JP6900496B2 - 半固体状洗浄剤 - Google Patents
半固体状洗浄剤 Download PDFInfo
- Publication number
- JP6900496B2 JP6900496B2 JP2019544454A JP2019544454A JP6900496B2 JP 6900496 B2 JP6900496 B2 JP 6900496B2 JP 2019544454 A JP2019544454 A JP 2019544454A JP 2019544454 A JP2019544454 A JP 2019544454A JP 6900496 B2 JP6900496 B2 JP 6900496B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- semi
- mass
- solid detergent
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000012459 cleaning agent Substances 0.000 title claims description 37
- 239000007787 solid Substances 0.000 title claims description 32
- 239000013042 solid detergent Substances 0.000 claims description 77
- 239000000194 fatty acid Substances 0.000 claims description 39
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 38
- 229930195729 fatty acid Natural products 0.000 claims description 38
- 229920002125 Sokalan® Polymers 0.000 claims description 33
- 150000004665 fatty acids Chemical class 0.000 claims description 33
- 150000003839 salts Chemical class 0.000 claims description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000004615 ingredient Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 229920006037 cross link polymer Polymers 0.000 claims description 11
- 239000002562 thickening agent Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 claims description 8
- 235000021360 Myristic acid Nutrition 0.000 claims description 8
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 8
- 229920001282 polysaccharide Polymers 0.000 claims description 7
- 239000005017 polysaccharide Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 238000003860 storage Methods 0.000 description 27
- -1 fatty acid salts Chemical class 0.000 description 24
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 22
- 239000006260 foam Substances 0.000 description 21
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000003599 detergent Substances 0.000 description 13
- 238000011156 evaluation Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 229960003237 betaine Drugs 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000005639 Lauric acid Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000005187 foaming Methods 0.000 description 10
- 125000005250 alkyl acrylate group Chemical group 0.000 description 9
- 239000002280 amphoteric surfactant Substances 0.000 description 9
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 6
- 150000004804 polysaccharides Chemical class 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 238000003892 spreading Methods 0.000 description 6
- 230000007480 spreading Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229920002907 Guar gum Polymers 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000002950 deficient Effects 0.000 description 5
