JP6906545B2 - 耐熱性ポリマー層およびポリラクチド樹脂層を含有する多層シートの化粧面を有するポリマーフォーム断熱材構造 - Google Patents
耐熱性ポリマー層およびポリラクチド樹脂層を含有する多層シートの化粧面を有するポリマーフォーム断熱材構造 Download PDFInfo
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- JP6906545B2 JP6906545B2 JP2018554666A JP2018554666A JP6906545B2 JP 6906545 B2 JP6906545 B2 JP 6906545B2 JP 2018554666 A JP2018554666 A JP 2018554666A JP 2018554666 A JP2018554666 A JP 2018554666A JP 6906545 B2 JP6906545 B2 JP 6906545B2
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- multilayer sheet
- polylactide
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Classifications
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Landscapes
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Description
1.例えば、Aが第1の非気泡層を表し、そしてBが第2の非気泡層を表す、A−B構成を有する2層シート;
2.Cが異なる材料の層(例えば、第1の非気泡層31の熱可塑性樹脂および第2の非気泡層32ポリラクチド樹脂のブレンドの層を含む)を表し、A−B−A、A−A−B、A−B−CまたはA−C−B構成を有する3層シート;
3.A−A−B−B、A−B−A−B、A−B−A−C、A−B−C−B、A−B−C−A、A−C−B−AまたはA−C−B−C構成を有する4層シート;
4.それぞれのXが、独立して、A、BまたはCを表す、A−B−X−X−X構成を有する5プライシート。
ポリラクチド樹脂とポリ(メタクリル酸メチル)(PMMA)樹脂とを共押出することによって、0.4mmの2層シートを調製する。ポリラクチド樹脂は、95.5%のL−乳酸単位および4.5%のD−乳酸単位を含有し、そして3.5〜4.5の相対粘度を有する。実施例1Aおよび1Bに関して、PMMAは、約111℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有するPlexiglas(登録商標)V825樹脂である。実施例2Aおよび2Bに関して、PMMAは、約78℃のビカー軟化温度を有するPlexiglas(登録商標)Rnew B514である。
1mmの2層シート実施例3A、3Bおよび3Cは、約108℃のビカー軟化温度を有するPlexiglas(登録商標)MI-7Tアクリル樹脂と、実施例1で記載されたポリラクチド樹脂を共押出することによって調製される。共押出成形条件は、実施例1および2と類似である。層厚さは、実施例1と同様に顕微鏡で決定する。実施例3A、3Bおよび3Cのそれぞれの第1の変形温度を測定する。実施例3A、3Bおよび3Cは、それぞれ、実施例1A、2Aおよび2Bと同一の方法で熱成形される。
1.2mmの2層シート実施例4A、4Bおよび4Cは、実施例1および2と同様の一般的な方法で製造される。それぞれの場合のPMMA層は、98重量部のPlexiglas(登録商標)V920アクリル樹脂(ビカー軟化温度約100℃)と2重量部のコア−シェルゴムとをブレンドすることによって製造された衝撃変性PMMAである。それぞれの場合のポリラクチド層は、95部の実施例1に記載されるポリラクチド樹脂と2.6部の二酸化チタン粉末と2.4部のコア−シェルゴムをブレンドすることによって製造される。
1.2mmの2層シート実施例6は、実施例1および2と同様の一般的な方法で製造される。それぞれの場合のPMMA層は、98重量部のPlexiglas(登録商標)V825アクリル樹脂と2重量部のコア−シェルゴムとをブレンドすることによって製造された衝撃変性PMMAである。その厚さは0.25mmである。それぞれの場合のポリラクチド層は、0.85mmの厚さを有し、そして80部の実施例1に記載されるポリラクチド樹脂と15部のPlexiglas(登録商標)V825アクリル樹脂と2.6部の二酸化チタン粉末と2.4部のコア−シェルゴムをブレンドすることによって製造される。この実施例は、いくつかのスクラップ材料がポリラクチド層中にリサイクルされる製造設定をシミュレートする。
2層シート実施例1〜6のそれぞれからフォーム断熱材パネルを製造する。厚さ50mmの独立気泡の硬質ポリウレタンフォームを、現場注入法で2層シート間に形成し、フォーム層が中央にあり、かつPMMA層がフォームに面する3層サンドウィッチ構造を形成する。ポリウレタンフォームは、シクロペンタンの存在下、ポリイソシアネート、ポリオール混合物および水を反応させることによって得られた生成物であり、したがって、その気泡中に二酸化炭素およびシクロペンタンの混合物を含有する。フォーム層の全ての露出した端部は、気体不透過性の金属テープで被覆されている。
1.a)対向する主要表面と、物理的発泡剤を含有する気体充てん気泡とを有するポリマーフォーム層、およびb)ポリマーフォーム層の上記対向する主要表面の少なくとも1つに付着された多層シートを含む、フォーム断熱材構造であって、多層シートが、i)少なくとも50重量%の、ポリラクチド樹脂ではなく、かつ少なくとも70℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有する1種以上の熱可塑性樹脂を含有する第1の非気泡層と、ii)少なくとも50重量%のポリラクチド樹脂を含有する第2の非気泡層を含み、多層シートの第1の非気泡層が、ポリマーフォーム層に密封付着され、多層シートの第2の非気泡層が、多層シートの第1の非気泡層に密封付着される、フォーム断熱材構造。
Claims (20)
