JP7399946B2 - 膨張層を備える電池 - Google Patents
膨張層を備える電池 Download PDFInfo
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- JP7399946B2 JP7399946B2 JP2021510866A JP2021510866A JP7399946B2 JP 7399946 B2 JP7399946 B2 JP 7399946B2 JP 2021510866 A JP2021510866 A JP 2021510866A JP 2021510866 A JP2021510866 A JP 2021510866A JP 7399946 B2 JP7399946 B2 JP 7399946B2
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- 239000000203 mixture Substances 0.000 claims description 104
- 238000000576 coating method Methods 0.000 claims description 61
- 239000011248 coating agent Substances 0.000 claims description 60
- 229920005989 resin Polymers 0.000 claims description 59
- 239000011347 resin Substances 0.000 claims description 59
- 150000001875 compounds Chemical class 0.000 claims description 58
- 229920000647 polyepoxide Polymers 0.000 claims description 45
- -1 poly(amine amide Chemical class 0.000 claims description 42
- 239000002253 acid Substances 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- 239000007787 solid Substances 0.000 claims description 30
- 229910001416 lithium ion Inorganic materials 0.000 claims description 29
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 23
- 229920000768 polyamine Polymers 0.000 claims description 23
- 239000003822 epoxy resin Substances 0.000 claims description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011574 phosphorus Substances 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- 229920000877 Melamine resin Polymers 0.000 claims description 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 13
- 150000001412 amines Chemical class 0.000 claims description 13
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 12
- 238000000197 pyrolysis Methods 0.000 claims description 11
- 230000008961 swelling Effects 0.000 claims description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 10
- 239000004327 boric acid Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 8
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 150000001408 amides Chemical class 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 5
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 5
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 5
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 4
- LWFBRHSTNWMMGN-UHFFFAOYSA-N 4-phenylpyrrolidin-1-ium-2-carboxylic acid;chloride Chemical compound Cl.C1NC(C(=O)O)CC1C1=CC=CC=C1 LWFBRHSTNWMMGN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004471 Glycine Substances 0.000 claims description 4
- MGJKQDOBUOMPEZ-UHFFFAOYSA-N N,N'-dimethylurea Chemical compound CNC(=O)NC MGJKQDOBUOMPEZ-UHFFFAOYSA-N 0.000 claims description 4
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 4
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 4
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 4