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000010417 guar gum Nutrition 0.000 description 5
- 239000000665 guar gum Substances 0.000 description 5
- 229960002154 guar gum Drugs 0.000 description 5
- 229920000591 gum Polymers 0.000 description 5
- 229940070765 laurate Drugs 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 235000021314 Palmitic acid Nutrition 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 235000010980 cellulose Nutrition 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 229960000541 cetyl alcohol Drugs 0.000 description 4
- 238000005243 fluidization Methods 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 238000005201 scrubbing Methods 0.000 description 4
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229960000735 docosanol Drugs 0.000 description 3
- 229910001651 emery Inorganic materials 0.000 description 3
- 229920002674 hyaluronan Polymers 0.000 description 3
- 229960003160 hyaluronic acid Drugs 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 229920002709 Ultraz Polymers 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229960001631 carbomer Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 235000010418 carrageenan Nutrition 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 229940113118 carrageenan Drugs 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- FOUZISDNESEYLX-UHFFFAOYSA-N 2-(2-hydroxyethylazaniumyl)acetate Chemical class OCCNCC(O)=O FOUZISDNESEYLX-UHFFFAOYSA-N 0.000 description 1
- HVNMCCPQUIEPCT-UHFFFAOYSA-N 2-(dimethylazaniumyl)pentanoate Chemical compound CCCC(N(C)C)C(O)=O HVNMCCPQUIEPCT-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920002752 Konjac Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- ZXFQDPHJZVBMJZ-UHFFFAOYSA-N OCC[N+]1(CC([O-])=O)CCN=C1 Chemical compound OCC[N+]1(CC([O-])=O)CCN=C1 ZXFQDPHJZVBMJZ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241000282372 Panthera onca Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940023476 agar Drugs 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229920006321 anionic cellulose Polymers 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 235000010485 konjac Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940105082 medicinal charcoal Drugs 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000010491 tara gum Nutrition 0.000 description 1
- 239000000213 tara gum Substances 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dermatology (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
成分(A):高級脂肪酸及び/又はその塩
成分(B):20℃で固体であり且つ炭素数16〜20である高級アルコール
成分(C):カルボキシビニルポリマー
成分(D):多糖増粘剤
成分(E):界面活性剤
成分(A)である高級脂肪酸及び/又はその塩(高級脂肪酸(塩))は、高級脂肪酸及び高級脂肪酸塩のうちのいずれか一方又は両方であり、本発明の半固体状洗浄剤の洗浄性、泡立ち、泡質、及び保存安定性に寄与する。成分(A)は、1種のみを用いてもよいし、2種以上を用いてもよい。