- a)対向する主要表面と、物理的発泡剤を含有する気体充てん気泡とを有するポリマーフォーム層、およびb)前記ポリマーフォーム層の前記対向する主要表面の少なくとも1つに付着された多層シートを含む、フォーム断熱材構造であって、前記多層シートが、i)少なくとも50重量%の、ポリラクチド樹脂ではなく、かつ少なくとも70℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有する1種以上の熱可塑性樹脂を含有する第1の非気泡層と、ii)少なくとも50重量%のポリラクチド樹脂を含有する第2の非気泡層を含み、前記多層シートの前記第1の非気泡層が、前記ポリマーフォーム層に密封付着され、かつ前記多層シートの前記第2の非気泡層が、前記多層シートの前記第1の非気泡層に密封付着される、フォーム断熱材構造。
- 前記1種以上の熱可塑性樹脂が、少なくとも100℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有する、請求項1に記載のフォーム断熱材構造。
- 前記1種以上の熱可塑性樹脂が、メタクリル酸メチルのホモポリマー、または少なくとも70重量%の重合メタクリル酸メチルを含有するコポリマーである、請求項1または2のいずれか一項に記載のフォーム断熱材構造。
- 前記物理的発泡剤が、3〜8個の炭素原子を有する炭化水素;8個までの炭素原子を有するフルオロカーボン、ヒドロフルオロカーボン、フルオロクロロカーボンまたはヒドロフルオロクロロカーボン;8個までの炭素原子を有するヒドロハロオレフィン;および8個までの炭素原子を有するジアルキルエーテルの1種以上から選択される、請求項1〜3のいずれか一項に記載のフォーム断熱材構造。
- 前記物理的発泡剤が、3〜8個の炭素原子を有する炭化水素を含む、請求項1〜4のいずれか一項に記載のフォーム断熱材構造。
- 前記物理的発泡剤が、シクロペンタンを含む、請求項5に記載のフォーム断熱材構造。
- 前記ポリマーフォームが、少なくとも1種のポリイソシアネート、水および前記物理的発泡剤を含有するフォーム前駆体混合物の反応生成物である、請求項1〜6のいずれか一項に記載のフォーム断熱材構造。
- 前記第1の非気泡層の厚さが、前記多層シートの全厚さの少なくとも10%を構成する、請求項1〜7のいずれか一項に記載のフォーム断熱材構造。
- 前記第2の非気泡層が、前記第2の非気泡層中のポリラクチド樹脂1グラムあたり25J未満のポリラクチド結晶子を含有する、請求項1〜8のいずれか一項に記載のフォーム断熱材構造。
- 前記多層シートが、熱成形によって製造される非平面幾何構造を有する、請求項1〜9のいずれか一項に記載のフォーム断熱材構造。
- 多層シートが、b)前記ポリマーフォーム層の両方の対向主要表面に密封付着されている、請求項1〜10のいずれか一項に記載のフォーム断熱材構造。
- 金属層が、前記ポリマーフォーム層の前記対向主要表面に密封付着されている、請求項1〜10のいずれか一項に記載のフォーム断熱材構造。
- 製品キャビネットまたはドアの全体または一部を構成する、請求項1〜12のいずれか一項に記載のフォーム断熱材構造。
- (1)i)少なくとも50重量%の、ポリラクチド樹脂ではなく、かつ少なくとも70℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有する1種以上の熱可塑性樹脂を含有し、第2の非気泡層に密封付着された第1の非気泡層と、ii)少なくとも50重量%のポリラクチド樹脂を含有する第2の非気泡層を含む多層シートの前記第1の非気泡層の表面に、少なくとも1種のポリイソシアネート、水および物理的発泡剤を含有するフォーム前駆体混合物を適用すること、ならびに(2)前記多層シートの前記第1の非気泡層と接触させながら、前記フォーム前駆体混合物を硬化して、前記多層シートの前記第1の非気泡層に接着されたポリマーフォーム層を形成することを含む方法。
- 前記1種以上の熱可塑性樹脂が、少なくとも100℃のビカー軟化温度(ASTM D1525、50℃/時間、1kg)を有する、請求項14に記載の方法。
- 前記1種以上の熱可塑性樹脂が、メタクリル酸メチルのホモポリマー、または少なくとも70重量%の重合メタクリル酸メチルを含有するコポリマーである、請求項14〜15のいずれか一項に記載の方法。
- 前記物理的発泡剤が、3〜8個の炭素原子を有する炭化水素;8個までの炭素原子を有するフルオロカーボン、ヒドロフルオロカーボン、フルオロクロロカーボンまたはヒドロフルオロクロロカーボン;8個までの炭素原子を有するヒドロハロオレフィン;および8個までの炭素原子を有するジアルキルエーテルの1種以上から選択される、請求項14〜16のいずれか一項に記載の方法。
- 前記第1の非気泡層が、前記多層シートの全厚さの少なくとも10%を構成する、請求項14〜17のいずれか一項に記載の方法。
- 前記第2の非気泡層が、前記第2の非気泡層中のポリラクチド樹脂1グラムあたり25J未満のポリラクチド結晶子を含有する、請求項14〜18のいずれか一項に記載の方法。
- 前記フォーム前駆体混合物が、前記多層シートのシートおよび第2の層によって形成された空洞中に分散され、そして前記空洞内で硬化され、前記多層シートおよび前記第2の層に接着したポリマーフォーム層が形成される、請求項14〜19のいずれか一項に記載の方法。
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US11352783B2 (en) | 2020-01-28 | 2022-06-07 | University Of North Texas | Fabrication of a phase change material (PCM) integrated insulation |
US20220205709A1 (en) * | 2020-12-30 | 2022-06-30 | Whirlpool Corporation | Insulation materials for a vacuum insulated structure and methods of forming |
IT202100010037A1 (it) | 2021-04-21 | 2022-10-21 | Tema Tech And Materials Srl | Pannello rigido per edilizia con strato centrale schiumato e rivestimento in resina. |
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Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3655825A (en) | 1969-03-24 | 1972-04-11 | Rohm & Haas | Acrylic impact resistant modifiers for polyvinyl chloride |
