づいて3.7~5.7の平均ヒドロキシル官能価、前記ポリオール組成物の総ポリオールに基づいて370~550mg KOH/gの平均ヒドロキシル価、および前記ポリオール組成物の総ポリオールに基づいて400~750g/モルの数平均分子量を有するポリオール組成物と、
3.0以上の平均官能価を有する高官能性架橋剤であって、前記高官能性架橋剤の官能基が、アクリレート基、アリル基、OH基、NH2基、COOH基、およびそれらの組み合わせから選択され、前記高官能性架橋剤の前記官能基の10~99パーセントが、アクリレート基、アリル基、またはそれらの組み合わせである、高官能性架橋剤と、
アゾ系ラジカル開始剤と、
イソシアネートと、を組み合わせて、ハイブリッドフォーム配合物を形成することと、
前記ハイブリッドフォーム配合物を硬化させて前記フォーム製品を形成することと、を含む、方法。
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PCT/US2019/065352 WO2020131478A1 (en) | 2018-12-18 | 2019-12-10 | Hybrid foam formulations |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008223001A (ja) | 2006-12-12 | 2008-09-25 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2009263647A (ja) | 2008-03-31 | 2009-11-12 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2010006914A (ja) | 2008-06-25 | 2010-01-14 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2010031242A (ja) | 2008-06-25 | 2010-02-12 | Sanyo Chem Ind Ltd | ポリウレタン樹脂 |
JP2013122007A (ja) | 2011-12-12 | 2013-06-20 | Sanyo Chem Ind Ltd | ポリウレタン樹脂製造用ポリオール組成物及びこれを用いたポリウレタン樹脂の製造方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3332934A (en) * | 1965-05-21 | 1967-07-25 | Allied Chem | Trialkylolamine polyether polyols |
US4839393A (en) * | 1988-07-08 | 1989-06-13 | Wm. T. Burnett & Co., Inc. | Polyurethane foams containing organofunctional silanes |
MXPA01012501A (es) * | 1999-06-01 | 2003-10-14 | Ferro Corp | Composicion para utilizarse en espumas de poliuretano flexibles. |
JP2003138234A (ja) * | 2001-11-02 | 2003-05-14 | Nippon Synthetic Chem Ind Co Ltd:The | 活性エネルギー線硬化型樹脂組成物 |
DE10247241A1 (de) * | 2002-10-10 | 2004-04-22 | Basf Ag | Superabsorbierender Schaum, Verfahren zu seiner Herstellung und seine Verwendung |
US7338983B2 (en) * | 2004-02-10 | 2008-03-04 | World Properties, Inc. | Low density polyurethane foam, method of producing, and articles comprising the same |
DE102004048728A1 (de) * | 2004-10-05 | 2006-04-06 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen |
WO2006056485A1 (en) * | 2004-11-29 | 2006-06-01 | Fritz Nauer Ag. | Polyurethane foam |
JP2009504864A (ja) * | 2005-08-17 | 2009-02-05 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | ポリアクリレートポリオール、ポリエステルポリオール、およびイソシアネート官能性架橋剤を含んでいるコーティング組成物 |
DE102006056401A1 (de) * | 2006-11-29 | 2008-06-05 | Hilti Ag | Zweikomponenten-Polyurethan/Vinylester-Hybridschaumsystem und seine Verwendung als Flammschutzmaterial und Material zum Ausschäumen von Öffnungen in Gebäuden |
CA2745920A1 (en) * | 2008-12-10 | 2010-06-17 | Basf Se | Water-blown rigid foams with improved mechanical properties at low temperatures |
KR20110049572A (ko) * | 2009-11-05 | 2011-05-12 | 삼성전자주식회사 | 유기 에어로젤, 유기 에어로젤용 조성물 및 상기 유기 에어로젤의 제조 방법 |
CN103052668B (zh) * | 2010-08-06 | 2015-02-11 | 三井化学株式会社 | 多元醇、多元醇组合物、及使用其的软质聚氨酯泡沫体 |
US9725555B2 (en) * | 2010-09-09 | 2017-08-08 | Innovative Urethane, Llc | Sugar-based polyurethanes, methods for their preparation, and methods of use thereof |
EP2751158A1 (en) * | 2011-09-02 | 2014-07-09 | Dow Global Technologies LLC | Polyurethane rigid foams |
ES2841988T3 (es) | 2011-10-14 | 2021-07-12 | Dow Global Technologies Llc | Polioles poliéster-poliéter híbridos para una expansión del desmoldo en espumas rígidas de poliuretanos mejorada |
CN107531873B (zh) * | 2015-03-17 | 2020-09-01 | 陶氏环球技术有限责任公司 | 硬质聚氨酯泡沫的异氰酸酯反应性配制物 |
-
2019
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008223001A (ja) | 2006-12-12 | 2008-09-25 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2009263647A (ja) | 2008-03-31 | 2009-11-12 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2010006914A (ja) | 2008-06-25 | 2010-01-14 | Sanyo Chem Ind Ltd | 硬質ポリウレタンフォームの製造方法 |
JP2010031242A (ja) | 2008-06-25 | 2010-02-12 | Sanyo Chem Ind Ltd | ポリウレタン樹脂 |
JP2013122007A (ja) | 2011-12-12 | 2013-06-20 | Sanyo Chem Ind Ltd | ポリウレタン樹脂製造用ポリオール組成物及びこれを用いたポリウレタン樹脂の製造方法 |
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