成分(B)である、20℃で固体であり且つ炭素数16〜20である高級アルコールは、成分(C)との併用により、成分(A)の配合量が少ない状態において半固体状を形成し、且つ保存安定性を向上させる作用を有する。具体的には、20℃で固体である高級アルコールを用いることにより洗浄剤を半固体状とすることができる。また20℃で固体である高級アルコールの中でも、炭素数16以上のものを用いることにより洗浄剤が適度な粘度となり垂れ落ちにくくなり、炭素数20以下のものを用いることにより、親油性が高くなり過ぎず適度であることによるものと推測され、洗浄剤がゲル構造をとるため、半固体状での保存安定性に優れる。成分(B)は、1種のみを用いてもよいし、2種以上を用いてもよい。
成分(C)であるカルボキシビニルポリマーは、成分(B)との併用により、成分(A)の配合量が少ない状態において半固体状を形成し、且つ保存安定性を向上させる作用を有する。成分(C)は、1種のみを用いてもよいし、2種以上を用いてもよい。
本発明の半固体状洗浄剤は、さらに、多糖増粘剤(「成分(D)」と称する場合がある)を含むことが好ましい。本発明の半固体状洗浄剤が成分(D)を含む場合、半固体状及び保存安定性を維持しつつ、伸びなじみがよく、また水なじみがより優れ、泡質(特に、泡のキメ、弾力)がより向上する。これは、成分(D)が泡の皮膜を強化することによるものと推測される。成分(D)は、1種のみを用いてもよいし、2種以上を用いてもよい。
本発明の半固体状洗浄剤は、さらに、界面活性剤(「成分(E)」と称する場合がある)を含むことが好ましい。成分(E)としては、ノニオン性界面活性剤、アニオン性界面活性剤、両性界面活性剤が好ましい。中でも、半固体状及び保存安定性を維持しつつ、水なじみがより優れ、泡質(特に、泡のキメ、弾力)がより向上する観点から、両性界面活性剤がより好ましい。成分(E)は、1種のみを用いてもよいし、2種以上を用いてもよい。
本発明の半固体状洗浄剤は水を含む。上記水は、特に限定されないが、精製水が好ましい。本発明の半固体状洗浄剤中の水の含有割合は、特に限定されないが、本発明の半固体状洗浄剤100質量%に対して、30.0〜90.0質量%が好ましく、より好ましくは40.0〜85.0質量%である。
本発明の半固体状洗浄剤は、本発明の目的を阻害しない範囲内で、上記成分(A)〜(E)や水以外の成分(その他の成分)を含んでいてもよい。上記その他の成分しては、特に限定されず、例えば、化粧品や医薬部外品に通常用いられる成分等が挙げられる。具体的には、例えば、エタノール等の低級アルコール;油脂、多価アルコール、成分(B)以外の高級アルコール、エステル油、植物油、炭化水素油等の油性成分;カチオン性ポリマー等の成分(D)以外の増粘剤;保湿剤;殺菌剤;パール化剤;スクラブ剤;グリチルリチン酸及びその塩等の抗炎症剤;メントール等の清涼剤;リン酸及びその塩類、クエン酸及びその塩類、乳酸及びその塩類、水酸化ナトリウム、トリエタノールアミン等のpH調整剤;香料;紫外線吸収剤;酸化防止剤;金属イオン封鎖剤(キレート剤);被膜形成性高分子化合物;粉体;色素;顔料;ビタミン類;アミノ酸類;収斂剤;美白剤;動植物抽出物;酸;アルカリ等が挙げられる。なお、上記その他の成分からは、上記成分(A)〜(E)に含まれるものは除かれるものとする。
表に記した各成分(成分(A)〜(E)、水、及びその他の成分)を用い、実施例及び比較例の各洗浄剤を常法により調製した。
ラウリン酸:商品名「EDENOR C12−99」(Emery Oleochemicals社製)
ミリスチン酸:商品名「EDENOR C14−99」(Emery Oleochemicals社製)
パルミチン酸:商品名「EDENOR C16−98 MY」(Emery Oleochemicals社製)
<成分(B)>
ステアリルアルコール:商品名「カルコール 8688」(花王株式会社製)
セタノール:商品名「カルコール 6870」(花王株式会社製)
セトステアリルアルコール:商品名「カルコール 6850」(花王株式会社製)
<成分(C)>
成分(C−1):商品名「Carbopol SC−200 Polymer」(Lubrizol Advanced Materials社製)、(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
成分(C−2):商品名「PEMULEN TR−1」(Lubrizol Advanced Materials社製)、(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
成分(C−3):商品名「Carbopol Ultrez 21 Polymer」(Lubrizol Advanced Materials社製)、(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
成分(C−4):商品名「Carbopol 980 Polymer」(Lubrizol Advanced Materials社製)、カルボマー
<成分(D)>
キサンタンガム:商品名「エコーガムT」(DSP五協フード&ケミカル株式会社製)
カチオン化グァーガム:商品名「ラボールガムCG−M」(DSP五協フード&ケミカル株式会社製)
<成分(E)>
ラウリン酸アミドプロピルベタイン液(30%):商品名「リカビオン B−300」(新日本理化株式会社製)、両性界面活性剤(有効成分:30質量%)
<その他の成分>
ベヘニルアルコール:商品名「ベヘニルアルコール 2265」(高級アルコール工業株式会社製)
カチオン性ポリマー:商品名「マーコート550PR」(Lubrizol Advanced Materials社製)
実施例及び比較例で得られた各洗浄剤について以下の通り評価した。評価結果は表に記載した。
実施例及び比較例で得られた各洗浄剤50gを、ポリプロピレン製のチューブ容器(100mL容量、吐出口の内径5mm)の内部に注入し、吐出口まで充填した。その後、このチューブ容器の吐出口を下に向けて、20℃の雰囲気中で10秒間保持し、チューブ容器の吐出口からの洗浄剤の垂れ落ちの有無を目視で観察した。そして、洗浄剤の状態を下記評価基準で評価した。
[状態の評価基準]
◎(優れる):チューブ容器の吐出口から洗浄剤の垂れ落ちがなく、半固体状の性状を保持している。
○(良好):チューブ容器の吐出口から洗浄剤の垂れ落ちがなく、洗浄剤の表面にわずかな流動化が認められる。