US3808180A (en) | 1970-04-13 | 1974-04-30 | Rohm & Haas | Composite interpolymer and low haze impact resistant thermoplastic compositions thereof |
US3678133A (en) | 1970-04-24 | 1972-07-18 | Rohm & Haas | Modified vinyl halide polymers |
US3668274A (en) | 1970-09-10 | 1972-06-06 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
US3796771A (en) | 1970-09-10 | 1974-03-12 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
BE788214A (fr) | 1971-09-01 | 1973-02-28 | Ciba Geigy | Procede de production de 3-perfluoroalkyl-1-propenes |
US3793402A (en) | 1971-11-05 | 1974-02-19 | F Owens | Low haze impact resistant compositions containing a multi-stage,sequentially produced polymer |
US3985703A (en) | 1975-06-24 | 1976-10-12 | Rohm And Haas Company | Process for manufacture of acrylic core/shell polymers |
US5219665A (en) * | 1991-01-30 | 1993-06-15 | E. I. Du Pont De Nemours And Company | Fabricated articles with improved resistance to hydrohalocarbons |
TW197982B (ja) * | 1991-01-30 | 1993-01-11 | Du Pont | |
DE69308429T3 (de) | 1992-08-24 | 2003-07-17 | Mitsui Chemicals, Inc. | Geformtes Produkt aus Polymer und Verfahren zu seiner Herstellung |
GB9403334D0 (en) | 1993-04-23 | 1994-04-13 | Ici Plc | Process for rigid polyurethane foams |
US5359026A (en) | 1993-07-30 | 1994-10-25 | Cargill, Incorporated | Poly(lactide) copolymer and process for manufacture thereof |
JP3772426B2 (ja) * | 1995-11-28 | 2006-05-10 | 大日本インキ化学工業株式会社 | 発泡体及び積層体 |
PT922554E (pt) * | 1997-12-08 | 2003-11-28 | Dow Deutschland Inc | Espumas com multiplas camadas metodo de producao e utilizacao |
US6989190B2 (en) | 2000-10-17 | 2006-01-24 | General Electric Company | Transparent polycarbonate polyester composition and process |
CA2426013C (en) * | 2000-10-24 | 2009-09-15 | Dow Global Technologies Inc. | A water-free preparation process for multimodal thermoplastic polymer foam and foam therefrom |
EP1406947A4 (en) | 2001-06-08 | 2010-08-04 | Cargill Dow Llc | COPOLYMERS OF MONOCYCLIC ESTERS AND CARBONATES AND METHODS OF PRODUCING THE SAME |
ATE383934T1 (de) * | 2001-08-20 | 2008-02-15 | Cargill Dow Llc | Verfahren zum herstellen von gegenständen aus teilkristalliner polymilchsäure |
US6753357B2 (en) | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
US20060148918A1 (en) * | 2003-08-08 | 2006-07-06 | Solvay S.A. | Process for the manufacture of a polymer foam |
CA2570822C (en) | 2004-06-23 | 2010-10-05 | Natureworks Llc | Branched polylactic acid polymers and method of preparing same |
JP4446385B2 (ja) * | 2004-10-04 | 2010-04-07 | 株式会社ジェイエスピー | 熱成形用多層ポリ乳酸系樹脂発泡体 |
EP1887044A4 (en) | 2005-05-12 | 2009-05-27 | Mitsui Chemicals Inc | POLYMER COMPOSITION OF LACTIC ACID, MOLDED ARTICLE MADE THEREFROM, AND METHOD OF PRODUCING SUCH MOLDED ARTICLE |
GB2428628A (en) * | 2005-07-14 | 2007-02-07 | Green Light Products Ltd | Multilayer material useful for packaging |
