JP6715840B6 - カチオン性ポリマーを含有するヘアケア組成物 - Google Patents
カチオン性ポリマーを含有するヘアケア組成物 Download PDFInfo
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- JP6715840B6 JP6715840B6 JP2017527768A JP2017527768A JP6715840B6 JP 6715840 B6 JP6715840 B6 JP 6715840B6 JP 2017527768 A JP2017527768 A JP 2017527768A JP 2017527768 A JP2017527768 A JP 2017527768A JP 6715840 B6 JP6715840 B6 JP 6715840B6
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- 102000004169 proteins and genes Human genes 0.000 description 1
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- WROMPOXWARCANT-UHFFFAOYSA-N tfa trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F.OC(=O)C(F)(F)F WROMPOXWARCANT-UHFFFAOYSA-N 0.000 description 1
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- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 description 1
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
発明の陳述
例示的なカチオン性ポリマーの調製
本発明による例示的なカチオン性ポリマーは、表1に列挙される構成成分を含有する。
例示及び比較のヘアケア組成物の調製
例示(本発明のサンプルE1及びE2)及び比較の(比較のサンプルC1)ヘアケア組成物は、表2に列挙される構成成分を含有する。
シャンプー製剤の評価
上記の実施例1〜2において調製された製剤を、小型引張試験機を使用して、外観及びウェットコーム力低下について評価した。編んだ一房の髪(約5g)を、界面活性剤溶液単独(0.5g)を用いるか、または界面活性剤及びカチオン性ポリマーを含有したシャンプー製剤を用いるかのいずれかで洗浄した。処理された編んだ一房の髪を、一定温度ですすぎ、引張試験機に装着した。櫛を、40mm/分の引張速度及び160mmの引張経路長で、各編んだ一房の髪を通して引っ張った。編んだ一房の髪をとかすために必要とされる力を、曲線の下の領域として測定した。シャンプー製剤内のコンディショニングポリマーの性能を、ポリマーを有さないシャンプーを用いて洗浄された濡れた髪のコーミング摩擦に対して、髪をそのような製剤を用いて処理するときのコーミング摩擦の低下として決定した。結果を、ウェットコームワークダン値(wet combing work done)(WCWD、引張曲線のウェットコーム領域)として報告する。結果を、表3に示す。
例示及び比較のヘアケア組成物の調製
例示(本発明のサンプルE3)及び比較の(比較のサンプルC2)ヘアケア組成物は、表4に列挙される構成成分を含有する。
目的のウェットコーム評価
上記の実施例1及び4において調製された製剤を、小型引張試験機を使用して、ウェットコーム力低下について評価した。編んだ一房の髪(約5g)を、界面活性剤溶液単独(0.5g)を用いるか、または界面活性剤及びカチオン性ポリマーを含有したシャンプー製剤を用いるかのいずれかで洗浄した。処理された編んだ一房の髪を、一定温度ですすぎ、引張試験機に装着した。櫛を、40mm/分の引張速度及び160mmの引張経路長で、各編んだ一房の髪を通して引っ張った。編んだ一房の髪をとかすために必要とされる力を、曲線の下の領域として測定した。シャンプー製剤内のコンディショニングポリマーの性能を、濡れた未処理の髪のコーミング摩擦に対して、髪をそのような製剤を用いて処理するときのコーミング摩擦の低下として決定した。結果を、ウェットコームワークダン値(WCWD、引張曲線のウェットコーム領域)として、または対照としての未処理の濡れた編んだ一房の髪についてのウェットコームワークに対する、ウェットコームにおけるワーク低下(RWC)の割合として報告する。
図1に示される通り、本発明のシャンプー製剤E3を用いて処理された編んだ一房の髪は、比較の製剤C2よりも低いウェットコームワークダン値を証明した。これらの結果から、本発明のポリマーを含有する本発明のヘアケア組成物が、髪に適用される場合、優れたウェットコーム能力を提供することが証明される。
Claims (8)
- ヘアケア組成物であって、
(a)カチオン性ポリマーであり、
(i)30〜80重量%の(3−アクリルアミドプロピル)トリメチルアンモニウムクロライド(APTAC)、
(ii)10〜65重量%の下記構造:
(iii)2〜30重量%のアクリルモノマーの極性非イオン性誘導体であって、(メタ)アクリル酸及びそれらのC 1 −C 22 アルキルまたはヒドロキシアルキルエステル、クロトン酸、イタコン酸、フマル酸、マレイン酸、無水マレイン酸、(メタ)アクリロニトリル、及びクロトン酸、イタコン酸、フマル酸、またはマレイン酸のアルキルまたはヒドロキシアルキルエステル、並びに下記構造:
(b)少なくとも1つの美容的に許容される界面活性剤、レオロジー調整剤、または美容活性剤と、を含む、ヘアケア組成物。 - 前記アクリルモノマーの極性非イオン性誘導体は、5〜25重量%の量で存在する、請求項1に記載のヘアケア組成物。
- 前記パーソナルケア組成物は、リーブオンコンディショナー、ヘアトリートメント製剤、またはコーミングクリームである、請求項1または2に記載のヘアケア組成物。
- 前記アクリルモノマーの極性非イオン性誘導体は、2−(ジメチルアミノ)エチルアクリレート、2−(ジメチルアミノ)エチルメタクリレート、及び3−(ジメチルアミノ)プロピルアクリレートのうちの少なくとも1つを含む、アルキル(メタ)アクリレートのうちの少なくとも1つを含む、請求項1〜3のいずれか1項に記載のヘアケア組成物。
- 前記カチオン性ポリマーは、前記組成物の重量で、0.05〜10重量%の範囲で存在する、請求項1〜4のいずれか1項に記載のヘアケア組成物。
- 髪を処理するための方法であって、
(a)カチオン性ポリマーであり、
(i)30〜80重量%の(3−アクリルアミドプロピル)トリメチルアンモニウムクロライド(APTAC)、
(ii)10〜65重量%の下記構造:
(iii)2〜30重量%のアクリルモノマーの極性非イオン性誘導体であって、
(メタ)アクリル酸及びそれらのC 1 −C 22 アルキルまたはヒドロキシアルキルエステル、クロトン酸、イタコン酸、フマル酸、マレイン酸、無水マレイン酸、(メタ)アクリロニトリル、及びクロトン酸、イタコン酸、フマル酸、またはマレイン酸のアルキルまたはヒドロキシアルキルエステル、並びに下記構造:
(b)少なくとも1つの美容的に許容される界面活性剤、レオロジー調整剤、または美容活性剤と、を含むパーソナルケア組成物に髪を接触させることを含む、方法。 - 前記アクリルモノマーの極性非イオン性誘導体は、5〜25重量%の量で存在する、請求項6に記載の方法。
- 前記パーソナルケア組成物は、リーブオンコンディショナー、ヘアトリートメント製剤、またはコーミングクリームである、請求項6または7に記載の方法。
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PCT/US2015/061054 WO2016085706A1 (en) | 2014-11-25 | 2015-11-17 | Hair care compositions containing cationic polymers |
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WO2016085707A1 (en) * | 2014-11-25 | 2016-06-02 | The Dow Chemical Company | Personal care compositions containing cationic polymers |
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US5338541A (en) * | 1992-10-15 | 1994-08-16 | Calgon Corporation | Dual cationic terpolymers providing superior conditioning properties in hair, skin and nail care products |
FR2702653B1 (fr) | 1993-03-16 | 1995-05-24 | Oreal | Utilisation en cosmétique ou en application topique d'une dispersion aqueuse à base d'organopolysiloxanes non volatils et d'un polymère réticulé de chlorure de méthacryloyloxyéthyl triméthylammonium . |
FR2737660B1 (fr) * | 1995-08-11 | 1997-09-12 | Oreal | Composition cosmetique a pouvoir fixant et/ou conditionneur contenant un copolymere acrylique particulier |
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JP2003095887A (ja) * | 2001-09-27 | 2003-04-03 | Lion Corp | 毛髪洗浄剤組成物 |
WO2003039499A1 (en) | 2001-11-02 | 2003-05-15 | The Procter & Gamble Company | Composition containing a cationic polymer and water insoluble solid material |
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JP2003176496A (ja) * | 2001-12-13 | 2003-06-24 | Kao Corp | 洗浄剤組成物 |
WO2004069979A2 (en) | 2003-02-03 | 2004-08-19 | Unilever Plc | Laundry cleansing and conditioning compositions |
FR2851251B1 (fr) | 2003-02-13 | 2005-04-08 | Seppic Sa | Nouveaux epaississants cationiques, procede pour leur preparation et composition en contenant |
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US10507176B2 (en) | 2014-11-25 | 2019-12-17 | Dow Global Technologies Llc | Hair care compositions containing cationic polymers |
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