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- 239000001095 magnesium carbonate Substances 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- OTRAYOBSWCVTIN-UHFFFAOYSA-N OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N Chemical compound OB(O)O.OB(O)O.OB(O)O.OB(O)O.OB(O)O.N.N.N.N.N.N.N.N.N.N.N.N.N.N.N OTRAYOBSWCVTIN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052810 boron oxide Inorganic materials 0.000 claims description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 2
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 claims description 2
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims description 2
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims 1
- 239000006012 monoammonium phosphate Substances 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 38
- 125000000524 functional group Chemical group 0.000 description 36
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 35
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 33
- 239000003981 vehicle Substances 0.000 description 31
- 239000004593 Epoxy Substances 0.000 description 29
- 239000010410 layer Substances 0.000 description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 22
- 150000007513 acids Chemical class 0.000 description 20
- 229920000178 Acrylic resin Polymers 0.000 description 18
- 239000004925 Acrylic resin Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 17
- 229920000728 polyester Polymers 0.000 description 17
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- 229920005862 polyol Polymers 0.000 description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 150000003077 polyols Chemical class 0.000 description 12
- 150000003573 thiols Chemical class 0.000 description 12
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 11
- 239000008199 coating composition Substances 0.000 description 11
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- 239000000758 substrate Substances 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 10
- 229920002554 vinyl polymer Polymers 0.000 description 10
- 150000008064 anhydrides Chemical class 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
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- 229930195729 fatty acid Natural products 0.000 description 8
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 239000004952 Polyamide Substances 0.000 description 7
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
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- 239000005056 polyisocyanate Substances 0.000 description 7
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- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
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- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
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- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000008733 trauma Effects 0.000 description 1
- LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- MDCWDBMBZLORER-UHFFFAOYSA-N triphenyl borate Chemical compound C=1C=CC=CC=1OB(OC=1C=CC=CC=1)OC1=CC=CC=C1 MDCWDBMBZLORER-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 235000016804 zinc Nutrition 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/14—Primary casings; Jackets or wrappings for protecting against damage caused by external factors
