JP7426952B2 - エポキシ樹脂配合物 - Google Patents
エポキシ樹脂配合物 Download PDFInfo
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- JP7426952B2 JP7426952B2 JP2020569817A JP2020569817A JP7426952B2 JP 7426952 B2 JP7426952 B2 JP 7426952B2 JP 2020569817 A JP2020569817 A JP 2020569817A JP 2020569817 A JP2020569817 A JP 2020569817A JP 7426952 B2 JP7426952 B2 JP 7426952B2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 39
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- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
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- HBGPNLPABVUVKZ-POTXQNELSA-N (1r,3as,4s,5ar,5br,7r,7ar,11ar,11br,13as,13br)-4,7-dihydroxy-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-2,3,4,5,6,7,7a,10,11,11b,12,13,13a,13b-tetradecahydro-1h-cyclopenta[a]chrysen-9-one Chemical compound C([C@@]12C)CC(=O)C(C)(C)[C@@H]1[C@H](O)C[C@]([C@]1(C)C[C@@H]3O)(C)[C@@H]2CC[C@H]1[C@@H]1[C@]3(C)CC[C@H]1C(=C)C HBGPNLPABVUVKZ-POTXQNELSA-N 0.000 claims 2
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical group [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 5
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 4
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 4
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 4
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- 150000002118 epoxides Chemical group 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- SKTSVWWOAIAIKI-UHFFFAOYSA-N furan-2-carbohydrazide Chemical compound NNC(=O)C1=CC=CO1 SKTSVWWOAIAIKI-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- AQTNCAREYVLVMX-UHFFFAOYSA-N icosanedihydrazide Chemical compound NNC(=O)CCCCCCCCCCCCCCCCCCC(=O)NN AQTNCAREYVLVMX-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- IGALFTFNPPBUDN-UHFFFAOYSA-N phenyl-[2,3,4,5-tetrakis(oxiran-2-ylmethyl)phenyl]methanediamine Chemical compound C=1C(CC2OC2)=C(CC2OC2)C(CC2OC2)=C(CC2OC2)C=1C(N)(N)C1=CC=CC=C1 IGALFTFNPPBUDN-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- DSROZUMNVRXZNO-UHFFFAOYSA-K tris[(1-naphthalen-1-yl-3-phenylnaphthalen-2-yl)oxy]alumane Chemical compound C=1C=CC=CC=1C=1C=C2C=CC=CC2=C(C=2C3=CC=CC=C3C=CC=2)C=1O[Al](OC=1C(=C2C=CC=CC2=CC=1C=1C=CC=CC=1)C=1C2=CC=CC=C2C=CC=1)OC(C(=C1C=CC=CC1=C1)C=2C3=CC=CC=C3C=CC=2)=C1C1=CC=CC=C1 DSROZUMNVRXZNO-UHFFFAOYSA-K 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L63/04—Epoxynovolacs
-
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- C08K3/016—Flame-proofing or flame-retarding additives
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64D—EQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENT OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
- B64D11/00—Passenger or crew accommodation; Flight-deck installations not otherwise provided for
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
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- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
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- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
- C08G59/308—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing halogen atoms
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
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- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Aviation & Aerospace Engineering (AREA)