△(使用可能):チューブ容器の吐出口から洗浄剤の僅かな垂れ落ちが認められ、洗浄剤の表面に明らかな流動化が認められる。
×(不良):チューブ容器の吐出口から洗浄剤の垂れ落ちが認められ、液体状である。
実施例及び比較例で得られた各洗浄剤(約1.0g)を、手のひらでのばした際の伸びのよさを、下記評価基準に従って専門評価員4名が評価を行った。
[塗布時の伸び評価基準]
◎(優れる):洗浄剤が均一に塗布できる。
○(良好):◎と比較して、均一塗布性がわずかに劣る。
△(使用可能):○と比較して、均一塗布性が劣るが、使用可能である。
×(不良):弾性が高く、剤の伸び広がりが悪く、洗浄剤が均一に塗布できない。
実施例及び比較例で得られた各洗浄剤(約1.0g)を、手のひらでのばした後、約40℃のお湯適量と混ぜながら20回手のひらで泡立てた後の泡質を、下記評価基準に従って専門評価員4名が評価を行った。
[塗布時の伸び評価基準]
◎(優れる):泡のキメ、弾力がある。
○(良好):◎と比較して、泡のキメ、弾力がわずかに劣る。
△(使用可能):○と比較して、泡のキメ、弾力が劣るが、使用可能。
×(不良):泡立ちが悪く、手のひらから垂れ落ちる。
実施例及び比較例で得られた各洗浄剤50gを、ポリプロピレン製のチューブ容器(100mL容量、吐出口の内径5mm)の内部に注入し、吐出口まで充填し、40℃の恒温槽に4週間保存した。その後、チューブ容器の吐出口を10秒間下に向けて20℃の雰囲気中でチューブ容器の吐出口からの各洗浄剤の垂れ落ちの有無を目視で観察した。また、20℃の雰囲気中で透明ガラス板上に各洗浄剤を吐出し、吐出された各洗浄剤の状態を目視で観察した。さらに、各洗浄剤(約1.0g)を、手のひらでのばした際の伸びのよさを評価した。そして、保存後の洗浄剤の垂れ落ちの有無、状態、及び伸びを、下記評価基準に従って専門評価員4名が評価した。なお、状態が液状と判断された洗浄剤については、伸びの評価は行わなかった。
[保存安定性の評価基準]
◎(優れる):チューブ容器の吐出口から洗浄剤の垂れ落ちがなく、半固体状の性状を保持しており、且つ、前記「(2)伸び」の評価基準△以上の均一塗布性がある。
○(良好):チューブ容器の吐出口から洗浄剤の垂れ落ちがなく、洗浄剤の表面にわずかな流動化が認められ、且つ、前記「(2)伸び」の評価基準△以上の均一塗布性がある。
△(使用可能):チューブ容器の吐出口から洗浄剤の僅かな垂れ落ちが認められ、洗浄剤の表面に明らかな流動化が認められ、且つ、前記「(2)伸び」の評価基準△以上の均一塗布性がある。
×1(不良):チューブ容器の吐出口から洗浄剤の垂れ落ちが認められ、液体状である。
×2(不良):チューブ容器の吐出口から洗浄剤の垂れ落ちがなく、半固体状の性状を保持しているが、剤の伸び広がりが悪く、洗浄剤が均一に塗布できない。
(処方例1:クールタイプ)
ラウリン酸 5.0質量%
ミリスチン酸 10.0質量%
ステアリルアルコール 5.0質量%
(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
0.3質量%
キタンサンガム 0.15質量%
ラウリン酸アミドプロピルベタイン液(30%) 3.0質量%
水酸化カリウム 適量(pH9.8に調整)
エデト酸四ナトリウム四水塩 0.05質量%
l−メントール 0.9質量%
香料 0.2質量%
精製水 残量
ラウリン酸 5.0質量%
ミリスチン酸 9.0質量%
パルミチン酸 2.0質量%
セチルアルコール 2.0質量%
ステアリルアルコール 3.0質量%
(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
0.3質量%
カチオン化グァーガム 0.2質量%
ラウリン酸アミドプロピルベタイン液(30%) 2.0質量%
塩化ジメチルジアリルアンモニウム・アクリルアミド
共重合体液(8.5%) 3.0質量%
グリセリン 30.0質量%
水酸化カリウム 適量(pH9.8に調整)
エデト酸四ナトリウム四水塩 0.05質量%
香料 0.2質量%
ヒアルロン酸 0.1質量%
コラーゲン 0.1質量%
精製水 残量
ラウリン酸 5.0質量%
ミリスチン酸 10.0質量%
パルミチン酸 2.0質量%
ステアリン酸 1.0質量%
ステアリルアルコール 5.0質量%
(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー
0.25質量%
ラウリン酸アミドプロピルベタイン液(30%) 2.0質量%
グリセリン 10.0質量%
水酸化カリウム 適量(pH9.8に調整)
エデト酸四ナトリウム四水塩 0.05質量%
l−メントール 0.3質量%
香料 0.2質量%
結晶セルロース 5.0質量%
シリカ 1.0質量%
ベントナイト 0.5質量%
薬用炭 0.1質量%
精製水 残量
Claims (6)
- 下記成分(A)、下記成分(B)、及び下記成分(C)を含有し、前記成分(A)の含有割合が5.0〜25.0質量%である、半固体状洗浄剤。
成分(A):成分(A)の総量100質量%に対して10質量%以上のミリスチン酸を含有する高級脂肪酸及び/又はその塩
成分(B):20℃で固体であり且つ炭素数16〜20である高級アルコール
成分(C):カルボキシビニルポリマー - 前記成分(C)がアルキル変性カルボキシビニルポリマーである、請求項1に記載の半固体状洗浄剤。
- 前記成分(B)の含有割合が1.0〜10.0質量%であり、前記成分(C)の含有割合が0.1〜1.0質量%である、請求項1又は2に記載の半固体状洗浄剤。
- 下記成分(D)を含有する、請求項1〜3のいずれか1項に記載の半固体状洗浄剤。
成分(D):多糖増粘剤 - 下記成分(E)を含有する、請求項1〜4のいずれか1項に記載の半固体状洗浄剤。
成分(E):界面活性剤 - 前記成分(C)が(アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマーである、請求項1〜5のいずれか1項に記載の半固体状洗浄剤。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017187558 | 2017-09-28 | ||
JP2017187558 | 2017-09-28 | ||