- H01M50/143—Fireproof; Explosion-proof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/233—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions
- H01M50/24—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
- H01M10/625—Vehicles
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/07—Fire prevention, containment or extinguishing specially adapted for particular objects or places in vehicles, e.g. in road vehicles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K1/00—Arrangement or mounting of electrical propulsion units
- B60K1/04—Arrangement or mounting of electrical propulsion units of the electric storage means for propulsion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D25/00—Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
- B62D25/20—Floors or bottom sub-units
- B62D25/2009—Floors or bottom sub-units in connection with other superstructure subunits
- B62D25/2045—Floors or bottom sub-units in connection with other superstructure subunits the subunits being fire walls
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
- H01M10/623—Portable devices, e.g. mobile telephones, cameras or pacemakers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/658—Means for temperature control structurally associated with the cells by thermal insulation or shielding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/247—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for portable devices, e.g. mobile phones, computers, hand tools or pacemakers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/249—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders specially adapted for aircraft or vehicles, e.g. cars or trains
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
- B60K1/00—Arrangement or mounting of electrical propulsion units
- B60K1/04—Arrangement or mounting of electrical propulsion units of the electric storage means for propulsion
- B60K2001/0405—Arrangement or mounting of electrical propulsion units of the electric storage means for propulsion characterised by their position
- B60K2001/0438—Arrangement under the floor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
- H01M2200/10—Temperature sensitive devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biophysics (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Transportation (AREA)
- Combustion & Propulsion (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- Health & Medical Sciences (AREA)
- Computer Hardware Design (AREA)
- Aviation & Aerospace Engineering (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cell Separators (AREA)
- Battery Mounting, Suspending (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Description
(a)複数の官能基を有する1つ以上のオリゴマーまたはポリマー化合物を含む樹脂成分と、
(b)任意選択的に、樹脂成分(a)のオリゴマーまたはポリマー化合物の官能基と反応性である複数の官能基を有する硬化剤と、
(c)熱分解時に膨張ガスを提供する化合物と、を含む、硬化性膨張組成物から形成され、化合物(a)~(c)は、互いに異なる。
(a)複数の官能基を有する1つ以上のオリゴマーまたはポリマー化合物を含む樹脂成分と、
(b)任意選択的に、樹脂成分(a)のオリゴマーまたはポリマー化合物の官能基と反応性である複数の官能基を有する硬化剤と、
(c)熱分解時に膨張ガスを提供する化合物と、を含む硬化性膨張組成物から形成され、化合物(a)~(c)が、互いに異なる、層を備える。
本発明で使用される複数の官能基を保有するオリゴマーまたはポリマー化合物は、特に限定されず、それには、エポキシ樹脂、アクリル樹脂、ポリシロキサン、ポリウレタン、ポリ尿素、ポリビニル、フェノール樹脂、尿素-ホルムアルデヒド樹脂、ポリイミド、メラミン樹脂、ポリエステル樹脂、およびシアネート樹脂が含まれるがこれらに限定されない。これらの樹脂の中では、エポキシ樹脂、アクリル樹脂、および/またはポリウレタン樹脂が特に好適である。
-エチレン系不飽和ニトリル化合物、
-ビニル芳香族モノマー、
-エチレン系不飽和酸のアルキルエステル、
-エチレン系不飽和酸のヒドロキシアルキルエステル、
-エチレン系不飽和酸のアミド、
-エチレン系不飽和酸、
-エチレン系不飽和スルホン酸モノマーおよび/またはエチレン系不飽和リン含有酸モノマー、
-ビニルカルボキシレート、
-共役ジエン、
-少なくとも2つのエチレン系不飽和基を有するモノマー、および
-それらの組み合わせ、から選択することができる。
(i)(メタ)アクリル酸のベータ-ヒドロキシエステル、
(ii)化合物(i)とは異なる(メタ)アクリレート官能性化合物、またはそれらの組み合わせ、をさらに含み得る。
本発明による硬化性膨張組成物で使用される硬化剤には、樹脂成分(a)のオリゴマーまたはポリマー化合物の官能基と反応して、それを硬化させることができる限り、特に制限はない。好適な硬化剤には、ポリアミン、例えば、ポリエーテルアミン、ポリアミド、ポリエポキシド、アミノプラスト樹脂、フェノール樹脂、ポリイソシアネート、ポリチオール、およびポリオールなどが含まれる。硬化は、周囲温度または熱の適用時のいずれかで行うことができる。
(a)複数の官能基を有する1つ以上のオリゴマーまたはポリマー化合物を含む樹脂成分と、
(b)任意選択的に、樹脂成分(a)のオリゴマーまたはポリマー化合物の官能基と反応性である複数の官能基を有する硬化剤と、
(c)熱分解時に膨張ガスを提供する化合物と、を含む、硬化性膨張組成物から形成され、
化合物(a)~(c)が、互いに異なる、電池。
-脂肪族ポリアミン、芳香族ポリアミン、ポリ(アミンアミド)ポリエーテルアミン、およびそれらの組み合わせから選択され得るポリアミン官能性化合物、もしくは
-ポリスルフィドチオール、ポリエーテルチオール、ポリエステルチオール、ペンタエリスリトール系チオール、およびそれらの組み合わせから選択され得るポリチオール官能性化合物、または
-それらの組み合わせ、を含む、態様1~6のいずれかに記載の電池。
(i)(メタ)アクリル酸のベータ-ヒドロキシエステル、
(ii)化合物(i)とは異なる(メタ)アクリレート官能性化合物、またはそれらの組み合わせ、をさらに含む、態様7~11のいずれかに記載の電池。
-樹脂成分(a)の総量が、組成物の総固体重量に基づいて、10~40重量%であり、
-硬化剤(b)の総量が、組成物の総固体重量に基づいて、10~30重量%であり、
-熱分解時に膨張ガスを提供する化合物(c)の総重量が、組成物の総固体重量に基づいて、0.1~25重量%であり、
-存在する場合、リン源の総量が、組成物の総固体重量に基づいて、0.05~20重量%であり、
-存在する場合、亜鉛源の総量が、組成物の総固体重量に基づいて、0.1~25重量%であり、
-存在する場合、ホウ素源の総量が、組成物の総固体重量に基づいて、0.1~10重量%であり、
-存在する場合、酸源の総量が、組成物の総固体重量に基づいて、5~30重量%である、態様1~15のいずれかに記載の電池。
エポキシ系樹脂パックであるPittchar(登録商標)XP成分A、ならびにポリアミン硬化剤およびガス源としてメラミンを含有する硬化パックであるPittchar(登録商標)XP成分Bの両方は、PPG Industries Pittsburg PAから市販されており、それぞれ、75重量%および25重量%の量で混合した。混合物を、Graco Plural成分噴霧機を使用して、新鮮なサンドブラスト鋼板(厚さ=5mm、サイズ15.24cm×15.24cm、SA2.5)に噴霧し、23℃で最短7日間硬化させた。硬化コーティングの乾燥コーティング厚さは、5mmであった。
鋼板の寸法が、25.4cm×25.4cmであり、1、2、および5mmの硬化コーティングの様々な乾燥コーティング厚さで手ブラシによって、コーティング組成物を適用したことを除いて、実施例1を繰り返した。
実施例1の膨張コーティング組成物(厚さ=1、2、および5mm)の遊離フィルムを、矩形成形型(ポリプロピレンシートから切断)を使用して鋳造し、23℃で7日間硬化させた。フィルム剥離後、片面に裏打ちされた市販の接着フィルム(3M 950転写テープ)を各フィルムの裏面上に適用した。試料を鋼板サイズ(15.24cm×15.24cm)に切断し、その後ライナーを剥離し、膨張コーティングを鋼基材(鋼板:厚さ5mm、サイズ15.24cm×15.24cm)に押し付けた。
典型的にはリチウムイオン電池(3/7w/wエチレンカーボネート/メチルエチルカーボネート中1.2MのLi+OH-)で使用される燃焼液体電解質によって、プロパントーチを置き換えたことを除いて、実施例1を繰り返した。炎温度は、650℃前後であった。
エポキシ系樹脂パックおよびガス源としてのメラミンであるSteelguard(登録商標)951成分A、ならびにポリアミン硬化剤を含有する硬化パックであるSteelguard(登録商標)951成分Bの両方は、PPG Industries Pittsburg PAから市販されており、それぞれ、45重量%および55重量%の量で混合した。混合物を、Graco Plural成分噴霧機を使用して、アルミパネル(厚さ=0.64mm、サイズ7.5cm×15.1cm)に噴霧し、23℃で最短7日間硬化させた。硬化コーティングの乾燥コーティング厚さは、0.18mmであった。
以下の寸法を有する鋼板を使用した(厚さ=5mm、サイズ25cm×25cm)ことを除いて、実施例5を繰り返した。コーティング組成物をハンドブラシによって鋼板に適用し、23℃で最短7日間乾燥させた。硬化コーティングの様々な乾燥コーティング厚さ(1、2、および6mm)を観察した。
本発明の好ましい実施形態によれば、例えば、以下が提供される。
(項1)
コーティングおよび自己支持フィルムまたはシートから選択される架橋した膨張層を備える電池であって、前記層が、
(a)複数の官能基を有する1つ以上のオリゴマーまたはポリマー化合物を含む樹脂成分と、
(b)任意に、樹脂成分(a)の前記オリゴマーまたはポリマー化合物の前記官能基と反応性である複数の官能基を有する硬化剤と、
(c)熱分解時に膨張ガスを提供する化合物と、を含む、硬化性膨張組成物から形成され、
化合物(a)~(c)が、互いに異なる、電池。
(項2)
前記樹脂成分(a)が、1つ以上のエポキシ樹脂、ポリシロキサン樹脂、アクリル樹脂、ポリウレタン樹脂、ポリ尿素樹脂、ポリビニル樹脂、フェノール樹脂、尿素ホルムアルデヒド樹脂、ポリイミド樹脂、メラミン樹脂、ポリエステル樹脂、およびシアネート樹脂を含む、上記項1に記載の電池。
(項3)
前記樹脂成分(a)の前記官能基が、エポキシ、アミン、ビニル、アミド、カルバメート、尿素、メルカプタン、カルボン酸、(メタ)アクリロイル、イソシアネート、アルコキシシリル、無水物、ヒドロキシル、アルコキシ基、互いと反応することが可能である官能基、およびそれらの組み合わせから選択される、上記項1または2に記載の電池。
(項4)
互いと反応することが可能である前記官能基が、N-メチロールアミド基、シリコン結合加水分解性または縮合性基を有するシラン基、エチレン系不飽和脂肪酸基、アゾメチン基、アゼチジン基、熱可逆性Diels-Alder反応が可能である基から選択される、上記項3に記載の電池。
(項5)
前記樹脂化合物(a)が、エポキシ樹脂を含み、前記硬化剤(b)が、必須であり、かつ
-脂肪族ポリアミン、芳香族ポリアミン、ポリ(アミンアミド)ポリエーテルアミン、およびそれらの組み合わせから選択され得るポリアミン官能性化合物、もしくは
-ポリスルフィドチオール、ポリエーテルチオール、ポリエステルチオール、ペンタエリスリトール系チオール、およびそれらの組み合わせから選択され得るポリチオール官能性化合物、または
-それらの組み合わせ、を含む、上記項1~4のいずれかに記載の電池。
(項6)
熱分解時に膨張ガスを提供する前記化合物(c)が、メラミン、リン酸のアンモニウム塩、グアニジン、メチロール化メラミン、ヘキサメトキシメチルメラミン、尿素、ジメチル尿素、ピロリン酸メラミン、ジシアンジアミド、グアニル尿素リン酸塩、グリシン、炭酸カルシウム、炭酸マグネシウム、水酸化カルシウム、二水酸化マグネシウム、三水酸化アルミニウム、ホウ酸、およびホウ酸エステルから選択される、上記項1~5のいずれかに記載の電池。
(項7)
リン源、ホウ素源、亜鉛源、酸源、および任意に、炭素源の組み合わせを含む添加剤(d)をさらに含み、それによって、単一の材料が、定義された要素のうちの2つ以上の源であり得る、上記項1~6のいずれかに記載の電池。
(項8)
-樹脂成分(a)の総量が、前記組成物の総固体重量に基づいて、10~40重量%であり、
-硬化剤(b)の総量が、前記組成物の総固体重量に基づいて、10~30重量%であり、
-熱分解時に膨張ガスを提供する前記化合物(c)の総重量が、前記組成物の総固体重量に基づいて、0.1~25重量%であり、
-存在する場合、リン源の総量が、前記組成物の総固体重量に基づいて、0.05~20重量%であり、
-存在する場合、亜鉛源の総量が、前記組成物の総固体重量に基づいて、0.1~25重量%であり、
-存在する場合、ホウ素源の総量が、前記組成物の総固体重量に基づいて、0.1~10重量%であり、
-存在する場合、酸源の総量が、前記組成物の総固体重量に基づいて、5~30重量%である、上記項1~7のいずれかに記載の電池。
(項9)
ハウジングを画定する外壁要素と、任意に、内壁要素と、をさらに備え、前記架橋した膨張層が、存在する場合、少なくとも部分的に、前記外壁要素のいずれかの外側および/もしくは内側に、かつ/または前記内壁要素のいずれかの任意の側面に適用される、上記項1~8のいずれかに記載の電池。
(項10)
前記電池が、リチウムイオン電池である、上記項1~9のいずれかに記載の電池。
(項11)
電池を備える物品であって、上記項1~8のいずれかに記載の架橋した膨張層が、前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用され、好ましくは、前記物品が、リチウムイオン電池および乗客キャビンを備える車両であり、前記架橋した膨張層が、前記電池と前記車両本体との間の前記電池に隣接する前記車両の床の少なくとも一部に適用される、物品。
(項12)
上記項1~8のいずれかに記載の硬化性膨張組成物の使用であって、前記電池の任意の部分に適用されるときに電池に対する防火を提供するため、かつ/もしくは電池の熱暴走を低減もしくは防止するため、または前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用されるときに電池を備える物品に対する防火を提供するための、使用。
(項13)
-上記項1~8のいずれかに記載の硬化性膨張組成物を前記電池の任意の部分に適用して、その上にコーティングを形成し、かつ前記コーティングを硬化してその上に架橋した膨張コーティングを得ること、あるいは
-上記項1~8のいずれかに記載の硬化性膨張組成物を膨張自己支持フィルムまたはシートに形成し、前記架橋した膨張自己支持フィルムまたはシートを電池に適用し、かつ電池への前記適用の前または後に前記膨張自己支持フィルムまたはシートを硬化させること、によって、電池への防火を提供する、または電池の熱暴走を低減もしくは防止する方法。
(項14)
-上記項1~8のいずれかに記載の硬化性膨張組成物を前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用して、その上にコーティングを形成し、かつ前記コーティングを硬化してその上に架橋した膨張コーティングを得ること、あるいは
-上記項1~8のいずれかに記載の硬化性膨張組成物を膨張自己支持フィルムまたはシートに形成し、前記膨張自己支持フィルムまたはシートを前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用し、かつ前記物品の前記一部への前記適用の前または後に前記膨張自己支持フィルムまたはシートを硬化させること、によって、電池を備える物品に対する防火を提供する方法。
(項15)
前記物品が、リチウムイオン電池および乗客キャビンを備える車両であり、前記架橋した膨張コーティングが、電池火災から前記車両の前記乗客キャビンを保護するように位置付けられる、上記項14に記載の方法。
Claims (12)
- コーティングおよび自己支持フィルムまたはシートから選択される架橋した膨張層を備える電池であって、前記層が、
(a)樹脂成分であって、ここで、前記樹脂成分(a)が、エポキシ樹脂を含む、樹脂成分と、
(b)硬化剤であって、ここで、前記硬化剤(b)は、脂肪族ポリアミン、芳香族ポリアミン、ポリ(アミンアミド)ポリエーテルアミンおよびそれらの組み合わせから選択され得るポリアミン官能性化合物を含む、硬化剤と、