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Description
a.配合物の10~80重量%を占めるハロゲン化エポキシ樹脂、
b.配合物の1~15重量%を占めるアンチモンベースの難燃剤、
c.組成物の1~10重量%を占める無機又は非ポリマー有機リン含有難燃剤、及び
d.配合物の1~30重量%を占める硬化剤系
を含む配合物を提供する。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.配合物の2~15重量%を占めるコアシェルエラストマー粒子及び/又はエラストマー/エポキシ付加物を含むエラストマー強化剤成分;
h.配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;及び
i.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.配合物の2~15重量%を占めるコアシェルエラストマー粒子及び/又はエラストマー/エポキシ付加物を含むエラストマー強化剤成分;及び
h.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.配合物の2~15重量%を占めるコアシェルエラストマー粒子及び/又はエラストマー/エポキシ付加物を含むエラストマー強化剤成分;
h.配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
i.組成物の2~38重量%を占める煙抑制剤;及び
j.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の3~20重量%を占める硬化剤系;
c.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
d.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
e.配合物の6~25重量%を占めるエポキシノボラック樹脂;
f.配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
g.組成物の2~38重量%を占める煙抑制剤;及び
h.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
h.組成物の2~38重量%を占める煙抑制剤;及び
i.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
h.組成物の2~38重量%を占める煙抑制剤;
i.0.05~1.5重量%の湿潤剤、及び
j.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a.配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.配合物の3~20重量%を占める硬化剤系;
d.配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.組成物の2~38重量%を占める煙抑制剤;
h.0.05~1.5重量%の湿潤剤、及び
i.ハロゲン化エポキシ樹脂に加えて配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む。
a)ASTM D2344で測定した場合、少なくとも50MPa、好ましくは少なくとも60MPa、より好ましくは少なくとも70MPaの層間せん断強度(ILSS);
b)ASTM D790で測定した場合、少なくとも1100MPa、好ましくは少なくとも1400MPa、より好ましくは少なくとも1600MPaの0°曲げ強度;
c)ASTM D790で測定した場合、少なくとも95GPa、好ましくは少なくとも100GPa、より好ましくは少なくとも120GPaの0°曲げ弾性率;
d)ASTM D3039で測定した場合、少なくとも1400MPa、好ましくは少なくとも1600MPa、より好ましくは少なくとも1900MPaの0°引張強度;又は
e)ASTM D3039で測定した場合、少なくとも110GPa、好ましくは少なくとも115GPa、より好ましくは少なくとも120GPaの0°引張弾性率
のうちの少なくとも1つを有する。
・LME11082-HunstmanのEEW205の塩素化ビスフェノール-Cエポキシ樹脂、
・Phenoxy YP50P-Kukdoのフェノキシ樹脂強化剤、
・Araldite GY281-EEW 159~172のビスフェノールFエポキシ樹脂、Huntsmanから入手可能、
・MX153-カネカから入手可能な、EEW 270(67重量%)のビスフェノールAエポキシ樹脂と混合されたコアシェルゴム(33重量%)、
・Kaneka MX965-カネカのEEW 220(75重量%)のビスフェノールFエポキシ樹脂と混合されたシリコーンコアシェルゴム(25重量%)、
・Exolit RP6500-ClariantのEEW180~190(53~58重量%)のビスフェノールAエポキシ樹脂に含まれる赤リン難燃剤(42~47重量%)、
・Exolit OP395-Clariantの10%ホスフィナートベースの難燃剤、
・Technicure ADH-J-Geniechemのアジピン酸ジヒドラジド硬化剤、
・Omicure U52M-Alzchemの尿素ベースの促進剤、
・YD PN638-Kukdo EEW170~190のエポキシフェノールノボラック樹脂、
・Nofia OL3001-Veloxの粉砕リンオリゴマー、
・Chemisphereの五酸化アンチモン、
・Firebrake ZB-Boraxのホウ酸亜鉛、
・Magnifin H10-Martinswerkの水酸化マグネシウム、
・Polyfox159-Omnova Solutionsから入手可能な表面仕上げ/湿潤剤、
・BYK-W9010-BYK Additives&Instrumentsから入手可能な湿潤剤、
・Araldite MY9512-Huntsmanから入手可能なEEW117~134の四官能性エポキシ樹脂、
・CHS-130T-SpolchemieのEEW800(70重量%)の固体エポキシ樹脂中のコアシェルゴム(30重量%)、
・Araldite LY3581-HuntsmanのEEW160~170のビスフェノール(bishphenol)Fエポキシ樹脂、
・SCT150-Shin-AのEEW160~170のエポキシフェノールノボラック、
・DICY-AlzChemのDyhard100S微粉化グレードのジシアンジアミド硬化剤、
・Dyhard UR505-AlzChemのビス尿素硬化剤、
・Dyhard D50EP-ビスフェノールAエポキシ樹脂(50重量%)中のジシアンジアミド(50重量%)。
例1及び2並びに比較例1及び2の配合物を表1に示す。Phenoxy YP50P(使用時)を130℃で樹脂に溶解した後、Nofia OL3001(使用時)を100℃で溶解することにより配合物を調製した。配合物を、90℃に冷却して、Exolit RP6500及び残りの難燃剤(使用時)を添加した。硬化剤を60~65℃で添加した。混合物を連続混合下で作製した。
例3、例4及び例5の配合物を表5に示す。
例6の配合物を表12に示す。
例7の配合物を表17に示す。
なお、本発明に包含され得る諸態様または諸実施形態は、以下のとおり要約される。
[1].