PCT/JP2018/032024 WO2019065060A1 (ja) | 2017-09-28 | 2018-08-29 | 半固体状洗浄剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2019065060A1 JPWO2019065060A1 (ja) | 2020-02-27 |
JP6900496B2 true JP6900496B2 (ja) | 2021-07-07 |
Family
ID=65903250
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019544454A Active JP6900496B2 (ja) | 2017-09-28 | 2018-08-29 | 半固体状洗浄剤 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP6900496B2 (ja) |
KR (1) | KR102331771B1 (ja) |
CN (1) | CN110809463B (ja) |
WO (1) | WO2019065060A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2024142838A1 (ja) * | 2022-12-26 | 2024-07-04 | 株式会社 資生堂 | 組成物 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1051461A (en) * | 1963-11-04 | 1966-12-14 | Gillette Co | Dermatologic composition |
GB1109511A (en) * | 1965-02-05 | 1968-04-10 | Unilever Ltd | Skin cleansing composition |
SE353658B (ja) * | 1967-06-13 | 1973-02-12 | Dow Corning | |
JPH0753649B2 (ja) * | 1985-11-02 | 1995-06-07 | ポーラ化成工業株式会社 | メ−クアツプ化粧料 |
GB9414572D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Soap composition |
US5534265A (en) * | 1994-08-26 | 1996-07-09 | The Procter & Gamble Company | Thickened nonabrasive personal cleansing compositions |
USH2043H1 (en) * | 1997-05-23 | 2002-08-06 | The Procter & Gamble Company | Skin care compositions |
JP3600437B2 (ja) * | 1997-09-30 | 2004-12-15 | 株式会社資生堂 | 水中油型毛髪化粧料 |
US7074747B1 (en) * | 1999-07-01 | 2006-07-11 | Johnson & Johnson Consumer Companies, Inc. | Cleansing compositions |
JP3704602B2 (ja) | 2000-11-28 | 2005-10-12 | 株式会社マンダム | 洗浄剤組成物 |
JP2002255788A (ja) * | 2001-02-28 | 2002-09-11 | Mandom Corp | 半固形状洗浄剤組成物 |
SE0103528D0 (sv) * | 2001-10-21 | 2001-10-21 | Jan Faergeman | Topiska kompositioner med förstärkt effekt |
US20050176615A1 (en) * | 2002-06-25 | 2005-08-11 | Koichi Kinoshita | Detergent compositions |
US7378479B2 (en) * | 2002-09-13 | 2008-05-27 | Lubrizol Advanced Materials, Inc. | Multi-purpose polymers, methods and compositions |
JP2004231580A (ja) * | 2003-01-30 | 2004-08-19 | Mandom Corp | 身体用洗浄剤組成物及び洗顔剤 |
JP2005002039A (ja) | 2003-06-11 | 2005-01-06 | Mandom Corp | 半固形状洗顔剤組成物 |
DE10327138A1 (de) * | 2003-06-17 | 2005-01-13 | Henkel Kgaa | Hemmung der asexuellen Vermehrung von Pilzen |
US7759296B2 (en) * | 2003-06-19 | 2010-07-20 | Lubrizol Advanced Materials, Inc. | Cationic polymers and fixative application therefor |
AU2006227205A1 (en) * | 2005-03-23 | 2006-09-28 | Mary Kay Inc. | Skin lightening compositions |
CN101484127B (zh) * | 2006-07-04 | 2013-03-20 | 花王株式会社 | 皮肤用清洁剂组合物 |
JP5089196B2 (ja) | 2007-03-02 | 2012-12-05 | 株式会社マンダム | 半固形状洗顔剤用組成物 |
JP2009275009A (ja) * | 2008-05-16 | 2009-11-26 | Kao Corp | 皮膚洗浄剤組成物 |
DE102010021671A1 (de) * | 2010-05-27 | 2011-12-01 | Intendis Gmbh | Azelainsäurehaltige Formulierung mit Pigmentzusatz |