(c)熱分解時に膨張ガスを提供する化合物と、を含む、硬化性膨張組成物から形成され、
化合物(a)~(c)が、互いに異なり、
ここで、
-樹脂成分(a)の総量が、前記組成物の総固体重量に基づいて、10~40重量%であり、
-硬化剤(b)の総量が、前記組成物の総固体重量に基づいて、10~30重量%であり、
-熱分解時に膨張ガスを提供する前記化合物(c)の総重量が、前記組成物の総固体重量に基づいて、0.1~25重量%である、
電池。 - 熱分解時に膨張ガスを提供する前記化合物(c)が、メラミン、リン酸のアンモニウム塩、グアニジン、メチロール化メラミン、ヘキサメトキシメチルメラミン、尿素、ジメチル尿素、ピロリン酸メラミン、ジシアンジアミド、グアニル尿素リン酸塩、グリシン、炭酸カルシウム、炭酸マグネシウム、水酸化カルシウム、二水酸化マグネシウム、三水酸化アルミニウム、ホウ酸、およびホウ酸エステルから選択される、請求項1に記載の電池。
- リン源、ホウ素源、亜鉛源、酸源、および任意に、炭素源の組み合わせを含む添加剤(d)をさらに含み、それによって、単一の材料が、定義された要素のうちの2つ以上の源であり得る、請求項1~2のいずれかに記載の電池。
- -存在する場合、リン源の総量が、前記組成物の総固体重量に基づいて、0.05~20重量%であり、ここで、前記リン源は、リン酸、リン酸モノアンモニウム、リン酸ジアンモニウム、リン酸トリス(2-クロロエチル)、リン含有アミド、ピロリン酸メラミン、またはそれらの組み合わせを含み;
-存在する場合、亜鉛源の総量が、前記組成物の総固体重量に基づいて、0.1~25重量%であり、
-存在する場合、ホウ素源の総量が、前記組成物の総固体重量に基づいて、0.1~10重量%であり、ここで、前記ホウ素源は、五ホウ酸アンモニウム、酸化ホウ素、ホウ酸ナトリウム、ホウ酸カリウム、ホウ酸アンモニウム、ホウ酸エステル、またはそれらの組み合わせを含み、
-存在する場合、酸源の総量が、前記組成物の総固体重量に基づいて、5~30重量%であり、ここで、前記酸源は、リン酸生成材料、ホウ酸、またはそれらの組み合わせを含む、請求項1~3のいずれかに記載の電池。 - ハウジングを画定する外壁要素と、任意に、内壁要素と、をさらに備え、前記架橋した膨張層が、少なくとも部分的に、前記外壁要素のいずれかの外側および/もしくは内側に適用されるか、あるいは、前記内壁要素が存在する場合に、前記架橋した膨張層が、少なくとも部分的に、前記外壁要素のいずれかの外側および/もしくは内側に、かつ/または前記内壁要素のいずれかの任意の側面に適用される、請求項1~4のいずれかに記載の電池。
- 前記電池が、リチウムイオン電池である、請求項1~5のいずれかに記載の電池。
- 電池を備える物品であって、請求項1~4のいずれかに記載の架橋した膨張層が、前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用される、物品。
- 前記物品が、リチウムイオン電池および乗客キャビンを備える車両であり、前記架橋した膨張層が、前記電池と前記車両本体との間の前記電池に隣接する前記車両の床の少なくとも一部に適用される、請求項7に記載の物品。
- 請求項1~4のいずれかに記載の硬化性膨張組成物の使用であって、前記電池の任意の部分に適用されるときに電池に対する防火を提供するため、かつ/もしくは電池の熱暴走を低減もしくは防止するため、または前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用されるときに電池を備える物品に対する防火を提供するための、使用。
- -請求項1~4のいずれかに記載の硬化性膨張組成物を前記電池の任意の部分に適用して、その上にコーティングを形成し、かつ前記コーティングを硬化してその上に架橋した膨張コーティングを得ること、あるいは
-請求項1~4のいずれかに記載の硬化性膨張組成物を膨張自己支持フィルムまたはシートに形成し、前記架橋した膨張自己支持フィルムまたはシートを電池に適用し、かつ電池への前記適用の前または後に前記膨張自己支持フィルムまたはシートを硬化させること、によって、電池への防火を提供する、または電池の熱暴走を低減もしくは防止する方法。 - -請求項1~4のいずれかに記載の硬化性膨張組成物を前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用して、その上にコーティングを形成し、かつ前記コーティングを硬化してその上に架橋した膨張コーティングを得ること、あるいは
-請求項1~4のいずれかに記載の硬化性膨張組成物を膨張自己支持フィルムまたはシートに形成し、前記膨張自己支持フィルムまたはシートを前記電池と前記物品との間の前記電池に隣接する前記物品の一部に適用し、かつ前記物品の前記一部への前記適用の前または後に前記膨張自己支持フィルムまたはシートを硬化させること、によって、電池を備える物品に対する防火を提供する方法。 - 前記物品が、リチウムイオン電池および乗客キャビンを備える車両であり、前記架橋した膨張コーティングが、電池火災から前記車両の前記乗客キャビンを保護するように位置付けられる、請求項11に記載の方法。
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KR102629554B1 (ko) * | 2021-06-18 | 2024-01-26 | 진양오토모티브 (주) | 세이프티 패드 그리고, 이를 구비하는 배터리셀 및 배터리모듈 |
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RU2764294C1 (ru) | 2022-01-17 |
MX2021002419A (es) | 2021-06-15 |
TWI783168B (zh) | 2022-11-11 |
WO2020047059A1 (en) | 2020-03-05 |
CN112930386A (zh) | 2021-06-08 |
KR20210047347A (ko) | 2021-04-29 |
CA3110512A1 (en) | 2020-03-05 |
SG11202101846UA (en) | 2021-03-30 |
EP3844825A1 (en) | 2021-07-07 |
TW202017228A (zh) | 2020-05-01 |
BR112021003777A2 (pt) | 2021-05-18 |
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US20210218094A1 (en) | 2021-07-15 |
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