配合物であって、
a.配合物の10~80重量%を占めるハロゲン化エポキシ樹脂、
b.配合物の1~15重量%を占めるアンチモンベースの難燃剤、
c.配合物の1~10重量%を占める無機又は非ポリマー有機リン含有難燃剤、及び
d.配合物の1~30重量%を占める硬化剤系
を含む配合物。
[2].
前記ハロゲン化エポキシ樹脂が、塩素化若しくは臭素化エポキシ樹脂又はそれらの混合物を含み、好ましくは、前記ハロゲン化エポキシ樹脂が、ビスフェノール-Cエポキシ樹脂などの塩素化エポキシ樹脂を含む、上記項目1に記載の配合物。
[3].
前記アンチモンベースの難燃剤が、三酸化アンチモン、五酸化アンチモン、又はそれらの混合物を含む、上記項目1又は上記項目2に記載の配合物。
[4].
前記無機又は非ポリマー有機リン含有難燃剤が、赤色リン、ポリリン酸アンモニウム、ポリホスファゼン、リン酸メラミン(ポリホスファート及びピロホスファートを含む)又はそれらの混合物を含み、より好ましくは前記無機リン含有難燃剤が赤色リンを含む、上記項目1~3のいずれかに記載の配合物。
[5].
さらに有機ポリマー又はオリゴマーリン含有難燃剤を前記配合物の4~35重量%の割合で含み、好ましくは、前記有機ポリマー又はオリゴマーリン含有難燃剤が、反応性ホスホナート、より好ましくは、フェノールヒドロキシル末端基を含むホスホナートを含む、上記項目1~4のいずれかに記載の配合物。
[6].
さらに組成物の1~40重量%の割合で煙抑制剤を含み、好ましくは、前記煙抑制剤が、ホウ素化合物、亜鉛化合物、金属水酸化物又はそれらの混合物を含み、より好ましくは前記煙抑制剤が、ヒドロキシスズ酸亜鉛又はホウ酸亜鉛と水酸化マグネシウムの混合物を含む、上記項目1~5のいずれかに記載の配合物。
[7].
前記配合物の5~30重量%の割合でエポキシノボラック樹脂をさらに含み、好ましくは前記エポキシノボラック樹脂が、フェノールエポキシノボラック樹脂、クレゾールエポキシノボラック樹脂、トリスフェニルメタンエポキシノボラック樹脂又はそれらの混合物を含み、より好ましくは、前記エポキシノボラック樹脂がフェノールエポキシノボラック樹脂を含む、上記項目1~6のいずれかに記載の配合物。
[8].
さらに、前記ハロゲン化エポキシ樹脂に加えて1つ以上のビスフェノールエポキシ樹脂を前記組成物の1~40重量%の割合で含み、好ましくは追加の前記1つ以上のビスフェノールエポキシ樹脂が、ビスフェノールAのジグリシジルエーテル、ビスフェノールFのジグリシジルエーテル、多官能性エポキシ樹脂又はそれらの混合物を含む、上記項目1~7のいずれかに記載の配合物。
[9].
前記硬化剤系がヒドラジド又はジシアンジアミドを含み、好ましくは前記硬化剤系がアジピン酸ジヒドラジド又はジシアンジアミドを含む、上記項目1~8のいずれかに記載の配合物。
[10].
前記硬化剤系が、前記硬化剤系のための促進剤を含み、好ましくは前記促進剤が尿素ベースである、上記項目1~9のいずれかに記載の配合物。
[11].
さらに0.05~1.5重量%の割合で湿潤剤を含み、好ましくは、前記湿潤剤が、非イオン系フッ素化ポリエーテルエトキシル化ポリマー又は酸性基を有するコポリマーを含む、上記項目1~10のいずれかに記載の配合物。
[12].
前記エポキシ樹脂の全成分及び任意の熱可塑性強化剤の合計と、前記無機リン、アンチモン及び任意の煙抑制剤成分の合計との重量比が10:1~1:1である、上記項目1~11のいずれかに記載の配合物。
[13].
a.前記配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.前記配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.前記配合物の3~20重量%を占める硬化剤系;
d.前記配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.前記配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.前記配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.前記配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
h.前記組成物の2~38重量%を占める煙抑制剤;
i.0.05~1.5重量%の湿潤剤、及び
j.前記ハロゲン化エポキシ樹脂に加えて前記配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む、上記項目1に記載の配合物。
[14].
a.前記配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.前記配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.前記配合物の3~20重量%を占める硬化剤系;
d.前記配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.前記配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.前記配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.前記組成物の2~38重量%を占める煙抑制剤;
h.0.05~1.5重量%の湿潤剤、及び
i.前記ハロゲン化エポキシ樹脂に加えて前記配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む、上記項目1に記載の配合物。
[15].
前記配合物が、2℃/分の昇温を使用するオートクレーブ硬化下において、140℃で30分以下及び150℃で15分以下で硬化可能である、上記項目1~14のいずれかに記載の配合物。
[16].
前記配合物が、160℃及び最大7バールの圧力でホットロード/ホットアンロードプレス硬化を使用して15分以内に硬化可能である、上記項目1~15のいずれかに記載の配合物。
[17].
少なくとも145℃の硬化乾燥Tgを有する、上記項目1~16のいずれかに記載の配合物。
[18].
110℃で10PaS -1 以下の粘度を有する、上記項目1~17のいずれかに記載の配合物。
[19].
プリプレグ中のマトリックスとしての、上記項目1~18のいずれかに記載の配合物の使用。
[20].
強化繊維及び上記項目1~18のいずれかに記載の配合物を含むプリプレグ。
[21].
前記強化繊維がガラス繊維及び/又は炭素繊維である、上記項目20に記載のプリプレグ。
[22].
上記項目1~18のいずれかに記載の配合物をプリプレグの25~70重量%の割合で含む、上記項目20又は上記項目21に記載のプリプレグ。
[23].
前記強化繊維が炭素であり、硬化後、以下の特性:
a)ASTM D2344で測定した場合に少なくとも50MPaの層間せん断強度(ILSS)、
b)ASTM D790で測定した場合に少なくとも1100MPaの0°曲げ強度、
c)ASTM D790で測定した場合に少なくとも95GPaの0°曲げ弾性率、
d)ASTM D3039で測定した場合に少なくとも1400MPaの0°引張強度、又は
e)ASTM D3039で測定した場合に少なくとも110GPaの0°引張弾性率
のうちの少なくとも1つを有している、上記項目20~22のいずれかに記載のプリプレグ。
[24].
上記項目20~23のいずれかに記載の硬化プリプレグの1つ以上の層を含み、任意選択で他の材料の1つ以上の層をさらに含む層状構造物。
[25].
好ましくはシート又はその部品、例えば、シートパン、シートバック又はシートレストである、航空機の部材としての上記項目24に記載の層状構造物の使用。
[26].
硬化プリプレグを含む航空機部材であって、前記プリプレグのマトリックスが上記項目1~18のいずれかに記載の配合物を含み、好ましくは前記硬化プリプレグがガラス繊維及び/又は炭素繊維を含む、航空機部材。
Claims (26)
- 配合物であって、
a.配合物の10~80重量%を占めるハロゲン化エポキシ樹脂であって、塩素化エポキシ樹脂を含むハロゲン化エポキシ樹脂、
b.配合物の1~15重量%を占めるアンチモンベースの難燃剤、
c.配合物の1~10重量%を占める無機又は非ポリマー有機リン含有難燃剤、及び
d.配合物の1~30重量%を占める硬化剤系
を含み、
配合物の5~30重量%を占めるエポキシノボラック樹脂を更に含み、及び
配合物の1~40重量%を占める1つ以上のビスフェノールエポキシ樹脂を更に含む
配合物。 - 前記ハロゲン化エポキシ樹脂が、塩素化エポキシ樹脂又は塩素化エポキシ樹脂と臭素化エポキシ樹脂との混合物を含み、前記塩素化エポキシ樹脂が、塩素化ビスフェノール-Cエポキシ樹脂を含む、請求項1に記載の配合物。
- 前記アンチモンベースの難燃剤が、三酸化アンチモン、五酸化アンチモン、又はそれらの混合物を含む、請求項1又は請求項2に記載の配合物。
- 前記無機又は非ポリマー有機リン含有難燃剤が、赤色リン、ポリリン酸アンモニウム、ポリホスファゼン、リン酸メラミン(ポリホスファート及びピロホスファートを含む)又はそれらの混合物を含む、請求項1~3のいずれかに記載の配合物。
- さらに有機ポリマー又はオリゴマーリン含有難燃剤を前記配合物の4~35重量%の割合で含む、請求項1~4のいずれかに記載の配合物。
- さらに配合物の1~40重量%の割合で煙抑制剤を含む、請求項1~5のいずれかに記載の配合物。
- 前記エポキシノボラック樹脂が、フェノールエポキシノボラック樹脂、クレゾールエポキシノボラック樹脂、トリスフェニルメタンエポキシノボラック樹脂又はそれらの混合物を含む、請求項1~6のいずれかに記載の配合物。
- 追加の前記1つ以上のビスフェノールエポキシ樹脂が、ビスフェノールAのジグリシジルエーテル、ビスフェノールFのジグリシジルエーテル、多官能性エポキシ樹脂又はそれらの混合物を含む、請求項1~7のいずれかに記載の配合物。
- 前記硬化剤系がヒドラジド又はジシアンジアミドを含む、請求項1~8のいずれかに記載の配合物。
- 前記硬化剤系が、前記硬化剤系のための促進剤を含む、請求項1~9のいずれかに記載の配合物。
- さらに0.05~1.5重量%の割合で湿潤剤を含む、請求項1~10のいずれかに記載の配合物。
- 前記エポキシ樹脂の全成分及び任意の熱可塑性強化剤の合計と、前記無機リン、アンチモン及び任意の煙抑制剤成分の合計との重量比が10:1~1:1である、請求項1~11のいずれかに記載の配合物。
- a.前記配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.前記配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.前記配合物の3~20重量%を占める硬化剤系;
d.前記配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.前記配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.前記配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.前記配合物の1~10重量%を占める1つ以上の熱可塑性強化剤;
h.前記配合物の2~38重量%を占める煙抑制剤;
i.0.05~1.5重量%の湿潤剤、及び
j.前記ハロゲン化エポキシ樹脂に加えて前記配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む、請求項1に記載の配合物。 - a.前記配合物の15~60重量%を占めるハロゲン化エポキシ樹脂;
b.前記配合物の5~30重量%を占める有機ポリマー又はオリゴマーリン含有難燃剤;
c.前記配合物の3~20重量%を占める硬化剤系;
d.前記配合物の1.5~12重量%を占めるアンチモンベースの難燃剤;
e.前記配合物の1.5~7.5重量%を占める無機又は非ポリマー有機リン含有難燃剤;
f.前記配合物の6~25重量%を占めるエポキシノボラック樹脂;
g.前記配合物の2~38重量%を占める煙抑制剤;
h.0.05~1.5重量%の湿潤剤、及び
i.前記ハロゲン化エポキシ樹脂に加えて前記配合物の5~35重量%を占める1つ以上のビスフェノールエポキシ樹脂
を含む、請求項1に記載の配合物。 - 前記配合物が、2℃/分の昇温を使用するオートクレーブ硬化下において、140℃で30分以下及び150℃で15分以下で硬化可能である、請求項1~14のいずれかに記載の配合物。
- 前記配合物が、160℃及び最大7バールの圧力でホットロード/ホットアンロードプレス硬化を使用して15分以内に硬化可能である、請求項1~15のいずれかに記載の配合物。
- 少なくとも145℃の硬化乾燥Tgを有する、請求項1~16のいずれかに記載の配合物。
- 110℃で10Pa・s以下の粘度を有する、請求項1~17のいずれかに記載の配合物。
- プリプレグ中のマトリックスとしての、請求項1~18のいずれかに記載の配合物の使用。
- 強化繊維及び請求項1~18のいずれかに記載の配合物を含むプリプレグ。
- 前記強化繊維がガラス繊維及び/又は炭素繊維である、請求項20に記載のプリプレグ。
- 請求項1~18のいずれかに記載の配合物をプリプレグの25~70重量%の割合で含む、請求項20又は請求項21に記載のプリプレグ。
- 前記強化繊維が炭素であり、硬化後、以下の特性:
a)ASTM D2344で測定した場合に少なくとも50MPaの層間せん断強度(ILSS)、
b)ASTM D790で測定した場合に少なくとも1100MPaの0°曲げ強度、
c)ASTM D790で測定した場合に少なくとも95GPaの0°曲げ弾性率、
d)ASTM D3039で測定した場合に少なくとも1400MPaの0°引張強度、又は
e)ASTM D3039で測定した場合に少なくとも110GPaの0°引張弾性率
のうちの少なくとも1つを有している、請求項20~22のいずれかに記載のプリプレグ。 - 請求項20~23のいずれかに記載の硬化プリプレグの1つ以上の層を含み、任意選択で他の材料の1つ以上の層をさらに含む層状構造物。
- 航空機の部材としての請求項24に記載の層状構造物の使用。
- 硬化プリプレグを含む航空機部材であって、前記プリプレグのマトリックスが請求項1~18のいずれかに記載の配合物を含む、航空機部材。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000063485A (ja) | 1998-08-20 | 2000-02-29 | Asahi Denka Kogyo Kk | 硬化性組成物 |
JP2009096881A (ja) | 2007-10-17 | 2009-05-07 | Toray Ind Inc | 樹脂組成物およびそれからなる成形品 |
JP2016510077A (ja) | 2013-02-13 | 2016-04-04 | ヘクセル コンポジッツ、リミテッド | 難燃性エポキシ樹脂配合物およびその使用 |
CN106398110A (zh) | 2016-09-13 | 2017-02-15 | 抚州市龙兴电子材料有限公司 | 一种覆铜板用胶液、复合基cem‑1覆铜板及其制备方法 |
JP2023036020A (ja) | 2021-08-31 | 2023-03-13 | 三菱ケミカル株式会社 | ビスフェノールc型ジグリシジルエーテル、硬化性組成物、硬化物及び電気・電子部品 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1444091A1 (de) * | 1961-05-04 | 1968-10-17 | Minnesota Mining & Mfg | Blattmaterial |
JPS592446B2 (ja) * | 1979-01-09 | 1984-01-18 | 東レ株式会社 | 炭素繊維強化用難燃性エポキシ樹脂組成物 |
TW203081B (ja) * | 1991-10-09 | 1993-04-01 | Gen Electric | |
US5863974A (en) * | 1997-01-28 | 1999-01-26 | General Electric Company | Flame retardant polyamide composition |
JP5485487B2 (ja) * | 1999-12-13 | 2014-05-07 | ダウ グローバル テクノロジーズ エルエルシー | 難燃性リン元素含有エポキシ樹脂組成物 |
US7255927B2 (en) * | 2001-12-05 | 2007-08-14 | Isola Usa Corp. | Laminate composition |