MX340844B (es) * | 2010-12-09 | 2016-07-27 | Colgate Palmolive Co | Composición de limpieza. |
CN102133163B (zh) * | 2011-02-25 | 2012-07-18 | 广州市天吻娇颜化妆品有限公司 | 一种洗面奶 |
JP5714359B2 (ja) * | 2011-02-28 | 2015-05-07 | 株式会社マンダム | 半固体状洗浄剤 |
CA2833803C (en) * | 2011-04-21 | 2020-04-07 | Mary Kay Inc. | Topical skin care formulations comprising clerodendrum trichotomum extracts |
KR101877805B1 (ko) * | 2011-11-18 | 2018-07-13 | (주)아모레퍼시픽 | 자외선 흡수제 또는 차단제가 포함된 비드를 함유하는 젤타입 자외선 차단용 화장료 조성물 |
CN103550108B (zh) * | 2013-11-15 | 2016-01-20 | 广州好迪集团有限公司 | 营养头发及损伤修复洗发液 |
CN105560100A (zh) * | 2015-12-26 | 2016-05-11 | 青岛朝阳华泰管理咨询服务有限公司 | 一种宠物用香波 |
CN106994105A (zh) * | 2017-04-18 | 2017-08-01 | 徐丹 | 一种磨面膏 |
-
2018
- 2018-08-29 JP JP2019544454A patent/JP6900496B2/ja active Active
- 2018-08-29 CN CN201880043964.0A patent/CN110809463B/zh active Active
- 2018-08-29 WO PCT/JP2018/032024 patent/WO2019065060A1/ja active Application Filing
- 2018-08-29 KR KR1020207000087A patent/KR102331771B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN110809463B (zh) | 2022-09-09 |
WO2019065060A1 (ja) | 2019-04-04 |
KR20200015698A (ko) | 2020-02-12 |
KR102331771B1 (ko) | 2021-12-01 |
CN110809463A (zh) | 2020-02-18 |
JPWO2019065060A1 (ja) | 2020-02-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5020415B1 (ja) | ゲル状洗浄料 | |
JP5965803B2 (ja) | デオドラント組成物及びデオドラント剤 | |
JP5522828B2 (ja) | 皮膚洗浄剤 | |
JP2008231346A (ja) | 洗浄料 | |
JP6235214B2 (ja) | 毛髪化粧料 | |
TWI680771B (zh) | 清洗製品 | |
JP6602119B2 (ja) | 皮膚洗浄剤 | |
JP2005015359A (ja) | 皮膚洗浄剤組成物 | |
JP6900496B2 (ja) | 半固体状洗浄剤 | |
JP5089196B2 (ja) | 半固形状洗顔剤用組成物 | |
JP2015172187A (ja) | 洗浄剤組成物 | |
JP2003267835A (ja) | オイルクレンジング組成物 | |
JP2010150175A (ja) | シャンプー組成物 | |
JP5495709B2 (ja) | 皮膚洗浄剤組成物 | |
JP2011144143A (ja) | 皮膚外用剤 | |
JP6328495B2 (ja) | ジェル状皮膚洗浄料 | |
JP6242179B2 (ja) | 透明洗浄剤用組成物 | |
JP2018070825A (ja) | 洗浄剤組成物 | |
JP2005314615A (ja) | 洗浄剤組成物 | |
JP5192871B2 (ja) | 洗浄剤組成物 | |
JP2020529966A (ja) | 死海塩化粧品組成物 | |
US20240189209A1 (en) | Additive composition for improving bubble density and bubble elasticity and composition for skin cleansing | |
JP5470941B2 (ja) | 毛髪洗浄剤組成物 | |
JP7293007B2 (ja) | 洗浄料組成物 | |
JP2003095917A (ja) | 固形状クレンジング料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20191011 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200721 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200916 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20210202 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20210323 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20210601 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20210616 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6900496 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |