JP6915223B2 - 化粧シートおよび化粧シートの製造方法 - Google Patents
化粧シートおよび化粧シートの製造方法 Download PDFInfo
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- JP6915223B2 JP6915223B2 JP2017044251A JP2017044251A JP6915223B2 JP 6915223 B2 JP6915223 B2 JP 6915223B2 JP 2017044251 A JP2017044251 A JP 2017044251A JP 2017044251 A JP2017044251 A JP 2017044251A JP 6915223 B2 JP6915223 B2 JP 6915223B2
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Description
以下に、本発明における超臨界逆相蒸発法を用いた有機系紫外線吸収剤ベシクルまたは無機系紫外線吸収剤ベシクルの詳しい調製方法について説明する。
実施例1〜5においては、トップコート層5の主成分である樹脂組成物としてのウレタン系樹脂に対して、上述の方法で調製した有機系紫外線吸収剤ベシクル0.5、1.0、5.0、10.0、20.0重量部添加するとともに、上記の方法で調製した無機系紫外線吸収剤ベシクル0.5、1.0、5.0、10.0、20.0重量部を添加した化粧シート1とした。
実施例6〜10においては、透明樹脂層4の主成分である樹脂組成物としての結晶性ホモポリプロピレン樹脂に対して、上述の方法で調製した有機系紫外線吸収剤ベシクル0.1、0.5、1.0、2.5、5.0重量部を添加するとともに、上述の方法で調製した無機系紫外線吸収剤ベシクル0.1、0.5、1.0、2.5、5.0重量部を添加した化粧シート1とした。
実施例11においては、トップコート層5の主成分である樹脂組成物としてのウレタン系樹脂に対して、上述の方法で調製した有機系紫外線吸収剤ベシクルを1.25重量部、上記の方法で調製した無機系紫外線吸収剤ベシクル1.25重量部を添加するとともに、透明樹脂層4の主成分である樹脂組成物としての結晶性ホモポリプロピレン樹脂に対して、上述の方法で調製した有機系紫外線吸収剤ベシクルを1.25重量部、上述の方法で調整した無機系紫外線吸収剤ベシクルを1.25重量部添加した化粧シート1とした。
比較例1,2においては、トップコート層5の主成分である樹脂組成物としてのウレタン系樹脂に対して、ベシクル化していない有機系紫外線吸収剤0.5または50.0重量部を添加するとともに、ベシクル化していない無機系紫外線吸収剤0.5または50.0重量部を添加した化粧シート1とした。その他の構成は、実施例1〜5の化粧シート1と同じである。
比較例3,4においては、透明樹脂層4の主成分である樹脂組成物としての結晶性ホモポリプロピレン樹脂に対して、ベシクル化していない有機系紫外線吸収剤0.5または50.0重量部を添加するとともに、ベシクル化していない無機系紫外線吸収剤0.5または50.0重量部を添加した化粧シート1とした。その他の構成は、実施例6〜10の化粧シート1と同じである。
比較例5においては、トップコート層5の主成分である樹脂組成物としてのウレタン系樹脂に対して、ベシクル化していない有機系紫外線吸収剤を0.5重量部、ベシクル化していない無機系紫外線吸収剤0.5重量部を添加するとともに、透明樹脂層4の主成分である樹脂組成物としての結晶性ホモポリプロピレン樹脂に対して、ベシクル化していない有機系紫外線吸収剤を0.5重量部、ベシクル化していない無機系紫外線吸収剤を0.5重量部添加した化粧シート1とした。その他の構成は、実施例11の化粧シート1と同じである。
比較例6においては、紫外線吸収剤をいずれの樹脂層に対しても添加しない化粧シート1とした。その他の構成は、実施例1の化粧シート1と同じである。
<外観変化の記号>
◎:全く変化なし
○:わずかな変化あり
△:若干の白化や亀裂あり
×:激しい白化および一部が破壊・破断
2 原反層
3 インキ層
4 透明樹脂層
4a エンボス模様
5 トップコート層
6 プライマー層
7 接着層
8 隠蔽層
B 基材
Claims (6)
- 最表層にトップコート層を備え、前記トップコート層の下層に透明樹脂層を備える化粧シートであって、
前記トップコート層および/または前記透明樹脂層を、有機系紫外線吸収剤および無機系紫外線吸収剤を添加して形成し、
前記有機系紫外線吸収剤および前記無機系紫外線吸収剤が、単層膜の外膜を具備するベシクルにそれぞれ別々に内包された有機系紫外線吸収剤ベシクルおよび無機系紫外線吸収剤ベシクルであるとともに等量ずつ添加されていることを特徴とする化粧シート。 - 前記有機系紫外線吸収剤および前記無機系紫外線吸収剤の前記トップコート層および/または前記透明樹脂層に対する添加量が1.0重量部以上であることを特徴とする請求項1に記載の化粧シート。
- 前記有機系紫外線吸収剤が、ベンゾトリアゾール系またはトリアジン系であることを特徴とする請求項1または請求項2に記載の化粧シート。
- 前記無機系紫外線吸収剤が、酸化亜鉛であることを特徴とする請求項1乃至請求項3のいずれか1項に記載の化粧シート。
- 前記トップコート層側の前記透明樹脂層の表面には、エンボス模様が形成されており、
前記エンボス模様の凹部には、前記トップコート層が埋め込まれて設けられていることを特徴とする請求項1乃至4のいずれか1項に記載の化粧シート。 - 最表層に樹脂からなるトップコート層を備え、前記トップコート層の下層に透明オレフィン系樹脂からなる透明樹脂層を備える化粧シートの製造方法であって、
前記トップコート層および/または前記透明樹脂層を構成する樹脂に対して、超臨界逆相蒸発法によって単層膜の外膜を具備するベシクルに有機系紫外線吸収剤および無機系紫外線吸収剤をそれぞれ別々に内包した有機系紫外線吸収剤ベシクルおよび無機系紫外線吸収剤ベシクルを等量ずつ添加することを特徴とする化粧シートの製造方法。
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