JP7322350B2 - Fe系ナノ結晶粒合金及びこれを用いた電子部品 - Google Patents
Fe系ナノ結晶粒合金及びこれを用いた電子部品 Download PDFInfo
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- 229910045601 alloy Inorganic materials 0.000 title claims description 44
- 239000000956 alloy Substances 0.000 title claims description 44
- 230000005291 magnetic effect Effects 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 26
- 230000004907 flux Effects 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 239000006249 magnetic particle Substances 0.000 claims description 12
- 239000003566 sealing material Substances 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000012212 insulator Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 44
- 235000013339 cereals Nutrition 0.000 description 22
- 239000010955 niobium Substances 0.000 description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 239000010949 copper Substances 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000696 magnetic material Substances 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002159 nanocrystal Substances 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 229910052732 germanium Inorganic materials 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- 238000007709 nanocrystallization Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15308—Amorphous metallic alloys, e.g. glassy metals based on Fe/Ni
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15333—Amorphous metallic alloys, e.g. glassy metals containing nanocrystallites, e.g. obtained by annealing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/0006—Printed inductances
- H01F17/0013—Printed inductances with stacked layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/04—Fixed inductances of the signal type with magnetic core
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/28—Coils; Windings; Conductive connections
- H01F27/29—Terminals; Tapping arrangements for signal inductances
- H01F27/292—Surface mounted devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F3/00—Cores, Yokes, or armatures
- H01F3/08—Cores, Yokes, or armatures made from powder
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2200/00—Crystalline structure
- C22C2200/02—Amorphous
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2200/00—Crystalline structure
- C22C2200/04—Nanocrystalline
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F17/00—Fixed inductances of the signal type
- H01F17/04—Fixed inductances of the signal type with magnetic core
- H01F2017/048—Fixed inductances of the signal type with magnetic core with encapsulating core, e.g. made of resin and magnetic powder
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Soft Magnetic Materials (AREA)
- Powder Metallurgy (AREA)
- Coils Or Transformers For Communication (AREA)
Description
以下、本発明の一実施形態による電子部品について説明する。代表的な例としてコイル部品を選定したが、後述するFe系ナノ結晶粒合金は、コイル部品以外にも、他の電子部品、例えば、無線充電装置、フィルタなどにも適用されることができるのは明白である。
本発明の発明者らの研究によると、特定の組成のFe系ナノ結晶粒合金では、相対的に大粒径の粒子や厚さの大きい金属リボンの形態に製造する際に、母相の非晶質性が高いことが確認できた。母相の非晶質性能と飽和磁束密度に優れた合金組成の範囲が確認され、特に、Cを添加してその含量を適宜調節することで、従来よりも飽和磁束密度が向上したことが確認された。ここで、相対的に大粒径の粒子とは、D50が約20μmである場合として定義され、例えば、磁性粒子111のD50が約20~40μmである場合に該当する。また、金属リボンの形態に製造される場合には、約20μm以上の厚さを有する場合に該当するが、直径や厚さの基準は絶対的なものではなく、状況によって変更されることができる。
101 シール材
102 支持部材
103 コイル部
111 磁性粒子
112 絶縁体
120、130 外部電極
C コア領域