WO2003048251A1 (en) * | 2001-12-05 | 2003-06-12 | Isola Laminate Systems Corp. | Prepreg and composition of epoxy resin(s), sma copolymers(s) and bis-maleimide triazine resin(s) |
BRPI0621068A2 (pt) * | 2005-12-22 | 2011-11-29 | Dow Global Technologies Inc | composição de resina epóxi contendo halogênio curável, artigo compósito reforçado com fibra, componente de circuito elétrico, processo para produzir um artigo revestido, pré-impregnado, laminado, placa de circuito impresso (pcb), processo para preparar um artigo revestido com resina, e artigo revestido com resina |
JPWO2008136096A1 (ja) | 2007-04-24 | 2010-07-29 | パナソニック電工株式会社 | ハロゲンフリーエポキシ樹脂組成物、カバーレイフィルム、ボンディングシート、プリプレグ、プリント配線板用積層板 |
TW200900446A (en) | 2007-06-22 | 2009-01-01 | Advanced Int Multitech Co Ltd | Flame resistant prepreg |
GB2472423B (en) | 2009-08-05 | 2012-01-11 | Gurit Uk Ltd | Fire-retardant composite materials |
JP5482253B2 (ja) * | 2010-02-03 | 2014-05-07 | 東レ株式会社 | 難燃性スチレン系熱可塑性樹脂組成物およびその成形体 |
CN102850733B (zh) * | 2011-06-29 | 2015-05-20 | 合肥杰事杰新材料股份有限公司 | 一种聚对苯二甲酸丁二酯组合物及其制备方法 |
CN104231527A (zh) * | 2014-08-28 | 2014-12-24 | 天津市利顺塑料制品有限公司 | 一种抗静电阻燃abs塑料 |
CN104327467B (zh) * | 2014-11-21 | 2016-06-08 | 古道尔工程塑胶(深圳)有限公司 | 一种膨胀型高灼热丝点燃温度pbt复合材料及其制备方法 |
US9534108B2 (en) * | 2015-03-13 | 2017-01-03 | Chemtura Corporation | Flame retardant epoxy resins comprising phosphorus containing flame retardants |
CN106674788A (zh) * | 2016-12-05 | 2017-05-17 | 天津金发新材料有限公司 | 一种阻燃热塑性弹性体合金材料及其制备方法 |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000063485A (ja) | 1998-08-20 | 2000-02-29 | Asahi Denka Kogyo Kk | 硬化性組成物 |
JP2009096881A (ja) | 2007-10-17 | 2009-05-07 | Toray Ind Inc | 樹脂組成物およびそれからなる成形品 |
JP2016510077A (ja) | 2013-02-13 | 2016-04-04 | ヘクセル コンポジッツ、リミテッド | 難燃性エポキシ樹脂配合物およびその使用 |
CN106398110A (zh) | 2016-09-13 | 2017-02-15 | 抚州市龙兴电子材料有限公司 | 一种覆铜板用胶液、复合基cem‑1覆铜板及其制备方法 |
JP2023036020A (ja) | 2021-08-31 | 2023-03-13 | 三菱ケミカル株式会社 | ビスフェノールc型ジグリシジルエーテル、硬化性組成物、硬化物及び電気・電子部品 |
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