JP7071609B2 - 3dキャパシタ、及び光活性基板を作製するキャパシタアレイ - Google Patents
3dキャパシタ、及び光活性基板を作製するキャパシタアレイ Download PDFInfo
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- 239000000758 substrate Substances 0.000 title claims description 74
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000003990 capacitor Substances 0.000 title description 17
- 239000011521 glass Substances 0.000 claims description 73
- 239000002241 glass-ceramic Substances 0.000 claims description 47
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 239000002184 metal Substances 0.000 claims description 30
- 238000005530 etching Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 28
- 238000000231 atomic layer deposition Methods 0.000 claims description 20
- 239000000919 ceramic Substances 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000011248 coating agent Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 7
- 229910001947 lithium oxide Inorganic materials 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- 239000002178 crystalline material Substances 0.000 claims description 5
- 238000013461 design Methods 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 230000000873 masking effect Effects 0.000 claims description 4
- 229910004166 TaN Inorganic materials 0.000 claims description 3
- 229910008599 TiW Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 12
- 239000006089 photosensitive glass Substances 0.000 description 11
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000001939 inductive effect Effects 0.000 description 5
- 239000006090 Foturan Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003989 dielectric material Substances 0.000 description 3
- 239000006112 glass ceramic composition Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000001020 plasma etching Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- -1 silver ions Chemical class 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical group [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 229910000413 arsenic oxide Inorganic materials 0.000 description 1
- 229960002594 arsenic trioxide Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005459 micromachining Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000012634 optical imaging Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000003378 silver Chemical group 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- VFWRGKJLLYDFBY-UHFFFAOYSA-N silver;hydrate Chemical compound O.[Ag].[Ag] VFWRGKJLLYDFBY-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/008—Selection of materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/005—Electrodes
- H01G4/012—Form of non-self-supporting electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
- H01G4/129—Ceramic dielectrics containing a glassy phase, e.g. glass ceramic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/33—Thin- or thick-film capacitors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/38—Multiple capacitors, i.e. structural combinations of fixed capacitors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0002—Apparatus or processes for manufacturing printed circuits for manufacturing artworks for printed circuits
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/06—Solid dielectrics
- H01G4/08—Inorganic dielectrics
- H01G4/12—Ceramic dielectrics
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- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Glass Compositions (AREA)
- Ceramic Capacitors (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Semiconductor Integrated Circuits (AREA)
- Micromachines (AREA)
Description
Ce3+ + Ag+ = Ce4+ + Ag0
Claims (6)
- 感光性ガラスセラミック基板内にエッチングされた三次元構造内に創成されるガラスセラミック容量性デバイスであって、前記ガラスセラミック容量性デバイス中の電気容量を増大させる増大した表面積を有する、形成された1又は2以上のビア又はポストチャネルを備え、前記エッチングされた三次元構造の異方性エッチング比が、少なくとも30:1である、前記ガラスセラミック容量性デバイス。
- 感光性ガラスセラミック基板内にエッチングされた三次元構造内に創成されるガラスセラミック容量性デバイスを創成する方法であって、前記ガラスセラミック容量性デバイスが、前記ガラスセラミック容量性デバイス中の電気容量を増大させる増大した表面積を有する、形成された1又は2以上のビア又はポストチャネルを備え、前記エッチングされた三次元構造の異方性エッチング比が、少なくとも30:1であり、
シリカ、酸化リチウム、酸化アルミニウム、及び酸化セリウムを少なくとも含む感光性ガラスセラミック基板を調製するステップ、
1又は2以上の電気伝導路を前記感光性ガラスセラミック基板上に形成する1又は2以上の構造を含むデザインレイアウトをマスキングするステップ、
前記感光性ガラスセラミック基板の少なくとも一部分を活性エネルギー源に露光するステップ、
前記感光性ガラスセラミック基板を、そのガラス転移温度を上回る、少なくとも10分間の加熱相にさらすステップ、
前記感光性ガラスセラミック基板を冷却し、露光されたガラスの少なくとも一部を結晶性材料へ転換して結晶性ガラス基板を形成するステップ、
前記結晶性ガラス基板をエッチング溶液でエッチングし、前記1又は2以上のエッチングされた三次元構造を前記結晶性ガラス基板中に形成するステップであって、前記1又は2以上のエッチングされた三次元構造の一部分が、異方性エッチング比が少なくとも30:1であるビア又はポストチャネルであるステップ、
前記エッチングされた三次元構造の前記ビア又はポストチャネルに隣接する前記結晶性ガラス基板を、セラミック相へ変換するステップ、
前記ビア又はポストチャネルに隣接するセラミック相の表面を希釈ガラスエッチング液でリンスし、前記セラミック相の前記表面積を増大させて前記ガラスセラミック容量性デバイスの電気容量を増大させるステップ、
原子層堆積(ALD)を用いて、前記ビア又はポストチャネルを底部電極用金属で被覆するステップ、
原子層堆積(ALD)を用いて、前記構造の全部又は一部を誘電体媒体で被覆するステップ、
原子層堆積(ALD)を用いて、前記ビア又はポストチャネルを上部電極用金属で被覆するステップ、並びに
前記上部電極及び前記誘電体媒体の少なくとも一部分を除去し、前記容量性デバイスと回路との間の電気的接続を成す電気接点を提供するステップ、から構成され、
前記底部電極用金属、前記上部電極用金属、又はその両方が、前記容量性デバイスの表面又は前記容量性デバイス中に埋設された電気接点を介して回路に接続される、前記方法。 - 感光性ガラスセラミック基板内にエッチングされた三次元構造内に創成されるガラスセラミック容量性デバイスを作製する方法であって、前記ガラスセラミック容量性デバイスが、前記ガラスセラミック容量性デバイス中の電気容量を増大させる増大した表面積を有する、形成された1又は2以上のビア又はポストチャネルを備え、前記エッチングされた三次元構造の異方性エッチング比が、少なくとも30:1であり、
シリカ、酸化リチウム、酸化アルミニウム、及び酸化セリウムを少なくとも含む感光性ガラスセラミック基板を用意するステップ、
前記感光性ガラスセラミック基板上のデザインレイアウトをマスキングするステップであって、前記デザインレイアウトが、1又は2以上の電気伝導路を形成する1又は2以上の構造を含む、ステップ、
前記感光性ガラスセラミック基板の少なくとも一部分を活性エネルギー源に露光するステップ、
前記感光性ガラスセラミック基板を、そのガラス転移温度を上回る、少なくとも10分間の加熱相まで加熱するステップ、
前記感光性ガラスセラミック基板を冷却し、露光されたガラスの少なくとも一部を結晶性材料へ転換して結晶性ガラス基板を形成するステップ、
前記結晶性ガラス基板をエッチング溶液でエッチングし、1又は2以上のエッチングされた三次元構造を前記結晶性ガラス基板中に形成するステップであって、前記1又は2以上のエッチングされた三次元構造の一部分が、異方性エッチング比が少なくとも30:1であるビア又はポストチャネルであるステップ、
前記エッチングされた三次元構造の前記ビア又はポストチャネルに隣接する前記結晶性ガラス基板の一部分をセラミック相へ変換するステップ、
前記ビア又はポストチャネルに隣接するセラミック相の表面を希釈ガラスエッチング液でリンスし、前記セラミック相の前記表面積を増大させて前記ガラスセラミック容量性デバイスの電気容量を増大させるステップ、
前記ビア又はポストチャネルを第1の金属で被覆し、底部電極を形成するステップ、
前記構造の少なくとも一部分を誘電体媒体で被覆するステップ、
前記ビア又はポストチャネルを第2の金属で被覆し、上部電極を形成するステップ、
前記上部電極及び前記誘電体媒体の少なくとも一部分を除去し、前記ガラスセラミック容量性デバイスと回路との間の電気的接続を成す電気接点を提供するステップ、並びに
前記第1の金属、前記第2の金属、又はその両方を、前記ガラスセラミック容量性デバイスの表面又は前記ガラスセラミック容量性デバイス中に埋設された電気接点を介して回路に接続するステップ
を含む、前記方法。 - 第1の金属、第2の金属、又はその両方の被覆が、原子層堆積(ALD)を用いる、請求項3に記載の方法。
- 第1の金属、第2の金属、又はその両方が、Au、Ag、Pt、Cu、W、TiW、TiN、TaN、WN、Al2O3、又はそれらの混合物及び合金を含む、請求項3に記載の方法。
- 誘電体媒体が、Ta2O5、Al2O3、又は気相誘電体を含む、請求項3に記載の方法。
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PCT/US2017/019483 WO2017147511A1 (en) | 2016-02-25 | 2017-02-24 | 3d capacitor and capacitor array fabricating photoactive substrates |
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