Claims (6)
- Fe100-b-c-d-e-gNbbBcPdCueM3 gの組成式で表され、ここで、M3はC及びSiで、b、c、d、e、gは、原子%で、1.5≦b≦3、10≦c≦13、1≦d≦4、0<e≦1.5、8.5≦g≦12の含量条件を満たし、C含量/(Fe含量+C含量)は、重量比で、0.1%以上0.7%以下である、Fe系ナノ結晶粒合金組成物。
- 母相は非晶質単相構造である、請求項1に記載のFe系ナノ結晶粒合金組成物。
- コイル部と、
前記コイル部をシールし、絶縁体と該絶縁体に分散された多数の磁性粒子を含むシール材と、を含み、
前記磁性粒子は、Fe100-b-c-d-e-gNbbBcPdCueM3 gの組成式で表され、ここで、M3はC及びSiで、b、c、d、e、gは、原子%で、1.5≦b≦3、10≦c≦13、1≦d≦4、0<e≦1.5、8.5≦g≦12の含量条件を満たし、C含量/(Fe含量+C含量)は、重量比で、0.1%以上0.7%以下であるFe系ナノ結晶粒合金からなる電子部品。 - 前記多数の磁性粒子は、D50が20μm以上である、請求項3に記載の電子部品。
- 前記Fe系ナノ結晶粒合金は、結晶粒の大きさが50nm以下である、請求項3又は4に記載の電子部品。
- 前記Fe系ナノ結晶粒合金は、1.4T以上の飽和磁束密度を有する、請求項3から5のいずれか一項に記載の電子部品。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20170105060 | 2017-08-18 | ||
KR10-2017-0105060 | 2017-08-18 | ||
KR10-2017-0144474 | 2017-11-01 | ||
KR1020170144474A KR102465581B1 (ko) | 2017-08-18 | 2017-11-01 | Fe계 나노결정립 합금 및 이를 이용한 전자부품 |
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JP2019035140A JP2019035140A (ja) | 2019-03-07 |
JP7322350B2 true JP7322350B2 (ja) | 2023-08-08 |
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JP2018117410A Active JP7322350B2 (ja) | 2017-08-18 | 2018-06-20 | Fe系ナノ結晶粒合金及びこれを用いた電子部品 |
Country Status (3)
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US (1) | US20230160047A1 (ja) |
JP (1) | JP7322350B2 (ja) |
KR (1) | KR102465581B1 (ja) |
Families Citing this family (3)
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JP7099482B2 (ja) * | 2020-01-07 | 2022-07-12 | 株式会社村田製作所 | コイル部品 |
CN113025906A (zh) * | 2021-03-05 | 2021-06-25 | 江西大有科技有限公司 | 铁基纳米晶合金材料及其制作方法 |
KR20230041640A (ko) * | 2021-09-17 | 2023-03-24 | 주식회사 아모그린텍 | Fe계 연자성 합금 및 이의 제조방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007182594A (ja) | 2006-01-04 | 2007-07-19 | Hitachi Metals Ltd | 非晶質合金薄帯、ナノ結晶軟磁性合金ならびにナノ結晶軟磁性合金からなる磁心 |
JP2014167953A (ja) | 2013-02-28 | 2014-09-11 | Seiko Epson Corp | 非晶質合金粉末、圧粉磁心、磁性素子および電子機器 |
CN105741998A (zh) | 2015-12-31 | 2016-07-06 | 安泰科技股份有限公司 | 一种韧性增强的铁基块体非晶软磁合金及其制备方法 |
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JP2823203B2 (ja) * | 1988-05-17 | 1998-11-11 | 株式会社東芝 | Fe基軟磁性合金 |
JP2004353090A (ja) | 1999-04-15 | 2004-12-16 | Hitachi Metals Ltd | 合金薄帯並びにそれを用いた部材 |
JP4514828B2 (ja) * | 2008-08-22 | 2010-07-28 | 彰宏 牧野 | 合金組成物、Fe基ナノ結晶合金及びその製造方法、並びに磁性部品 |
KR101994730B1 (ko) * | 2014-01-02 | 2019-07-01 | 삼성전기주식회사 | 인덕터 |
KR101832564B1 (ko) * | 2015-10-27 | 2018-02-26 | 삼성전기주식회사 | 코일 부품 |
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- 2017-11-01 KR KR1020170144474A patent/KR102465581B1/ko active IP Right Grant
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- 2018-06-20 JP JP2018117410A patent/JP7322350B2/ja active Active
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- 2023-01-09 US US18/094,666 patent/US20230160047A1/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007182594A (ja) | 2006-01-04 | 2007-07-19 | Hitachi Metals Ltd | 非晶質合金薄帯、ナノ結晶軟磁性合金ならびにナノ結晶軟磁性合金からなる磁心 |
JP2014167953A (ja) | 2013-02-28 | 2014-09-11 | Seiko Epson Corp | 非晶質合金粉末、圧粉磁心、磁性素子および電子機器 |
CN105741998A (zh) | 2015-12-31 | 2016-07-06 | 安泰科技股份有限公司 | 一种韧性增强的铁基块体非晶软磁合金及其制备方法 |
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KR20190019796A (ko) | 2019-02-27 |
KR102465581B1 (ko) | 2022-11-11 |
JP2019035140A (ja) | 2019-03-07 |
US20230160047A1 (en) | 2023-05-25 |
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