EP1942001B1 (en) | 2005-11-30 | 2009-09-30 | Toray Industries, Inc. | Polylactic acid resin multilayer sheet and molded body made of same |
CA2722437C (en) * | 2008-04-30 | 2016-08-16 | Natureworks Llc | Extruded foams made with polylactides that have high molecular weights and high intrinsic viscosities |
US8481605B2 (en) | 2009-05-21 | 2013-07-09 | Huntsman International Llc | Rigid polyurethane foam and system and method for making the same |
IN2012DN02547A (ja) * | 2009-09-25 | 2015-08-28 | Arkema Inc | |
JP2011231284A (ja) * | 2010-04-30 | 2011-11-17 | Sekisui Plastics Co Ltd | ポリ乳酸系樹脂フィルム及び積層シート |
JP2012030571A (ja) * | 2010-06-28 | 2012-02-16 | Sekisui Plastics Co Ltd | 生分解性樹脂積層発泡シート、折箱用周側枠材及び折箱 |
JP2012131552A (ja) * | 2010-12-22 | 2012-07-12 | Sekisui Plastics Co Ltd | 納豆容器製造用積層発泡シートとその製造方法及び納豆容器 |
JP5608070B2 (ja) * | 2010-12-22 | 2014-10-15 | 積水化成品工業株式会社 | 積層発泡シートとその製造方法及び容器 |
US20140377568A1 (en) | 2011-04-26 | 2014-12-25 | Biovation, Llc | Fire retardant biolaminate composite and related assembly |
FI124660B (fi) * | 2011-07-12 | 2014-11-28 | Stora Enso Oyj | Polybutyleenisukkinaatin käyttö pakkausmateriaalin ekstruusiopäällystyksessä |
EP2737073B1 (en) | 2011-07-28 | 2021-10-20 | Butamax Advanced Biofuels LLC | Keto-isovalerate decarboxylase enzymes and methods of use thereof |
EP2751158A1 (en) | 2011-09-02 | 2014-07-09 | Dow Global Technologies LLC | Polyurethane rigid foams |
MY168779A (en) * | 2011-09-09 | 2018-12-04 | Total Res & Technology Feluy | Multilayered rotomoulded articles comprising a layer of polyester |
KR101393811B1 (ko) * | 2011-12-13 | 2014-05-13 | (주)엘지하우시스 | 가교된 폴리락트산을 이용한 발포 시트 및 이의 제조방법 |
US9266991B2 (en) | 2012-03-15 | 2016-02-23 | Dow Global Technologies Llc | Low density full water blown polyurethane rigid foam |
CN104334328B (zh) * | 2012-04-27 | 2017-03-01 | 依云矿泉水股份有限公司 | 包含发泡聚乳酸的制品及其制造方法 |
EP2877344B1 (en) | 2012-07-27 | 2019-07-03 | Arkema France | Multilayer structures containing biopolymers |
WO2014068348A1 (en) | 2012-10-30 | 2014-05-08 | Sa Des Eaux Minerales D'evian Saeme | Article comprising polylactic acid layers and process of making the same |
SG11201506001VA (en) | 2013-02-13 | 2015-09-29 | Fujimi Inc | Polishing composition, method for producing polishing composition and method for producing polished article |
FR3002877B1 (fr) | 2013-03-07 | 2015-03-27 | Arkema France | Procede de fabrication d'un materiau composite multicouche, materiau composite multicouche obtenu par le procede et pieces ou structures mecaniques realisees avec ledit materiau. |
EP2873779B1 (de) * | 2013-11-13 | 2016-02-03 | STO SE & Co. KGaA | Verfahren zur Herstellung eines mehrschichtigen Formkörpers sowie mehrschichtiger Formkörper zur Wärmedämmung von Gebäuden |
CN105015125B (zh) * | 2015-07-17 | 2017-06-06 | 湖南工业大学 | 一种轻质高强度隔热防潮复合纸板 |
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